Digital overlay

Information

  • Patent Grant
  • 11566380
  • Patent Number
    11,566,380
  • Date Filed
    Wednesday, March 31, 2021
    3 years ago
  • Date Issued
    Tuesday, January 31, 2023
    a year ago
Abstract
A method to form a protective overlay with wear resistant particles applied in well-defined patterns by applying wear resistant particles on a surface, bonding a part of the wear resistant particles with a binder preferably applied with a digital drop application head and removing the non-bonded wear resistant particles from the surface.
Description
TECHNICAL FIELD

The disclosure relates to the field of digitally created wear resistant surfaces for building panels such as floor and furniture components. The disclosure relates to hard wear resistant particles that are positioned in pre-determined patterns on a surface.


FIELD OF APPLICATION

Embodiments of the present disclosure are particularly suitable for use in floors, which are formed of floor panels comprising a core, a decorative layer and a transparent wear resistant protective layer above the decorative layer. Preferred embodiments are conventional laminate floors, powder based floor, wood floors, plastic based LVT floors and ceramic tiles. The following description of techniques, problems of known technology and objects and features of the disclosure will therefore, as a non-restrictive example, be aimed above all at this field of application and in particular at floorings which are similar to conventional laminated floorings. The embodiments of the disclosure may also be used to produce wear resistant surfaces on any essentially flat panels preferably furniture components.


BACKGROUND

The following description is used to describe the background and products, materials and production methods that may comprise specific parts of preferred embodiments in the disclosure of this disclosure.


The majority of all laminate floors are produced according to a production method generally referred to as Direct Pressed Laminate (DPL). Such laminated floors have a core of 6-12 mm fibreboard, a 0.2 mm thick upper decorative surface layer of laminate and a 0.1-0.2 mm thick lower balancing layer.


The surface layer of a laminate floor is characterized in that the decorative and wear properties are generally obtained with two separate layers of paper, one above the other. The decorative layer is generally a melamine formaldehyde (hereafter shortened to melamine) impregnated printed paper and the wear layer is a melamine impregnated transparent overlay paper, which comprises small wear resistant aluminium oxide particles such as corundum, hereafter shortened to aluminium oxide.


The overlay paper is made of pure cellulose, which is based on delignified pulp. The overlay paper becomes almost completely transparent after lamination and the appearance of the decor paper is visible. Thicker overlay papers with a considerable amount of aluminium oxide particles may give a high wear resistance. The disadvantage is that they are less transparent and a grey layer that disturbs the printed pattern covers the decorative pattern.


The wear resistant aluminium oxide particles may be included in an overlay paper in several ways during impregnation. They may be mixed into the liquid melamine resin or scattered on the wet overlay paper. Paper based overlay may be replaced with a liquid overlay comprising a mix of aluminium oxide particles and liquid melamine resin that is applied on the impregnated décor paper.


The printed decorative paper and the overlay are laminated to a HDF core in large discontinuous or continuous laminate presses where the resin cures under high heat (about 170° C.) and pressure (40-60 bars) and the papers are laminated to the core material. An embossed press plate or steal belt forms the surface structure. Sometimes a structured paper is used as a press matrix. The embossing is in high quality floors made in register with the design.


Laminated floors may also be produced with direct printing technology. Hydro printing inks are used to print the décor by a multicolour printing press. The print is covered with a protective transparent wear layer that may be an overlay, a plastic foil or a lacquer that may comprise wear resistant particles.


Direct printing technology may be replaced with digital printing technology that is much more flexible and small production volumes can be economically manufactured. The difference between these two methods is mainly the printing step where the printing rollers are replaced by a digital non-contact printing process.


Recently new “paper free” floor types have been developed with solid surfaces comprising a substantially homogenous powder mix of fibres, binders and wear resistant particles hereafter referred to as WFF (Wood Fibre Floor).


The powder mix may comprise aluminium oxide particles, melamine resins and wood fibres. In most applications colour pigments are included in the mix and all these materials are applied in dry form as a mixed powder on a HDF core and cured under heat and pressure to a 0.1-1.0 mm solid layer.


Several advantages over known technology and especially over conventional laminate floorings may be obtained such as increased wear and impact resistance, deep embossing, increased production flexibility and lower costs. Digital powder printing has been developed and it is possible to create very advanced designs by injecting ink into the powder prior to pressing. The powder layer may include one or several powder based base colours and digital ink jet printing may only produce a small part of the total décor. A powder overlay comprising a mix of transparent fibres, wear resistant particles and melamine powder may be used to increase the wear resistance of the digital print. Such protective layer is applied even on the base layer where it is not needed since abase layer comprising wear resistant particles have sufficient wear resistance.


Wood floors are delivered as pre finished floors with a wood surface that is coated with several transparent layers in the factory. The coating may be made with UV cured polyurethane that comprises wear restante particles.


Ceramic tiles are one of the major materials used for flooring and wall coverings. A tile body comprising clay minerals is covered with one or several layers of glaze that may comprise wear resistant particles.


Luxury Vinyl Tiles, generally referred to as LVT floorings, are constructed as a layered product. The base layer is made primarily of PVC mixed with chalk filler in order to reduce material costs. The base layer has a high quality printed decorative PVC foil on the upper side. A transparent wear layer of vinyl with a thickness of 0.2-0.6 mm is generally applied on the decorative foil. The transparent layer may include a coating of polyurethane, which provides additional wear and stain resistance. Such polyurethane layer may comprise wear resistant particles.


As a summary it may be mentioned that wear resistant particles, especially aluminium oxide, are used in many floor types in order to increase the wear resistance of the floor surface.


Definition of Some Terms

In the following text, the visible surface of the installed floor panel is called “front side”, while the opposite side of the floor panel, facing the sub floor, is called “rear side”.


By “up” is meant towards the front side and by “down” towards the rear side. By “vertically” is meant perpendicular to the surface and by “horizontally” parallel to the surface.


By “binder” is meant a substance that connects or contributes to connect two particles or materials. A binder may be liquid, powder based, a thermosetting or thermoplastic resin and similar. A binder may consist of two components that react when in contact with each other.


By “digital printing” is meant a digitally controlled ejection of drops of fluid comprising a colorant from a print head onto a surface.


By “panel” is meant a sheet shaped material with a length and width that is larger than the thickness. This rather broad definition covers, for example, laminate and wood floors, tiles, LVT, sheet shaped wall coverings and furniture components.


