The present invention relates to a display device.
A liquid crystal panel in a liquid crystal display device includes a number of TFTs disposed in a matrix. The TFTs are switching components for controlling operations of pixels. Silicon semiconductors including amorphous silicon semiconductors have been commonly used for semiconductor films in the TFTs. In recent years, use of oxide semiconductors having higher electron mobility for semiconductor films is proposed. An example of a liquid crystal display device including TFTs using such oxide semiconductors as switching components is disclosed in Patent Document 1.
Patent Document 1: Japanese Unexamined Patent Application Publication No. 2011-29373
An oxide semiconductor has high electron movability. Therefore, sizes of TFTs can be reduced and an aperture ratio of a liquid crystal panel can be increased. Furthermore, various circuits can be disposed on an array board on which the TFTs are disposed. However, if an oxide semiconductor takes moisture therein, electrical characteristics of the oxide semiconductor are more likely to change. This may cause malfunctions of the circuits.
The present invention was made in view of the above circumstances. An object is to provide technology for reducing malfunctions of non-display area transistors.
A display device according to the present invention includes a substrate, a display area transistor, a non-display area transistor, a gate electrode, an oxide semiconductor film, a source electrode, a drain electrode, and an insulator. The substrate includes a display area and a non-display area. The display area is configured to display image and located medially. The non-display area is located closer to peripheral edges of the substrate so as to surround the display area. The display area transistor is disposed in the display area. The non-display area transistor is disposed in the non-display area. The gate electrode is included in the non-display area transistor. The oxide semiconductor film is included in the non-display area transistor. At least a portion of the oxide semiconductor film overlaps the gate electrode in a plan view. The source electrode is included in the non-display area transistor. At least a portion of the source electrode is layered on the oxide semiconductor film in a plan view and connected to the oxide semiconductor film. The drain electrode is included in the non-display area transistor. At least a portion of the drain electrode is layered on the oxide semiconductor film and connected to the oxide semiconductor film with a gap between the source electrode and the drain electrode. The insulator is layered on the source electrode and the drain electrode. The insulator has a multilayer structure including a lower insulator and an upper insulator. The lower insulator is disposed in a lower layer. The lower insulator contains at least silicon and oxide. The upper insulator is disposed in an upper layer. The upper insulator contains at least silicon and nitrogen. The upper insulator has a thickness in a range from 35 nm to 75 nm.
According to the configuration, in the non-display area transistor, a current flows between the source electrode and the drain electrode via the oxide semiconductor film when a voltage is applied to the gate electrode. In comparison to an amorphous silicon thin film, the oxide semiconductor film has higher electron mobility. This configuration is preferable for passing a large current between the source electrode and the drain electrode.
In the substrate having the configuration in which the non-display area is disposed closer to the peripheral edges so as to surround the display area disposed medially, the non-display area transistor in the non-display area is more likely to be subject to moisture that exists outside in comparison to the display area transistor in the display area. If the oxide semiconductor film in the non-display area transistor takes the moisture therein from the outside and degrades, electrical characteristics of the oxide semiconductor film change. The non-display area transistor may not function properly.
The insulators layered at least on the source electrode and the drain electrode has the multilayer structure including the lower insulator and the upper insulator. The lower insulator is disposed in the lower layer. The lower insulator contains at least silicon and oxygen. The upper insulator is disposed in the upper layer. The upper insulator contains at least silicon and nitrogen. With upper insulator, the moisture from the outside is less likely to reach the oxide semiconductor film. Even if the upper insulator contains hydrogen during the formation of the upper insulator and the hydrogen is desorbed from the upper insulator, the hydrogen desorbed from the upper insulator is less likely to reach the oxide semiconductor film because of the lower insulator. Therefore, the oxide semiconductor is less likely to deteriorate due to the moisture and the hydrogen taken into the oxide semiconductor and thus the electrical characteristics are less likely to change. A malfunction of the non-display area transistor is less likely to occur.
If the thickness of the upper insulator is larger than 75 nm, a large amount of hydrogen is contained in the upper insulator during the formation of the upper insulator.
Furthermore, the amount of hydrogen desorbed from the upper insulator tends to increase. Therefore, the oxide semiconductor film may be deteriorated by the hydrogen desorbed from the upper insulator and the electrical characteristics thereof are more likely to change. If the thickness of the upper insulator is smaller than 35 nm, the coverage of the upper insulator to the lower insulator decreases. The cracks (gaps) are more likely to be created and thus the moisture resistance decreases. As a result, the oxide semiconductor film is more likely to take the moisture therein. When the thickness of the upper insulator is in the range from 35 nm to 75 nm, the amount of hydrogen desorbed from the upper insulator is small. The sufficient moisture resistance of the upper insulator is provided and the electrical characteristics of the oxide semiconductor film are less likely to change. Therefore, the malfunction of the non-display area transistor is less likely to occur. Because the upper insulator has the sufficient moisture resistance, the source electrode and the drain electrode are less likely to be corroded by the moisture.
