Patent Application
20110230353
The present invention relates to water-dispersible struvite and dehydrates thereof; and more particularly, to a binder holding water-dispersible struvite particulate in a pelletized form that rapidly works into a soil substrate.
A continuing problem in care of large areas of cultivated vegetation is the difficulty of delivery of fertilizer to the target in an efficient manner. A practical and labor-saving approach to agent delivery in areas such as golf courses, parks, lawns, gardens and woodlands has been broadcast application of granular products containing an agent, for example via rotary spreader. Using granular products having particle sizes in the range of about 1 millimeter to about 10 millimeters, an operator can cover a large area with minimal distance traversed by the spreader itself, while applying the granular products relatively uniformly to the desired area. Unfortunately, such granular products often remain in solid or semisolid form several days following their application yielding a high concentration dispersion zone immediately beneath a particle with much lower concentrations in proximity. With potash delivery this can lead to chemical burning proximal to a pellet.
A further consequence of the fact that granular products often remain in solid or semisolid form for long periods following application is that the granules are subject to removal by cultural practices such as mowing with clipping removal, leaf and or yard waste vacuuming; or runoff from weather events, especially on sloping ground where the underlying soils have low percolation rates; where the ground cover is closely mown or relatively thin and sparse; and where the equipment or pedestrian traffic is high. This causes a loss of the uniformity of the biological response sought by the use of the product. In addition, product efficacy may be altered due to excessive concentration of the product within the areas treated.
The long persistence of the granular products also results in a greater likelihood that people and or animals may come into physical contact with the granules, which may result in skin irritation, sensitization, dermal absorption and toxicity. Additionally, when clothing, footwear and equipment come into physical contact with the granules, they can cause damage, corrosion or staining.
Struvite poses a serious problem in sewage and waste water treatment facilities where it tends to form occluding scales on pipes and other equipment. While struvite represents a source of fertilizer phosphorus, struvite has met with limited acceptance owing to the kinetically slow dispersion of struvite into soil. The solid or semisolid crystalline granules are susceptible to secondary pick up and environmental migration.
The present invention solves the problems associated with persistence of granular products by providing compositions and methods for making controlled release nitrogen pellets that are water dispersible. The inventive pellets, when handled without coming into contact with water, have physical characteristics similar to existing controlled release granules such as those detailed in U.S. Pat. No. 6,884,756. Following application, the inventive pellets disperse on contact with moisture from the treated area itself, from irrigation or from natural precipitation. The dispersion of the pellets allows the controlled release nitrogen and other active ingredients to be deposited downwards and laterally from the original position of the pellet, so that the controlled release nitrogen and other active ingredients are less likely to be removed from the treated area, ingested by small children or animals, or otherwise contacted by people, animals, clothing, footwear or equipment. Water dispersibility also prevents wastage of any relatively expensive components of the inventive pellets since more of the ingredients reach their respective targets.
While mineral mined sources of potassium have predominantly supplied agricultural and horticultural needs for fertilizer, such as Floridian Phosphate rock, such sources are rapidly depleting. There is a growing recognition that traditional biological sources of phosphate may reduce the ecological footprint of potassium fertilizer material production. Additionally, biological sources of potassium often lend themselves to pelletizing.
Thus, there is a continuing need for a uniformly sized, durable product in particle form which can deliver phosphate in a controlled release manner and whose components are quickly dispersible in order to provide even delivery of active agents to target plants and organisms over a large area.
A water-dispersible particle is proving that includes struvite of a dehydrate thereof present in an amount ranging from 5% to 99.9% by weight of the total dry weight of the particle. A binder component is present in an amount ranging from 1% to 95% by weight of the total dry weight of the particle. The struvite and the binder component are present in a form such that contact with water causes particle dispersion into more than 100 pieces.
A process for making a water-dispersible particle includes mechanical aggregation of struvite. A binder component, is present in the particle in an amount ranging from 1% to 95% by weight of the total dry weight of the particle. The struvite, or a dehydrate thereof and the binder component are present in a form such that contact with water causes particle dispersion into more than 100 pieces. The pellet is then dried and ready to be applied.
