This application is based upon and claims the benefit of priority from prior Japanese Patent Applications No. 2004-168619, filed Jun. 7, 2004; and No. 2004-171192, filed Jun. 9, 2004, the entire contents of both of which are incorporated herein by reference.
1. Field of the Invention
The present invention relates to a display device having light-emitting elements and a method of manufacturing the same.
2. Description of the Related Art
Display devices can roughly be classified into non-selfluminous display devices such as a liquid crystal display device and selfluminous display devices such as a plasma display and an organic electroluminescent display device. These display devices can be also classified into passive driving devices and active matrix driving devices. The active matrix driving organic electroluminescent display devices are more excellent than the passive driving devices because of their high contrast and high resolution. For example, in an active matrix driving organic electroluminescent display device described in Jpn. Pat. Appln. KOKAI Publication No. 8-330600, an organic electroluminescent element (to be referred to as an organic El element hereinafter), a driving transistor which supplies a current to the organic El element when a voltage signal corresponding to image data is applied to the gate, and a switching transistor which executes switching to supply the voltage signal corresponding to the image data to the gate of the driving transistor are provided for each pixel. In the organic electroluminescent display panel, when a scanning line is selected, the switching transistor is turned on. At this time, a signal voltage of a potential as the luminance data of the organic El element is applied to the gate of the driving transistor through a data line. Hence, the driving transistor is turned on. A driving current having a magnitude corresponding to the gate voltage value flows from the power supply to the organic El element through the source and drain of the driving transistor so that the organic El element emits light at a luminance corresponding to the magnitude of the current. During the time after selection of the scanning line is ended until the next scanning line is selected, the gate voltage value of the driving transistor is continuously held even when the switching transistor is turned off. Hence, the organic El element emits light at a luminance corresponding to the magnitude of the driving current corresponding to the voltage.
In the organic electroluminescent display device, driving circuits are provided in the periphery of the organic electroluminescent display panel to apply voltages to the scanning lines, data lines, and power supply line formed on the organic electroluminescent display panel.
In the conventional active matrix driving organic electroluminescent display device, the scanning lines, data lines, and power supply line are patterned simultaneously in the process of patterning pixel circuits such as switching transistors and driving transistors. More specifically, in manufacturing the organic electroluminescent display device, photolithography and etching are executed for a thin film as the prospective electrodes of the pixel circuits. With this process, the electrodes of the pixel circuits are shaped from the thin film. Simultaneously, interconnections to be connected to the electrodes are also shaped.
When the interconnections are formed from the thin film as the prospective electrodes of the pixel circuits, the interconnections have the same thickness as the electrodes of the pixel circuits. However, the thickness of the electrodes of the pixel circuits is designed in accordance with the required characteristics of the pixel circuits. Hence, when the current is supplied to the plurality of pixel circuits, the resistance of the interconnections is high. For this reason, a voltage drop readily occurs depending on the electrical resistance or parasitic capacitance of the interconnections. Alternatively, the current readily delays through the interconnections. Especially an interconnection connected to a plurality of pixel circuits must have a low resistance because a relatively large current needs to be supplied for the plurality of light-emitting elements.
The present invention has been made to solve the above-described problems, and has as its object to suppress any voltage drop or current delay.
In order to solve the above problems, according to a first aspect, a display device comprising:
According to a second aspect of the present invention, there is provided a display device comprising:
According to a third aspect of the present invention, there is provided a display device comprising:
According to a fourth aspect of the present invention, there is provided a display device comprising:
A display device manufacturing method according to a fifth aspect of the present invention is a method of manufacturing a display device, comprising:
In the present invention, since the pixel circuit connecting interconnection or light-emitting element connecting interconnection having a conductive layer different from the electrode of the pixel circuit is provided, the electrical resistance of the pixel circuit connecting interconnection or light-emitting element connecting interconnection can be made lower than that of the pixel circuit. For this reason, any current delay or voltage drop in the interconnection can be suppressed.
According to a sixth aspect of the present invention, there is provided a method of manufacturing a display device, comprising:
In the present invention, since the interconnection having a conductive layer different from the electrode of the pixel circuit is provided, the electrical resistance of the interconnection can be made lower than that of the electrode of the pixel circuit. For this reason, any current delay or voltage drop in the interconnection can be suppressed.
Preferred embodiments of the present invention will be described below with reference to the accompanying drawings. The embodiments to be described below include various kinds of limitations which are preferable in terms of techniques for practicing the present invention. However, the scope of the present invention is not limited to the following embodiments and illustrated examples.
A method of manufacturing a display device having, as pixels, organic electroluminescent elements serving as light-emitting elements will be described with reference to FIGS. 2 to 7. FIGS. 2 to 7 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 2 to 7.
A transistor array substrate 1 having pixel circuits, as shown in
More specifically, as shown in
Each pixel circuit 6 is provided in the periphery of a pixel. The pixel circuit 6 has the three thin-film transistors (to simply be referred to as transistors hereinafter) 7, 8, and 9 and the capacitor 10. Each of the transistors 7, 8, and 9 is an n-channel MOSFET transistor which has a gate insulating films 41 (
As shown in
The first, second, and third transistors 7, 8, and 9 are patterned simultaneously in the same process. For this reason, the compositions of the gates 7G, 8G, and 9G, gate insulating films 41, semiconductor layers 42, impurity-doped semiconductor layers 44, drains 7D, 8D, and 9D, sources 7S, 8S, and 9S are the same between the transistors 7, 8, and 9. However, the transistors 7, 8, and 9 have different shapes, sizes, dimensions, channel widths, and channel lengths in accordance with the their functions.
The signal current lines 3 are formed by patterning a source/drain conductive film as the prospective sources 7S, 8S, and 9S and drains 7D, 8D, and 9D of the transistors 7, 8, and 9 simultaneously in the same process.
The scanning lines 4 are formed by patterning a gate conductive film as the prospective gates 7G, 8G, and 9G of the transistors 7, 8, and 9 simultaneously in the same process.
Interconnections 36, interconnections 39, and a plurality of interconnections 45 shown in
Referring back to
As shown in
As shown in
As shown in
A transparent metal oxide film 16 is formed on the entire surface of the reflecting metal film 15 by vapor deposition such as sputtering. The transparent metal oxide film 16 is made of indium oxide, zinc oxide, tin oxide, or a mixture containing at least one of them (e.g., indium tin oxide (ITO), indium zinc oxide, or cadmium-tin oxide (CTO)). The transparent metal oxide film 16 is formed on the surface even in the contact holes 12 and 13.
A metal layer 17 is formed on the entire surface of the transparent metal oxide film 16. The metal layer 17 has a lower layer with a thickness of about 30 to 50 nm and an upper layer with a thickness of about 500 nm. The lower layer is formed from a metal material such as copper or nickel by vapor deposition such as sputtering. The upper layer is formed from copper by electroplating.
A photoresist film 61 is formed while exposing the metal layer 17 at a portion which overlaps the contact hole 13 along the row direction and the metal layer 17 at a portion which overlaps the organic EL isolation insulating film 14 along the row direction. In addition, the photoresist film 61 also exposes the metal layer 17 connected to the interconnections 36 through the contact holes 37, the metal layer 17 connected to the interconnections 39 through the contact holes 40, and the metal layer 17 connected to the interconnections 45 through the contact holes 46.