Preferable embodiments may include the following configurations.
(1) The upper insulator of the insulator may have a refractive index in a range from 1.5 to 1.9. The refractive index of the upper insulator varies according to the composition. Specifically, if the content of the nitrogen decreases, the refractive index tends to decrease. If the content of the nitrogen increases, the refractive index tends to increase. If the refractive index of the upper insulator is equal to or smaller than 1.5, the content of nitrogen is small and thus the moisture resistance is low. Namely, the moisture is more likely to enter the oxide semiconductor film, which may results in adverse effect on the electrical characteristics of the oxide semiconductor film. If the refractive index of the upper insulator is equal to or larger than 1.9, the content of nitrogen is large and thus it may be difficult to form the film by general fabrication equipment. If the refractive index of the upper insulator is in the range from 1.5 to 1.9, the sufficient moisture resistance is ensured. The electrical characteristics of the oxide semiconductor film are less likely to change and thus the film is easily formed by general fabrication equipment.
(2) The refractive index of the upper insulator of the insulator is may be in a range from 1.5 to 1.72. The content of hydrogen in the upper insulator during the formation of the film tends to increase as the content of nitrogen increases. By setting the upper limit of the refractive index of the upper insulator to 1.72, a small amount of hydrogen is contained in the upper insulator. The amount of hydrogen desorbed from the upper insulator is small and thus the electrical characteristics of the oxide semiconductor film are less likely to change due to the hydrogen desorbed from the upper insulator.
(3) The display device may further include a counter substrate, liquid crystals, and a sealing member. The counter substrate may be disposed opposite the substrate. The liquid crystals are sandwiched between the substrate and the counter substrate. The sealing member is disposed between the substrate and the counter substrate so as to surround the liquid crystals and seals the liquid crystals. The non-display area transistor is disposed closer to the sealing member than the display area transistor. According to the configuration, the liquid crystals sandwiched between the substrate and the counter substrate are sealed by the sealing member disposed between the substrate and the counter substrate so as to surround the liquid crystals. The non-display area transistor is closer to the sealing member than the display area transistor. If the moisture from the outside permeates the sealing member, the non-display area transistor is subject to the moisture. As described above, the insulator has the multilayer structure including the upper insulator and the lower insulator and the thickness of the upper insulator is in the range from 35 nm to 75 nm. Therefore, the oxide semiconductor film in the non-display area transistor is less likely to take the moisture that permeates the sealing member therein and thus the malfunction of the non-display transistor is less likely to occur.
(4) The oxide semiconductor film may include an extending portion that projects toward an opposite direction to the source electrode at a position at which the drain electrode is connected. At least a portion of the extending portion may not overlap the gate electrode in a plan view. The oxide semiconductor film may have such a configuration. Namely, the oxide semiconductor film may include the extending portion that projects toward an opposite direction to the source electrode at a position at which the drain electrode is connected. At least a portion of the extending portion may not overlap the gate electrode in a plan view. According to the configuration, light from the outside toward the non-overlapping portion of the extending portion is less likely to be blocked by the gate electrode. Therefore, the non-overlapping portion is subject to irradiation of the light from the outside and thus the electrical characteristics thereof may degrade. Specifically, the oxide semiconductor film has characteristics that the flow of electric charge tends to be easily affected by energy of light. During driving of the non-display area transistor, electric charge may buildup in the non-overlapping portion of the extending portion. Such a problem tends to result in a malfunction of the non-display transistor together with the problem that the oxide semiconductor film deteriorates caused by the moisture taken into the oxide semiconductor film. As described above, the insulator has the multilayer structure including the upper insulator and the lower insulator and the thickness of the upper insulator is in the range from 35 nm to 75 nm. Therefore, the moisture and the hydrogen are less likely to be taken into the oxide semiconductor film and thus the malfunction of the non-display area transistor is less likely to occur.
(5) The display device may further include a protection film for protecting the oxide semiconductor film. The protection film may be disposed between the source electrode and the oxide semiconductor film and between the drain electrode and the oxide semiconductor film. The protection film may include a pair of holes formed at positions overlapping the source electrode and the drain electrode, respectively, in a plan view and through which the source electrode and the drain electrode are connected to the oxide semiconductor film. According to the configuration, during etching for forming the source electrode and the drain electrode in the fabrication process, the oxide semiconductor film is protected by the protection film in the upper layer from being etched. After the fabrication, the oxide semiconductor film is protected by the protection film. The hydrogen is less likely to be taken into the oxide semiconductor film and thus the malfunction of the non-display area transistor is less likely to occur. Furthermore, the protection film may include the pair of holes formed at positions that overlap the source electrode and the drain electrode, respectively, in a plan view. The source electrode and the drain electrode may be connected to the oxide semiconductor film through the holes.