The present invention relates to a water-dispersible struvite particle for delivery of fertilizer to a plant. The invention further relates to a method for making and using the water-dispersible particle. The inventive particle retains its size and shape during handling and application to a desired area and dissolves or crumbles into small particles upon contact with a water overspray within twelve hours. Thus the durability of the particle allows delivery of the particle to the vicinity of the desired site of action whereupon contact with water sufficient to wet the particle surface causes dispersion of particle components, facilitating distribution of the active agents to the target. The term dispersion in the context of the present invention is intended to mean that an inventive particle disperses by breaking into numerous smaller pieces upon contact with water. In a preferred embodiment, an inventive particle disperses by breaking up into greater than 100 smaller pieces upon contact with water over a period of time ranging from 1 second to 24 hours. Preferably, an inventive particle disperses into 1,000 to 10,000 smaller pieces over a period of time ranging from 1 second to 12 hours. Even more preferably, a particle disperses into 100 to 10,000 smaller pieces over a period of 30 seconds to 6 hours. Most preferably, a particle disperses as described over a period of 1 minute to 1 hour. The ability of the inventive material to degrade with water is generally measured in a water dispersibility test. The test involves placing about 10 grams of the inventive material into 100 ml of water at room temperature in a closed glass container. The container is then inverted and the time is observed until the material disperses. After every minute, the container is inverted. The inventive material of the present invention has a dispersibility time of generally less than 15 minutes with a period of less than 5 minutes being preferred and a period of less than 2 minutes being most preferred. The inventive particle provides a delivery system for struvite, and optional additional agents such as nitrogen sources, plant nutrients, pesticides, hormones, herbicides, micronutrients and other active ingredients. A typical particle size is between 20 and 1,200 microns.
A particle of the present invention includes struvite and a binder component. The struvite is readily obtained from sewage of waste water treatment and ground to size of less than −15 mesh. It is appreciated that the particle optionally contains an active ingredient. In a preferred embodiment the water-dispersible struvite is targeted to cultivated plants such as lawn grass, crops, flowers, shrubs, trees and bushes. The water-dispersible struvite is present in amounts ranging from 5% to 99.9% by weight of the total dry weight of the particle. More preferably, the water-dispersible struvite is present in amounts ranging from 30% to 99.5% by weight of the total dry weight of the particle. Still more preferably, the water-dispersible struvite is present in amounts ranging from 50% to 99% by weight of the total dry weight of the particle.
An optional nitrogen-containing ingredient added to the water-dispersible struvite includes methylene urea oligomers, oxamide, urea formaldehyde-based compounds, dicyandiamide, crotilidiene diurea, nitrocellulose, metal ammonium phosphates, ammonium nitrate, ammonium sulfate, urea, coated urea, monoammonium phosphate, diammonium phosphate, calcium nitrate, isobutylidene diurea and other fertilizers as detailed herein.
In a preferred embodiment the particle contains a binder that produces or promotes cohesion of the struvite water-dispersible fines. The binder component is present in amounts ranging from 1% to 95% by weight of the total dry weight of the particle. More preferably, the binder component is present in amounts ranging from 1% to 75% by weight of the total dry weight of the particle. Still more preferably, the binder component is present in amounts ranging from 1% to 50% by weight of the total dry weight of the particle. Most preferably, the binder is present in amounts ranging from 1% to 25% by weight of the total dry weight of the particle. Illustrative examples of binders operative herein are carbohydrates such as monosaccharides, disaccharides, oligosaccharides and polysaccharides; proteins; lipids; glycolipid; glycoprotein; lipoprotein; clays; and combinations and derivatives of these. Specific carbohydrate binders illustratively include glucose, mannose, fructose, galactose, sucrose, lactose, maltose, xylose, arabinose, trehalose and mixtures thereof such as corn syrup; celluloses such as carboxymethylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxymethylethylcellulose, hydroxyethylpropylcellulose, methylhydroxyethyl-cellulose, methylcellulose; starches such as anylose, seagel, starch acetates, starch hydroxyethyl ethers, ionic starches, long-chain alkyl starches, dextrins, amine starches, phosphates starches, and dialdehyde starches; plant starches such as corn starch and potato starch; other carbohydrates such as pectin, amylopectin, xylan, glycogen, agar, alginic acid, phycocolloids, chitin, gum arabic, guar gum, gum karaya, gum tragacanth and locust bean gum; complex organic substances such as lignin and nitrolignin; derivatives of lignin such as lignosulfonate salts illustratively including calcium lignosulfonate and sodium lignosulfonate and complex carbohydrate-based compositions containing organic and inorganic ingredients such as molasses. Suitable protein binders illustratively include soy extract, zein, protamine, collagen, and casein. Binders operative herein also include synthetic organic polymers capable of promoting or producing cohesion of methylene urea oligomer fines and these illustratively include ethylene oxide polymers, polyacrylamides, polyacrylates, polyvinyl pyrrolidone, polyethylene glycol, polyvinyl alcohol, polyvinylmethyl ether, polyvinyl acrylates, polylactic acid, and latex. Clay binders illustratively include montmorillonite, and bentonite.