When electroplating is executed by using the exposed metal layers 17 as electrodes, the current source line 18 and EL line 19 made of a copper plating film having a thickness of 2 to 100 μm and a width of 2 to 50 μm are formed on the exposed metal layers 17, as shown in
The current source lines 18, EL lines 19, and common interconnections 35 and 38 are deposited thicker than the sources 7S, 8S, and 9S and drains 7D, 8D, and 9D of the transistors 7, 8, and 9. The resistance per unit length of the current source lines 18, EL lines 19, and common interconnections 35 and 38 is lower than the resistance per unit length of the sources 7S, 8S, and 9S and drains 7D, 8D, and 9D of the transistors 7, 8, and 9. The resistivity of the current source lines 18, EL lines 19, and common interconnections 35 and 38 is preferably lower than the resistivity of the conductive material of the sources 7S, 8S, and 9S and drains 7D, 8D, and 9D of the transistors 7, 8, and 9. The current source lines 18, EL lines 19, and common interconnections 35 and 38 are deposited thicker than the gates 7G, 8G, and 9G of the transistors 7, 8, and 9. The resistance per unit length of the current source lines 18, EL lines 19, and common interconnections 35 and 38 is lower than the resistance per unit length of the gates 7G, 8G, and 9G of the transistors 7, 8, and 9. The resistivity of the current source lines 18, EL lines 19, and common interconnections 35 and 38 is preferably lower than the resistivity of the conductive material of the gates 7G, 8G, and 9G of the transistors 7, 8, and 9. The current source lines 18 correspond to the conductive layer of the pixel circuit connecting interconnection. The pixel circuits 6 arrayed in the same row along the scanning line 4 are connected to the same current source line 18. The current source lines 18, EL lines 19, and common interconnections 35 and 38 are resistances and are formed long. To the contrary, the interconnections 36, 39, and 45 are relatively short and less affect the entire interconnection resistance.
The number of current source line 18, the number of EL line 19, and the number of interconnections 45 equal the number of scanning lines 4. Each row has one current source line 18, one EL line 19, one interconnection 45, and one scanning line 4. After that, the photoresist film 61 is removed. The copper thick film may be formed by sputtering, sublimation deposition, or dispenser method in place of electroplating.
The metal layer 17 except the portions covered with the current source lines 18, EL lines 19, and common interconnections 35 and 38 is shaped by etching to form an underlayer 17a under the current source line 18 and an underlayer 17b under the EL line 19.
As shown in
The reflecting metal film 15 is patterned into the same shape as the pixel electrode 16a by using the pixel electrode 16a and resist mask as a mask to form a reflecting metal underlying film 15a. The reflecting metal film 15 under the transparent metal oxide underlying film 16b is left by etching to form a reflecting metal underlying film 15b. The reflecting metal film 15 under the transparent metal oxide underlying film 16c is left by etching to form a reflecting metal underlying film 15c. The reflecting metal underlying film 15a overlaps the contact hole 12 when viewed from the upper side. For this reason, the pixel electrodes 16a are electrically insulated from each other for each pixel. The pixel electrode 16a is connected to the source 9S of the current control transistor 9 of the pixel.
In the transistor array substrate 1 without the organic EL elements 26, a test scan driver is connected to the scanning lines 4. A test driving driver to output a predetermined voltage is connected to the current source lines 18. A test current control driver to supply a current having a predetermined current value to the signal current lines 3 is connected to the signal current lines 3. A predetermined voltage is applied from the driving driver to the scanning lines 4 and current source lines 18. A predetermined current is supplied from the current control driver to the signal current lines 3. In this way, it can be tested whether the current having the predetermined current value flows from the current source lines 18 to the signal current lines 3 through the path between the source 9S and drain 9D of the current control transistor 9 and the path between the source 7S and drain 7D of the current path control transistor 7 of each pixel circuit 6. It can be confirmed whether each pixel circuit 6 is normal before the organic EL elements 26 are provided. If one of the transistors 7, 8, and 9 and capacitor 10 of a certain pixel circuit 6 of the transistor array substrate 1 has an operation error and is recognized as a defective, the organic EL elements 26 need not be formed on the transistor array substrate 1. Hence, the productivity can be increased.
Referring to
As shown in
Alternatively, the current source line insulating film 21 formed from an inorganic insulating film of silicon nitride or silicon oxide or a water-repellent organic insulating film may be patterned by vapor deposition, photolithography, and etching to cover only the current source lines 18. Alternatively, the current source line insulating film 21 made of an insulating material may be patterned by executing spin coating by using a mask and peeling the mask (lift-off method) to cover only the current source lines 18.
As shown in
After the hole transport layer 22 is dried, a light-emitting layer 23 is formed by wet film formation such as droplet discharge (ink jet), spin coating, dip coating, or injection by a needle by using a solution containing a polyparavinylene-based light-emitting or polyfluorene-based light-emitting material having conjugated double bonds. As shown in
As shown in
An overcoat insulating layer 25 is formed on the entire surface by spin coating, dip coating, or vapor deposition.
As shown in
The completed display device comprises circuits shown in
An example of the driving method of the electroluminescent display panel will be described.
The scan driver 32 sequentially outputs a shift pulse of ON level (high level) to the plurality of scanning lines 4. In synchronism with this, the current source driver 34 sequentially outputs a shift pulse of low level (potential equal to or lower than the constant voltage VSS of the EL lines 19) to the plurality of current source lines 18. While the shift pulse is output to the scanning lines 4, the data driver 33 forcibly supplies a storage current (pull-out current) having a current value corresponding to the luminance gray level to the path between the drain 9D and source 9S of the current control transistor 9 through the signal current line 3 and the path between the drain 7D and source 7S of the current path control transistor 7 connected to the current control transistor 9.
More specifically, during the selection period of a given row, a shift pulse of high level is output to the scanning line 4 of the row, and a voltage of OFF level (low level) is applied to the plurality of scanning lines 4 except the row. At this time, a shift pulse of low level equal to or lower than the constant voltage VSS of the EL line 19 is output to the current source line 18 of the row. The current path control transistor 7 and holding transistor 8 are turned on (selected). At this time, the data driver 33 controls to forcibly supply a storage current having a current value corresponding to gray level data to the path between the drain 9D and source 9S of the current control transistor 9. The storage current flows from the current source line 18 to the signal current line 3 through the path between the drain 9D and source 9S of the current control transistor 9 and the path between the drain 7D and source 7S of the current path control transistor 7. The current value of the storage current is automatically controlled by the data driver 33 in accordance with the light emission luminance gray level of the organic EL element 26.
Because of the characteristics of a transistor, the current value of the current flowing to the path between the drain 9D and source 9S of the current control transistor 9 depends on the potential between the gate 9G and source 9S of the current control transistor 9 and the potential between the drain 9D and source 9S of the current control transistor 9. The data driver 33 sets the potential between the gate 9G and source 9S of the current control transistor 9 and the potential between the drain 9D and source 9S of the current control transistor 9 in accordance with the current value of the storage current. The voltage value between the gate 9G and source 9S at this time is held (stored) during the subsequent light emission period by charges accumulated in the capacitor 10 between the gate 9G and source 9S of the current control transistor 9. During the light emission period after the selection period of the row, the scan driver 32 changes the scanning line 4 of the row to OFF level so that the current path control transistor 7 and holding transistor 8 are turned off. The charges in the capacitor 10 are held by the holding transistor 8 in the OFF state, and the voltage between the gate 9G and source 9S of the current control transistor 9 is maintained. When the current source line 18 changes to high level (level higher than the voltage of the EL line 19), a potential difference enough to saturate the path between the drain 9D and source 9S of the current control transistor 9 is generated. Hence, a driving current whose current value is uniquely determined by the magnitude of the voltage between the gate 9G and source 9S of the current control transistor 9 flows from the current source line 18 to the organic EL element 26 through the current control transistor 9. The organic EL element 26 emits light in accordance with the current value of the driving current. The magnitude of the driving current depends on the voltage between the gate 9G and source 9S of the current control transistor 9. For this reason, the current value of the driving current during the light emission period is uniquely determined by the current value of the storage current during the selection period. When the selection period and light emission period are shifted for each row, the electroluminescent display panel can execute frame display.
