This invention relates to improved dispensing nozzles suitable for applying spray foams and devices comprising the same, and relates particularly to satisfactorily applying spray foams in an environmentally-friendly manner. The dispensing nozzles are especially suitable for applying spray foams using carbon dioxide blowing agents, and can be used with two component spray foams.
Many existing blowing agents used in the dispensing and frothing of one and two component spray foams, particularly two component low pressure (TCLP) spray foams, are undesirable due to their high global warming potential (GWP) properties. Such undesirable blowing agents are primarily hydrofluorocarbon (HFC) based. Low GWP hydrofluoro-olefins (HFO) alternatives have been considered as potential replacements for HFC blowing agents. However, it has been found that HFO alternatives can react with catalysts used in some spray foams, degrading the foam performance and possibly even posing industrial hygiene concerns.
A more desirable blowing agent is carbon dioxide (CO2); however, CO2 has its own challenges when used to dispense foams. Carbon dioxide is less soluble than either HFCs or HFOs in foam-making chemicals. This means a lower amount of the blowing agent (CO2) is present in the foam-making chemicals, which results in less frothing of the dispensed foam. Therefore, the use of CO2 as a blowing agent results in a foam mixture that sprays with larger droplets and has more liquid than foam mixtures sprayed with HFC or HFO alternatives. Thus, the dispensed foam mixture tends to spray in a concentrated stream with splattering rather than a well distributed misty spray pattern.
What is needed is a nozzle, suitable for dispensing liquid foamable products, having features that improve the spray pattern of the foam mixture when applied to a surface. Such nozzles are especially desirable when environmentally-friendly but perhaps less than ideal blowing agents such as CO2 are used, and especially useful for the application of two component spray foams.
This invention relates to a nozzle suitable for dispensing liquid foamable products, the nozzle comprising a tubular exit zone having an inlet and an outlet; the tubular exit zone having an inner wall surface defining a passageway for dispensing, the passageway having a centerline axis; the tubular exit zone further having a plurality of vanes attached to the inner wall surface parallel to the centerline axis with the vanes extending radially into the passageway for dispensing; the vanes having a length having a length dimension, a thickness having a thickness dimension, and a width having a width dimension, the thickness dimension being smaller than the width dimension, and the width dimension being smaller than the length dimension; the length dimension being a distance the vane contacts the inner wall surface parallel to the centerline axis, and the thickness dimension being an effective thickness of the vane at the inner wall surface perpendicular to the centerline axis; and the width dimension being a distance from the inner wall surface that the vane extends into the passageway for dispensing; and wherein the vanes do not connect or touch at the centerline of the passageway for dispensing.
This invention also relates to a process for dispensing liquid foamable products with a nozzle comprising a tubular exit zone having an inlet and an outlet, comprising the steps of:
a) supplying a liquid foamable product comprising at least one blowing agent to the inlet of the tubular exit zone, the tubular exit zone having an inner wall surface defining a passageway for dispensing, the passageway having a centerline axis; the tubular exit zone further having a plurality of vanes attached to the inner wall surface parallel to the centerline axis with the vanes extending radially into the passageway for dispensing; the vanes having a length having a length dimension, a thickness having a thickness dimension, and a width having a width dimension, the thickness dimension being smaller than the width dimension, and the width dimension being smaller than the length dimension;
the length dimension being a distance the vane contacts the inner wall surface parallel to the centerline axis, and the thickness dimension being an effective thickness of the vane at the inner wall surface perpendicular to the centerline axis; and the width dimension being a distance from the inner wall surface that the vane extends into the passageway for dispensing; and wherein the vanes do not connect or touch at the centerline of the passageway for dispensing; and
b) dispensing the liquid foamable product from the outlet of the tubular exit zone.
As shown in
It has been found that when dispensing nozzles such as those depicted in
Further, it was unexpectantly found that modifying the outlet of the tubular exit zone of the dispensing nozzle to simultaneously increase the shear on the foamable mixture while dividing the foamable mixture into separate streams reduced the droplet size, increased the frothing of the foam mixture, and improved the distribution of the sprayed droplets in the intended spray pattern.
Therefore, this invention relates to a nozzle suitable for dispensing liquid foamable products, the nozzle comprising a tubular exit zone having an inlet and an outlet; the tubular exit zone having an inner wall surface defining a passageway for dispensing, the passageway having a centerline axis; the tubular exit zone further having a plurality of vanes attached to the inner wall surface parallel to the centerline axis with the vanes extending radially into the passageway for dispensing; the vanes having a length having a length dimension, a thickness having a thickness dimension, and a width having a width dimension, the thickness dimension being smaller than the width dimension, and the width dimension being smaller than the length dimension; the length dimension being a distance the vane contacts the inner wall surface parallel to the centerline axis, and the thickness dimension being an effective thickness of the vane at the inner wall surface perpendicular to the centerline axis; and the width dimension being a distance from the inner wall surface that the vane extends into the passageway for dispensing; and wherein the vanes do not connect or touch at the centerline of the passageway for dispensing.