The particles of the present invention are optionally associated with an active ingredient. Illustrative examples of active ingredients include fertilizers, soil nutrients, amendment materials, biological factors and biostimulants. A solid, liquid or powder active ingredient is recognized to be operative herein. It will be recognized by those skilled in the art that more than one active ingredient may be incorporated into the particle and that the choice of active ingredient or combination of active ingredients will depend on the intended purpose of the particle and the chemical compatibility of the ingredients and other particle components.
In a preferred embodiment, where the active ingredient is a fertilizer, soil nutrient or amendment material, the fertilizer, soil nutrient or amendment material active ingredient is present in an amount ranging from 0.05% to 50% by weight of the total dry weight of the particle. In a more preferred embodiment, the fertilizer, soil nutrient or amendment material active ingredient is present in an amount ranging from 0.1% to 30% by weight of the total dry weight of the particle. In a still more preferred embodiment, the fertilizer, soil nutrient or amendment material active ingredient is present in an amount ranging from 0.5% to 10% by weight of the total dry weight of the particle.
Where the active ingredient is a biological factor or biostimulant, the active ingredient is present in an amount ranging from 0.05% to 10% by weight of the total dry weight of the particle. In a more preferred embodiment, the biological factor or biostimulant active ingredient is present in an amount ranging from 0.1% to 5% by weight of the total dry weight of the particle. In a still more preferred embodiment, the biological factor or biostimulant active ingredient is present in an amount ranging from 0.25% to 1% by weight of the total dry weight of the particle.
Fertilizers are substances containing one of the plant nutrients nitrogen, phosphate or potassium and illustratively include urea, sulfur-coated urea, isobutylidene diurea, ammonium nitrate, ammonium sulfate, ammonium phosphate, triple super phosphate, phosphoric acid, potassium sulphate, potassium nitrate, potassium metaphosphate, potassium chloride, dipotassium carbonate, potassium oxide and a combination of these. Soil nutrients illustratively include calcium, magnesium, sulfur, iron, manganese, copper, zinc; oxides thereof, salts thereof and combinations thereof. Amendment materials are natural organic products such as humic acid, blood meal, bone meal, seed meal, feather meal and soy meal; meat meal; animal waste from various animal sources; activated sludge, hydrolyzed animal hair; fish byproducts; chitin; composts; and a combination thereof. Biological factors are those factors that have a deleterious effect on a biological organism and illustratively include algicides, bacteriocides, defoliants, desiccants, fungicides, herbicides, insecticides, insect growth regulators, miticides, nematicides, ovicides, pesticides, pheromones, repellents, rodenticides and a combination thereof. Biostimulants are substances that promote plant survival and health and illustratively include plant growth hormones and plant growth regulators such as cytokinins, auxins, gibberellins, ethylene, absisic acid and a combination of these.
In a preferred embodiment, water-dispersible potash fines are mechanically aggregated into pellets in a pan-granulator in the presence of a binder. Water-dispersible potash fines are small methylene urea oligomer aggregates that have a mean aggregate domain size that is less than 500 micrometers. More preferably, the mean aggregate domain size of the fines is less than 250 micrometers. Still more preferably, the mean aggregate domain size of the fines is less than 180 micrometers.