As described above, the current value of the storage current pulled out by the signal current line 3 almost equals the current value of the driving current flowing to one organic EL element 26. Hence, the signal current line 3 can be set to such a resistance that the signal current line 3 can sufficiently function even when the same film as the sources and drains of the transistors 7, 8, and 9 is used. Since the scanning line 4 only needs to ON/OFF-control the current path control transistor 7 and holding transistor 8 by voltage modulation, a large current need not always be supplied to the scanning line 4. For this reason, the scanning line 4 can be set to such a resistance that the scanning line 4 can sufficiently function even when the same film as the gates of the transistors 7, 8, and 9 is used.
However, the current source line 18 of a given row must have a low resistance to flow a current having a large current value because the current source line 18 serves as the current source of the driving currents to be supplied to the organic EL elements 26 of the plurality of pixels of the row during the light emission period of the row. The EL line 19 of a given row must have a low resistance to flow a current having a large current value because the driving currents to be supplied to the organic EL elements 26 of the plurality of pixels of the row flow together to the EL line 19 during the light emission period of the row. The resistances of the current source line 18 and EL line 19 must be reduced as the number of pixels (the number of organic EL elements 26) of each row increases. When the number of pixels is sufficiently large, the current cannot be sufficiently be supplied by using the same film as the gates of the transistors 7, 8, and 9.
In this embodiment, the current source line 18 and EL line 19 are formed from a conductive film different from that forming part of the transistors 7, 8, and 9. For this reason, the current source line 18 and EL line 19 can be deposited thicker than the sources 7S, 8S, and 9S and drains 7D, 8D, and 9D of the transistors 7, 8, and 9. Hence, the resistance per unit length can be set to be lower than the sources 7S, 8S, and 9S and drains 7D, 8D, and 9D. In addition, the current source line 18 and EL line 19 can be deposited thicker than the gates 7G, 8G, and 9G of the transistors 7, 8, and 9. Hence, the resistance per unit length can be set to be lower than the gates 7G, 8G, and 9G. For these reasons, the electrical resistances of the current source line 18 and EL line 19 can be set low. The time delay from the start of the light emission period until the organic EL element 26 emits light of desired brightness (gray level) can be suppressed. The voltage drop in the current source line 18 and EL line 19 can be suppressed. Furthermore, since the resistances of the current source line 18 and EL line 19 are low, any decrease in brightness, variation in brightness, and display degradation such as crosstalk in the electroluminescent display panel can be suppressed.
For example, assume that the current source line 18 and EL line 19 are set to an interconnection width of 20 μm and an interconnection length of 664 nm, and copper with a thickness of 5 μm is used, as in the present invention. In this case, the sheet resistance is 0.003 Ω/□, and the resistance is 111 Ω. At 40 mA, the voltage drop is suppressed to 4.4 V. On the other hand, assume that Al—Ti having a thickness of 0.3 μm, which is used for the drains and sources of the transistors 7, 8, and 9, is used as the current source line 18 and EL line 19, as in the prior art. In this case, the sheet resistance is 0.5 Ω/□, and the resistance is 16,600 Ω. At 40 mA, the voltage drop is 6,644 V.
The present invention is not limited to the above embodiment, and various changes and modifications in design can be made without departing from the spirit and scope of the present invention.
For example, a contact hole may be provided in the gate insulating film 41 and planarizing film 11 to expose the scanning line 4 except the portion crossing the signal current line 3. A plating layer may be formed on the scanning line 4 in the same process as film formation of the current source line 18 and EL line 19 to reduce the resistance of the scanning line 4. To insulate the plating layer from the common electrode 24, an insulating film is inserted between the plating layer and the common electrode 24, like the current source line insulating film 21 of the current source line 18. The plating layer is electrically connected to the gates of the transistors 7 and 8.
In the above embodiment, the transistors 7, 8, and 9 are n-channel thin-film transistors. The transistors 7, 8, and 9 may be p-channel thin-film transistors. When the transistors 7, 8, and 9 are p-channel thin-film transistors, connection of the source and drain reverses. In the description, “source” is changed to “drain”, and “drain” is changed to “source”. “High level” of a signal is changed to “low level”, and “low level” is changed to “high level”. Even in this case, the direction of the storage current does not change.
A method of manufacturing a display device according to the second embodiment will be described with reference to FIGS. 11 to 16. FIGS. 11 to 16 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 11 to 16. The same reference numerals as in the display device of the first embodiment denote the same parts in FIGS. 11 to 16, and some of the same steps as in the first embodiment are not illustrated.
As shown in
A transparent insulating film 131 is formed on the entire surface by vapor deposition to cover the reflecting metal film 15d. The reflecting metal film 15d is electrically insulated by the transparent insulating film 131. The second embodiment is different from the first embodiment in that the transparent insulating film 131 is formed.
Photolithography and etching are executed to form, in the planarizing film 11 and transparent insulating film 131, a contact hole 12 communicating with a source 9S of each current control transistor 9 and a contact hole 13 communicating with a drain 9D of each current control transistor 9. An organic EL isolation insulating film 14 made of silicon nitride or silicon oxide is patterned to be parallel to scanning lines 4 between pixels adjacent in the longitudinal direction.
As shown in
A metal layer 17 made of a metal material such as copper or nickel is formed on the entire surface of the transparent metal oxide film 16 by vapor deposition such as sputtering. A photoresist film 62 is formed while exposing the metal layer 17 at a portion which overlaps the contact hole 13 along the row direction and the metal layer 17 at a portion which overlaps the organic EL isolation insulating film 14 along the row direction. Like the photoresist film 61 of the first embodiment, the photoresist film 62 exposes the metal layer 17 connected to interconnections 36 through contact holes 37, the metal layer 17 connected to interconnections 39 through contact holes 40, and the metal layer 17 connected to interconnections 45 through contact holes 46.
When electroplating is executed, a current source line 18 and EL line 19 made of a thick copper plating film having a thickness of 2 to 100 μm, i.e., thicker than the sources, drains, and gates of transistors 7, 8, and 9, and a width of 5 to 50 μm are formed on the exposed metal layers 17, as shown in
As shown in
A current source line insulating film 21 is patterned to cover only the current source line 18. As shown in
After the hole transport layer 22 is dried, a light-emitting layer 23 made of polyfluorene-based light-emitting material is patterned for each pixel by wet film formation such as droplet discharge (ink jet) or dropping by a needle, as in the first embodiment. The transparent metal oxide underlying film 16c, underlayer 17b, and EL line 19 remain on the organic EL isolation insulating film 14. The hole transport layer 22 and light-emitting layer 23 are thinner than the organic EL isolation insulating film 14. The height of the solution or suspension as the prospective hole transport layer 22 and the height of the solution or suspension as the prospective light-emitting layer 23 which covers the pixel region are smaller than the height of the current source line 18 and the height of the EL line 19. Hence, the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23 do not flow to a pixel of an adjacent row over the current source line 18 and EL line 19. That is, the current source line 18 and EL line 19 function as partitions to prevent any outflow of the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23. Hence, as shown in
As shown in
An overcoat insulating layer 25 is formed on the entire surface by spin coating, dip coating, or vapor deposition. A scan driver 32, data driver 33, and current source driver 34 are connected, and a transparent sealing substrate is bonded.