(6) The protection film may contain at least silicon and oxygen. According to the configuration, that is, the protection film may contain at least silicon and oxygen, the amount of hydrogen desorbed from the protection film is small. The hydrogen is less likely to be taken into the oxide semiconductor film and thus the malfunction of the non-display area transistor is less likely to occur.
(7) The oxide semiconductor film may contain at least indium, gallium, and zinc. The oxide semiconductor film that contains at least indium, gallium, and zinc may tend to deteriorate due to the moisture or the hydrogen. As described above, the insulator has the multilayer structure including the upper insulator and the lower insulator and the thickness of the upper insulator is in the range from 35 nm to 75 nm. Therefore, the moisture and the hydrogen are less likely to be taken into the oxide semiconductor film and thus the malfunction of the non-display area transistor is less likely to occur.
(8) The display device may further include a scan signal line and a buffer circuit. The scan signal line may be disposed in the display area and connected to the display area transistor to transmit scan signals to the display area transistor. The buffer circuit may be disposed in the non-display area and connected to the scan signal line. The non-display area transistor may be included in the buffer circuit. According to the configuration, in the non-display area transistor in the buffer circuit, a current that flows between the source electrode and the drain electrode tends to be larger in comparison to the display area transistor. The malfunction of the non-display area transistor due to change in electrical characteristics caused by the moisture or the hydrogen taken into the oxide semiconductor film in the non-display area transistor is more likely to occur. As described above, the insulator has the multilayer structure including the upper insulator and the lower insulator and the thickness of the upper insulator is in the range from 35 nm to 75 nm. Therefore, the moisture and the hydrogen are less likely to be taken into the oxide semiconductor film and thus the malfunction of the non-display area transistor in the buffer circuit is less likely to occur.
(9) The source electrode and the drain electrode may contain at least copper. In comparison to a source electrode and a drain electrode each containing aluminum, the source electrode and the drain electrode each containing copper have higher electrical conductivities but tend to be corroded by the moisture. As described above, the insulator has the multilayer structure including the upper insulator and the lower insulator and the thickness of the upper insulator is in the range from 35 nm to 75 nm. Therefore, the moisture from the outside is less likely to permeate through the insulator and to reach the source electrode and the drain electrode and thus the source electrode and the drain electrode are less likely to be corroded by the moisture.
According to the present invention, a malfunction of the non-display area transistor is less likely to occur.
A first embodiment of the present invention will be described with reference to
As illustrated in
The backlight unit 14 will be described. As illustrated in
Next, the liquid crystal panel 11 will be described. As illustrated in
Next, the components connected to the liquid crystal panel 11 will be described. As illustrated in
The flexible printed circuit board (an FPC board) 13 includes a base member made of synthetic resin having insulating property and flexibility (e.g., polyimide resin). A number of traces are formed on the base member (not illustrated). As illustrated in
As illustrated in
The liquid crystal panel 11 will be described in more detail. As illustrated in
The liquid crystal panel 11 according to this embodiment operates in fringe field switching (FFS) mode that is a mode improved from an in-plane switching (IPS) mode. As illustrated in
The films formed in layers on the inner surface of the array board 11b (on the liquid crystal layer 11c side, a surface opposite the CF board 11a) by a known photolithography method will be described. As illustrated in
The first metal film 34 is a single layer film of copper (Cu). In comparison to a configuration in which the first metal film 34 is a single layer film of aluminum (AL), a wiring resistance is lower and thus higher electrical conductivity is achieved. The gate insulator 35 is formed at least on the first metal film 34. The gate insulator 35 is made of silicon oxide (SiO2). The oxide semiconductor film 36 is formed on the gate insulator 35. The oxide semiconductor film 36 is an oxide thin film that is a kind of oxide semiconductors containing indium (In), gallium (Ga), and zinc (Zn). The oxide semiconductor that contains indium (In), gallium (Ga), and zinc (Zn), that is, the oxide semiconductor film 36 may be amorphous or crystalline. In the display area AA, the oxide semiconductor film 36 forms first channels of display area TFTs 17, which will be described later. In the non-display area NAA, the oxide semiconductor film 36 forms second channels 29d of non-display area TFTs 29, which will be described later. The protection film 37 is formed at least on the oxide semiconductor film 36. The protection film 37 is made of silicon oxide (SiO2).