The binder is sprayed into the pan granulator with the water-dispersible potash fines. The pellets are dried and the resulting particles are size-screened and particles of desired size are stored. Optionally, the particles are transferred to a coating drum for addition of an active ingredient or a conditioner material.
In another embodiment, struvite alone or with other aforementioned optional fines are mechanically aggregated into pellets in a drum-granulator in the presence of a binder. Water-dispersible struvite, alone or with other optional fines are small methylene urea oligomer aggregates that have a mean aggregate domain size that is less than 500 micrometers. More preferably, the mean aggregate domain size of the fines is less than 250 micrometers. Still more preferably, the mean aggregate domain size of the fines is less than 180 micrometers.
The binder is sprayed into the drum granulator with the water-dispersible struvite fines. The pellets are dried and the resulting particles are size-screened and particles of desired size are stored. Optionally, the particles are transferred to a coating drum for addition of an active ingredient or a conditioner material.
In another embodiment, struvite alone or with other aforementioned optional fines are mechanically aggregated into pellets in an Eirich unit in the presence of a binder. Water-dispersible potash fines are small methylene urea oligomer aggregates that have a mean aggregate domain size that is less than 500 micrometers. More preferably, the mean aggregate domain size of the fines is less than 250 micrometers. Still more preferably, the mean aggregate domain size of the fines is less than 180 micrometers.
The binder is sprayed into the Eirich unit granulator with the water-dispersible fines. The pellets are dried and the resulting particles are size-screened and particles of desired size are stored. Optionally, the particles are transferred to a coating drum for addition of an active ingredient or a conditioner material.
Various means of drying the material are available. A preferred method is fluid bed drying. The material is placed in a fluid bed drier and the drier inlet air temperature ranges from about 120° F. to about 220° F. More preferably, the temperature ranges from 140° F. to 190° F. Further methods of drying particles will be apparent to one of skill in the art and illustratively include use of a rotary drum drier and drying under vacuum conditions.
An active ingredient is associated with a particle during the process of particle formation or after particles are formed. For example, an active ingredient is mixed with the binder. The binder/active ingredient mixture is added to water-dispersible struvite, alone or with other optional fines, and mechanically aggregated in a pan granulator resulting in particles wherein the active ingredient and water-dispersible fines are in suspension in the binder.
Where it is desirable to add the active ingredient after particle formation, for example where the active ingredient is incompatible with suspension in the binder, the active ingredient is added to the particle following particle formation in the presence or absence of an adhesive. Methods of active ingredient addition illustratively include spraying onto the particle or adsorption of the active ingredient by coating the particle in a non-aqueous solution of the active ingredient.
In another embodiment, the active ingredient is mixed with an adhesive before application to a particle. An adhesive is a substance that binds to a particle, such that the active ingredient adheres to the particle in suspension in the adhesive. The adhesive may be the same as the binder or different. The choice of adhesive depends on the particle components and will be evident to one skilled in the art. Examples of adhesives include, but are not limited to, substances listed herein as binder components. Preferably, the adhesive is calcium lignosulfonate, molasses, a liquid corn starch, a liquid corn syrup, bentonite clay or a combination of these.
For example, the active ingredient in powdered form is adhered to the outside surface of the particle with the use of an adhesive. An adhesive liquid may be used and is applied before or after the addition of the powdered active ingredient or it may be applied at the same time as the active ingredient. The choice of adhesive depends on the particle components and will be evident to one skilled in the art. Examples of a liquid adhesive include but are not limited to binders listed herein, including mineral oils or polymer liquids such as polybutene.
The particles of the present invention have a minimum Resistance To Attrition (RTA) rating ranging from 60% to 100% as determined by the method detailed in Example R or an art-recognized equivalent procedure.
The particles of the present invention have a mean particle domain size that ranges from 0.1 millimeter to 30 millimeters. More preferably, the mean particle domain size ranges from 0.25 millimeter to 20 millimeters. Still more preferably, the mean particle domain size ranges from 0.50 millimeter to 15 millimeters. The particles formed by the process of the present invention have a Uniformity Index rating in the range of 30 to 60 where the Uniformity Index rating is calculated as the 10.sup.th percentile particle size expressed as a percentage of the 95.sup.th percentile particle size.
