In order that the invention may be better understood, preferred embodiments thereof will be now described, by way of example only, with reference to the accompanying drawings, in which:
A dispenser 10 consists of a hollow housing 8 connected to a hanger 11. The hanger is shaped in the form of a coil to be removably hung from the rim of a toilet, so that the housing 8 hangs downwards as shown in
A pair of small apertures 51 are provided adjacent the hinge 32 at the base of the housing, for allowing water to drain slowly from the housing once flushing is complete. Such water will contain a dissolved portion of the treatment composition which is held in a solid block 28 within the housing. In this example, the small apertures 51 are formed by unshaped notches 51a and 51c in the edge of the rear portion of the clam shell moulding, which cooperate with corresponding notches 51b and 51d in the other clam shell half, as shown in
The interior of the lower wall 26 of the housing is formed with a series of four parallel plinth projections 27, shown in
As shown most clearly in
In this example, the housing is about 60 mm high by 60 mm wide by 40 mm deep and the hanger length is adjustable between about 50 mm and 80 mm.
A typical gel impregnated with fragrance, forming the fragrance block 24, will shrink, as the fragrance evaporates during use, by about 1 mm around its perimeter, in the radial direction. For this reason, the shoulder 23 has to be sufficiently wide to accommodate such shrinkage in use, whilst still retaining the gel block 24 and plugging the aperture. By way of comparison, the shrinkage from front to back of the gel block 24 may typically be less than 0.5 mm each side for a block which is 6 to 8 mm. thick. The degree of shrinkage will depend on the polymer matrix forming the gel, and the volume percentage of perfume in the gel.
The apertures in the housing are separate, transversely, from the vertical major surface or the fragrance block 24, but water will still cascade over the front face of the housing and the block 24 in turbulent flow toilet systems. The block may be in contact briefly with water trapped in the housing, which will contain dissolved constituents of block 28, but with appropriate choice of materials, such as a hydrophobic gel and fragrance for block 24, this exposure is insufficient to cause significant washing of fragrance composition into the water.
The composition of the treatment block may be one of those well known in the art and for example as described in WO 03/042462. Such compositions may include one or more of a colourant, a surfactant, a bleach or other disinfectant, and a limescale inhibitor or remover. A composition comprising a surfactant and/or a colourant is particularly preferred.
Preferred block formulations are, in % by weight:
To maximise the active ingredients in the block the amount of hydrophobe is reduced, and the quantity of water entering the housing is limited by the size of the apertures in the housing wall to reduce the rate of solubilisation of the block.
When using a bleach containing block 28, the amount of bleach which needs to be contained in the block, and hence dissolved, can be minimised by restricting the outflow of water from the housing so that the majority of the water in the housing will flow into the bowl after the bowl contents have been replenished by the flush water.
Suitable fragrance containing gel formulations are as described in WO 02/066084, particularly at examples 1 to 7.
Preferred formulations have a range of 30% to 70% by weight fragrance in a polymer gellant such as ETPA (ester terminated polyamide) as in WO 98/17243 or ATPA. About 50% by weight ETPA or ATPA polymer gellant and 50% by weight fragrance oil with a colourant is particularly preferred.
The required rigidity of the gel will depend in part on the size of the aperture in the housing wall. Thus a sinuous outline to the aperture is preferred to provide a large area but maintain a smaller span in at least one direction across the aperture. The aperture may be spanned by supporting ribs which may be encased within the gel body or be exposed to provide a part of the decorative effect. A honeycomb or grid type structure may also be provided for gels which are less self supporting.
As shown in
For more rigid gels, the gel may be formed with apertures in the gel, thus increasing the exposed surface area of the gel for more enhanced fragrance release.
The dispenser may be packaged in a blister pack of the type known for such toilet products. The dispenser is then clipped over the rim of the toilet, so that it hangs vertically, with the housing in line with the flow of water during flushing. The front face 21 faces inwards in the toilet. Whenever the toilet is then flushed, water passes into the housing and then drains slowly from the housing, the period of dwell of that water being sufficient to allow some of the treatment composition in the treatment block to be dissolved into the water. Due to the relatively short period, typically about 10 seconds after the initiation of the flushing, during which the treatment block is exposed to the water, only a limited, reasonably controlled amount is dissolved. Further, due to this relatively short period, the effect of any water contacting the inner surface of the fragrance block is minimal.
The inner surface of the fragrance block 24 is continuously exposed to the air in the housing, which allows fragrance vapour to emerge through the apertures into the room surrounding the toilet. At the same time, there is a continuous spread of vapour from the external surface of the fragrance block 24 into the room. Thus the effective surface area of the fragrance block is a large part of its total surface area, excluding the edge which is in contact with the flange 22.
In this example, the dispenser is intended to be disposable at end of life. This may be indicated by the disappearance of the block, or more easily by using a treatment block containing a dye or surfactant, the absence of colour or foam in the toilet bowl indicating the end of life. When the fragrance is depleted, it is preferred that the matrix of the fragrance block remain, plugging the aperture in the housing front wall.
The dispenser is manufactured as follows. The one-piece plastic moulding shown in
The puck may be embossed or otherwise formed to provide the required patterns in the surface of the gel block. A three dimensional surface to the gel will provide increased evaporation rate of the fragrance. Different nozzles may be provided for different colours of gel, to give a desired aesthetic effect by mixing colours. The puck may have upstands which extend through the thickness of the gel layer, to form through apertures in the moulded gel block.
Once the gel has set and the puck has separated from the clam shell, a treatment block is dropped into the rearward half shell 29, and the clam shell is closed by folding it about its hinge 32, until the inter-engaging formations 33 close it with a snap fit. The housing is then closed except for the apertures which admit water.
It will be appreciated that alternative materials may be used for the fragrance block, other than gels; the block however has to be sufficiently rigid to act as a plug for the aperture.
Further, the dispenser could adopt different shapes and configurations, and it need not have a carrier 11, for example if it could be wedged effectively under the toilet rim by other means.
For Japanese style toilets in which water flows from an open tap into the top of the toilet cistern, the housing may be supported on top of the cistern, on legs for example. The treatment composition of block 28 thus being washed into the cistern. One such embodiment is shown in
Depending on the direction and flow of the flushing water, the arrangement of apertures shown is intended to be used with most commercially available toilets, but it will be appreciated that other arrangements will be possible, including those appropriate to particular types of toilet bowl.
Number | Date | Country | Kind |
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0406616.3 | Mar 2004 | GB | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/GB05/01194 | 3/24/2005 | WO | 00 | 11/20/2006 |