Known Technique and Problems Thereof

The general technologies, which are used by the flooring industry to provide a wear resistant surface, are mainly based on applying wear resistant particles such as aluminium oxide on an upper part of the floor surface. The particles are applied at random. Due to production tolerances, some parts of the surface may comprise larger amounts than other part and the average amount is generally higher than needed. Clusters of particles may create grey spots and unwanted shadings. Laminate floors are produced as large sheets that are cut into several panels. Wear resistant particles are applied over the whole sheet and even on areas where the saw blade cuts the sheet into individual panels and where parts of the surface is removed when the locking systems are formed. This creates high wear on the saw blades and on the milling tools. The surface is generally embossed with low and high portions. The wear on the high portions is much higher that on the low portions.


Powder based digitally printed floors may comprise much more wear resistant particles than necessary if they are covered by a powder overlay that covers even the unprinted parts where no protective layer is needed.


It would be a major advantage if the wear resistant particles may be applied in a more precise way and especially if they may be applied in well-defined pre-determined patterns that may cover parts of the floor surface.


It is known from pre-published material (IP.COM 000224950D, the entire contents of which are hereby incorporated herein by reference in their entirety) and from the web site of Välinge innovation AB that particles may be applied in well-defined patterns with a combination of blank and dry ink. A cost efficient method to apply wear resistant particles on specific surface portions is not described.


OBJECTS AND SUMMARY

The main objective of certain embodiments of the disclosure is to provide an improved and cost efficient wear resistant protective layer comprising wear resistant particles.


Embodiments of the disclosure is based on a main principle where application of the wear resistant particles is divided in two separate steps. The particles are applied on a surface. Some particles are bonded by a preferably digitally formed pattern. Other non-bonded particles are removed and the remaining bonded particles form a pre-determined pattern of wear resistant particles. This two-step process may be repeated and several layers of wear and scratch resistant particles may be applied such that an advanced wear resistant layer with particles spaced from each other with pre-determined distances may be formed.


The major advantages compared to conventional random applications are that application of the wear resistant particles may be made in a controlled and very precise way. Contrary to known technology wear resistant particles may be evenly distributed and applied in precise digitally formed raster patterns and only on surface portions where they are needed and in amounts that are adapted to the wear properties of the underlying surface portions and to the wear intensity that surface portions are exposed to, for example, edge portions and upper portions of embossed surfaces where the wear is considerably higher than in other parts of the floor. Embodiments of the disclosure may provide wear resistant surfaces with surface portions comprising variations in wear properties, scratch resistant properties and gloss levels. Surface portion that are cut and milled may be formed without wear resistant particles in order to reduce tool wear.


A first aspect of the disclosure is a method of forming a digital pattern of wear resistant particles on a sheet comprising a surface wherein the method comprises the steps of:

    • applying a liquid binder in a pattern on the surface;
    • applying wear resistant particles on the surface;
    • bonding a part of the wear resistant particles to the surface with the liquid binder; and
    • removing non-bonded wear resistant particles from the surface such that a digital pattern is formed by the bonded wear resistant particles.


The wear resistant particles may be applied in a raster pattern with pre-determined distance between the wear resistant particles.


The pre-determined distance may essentially correspond to surface portions where the sheet is to be cut into several panels and/or where locking systems will be formed.


The surface may comprises a printed décor and the wear resistant particles are spaced from each other and coordinated in register with the printed décor.


The surface may comprise a printed and embossed décor with upper and lower surface portions and wherein the content of wear resistant particles are higher in the upper portions than in the lower portions.


The wear resistant particles may comprise aluminium oxide such as corundum.


The wear resistant particles may be coated or mixed with a thermosetting resin.


The surface may be a powder layer, a paper layer or a foil.


The surface may be a part of a floor panel.


The wear resistant particles may be removed by an airstream.


The binder may be blank ink comprising a liquid substance that is applied by a digital drop application head.


The liquid substance may be water based.


The liquid substance may be exposed to IR light or hot air.


The liquid substance may be applied with a Piezo ink head.


The liquid substance may be applied with a thermo ink head.


The surface with the wear resistant particles may be heated and pressed.


The wear resistant particles may be applied by scattering.


The wear resistant particles may be arranged in a wood grain or a stone pattern.


A second aspect of the disclosure is a panel with a decorative surface comprising a pattern of wear resistant particles wherein the wear resistant particles are applied in a raster pattern with pre-determined distance between the wear resistant particles.


The surface may comprise a printed décor and the wear resistant particles are spaced from each other and coordinated with the printed décor.


The surface may comprise a printed and embossed décor with an upper and a lower surface portion and wherein the content of wear resistant particles are higher in the upper surface portion than in the lower surface portion.


An edge portion may comprise a higher content of wear resistant particles than an inner surface portion spaced from the edge portion.


The surface may be a paper layer or a foil.


The surface may comprise a powder layer.


The surface may be a part of a building panel.


The surface may be a part of a floor panel.


The wear resistant particles may comprise aluminium oxide such as corundum.


The wear resistant particles may be arranged in a wood grain or a stone pattern.


The surface may be a part of a panel that is a laminate or wood floor, a powder based floor, a tile or a LVT floor.


A third aspect of the disclosure is a sheet with a decorative surface comprising a pattern of wear resistant particles wherein the wear resistant particles are applied in a raster pattern with pre-determined distance between the wear resistant particles.


The pre-determined distance may essentially correspond to surface portions where the sheet is to be cut into several panels and/or where locking systems will be formed.


The surface may comprise a printed décor and the wear resistant particles are spaced from each other and coordinated in register with the printed décor.


The surface may comprise a printed and embossed décor with upper and lower surface portions and wherein the content of wear resistant particles are higher in the upper portions than in the lower portions.


The wear resistant particles may comprise aluminium oxide such as corundum.


A fourth aspect of the disclosure is a paper comprising a pattern of wear resistant particles wherein the wear resistant particles are applied in a raster pattern with pre-determined distance between the wear resistant particles.





BRIEF DESCRIPTION OF THE DRAWINGS

The disclosure will in the following be described in connection to preferred embodiments and in greater detail with reference to the appended exemplary drawings, wherein,



FIGS. 1a-e Illustrate surfaces comprising wear resistant particles;



FIGS. 2a-b Illustrate a sheet and a floor panel having a surface with wear resistant particles;



FIGS. 2c-e Illustrate bonding of wear resistant particles;



FIG. 2f Illustrate a method and equipment to apply wear resistant particles in pre-determined patterns.





DETAILED DESCRIPTION OF EMBODIMENTS


FIG. 1a shows a conventional application of aluminium oxide particles on a paper based overlay surface 2 used in laminate floorings. The particles, which have a size of about 0.1 mm are applied at random and the whole surface, is covered. Some surface portions comprise larger amounts and some smaller amounts. Two to five particles and even more may be connected to each in clusters and some particles may be spaced from each other with a distance D1 of up to about 1 mm.



