Patent Application
20240158682
This disclosure relates generally to thermal management fluids. More particularly this disclosure relates to a dielectric thermal management fluid suitable for use managing heat in battery systems through direct cooling, such as lithium-ion batteries used in electric vehicles, electric motors, and power electronics, methods of using such thermal management fluids, and systems including such thermal management systems.
The number of electric vehicles (i.e., vehicles using electric power for all or a portion of their motive power such as battery electric vehicles (BEVs), hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and the like) sold globally has increased over the last several years, and is expected to continue to increase. Ultimately, the vast majority of vehicles will likely be electric. As electric vehicle technology continues to evolve, there is a need to provide improved power sources (e.g., battery systems or modules). For example, it is desirable to increase the distance that such vehicles may travel without the need to recharge the batteries, to improve the performance of such batteries, and to reduce the costs and time associated with battery charging.
Most batteries will generate heat as current is delivered to or drawn from the batteries. Typically, as the amount of current flowing into or out of the battery increases, the amount of heat that is generated also increases. If the heat that is generated is not dissipated the battery will rise in temperature. Most batteries have an effective operating temperature range, and if the battery exceeds the maximum operating temperature, the batteries can become ineffective or even result in thermal runaway and failure. In some cases, after a slight rise in temperature, a battery may be able to dissipate heat to its surroundings through a simple heat sink or without any thermal management. In other cases, a more specific thermal management system is needed to dissipate heat that is generated by the battery.
Currently, battery-powered electric vehicles almost exclusively use lithium-ion battery technology. Lithium-ion batteries offer many advantages over the comparable nickel-metal-hydride batteries, but as compared to nickel-metal-hydride batteries, lithium-ion batteries are more susceptible to variations in battery temperature and thus have more stringent thermal management requirements. For example, optimal lithium-ion battery operating temperatures are in the range of 10 and 35° C. Operation is increasingly inefficient as temperatures rise from 35 to 70° C., and, more critically, operation at these temperatures can damage the battery over time. Temperatures over 70° C. present increased risk of thermal runaway. As a result, lithium-ion batteries require specific thermal management systems to regulate their temperatures during vehicle operation. In addition, during charging, up to 10% of the inputted power ends up as heat. As the fast charging of lithium-ion batteries becomes more common, the need remains for efficient systems for thermal management of the batteries.
Lithium-ion batteries may be cooled directly or indirectly, using thermal management fluids to carry heat away from the battery component (i.e., as a cooling fluid or coolant). Direct cooling advantageously allows the thermal management fluid to come into direct contact with the hot components to carry heat away therefrom. In indirect cooling, a hot component is electrically shielded by an electrically-insulating barrier and the thermal management fluid carries away heat passing through this barrier. The most common thermal management fluids are based on mixtures of water with glycol. But because water-based fluids typically conduct electricity, they cannot be used in the direct cooling of electrical components of lithium-ion batteries. While indirect cooling allows for water-based coolants to be used, the requirement of electrical shielding can create a bottleneck for heat flow in the cooling process. There exist dielectric thermal management fluids that can be used for direct cooling of electrical components due to their non-electrically-conductive nature; examples include those conventionally used in the cooling of electrical transformers. However, the thermal properties of such dielectric thermal management fluids are typically poor in comparison to water-glycol.
Thus, there remains a need for improved dielectric thermal management systems, especially those suitable for use in the cooling of lithium-ion batteries.
One aspect of the disclosure provides thermal management fluids that have a flash point of at least 100° C., measured in accordance with ASTM D93, and have a dielectric constant of at least 1.5 at 25° C. Such dielectric thermal management fluids include:
Another aspect of the disclosure provides a battery system. The battery system includes a housing; one or more electrochemical cells disposed in the housing; a fluid path extending in the housing and in substantial thermal communication with the one or more electrochemical cells; and a thermal management fluid of the disclosure as described herein disposed in the fluid path.
In another aspect, the disclosure provides an electric vehicle comprising the battery system of the disclosure as described herein.
In another aspect the disclosure provides a thermal management circuit including: a fluid path extending around and/or through a heat source; and a thermal management fluid of the disclosure, disposed in and configured to circulate in the fluid path and to absorb thermal energy produced by the heat source, wherein the fluid is disposed in the fluid path, the heat exchanger, the pump and the connecting duct.
Another aspect of the disclosure provides a method including contacting a thermal management fluid of the disclosure with a surface having a temperature of at least 25° C. (e.g., at least 30° C.), the surface being in substantial thermal communication with a heat source; and absorbing thermal energy in the thermal management fluid from the heat source through the surface.
Another aspect of the disclosure provides a method for preparing the thermal management fluid of the disclosure. Such method includes contacting a compound of formula (II)
Another aspect of the disclosure provides a method for preparing the thermal management fluid of the disclosure. Such method includes contacting a compound of formula (III)
The accompanying drawings are included to provide a further understanding of the compositions and methods of the disclosure, and are incorporated in and constitute a part of this specification. The drawings are not necessarily to scale, and sizes of various elements may be distorted for clarity. The drawings illustrate one or more embodiment(s) of the disclosure and, together with the description, serve to explain the principles and operation of the disclosure.
The present inventors have noted that desirable thermal management fluids would in many cases have a high capacity to carry heat away in a temperature range relevant to operation of a particular electrical device or system (e.g., a lithium-ion battery), yet have a sufficiently high dielectric constant to be suitable for use in direct cooling of the device or system. Critically, because there is always a risk that oxygen might enter the overall system, desirable thermal management fluids would advantageously have a high flash point, to reduce the risk of ignition. And to provide more efficient heat transfer during the operation, desirable thermal management fluids would advantageously have low viscosity allowing for better flowability in a particular electrical device or system.
The present inventors have identified thermal management fluid compositions that provide not only a desirably low viscosity but also have a high flash point, so they can be easily pumped through a system with low-to-no risk of ignition. Specifically, the present inventors recognized that conventional dielectric fluids (e.g., organic or silicone) typically have good thermal conductivity and specific heat capacity but have undesirably high viscosity. Typical low-viscosity dielectric fluids, however, generally have unacceptably low flash points (and other ignition properties) making them unsuitable for use as coolants in systems where there is the potential for temperatures to rise where ignition is a risk. The present inventors have determined that the dielectric compounds of the disclosure can provide a thermal management fluid that does not have a low flash point and has advantageously low viscosity. These properties of the thermal management fluid make them particularly suitable, for example, for direct cooling of electrical devices and systems.
The thermal management fluids and methods of the disclosure can have a number of additional advantages over conventional fluids. Notably, the thermal management fluid of the disclosure can also, in various embodiments, provide one or more of desirably high heat conductivity, low risk of ignition, high dielectric constant, and fast temperature response. The thermal management fluid of the disclosure can in various embodiments also have lower surface tension than conventional low-viscosity dielectric fluids.
Thus, one aspect of the disclosure provides a thermal management fluid including one or more dielectric compounds of formula (I), the one or more dielectric compounds being present in a total amount in the range of 1 wt % to 100 wt %. Such thermal management fluids can have a flash point of at least 100° C., measured in accordance with ASTM D93 (“Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester”), and a dielectric constant of at least 1.5 at 25° C.
Because there is always some risk that oxygen might enter the system, the thermal management fluids of the disclosure advantageously have a high flash point to prevent ignition. As described above, the thermal management fluids of the disclosure can have a flash point of at least 100° C., as measured in accordance with ASTM D93. For example, in various embodiments, a thermal management fluid as otherwise described herein has a flash point of at least 110° C., e.g., at least 120° C., at least 125° C., at least 130° C., or at least 135° C., measured in accordance with ASTM D93. In various embodiments, a thermal management fluid as otherwise described herein has a flash point of at least 140° C., e.g., at least 145° C., at least 150° C., or at least 155° C., measured in accordance with ASTM D93. A material that does not have a flash point below 100° C. is considered to have a flash point above 100° C. for the purposes of this disclosure, even if no flash point is measurable for the material (i.e., due to decomposition at a temperature below where a flash point is reached).