The second metal film 38 is formed at least on the protection film 37. The second metal film 38 is a multilayer film that includes a lower metal film 38a containing titanium (Ti) and an upper metal film 38b contacting copper (Cu). In comparison to a configuration in which the second metal film is a multilayer film of titanium and aluminum (Al), the wiring resistance is lower and thus higher electrical conductivity is achieved. The first interlayer insulator 39 is formed on at least on the second metal film 38. The first interlayer insulator 39 has a multilayer structure including a lower first interlayer insulator (a lower insulator) 39a and an upper first interlayer insulator (an upper insulator) 39b. The lower first interlayer insulator 39a contains at least silicon and oxygen. The upper first interlayer insulator 39b contains at least silicon and nitrogen. The first interlayer insulator 39 will be described in more detail later. The organic insulator 40 is formed on the first interlayer insulator 39. The organic insulator 40 is made of acrylic resin (e.g., polymethyl methacrylate (PMMA)), which is an organic material, and functions as a planarization film.
The first transparent electrode film 23 is formed on the organic insulator 40. The first transparent electrode film 23 is made of transparent electrode material such as indium tin oxide (ITO) and zinc oxide (ZnO). The second interlayer insulator 41 is formed at least on the first transparent electrode film 23. The second interlayer insulator 41 is made of silicon nitride (SiNx). A pattern on the second interlayer insulator 41 in a plan view is equal to a pattern on the first interlayer insulator 39, which will be described in detail later. The second transparent electrode film 24 is formed at least on the second interlayer insulator 41. The second transparent electrode film 24 is made of transparent electrode material such as indium tin oxide (ITO) and zinc oxide (ZnO). The first transparent electrode film 23 and the second transparent electrode film 24 among the films are formed only in the display area AA of the array board 11b, that is, are not formed in the non-display area NAA. The insulators 35, 37, 39, 41 made of insulating materials including the gate insulator 35, the protection film 37, the first interlayer insulator 39, and the second interlayer insulator 41 are formed in solid patterns (although holes are formed in some areas) disposed in a whole area of the surface of the array board 11b. The first metal film 34, the oxide semiconductor film 36, and the second metal film 38 are formed in predetermined patterns in the display area AA and the non-display area NAA of the array board 11b.
Next, configurations of components in the display area AA of the array board 11b will be described in sequence. As illustrated in
As illustrated in
As illustrated in
Each pixel electrode 18 is formed from the second transparent electrode film 24. The pixel electrode 18 has a vertically-long rectangular overall shape in a plan view and disposed in an area defined by the gate lines 19 and the source lines 20. The pixel electrode 18 includes longitudinal slits (not illustrated), with which a comb-shaped portion is formed. As illustrated in
The common electrode 22 is formed from the first transparent electrode film 23. The common electrode 22 is a solid trace formed in a substantially whole area of the display area AA of the array board 11b. As illustrated in
Next, configurations of components in the display area AA of the CF board 11a will be described in detail. As illustrated in
Next, configurations of components in the non-display area NAA of the array board 11b will be described in detail. As illustrated in
As illustrated in
As illustrated in
As illustrated in
A stacking structure of each non-display area TFT 29 will be described. As illustrated in
The arrangement of the second gate electrode 29a, the second source electrode 29b, the second drain electrode 29c, the second channel 29d, and the second protection portion 29e of each non-display area TFT 29 in a plan view is similar to those of each display area TFT 17 described earlier and as illustrated in
As illustrated in
On the array board 11b according to this embodiment, each first interlayer insulator 39 that covers the second source electrode 29b, the second drain electrode 29c, and the second channel 29d in each non-display area TFT 29 from above has a multilayer structure including the lower first interlayer insulator 39a and the upper first interlayer insulator 39b. The lower first interlayer insulator 39a is disposed in the lower layer between the two. The lower first interlayer insulator 39a contains at least silicon and oxygen. The upper first interlayer insulator 39b is disposed in the upper layer between the two. The upper first interlayer insulator 39b contains at least silicon and nitrogen. With this configuration, the following functions and effects are achieved. The upper first interlayer insulator 39b of the first interlayer insulator 39 disposed in the upper layer contains at least silicon and nitrogen. Even if moisture enters into the non-display area TFT 29 from the outside because it is disposed closer to the sealing member 11j, the moisture is less likely to permeate the upper first interlayer insulator 39b. Therefore, the moisture is less likely to reach the second channel 29d formed from the oxide semiconductor film 36. The upper first interlayer insulator 39b contains silicon and nitrogen. During the formation of the upper first interlayer insulator 39b, hydrogen is generated in a process of forming the film by reaction of silane (SiH4) and ammonia (NH3). Namely, the upper first interlayer insulator 39b may take the moisture therein and the hydrogen may be desorbed depending on a thermal environment after the formation of the film. Even in such a case, because the lower first interlayer insulator 39a of the first interlayer insulator 39 disposed in the lower layer contains at least the silicon and the oxygen, the hydrogen desorbed from the upper first interlayer insulator 39b is less likely to permeate the lower first interlayer insulator 39a. Therefore, the desorbed hydrogen is less likely to reach the second channel 29d formed from the oxide semiconductor film 36. The second channel 29d formed from the oxide semiconductor film 36 is less likely to deteriorate due to the moisture taken into the second channel 29d and the electrical characteristics are less likely to change. Therefore, the malfunction of the non-display area TFT 29 is less likely to occur.