Particles of the present invention take any shape illustratively including spheres, cylinders, ellipses, rods, cones, discs, needles and irregular. In a preferred embodiment the particles are approximately spherical.
The particles of the present invention are administered to a target to produce a desired effect on a desirable or an undesirable organism. Particles are administered by a method that delivers the nitrogen-containing ingredient to the vicinity of a desirable organism whose health is to be encouraged. Further, the particles are administered by a method that delivers the active ingredient to an area where it will be available to a targeted desirable or undesirable organism. For example, where an inventive struvite particle contains an optional controlled release fertilizer source such as methylene urea oligomers and an active ingredient such as a plant hormone, the particles are delivered to a desirable plant target, such as a golf course lawn, by broadcast scattering via rotary spreader. The particles are then dispersed by water that is user applied or natural such as rain, dew or atmospheric humidity.
Alternatively, the particles are placed in a limited target area such as near a particular desired plant in a garden or in a crop row. In another embodiment, the particles are placed under the soil surface.
A target desirable organism illustratively includes cultivated plants such as lawn grass, crops, flowers, shrubs, trees and bushes. Target undesirable organisms illustratively include pest insects at any stage of development, bacteria, molds, algaes, weeds, worms and rodents.
Dispersible Struvite: Using a pan agglomeration disk, a binder such as calcium lignosulfanate, corn starch, and corn syrup is applied to a mixture of water-dispersible fines (material less than 250 microns) struvite obtained from a sewage treatment plant, dried and ground. The agglomeration disk is operated and adjusted to generate the desired size distribution of particles before the particles are conveyed to a fluid bed drier where the material is dried at a temperature of 140° F. to a moisture content of less than 0.5% with 95 total weight percent of the dried particles being struvite. The material is then separated into various size categories using conventional gyroscopic screeners. General size of these product streams are as follows: 3,360 microns and larger, from 3,360 microns to 1,191 microns, from 1,191 microns to 594 microns, and material smaller than 594 microns. The range of sizing for each product stream can be varied to separate the desired material from the mixture of sizing.
Dispersible Struvite Containing Pesticides (Powdered Pesticides): A mixture of water-dispersible struvite fines and a powdered pesticide (such as PCNB, Prodiamine, or Thiphanate-Methyl) is added to a pan agglomeration disk. A binder such as calcium lignosulfonate, corn starch, bentonite clay, or corn syrup is sprayed onto the mixture. The pan agglomeration disk is operated and adjusted to provide the desired size distribution of particles. The material is then conveyed to a fluid bed drier where the material is dried at a temperature of 140 F. to a moisture content of less than 0.5%, The material is then separated into various size categories using conventional gyroscopic screeners. General size of these product streams are as follows: 3,360 microns and larger, from 3,360 microns to 1,191 microns, from 1,191 microns to 594 microns, and material smaller than 594 microns. The range of sizing for each product stream can be varied to separate the desired material from the mixture of sizing.
Dispersible Struvite Containing Pesticides such as liquid pesticides: Using a pan agglomeration disk, a liquid pesticide and a binder such as calcium lignosulfonate, corn starch, and corn syrup was applied to a mixture of water-dispersible struvite fines (material less than 250 microns). The agglomeration disk is operated and adjusted to generate the desired size distribution of particles before the particles are conveyed to a fluid bed drier where the material was dried at a temperature of 140° F. to a moisture content of less that 0.5%. The material is then separated into various size categories using conventional gyroscopic screeners. General size of these product streams are as follows: 3,360 microns and larger, from 3,360 microns to 1,191 microns, from 1,191 microns to 594 microns, and material smaller than 594 microns. The range of sizing for each product stream can be varied to separate the desired material from the mixture of sizing.
