Patent Application
20230274891
The present invention generally relates to the field of electrical energy storage devices. More particularly, the present invention relates to the electrode by direct growth cross-linked carbon nanotubes on a microstructured metal substrate and supercapacitors made of these electrodes.
Supercapacitors, also known as an electrochemical capacitor (EC) or electronic double-layer capacitor (EDLC), is a unique electrical energy storage devices. Compared to the batteries, supercapacitors have the advantages in higher power density, faster charging-discharging, longer life span, and broader operating temperature.
Usually, supercapacitors have the potential used in the field of mid-range energy storage due to a lower energy density than batteries. Supercapacitors are physically storing the charges on the surface of the electrode and achieving the separation of charge in a Helmholtz double layer at the interface between the electrode surface and an electrolyte. One example of such a supercapacitor based on a silicon substrate is shown in WO2018/162580. Therefore, the corresponding capacitance and energy density of supercapacitors are proportional to the surface area of electrode materials. In order to increase the energy density of supercapacitors, two requirements are put forward on the active material: (1) a superb electrical conductivity, which a prerequisite condition to make sure the chargers can flow quickly during charging/discharging, and (2) a larger effective surface area, which is an essential condition to offer enough positions for chargers adherence.
Carbon nanotubes (CNTs), deriving from the development of nanoscience and nanotechnology, possess unique properties, such as extraordinary mechanical, excellent electrical conductivity, and nanoscale sizes making them suitable for a promising application in the field of energy storage. A typical method for a CNTs layer synthesized by chemical vapor deposition (CVD) is using Fe nanoparticles as the catalysts which are deposited on a barrier layer of Al2O3 or SiO2 (Reference: Kenji Hata et al. Science 306, 1362 (2004); O. Pitkänen, et al. Scientific Reports 7.1 (2017): 1-7). Other examples using nanotube on metal foil are discussed in U.S. Pat. No. 7,553,341, Fabien Nassoy et al: “Single step synthesis of a vertically aligned carbon nanotube forest on aluminum foils”; Nanomaterials 2019, 9, 1590, and Itir Bakis Dogru et al.; “Flexible supercapacitor electrodes with vertically aligned nanotubes grown on aluminum foils.” Progress in Natural Science: Materials International 26 (2016) 232-236. However, there are several drawbacks associated with such a CNTs layer for supercapacitor applications. First, the existence of a barrier increases the contact resistance between the CNTs layer and the current collector. Second, this CNTs layer perpendicular to the substrate, which is a loose structure with a small mass density that is not beneficial to improve the energy density of supercapacitors.
Other example of the prior art are discussed in WO2008/048347 where aligned nanostructures are provided on a surface, where the surface has been patterned to provide catalyst island where the nanotubes as grown. In WO2005/065425 presents a method for initiating nanostructure growth where a catalyst is deposited on a resistive element prior to a heating process. CN108217628 describes a method for making a threedimensional network of nanotubes from an alumina template, such as a through hole, containing nickel sulfate particles, where the nanotubes are upright relative to the surface and includes further nanotubes linking the upright nanotubes.
In addition, several methods use CNTs ink or CNTs nanocomposites to form an electrode on a current collector (Reference: Bolin Chen et al., “Fully packaged carbon nanotube supercapacitors by direct ink writing on flexible substrates.” ACS applied materials & interfaces 9, no. 34 (2017): 28433-28440, and Wei Gong et al., “Carbon nanotubes and manganese oxide hybrid nanostructures as high performance fiber supercapacitors.” Communications Chemistry 1, no. 1 (2018): 1-8). Supercapacitor assembled with such electrodes shows poor equivalent series resistance (ESR) because a binder is often used to hold the CNTs layer on the current collector, resulting in increased contact resistance and further limiting the power density of supercapacitors. Besides, charge transfer across parallel CNTs generally is more resistive than that via inner tube paths in interconnected CNTs. WO2005/065425
Pai Lu et al. reported a method to synthesize a carbon nanotube film on etched silicon for on-chip supercapacitor (Pub. No.: US 2020/001356A1, and Pai Lu et al., “Taper silicon nano-scaffold regulated compact integration of 1D nanocarbons for improved on-chip supercapacitor.” Nano Energy 41 (2017): 618-625). Silicon is a good candidate substrate to develop on-chip supercapacitor due to compatible with intergrated circuits chip manufacturing. However, the silicon substrate is not flexible, and more expensive and poor conductivity comparing to metal film substrates
It is therefore and object of the present invention to provide a method for fabricating a high-performance supercapacitor electrode without the above-described problems.