With the above process, an active matrix driving electroluminescent display panel is completed.
Even in the second embodiment, the current source line 18 and EL line 19 are formed from a conductive film different from that forming part of the transistors 7, 8, and 9. For this reason, the current source line 18 and EL line 19 can be formed thicker than the drains, sources, and gates of the transistors 7, 8, and 9, a signal current line 3, and the scanning line 4, and the resistance per unit length can be reduced. Hence, the electrical resistances of the current source line 18 and EL line 19 can be set low. The time delay from the start of the light emission period until the organic EL element 26 emits light of desired brightness (gray level) can be suppressed. The voltage drop in the current source line 18 and EL line 19 can be suppressed. Furthermore, since the resistances of the current source line 18 and EL line 19 are low, any decrease in brightness, variation in brightness, and display degradation such as crosstalk in the electroluminescent display panel can be suppressed.
A method of manufacturing an electroluminescent display panel according to the third embodiment will be described with reference to FIGS. 17 to 22. FIGS. 17 to 22 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 17 to 22. The same reference numerals as in the electroluminescent display panel of the second embodiment denote the same parts in FIGS. 17 to 22, and some of the same steps as in the first embodiment are not illustrated.
As shown in
A transparent insulating film 131 is formed on the entire surface by vapor deposition to cover the reflecting metal film 15d. The reflecting metal film 15d is electrically insulated by the transparent insulating film 131.
Photolithography and etching are executed to form, in the planarizing film 11 and transparent insulating film 131, a contact hole 12 communicating with a source 9S of each current control transistor 9 and a contact hole 13 communicating with a drain 9D of each current control transistor 9.
In the second embodiment, the organic EL isolation insulating film 14 is patterned. In the third embodiment, however, no organic EL isolation insulating film is patterned.
As shown in
As shown in
When electroplating is executed, a current source line 18 and partition 231 made of a thick copper plating film having a thickness of 2 to 100 μm, i.e., thicker than the sources, drains, and gates of transistors 7, 8, and 9, and a width of 5 to 50 μm are formed on the exposed underlayers 17a and 17b. The drains 9D of the current control transistors 9 of the plurality of pixels arrayed in the row direction are electrically connected to the common current source line 18. The copper thick film may be formed by sputtering or sublimation deposition in place of electroplating.
In patterning the current source line 18 and partition 231, the current source line 18 is provided in parallel to the partition 231, and the current source line 18 and partition 231 are provided in parallel to a scanning line 4. The current source line 18 is patterned such that it overlaps the contact holes 13 of all pixels arrayed in the lateral direction (row direction) when viewed from the upper side. In addition, the current source line 18 is patterned such that it runs up to the edge of the transistor array substrate 1.
As shown in
As shown in
A hole transport layer 22 made of polythiophene (PEDOT) and polystyrene sulfonate (PSS) as a dopant is formed by wet film formation such as droplet discharge (ink jet), spin coating, dip coating, or dropping by a needle. The hole transport layer 22 may be formed on the entire surface of the transistor array substrate 1 and shared by all pixels. Alternatively, the hole transport layer 22 may be formed independently for each pixel.
After the hole transport layer 22 is dried, a light-emitting layer 23 made of polyfluorene-based light-emitting material is patterned for each pixel by wet film formation such as droplet discharge (ink jet) or dropping by a needle, as in the first embodiment. The hole transport layer 22 and light-emitting layer 23 are thinner than the partition 231. The height of the solution or suspension as the prospective hole transport layer 22 and the height of the solution or suspension as the prospective light-emitting layer 23 which covers the pixel region are smaller than the height of the current source line 18 and the height of the partition 231. Hence, the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23 do not flow to a pixel of an adjacent row over the current source line 18 and partition 231. That is, the current source line 18 and partition 231 function as partitions to prevent any outflow of the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23. Hence, when a plurality of pixels in the row direction surrounded along the current source line 18 and partition 231 should have light-emitting layers which emit the same color light, the light-emitting layers 23 for the plurality of pixels in the row direction can be formed at once by supplying the solution or suspension for the light-emitting layer 23 between the current source line 18 and the partition 231.
As shown in
An EL line 233 thicker than the sources, drains, and gates of the transistors 7, 8, and 9 is formed on the common electrode 24 by deposition, sputtering, screen printing, sublimation deposition, or dispenser method such that the EL line 233 overlaps the partition 231 when viewed from the upper side. The EL line 233 corresponds to the EL line 19 of the first embodiment and has the same shape, length, and thickness as the EL line 19. Since the EL line 233 is thicker than sources 7S, 8S, and 9S, drains 7D, 8D, and 9D, and gates 7G, 8G, and 9G of the transistors 7, 8, and 9, the resistance per unit interconnection length is set lower than that of these electrodes. The EL line 233 may be deposited by electroplating by using a photoresist film 61, like the EL line 19 of the first embodiment. The EL line 233 is connected to the common electrode 24 common to all pixels above the partition 231. The number of current source line 18 and the number of EL lines 233 equal the number of scanning lines 4. Each row has one current source line 18, one EL line 233, and one scanning line 4.
An overcoat insulating layer 25 is formed on the entire surface by spin coating, dip coating, or vapor deposition. A scan driver 32, data driver 33, and current source driver 34 are connected, and a transparent sealing substrate is bonded.
With the above process, an active matrix driving display device is completed.
Even in the third embodiment, the current source line 18 and EL line 233 are formed from a conductive film different from that forming part of the transistors 7, 8, and 9. For this reason, the current source line 18 and EL line 233 can be formed thicker than the drains, sources, and gates of the transistors 7, 8, and 9, a signal current line 3, and the scanning line 4. Hence, the electrical resistances of the current source line 18 and EL line 233 can be set low. The time delay from the start of the light emission period until the organic EL element 26 emits light of desired brightness (gray level) can be suppressed. The voltage drop in the current source line 18 and EL line 233 can be suppressed. Furthermore, since the resistances of the current source line 18 and EL line 233 are low, any decrease in brightness, variation in brightness, and display degradation such as crosstalk in the electroluminescent display panel can be suppressed.
A method of manufacturing an electroluminescent display panel according to the fourth embodiment will be described with reference to FIGS. 23 to 28. FIGS. 23 to 28 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 23 to 28. The same reference numerals as in the electroluminescent display panel of the first embodiment denote the same parts in FIGS. 23 to 28, and some of the same steps as in the first embodiment are not illustrated.
As shown in
An organic EL isolation insulating film 14 made of silicon nitride or silicon oxide is formed by patterning to be parallel to scanning lines 4 between pixels adjacent in the longitudinal direction (column direction).
As shown in
A mask is patterned by photolithography. A gold film is formed by a method such as deposition. The mask is peeled to form a pixel electrode 331 made of the gold thin film. In patterning the pixel electrode 331, the mask is formed such that underlying films 331a and 331b remain respectively at a portion corresponding to a current source line 18 (to be described later), i.e., a portion which overlaps the contact hole 13 and runs in the row direction and a portion corresponding to an EL line 19, i.e., a portion which overlaps the organic EL isolation insulating film 14 and runs in the row direction.
As shown in
As shown in
As shown in
A hole transport layer 22 made of polythiophene (PEDOT) and polystyrene sulfonate (PSS) as a dopant is formed by wet film formation such as droplet discharge (ink jet), spin coating, dip coating, or dropping by a needle. The hole transport layer 22 may be formed on the entire surface of the transistor array substrate 1 and shared by all pixels. Alternatively, the hole transport layer 22 may be formed independently for each pixel.