Dispersible Struvite with Other Nutrient Sources, Micronutrients, Soil Amendments, or Biostimulants: Using a pan agglomeration disk, a binder such as calcium lignosulfonate, corn starch, bentonite clay and corn syrup is applied to a mixture of water-dispersible struvite fines, other nutrient sources (potash diammonium phosphate or sulfate of potash for example), micronutrients (such as iron sulfate or manganese oxide), soil amendments (such as humic acid materials), or biostimulants with all materials less than 250 microns in size. The agglomeration disk is operated and adjusted to generate the desired size distribution of particles before the larger particles were conveyed to a fluid bed drier where the material was dried at a temperature of 140° F. to a moisture content of less that 0.5%. The material is then separated into various size categories using conventional gyroscopic screeners. General size of these product streams are as follows: 3,360 microns and larger, from 3,360 microns to 1,191 microns, from 1,191 microns to 594 microns, and material smaller than 594 microns. The range of sizing for each product stream can be varied to separate the desired material from the mixture of sizing.
Dispersible Struvite with Other Nutrient Sources, Micronutrients, Soil Amendments, or Biostimulants Containing Pesticides such as powdered pesticides: A mixture of struvite fines, other nutrient sources (potash methylene urea for example), micronutrients (such as iron sulfate or manganese oxide), soil amendments (such as humic acid materials), or biostimulants and a powdered pesticide (such as PCNB, Prodiamine, or Thiphanate-Methyl) is added to a pan agglomeration disk. A binder such as calcium lignosulfonate, corn starch, bentonite clay, or corn syrup is sprayed onto the mixture. The pan agglomeration disk is operated and adjusted to provide the desired size distribution of particles. The material is then conveyed to a fluid bed drier where the material is dried at a temperature of 140° F. to a moisture content of less than 0.5%. The material is then separated into various size categories using conventional gyroscopic screeners. General size of these product streams were as follows: 3,360 microns and larger, from 3,360 microns to 1,191 microns, from 1,191 microns to 594 microns, and material smaller than 594 microns. The range of sizing for each product stream can be varied to separate the desired material from the mixture of sizing.
Dispersible Struvite with Other Nutrient Sources, Micronutrients, Soil Amendments, or Biostimulants Containing Pesticides such as liquid pesticides: Using a pan agglomeration disk, a liquid pesticide and a binder such as calcium lignosulfonate, corn starch, bentonite clay, or corn syrup are applied to a mixture of water-dispersible struvite fines, other nutrient sources (isobutylidene diurea for example), micronutrients (such as iron sulfate or manganese oxide), soil amendments (such as humic acid materials), or biostimulants, with all material less than 250 microns in diameter. The agglomeration disk is operated and adjusted to generate the desired size distribution of particles before the particles are conveyed to a fluid bed drier where the material was dried at a temperature of 140° F. to a moisture content of less that 0.5%. The material is then separated into various size categories using conventional gyroscopic screeners. General size of these product streams were as follows: 3,360 microns and larger, from 3,360 microns to 1,191 microns, from 1,191 microns to 594 microns, and material smaller than 594 microns. The range of sizing for each product stream can be varied to separate the desired material from the mixture of sizing.
Post Production Surface Coating of Dispersible Struvite (Example A) or Dispersible Struvite Containing Other Nutrient Sources, Micronutrients, Soil Amendments, or Biostimulants (Example D) with a Powdered Pesticide. Materials generated by the methods described in Example A or Example D above, are fed to a blender (such as a Forberg fluidized zone blender) or other coating equipment (such as a coating drum). The material is sprayed with a liquid, such as a light weight mineral oil, to make the surface slightly tacky before adding a powdered pesticide (such as Prodiamine, Thiophanate-Methyl, or PCNB). A second spray of liquid may be necessary to adhere the powder to the surface of the material.
Post Production Surface Impregnation of Dispersible Struvite (Example A) or Dispersible Struvite Containing Other Nutrient Sources, Micronutrients, Soil Amendments, or Biostimulants (Example D) with a Liquid Pesticide. Materials generated by the methods described in Example A or Example D above, are fed to a blender (such as a Forberg fluidized zone blender) or other coating equipment (such as a coating drum). The material is then sprayed with a liquid pesticide that slightly penetrates the surface of the material. The material is mixed to assure even distribution of the pesticide to all particles.
Water-dispersible struvite particles are generated in an exemplary method, using an 18″ agglomeration pan and a fluid bed drier.
An illustrative procedure for producing a small batch of particles:
1. 500-1000 grams of struvite particles fines passing 50 mesh are weighed out.