A low viscosity is often desired for a thermal management fluid, to simplify the pumping thereof through a system, especially when relatively narrow passageways are used. The person of ordinary skill in the art will, based on the present disclosure, select components to provide the thermal management fluids with a desired viscosity, e.g., to be conveniently conducted through a system. Accordingly, in various embodiments, a thermal management fluid as otherwise described herein has a kinematic viscosity at 40° C. in the range of 1.5 to 20 cSt, e.g., in the range of 1.5 to 15 cSt, or 2 to 15 cSt, or 2 to 20 cSt, or 3 to 20 cSt, or 3 to 15 cSt, or 5 to 20 cSt, or 5 to 15 cSt. In various embodiments, a thermal management fluids as otherwise described herein has a kinematic viscosity at 40° C. in the range of 1.5 to 10 cSt, e.g., 1.5 to 8 cSt, or 1.5 to 6 cSt, or 2 to 10 cSt, or 2 to 8 cSt, or 2 to 6 cSt, or 3 to 10 cSt, or 3 to 8 cSt, or 3 to 6 cSt, or 5 to 10 cSt, or 5 to 8 cSt, or 5 to 6 cSt, or 6 to 10 cSt, or 8 to 10 cSt, as measured in accordance with ASTM D455. And in various embodiments, a thermal management fluids as otherwise described herein has a kinematic viscosity at 40° C. in the range of 1.5 to 5 cSt, e.g., 1.5 to 4 cSt, or 1.5 to 3 cSt, or 2 to 5 cSt, or 2 to 4 cSt, or 2 to 3 cSt, or 3 to 5 cSt, or 3 to 4 cSt, or 4 to 5 cSt, as measured in accordance with ASTM D455.
The thermal management fluids of the disclosure are desirably dielectric, so that they can be used in direct cooling applications. Accordingly, they have a dielectric constant of at least 1.5 as measured at 25° C. The dielectric constant is measured using the coaxial probe method, using ASTM D924. In various embodiments, a thermal management fluid of the disclosure has a dielectric constant of at least 1.75, e.g., at least 2.0, or at least 2.25 as measured at 25° C. In various embodiments, a thermal management fluid of the disclosure has a dielectric constant in the range of 1.5 to 10, or 1.8 to 10, or 1.5 to 2.8, or 1.8 to 2.8.
In various embodiments of the disclosure, the thermal management fluid of the disclosure may have density of no more than 1.1 g/cm3 at 25° C. For example, in various embodiments of the disclosure, the thermal management fluid of the disclosure may have density of no more than 1 g/cm3 at 25° C.
In various embodiments of the disclosure, the thermal management fluid of the disclosure may have a heat capacity of at least 1 J/g·K, or at least 1.2 J/g·K, or even at least 1.5 J/g·K, at 25° C. In various embodiments of the disclosure, the thermal management fluid of the disclosure may have a thermal conductivity in the range of 0.05 W/m·K to 1 W/m·K at 25° C. In various embodiments of the disclosure, the thermal management fluid of the disclosure may have a coefficient of thermal expansion is no more than 1100×10−6/K (e.g., no more than 1050×10−6/K, or no more than 1000×10−6/K).
As described above, the thermal management fluid of the disclosure includes one or more dielectric compounds of formula (I).
The person of ordinary skill in the art can select the chain length and branching of R1 and R2 based on the disclosure herein to select properties of the overall material, e.g., viscosity and flash point.
In the one or more dielectric compounds of formula (I) as described herein R1 is C1-C5 alkyl. In various embodiments as otherwise described herein, in one or more dielectric compounds of formula (I) R1 is C3-C5 alkyl. In various embodiments as otherwise described herein, in one or more dielectric compounds of formula (I) R1 is a branched C3-C5 alkyl, such as branched C4-C5 alkyl. Branching can be, for example, at an α-position or at a β-position with respect to the oxygen atom to which R1 is bound. In various embodiments, branching is at an α-position with respect to the oxygen atom. For example, in various embodiments as otherwise described herein, in one or more dielectric compounds of formula (I) R1 is an α-branched C3-C5 alkyl, such as t-butyl or t-pentyl. In various embodiments as otherwise described herein, in one or more dielectric compounds of formula (I) R1 is —C(CH3)(CH3)(Rc), wherein Rc is methyl or ethyl.
In the one or more dielectric compounds of formula (I) as otherwise described herein R2 is C6-C12 alkyl, such as C6-C10 or C6-C8 alkyl. In various embodiments of the dielectric compounds of formula (I) of the disclosure, R2 is C8-C12 alkyl, such as C8-C10 alkyl or C10-C12 alkyl. In various embodiments of the dielectric compounds of formula (I) of the disclosure, R2 is a branched C6-C12 alkyl, such as branched C6-C10 alkyl, branched C6-C8 alkyl, branched C8-C12 alkyl, branched C8-C10 alkyl, or branched C10-C12 alkyl. Branching can be, for example, at an α-position or at a β-position with respect to the oxygen atom to which R2 is bound. In various embodiments, branching is at a β-position with respect to the oxygen atom. For example, in certain compounds of formula (I), R2 is a β-branched C6-C12 alkyl, such as β-branched C6-C10 alkyl, β-branched C6-C8 alkyl, β-branched C8-C12 alkyl, β-branched C8-C10 alkyl, or β-branched C10-C12 alkyl.
In various embodiments, in the one or more dielectric compounds of formula (I) as described herein each of R3, R4, R5 and R6 is independently selected from H and C1-C4 alkyl (such as C1-C3 alkyl or C1-C2 alkyl). In certain other embodiments, each of R3, R4, R5 and R6 is independently selected from H and C1 alkyl (i.e., methyl).
In various embodiments, each R4 is H and each R3 is H or C1-C6 alkyl (such as C1-C4 alkyl or C1-C2 alkyl); and each R5 is H and each R6 is H or C1-C6 alkyl (such as C1-C4 alkyl or C1-C2 alkyl). In various embodiments, R3 is H, R4 is H, R5 is H and each R6 is H or C1-C6 alkyl (such as C1-C4 alkyl or C1-C2 alkyl).
In various embodiments as otherwise described herein, in the one or more dielectric compounds of formula (I) each of R3, R4, R5, and R6 is H, i.e., the compounds have the formula:
In various embodiments, in the one or more dielectric compounds of formula (I) as otherwise described herein, each of R4, R5, and R6 is H, and R3 is H or C1-C6 alkyl. For example, in some embodiments, each of R4, R5, and R6 is H, and R3 is C1-C6 alkyl (such C1-C4 alkyl, C1-C3 alkyl, ethyl, or methyl), i.e., the compounds have the formula
In various embodiments, each of R4, R5, and R6 is independently H, and wherein R3 is C1-C6 alkyl (such C1-C4 alkyl, C1-C3 alkyl, ethyl, or methyl).
In various embodiments, in the one or more dielectric compounds of formula (I) as otherwise described herein, n is an integer 1 or 2. In various embodiments, n is an integer 2 or 3. In various embodiments, n is an integer 1, i.e., the compounds have the formula:
In various embodiments, the one or more dielectric compounds is of formula:
In various embodiments, the one or more dielectric compounds is of formula:
In various embodiments, n is an integer 2, i.e., the compounds have the formula:
In various embodiments as otherwise described herein, in the one or more dielectric compounds of formula (I) m is 1. However, in other embodiments, m is 2, or m is 3. In other embodiments, m is 4, or is 5.