After the hole transport layer 22 is dried, a light-emitting layer 23 made of polyfluorene-based light-emitting material is patterned for each pixel by wet film formation such as droplet discharge (ink jet) or dropping by a needle. The transparent metal oxide underlying film 16c, underlayer 17b, and EL line 19 remain on the organic EL isolation insulating film 14. The hole transport layer 22 and light-emitting layer 23 are thinner than the organic EL isolation insulating film 14. The height of the solution or suspension as the prospective hole transport layer 22 and the height of the solution or suspension as the prospective light-emitting layer 23 which covers the pixel region are smaller than the height of the current source line 18 and the height of the EL line 19. Hence, the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23 do not flow to a pixel of an adjacent row over the current source line 18 and EL line 19. That is, the current source line 18 and EL line 19 function as partitions to prevent any outflow of the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23. Hence, as shown in
As shown in
An overcoat insulating layer 25 is formed on the entire surface by spin coating, dip coating, or vapor deposition. A scan driver 32, data driver 33, and current source driver 34 are connected, and a transparent sealing substrate is bonded.
With the above process, an active matrix driving display device is completed.
A contact hole may be provided in the gate insulating film 41 and planarizing film 11 to expose the scanning line 4 except the portion crossing a signal current line 3. An electroplating layer may be formed on the scanning line 4 in the same process as film formation of the current source line 18 and EL line 19. In this case, to insulate the plating layer from the common electrode 24, an insulating film is inserted between the plating layer and the common electrode 24, like the current source line insulating film 21 of the current source line 18. The plating layer is electrically connected to the gates of the transistors 7 and 8.
Even in the fourth embodiment, the current source line 18 and EL line 19 are formed from a conductive film different from that forming part of the transistors 7, 8, and 9. For this reason, the current source line 18 and EL line 19 can be formed thicker than the drains, sources, and gates of the transistors 7, 8, and 9, the signal current line 3, and the scanning line 4. Hence, the electrical resistances of the current source line 18 and EL line 19 can be set low. The time delay from the start of the light emission period until the organic EL element 26 emits light of desired brightness (gray level) can be suppressed. The voltage drop in the current source line 18 and EL line 19 can be suppressed. Furthermore, since the resistances of the current source line 18 and EL line 19 are low, any decrease in brightness, variation in brightness, and display degradation such as crosstalk in the electroluminescent display panel can be suppressed.
A method of manufacturing an electroluminescent display panel according to the fifth embodiment will be described with reference to FIGS. 29 to 34. FIGS. 29 to 34 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 29 to 34. The same reference numerals as in the electroluminescent display panel of the second embodiment denote the same parts in FIGS. 29 to 34, and some of the same steps as in the first embodiment are not illustrated.
As shown in
A transparent insulating film 131 is formed on the entire surface by vapor deposition to cover the reflecting metal film 15d.
Photolithography and etching are executed to form, in the planarizing film 11 and transparent insulating film 131, a contact hole 12 communicating with a source 9S of each current control transistor 9 and a contact hole 13 communicating with a drain 9D of each current control transistor 9.
The fifth embodiment is different from the second embodiment in that the organic EL isolation insulating film 14 of the second embodiment is not formed.
As shown in
A metal layer 17 made of a metal material such as copper or nickel is formed on the entire surface of the transparent metal oxide film 16 by vapor deposition such as sputtering.
As shown in
After the photoresist film 65 is removed, the exposed metal layers 17 are removed by etching by using the current source line 18 and EL line 19 as a mask to leave the underlayer 17a under the current source line 18 and the underlayer 17b under the EL line 19, as shown in
As shown in
A hole transport layer 22 made of polythiophene (PEDOT) and polystyrene sulfonate (PSS) as a dopant is formed by wet film formation such as droplet discharge (ink jet), spin coating, dip coating, or dropping by a needle. The hole transport layer 22 may be formed on the entire surface of the transistor array substrate 1 and shared by all pixels. Alternatively, the hole transport layer 22 may be formed independently for each pixel.
After the hole transport layer 22 is dried, a light-emitting layer 23 made of polyfluorene-based light-emitting material is patterned for each pixel by wet film formation such as droplet discharge (ink jet), dropping by a needle, or printing, as in the first embodiment. The hole transport layer 22 and light-emitting layer 23 are thinner than the EL line 19. The height of the solution or suspension as the prospective hole transport layer 22 and the height of the solution or suspension as the prospective light-emitting layer 23 which covers the pixel region are smaller than the height of the current source line 18 and the height of the EL line 19. Hence, the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23 do not flow to a pixel of an adjacent row over the current source line 18 and EL line 19. That is, the current source line 18 and EL line 19 function as partitions to prevent any outflow of the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23. Hence, when a plurality of pixels in the row direction surrounded along the current source line 18 and EL line 19 should have light-emitting layers which emit the same color light, the light-emitting layers 23 for the plurality of pixels in the row direction can be formed at once by supplying the solution or suspension for the light-emitting layer 23 between the current source line 18 and the EL line 19.
After the light-emitting layer 23 is dried, a contact hole 51 is formed in the hole transport layer 22 and light-emitting layer 23 to partially expose the surface of the auxiliary electrode line 16d.
As shown in
An overcoat insulating layer 25 is formed on the entire surface by spin coating, dip coating, or vapor deposition. A scan driver 32, data driver 33, and current source driver 34 are connected, and a transparent sealing substrate is bonded.
With the above process, an active matrix driving display device is completed.
Even in the fifth embodiment, the current source line 18 and EL line 19 are formed from a conductive film different from that forming part of the transistors 7, 8, and 9. For this reason, the current source line 18 and EL line 19 can be formed thicker than the drains, sources, and gates of the transistors 7, 8, and 9, a signal current line 3, and the scanning line 4.
In the first embodiment, the current source line 18 and EL line 19 are formed on the transistor layer (multilayered film from the surface of the substrate 2 to the surface of the planarizing film 11). In the sixth embodiment, a current source line 18 and EL line 19 are formed under the transistor layer. More specifically, a manufacturing method shown in FIGS. 35 to 40 is employed.
A method of manufacturing an electroluminescent display panel according to the sixth embodiment will be described with reference to FIGS. 35 to 41. FIGS. 35 to 40 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 35 to 40. The same reference numerals as in the electroluminescent display panel of the first embodiment denote the same parts in FIGS. 35 to 40, and some of the same steps as in the first embodiment are not illustrated.
As shown in
An interlayer dielectric film 501 is formed on the entire surface of the substrate 2 to cover the current source line 18 and EL line 19. A contact hole 502 communicating with the current source line 18 and contact hole 503 communicating with the EL line 19 are formed in the interlayer dielectric film 501 in correspondence with each pixel.
As shown in
Photolithography and etching are executed for a planarizing film 11 to form, in the planarizing film 11, a contact hole 12 communicating with a source 9S of each current control transistor 9 and a contact hole 505 communicating with the underlying film 504.
As shown in
Contact holes are formed even in the transparent insulating film 131 in correspondence with the contact holes 12 and 505.
A transparent metal oxide film is formed on the entire surface of the transparent insulating film 131 by vapor deposition. The transparent metal oxide film is formed on the surface even in the contact holes 12 and 505 and contacts the source 9S of the current control transistor 9 and the underlying film 504.
As shown in
As shown in
A hole transport layer 22 made of polythiophene (PEDOT) and polystyrene sulfonate (PSS) as a dopant is formed by wet film formation such as droplet discharge (ink jet), spin coating, dip coating, or dropping by a needle. The hole transport layer 22 may be formed on the entire surface of the transistor array substrate 1 and shared by all pixels. Alternatively, the hole transport layer 22 may be formed independently for each pixel.