The upper first interlayer insulator 39b of the first interlayer insulator 39 according to this embodiment has a thickness in a range from 35 nm to 75 nm. Therefore, the amount of hydrogen desorbed from the upper first interlayer insulator 39b is reduced and a sufficient level of moisture resistance of the upper first interlayer insulator 39b is achieved. The electrical characteristics of the second channel 29d formed from the oxide semiconductor film. 36 are less likely to change and thus the non-display area TFT 29 is less likely to cause a malfunction. Because the non-display area TFT 29 is less likely to cause the malfunction, proper operation of the buffer circuit 26 is ensured. The liquid crystal panel 11 is less likely to have display defects and has high operation reliability. The second channel 29d of the non-display area TFT 29 includes the second extending portion 29d1 that is subject to irradiation of light. According to this configuration, a malfunction of the second channel 29d tends to occur. However, the malfunctions due to the moisture from the outside are less likely to occur as described above. Therefore, a sufficient level of the operation reliability is ensured. Furthermore, the protection film 37 (the second protection portion 29e) made of silicon oxide is disposed between the second source electrode 29b and the second channel 29d and the second drain electrode 29c and the second channel 29d. According to this configuration, the amount of hydrogen desorbed from the protection film 37 is reduced and thus the second channel 29d is less likely to take the hydrogen therein. Therefore, the malfunction of the non-display TFT 29 is less likely to occur. The second source electrode 29b and the second drain electrode 29c contain cupper and thus corrosion tends to occur due to the moisture. However, because permeation of the moisture is restricted by the upper first interlayer insulator 39b, the corrosion is reduced and thus the malfunction of the non-display area TFT 29 is less likely to occur. The lower first interlayer insulator 39a has a thickness larger than that of the upper first interlayer insulator 39b.
Compositions of the lower first interlayer insulator 39a and the upper first interlayer insulator 39b will be described in detail. The lower first interlayer insulator 39a may be made of silicon oxide (SiO2). The upper first interlayer insulator 39b may be made of silicon nitride (SiNx). The composition of the upper first interlayer insulator 39b is not limited to that contains only the silicon and the nitrogen. The composition may include other elements (oxygen). The upper first interlayer insulator 39b is configured such that a refractive index thereof varies according to a content of nitrogen. The refractive index tends to become smaller as the content of nitrogen decreases, and the refractive index tends to become larger as the content of nitrogen increases. Specifically, the composition of the upper first interlayer insulator 39b becomes closer to that of pure silicon nitride as the refractive index becomes closer to 2.0. The content of nitrogen decreases and a content of oxygen increases as the refractive index becomes farther from 2.0. Similarly, the composition of the lower first interlayer insulator 39a is not limited to that includes only silicon and oxygen. The composition may include elements other than the silicon and the oxygen (e.g., nitrogen). If the composition includes the nitrogen, the lower first interlayer insulator 39a has a relationship between the refractive index and the content of nitrogen similar to that in the upper first interlayer insulator 39b. The refractive index of the upper first interlayer insulator 39b according to this embodiment is in a range from 1.5 to 1.9. With this configuration, a sufficient level of moisture resistance is achieved and thus the electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36 are less likely to change. Furthermore, the formation of the film is easily performed by general fabrication equipment. The refractive index of the upper first interlayer insulator 39b according to this embodiment is in a range from 1.5 to 1.72. With this configuration, a content of hydrogen in the upper first interlayer insulator 39b further decreases and thus the content of hydrogen desorbed from the upper first interlayer insulator 39b decreases. Therefore, the electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36 are less likely to change due to the desorbed hydrogen.
The ranges of the thickness and the refractive index of the upper first interlayer insulator 39b in each non-display area TFT 29 included in the buffer circuit 26 have been described. The upper first interlayer insulators 39b are formed from the same material and with substantially even thickness for the entire surface of the array board 11b. The ranges of thicknesses and refractive indexes of the upper first interlayer insulators 39b in each non-display area TFT 29 in a circuit other than the buffer circuit 26 and in each display area TFT 17 in the display area AA are defined similar to the non-display area TFT 29 in the buffer circuit 26. Therefore, the same functions and effects are achieved.