FIG. 1b shows schematically an embodiment of the disclosure, which is based on a preferred principle where a binder pattern BP is formed digitally by an ink head, hereafter referred to as digital drop application head, that preferably only applies a binder 11, hereafter referred to as blank ink, on a surface 2. Wear resistant particles hereafter referred to as dry overlay 15 that comprises, for example, small aluminium oxide particles, are applied such that they are in contact with the binder pattern BP. The blank ink 11 connects some particles that form the same pattern as the binder 11 and a pattern BP of wear resistant particles is formed on the surface 2 when other non-bonded particles 15 are removed from the surface 2 by, for example, vacuum. This method allows that the surface 2 may be covered with wear resistant dry overlay comprising particles that are evenly distributed on the surface with pre-defined distances D1, D2 between the major parts of the particles. An ideal distance between the particles is about 0.2-0.6 mm and no clusters of connected particles should occur. Such evenly distributed particles of dry overlay provide a high quality surface with high wear resistance and transparency combined with low material costs.


The blank ink 11 and the dry overlay 15 may be applied in many alternative ways. The blank ink may be applied on the dry overlay or the dry overlay may be applied on the blank ink. The surface may point upwards or downwards and the blank and/or the dry overlay particles may be applied from above or from below. A surface with blank ink may, for example, point downwards and may be brought into contact with a dry overlay layer. Non-bonded dry overlay particles may be removed by gravity when the surface is separated from the dry overlay layer. In order to simplify the description, the majority of the preferred embodiments show a surface pointing upwards.



FIG. 1c shows a powder-based surface 2 comprising a base colour 2a and a digital print P applied on the base colour. The base colour may comprise wear resistant particles and a second layer of dry overlay particles 15 is only applied on the printed parts P. The application is made in two steps as described above with blank ink and dry overlay where the dry overlay applied on the non printed portions is removed.



FIG. 1d shows a surface 2 with embossed upper 17a and lower 17b surface portions. The wear resistant particles are preferably only applied on the upper portions 17a, which are exposed to high wear. Surface portions may also be formed with different amounts of particles per cm2. The amount of particles may, for example, be larger in the lower portions than in the upper portions.



FIG. 1e shows a sheet 1 which is after pressing divided into two floor panels 1a, 1b. The wear resistant particles are applied with a distance D1 that corresponds to the part of the surface that is removed when the sheet 1 is cut and the locking systems are formed on the individual panels 1a, 1b. The distance D1 is preferably larger than a few mm, which corresponds to the width of a saw blade SB. The distance may also be about 5-10 mm, which corresponds to the surface portion that is needed to form the major part of the mechanical locking system.


A protective layer of, for example, bleached fibres and melamine resin or only melamine or only fibres may be applied on the wear resistant particles in order to, for example, protect press plates during pressing or to create different gloss levels.



FIG. 2a shows a panel 1a with a core 3, a balancing layer 4 and an embossed surface 2 comprising upper 17a and lower parts 17b. The panel edges are formed with a mechanical locking system comprising a strip 6, with a locking element 8 in one edge that cooperates with a locking groove 14 in an adjacent edge of another panel for horizontal locking of the adjacent edges and a tongue 10 in one edge that cooperates with a tongue groove 9 in another edge for vertical locking of the panels. The panel comprises bevels 5 at the upper edges. The panel may comprise different amounts of dry overlay on the upper and lower surface portions



FIG. 2b shows a sheet 1 which is cut into two individual panels 1a and 1b. The wear resistant particles are applied in patterns with a distance D2 between the particles such that the wear properties of surface portions, which are removed in connection with cutting, and milling of the locking systems and the bevels are lower in such portions than in other parts of the sheet. Preferably such portions should be produced such that the content of wear resistant particles is as small as possible, preferably less than 10% of the average content of the panel surface.


Floor panels may warp in different humidity and the wear on the edges that generally warp upwards in dry conditions is much higher than on the inner part of the panel. Increase amounts of wear resistant particles may be applied at surface portions 2a adjacent to the panel edge.



FIGS. 2c-2e shows how wear resistant particles, preferably aluminium oxide 63, may be bonded and position in well-defined patterns. A binder of blank ink 11 is applied on a surface with preferably a conventional digital ink head. The binder may also be applied with rollers and other similar methods. Water may be sufficient to bond the particles until they are pressed.



FIG. 2c shows that a binder is preferably included in the surface 2 and may react with the liquid pattern of blank ink 11 applied by the digital drop application head.



FIG. 2d shows that aluminium oxide particles 63, may be coated with a thermoplastic or thermosetting resin, for example, melamine 13.



FIG. 2e shows that dry overlay particles 15 may also be mixed with a spray dried binder in powder form such as melamine particles 13 that melt when they are in contact with the blank ink 11.



FIG. 2f shows schematically a digital particle application equipment 40 that may be used to create a digital patter P of wear resistant particles on a panel 1 comprising a surface 2, a core 3 and a backing layer 4. A blank ink application station 36 comprising a digital drop application head 30′, that preferably is a Piezo head or a thermal print head, applies a binder pattern with blank ink 11. Several heads 30′ may be positioned side by side in order to cover the width of the surface that is printed. The binder pattern is created digitally in the same way as in conventional digital printing. The digital drop application head is connected with a feeding pipe 32 to a container 31 with blank ink. The digital drop application heads 30′ are digitally connected with preferably data cables 33 or wireless to a digital control unit 34 that controls the application of the drops, the speed of the conveyor 21, the function of a dry ink application unit 27 and all other equipment that is used to bond and remove particles.


The water based drops of the blank ink 11, which in this embodiment serve as an application binder, should be wet until they pass the dry ink application unit 27 that in this preferred embodiment is a scattering station. Dry overlay 15, that in this preferred embodiment comprises aluminium oxide particles mixed with a resin of spray dried melamine powder, is scattered on the liquid blank ink 11.


The scattering equipment comprises a hopper 45 that contains dry overlay 15, a doctor blade 47 that together with a roller 46, preferably comprising an engraved, embossed, etched or sand blasted roller surface 44, acts as a dispensing device that moves a pre-determined amount of dry overlay 15 from the hopper 45 and to the surface 2. The roller 46 may also have a roller surface 44 that comprise small needles. A material-removing device that may be an oscillating or rotating brush 48 may also be used in some applications together with one or several rotating or oscillating meshes 49 that may oscillate or rotate in different directions.


The doctor blade 47 may be rigid or flexible and may have an edge that is adapted to the structure of the roller surface. The oscillating or rotating meshes 49 may also be formed such that they spread the dry overlay 15 in a pre-defined way and they may be combined with one of several nets that may be used to sieve the particles before they are applied as a layer. The rotation of the roller, the position of the doctor blade and the speed of the surface that is intended to be covered with the dry overlay may be used to control the layer thickness.