The words “nozzle” and “dispensing nozzle” are used interchangeably herein. Further, it is not intended that the nozzles described herein to be limited to the “mixing and dispensing nozzle” or an “anti-crossover or crossover-resistant nozzle” that is used with a spray gun, however, this is a preferred embodiment. It is contemplated that the principles described herein relating to a tubular exit zone having a plurality of vanes could be used at the exit of essentially any device used to spray foam; therefore, the words “nozzle” or “dispensing nozzle” are intended to include essentially any device suitable for spraying any foam composition that further has an exit passageway including a tubular exit zone having a plurality of vanes as disclosed or arranged herein.
One version of a tubular exit zone that simultaneously increases the shear on the foamable mixture while dividing the foamable mixture into separate streams is shown in
Each vane 7 has a length, a thickness, and a width. Additionally, the thickness dimension is smaller than the width dimension, and the width dimension is smaller than the length dimension.
As shown in
The vane thickness is characterized by a thickness dimension; the thickness dimension being defined herein as the effective thickness of the vane at the inner wall surface perpendicular to the centerline axis. If the thickness of the vane varies along the length of the vane at the inner wall surface, the effective thickness of the vane is therefore considered to be the maximum thickness dimension of the vane at the inner wall surface along the length of the vane. As shown in
In some embodiments, the thickness dimension of each vane increases along the length of the vane from a minimum value at the outlet for the tubular exit zone. One such illustration of this embodiment is shown in
The vane width is characterized by a width dimension; the width dimension being defined herein as the maximum distance 22 from the inner wall surface that the vane extends into the passageway for dispensing. Preferably each vane is triangular shaped along its length, with the width varying linearly from a maximum at the tubular exit zone outlet (or the exit face 25) to a minimum at the opposing end of the vane (point 9 in the tubular passageway). The vanes further do not connect or touch at the centerline of the passageway for dispensing. Preferably, the vanes do not extend radially into the passageway as far as the centerline axis.
Preferably, all the vanes have a similar shape and dimensions, that is, all the vanes have the same combination of width, thickness, and length dimensions.
The nozzle suitable for dispensing liquid foamable products comprises a tubular exit zone having a plurality of vanes attached to the inner wall surface parallel to the centerline axis with the vanes extending radially into the passageway for dispensing. By “plurality” it is meant 2 or more vanes. In some embodiments, the nozzle comprises a tubular exit zone having 3 or more vanes. In some other embodiments, the nozzle comprises a tubular exit zone having 5 to 8 vanes; in some other embodiments, the nozzle comprises a tubular exit zone having 5 to 10 vanes. It is believed that 10 is a practical maximum for most foamable compositions.
The nozzle suitable for dispensing liquid foamable products comprises a tubular exit zone having an inlet and an outlet, and in some embodiments the outlet for the tubular exit zone is an exit face of the dispensing nozzle. The vanes are preferably present in the tubular exit zone extending from the outlet end of the tubular exit zone into the tubular exit zone, the vanes ending some distance (parallel to the centerline) between the tubular exit zone inlet and outlet. Generally the vanes will extend in from outlet (or the exit face 25) into the tubular exit zone a distance parallel to the centerline that is no more than about one third the total length of the tubular exit zone, and preferably the vanes will extend no more than about one fourth the total length of the tubular exit zone. In a preferred embodiment illustrated in
In some embodiments, such as shown in
In some embodiments, the thickness dimension of each vane has a maximum value at the inner wall surface and decreases radially into the passageway for dispensing as shown in
In some preferred embodiments, the vanes are symmetrically distributed radially about the centerline of the passageway for dispensing. However, in some embodiments the vanes are unsymmetrically distributed radially about centerline of the passageway for dispensing.
While the figures depict the vanes being located in the tubular exit zone with the vane length-wise being strictly parallel to the centerline axis and the vane width-wise being strictly radial in relation to the centerline axis of the tubular exit zone, if desirable, the vanes could be positioned offset from a truly parallel or radial position in relation to the centerline axis of the tubular exit zone if desired, as long as spray performance was not affected.
The devices suitable for dispensing liquid foamable products that could comprise nozzles having the tubular exit zone with vanes described herein include spray parts known as “mixing and dispensing nozzles” or an “anti-crossover or crossover-resistant nozzles”, or even “mixing devices”. For example, the tubular exit zone could be attached to the exit of a mixing device or other nozzles could be modified to include the tubular exit zone described herein.