<Comparative Experiments>
The thickness of the upper first interlayer insulator 39b is set in the range from 35 nm to 75 nm and the refractive index thereof is set in the range from 1.5 to 1.9, more preferably, from 1.5 to 1.73 in this embodiment based on results of comparative experiments 1 to 3. The comparative experiments 1 to 3 will be described. In comparative experiment 1, the refractive index of the upper first interlayer insulator 39b of the first interlayer insulator 39 in each non-display area TFT 29 was varied in a range from 1.475 to 1.9. Furthermore, amounts of desorbed moisture and desorbed hydrogen per one nm of thickness of the upper first interlayer insulator 39b were measured through thermal disportion spectroscopy (TDS). In comparative experiment 1, a comparative sample 1 including the upper first interlayer insulator 39b having a refractive index set to 1.475 was used. Furthermore, samples having the following refractive indexes were used. The refractive index was set to 1.51 in sample 1. The refractive index was set to 1.51 in sample 1. The refractive index was set to 1.53 in sample 2. The refractive index was set to 1.6 in sample 3. The refractive index was set to 1.60 in sample 4. The refractive index was set to 1.65 in sample 5. The refractive index was set to 1.72 in sample 6. The refractive index was set to 1.815 in sample 7. The refractive index was set to 1.9 in sample 8.
In comparative experiment 2, the thickness of the upper first interlayer insulator 39b of the first interlayer insulator 39 in the non-display area TFT 29 was varied in a range from 0 nm to 100 nm and current-voltage characteristics of the non-display area TFT 29 were measured. Specifically, in comparative experiment 2, the thickness of the upper first interlayer insulator 39b was set to 0 nm in comparative sample 1. The thickness was set to 25 nm in comparative sample 2. The thickness was set to 50 nm in sample 1. The thickness was set to 75 nm in sample 2. The thickness was set to 85 nm in comparative sample 3. The thickness was set to 100 nm in comparative sample 4. In comparative sample 1, the upper first interlayer insulator 39b was removed from the first interlayer insulator 39, that is, the first interlayer insulator 39 included only the lower first interlayer insulator 39a. In the comparative samples and the samples in comparative experiment 2, the thicknesses of the lower first interlayer insulators 39a were all set to 265 nm.
In comparative experiment 3, the thickness of the upper first interlayer insulator 39b of the first interlayer insulator 39 in the non-display area TFT 29 was varied and images of cross-sectional configurations were captured by an electron microscope such as a scanning electron microscope (SEM). Specifically, in comparative experiment 2, the thickness T1 of the upper first interlayer insulator 39b in comparative sample 1 was set to 25 nm. In sample 1, the thickness T2 is set to 35 nm. In comparative sample 1 and sample 1 in comparative experiment 3, the thicknesses of the lower first interlayer insulators 39a were all set to 150 nm. The images captured in comparative experiment 3 are provided in
Next, results of the comparative experiments will be described. Regarding comparative experiment 1,
From the graph in
Regarding comparative experiment 2, the non-display area TFTs 29 in comparative samples 3 and 4 do not have threshold voltages and switching properties as transistors according to the graph in
Regarding comparative experiment 3, the thickness T1 of the upper first interlayer insulator 39b in comparative sample 1 is equal to or smaller than 25 nm. The picture in
As described above, the liquid crystal panel (a display device) 11 according to this embodiment includes the array board (a substrate) 11b, the display area TFTs (display area transistors) 17, the non-display area TFTs (non-display area transistors) 29, and the first interlayer insulators 39. The array board 11b includes the display area AA and the non-display area NAA. The display area AA is located inner and the non-display area NAA is located outer so as to surround the display area AA. The display area TFTs 17 are disposed in the display area AA. The non-display area TFTs 29 are disposed in the non-display area NAA. Each non-display area TFT 29 includes the second gate electrode (a gate electrode) 29a, the second channel 29d, the second source electrode (a source electrode) 29b, and the second drain electrode (a drain electrode) 29c. At least a portion of the second channel 29d overlaps the second gate electrode 29a in a plan view. The second channel 29d is formed from the oxide semiconductor film 36. At least a portion of the source electrode 29b is layered on the second channel 29d formed from the oxide semiconductor film 36 and connected to the second channel 29d formed from the oxide semiconductor film 36. At least a portion of the second drain electrode 29c is layered on the second channel 29d formed from the oxide semiconductor film 36 and connected to the second channel 29d formed from the oxide semiconductor film 36 with a gap between the second source electrode 29b and the second drain electrode 29c. The first interlayer insulator 39 is layered at least on the second source electrode 29b and the second drain electrode 29c. The first interlayer insulator 39 has the multilayer structure including the lower first interlayer insulator (a lower insulator) 39a and the upper first interlayer insulator (an upper insulator) 39b. The lower first interlayer insulator 39a is disposed in the lower layer. The lower first interlayer insulator 39a contains at least silicon and oxygen. The upper first interlayer insulator 39b is disposed in the upper layer. The upper first interlayer insulator 39b contains at least silicon and nitrogen. The thickness of the upper first interlayer insulator 39b is in the range from 35 nm to 75 nm.