In various embodiments as otherwise described herein, in the one or more dielectric compounds of formula (I) has the formula
in which m is 1, 2, 3, 4, or 5, R1 is C1-C5 alkyl, and R2 is C6-C10 alkyl. In certain such embodiment, R1 is methyl or ethyl. In certain such embodiments, R1 is propyl (e.g., n-propyl, isopropyl) or butyl, e.g., n-butyl, t-butyl, sec-butyl or isobutyl. In certain such embodiments, R1 is a branched pentyl, e.g., 1,1-dimethylpropyl, 2,2-dimethylpropyl. In certain such embodiments, R2 is branched, e.g., 2-ethylhexyl, or a group —CH2—CH(Rb)(Rd) in which Rb is methyl or ethyl, and Rd is C3-C8 alkyl, such as 2-ethylhexyl. In certain such embodiments, m is 1, In other embodiments, m is or 2 or 3. In still other embodiments, m is 4 or 5.
In various embodiments as otherwise described herein, the one or more dielectric compounds of formula (I) contain a total number of carbon atoms from 10 to 30 (e.g., from 10 to 26, from 10 to 22, from 10 to 18, from 12 to 30, from 12 to 26, from 12 to 22, from 14 to 30, from 14 to 26, or from 14 to 22). For example, in various embodiments the one or more dielectric compounds of formula (I) contains a total number of carbon atoms from 12 to 18. In various embodiments the one or more dielectric compounds of formula (I) contains a total number of carbon atoms from 14 to 22. In various embodiments the one or more dielectric compounds of formula (I) contains a total number of carbon atoms from 14 to 20.
Examples of the compounds of formula (I) of the disclosure include, but are not limited to:
In various embodiments as otherwise described herein, the one or more dielectric compounds of the thermal management fluid have a flash point of at least 100° C. measured in accordance with ASTM D93. The present inventors have advantageously determined that the use of the dielectric compounds of the disclosure having high flash points can provide an overall thermal management fluid with a high flash point and thereby decrease the risk of ignition. In various embodiments of the thermal management fluids as otherwise described herein, the one or more dielectric compounds has a flash point of at least 110° C. (e.g., at least 120° C., at least 125° C., at least 130° C., or at least 135° C.) or at least 140° C. (e.g., at least 145° C., at least 150° C., or at least 155° C.), measured in accordance with ASTM D93.
The present inventors have advantageously determined that the one or more dielectric compounds as described herein have relatively low viscosity yet a reduced risk of ignition. Accordingly, in various embodiments of the thermal management fluids as otherwise described herein, the one or more dielectric compounds has a kinematic viscosity at 40° C. in the range of 1.5 to 20 cSt, e.g., in the range of 1.5 to 15 cSt, or 2 to 20 cSt, or 2 to 15 cSt, or 3 to 20 cSt, or 3 to 15 cSt, or 5 to 20 cSt, or 5 to 15 cSt. In various embodiments of the thermal management fluids as otherwise described herein, the one or more dielectric compounds has a kinematic viscosity at 40° C. in the range of 1.5 to 10 cSt, e.g., 1.5 to 8 cSt, or 1.5 to 6 cSt, or 2 to 10 cSt, or 2 to 8 cSt, or 2 to 6 cSt, or 3 to 10 cSt, or 3 to 8 cSt, or 3 to 6 cSt, or 5 to 10 cSt, or 5 to 8 cSt, or 5 to 6 cSt, or 6 to 10 cSt, or 8 to 10 cSt, as measured in accordance with ASTM D455. And In various embodiments of the thermal management fluids as otherwise described herein, the one or more dielectric compounds has a kinematic viscosity at 40° C. in the range of 1.5 to 5 cSt, or 1.5 to 4 cSt, or 1.5 to 3 cSt, or 2 to 5 cSt, or 2 to 4 cSt, or 2 to 3 cSt, or 3 to 5 cSt, or 3 to 4 cSt, or 4 to 5 cSt, as measured in accordance with ASTM D455.
The person of ordinary skill in the art will appreciate that various combinations of dielectric compounds of the disclosure can be used in thermal management fluids of the disclosure. Accordingly, embodiments of dielectric compounds described above can be combined in any number and in any combination in thermal management fluids of the disclosure. When two or more dielectric compounds are used in a thermal management fluid, the relative amounts of the two can be varied based on the disclosure herein, depending on the effect desired. In various embodiments, the mass ratio of a first dielectric compound to a second dielectric compound is in the range of 1:9 to 9:1 (e.g., 1:5 to 5:1, or 1:5 to 1:1, or 1:1 to 5:1).
The one or more dielectric compounds can be present in the thermal management fluids described herein in a variety of amounts. In various embodiments as otherwise described herein, the one or more dielectric compounds is present in a total amount in the range of 1 wt % to 100 wt % (e.g., 5 wt % to 100 wt %, or 10 wt % to 100 wt %, or 20 wt % to 100 wt %) based on the total weight of the thermal management fluid. For example, in various embodiments, the one or more dielectric compounds is present in a total amount in the range of 50 wt % to 100 wt %, for example, 75 wt % to 100 wt %, or 85 wt % to 100 wt %, or 90 wt % to 100 wt %, or 95 wt % to 100 wt %, or 98 wt % to 100 wt %. For example, in various embodiments of the thermal management fluid as otherwise described herein, the one or more dielectric compounds is present in a total amount in the range of 1 wt % to 99.9 wt % (e.g., 5 wt % to 99.9 wt %, or 10 wt % to 99.9 wt %, or 20 wt % to 99.9 wt %), or 50 wt % to 99.9 wt %, for example, 75 wt % to 99.9 wt %, or 85 wt % to 99.9 wt %, or 90 wt % to 99.9 wt %, or 95 wt % to 99.9 wt %, or 98 wt % to 99.9 wt %, based on the total weight of the thermal management fluid. In various embodiments of the thermal management fluid as otherwise described herein, the one or more dielectric compounds is present in a total amount in the range of 1 wt % to 99 wt % (e.g., 5 wt % to 99 wt %, or 10 wt % to 99 wt %, or 20 wt % to 99 wt %), or 50 wt % to 99 wt %, for example, 75 wt % to 99 wt %, or 85 wt % to 99 wt %, or 90 wt % to 99 wt %, or 95 wt % to 99 wt %, based on the total weight of the thermal management fluid. In various embodiments of the thermal management fluid as otherwise described herein, the one or more dielectric compounds is present in a total amount in the range of 1 wt % to 95 wt % (e.g., 5 wt % to 95 wt %, or 10 wt % to 95 wt %, or 20 wt % to 95 wt %), or 50 wt % to 95 wt %, for example, 75 wt % to 95 wt %, or 85 wt % to 95 wt %, based on the total weight of the thermal management fluid. In various embodiments of the thermal management fluid as otherwise described herein, the one or more dielectric compounds is present in a total amount in the range of 1 wt % to 85 wt % (e.g., 5 wt % to 85 wt %, or 10 wt % to 85 wt %, or 20 wt % to 85 wt %), or 50 wt % to 85 wt %, for example, 65 wt % to 85 wt %, or 75 wt % to 85 wt %, based on the total weight of the thermal management fluid. The person of ordinary skill in the art will, based on the disclosure herein, provide the dielectric compound(s) in an amount to provide a desired high flash point to the thermal management fluid, in addition with any other desired properties (e.g., viscosity).
As the person of ordinary skill in the art will appreciate based, the thermal management fluids of the disclosure can also include a variety of other components, such as those conventional in compositions for thermal management applications. For example, the thermal management fluid may further include an oil, e.g., a mineral oil, a synthetic oil, or a silicone oil. For example, in various embodiments, the oil is a low-viscosity Group II, III, IV, or V base oil as defined by the American Petroleum Institute (API Publication 1509). These are shown in Table 1.