A further object of the present invention is to offer an electrode that can be mass-produced and used for energy storage devices.
The objects of the invention are solved by providing a method, electrode and supercapacitor as defined in the accompanying claims.
According to the invention a method is provided for directly growing cross-linked carbon nanotubes on a metal) current collector film without using a binder or a barrier layer, and also a method for synthesizing highly dense cross-linked carbon nanotubes with an interconnected structure and high mass loading.
More in detail the present invention thus provides a process for fabricating an electrode by use of a direct growth cross-linked carbon nanotubes on a microstructured metal substrate, which can also act as a current collector. More specifically, the process begins to form the microstructures on the surface of a metal film substrate. Next, the microstructured substrate is coated with a metal layer or metal compounds which can convert into metal nanoparticles by subsequent heat treatment in a reducing gas atmosphere. Finally, the cross-linked carbon nanotubes are grown on the microstructured substrate under the catalysis of metal nanoparticles by atmospheric pressure chemical vapor deposition (APCVD) technique. A supercapacitor assembled with such electrodes exhibits an extremely high capacitance and an excellent equivalent series resistance (ESR).
The present invention provides a process for fabricating an electrode as well as the resulting electrode and supercapacitor utilizing said electrode, which composes a microstructured metal film substrate (current collector), metal nanoparticles, and cross-linked carbon nanotubes directly grown onto the current collector. The process comprises: (a) forming the microstructures on a metal film substrate for achieving surface gain and enabling cross-linked CNTs growth; (b) depositing metal or metal compounds layer on the surface of the microstructures; (c) converting metal or metal compounds layer into metal nanoparticles as the catalysts; (d) growing cross-linked carbon nanotubes on the microstructures in the presence of the catalysts. Specifically, the surface area of the microstructured metal film substrate is enlarged, offering larger space than the flat metal film substrate to deposit plenty of metal nanoparticles as catalysts for growing CNTs. Simultaneously, the irregular surface provides a scaffold template to grow CNTs along various directions to achieve CNTs interweaving together, eventually forming highly dense cross-linked carbon nanotubes with high mass loading coated onto the microstructured metal film substrate. More particularly, the highly-dense cross-linked carbon nanotubes are directly grown on the current collector without a binder or a barrier layer, which effectively reduces the contact resistance between the cross-linked carbon nanotubes and the current collector. Supercapacitors assembled with such electrodes could show a high capacitance and a low equivalent series resistance (ESR). Also, cross-linked carbon nanotubes are a superb scaffold structure for loading with pseudocapacitive materials to form a pseudocapacitive electrode. Typically, pseudocapacitive materials include transition metal oxides (manganese oxide, nickel oxide, cobalt oxide, and ruthenium oxide) and conductive polymers (polyaniline, polypyrrole, and Poly(3,4-ethylene dioxythiophene): poly(4-styrene sulfonate) (PEDOT: PSS)).
The metal film substrate involved in this invention could be any metals, which can be fabricated with a microstructured surface with corresponding fabricating methods. The microstructured surface can support metal nanoparticles as the catalysts and simultaneously offer a scaffold template to direct grow cross-linked carbon nanotubes on the metal film substrate. The metal film substrate includes any type of metals, such as aluminum, copper, nickel, titanium, chromium, or stainless steel. The metal film substrates should have impurity controlled for leakage current optimization. The metal film substrate should form a stable electrochemical system with the electrolyte. Both dry and wet etching can be applied to create the microstructures on these metal film substrates by physical or chemical ways, such as chemical etching, mechanical lapping, or laser etching, etc. The structures are with uniaxial open down to the substrate about sub-microns to tens microns deep and range from submicron to microns wider at the top, preferably within the range of 0.5 to 50 microns deep depending on the thickness of the metal film substrate and 0.4 to 5 microns wide.
According to the invention, aluminum (Al) is the preferred metal but not limited to Al based on its properties.
The metal film substrate in this invention is therefore preferable using aluminum foil as an example to grow directly cross-linked carbon nanotubes. Therefore, aluminum foil is involved in some embodiments as one of the metal substrates.
In some embodiments, the metal film substrate includes any structural type of metal products, such as: flat metal foil, porous metal foil.
According to the present invention, there is provided the methods to deposit metal or metal compounds layer on the microstructured metal film substrate by physical vapor deposition (PVD) or coating with metal compound precursors.
In some embodiments, a metal layer deposited by physical vapor deposition (PVD) may include electron-beam evaporation, thermal evaporation, or sputtering.