The liquid blank ink 11 and the dry overlay is in this embodiment heated and stabilized when it is displaced under preferably a hot IR lamp 23, which is located preferably after the digital drop application head 30′ in the feeding direction.


A dry overlay removal station 28, that in this embodiment is based on air streams and vacuum, removes dry overlay particles that are not wet and not bonded by the binder pattern and a perfect dry overlay pattern P is provided. The dry overlay removal station may be located after the IR lights 23 or between the IR lights and the scattering unit 27. This production step may be repeated and several types of wear resistant particles may be applied at different portions of the surface. The removed particles may pass through a sieve or a filter and they may be recycled and reused again several times.


The dry overlay may in addition to wear resistant particles also comprise melamine particles and/or pigments and/or fibres, preferably bleached transparent or semi-transparent wood fibres.


The method to apply wear resistant particles in patterns in order to reach cost saving and increased transparency may also be used together with a conventional overlay paper or decorative paper. Wear resistant particles may be applied in patterns on the overlay prior or after impregnation and the overlay paper with the wear resistant particles applied in patterns may be applied on a decorative paper. Wear resistant particles may be applied in patterns on the decorative paper preferably after impregnation when the decorative paper is positioned on a carrier, preferably a sheet material such as HDF. Impregnation of the decorative paper may be avoided if the paper is applied on a layer comprising thermosetting resin, for example, a powder layer.


A transparent overlay paper without any wear resistant particles or with only small scratch resistant particles may be applied on the wear resistant pattern in order to provide additional properties such as different gloss levels or to provide a layer that protects the press plate against wear during pressing.


Powder based surfaces may be applied with a basic mix that does not include any aluminium oxide particles. Such wear resistant particles may be applied in patterns in a second step and surface portions without any wear resistant particles may be formed even in powder based surfaces in order to reduce tool wear.


All described embodiments may be partly or completely combined.


Example 1—Digitally Formed Powder Overlay

A HDF sheet with a thickens of 8 mm was sprayed with deionized water and a powder mix of about 200 g/m2 of powder comprising wood fibres, melamine particles, brown colour pigments and aluminium particles was applied by scattering equipment on the HDF sheet. The water penetrated into the lower parts of the mix. The upper dry part of the mix was removed by vacuum and a very even powder mix of 150 gr/m2 was obtained. The mix was cold pressed with a metal roller and a hard stabilized powder based surface with a brown basic colour was obtained. The panel with the stabilized powder surface was put on a conveyer and displaced under a digital Piezo print head that provided a conventional ink jet print on the brown base coloured surface. The digital print covered about 20% of the surface and the basic colour. A digital print head was thereafter used to applied drops of blank ink comprising mainly water on the digitally printed surface portions. A higher intensity of drops was applied on the printed portions that were intended to form upper parts of the surface than on the printed portions that were intended to form lower parts of the surface after the final pressing operation. A dry mix of aluminium particles (85% weight) with an average size of 100 microns and spray dried melamine formaldehyde particles (15% weight) with a similar size was scattered on the whole surface. The sheet was thereafter displaced under a vacuum-sucking pipe where essentially all non-bonded aluminium oxide particles and melamine formaldehyde particles were removed. A protective transparent wear resistant layer or a so-called overlay was formed with aluminium oxide particles applied on essentially only the digitally printed surface portions. The panel was thereafter pressed against an embossed press plate during 15 seconds under a temperature of 170° C. in a 40 bars press. The surface with the protective layer was cured to a hard wear resistant surface with a high quality wear resistant digital print comprising a higher amount of aluminium oxide particles in the upper parts of the printed and embossed surface portions than in the lower surface portions.


Example 2—Digitally Formed Paper Overlay

A digital Piezo print head was used to applied drops of blank ink comprising mainly water on a melamine impregnated overlay paper sheet. The drops were applied in a raster pattern with a drop distance of about 1 mm. A higher intensity of drops with a drop distance of 0.5 mm was applied on the surface portions that were intended to form upper parts of the surface. No drops were applied on a 12 mm wide surface portion that extended over the whole length of the overlay paper and that corresponded to the surface portion where a saw blade cuts the pressed sheet and where the locking system is formed. A dry mix of aluminium particles with an average size of 100 microns was scattered on the whole overlay paper surface. The overlay paper was thereafter displaced under a vacuum-sucking pipe where essentially all non-bonded aluminium oxide particles were removed. The bonded aluminium oxide particles formed a pattern, which was essentially identical to the applied drops. The overlay with the aluminium oxide particles was displaced under an IR lamp and applied on a HDF sheet with a decorative melamine impregnated paper. The sheet was thereafter pressed against an embossed press plate during 15 seconds under a temperature of 170° C. in a 40 bars press. The surface with the decorative and overlay papers was cured to a hard wear resistant surface with a high quality wear resistant overlay comprising a base structure with accurately positioned aluminium oxide particles with a pre-defined distances between the particles and with a higher amount of aluminium oxide particles in the upper parts of the printed and embossed surface portions than in the lower surface portions. The sheet was thereafter cut along the surface area without any aluminium oxide particles and the locking system was formed in edge portions, which were almost completely free from aluminium oxide particles. The wear on the saw blade and the milling tool was considerably lower.


Example 3—Digital Wear Layer on Decorative Paper

A digital Piezo print head was used to applied drops of blank ink comprising mainly water on a melamine impregnated decorative paper applied on a HDF core. The drops were applied in a raster pattern with a drop distance of about 0.6 mm on surface portions that were intended to form lower parts of the pressed surface. A higher intensity of drops with a drop distance of about 0.3 mm was applied on surface portions that were intended to form upper parts of the pressed surface. No drops were applied on a 12 mm wide surface portion that extended over the whole length of the decorative paper and that corresponded to the surface portion where a saw blade cuts the pressed sheet and where the locking system is formed. A dry mix of aluminium particles with an average size of 100 microns was scattered on the whole surface of the decorative paper. The sheet was thereafter displaced under a vacuum-sucking pipe where essentially all non-bonded aluminium oxide particles were removed. The bonded aluminium oxide particles formed a pattern, which was essentially identical to the applied drops. The sheet with the decorative paper and with the aluminium oxide particles was displaced under an IR lamp. A conventional melamine impregnated overlay without any aluminium oxide particles was applied over the decorative paper and the sheet with the two papers was thereafter pressed against an embossed press plate during 15 seconds under a temperature of 170° C. in a 40 bars pressure. The surface with the decorative and overlay papers was cured to a hard wear resistant surface with a high quality wear resistant surface comprising a base structure with accurately positioned aluminium oxide particles with a pre-defined distances between the particles and with a higher amount of aluminium oxide particles in the upper parts of the embossed surface portions than in the lower surface portions. The sheet was thereafter cut along the surface area without any aluminium oxide particles and a locking system was formed in edge portions, which were almost completely free from aluminium oxide particles. The wear on the saw blade and the milling tool was considerably lower.