Group II and Group III base oils (such as hydrocracked and hydroprocessed base oils as well as synthetic oils such as hydrocarbon oils, polyalphaolefins, alkyl aromatics, and synthetic esters) and Group IV base oils (such as polyalphaolefins (PAO)) are wells known base oils. Oils suitable for use as transformer oils can, in many embodiments, be suitable for use in the compositions, systems and methods of the disclosure. For example, esters also form a useful base oil stock, including synthetic esters, as do GTL (gas-to-liquid) materials, particularly those derived from a hydrocarbon source. For example, the esters of dibasic acids with monoalcohols, or the polyol esters of monocarboxylic acid may be useful as base stocks of the disclosure. Bio-derived oils such as fatty acid methyl esters may also be useful.
In various embodiments, the thermal management fluid of the disclosure further comprises a Group II, Group III, Group IV, or Group V base oil. For example, in various embodiments, the thermal management fluid of the disclosure further comprises a Group II or Group III base oil. In certain other embodiments, the thermal management fluid of the disclosure further comprises a Group IV base oil such as polyalphaolefins (PAO). In certain other embodiments, the thermal management fluid of the disclosure further comprises an ester base oil stock.
In various embodiments, the thermal management fluid of the disclosure further comprises one or more of corrosion inhibitors, anti-oxidants (such as phenolic and aminic anti-oxidants), pour point depressants, antifoams, defoamers, viscosity index modifiers, preservatives, biocides, surfactants, seal swell additives, and combinations thereof. In various embodiments, corrosion inhibitors, anti-oxidants (such as phenolic and aminic anti-oxidants), pour point depressants, antifoams, defoamers, viscosity index modifiers, preservatives, biocides, surfactants, seal swell additives, and combinations thereof, for example, may be present in an amount up to 5.0 wt %, based on the total weight of the thermal management fluid. In certain such embodiments, one or more of corrosion inhibitors, anti-oxidants (such as phenolic and aminic anti-oxidants), pour point depressants, antifoams, defoamers, viscosity index modifiers, preservatives, biocides, surfactants, seal swell additives, and combinations thereof are present in an amount in the range of 0.2 wt % to 5.0 wt %, e.g., 1.0 wt % to 2.0 wt %, or 0.2 wt % to 1.0 wt %, or 0.2 wt % to 0.5 wt %, or 0.05 wt % to 0.2 wt %, based on the total weight of the thermal management fluid. In various embodiments, the thermal management fluid of the disclosure further comprises one or more flame retardants, e.g., in an amount up to 20 wt %, up to 10 wt %, or up to 5 wt %, based on the total weight of the thermal management fluid. In other embodiments, however, no flame retardant is present.
Another aspect of the disclosure provides a method comprising contacting a thermal management fluid as described herein with a surface having a temperature of at least 25° C., the surface being in substantial thermal communication with a heat source, and absorbing thermal energy in the thermal management fluid from the heat source through the surface.
The contacting of the thermal management fluid with the surface can be dynamic or static (i.e., conductive). For example, in various embodiments, the contacting of the thermal management fluid with the surface can be performed by circulating, e.g., by pumping or otherwise flowing, the fluid over the surface. In various embodiments, the contacting can also be performed without circulation, e.g., by contacting the surface with the thermal management fluid that is a stationary body of fluid.
The temperature of the surface can vary; the thermal management fluid can be adapted for use with a variety of temperatures. In various embodiments as otherwise described herein, the temperature of the surface is in the range of 25° C. to 150° C., e.g., 25° C. to 100° C., or 25° C. to 90° C., or 25° C. to 85° C., or 25° C. to 80° C., or 25° C. to 75° C., or 25° C. to 70° C. In various embodiments as otherwise described herein, the temperature of the surface is in the range of 30° C. to 150° C., e.g., 30° C. to 100° C., or 30° C. to 90° C., or 30° C. to 85° C., or 30° C. to 80° C., or 30° C. to 75° C., or 30° C. to 70° C. In various embodiments as otherwise described herein, the temperature of the surface is in the range of 40° C. to 150° C., e.g., 50° C. to 150° C., or 60° C. to 150° C., or 70° C. to 150° C., or 80° C. to 150° C., or 90° C. to 150° C., or 100° C. to 150° C., or 110° C. to 150° C. The temperature of the surface in various embodiments (and at certain times during operation of a device or system) is no more than a boiling point of any of the one or more dielectric compounds of formula (I) of the thermal management system. In various embodiments, throughout the contacting, each of the one or more dielectric compounds of formula (I) does not reach its boiling point.
An embodiment of the method of the disclosure is illustrated with reference to
In various embodiments as otherwise described herein, the method includes producing the thermal energy by operating an electrical component. For example, thermal management circuit 100 is associated with electrical component 140, which produces heat during operation. In various embodiments the heat is produced as elements of the electrical component charge and discharge. As will be understood by those of ordinary skill in the art, inefficiencies in the operation of the electrical component and resistances in the circuits corresponding circuits create heat as current passes through the circuits and elements of the electrical component. For example, the heat from the operation of electrical component 140 causes surface 142 to rise in temperature, which then results in the transfer of thermal energy to thermal management fluid 120. In other embodiments, the thermal energy is produced by a chemical reaction, such as an exothermic reaction, or by friction. In still other embodiments, the thermal management fluid is chilled and absorbs thermal energy from surfaces at ambient or slightly elevated temperatures.
In various embodiments as otherwise described herein, the electrical component includes a battery system, a capacitor, inverter, electrical cabling, a fuel cell, a motor, or a computer. For example, in various embodiments the electrical component is a battery system that includes one or more electrochemical cells disposed in a housing. In other embodiments the electrical component is one or more capacitors, such as an electrolytic capacitor or an electric double-layer capacitor, e.g., a supercapacitor. In still other embodiments, the electrical component is one or more fuel cells, such as a polymer electrolyte membrane fuel cell, a direct methanol fuel cell, an alkaline fuel cell, a phosphoric acid fuel cell, a molten carbonate fuel cell, a solid oxide fuel cell, or a reversible fuel cell. In various embodiments the electrical component is an electric motor. In other embodiments, the electrical component is a computer, for example a personal computer or a server. Still, in other embodiments, the electrical component is a high power charging equipment.
The electrical component of the disclosure can operate on direct current (DC) or alternating current (AC). In various embodiments as otherwise described herein, the electrical component operates at DC or AC voltage above 48 V. In various embodiments as otherwise described herein, the electrical component operates at DC or AC voltage above 100 V, above 200 V, or above 300 V.
In various embodiments as otherwise described herein, the surface is a surface of the electrical component. For example, in
In various embodiments as otherwise described herein, the surface is an internal surface of a conduit. For example,
In various embodiments as otherwise described herein, the conduit passes through a housing that surrounds the electrical component. For example, conduit 246 in thermal management circuit 200 extends through apertures 252 in the housing 250 surrounding electrical component 240, which allow thermal management fluid 220 to be conveyed to other elements of the thermal management circuit 200.
Another aspect of the disclosure provides a battery system including: a housing; one or more electrochemical cells disposed in the housing; a fluid path extending through the housing and in substantial thermal communication with the one or more electrochemical cells; and a thermal management fluid according to any of the embodiments described above that is disposed in the fluid path. For example, thermal management circuit 200 in
In various embodiments as otherwise described herein, the fluid path is at least partially defined by a cavity of the housing. For example, in various embodiments at least a portion of the fluid path is formed between the electrochemical cells and the inside wall of the housing, similar to fluid path 122 in component 140.