After the hole transport layer 22 is dried, patterning is executed for each pixel by wet film formation, as in the first embodiment. The hole transport layer 22 and light-emitting layer 23 are thinner than a partition 231. The height of the solution or suspension as the prospective hole transport layer 22 and the height of the solution or suspension as the prospective light-emitting layer 23 which covers the pixel region are smaller than the height of the partitions 506. Hence, the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23 do not flow to a pixel of an adjacent row over the partitions 506. That is, the partitions 506 function as partitions to prevent any outflow of the solution or suspension as the prospective hole transport layer 22 and the solution or suspension as the prospective light-emitting layer 23. Hence, when a plurality of pixels in the row direction surrounded along the partitions 506 should have light-emitting layers which emit the same color light, the light-emitting layers 23 for the plurality of pixels in the row direction can be formed at once by supplying the solution or suspension for the light-emitting layer 23 between the partitions 506.
After the light-emitting layer 23 is dried, a contact hole 51 is formed in the hole transport layer 22 and light-emitting layer 23 to partially expose the surface of the auxiliary electrode line 16e.
As shown in
As shown in
With the above process, an active matrix driving display device is completed.
Even in the sixth embodiment, the current source line 18 and EL line 19 are formed in the process different from that of the transistors 7, 8, and 9 by patterning a conductive film different from the sources, drains, and gates of the transistors 7, 8, and 9. Since the current source line 18 and EL line 19 can be formed thicker than the drains, sources, and gates of the transistors 7, 8, and 9, a signal current line 3, and a scanning line 4, the electrical resistances of the current source line 18 and EL line 19 can be set low. Hence, the signal delay or voltage drop in the current source line 18 and EL line 19 can be suppressed.
A method of manufacturing an electroluminescent display panel according to the seventh embodiment will be described with reference to
After a pixel electrode 16a is formed, a partition 507 is patterned along a current source line 18 by photolithography, as shown in
A conductive paste 510 is buried between the partitions 508 and 509. The conductive paste 510 is in tight contact with the auxiliary electrode line 16e remaining on the underlying film 504.
After the conductive paste 510 is dried, a hole transport layer 22 and light-emitting layer 23 are formed, as in the sixth embodiment. At this time, the partitions 507 and 508 have the same function as that of the partition 506 of the sixth embodiment.
As shown in
An overcoat insulating layer 25 is formed on the entire surface by spin coating, dip coating, or vapor deposition. A scan driver 32, data driver 33, and current source driver 34 are connected, and a transparent sealing substrate is bonded.
With the above process, an active matrix driving display device is completed.
Even in the seventh embodiment, the current source line 18 and EL line 19 are formed in the process different from that of transistors 7, 8, and 9. Since the current source line 18 and EL line 19 can be formed thicker than the drains, sources, and gates of the transistors 7, 8, and 9, a signal current line 3, and a scanning line 4, the resistances of the current source line 18 and EL line 19 can be set lower than that of the transistors 7, 8, and 9. The electrical resistances of the current source line 18 and EL line 19 can be set low. Hence, the signal delay or voltage drop in the current source line 18 and EL line 19 can be suppressed.
In the above embodiments, light emitted from the light-emitting layer 23 is caused to exit from the side of the common electrode 24 by providing the reflecting metal film 15. However, the present invention is not limited to this. Light emitted from the light-emitting layer 23 may be caused to exit from the side of the pixel electrode 16a without providing the reflecting metal film 15. In this case, the common electrode 24 is preferably opaque or reflects light. Especially, the common electrode 24 preferably has a multilayered structure including an electron emission film with a low work function and a conductive film which has a high work function and protects the electron emission film by covering it.
A method of manufacturing a display device which has organic electroluminescent elements serving as light-emitting elements as pixels will be described with reference to FIGS. 44 to 50. FIGS. 44 to 50 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 44 to 50. The same reference numerals as in the electroluminescent display panel of the first embodiment denote the same parts in FIGS. 44 to 50, and some of the same steps as in the first embodiment are not illustrated.
FIGS. 44 to 50 are sectional views of one pixel obtained by cutting a current control transistor 9 along a plane perpendicular to a scanning line 4. The remaining pixels also take the states shown in FIGS. 44 to 50 in the respective steps.
As shown in
A conductive film made of a conductive material selected from a simple metal such as aluminum, titanium, or gold, an alloy thereof, or a transparent metal oxide film is formed on the entire surface of the transistor array substrate 1 by vapor deposition such as sputtering or deposition. The conductive film is formed on the surface even in the contact holes 12 and 13. A transparent metal oxide film selected from indium oxide, zinc oxide, tin oxide, and a mixture containing at least one of them (e.g., indium tin oxide (ITO), indium zinc oxide, or cadmium-tin oxide (CTO)) is formed on the conductive film.
The stacked conductive films are patterned to form a pixel electrode 16a connected to the source 9S of the current control transistor 9 and an underlying interconnection 16b arranged in the row direction and connected to the drain 9D of the current control transistor 9 arrayed along the row direction.
As shown in
As shown in
As shown in
As shown in
As shown in
After the hole transport layer 22 is dried, a light-emitting layer 23 is formed by wet film formation such as droplet discharge (ink jet), spin coating, dip coating, or injection by a needle by using a solution containing a polyparavinylene-based light-emitting or polyfluorene-based light-emitting material having conjugated double bonds. As shown in
As shown in
A common electrode 24 serving as a cathode electrode is formed on the entire surface by vapor deposition such as deposition. The common electrode 24 has a two-layer structure including an electron injection layer made of a low work function material such as magnesium, calcium, lithium, barium, or a rare-earth metal and a transparent conductive layer containing indium oxide, zinc oxide, tin oxide, or a mixture containing at least one of them (e.g., indium tin oxide (ITO), indium zinc oxide, or cadmium-tin oxide (CTO)). The electron injection layer having a thickness of 1 to 20 nm is so thin that visible light passes through it. Hence, the electron injection layer can be cut by the step of the current source line 18 or EL line 19. The transparent conductive layer of the common electrode 24 is formed across the liquid-repellent insulating film 33a on the current source line 18 and across the EL line 19 to set one electrode of each of organic EL elements 26 of the plurality of pixels at an equipotential. The light-emitting layer 23 is covered with the common electrode 24 while being in tight contact with the common electrode 24. The EL line 19 is also covered with the common electrode 24 while being in tight contact with the common electrode 24. The common electrode 24 is electrically connected to the EL line 19 through the contact hole 33c but insulated from the current source line 18 by the liquid-repellent insulating film 33a.
An overcoat insulating layer 25 is formed on the entire surface by spin coating, dip coating, or vapor deposition. A scan driver 32, data driver 33, and current source driver 34 are connected, and a transparent sealing substrate is bonded.
A method of manufacturing an electroluminescent display panel according to the ninth embodiment will be described with reference to FIGS. 51 to 56. FIGS. 51 to 56 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 51 to 56. The same reference numerals as in the electroluminescent display panel of the eighth embodiment denote the same parts in FIGS. 51 to 56.
In this embodiment, after a transistor array substrate 1 is manufactured, underlayers 17a and 17b are formed by the processes shown in
As shown in
As shown in
After the photoresist film 63 is removed, an insulating film 52 which covers at least the exposed surface of the current source line 18, the side surface of the underlayer 17a, and the side surface of an underlying interconnection 16b is formed, as shown in
The method of forming the wettability changeable conductive film 30 will be described in detail.
A solution (to be referred to as a silazane-based solution hereinafter) containing a silazane compound having a functional group containing fluorine is applied to the surface of the transistor array substrate 1 on which the pixel electrode 16a is formed, thereby forming a film of the silazane compound solution.