Embodiments

1. A method of forming a wear resistant layer comprising transparent or semitransparent wear resistant particles (15) on a surface (2) wherein the method comprises the steps of:

    • applying a liquid binder (11) in a pattern (BP) on the surface (2),
    • applying the wear resistant particles (15) on the surface (2),
    • bonding a part of the wear resistant particles (15) to the surface (2) with the liquid binder (11), and
    • removing non-bonded wear resistant particles (15) from the surface (2) such that the wear resistant layer is formed with evenly distributed wear resistant particles (15).


2. The method as in embodiment 1, wherein the wear resistant particles (15) are applied in a raster pattern with pre-determined distance (D1, D2) between the wear resistant particles (15).


3. The method as in embodiment 2, wherein the pre-determined distance (D1, D2) essentially corresponds to surface portions where the surface (2) is to be cut and/or where locking systems will be formed.


4. The method as in embodiments 1-3, wherein the surface (2) comprises a printed décor (P) and the wear resistant particles (15) are spaced from each other and coordinated in register with the printed décor (P).


5. The method as in embodiments 1-4, wherein the surface (2) is formed with embossed surface portions comprising upper (17a) and lower (17b) surface portions and wherein the content of wear resistant particles are higher in the upper portions (17a) than in the lower portions (17b).


6. The method as in any one of the preceding embodiments, wherein the wear resistant particles (15) comprise aluminium oxide (63) such as corundum.


7. The method as in any one of the preceding embodiments, wherein the wear resistant particles (15) are coated or mixed with a thermosetting resin.


8. The method as in any one of the preceding embodiments, wherein the surface (2) is a powder layer, a paper layer or a foil.


9. The method as in any one of the preceding embodiments, wherein the surface (2) is a part of a floor panel (1).


10. The method as in any one of the preceding embodiments, wherein the wear resistant particles (15) are removed by an airstream.


11. The method as in any one of the preceding embodiments, wherein the binder is a blank ink (11) comprising a liquid substance that is applied by a digital drop application head (30′).


12. The method as in embodiment 11, wherein the liquid substance is water based.


13. The method as in embodiment 11 or 12, wherein the liquid substance is exposed to IR light (23) or hot air.


14. The method as in embodiment 11, wherein the liquid substance is applied with a Piezo ink head.


15. The method as in embodiment 11, wherein the liquid substance is applied with a thermo ink head.


16. The method as in any one of the preceding embodiments, wherein the surface (2) with the wear resistant particles (15) is heated and pressed.


17. The method as in any one of the preceding embodiments, wherein the wear resistant particles (15) are applied by scattering.


18. The method as in any one of the preceding embodiments, wherein the wear resistant particles (15) are arranged in a wood grain or a stone pattern.


19. A panel (1) with a decorative surface (2) comprising a pattern (P) of wear resistant particles (15) wherein the wear resistant particles (15) are applied in a raster pattern with pre-determined distance between the wear resistant particles (15).


20. The panel as in embodiment 19, wherein the surface (2) comprises a printed décor (P) and the wear resistant particles (15) are spaced from each other and coordinated with the printed décor (P).


21. The panel as in embodiment 19 or 20, wherein the surface (2) comprises a printed and embossed décor with an upper (17a) and a lower (17b) surface portion and wherein the content of wear resistant particles (15) are higher in the upper surface portion (17a) than in the lower surface portion (17b).


22. The panel as in embodiments 19-21, wherein an edge portion comprises a higher content of wear resistant particles than an inner surface portion spaced from the edge portion.


23. The panel as in any one of the preceding embodiments 19-22, wherein the surface (2) is a paper layer or a foil.


24. The panel as in any one of the preceding embodiments 19-22, wherein the surface (2) comprises a powder layer.


25. The panel as in any one of the preceding embodiments 19-24, wherein the surface (2) is a part of a building panel (1).


26. The panel as in any one of the preceding embodiments 19-25, wherein the surface (2) is a part of a floor panel (1).


27. The panel as in any one of the preceding embodiments 19-26, wherein the wear resistant particles (15) comprise aluminium oxide such as corundum.


28. The panel as in any one of the preceding embodiments 19-27, wherein the wear resistant particles (15) are arranged in a wood grain or a stone pattern.


29. The panel as in any one of the preceding embodiments 19-28, wherein the surface (2) is a part of a panel (1) that is a laminate or wood floor, a powder based floor, a tile or a LVT floor.


30. A sheet (1) with a decorative surface (2) comprising a pattern (P) of wear resistant particles (15) wherein the wear resistant particles (15) are applied in a raster pattern with pre-determined distance (D1, D2) between the wear resistant particles.


31. The sheet as in embodiment 30, wherein the pre-determined distance (D1, D2) essentially corresponds to surface portions where the sheet (1) is to be cut into several panels (1a, 1b) and/or where locking systems will be formed.


32. The sheet as in embodiments 30 or 31, wherein the surface (2) comprises a printed décor (P) and the wear resistant particles (15) are spaced from each other and coordinated in register with the printed décor (P).


33. The sheet as in embodiments 30-32, wherein the surface (2) comprises a printed and embossed décor with upper (17a) and lower (17b) surface portions and wherein the content of wear resistant particles (15) are higher in the upper portions (17a) than in the lower portions (17b).


34. The sheet as in any one of the preceding embodiments 30-33, wherein the wear resistant particles (15) comprise aluminium oxide (63) such as corundum.


35. A paper comprising a pattern (P) of wear resistant particles (15) wherein the wear resistant particles (15) are applied in a raster pattern with pre-determined distance between the wear resistant particles (15).


While illustrative embodiments of the invention have been described herein, the present invention is not limited to the various preferred embodiments described herein but includes any and all embodiments having equivalent elements, modifications, omissions, combinations (e.g. of aspects across various embodiments), adaptations and/or alterations as would be appreciated by those in the art based on the present disclosure. The limitations in the claims are to be interpreted broadly based on the language employed in the claims and not limited to the examples described in the present specification or during prosecution of the application, which examples are to be construed as non-exclusive.