In various embodiments as otherwise described herein, the fluid path is at least partially defined by at least one conduit disposed in the housing. For example, in battery system 210, conduit 246 provides the fluid path 222 through the housing 250.
In various embodiments as otherwise described herein, the electrochemical cells are lithium-ion electrochemical cells. In other embodiments, the electrochemical cells are solid state cells, lithium-sulfur cells, lithium iron phosphate cells, lithium-ion polymer cells, sodium-ion cells, aluminum-ion cells, lead-acid cells, or magnesium-ion cells.
In various embodiments as otherwise described herein, the battery system is a component of an electric vehicle. In some embodiments, the electric vehicle is a fully electric vehicle or a hybrid electric vehicle. In other embodiments the battery system is component of a power motor, for example an electric motor or a motor in power electronics. In other embodiments the battery system is part of a stationary energy storage solution, for example a home energy storage solution that operates in cooperation with local renewable energy sources, such as solar panels or wind turbines.
Another aspect of the disclosure provides a thermal management circuit including a fluid path extending around and/or through a heat source; a thermal management fluid of according to any of embodiments described above, disposed in and configured to circulate in the fluid path and to absorb thermal energy produced by the heat source, wherein the fluid is disposed in the fluid path, the heat exchanger, the pump and the connecting duct. For example, thermal management circuit 100 shown in
In various embodiments of the as otherwise described herein, the heat source is a battery including a plurality of electrochemical cells, and wherein the fluid path passes between at least two of the electrochemical cells.
In various embodiments as otherwise described herein, the fluid path is defined by a housing around the electrical component. For example, housing 150 in
In various embodiments as otherwise described herein, the fluid path is configured to position the thermal management fluid in substantial thermal communication with the electrical component so as to absorb thermal energy produced by the electrical component. For example, in thermal management circuit 100 fluid path 122 extends around electrical component 140 and is in direct contact with the surfaces of electrical component 140. Further, in thermal management circuit 200 fluid path 222 passes through a conduit 246 that runs adjacent to the elements of electrical component 240. In both cases, the fluid path places thermal management fluid in close proximity to the electrical component so that the thermal management fluid readily absorbs thermal energy from the component.
In various embodiments as otherwise described herein, the thermal management circuit further includes a heat exchanger in fluid communication with the fluid path, wherein the thermal management fluid is configured to circulate between the fluid path and the heat exchanger to dissipate heat through the heat exchanger. In various embodiments as otherwise described herein, the heat exchanger is configured to remove heat from the thermal management fluid. For example, in thermal management circuit 100, after thermal management fluid 120 is pumped out of housing 150 it passes to heat exchanger 160 where the thermal energy is transferred to a cooler fluid, such as ambient air or a cooling liquid.
In various embodiments as otherwise described herein, the thermal management circuit includes a battery system according to any of the embodiments described above. For example, thermal management circuit 200 includes battery system 210. In various embodiments as otherwise described herein, the thermal management circuit includes an immobilized desiccant material disposed according to any of the embodiments described above. For example, thermal management circuit 300 includes battery desiccant material 360.
The particulars shown herein are by way of example and for purposes of illustrative discussion of various embodiments of the present invention only and are presented in the cause of providing what is believed to be the most useful and readily understood description of the principles and conceptual aspects of various embodiments of the invention. In this regard, no attempt is made to show structural details of the invention in more detail than is necessary for the fundamental understanding of the invention, the description taken with the drawings and/or examples making apparent to those skilled in the art how the several forms of the invention may be embodied in practice. Thus, before the disclosed processes and devices are described, it is to be understood that the aspects described herein are not limited to specific embodiments, apparatus, or configurations, and as such can, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular aspects only and, unless specifically defined herein, is not intended to be limiting.
The terms “a,” “an,” “the” and similar referents used in the context of describing the invention (especially in the context of the following embodiments and claims) are to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context.
The term “alkyl” as used herein, means a straight or branched chain hydrocarbon containing from 1 to 12 carbon atoms unless otherwise specified. Representative examples of alkyl include, but are not limited to, methyl, ethyl, n-propyl, iso-propyl, n-butyl, sec-butyl, iso-butyl, tert-butyl, n-pentyl, isopentyl, neopentyl, n-hexyl, 3-methylhexyl, 2,2-dimethylpentyl, 2,3-dimethylpentyl, n-heptyl, n-octyl, n-nonyl, and n-decyl. When an “alkyl” group is a linking group between two other moieties, then it may also be a straight or branched chain; examples include, but are not limited to —CH2—, —CH2CH2—, —CH2CH2CHC(CH3)—, and —CH2CH(CH2CH3)CH2—.
All methods described herein can be performed in any suitable order of steps unless otherwise indicated herein or otherwise clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., “such as”) provided herein is intended merely to better illuminate the invention and does not pose a limitation on the scope of the invention otherwise claimed. No language in the specification should be construed as indicating any non-claimed element essential to the practice of the invention.
Unless the context clearly requires otherwise, throughout the description and the claims, the words ‘comprise’, ‘comprising’, and the like are to be construed in an inclusive sense as opposed to an exclusive or exhaustive sense; that is to say, in the sense of “including, but not limited to”. Words using the singular or plural number also include the plural and singular number, respectively. Additionally, the words “herein,” “above,” and “below” and words of similar import, when used in this application, shall refer to this application as a whole and not to any particular portions of the application.
As will be understood by one of ordinary skill in the art, each embodiment disclosed herein can comprise, consist essentially of or consist of its particular stated element, step, ingredient or component. As used herein, the transition term “comprise” or “comprises” means includes, but is not limited to, and allows for the inclusion of unspecified elements, steps, ingredients, or components, even in major amounts. The transitional phrase “consisting of” excludes any element, step, ingredient or component not specified. The transition phrase “consisting essentially of” limits the scope of the embodiment to the specified elements, steps, ingredients or components and to those that do not materially affect the embodiment.
All percentages, ratios and proportions herein are by weight, unless otherwise specified.
Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the disclosure are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements.
Groupings of alternative elements or embodiments of the disclosure are not to be construed as limitations. Each group member may be referred to and claimed individually or in any combination with other members of the group or other elements found herein. It is anticipated that one or more members of a group may be included in, or deleted from, a group for reasons of convenience and/or patentability. When any such inclusion or deletion occurs, the specification is deemed to contain the group as modified thus fulfilling the written description of all Markush groups used in the appended claims.
Some embodiments of various aspects of the disclosure are described herein, including the best mode known to the inventors for carrying out the methods described herein. Of course, variations on these described embodiments will become apparent to those of ordinary skill in the art upon reading the foregoing description. The skilled artisan will employ such variations as appropriate, and as such the methods of the disclosure can be practiced otherwise than specifically described herein. Accordingly, the scope of the disclosure includes all modifications and equivalents of the subject matter recited in the claims appended hereto as permitted by applicable law. Moreover, any combination of the above-described elements in all possible variations thereof is encompassed by the disclosure unless otherwise indicated herein or otherwise clearly contradicted by context.
The methods of the disclosure are illustrated further by the following example, which is not to be construed as limiting the disclosure in scope or spirit to the specific procedures and compounds described in them.
The compounds of the disclosure can be easily prepared from inexpensive starting materials. For example, compounds of formula (I) can be made by contacting a compound of formula (II)
Compounds of formula (I) can similarly be made by contacting a compound of formula (III)
Compounds of formula (I) can also be made by contacting a compound of formula (II)
Compounds of formula (I) can also be made by contacting a compound of formula (III)
The person of ordinary skill in the art will recognize that a variety of Lewis acids can be used in effecting these transformations. While iron(II) trifluoroacetate is a desirable Lewis acid, others can be used.