In some embodiments, metal compounds layer deposited by precursors may include dip coating or spray coating.
In some embodiments, the element of the metal layer includes nickel, iron, cobalt, or a mixture of any of the above; metal compounds have nickel compound, iron compound, cobalt compound, or a combination of any of the above.
In some embodiments, a metal compound precursor is prepared by dissolving the metal compounds into a soluble solvent (typically: water or organic solvents).
According to the present invention, there is provided the methods to form metal nanoparticles on the microstructured metal film substrate by heat treatment in a reducing atmosphere (typically: hydrogen) using a per se known process. The method preferably comprises the following steps: (a) oxidized metal layer is reduced to the metal layer, and further formed to metal nanoparticles; or (b) the formation of metal nanoparticles from the metal compounds is achieved by the simultaneous action of pyrolysis and reduction reactions. During heat treatment, surface energy plays a crucial role in the nucleation process. The size and number of metal nanoparticles are depended on the thickness of the metal layer or the concentration of the metal compound, heating rate, and holding temperature.
In some embodiments, the size of nickel nanoparticles is around 5˜100 nm, and the nickel clusters have a larger size of 0.5˜2 μm during heat treatment at 100˜400° C. in a hydrogen atmosphere.
According to the present invention, there is provided a method to grow cross-linked carbon nanotubes on the microstructured metal film substrate. This method is a typical catalytic process for producing carbon material through the APCVD technique, which is well-known to the skilled person. Carbon-containing gas is decomposed into carbon atoms, which are further orderly assembled to form CNTs (more specifically, multi-walled carbon nanotubes (MWCNTs)) in the presence of the metal catalysts at the temperature of 400˜600° C. Ultimately, abundant CNTs are intertwined together to form highly dense cross-linked carbon nanotubes.
In some embodiments, the carbon-containing gas includes acetylene, methane, ethylene, propane, butane, or a mixture of any of the above.
In some embodiments, the thickness of the cross-linked carbon nanotubes can reach up to 1200 μm (mass loading: up to ˜60 mg/cm2).
In an embodiment of the present invention provides electrodes to assemble supercapacitor for electrical energy storage, wherein the supercapacitor structure comprises: at least two opposing electrodes, the separator between any two electrodes, and electrolyte permeated into the electrodes and the separators. The supercapacitor structure can further be packaged into a cylindrical, stacking, flat jellyroll cell, or surface mounting device.
In a variation on this embodiment, the electrode used in electrical energy storage devices include: capacitor, battery, or hybrid capacitor.
Supercapacitor Electrode
Single-side electrode 1 and double-side electrode 2 have the same fabrication processes. Single-side electrode 1 is only fabricated with metal microstructures 4, deposited with metal nanoparticles 5, and coated with cross-linked carbon nanotubes 6 on one side of the metal film substrate 3. Double-side electrode 2 is fabricated with metal microstructures 4, deposited with metal nanoparticles 5, and coated with cross-linked carbon nanotubes 6 on both sides of the metal film substrate 3.
Preparation of Supercapacitor Electrode
The preparation supercapacitor electrode in this invention involves four steps: (1) forming metal microstructures 4 on the metal film substrate 3; (2) depositing metal or metal compounds layer on the surface of metal microstructures 4; (3) converting metal or metal compounds layer into metal nanoparticles 5 as the catalysts; (4) growing cross-linked carbon nanotubes 6 on the metal microstructures 5 in the presence of the catalysts. Aluminum foil, one of the typical metal film substrate, is used as the current collector in supercapacitor. Therefore, aluminum foil is used as one example of a metal film substrate to show the detailed fabrication process.
Fabrication of Microstructured Aluminum Foil
Before etching, aluminum foil is sequentially cleaned by deionized water, acetone, and isopropanol. Then, aluminum foil is performed surface alkali treatment by NaOH solution (1 mol/L) at 50˜60° C. for 2˜3 minutes. For a typical chemical acid etching, aluminum foil is etched by a mixed acid solution of 1 mol/L HCl and 3 mol/L H2SO4 at the temperature of 40˜50° C. for the etching time of 3˜6 hours. The etching time is one of the parameters to control the shape size and aspect ratio of aluminum microstructures on aluminum foil. The following reactions are carried out in chemical acid etching.