The “silazane compound having a functional group containing fluorine” has Si—N—Si bonds. The functional group containing fluorine is bonded to N and/or Si. Examples are oligomers or polymers expressed by
RfSi(NH)3/2 (1)
where Rf is a functional group containing fluorine.
An example of the “functional group containing fluorine” is a fluoroalkyl group. Examples of the functional group are
(CH2)a(CF2)bCF3 (2)
(CH2)a(CF2)bCF(CF3)2 (3)
(CH2)a(CF2)bC(CF3)3 (4)
(CF2)aCF3 (5)
(CF2)aCF(CF3)2 (6)
(CF2)aC(CF3)3 (7)
(CF2)a(C(CF3)2)bCF3 (8)
(CF2)a(C(CF3)2)bCF(CF3)2 (9)
(CF2)a(C(CF3)2)bC(CF3)3 (10)
(CF2)a(C(CF3)2)b(CF2)cCF3 (11)
(CF2)a(C(CF3)2)b(CF2)cCF(CF3)2 (12)
(CF2)a(C(CF3)2)b(CF2)cC(CF3)3 (13)
(C(CF3)2)aCF3 (14)
(C(CF3)2)aCF(CF3)2 (15)
(C(CF3)2)aC(CF3)3 (16)
(C(CF3)2)a(CF2)bCF3 (17)
(C(CF3)2)a(CF2)bCF(CF3)2 (18)
(C(CF3)2)a(CF2)bC(CF3)3 (19)
where a, b, and c are integers.
An example of the solvent medium of the silazane-based solution is a fluorine-based solvent.
In this example, silazane oligomer (KP-801M: available Shin-Etsu Chemical) expressed by
C8F17C2H4Si(NH)3/2 (20)
is used. In the above-described dip coating process, the transistor array substrate 1 is immersed in a silazane-based solution (concentration: 3 wt %) which is prepared by dissolving the silazane oligomer as a solute in an m-xylenehexafluoride solvent medium.
When an inert gas such as nitrogen gas is blown to the transistor array substrate 1 to evaporate the solvent medium of the silazane-based solution, the silazane compound is deposited on the surfaces of the pixel electrode 16a and interlayer dielectric film 20.
When the transistor array substrate 1 is let stand for 10 to 30 min, the silazane compound is hydrolyzed and condensed by water in the atmosphere. With this process, as shown in
The silazane compound is condensed in the planar direction of the surface of the pixel electrode 16a. In addition, the main chain in the monomolecular unit, i.e., the Rf-Si—X group or Rf-Si group is rarely stacked on the main chain in the monomolecular unit, i.e., the Rf-Si—X group or Rf-Si group formed on the surface of the pixel electrode 16a. X is the atom or atom group of the pixel electrode 16a, which is bonded to the silazane compound. For this reason, the thickness of the wettability changeable conductive film 30 almost equals the length of the main chain in the monomolecular unit (corresponding to the side chain of the condensate), i.e., the Rf-Si—X group or Rf-Si group. In addition, the wettability changeable conductive film 30 is condensed such that the functional group Rf containing fluorine in the main chain in the monomolecular unit is arranged on the surface side of the wettability changeable conductive film 30. Hence, the surface of the wettability changeable conductive film 30 exhibits liquid repellency against an organic compound containing solution because of the liquid repellency of the functional group Rf.
When the wettability changeable conductive film 30 is formed in the above-described way, the wettability changeable conductive film 30 is rinsed by an m-xylenehexafluoride solution (same solution as the solvent medium of the silazane-based solution) to wash away the deposited unreacted silazane compound or extra silazane compound.
A photomask substrate is made to oppose the transistor array substrate 1. Active rays are caused to pass through the photomask substrate to partially irradiate the wettability changeable conductive film 30 with the active rays. The wettability changeable conductive film 30 is patterned to form parts with low wettability and parts with high wettability. Examples of the active rays are visible light, UV rays, and infrared rays to excite a photocatalytic film (to be described later).
The photomask substrate will be described. The photomask substrate has a transparent substrate to pass active rays. A mask which is formed into a mesh shape having a plurality of opening portions arrayed in a matrix corresponding to the plurality of pixel electrodes 16a is formed on one surface of the transparent substrate. A photocatalytic film having a thickness of about 0.2 μm is formed on the entire surface to cover the whole mask. Each opening portion is set to a width to form an opening between the current source line 18 and the EL line 19 along the row direction.
The mask does not reflect, absorb, or pass the active rays. The photocatalytic film is made of one or two or more substances selected from titanium oxide (TiO2), zinc oxide (ZnO), tin oxide (SnO2), strontium titanate (SrTiO3), tungsten oxide (WO3), bismuth oxide (Bi2O3), and iron oxide (Fe2O3).
The active rays are applied to the photomask substrate. The active rays are blocked by the mask but pass through the photocatalytic film at opening portions without the mask. The active rays do not enter the region of the wettability changeable conductive film 30 overlapping the mask, i.e., the periphery of the pixel electrode 16a but enter the region overlapping the pixel electrode 16a.
When the active rays pass through the photocatalytic film, an active oxygen species (.OH) is generated. The active oxygen species causes chemical reaction with the wettability changeable conductive film 30. The active oxygen species which has passed through the photocatalytic film reaches the region of the wettability changeable conductive film 30 overlapping the pixel electrode 16a. The active oxygen species does not reach the region overlapping the mask because the mask blocks the active rays. With the function of the photocatalyst, the active oxygen species is generated when the active rays enter the photocatalytic film. The generated active oxygen species reaches the wettability changeable conductive film 30 and changes its chemical structure.
In the region of the wettability changeable conductive film 30 overlapping the opening portion, the Rf group having liquid repellency substitutes for a hydroxyl group having an affinity for water due to the active oxygen species (—OH) generated by the function of the photocatalyst so that a lyophilic film 30a is formed. Since the functional group (Rf) containing fluorine is decomposed and eliminated and substitutes for the hydroxyl group, the lyophilic film 30a is lyophilic to an organic compound containing solution. For this reason, a liquid containing the material of an electroluminescent layer 23 (to be described later) is not repelled, and a film of the liquid can uniformly be formed on the surface of the lyophilic film 30a.
In the lyophilic film 30a, the main chain in the condensate containing silicon and oxygen is formed along the surface of the pixel electrode 16a. In addition, the functional group containing fluorine and having liquid repellency substitutes for the hydroxyl group. Since the thickness equals the length of the main chain in the monomolecular unit (corresponding to the side chain of the condensate), i.e., the HO—Si—X group or HO—Si group, a very thin lyophilic film having a thickness of 1 nm or less can be formed. On the pixel electrode 16a in the region where the active oxygen species is generated, the pattern film or wettability changeable conductive film 30 is very thin. Hence, the lyophilic film 30a itself rarely inhibit injection or transport of charges such as holes.
The active oxygen species does not reach the region of the wettability changeable conductive film 30 overlapping the mask, and no chemical reaction occurs. This region still exhibit liquid repellency against the liquid containing the material of the light-emitting layer (to be described later). A liquid-repellent film 30b having the same characteristic as the wettability changeable conductive film 30 is formed in this region. The liquid-repellent film 30b is formed continuously from the lyophilic film 30a and is thicker than the lyophilic film 30a by an amount almost corresponding to the functional group Rf containing fluorine.