The ethers of formula (I) can generally be made by any convenient route—for example, from commercially available alcohols, bromides, carboxylic acids, esters and aldehydes by Williamson ether synthesis, reduction of esters, hydrogenation of acetals or enol ethers. Methods described in International Patent Application Publication no. 2018/150185, which is hereby incorporated by reference in its entirety, can also be used; in such methods, an alcohol and an alkene are contacted with one another in the presence of an acidic ion-exchange resin to provide a corresponding ether. Methods described in International Patent Application no. 2020/104768, which is hereby incorporated by reference in its entirety, can also be used; in such methods, an aldehyde and a alcohol are combined with a catalyst such as pyridium p-toluenesulfonate with removal of water (e.g., using Dean-Stark techniques) to provide an enol ether, which is hydrogenated over platinum catalyst to provide the desired ether. Purification can be by any known method e.g. flash chromatography or distillation, with distillation being preferred industrially.
A compound of the Formula (I) has been synthesized according to the scheme below.
Alternatively, the compound can be prepared according to the scheme below:
The alcohol is reacted with tri(2-ethylhexyl) phosphate (4.5 eq) in presence of iron(II)triflate (0.04 eq) at 100° C. for 72 hrs. Upon completion, the reaction mixture is cooled to ambient temperature and partitioned between aqueous K2CO3 and hexane. The hexane layer is separated, dried over sodium sulphate and evaporated to give a yellow oil, which is distilled to provide the target ether.
Alternatively, the compound can be prepared according to the scheme below:
The alcohol is reacted with tri-n-butyl-phosphate (4.5 eq) in presence of iron(II)triflate (0.04 eq) at 100° C. for 72 hrs. Upon completion, the reaction mixture is cooled to ambient temperature and partitioned between aqueous K2CO3 and hexane. The hexane layer is separated, dried over sodium sulphate and evaporated to give a yellow oil, which is distilled to provide the target ether.
Additionally, certain compounds of the disclosure can be prepared according to the scheme below:
The alcohol, di-tert-butyl-carbonate (4 eq.) and triflic acid (0.025 eq.) are placed in an autoclave and heated to 60° C. for 72 hrs, up to 40 bars of pressure. The autoclave is carefully vented, and the reaction mixture is added to water and extracted with hexane. The hexane layer is dried over sodium sulphate, reduced in vacuum to an oil which is distilled to provide the target diether. Alternatively, triflic acid (0.1 eq.) is added cautiously to a suspension of the alcohol (60 mmol) in MTBE (70 mL) at ambient temperature and the mixture is warmed to 60° C., followed by the dropwise addition of di-tert-butyl-carbonate (7 eq.) dissolved in MTBE (7 mLl) over 1 hour. The reaction mixture is heated at 60° C. for 18 hrs, cooled to ambient temperature, diluted with hexane, washed with water, dried over sodium sulphate, and reduced in vacuum to an oil which is distilled to provide the target diether.
Compounds of the disclosure include those of the table below:
The following table presents predictions of properties (kinematic viscosities at 40° C. and 100° C., viscosity index, pour point, oxidation threshold temperature, flashpoint, for the structures above, based on comparison with the properties of known molecules.
Other aspects of the disclosure are described with respect to the following enumerated embodiments, which may be combined in any fashion and in any number that is not technically or logically inconsistent.
Embodiment 1 is directed to a thermal management fluid comprising:
Embodiment 2 is directed to the thermal management fluid of embodiment 1, wherein R1 is C3-C5 alkyl.
Embodiment 3 is directed to the thermal management fluid of embodiment 1, wherein R1 is a branched C3-C5 alkyl, such as branched C4-C5 alkyl.
Embodiment 4 is directed to the thermal management fluid of embodiment 3, wherein branching of R1 is at an α-position to the oxygen atom to which R1 is bound.
Embodiment 5 is directed to the thermal management fluid of embodiment 1, wherein R1 is —C(CH3)(CH3)(Rc), wherein Rc is methyl or ethyl.
Embodiment 6 is directed to the thermal management fluid of any of embodiments 1-5, wherein R2 is C6-C10 alkyl, such as C6-C8 alkyl.
Embodiment 7 is directed to the thermal management fluid of any of embodiments 1-5, wherein R2 is C8-C12 alkyl, such as C8-C10 alkyl or C10-C12 alkyl.
Embodiment 8 is directed to the thermal management fluid of any of embodiments 1-5, wherein R2 is a branched C6-C12 alkyl, such as branched C6-C10 alkyl, branched C6-C8 alkyl, branched C8-C12 alkyl, branched C8-C10 alkyl, or branched C10-C12 alkyl.
Embodiment 9 is directed to the thermal management fluid of embodiment 8, wherein branching of R2 is at a β-position to the oxygen atom to which R2 is bound.
Embodiment 10 is directed to the thermal management fluid of any of embodiments 1-9, wherein each of R3, R4, R5 and R6 is independently selected from H and C1-C4 alkyl (such as C1-C3 alkyl or C1-C2 alkyl).
Embodiment 11 is directed to the thermal management fluid of any of embodiments 1-9, wherein each of R3, R4, R5 and R6 is independently selected from H and C1 alkyl (i.e., methyl).
Embodiment 12 is directed to the thermal management fluid of any of embodiments 1-9, wherein each R4 is H and each R3 is H or C1-C6 alkyl (such as C1-C4 alkyl or C1-C2 alkyl); and each R5 is H and each R6 is H or C1-C6 alkyl (such as C1-C4 alkyl or C1-C2 alkyl).
Embodiment 13 is directed to a thermal management fluid of any of embodiments 1-9, wherein R3 is H, R4 is H, R5 is H and each R6 is H or C1-C6 alkyl (such as C1-C4 alkyl or C1-C2 alkyl).
Embodiment 14 is directed to a thermal management fluid of any of embodiments 12 and 13, wherein only one R6 is C1-C6 alkyl (such as C1-C4 alkyl or C1-C2 alkyl).
Embodiment 15 is directed to the thermal management fluid of any of embodiments 1-9, wherein each of R3, R4, R5, and R6 is H, i.e., the compounds have the formula
Embodiment 16 is directed to the thermal management fluid of any of embodiments 1-9, wherein each of R4, R5, and R6 is H, and wherein R3 is C1-C6 alkyl (such as methyl or ethyl), i.e., the compounds have the formula
Embodiment 17 is directed to the thermal management fluid of any of embodiments 1-16, wherein n is an integer 1, 2, or 3, e.g., n is an integer 1 or 2.
Embodiment 18 is directed to the thermal management fluid of any of embodiments 1-16, wherein n is 1, e.g., the one or more dielectric compounds have the formula
Embodiment 19 is directed to the thermal management fluid of any of embodiments
1-18, wherein n is 2, e.g., the one or more dielectric compounds have the formula
Embodiment 20 is directed to the thermal management fluid of any of embodiments 1-19, wherein m is 1, 2 or 3, e.g., 1.
Embodiment 21 is directed to the thermal management fluid of any of embodiments 1-19, wherein m is 4, or is 5.
Embodiment 22 is directed to the thermal management fluid of embodiments 1-9, 20 and 21, wherein the one or more dielectric compounds have the formula
in which m is 1, 2 or 3, R1 is C1-C5 alkyl, and R2 is C6-C10 alkyl.
Embodiment 23 is directed to the thermal management fluid of embodiment 22, wherein R1 is methyl or ethyl.
Embodiment 24 is directed to the thermal management fluid of embodiment 22, wherein R1 is propyl (e.g., n-propyl, isopropyl) or butyl, e.g., n-butyl, t-butyl, sec-butyl or isobutyl.