Claims
  • 1. A panel with a decorative surface comprising a pattern of wear resistant particles, wherein the wear resistant particles are arranged in a raster pattern with pre-determined distances between the wear resistant particles.
  • 2. The panel as claimed in claim 1, wherein the wear resistant particles are arranged in the raster pattern in at least a first portion of the surface.
  • 3. The panel as claimed in claim 1, wherein at a first portion of the surface, the wear resistant particles are arranged in a first raster pattern, the first raster pattern having the wear resistant particles separated from each other with a first pre-determined distance, and wherein at a second portion of the surface, the wear resistant particles are arranged in a second raster pattern, the second raster pattern having the wear resistant particles separated from each other with a second pre-determined distance, said second pre-determined distance exceeding said first pre-determined distance.
  • 4. The panel as claimed in claim 3, wherein the first portion of the surface corresponds to upper surface portions and the second portion of the surface corresponds to lower surface portions.
  • 5. The panel as claimed in claim 1, wherein the surface comprises a printed décor and the raster pattern is coordinated with the printed décor.
  • 6. The panel as claimed in claim 1, wherein the surface is an embossed surface comprising upper surface portions and lower surface portions.
  • 7. The panel as claimed in claim 1, wherein the surface comprises a printed and embossed décor with an upper surface portion and a lower surface portion.
  • 8. The panel as claimed in claim 7, wherein the upper surface portion comprises the wear resistant particles in a first raster pattern, the first raster pattern having the wear resistant particles separated from each other with a first pre-determined distance, and wherein the lower surface portion comprises the wear resistant particles in a second raster pattern, the second raster pattern having the wear resistant particles separated from each other with a second pre-determined distance,said second pre-determined distance exceeding said first pre-determined distance.
  • 9. The panel as claimed in claim 1, wherein the panel further comprises an edge portion and an inner surface portion, wherein the edge portion comprises the wear resistant particles in a first raster pattern, the first raster pattern having the wear resistant particles separated from each other with a first pre-determined distance, and wherein the inner surface portion comprises the wear resistant particles in a second raster pattern, the second raster pattern having the wear resistant particles separated from each other with a second pre-determined distance,said second pre-determined distance exceeding said first pre-determined distance.
  • 10. The panel as claimed in claim 1, wherein the surface is a paper layer or a foil.
  • 11. The panel as claimed in claim 1, wherein the surface comprises a powder layer.
  • 12. The panel as claimed in claim 1, wherein the surface is a part of a building panel.
  • 13. The panel as claimed in claim 1, wherein the surface is a part of a floor panel.
  • 14. The panel as claimed in claim 1, wherein the wear resistant particles comprise aluminum oxide.
  • 15. The panel as claimed in claim 1, wherein the pattern of wear resistant particles resembles a wood grain or a stone pattern.
  • 16. The panel as claimed in claim 1, wherein the surface is a part of a panel that is a laminate or wood floor, a powder based floor, a tile or a luxury vinyl tile (LVT) floor.
Priority Claims (1)
Number Date Country Kind
1350135-8 Feb 2013 SE national
CROSS REFERENCE TO RELATED APPLICATIONS

The present application is a divisional of U.S. application Ser. No. 16/034,565, filed on Jul. 13, 2018, which is a continuation of U.S. application Ser. No. 14/155,096, filed on Jan. 14, 2014, now U.S. Pat. No. 10,041,212, which claims the benefit of Swedish Application No. SE 1350135-8, filed on Feb. 4, 2013. The entire contents of each of U.S. application Ser. No. 16/034,565, U.S. application Ser. No. 14/155,096 and Swedish Application No. SE 1350135-8 are hereby incorporated herein by reference in their entirety.