2Al+6HCl→2AlCl3+3H2
2Al+3H2SO4→Al2(SO4)3+3H2
For a typical electrochemical acid etching, aluminum foil is performed in an electrochemical cell as the working electrode, and platinum foil is used as the counter electrode. Aluminum foil is etched under a constant current density of 100˜400 mA/cm2 in a mixed solution of 1 mol/L HCl and 3 mol/L H2SO4 at the temperature of 70˜80° C. for the etching time of 30˜600 seconds. Similarly, the shape size and aspect ratio of aluminum microstructures are controlled by constant current density and etching time. For etching single-side aluminum microstructures, one side of aluminum foil is protected by tape and the other side is exposed to the mixed solution. For etching double-side aluminum microstructures, both sides of aluminum foil are without protection, which can contact and reaction with the mixed solution. The following equations take place during electrochemical acid etching.
Al→Al3++3e− Anode (aluminum foil)
2H++2e−→H2 Cathode (platinum foil)
As stated above this results in a microstructured surface having surface features with uniaxial open down to the substrate in the range of sub-microns to tens of microns deep and from submicron to microns wider at the top, preferably within the range of 0.5 To 50 microns deep depending on the thickness of the metal film substrate and 0.4 to 5 microns wide.
Deposition of nickel nanoparticles on microstructured aluminum foil After etching aluminum foil, aluminum microstructures are deposited and coated with nickel nanoparticles, as shown in
For the nickel compound pyrolysis method, various nickel precursors can be prepared by dissolving nickel compounds (NiCl2, Ni(NO3)2, or Ni(CH3CO2)2, etc.) in water, methanol, or ethanol. Then, these nickel precursors are sprayed on the microstructured aluminum foil. For the single-side electrode, nickel precursors only spray on one side of the microstructured aluminum foil, and both sides are sprayed for the double-sided electrode. Nickel compounds are well coated on the surface of aluminum microstructures as the solvent evaporation, and the following equations have described the formation of nickel compounds.
NiCl2 solution→NiCl2·6H2O
Ni(NO3)2 solution→Ni(NO3)2·6H2O
Ni(CH3CO2)2 solution→Ni(CH3CO2)2·xH2O, where x can be 0,2, and 4.
Growth of Cross-Linked Carbon Nanotubes on Microstructured Aluminum Foil
Cross-linked carbon nanotubes are the primary activated material for electric double-layer capacitors (EDLC).
In a typical process, the microstructured aluminum foil deposited with nickel or nickel compounds is placed in the center of the tube furnace. The air in the tube furnace is bumped out and then filled with an Argon gas several times to reduce oxygen content. Then, 300˜500 sccm of Ar and 50˜150 sccm of H2 is introduced into the tube to maintain atmospheric pressure. The tube furnace is heated up to 400˜600° C. at the heating rate of 10° C. When the temperature reached to 400˜600° C., 5˜20 sccm C2H2 carbon-containing gas is introduced into the tube and held at the temperature of 400˜600° C. for 10 minutes to 2 hours. After that, C2H2, Hz, and Ar supply are shut off, and the tube furnace is cooled down to room temperature (25° C.) in a nitrogen atmosphere with a flow rate of 400 sccm. At the end of the APCVD process, the cross-linked carbon nanotubes are produced on the microstructured aluminum foil. In an APCVD process, the following reactions are taking place, forming cross-linked carbon nanotubes on microstructured aluminum foil.
Ni Nanoparticle Formation
Carbon Materials Formation
Supercapacitor
Characterization of Electrode Materials
In one embodiment of the present invention, the thickness of the cross-linked carbon nanotubes can reach up to ˜1200 μm (mass loading: up to ˜60 mg/cm2), and which is adjusted by the number of nickel nanoparticles and the APCVD time. Supercapacitor with such electrodes has the outstanding impedance properties, (1) a reduced contact resistance because of CNT layer is directly grown on the current collector, it does not need a binder to fix carbon layer; (2) a reduced charge transfer resistance due to the superb the electrical conductivity of CNT and interweaved structure in the carbon layer.
Electrochemical Capacitive Performances
A supercapacitor is assembled to investigate the capacitive performances of the cross-linked carbon nanotubes electrode. Two electrodes (each in the size of 1×1 cm, mass loading of 32 mg) are packaged into a stainless steel button cell (CR2032) by a digital pressure controlled electric crimper (MSK-160E). Tetraethylammonium tetrafluoroborate (Et4NBF4, 1 mol/L in acetonitrile) is used as the electrolyte, and the glass fiber filter is used as the separator. The cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) are performed by an electrochemical potentiostat (BioLogic VSP-300). The Kelvin connection clips are used during the tests to eliminate the effect of contact resistance.