Embodiment 25 is directed to the thermal management fluid of embodiment 22, wherein R1 is branched pentyl, e.g., 1,1-dimethylpropyl, 2,2-dimethylpropyl.
Embodiment 26 is directed to the thermal management fluid of any of embodiments 22-25, wherein R2 is branched, e.g., a group —CH2—CH(Rb)(Rd) in which Rb is methyl or ethyl, and Rd is C3-C8 alkyl, e.g., R2 is 2-ethylhexyl.
Embodiment 27 is directed to the thermal management fluid of any of embodiments 22-26, wherein m is 1.
Embodiment 28 is directed to the thermal management fluid of any of embodiments 22-26, wherein m is 2, or is 3.
Embodiment 29 is directed to the thermal management fluid of any of embodiments 22-26, wherein m is 4, or is 5.
Embodiment 30 is directed to the thermal management fluid of any of embodiments 1-29, wherein each of the one or more compounds contains a total number of carbon atoms from 12-18.
Embodiment 31 is directed to the thermal management fluid of any of embodiments 1-29, wherein each of the one or more compounds contains a total number of carbon atoms from 10 to 30 (e.g., from 10 to 26, from 10 to 22, from 10 to 18, from 12 to 30, from 12 to 26, from 12 to 22, from 14 to 30, from 14 to 26, or from 14 to 22).
Embodiment 32 is directed to the thermal management fluid of embodiment 1, wherein the one or more dielectric compounds are independently selected from:
Embodiment 33 is directed to the thermal management fluid any of embodiments 1-32, wherein the one or more dielectric compounds has a flash point of at least 100° C., for example, at least 110° C. (e.g., at least 120° C., at least 125° C., at least 130° C., or at least 135° C.) or at least 140° C. (e.g., at least 145° C., at least 150° C., or at least 155° C.), measured in accordance with ASTM D93.
Embodiment 34 is directed to the thermal management fluid of any of embodiments 1-33, wherein the one or more dielectric compounds has a kinematic viscosity at 40° C. in the range of 1.5 to 20 cSt, e.g., in the range of 1.5 to 15 cSt, or 2 to 20 cSt, or 2 to 15 cSt, or 3 to 20 cSt, or 3 to 15 cSt, or 5 to 20 cSt, or 5 to 15 cSt, as measured in accordance with ASTM D455.
Embodiment 35 is directed to the thermal management fluid of any of embodiments 1-33, wherein the one or more dielectric compounds has a kinematic viscosity at 40° C. in the range of 1.5 to 10 cSt, e.g., 1.5 to 8 cSt, or 1.5 to 6 cSt, or 2 to 10 cSt, or 2 to 8 cSt, or 2 to 6 cSt, or 3 to 10 cSt, or 3 to 8 cSt, or 3 to 6 cSt, or 5 to 10 cSt, or 5 to 8 cSt, or 5 to 6 cSt, or 6 to 10 cSt, or 8 to 10 cSt, as measured in accordance with ASTM D455.
Embodiment 36 is directed to the thermal management fluid of any of embodiments 1-33, wherein the one or more dielectric compounds has a kinematic viscosity at 40° C. in the range of 1.5 to 5 cSt, or 1.5 to 4 cSt, or 1.5 to 3 cSt, or 2 to 5 cSt, or 2 to 4 cSt, or 2 to 3 cSt, or 3 to 5 cSt, or 3 to 4 cSt, or 4 to 5 cSt, as measured in accordance with ASTM D455.
Embodiment 37 is directed to the thermal management fluid of any of embodiments 1-36, wherein the one or more dielectric compounds is present in an amount in the range of 5 wt % to 100 wt %, or 10 wt % to 100 wt %, or 20 wt % to 100 wt %, based on the total weight of the thermal management fluid.
Embodiment 38 is directed to the thermal management fluid of any of embodiments 1-36 wherein the one or more dielectric compounds is present in an amount in the range of 50 wt % to 100 wt %, for example, 75 wt % to 100 wt %, or 85 wt % to 100 wt %, or 90 wt % to 100 wt %, or 95 wt % to 100 wt %, or 98 wt % to 100 wt %, based on the total weight of the thermal management fluid.
Embodiment 39 is directed to the thermal management fluid of any of embodiments 1-36, wherein the one or more dielectric compounds is present in an amount in the range of 1 wt % to 99.9 wt % (e.g., 5 wt % to 99.9 wt %, or 10 wt % to 99.9 wt %, or 20 wt % to 99.9 wt %), or 50 wt % to 99.9 wt %, for example, 75 wt % to 99.9 wt %, or 85 wt % to 99.9 wt %, or 90 wt % to 99.9 wt %, or 95 wt % to 99.9 wt %, or 98 wt % to 99.9 wt %, based on the total weight of the thermal management fluid.
Embodiment 40 is directed to the thermal management fluid of any of embodiments 1-36, wherein the one or more dielectric compounds is present in an amount in the range of 1 wt % to 99 wt % (e.g., 5 wt % to 99 wt %, or 10 wt % to 99 wt %, or 20 wt % to 99 wt %), or 50 wt % to 99 wt %, for example, 80 wt % to 99 wt %, or 85 wt % to 99 wt %, or 90 wt % to 99 wt %, or 95 wt % to 99 wt %, based on the total weight of the thermal management fluid.
Embodiment 41 is directed to the thermal management fluid of any of embodiments 1-36, wherein the one or more dielectric compounds is present in an amount in the range of 1 wt % to 95 wt % (e.g., 5 wt % to 95 wt %, or 10 wt % to 95 wt %, or 20 wt % to 95 wt %), or 50 wt % to 95 wt %, for example, 75 wt % to 95 wt %, or 85 wt % to 95 wt %, based on the total weight of the thermal management fluid.
Embodiment 42 is directed to the thermal management fluid of any of embodiments 1-36, wherein the one or more dielectric compounds is present in an amount in the range of 1 wt % to 85 wt % (e.g., 5 wt % to 85 wt %, or 10 wt % to 85 wt %, or 20 wt % to 85 wt %), or 50 wt % to 85 wt %, for example, 65 wt % to 85 wt %, or 75 wt % to 85 wt %, based on the total weight of the thermal management fluid.
Embodiment 43 is directed to the thermal management fluid of any of embodiments 1-42, further comprising a Group II, Group III, Group IV, or a Group V base oil.
Embodiment 44 is directed to the thermal management fluid of any of embodiments 1-42, further comprising a Group II or Group III base oil.
Embodiment 45 is directed to the thermal management fluid of any of embodiments 1-44, further comprising a Group IV base oil (such as polyalphaolefins (PAO)).
Embodiment 46 is directed to the thermal management fluid of any of embodiments 1-45, further comprising an ester base oil stock.
Embodiment 47 is directed to the thermal management fluid of any of embodiments 1-46, further comprising one or more of corrosion inhibitors, anti-oxidants (such as phenolic and aminic anti-oxidants), pour point depressants, antifoams, defoamers, viscosity index modifiers, preservatives, biocides, surfactants, seal swell additives, and combinations thereof, e.g., in an amount up to 0.5 wt %, up to 1.0 wt %, or up to 5.0 wt %.
Embodiment 48 is directed to the thermal management fluid of any of embodiments 1-47, further comprising one or more flame retardants, e.g., in an amount up to 20 wt %, up to 10 wt %, or up to 5 wt %.
Embodiment 49 is directed to the thermal management fluid of any of embodiments 1-48, wherein the thermal management fluid has a flash point of at least 110° C., e.g., at least 120° C., at least 125° C., at least 130° C., or at least 135° C., measured in accordance with ASTM D93.