US Referenced Citations (203)
Number Name Date Kind
3083116 Berndt Mar 1963 A
3397496 Sohns Aug 1968 A
3440076 Vaurio Apr 1969 A
3446184 Johnson May 1969 A
3545997 Hochberg Dec 1970 A
3634975 Hensley Jan 1972 A
3648358 Cannady et al. Mar 1972 A
3880687 Elmendorf et al. Apr 1975 A
3911160 Neuberg Oct 1975 A
4050409 Duchenaud et al. Sep 1977 A
4227200 Mansukhani Oct 1980 A
4233387 Mammino et al. Nov 1980 A
4312268 King et al. Jan 1982 A
4467007 Elgie Aug 1984 A
4504523 Miller et al. Mar 1985 A
4689259 Miller et al. Aug 1987 A
4796402 Pajala Jan 1989 A
4833530 Kohashi May 1989 A
4880689 Park et al. Nov 1989 A
4943816 Sporer Jul 1990 A
5204055 Sachs Apr 1993 A
5380392 Imamura et al. Jan 1995 A
5498466 Navarro Mar 1996 A
5594484 Furukawa Jan 1997 A
5597434 Kukoff Jan 1997 A
5627578 Weintraub May 1997 A
5718753 Suzuki et al. Feb 1998 A
5778789 Krishnan et al. Jul 1998 A
6094882 Pervan Aug 2000 A
6200410 Kukoff Mar 2001 B1
6387457 Jiang et al. May 2002 B1
6394595 Jiang et al. May 2002 B1
6402317 Yanagawa et al. Jun 2002 B2
6422696 Takahashi et al. Jul 2002 B1
6439713 Noguchi et al. Aug 2002 B1
6488994 Haller et al. Dec 2002 B1
6579616 Beckman Jun 2003 B1
6773799 Persson et al. Aug 2004 B1
7383768 Reichwein et al. Jun 2008 B2
7632561 Thiers Dec 2009 B2
7721503 Pervan May 2010 B2
7908815 Pervan Mar 2011 B2
8114513 Rentschler Feb 2012 B2
8337947 Camorani Dec 2012 B2
8353140 Pervan Jan 2013 B2
8371456 Scadden Feb 2013 B2
8464489 Pervan Jun 2013 B2
8465804 Provoost et al. Jun 2013 B2
8544230 Pervan Oct 2013 B2
8621814 Cappelle Jan 2014 B2
8763341 Pervan Jul 2014 B2
8808556 Kukoff Aug 2014 B2
9079212 Pervan et al. Jul 2015 B2
9140010 Pervan Sep 2015 B2
9279058 Pervan et al. Mar 2016 B2
9321925 Pervan et al. Apr 2016 B2
9346303 Grinberg May 2016 B2
9371456 Pervan et al. Jun 2016 B2
9446602 Pervan Sep 2016 B2
9528011 Pervan et al. Dec 2016 B2
9630404 Pervan et al. Apr 2017 B2
9670371 Pervan et al. Jun 2017 B2
9738095 Pervan et al. Aug 2017 B2
9873803 Pervan et al. Jan 2018 B2
10016988 Pervan et al. Jul 2018 B2
10029484 Pervan et al. Jul 2018 B2
10035358 Pervan et al. Jul 2018 B2
10041212 Pervan Aug 2018 B2
10189281 Pervan et al. Jan 2019 B2
10239346 Vermeulen Mar 2019 B2
10369814 Pervan et al. Aug 2019 B2
10384471 Pervan Aug 2019 B2
10414173 Pervan Sep 2019 B2
10556447 Pervan Feb 2020 B2
10596837 Pervan et al. Mar 2020 B2
10723147 Pervan et al. Jul 2020 B2
10800186 Pervan et al. Oct 2020 B2
10988901 Pervan Apr 2021 B2
11014378 Pervan et al. May 2021 B2
11065889 Pervan Jul 2021 B2
11130352 Pervan et al. Sep 2021 B2
11285508 Pervan et al. Mar 2022 B2
20010005542 Graab et al. Jun 2001 A1
20010022607 Takahashi et al. Sep 2001 A1
20020149137 Jang et al. Oct 2002 A1
20030108718 Simon et al. Jun 2003 A1
20030138618 Courtoy Jul 2003 A1
20030173695 Monkhouse Sep 2003 A1
20030207083 Hansson Nov 2003 A1
20040101619 Camorani May 2004 A1
20040142107 Eriksson et al. Jul 2004 A1
20040153204 Blanco Aug 2004 A1
20040170912 Brennan Sep 2004 A1
20040177788 Rick et al. Sep 2004 A1
20040180181 Franzoi et al. Sep 2004 A1
20040180980 Petter et al. Sep 2004 A1
20040217186 Sachs Nov 2004 A1
20050093194 Oriakhi May 2005 A1
20050128274 Matsushima Jun 2005 A1
20050176321 Crette et al. Aug 2005 A1
20050229353 Azmoun et al. Oct 2005 A1
20050249923 Reichwein et al. Nov 2005 A1
20060144004 Nollet Jul 2006 A1
20060179773 Pervan Aug 2006 A1
20060188670 Kojima Aug 2006 A1
20060192180 Ichitani Aug 2006 A1
20060246266 Hall Nov 2006 A1
20060276367 Shah et al. Dec 2006 A1
20070049047 Fujimoto Mar 2007 A1
20070091160 Kis Apr 2007 A1
20070107344 Kornfalt May 2007 A1
20070193174 Vogel et al. Aug 2007 A1
20070224438 Van Benthem et al. Sep 2007 A1
20070231583 Ilzuka et al. Oct 2007 A1
20070240585 Vaish et al. Oct 2007 A1
20070283648 Chen Dec 2007 A1
20070299196 Ohkoshi et al. Dec 2007 A1
20080010924 Pietruczynik et al. Jan 2008 A1
20080075859 Baker et al. Mar 2008 A1
20080098659 Sung May 2008 A1
20080185092 Blenkhorn Aug 2008 A1
20080241472 Shiao et al. Oct 2008 A1
20080261003 Lewis et al. Oct 2008 A1
20080292885 Dohring Nov 2008 A1
20090010682 Camorani Jan 2009 A1
20090031662 Chen et al. Feb 2009 A1
20090047480 Juers et al. Feb 2009 A1
20090116966 Althoff et al. May 2009 A1
20090151866 Endert Jun 2009 A1
20090155612 Pervan et al. Jun 2009 A1
20090252925 Provoost Oct 2009 A1
20100009282 Katoh et al. Jan 2010 A1
20100046010 Bauer Feb 2010 A1
20100092731 Pervan et al. Apr 2010 A1
20100134895 Hoffman et al. Jun 2010 A1
20100166997 Chisaka et al. Jul 2010 A1
20100192793 Verhaeghe Aug 2010 A1
20100196678 Vermeulen Aug 2010 A1
20100300020 Vermeulen Dec 2010 A1
20100300030 Pervan et al. Dec 2010 A1
20100307677 Buhlmann Dec 2010 A1
20100323187 Kalwa Dec 2010 A1
20110024938 Tripp et al. Feb 2011 A1
20110038826 Kimball et al. Feb 2011 A1
20110129640 Beall Jun 2011 A1
20110171412 Döhring Jul 2011 A1
20110176901 Chait et al. Jul 2011 A1
20110177354 Ziegler et al. Jul 2011 A1
20110189448 Lindgren et al. Aug 2011 A1
20110189471 Ziegler et al. Aug 2011 A1
20110190904 Lechmann et al. Aug 2011 A1
20110237739 Tada Sep 2011 A1
20110247748 Pervan et al. Oct 2011 A1
20110250404 Pervan Oct 2011 A1
20110261464 Hoffman et al. Oct 2011 A1
20110268937 Schacht et al. Nov 2011 A1
20110293906 Jacobsson Dec 2011 A1
20120176443 Robertson et al. Jul 2012 A1
20120196081 Gleich Aug 2012 A1
20120263878 Ziegler et al. Oct 2012 A1
20120263965 Persson et al. Oct 2012 A1
20120264853 Ziegler et al. Oct 2012 A1
20120269983 Grinberg Oct 2012 A1
20130043211 Vermeulen Feb 2013 A1
20130108873 Shiao et al. May 2013 A1
20130243460 Makiura et al. Sep 2013 A1
20140017452 Pervan et al. Jan 2014 A1
20140023832 Pervan et al. Jan 2014 A1
20140028772 Pervan Jan 2014 A1
20140196618 Pervan et al. Jul 2014 A1