2. The ratio of struvite fines to binder material depends on the binder and varies from about 19:1 to about 1:3. Preferably the ratio of struvite fines to binder is in the range from 10:1 to 1:1. More preferably, the ratio of struvite fines to binder is in the range from 7:1 to 2:1.
3. Approximately ⅔ of this material is placed into the 18″ agglomeration pan and the speed of rotation and the slope of incline of the pan are adjusted to ensure an acceptable falling curtain of material in the pan bed.
4. A binder is applied via a spray bottle, peristaltic pump with air atomizing nozzle, or sparge tube depending on the material used. Binder is added by the operator until particle growth begins to occur.
5. As necessary, the size of the particles is adjusted by the operator by crushing the material back down by hand as the material is rotating within the pan.
6. The additional ⅓ of the struvite fines is added in small amounts to the pan along with additional binder as needed.
7. After all of the struvite fines are added to the pan and any binder required to grow the particles is applied, the material is discharged into a collection container and transported to a fluid bed drier.
8. The material is placed in a fluid bed drier to drive off moisture added by the binder material. The temperature of the air entering the drier varies depending on the materials included in the particles. [0053]9. The material is dried until the temperature of the air exiting the drier stabilizes for a period of five minutes.
10. Once the material is taken from the drier, it is split into size fractions using round sieve screens by hand. For example, four fractions are used including: +6 mesh (overs), −6/+16 mesh (coarse), −16/+30 mesh (greens), and −30 mesh (fines).
11. The size fractions are placed into an oven and dried for additional period. For example, the particles are placed at a temperature ranging from 70° F. to 150° F. for 1 hour to 48 hours. More preferably the temperature ranges from 90° F. to 120° F. for 1 hour to 48 hours. In a specific example, the particles are dried at 110° F. for an additional 16+hours.
12. When pulled from the oven, the size fractions are checked for dispersibility and resistance to attrition.
An example procedure for making particles using Norlig A-Lignin as a binder is as follows:
500 g struvite fines, −50 mesh, are combined with 118.8 g of Norlig A/Water mixture (10:1) using a peristaltic pump/air atomizing nozzle. Drier inlet air is used at 190° F. Final drier exiting air has a temperature of 164° F.
Assay of dispersibility of particles is acceptable and Resistance to Attrition is 95.6%.
An example procedure for making particles using Cerestar Corn Starch as a binder is as follows: 500 g struvite fines, −50 mesh are combined with 158.3 g of Cerestar Corn Starch using a peristaltic pump/air atomizing nozzle. Drier inlet air is used at 140° F. Final drier exiting air has a temperature of 117° F.
Assay of dispersibility of particles is acceptable and Resistance to Attrition is 94.8%.
An example procedure for making particles using corn syrup as a binder is as follows: 500 g struvite fines, −50 mesh per Example I, are combined with 157.4 g of corn syrup/water (5:1) using a peristaltic pump/air atomizing nozzle. Drier inlet air is used at 140° F. Final drier exiting air has a temperature of 117° F.
Assay of dispersibility of particles is acceptable and Resistance to Attrition is 96.1%.
An example procedure for making particles using Norlig A-Lignin as a binder is as follows: 1000 g struvite fines, −50 mesh, are combined with 240 g of Norlig A/Water mixture (10:1) using a peristaltic pump/air atomizing nozzle. Drier inlet air is used at 190° F. Final drier exiting air has a temperature of 164° F.
Assay of dispersibility of particles is acceptable and Resistance to Attrition is 94.5%.
An example procedure for making particles coated with a powdered active ingredient is as follows: Particles are generated as outlined in Example I. When dry, 1000 grams of the selected size fraction of finished particles are placed in a blender. 40 grams of the powdered active ingredient is added to the blender, which is then turned on. After 30 seconds of blending, the adhesive liquid is added to the blender. A total of 20 grams of adhesive liquid is added over 1 minute, which is followed by an additional 1 minute of blending. The material is then discharged from the blender.
Apparatus: Ro-Tap sieve shaker with 8-inch sieves, balance with 0.1 g sensitivity, 10-min timer, and 10 steel balls with smooth surfaces and 16 mm (⅝ in.) in diameter.