One suitable dispensing nozzle is one that combines, mixes, and then dispenses a foamable mixture of at least two components in what is known as two-component spray foams. Accordingly, in one embodiment a mixing chamber is attached to the inlet of the tubular exit zone, as shown in dispensing nozzle 50 for two-component spray foams in
Useful dispensing nozzles including the tubular exit zone with vanes include any number of “spray gun nozzles” that could comprise a tubular exit zone with vanes described herein. One such dispensing device in the form of a spray gun 80 is shown in
This invention also relates to a process for dispensing liquid foamable products with a nozzle comprising a tubular exit zone having an inlet and an outlet, comprising the steps of:
a) supplying a liquid foamable product comprising at least one blowing agent to the inlet of the tubular exit zone, the tubular exit zone having an inner wall surface defining a passageway for dispensing, the passageway having a centerline axis; the tubular exit zone further having a plurality of vanes attached to the inner wall surface parallel to the centerline axis with the vanes extending radially into the passageway for dispensing; the vanes having a length having a length dimension, a thickness having a thickness dimension, and a width having a width dimension, the thickness dimension being smaller than the width dimension, and the width dimension being smaller than the length dimension;
the length dimension being a distance the vane contacts the inner wall surface parallel to the centerline axis, and the thickness dimension being an effective thickness of the vane at the inner wall surface perpendicular to the centerline axis; and the width dimension being a distance from the inner wall surface that the vane extends into the passageway for dispensing; and wherein the vanes do not connect or touch at the centerline of the passageway for dispensing; and
b) dispensing the liquid foamable product from the outlet of the tubular exit zone.
In a preferred embodiment, the process uses an environmentally-friendly blowing agent such as carbon dioxide. In some embodiments, the process further includes a step, prior to step a), of mixing more than one component to make a liquid foamable product, preferably mixing a two component foamable product and a blowing agent. Preferably the mixing is accomplished in the nozzle prior to the inlet of the tubular exit zone.
All of the features and elements of the tubular exit zone described herein can be used in the process for dispensing liquid foamable products using a nozzle comprising the said tubular exit zone. Namely, the tubular exit zone has 2 or more vanes attached to the inner wall surface parallel to the centerline axis with the vanes extending radially into the passageway for dispensing. In some embodiments, the nozzle comprises a tubular exit zone having 3 or more vanes. In some other embodiments, the nozzle comprises a tubular exit zone having 5 to 8 vanes; in other embodiments, the nozzle comprises a tubular exit zone having 5 to 10 vanes. The process can use a dispensing nozzle comprising a tubular exit zone wherein the vanes are symmetrically distributed radially about the centerline of the passageway for dispensing. Alternatively, the process can use a dispensing nozzle comprising a tubular exit zone wherein the vanes are unsymmetrically distributed radially about the centerline of the passageway for dispensing. Further, while the figures depict the vanes being located in the tubular exit zone with the vane length-wise being strictly parallel to the centerline axis and the vane width-wise being strictly radial in relation to the centerline axis of the tubular exit zone, if desirable, the vanes could be positioned offset from a truly parallel or radial position in relation to the centerline axis of the tubular exit zone if desired, as long as spray performance was not affected.
As previously discussed herein, in one embodiment of the process using a dispensing nozzle comprising a tubular exit zone, each vane is triangular shaped with the width dimension of each vane having a maximum value at the outlet for the tubular exit zone and decreasing linearly along the length of the vane to a minimum at the opposing end of the vane. Likewise, in another embodiment of the process using a dispensing nozzle comprising a tubular exit zone, the thickness dimension of each vane in the nozzle has a maximum value at the inner wall surface and decreases radially into the passageway for dispensing.
In one preferred embodiment of the process using a dispensing nozzle comprising a tubular exit zone, each of the vanes have, as shown in
In a further version of this preferred embodiment, while the thickness dimension varies along the length of the vane, the vane has the same thickness dimension at the inner wall surface as radially into the passageway; that is, the vane has a combination of the features of 23a combined with the features of 21a as shown in
In another version of this embodiment, while the thickness dimension varies along the length of the vane, the vane thickness dimension also decreases from the inner wall surface radially into the passageway; that is, the vane has a trapezoidal shape when viewed end-on as in
Further, it is generally preferred that all the vanes have the same dimensions and shape.
As previously discussed herein, in one embodiment of the process using a dispensing nozzle comprising a tubular exit zone, the dispensing nozzle further comprises a mixing chamber attached to the inlet of the tubular exit zone. Also, in still another embodiment of the process using a dispensing nozzle comprising a tubular exit zone the outlet for the tubular exit zone of the nozzle is an exit face of the nozzle.
A two-component foam was sprayed onto a flat horizontal substrate using a CO2 blowing agent using as a control a spray gun having a dispensing nozzle that had a hollow tubular exit zone without vanes, and then again with a spray gun having a dispensing nozzle as illustrated in
Number | Date | Country | |
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63120521 | Dec 2020 | US |