20140198168 Pervan et al. Jul 2014 A1
20140198170 Pervan et al. Jul 2014 A1
20140199495 Pervan et al. Jul 2014 A1
20140199513 Pervan et al. Jul 2014 A1
20140199531 Pervan et al. Jul 2014 A1
20140220318 Pervan Aug 2014 A1
20150030817 Wiegelmann Jan 2015 A1
20150274997 Pervan et al. Oct 2015 A1
20150298492 Palumbo Oct 2015 A1
20160144612 Pervan et al. May 2016 A1
20160208116 Pervan et al. Jul 2016 A1
20160250853 Pervan et al. Sep 2016 A1
20160325559 Pervan et al. Nov 2016 A1
20160368280 Pervan Dec 2016 A1
20170066255 Pervan et al. Mar 2017 A1
20170204281 Pervan et al. Jul 2017 A1
20170232761 Pervan et al. Aug 2017 A1
20170348984 Pervan et al. Dec 2017 A1
20180111390 Pervan et al. Apr 2018 A1
20180127605 Pervan et al. May 2018 A1
20180178553 Pervan Jun 2018 A1
20180298216 Pervan et al. Oct 2018 A1
20180320321 Pervan Nov 2018 A1
20190119513 Pervan et al. Apr 2019 A1
20190284819 Pervan et al. Sep 2019 A1
20190345348 Pervan et al. Nov 2019 A1
20190351685 Pervan Nov 2019 A1
20200079114 Pervan et al. Mar 2020 A1
20200139726 Pervan et al. May 2020 A1
20200171849 Pervan et al. Jun 2020 A1
20210001647 Pervan Jan 2021 A1
20210070065 Pervan Mar 2021 A1
20210379907 Pervan et al. Dec 2021 A1
Foreign Referenced Citations (60)
Number Date Country
10 2007 015 907 Oct 2008 DE
10 2010 036 454 Jan 2012 DE
0 403 264 Dec 1990 EP
0 657 309 Jun 1995 EP
0 769 535 Apr 1997 EP
0 769 535 Sep 1997 EP
1 020 303 Jul 2000 EP
1 020 765 Jul 2000 EP
1 209 199 May 2002 EP
1 584 378 Oct 2005 EP
1 961 556 Aug 2008 EP
2 106 903 Oct 2009 EP
2 108 524 Oct 2009 EP
2 213 476 Aug 2010 EP
2 264 259 Dec 2010 EP
2 363 299 Sep 2011 EP
1 215 551 Dec 1970 GB
1 344 197 Jan 1974 GB
2 065 556 Jul 1981 GB
2 128 898 May 1984 GB
2419110 Apr 2006 GB
2 452 545 Mar 2009 GB
S51-128409 Nov 1976 JP
H05-320541 Dec 1993 JP
H06-183128 Jul 1994 JP
H06-287467 Oct 1994 JP
H09-216351 Aug 1997 JP
H09-216453 Aug 1997 JP
H10-095165 Apr 1998 JP
2000-158796 Jun 2000 JP
2001-311254 Nov 2001 JP
2005-097339 Apr 2005 JP
2006-036559 Feb 2006 JP
2006-167651 Jun 2006 JP
2008-156573 Jul 2008 JP
2008-265229 Nov 2008 JP
2009-173003 Aug 2009 JP
2010-209325 Sep 2010 JP
2011-522138 Jul 2011 JP
2009-0112326 Oct 2009 KR
WO 9965699 Dec 1999 WO
WO 0147724 Jul 2001 WO
WO 0242373 May 2002 WO
WO 2005120847 Dec 2005 WO
WO 2006125036 Nov 2006 WO
WO 2007033031 Mar 2007 WO
WO 2007060298 May 2007 WO
WO 2008042088 Apr 2008 WO
WO 2008121749 Oct 2008 WO
WO 2009030935 Mar 2009 WO
WO 2009124704 Oct 2009 WO
WO 2010070485 Jun 2010 WO
WO 2011064075 Jun 2011 WO
WO 2011129757 Oct 2011 WO
WO 2012078533 Jun 2012 WO
WO 2012141651 Oct 2012 WO
WO 2014014400 Jan 2014 WO
WO 2014014400 Jan 2014 WO
WO 2014037823 Mar 2014 WO
WO 2014109703 Jul 2014 WO
Non-Patent Literature Citations (18)
Entry
U.S. Appl. No. 14/152,295, Darko Pervan and Tony Pervan, filed Jan. 10, 2014, (cited herein as US Patent Application Publication No. 2014/0199495 A1 of Jul. 17, 2014).
U.S. Appl. No. 15/845,828, Darko Pervan and Tony Pervan, filed Dec. 18, 2017, (Cited herein as US Patent Application Publication No. 2018/0127605 A1 of May 10, 2018).
U.S. Appl. No. 16/428,257, Darko Pervan and Tony Pervan, filed May 31, 2019, (Cited herein as US Patent Application Publication No. 2019/0284819 A1 of Sep. 19, 2019).
U.S. Appl. No. 16/733,493, Darko Pervan and Tony Pervan, filed Jan. 3, 2020, (Cited herein as US Patent Application Publication No. 2020/139726 A1 of May 7, 2020).
U.S. Appl. No. 16/946,312, Darko Pervan and Tony Pervan, filed Jun. 16, 2020, (Cited herein as US Patent Application Publication No. 2021/0070065 A1 of Mar. 11, 2021).
U.S. Appl. No. 17/406,424, Darko Pervan and Tony Pervan, filed Aug. 19, 2021.
International Search Report issued in PCT/SE2014/050141, Apr. 29, 2014, Patent-och registreringsverket, Stockholm, SE, 6 pages.
Extended European Search Report dated Aug. 16, 2016 in EP 14746498.6, European Patent Office, Munich, DE, 7 pages.
Extended European Search Report dated Oct. 22, 2018 in EP 18189041.9, European Patent Office, Munich, DE, 7 pages.
Extended European Search Report dated Sep. 20, 2021 in EP 21175495.7, European Patent Office, Munich, DE, 6 pages.
Pervan, Darko, et al., Technical Disclosure entitled Digital Printing and Embossing, IP.com No. IPCOM000224950D, IP.com PriorArtDatabase, Jan. 15, 2013, 89 pages.
Pervan, Darko, Technical Disclosure entitled “Digital Overlay,” IP.com No. IPCOM000225271D, IP.com PriorArtDatabase, Feb. 5, 2013, 24 pages.
Hudd, “Chapter 1: Inkjet Printing Technologies.” Chemistry of Inkjet Inks, 2010, pp. 3-18, World Scientific Publishing Co. PTE. Ltd. , Published in Singapore and Hackensack, NJ.
Owens, James C., “A Tutorial on Printing”, Imaging.org-Resources, 2010, pp. 1-5, Society for Imaging sciences and Technology, retrieved Jul. 27, 2015 and Dec. 27, 2018 from http://web.archive.org/web/20100706153535/http://www.imaging.org/ist/resources/tutorials/printing.cfm.
Odian, George, “Principles of Polymerization,” 1991, Third Edition, 5 pages incl. pp. 122-123, John Wiley & Sons, Inc., New York, NY, USA.
Romano, Frank J., Digital Printing Pocket Primer Series “Mastering On-Demand and Variable Data Printing for Profit,” Copyright 2000, 52 pages, Windsor Professional Information, L.L.C., San Diego, CA.
Pervan, Darko, et al., U.S. Appl. No. 17/406,424 entitled “Digital Binder and Powder Print,” filed in the U.S. Patent and Trademark Office on Aug. 19, 2021.
Pervan, Darko, et al., U.S. Appl. No. 17/673,445 entitled “Digital Thermal Binder and Powder Printing” filed in the U.S. Patent and Trademark Office on Feb. 16, 2022.
Related Publications (1)
Number Date Country
20210214898 A1 Jul 2021 US
Divisions (2)
Number Date Country
Parent 16034565 Jul 2018 US
Child 17218782 US
Parent 14155096 Jan 2014 US
Child 16034565 US