1) Using information from the Screen Analysis, choose your limiting screen size. The following table indicates the limiting screen for several fertilizer blends.
2) Place about 75 g of a representative sample onto the limiting screen.
3) Reassemble the screen apparatus with the limiting screen just above the pan.
4) Place the screen apparatus onto the shaker and run it for 10 min (Use the hammer).
5) Empty the pan. Transfer 50.0 g of sample to the pan.
6) Put ten (10) 16-mm steel balls in the pan with the sample.
7) Reassemble the screen apparatus and place it onto the shaker and run it for 10 min (Do not use the hammer).
8) Remove the steel balls from the pan and transfer the sample back into the limiting screen.
9) Place the screen apparatus back onto the shaker and run it for 10 min (Use the hammer).
10) Weigh out the amount that remained on the limiting screen to the nearest 0.1 g and compare it to the original amount.
Percent resistance to attrition={(100·a)/b}, where a is the weight of the fraction that remained on the limiting screen in Step 10 and b is total weight of the sample in Step 5.
A set of like containers of grown nursery stock of spirea is divided into a randomized grid of 48 pots. Each pot was 3 gallon (3.8 l) trade size pots containing 85% pine bark, 10% comtil, and 5% pea gravel. To each pot is applied one of: (a) nothing as a negative control, (b) pure struvite crystallites sieved to between 1191 and 3360 microns applied to as part of 15-5-11 fertilizer, and (c) inventive dispersible struvite particles 95 total weight percent struvite applied as part of a 15-5-11 fertilizer. The amount of fertilizer added is equated on the % N and bulk density of each of the treatments; all treatments received the same amount of nitrogen. The application occurred in May and continued for five months. The pots are otherwise treated the same throughout the growing season. Evaluations were taken at approximately 1, 2, 3, 4, and 5 MAT (months after treatment) and included the taking color and quality visual ratings on a scale of 1-5 with 1 being of excellent quality or color and 5 being dead. Color ratings are based on how “green” the plant appears, and quality is based on the shape in relation to size of the plant. Evaluations also consisted of testing leachates via the pour through method for pH, electrical conductivity (Ec), and nitrate levels. Growth is evaluated by taking growth index [(height+width1+width2)/3] at the beginning and end of the trial. The inventive particles of (c) provide growth value of 33 and only 17 for group (b). On a quality assessment scale with 1 being best and 5 being the worst, group (c) averaged 1.25 while group (b) had a quality rating of 2.7. Repeat of these tested with Buxus as the test plants show inventive particles of (c) with a growth value of 4.8 and only 2 for group (b). On the quality assessment scale with 1 being best and 5 being the worst, group (c) averaged 1.4 for Buxus while group (b) had a quality rating of 2.0.
Any patents or publications mentioned in this specification are indicative of the level of those skilled in the art to which the invention pertains. These patents and publications are herein incorporated by reference to the same extent as if each individual publication was specifically and individually indicated to be incorporated by reference.
One skilled in the art will readily appreciate that the present invention is well adapted to carry out the objects and obtain the ends and advantages mentioned, as well as those inherent therein. The present methods, procedures, treatments, molecules, and specific compounds described herein are presently representative of preferred embodiments, are exemplary, and are not intended as limitations on the scope of the invention. Changes therein and other uses will occur to those skilled in the art which are encompassed within the spirit of the invention as defined by the scope of the claims.
This application is a continuation-in-part of U.S. utility application Ser. No. 12/876,536 filed 7 Sep. 2010, which in turn is a continuation-in-part of U.S. utility application Ser. No. 11/672,553 filed 8 Feb. 2007 now U.S. Pat. No. 7,789,932 B2; which in turn claims priority of U.S. Provisional Patent Application Ser. No. 60/790,345 filed 7 Apr. 2006 and U.S. Provisional Patent Application Ser. No. 60/771,408 filed 8 Feb. 2006, which are incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| 60790345 | Apr 2006 | US | |
| 60771408 | Feb 2006 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 12876536 | Sep 2010 | US |
| Child | 13080235 | US | |
| Parent | 11672553 | Feb 2007 | US |
| Child | 12876536 | US |