Various electrodes are prepared by the APCVD technique. The prepared electrodes are loaded with different carbon mass from 12.7 mg to 52.2 mg, which are controlled by the number of nickel nanoparticles and the APCVD time (20˜60 minutes). Several supercapacitors are packaged into stainless steel button cell (CR2032), shown as example 1˜example 7. Tetraethylammonium tetrafluoroborate (Et4NBF4, 1 mol/L in acetonitrile) and the glass fiber filter are used as the electrolyte and the separator, respectively. The corresponding CV and EIS of examples are tested by an electrochemical potentiostat (BioLogic VSP-300). The calculated capacitance normalized to the area of cross-linked carbon nanotubes are listed in TABLE 1. The areal capacitance of examples is increased from 550 mF/cm2 to 2009 mF/cm2 as the function of carbon mass loadings from 12.7 mg to 52.2 mg. The corresponding gravimetric capacitances are also calculated from 32.7 to 43.3 F/g.
To summarize the present invention relates to a method for fabricating an electrode for a supercapacitor based on carbon nanotubes. The electrode composes a microstructured metal film substrate (current collector) and cross-linked carbon nanotubes grown onto the current collector. The method comprising the process of:
This way an electrode may be fabricated with the method described above constituted by said metal microstructures, metal catalysts, and cross-linked carbon nanotubes, which can be formed on the single or double side of the metal film substrate.
The electrode may be used to assemble a supercapacitor structure comprising two single-side electrodes, separator, and electrolyte. The supercapacitor may also include a double-sided electrode, the supercapacitor structure comprising two single-side electrodes, one double-side electrode, separator, and electrolyte. The supercapacitor structure can further be packaged into cylindrical, stacking, flat jellyroll cells. or surface mounting device as the metal film substrate is flexible.
The metal film substrate includes any structural type of metal products, such as: flat metal foil; or porous metal foil suitable for being provided with the microstructures within the suitable size range adapted to receiving and maintaining the catalyst particles interacting with the carbon nanotubes.
The metal film substrate may be constituted by or include any type of material capable of receiving and containing the metal layer or compound, preferably one or more of aluminum, copper, nickel, titanium, chromium, or stainless steel. The microstructures in the metal film substrate can be fabricated by a physical or chemical method.
The deposion of the metal layer on the substrate can be achieved by electron-beam evaporation, thermal evaporation, or sputtering and may include nickel, iron, cobalt, or a mixture of any of the above.
The deposition of a metal compound layer can be achieved by dip coating or spray coating using a metal compound precursor and may include a nickel compound, iron compound, cobalt compound, or a mixture of any of the above. The metal compound precursors can be prepared by dissolving the metal compounds into a soluble solvent, such as: water, methanol, ethanol, acetone, diethyl ether, or ethyl acetate, etc.
The process of converting the metal or metal compounds layer into metal nanoparticles is performed at 100˜400° C. in a hydrogen atmosphere, where the formed metal nanoparticles include nickel nanoparticles, iron nanoparticles, cobalt nanoparticles, or a mixture of any of the above.
The growing of cross-linked carbon nanotubes may be formed by the catalytic pyrolysis of carbon-containing gas by APCVD at 400˜600° C., where the carbon-containing gases include acetylene, methane, ethylene, propane, butane, or a mixture of any of the above. The cross-linked carbon nanotubes may include at least one of the following: single-walled carbon nanotubes (SWCNTs); and multi-walled carbon nanotubes (MWCNTs).
The cross-linked carbon nanotubes can be acted as a scaffold structure for loading with pseudocapacitive materials to form a pseudocapacitive electrode. The pseudocapacitive electrode may include transition metal oxides such as at least one of manganese oxide, nickel oxide, cobalt oxide, and ruthenium oxide, and conductive polymers include at least one of polyaniline, polypyrrole, and Poly(3,4-ethylene dioxythiophene): poly(4-styrene sulfonate) (PEDOT: PSS). The pseudocapacitor may comprise: at least two opposing pseudocapacitive electrodes, the separator between any two pseudocapacitive electrodes, and electrolyte permeated into the pseudocapacitive electrodes and the separators.
The supercapacitor according to the invention for electrical energy storage, preferably comprises: at least two opposing electrodes, the separator between any two electrodes, and electrolyte permeated into the electrodes and the separators. It may also include pseudocapacitive materials include transition metal oxides or conductive polymers.
| Number | Date | Country | Kind |
|---|---|---|---|
| 20201116 | Oct 2020 | NO | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2021/076796 | 9/29/2021 | WO |