An EL layer is formed on each pixel, i.e., each lyophilic film 30a. This will be described with reference to
A film of an aqueous solution or suspension containing polythiophene and polystyrene sulfonate as a dopant is formed by wet film formation such as spin coating or dip coating. The aqueous solution or suspension readily wets and smears the lyophilic film 30a having lyophilic properties. The aqueous solution or suspension hardly wets the liquid-repellent film 30b having liquid repellency and is readily repelled. For these reasons, the aqueous solution or suspension is selectively applied to the lyophilic film 30a. When the solvent medium of the aqueous solution or suspension dries on the lyophilic film 30a, the hole transport layer 22 is formed. The aqueous solution or suspension containing the material of the hole transport layer 22 is deposited thicker than the light-emitting layer 23 at the early stage of film formation because it contains several vol % of the material of the hole transport layer 22. However, since the current source line 18 and EL line 19 serve as partitions much higher than the solution or suspension, the aqueous solution or suspension can be prevented from flowing to a row adjacent to the row so that a film having a uniform thickness can be formed.
The current source line 18 can partition the hole transport layer 22 as at least one side of the block where the hole transport layer 22 is formed. The EL line 19 can partition the hole transport layer 22 as at least another side of the block where the hole transport layer 22 is formed.
After the hole transport layer 22 is formed, as shown in
Hence, when a plurality of pixels in the row direction surrounded along the current source line 18 and EL line 19 should have light-emitting layers which emit the same color light, the light-emitting layers 23 for the plurality of pixels in the row direction can be formed at once by supplying the solution or suspension containing the material of the light-emitting layer 23 between the current source line 18 and the EL line 19.
The current source line 18 can partition the light-emitting layer 23 as at least one side of the block where the light-emitting layer 23 is formed. The EL line 19 can partition the light-emitting layer 23 as at least another side of the block where the light-emitting layer 23 is formed.
As shown in
The overcoat insulating layer 25 is formed on the entire surface by spin coating, dip coating, or vapor deposition. A scan driver 32, data driver 33, and current source driver 34 are connected, and a transparent sealing substrate is bonded.
Each pixel of the completed display device has the structure shown in
Since the current source line 18 does not overlap the pixel electrode 16a when viewed from the upper side, the parasitic capacitance to the pixel electrode 16a can be suppressed. To suppress the parasitic capacitance to a scanning line 4 and the signal delay in the scanning line 4, the current source line 18 preferably does not overlap the scanning line 4 when viewed from the upper side. When the overlap area between the current source line 18 and a signal current line 3 to which a microcurrent flows is small when viewed from the upper side, the parasitic capacitance to the signal current line 3 can be suppressed. The current source line 18 may be made narrow at the portion overlapping the signal current line 3, as shown in
Since the EL line 19 does not overlap the pixel electrode 16a when viewed from the upper side, the parasitic capacitance to the pixel electrode 16a can be suppressed. To suppress the parasitic capacitance to the scanning line 4 and the signal delay in the scanning line 4, the EL line 19 preferably does not overlap the scanning line 4 when viewed from the upper side. When the overlap area between the EL line 19 and the signal current line 3 to which a microcurrent flows is small when viewed from the upper side, the parasitic capacitance to the signal current line 3 can be suppressed. The EL line 19 may be made narrow at the portion overlapping the signal current line 3.
In this embodiment, the current source line 18 and EL line 19 are formed from a conductive film different from that forming the transistors 7, 8, and 9. For this reason, the current source line 18 and EL line 19 can be deposited thicker than the sources 7S, 8S, and 9S and drains 7D, 8D, and 9D of the transistors 7, 8, and 9. Hence, the resistance per unit length can be set to be lower than the sources 7S, 8S, and 9S and drains 7D, 8D, and 9D. In addition, the current source line 18 and EL line 19 can be deposited thicker than the gates 7G, 8G, and 9G of the transistors 7, 8, and 9. Hence, the resistance per unit length can be set to be lower than the gates 7G, 8G, and 9G. For these reasons, the electrical resistances of the current source line 18 and EL line 19 can be set low. The time delay from the start of the light emission period until the organic EL element 26 emits light of desired brightness (gray level) can be suppressed. The voltage drop in the current source line 18 and EL line 19 can be suppressed. Furthermore, since the resistances of the current source line 18 and EL line 19 are low, any decrease in brightness, variation in brightness, and display degradation such as crosstalk in the electroluminescent display panel can be suppressed.
The present invention is not limited to the above embodiment, and various changes and modifications in design can be made without departing from the spirit and scope of the present invention.
For example, a contact hole may be provided in a gate insulating film 41 and planarizing film 11 to expose the scanning line 4 except the portion crossing the signal current line 3. An electroplating layer may be formed on the scanning line 4 in the same process as film formation of the current source line 18 and EL line 19. In this case, to insulate the plating layer from the common electrode 24, an insulating film is inserted, like the liquid-insulating films 33a and 33b. The plating layer is electrically connected to the gates of the transistors 7 and 8.
In the above embodiment, the transistors 7, 8, and 9 are n-channel thin-film transistors. The transistors 7, 8, and 9 may be p-channel thin-film transistors. When the transistors 7, 8, and 9 are p-channel thin-film transistors, connection of the source and drain reverses. In the description, “source” is changed to “drain”, and “drain” is changed to “source”. “High level” of a signal is changed to “low level”, and “low level” is changed to “high level”. Even in this case, the direction of the storage current does not change.
A method of manufacturing an electroluminescent display panel according to the 10th embodiment will be described with reference to FIGS. 57 to 61. FIGS. 57 to 61 are sectional views of steps in the manufacturing method. The steps are executed in the order of FIGS. 57 to 61. The same reference numerals as in the electroluminescent display panels of the first, eighth, and ninth embodiments denote the same parts in FIGS. 57 to 61.
As shown in
As shown in
As shown in
As in the ninth embodiment, as shown in
As shown in
A current control driver is connected to a plurality of signal current lines 3 on a substrate 2. A scan driver is connected to a plurality of scanning lines 4. A driving driver is connected to the plurality of current source lines 18. The plurality of EL lines 19 are set to an equipotential such as the ground potential and maintained at a constant voltage.
The embodiments include various kinds of limitations which are preferable in terms of techniques for practicing the present invention. However, the scope of the present invention is not limited to the above-described embodiments and illustrated examples.
In the above embodiments, the drain 8D of the holding transistor 8 is connected to the current source line 18. Even when the drain 8D is connected to the scanning line 4 instead, the same operation as described above can be executed.
In the above embodiments, the source 9S of the current control transistor 9 is connected to the anode of the organic EL element 26. The EL line 19 is connected to the cathode of the organic EL element 26. However, the present invention is not limited to this. The source 9S of the current control transistor 9 may be connected to the cathode of the organic EL element 26. The EL line 19 may be connected to the anode of the organic EL element 26.
In the above embodiments, the current source line 18 partitions the hole transport layer 22 as at least one side of the block where the hole transport layer 22 is formed and also partitions the light-emitting layer 23 as at least one side of the block where the light-emitting layer 23 is formed. Even when the organic EL element 26 has a single light-emitting layer without any hole transport layer, the current source line 18 may partition the light-emitting layer as at least one side of the block where the light-emitting layer is formed. Even when the organic EL element 26 has an electron transport layer, the current source line 18 may partition the electron transport layer as at least one side of the block where the electron transport layer is formed.
Similarly, even when the organic EL element 26 has a single light-emitting layer without any hole transport layer, the EL line 19 may partition the light-emitting layer as at least one side of the block where the light-emitting layer is formed. Even when the organic EL element 26 has an electron transport layer, the EL line 19 may partition the electron transport layer as at least one side of the block where the electron transport layer is formed.
Number | Date | Country | Kind |
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2004-168619 | Jun 2004 | JP | national |
2004-171192 | Jun 2004 | JP | national |