According to this configuration, in each non-display area TFT 29, when a voltage is applied to the second gate electrode 29a, a current starts flowing between the second source electrode 29b and the second drain electrode 29c via the second channel 29d formed from the oxide semiconductor film 36. The second channel 29d formed from the oxide semiconductor film 36 has higher electron mobility in comparison to the amorphous silicon thin film. Therefore, this configuration is preferable for passing a larger current between the second source electrode 29b and the second drain electrode 29c.
According to the configuration of the array board 11b in which the non-display area NAA is arranged outer so as to surround the display area AA arranged inner, the non-display area TFTs 29 in the non-display area NAA are more likely to be affected by the moisture from the outside in comparison to the display area TFTs 17 in the display area AA. If the second channel 29d formed from the oxide semiconductor film 36 in each non-display area TFT 29 takes the moisture therein and the second channel 29d is deteriorated, the electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36 change. As a result, a malfunction of the non-display area TFT 29 may occur.
The first interlayer insulator 39 is layered at least on the second source electrode 29b and the second drain electrode 29c. The first interlayer insulator 39 has the multilayer structure including the lower first interlayer insulator 39a and the upper first interlayer insulator 39b. The lower first interlayer insulator 39a is disposed in the lower layer. The lower first interlayer insulator 39a contains at least silicon and oxygen. The upper first interlayer insulator 39b is disposed in the upper layer. The upper first interlayer insulator 39b contains at least silicon and nitrogen. With the upper first interlayer insulator 39b, the moisture from the outside is less likely to reach the second channel 29d formed from the oxide semiconductor film 36. Furthermore, even if the upper first interlayer insulator 39b contains hydrogen during the formation of the film and the hydrogen is desorbed from the upper first interlayer insulator 39b, the hydrogen desorbed from the upper first interlayer insulator 39b is restricted by the lower first interlayer insulator 39a from reaching the second channel 29d formed from the oxide semiconductor film 36. Therefore, the deterioration of the second channel 29d formed from the oxide semiconductor film 36 due to the moisture and the hydrogen taken into the second channel 29d is less likely to occur and the electrical characteristics of the second channel 29d are less likely to change. As a result, the malfunction of the non-display area TFT 29 is less likely to occur.
If the thickness of the upper first interlayer insulator 39b is larger than 75 nm, a large amount of hydrogen is contained in the upper first interlayer insulator 39b during the formation of the upper first interlayer insulator 39b. Furthermore, the amount of hydrogen desorbed from the upper first interlayer insulator 39b tends to increase. Therefore, the second channel 29d formed from the oxide semiconductor film 36 may be deteriorated by the hydrogen desorbed from the upper first interlayer insulator 39b and the electrical characteristics thereof are more likely to change. If the thickness of the upper first interlayer insulator 39b is smaller than 35 nm, the coverage of the upper first interlayer insulator 39b to the lower first interlayer insulator 39a decreases. The cracks (gaps) are more likely to be created and thus the moisture resistance decreases. As a result, the second channel 29d formed from the oxide semiconductor film 36 is more likely to take the moisture therein. When the thickness of the upper first interlayer insulator 39b is in the range from 35 nm to 75 nm, the amount of hydrogen desorbed from the upper first interlayer insulator 39b is small. The sufficient moisture resistance of the upper first interlayer insulator 39b is provided and the electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36 are less likely to change. Therefore, the malfunction of the non-display area TFT 29 is less likely to occur. Because the upper first interlayer insulator 39b has the sufficient moisture resistance, the second source electrode 29b and the second drain electrode 29c are less likely to be corroded by the moisture.