Embodiment 50 is directed to the thermal management fluid of any of embodiments 1-48, wherein the thermal management fluid has a flash point of at least 140° C., e.g., at least 145° C., at least 150° C. or at least 150° C., measured in accordance with ASTM D93.
Embodiment 51 is directed to the thermal management fluid of any of embodiments 1-50, having a kinematic viscosity at 40° C. in the range of 1.5 to 20 cSt, e.g., in the range of 1.5 to 15 cSt, or 2 to 20 cSt, or 2 to 15 cSt, or 3 to 20 cSt, or 3 to 15 cSt, or 5 to 20 cSt, as measured in accordance with ASTM D455.
Embodiment 52 is directed to the thermal management fluid of any of embodiments 1-50, having a kinematic viscosity at 40° C. in the range of 1.5 to 10 cSt, e.g., 1.5 to 8 cSt, or 1.5 to 6 cSt, or 2 to 10 cSt, or 2 to 8 cSt, or 2 to 6 cSt, or 3 to 10 cSt, or 3 to 8 cSt, or 3 to 6 cSt, or 5 to 10 cSt, or 5 to 8 cSt, or 5 to 6 cSt, or 6 to 10 cSt, or 8 to 10 cSt, as measured in accordance with ASTM D455.
Embodiment 53 is directed to the thermal management fluid of any of embodiments 1-50, having a kinematic viscosity at 40° C. in the range of 1.5 to 5 cSt, or 1.5 to 4 cSt, or 1.5 to 3 cSt, or 2 to 5 cSt, or 2 to 4 cSt, or 2 to 3 cSt, or 3 to 5 cSt, or 3 to 4 cSt, or 4 to 5 cSt, as measured in accordance with ASTM D455.
Embodiment 54 is directed to the thermal management fluid of any of embodiments 1-53, having a dielectric constant of at least 1.75, e.g., at least 2.0, or at least 2.25, as measured at 25° C.
Embodiment 55 is directed to the thermal management fluid of any of embodiments 1-54, having a dielectric constant in the range of 1.5 to 10, or 1.8 to 10, or 1.5 to 2.8, or 1.8 to 2.8.
Embodiment 56 is directed to the thermal management fluid of any of embodiments 1-55, having density of no more than 1.1 g/cm3 at 25° C. (e.g., no more than 1 g/cm3 at 25° C.).
Embodiment 57 is directed to the thermal management fluid of any of embodiments 1-56, having a thermal conductivity in the range of 0.05 W/m·K to 1 W/m·K at 25° C.
Embodiment 58 is directed to the thermal management fluid of any of embodiments 1-57, having a specific heat capacity of at least 1 J/g·K (e.g., at least 1.2 J/g·K, or at least 1.5 J/g·K at 25° C.).
Embodiment 59 is directed to the thermal management fluid of any of embodiments 1-58, having a coefficient of thermal expansion of no more than 1100×10−6/K (e.g., no more than 1050×10−6/K, or no more than 1000×10−6/K).
Embodiment 60 is a method comprising:
Embodiment 61 is directed to the method according to embodiment 60, wherein the surface has a temperature of at least 30° C., e.g., at least 40° C.
Embodiment 62 is directed to the method according to embodiment 60, wherein the surface has a temperature in the range of 25° C. to 150° C., e.g., 25° C. to 100° C., or 25° C. to 90° C., or 25° C. to 85° C., or 25° C. to 80° C., or 25° C. to 75° C., or 25° C. to 70° C.
Embodiment 63 is directed to the method according to embodiment 60, wherein the surface has a temperature in the range of 30° C. to 150° C., e.g., 30° C. to 100° C., or 30° C. to 90° C., or 30° C. to 85° C., or 30° C. to 80° C., or 30° C. to 75° C., or 30° C. to 70° C.
Embodiment 64 is directed to the method according to embodiment 60, wherein the surface has a temperature in the range of 40° C. to 150° C., e.g., 50° C. to 150° C., or 60° C. to 150° C., or 70° C. to 150° C., or 80° C. to 150° C., or 90° C. to 150° C., or 100° C. to 150° C., or 110° C. to 150° C.
Embodiment 65 is directed to the method according to any of embodiments 60-64, wherein the thermal management fluid is a stationary (i.e., not circulating) body of fluid.
Embodiment 66 is directed to the method according to any of embodiments 60-64, wherein the contacting is performed by circulating the thermal management fluid over the surface.
Embodiment 67 is directed to the method according to any of embodiments 60-64, wherein the contacting is performed by circulating the thermal management fluid between a heat exchanger and the surface.
Embodiment 68 is directed to the method according to any of embodiments 60-67, wherein the heat source is an operating electrical component.
Embodiment 69 is directed to the method according to any of embodiments 60-68, wherein the heat source is a battery pack, a capacitor, inverter, electrical cabling, a fuel cell, a motor, a computer, or high power charging equipment.
Embodiment 70 is directed to the method according to any of embodiments 60-69, wherein the heat source is an electrochemical cell.
Embodiment 71 is directed to the method of embodiment 70, wherein the electrochemical cell is selected from solid state electrochemical cells, lithium-sulfur electrochemical cells, lithium iron phosphate electrochemical cells, lithium-ion polymer electrochemical cells, sodium-ion electrochemical cells, aluminum-ion cells, lead-acid cells, and magnesium-ion cells.
Embodiment 72 is directed to the method according to any of embodiments 60-71, wherein the surface is an internal surface of a conduit in substantial thermal communication with the heat source.
Embodiment 73 is directed to the method according to any of embodiments 60-72, wherein the conduit passes through a housing that surrounds the electrical component.
Embodiment 74 is directed to a battery system comprising:
Embodiment 75 is directed to the battery system of embodiment 74, wherein the electrochemical cells are lithium-ion electrochemical cells.
Embodiment 76 is directed to the battery system of embodiment 74, wherein the electrochemical cells are solid state electrochemical cells, lithium-sulfur electrochemical cells, lithium iron phosphate electrochemical cells, lithium-ion polymer electrochemical cells, sodium-ion electrochemical cells, aluminum-ion cells, lead-acid cells, or magnesium-ion cells.
Embodiment 77 is directed to an electric vehicle comprising the battery system of any of embodiments 74-76.
Embodiment 78 is directed to a thermal management circuit comprising:
Embodiment 79 is directed to a method for preparing the thermal management fluid of any of embodiments 1-59, the method comprising:
Embodiment 80 is directed to a method for preparing the thermal management fluid of any of embodiments 1-59, the method comprising:
Embodiment 81 is directed to a method for preparing the thermal management fluid of any of embodiments 1-59, the method comprising:
Embodiment 82 is directed to a method for preparing the thermal management fluid of any of embodiments 1-59, the method comprising:
Embodiment 83 is directed to the method of any of embodiments 79-82, further comprising admixing the dielectric compound in an amount in the range of 1 wt % to 99.9 wt %, based on the total weight of the thermal management fluid, with one or more of base oils, corrosion inhibitors, anti-oxidants (such as phenolic and aminic anti-oxidants), pour point depressants, antifoams, defoamers, viscosity index modifiers, preservatives, biocides, surfactants, seal swell additives, flame retardants, and combinations thereof.
In closing, it is to be understood that the various embodiments herein are illustrative of the methods of the disclosures. Other modifications that may be employed are within the scope of the disclosure. Thus, by way of example, but not of limitation, alternative configurations of the methods may be utilized in accordance with the teachings herein. Accordingly, the methods of the present disclosure are not limited to that precisely as shown and described.
This application claims the benefit of priority of U.S. Provisional Patent Application No. 63/153,163, filed Feb. 24, 2021, which is hereby incorporated herein by reference in its entirety.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/IB2022/051610 | 2/24/2022 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 63153163 | Feb 2021 | US |