The refractive index of the upper first interlayer insulator 39b of the first interlayer insulator 39 is in the range from 1.5 to 1.9. The refractive index of the upper first interlayer insulator 39b varies according to the composition. Specifically, if the content of the nitrogen decreases, the refractive index tends to decrease. If the content of the nitrogen increases, the refractive index tends to increase. If the refractive index of the upper first interlayer insulator 39b is equal to or smaller than 1.5, the content of nitrogen is small and thus the moisture resistance is low. Namely, the moisture is more likely to enter the second channel 29d formed from the oxide semiconductor film 36, which may results in adverse effect on the electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36. If the refractive index of the upper first interlayer insulator 39b is equal to or larger than 1.9, the content of nitrogen is large and thus it may be difficult to form the film by general fabrication equipment. If the refractive index of the upper first interlayer insulator 39b is in the range from 1.5 to 1.9, the sufficient moisture resistance is ensured. The electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36 are less likely to change and thus the film is easily formed by general fabrication equipment.
The refractive index of the upper first interlayer insulator 39b of the first interlayer insulator 39 is in the range from 1.5 to 1.72. During the formation of the film, the content of hydrogen in the upper first interlayer insulator 39b tends to increase as the content of hydrogen in the upper first interlayer insulator 39b increases. The upper limit of the refractive index of the upper first interlayer insulator 39b is 1.72. The content of hydrogen in the upper first interlayer insulator 39b is small and thus the amount of hydrogen desorbed from the upper first interlayer insulator 39b is small. Therefore, the electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36 are less likely to change due to the hydrogen desorbed from the upper first interlayer insulator 39b.
The liquid crystal panel 11 further includes the CF board (a counter substrate) 11a, the liquid crystal layer (liquid crystals) 11c, and the sealing member 11j. The CF board 11a is apposite the array board 11b. The liquid crystal layer 11c is sandwiched between the array board 11b and the CF board 11a. The sealing member 11j is between the array board 11b and the CF board 11a. The sealing member 11j is disposed so as to surround the liquid crystal layer 11c and seals the liquid crystal layer 11c. The non-display area TFTs 29 are arranged closer to the sealing member 11j with respect to the display area TFTs 17. The liquid crystal layer 11c between the array board 11b and the CF board 11a is sealed by the sealing member 11j disposed between the array board 11b and the CF board 11a so as to surround the liquid crystal layer 11c. The non-display area TFTs 29 are arranged closer to the sealing member 11j with respect to the display area TFTs 17 and thus more likely to be subject to the moisture from the outside and permeated through the seating member 11j. As described above, the first interlayer insulator 39 has the multilayer structure including the upper first interlayer insulator 39b and the lower first interlayer insulator 39a. Furthermore, the thickness of the upper first interlayer insulator 39b is in the range from 35 nm to 75 nm. Therefore, the moisture permeated through the sealing member 11j is less likely to be taken into the second channel 29d formed from the oxide semiconductor film 36 in each non-display area TFT 29. According to this configuration, the malfunctions of the non-display area TFTs 29 are less likely to occur.
The second channel 29d formed from the oxide semiconductor film 36 includes the second extending portion (an extending portion) 29d1. The second extending portion 29d1 projects toward the opposite direction to the second source electrode 29b at the position at which the second drain electrode 29c is connected. At least a portion of the extending portion 29d1 does not overlap the second gate electrode 29a in a plan view. The second channel 29d formed from the oxide semiconductor film 36 has such a configuration. Namely, the second channel 29d includes the second extending portion 29d1 that projects toward the opposite direction to the second source electrode 29b at the position at which the second drain electrode 29c is connected. Because the portion of the second extending portion 29d1, which does not overlap the second gate electrode 29a in a plan view, the light from the outside toward the non-overlapping portion of the second extending portion 29d1 is less likely to be blocked by the second gate electrode 29a. Namely, the non-overlapping portion is more likely to be subject to the irradiation of the light and thus the electrical characteristics thereof may degrade. Specifically, the second channel 29d formed from the oxide semiconductor film 36 has characteristics that the charge transferability is more likely to be affected when the second channel 29d receives optical energy. During driving of the non-display area TFT 29, the non-overlapping portion of the second extending portion 29d1 may be more likely to be charged. In addition to such a problem, the electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36 may change due to the moisture and the hydrogen taken into the second channel 29d. If such a problem occurs, the malfunction of the non-display area TFT 29 is more likely to occur. However, the first interlayer insulator 39 has the multilayer structure including the upper first interlayer insulator 39b and the lower first interlayer insulator 39a. Furthermore, the thickness of the upper first interlayer insulator 39b is in the range from 35 nm to 75 nm. According to the configuration, the second channel 39d formed from the oxide semiconductor film 36 is less likely to take the moisture and the hydrogen therein. Therefore, the malfunction of the non-display TFT 29 is less likely to occur.
Each non-display area TFT 29 further includes the second protection portion 29e formed from the protection film 37 for protecting the second channel 29d formed the oxide semiconductor film 36. The second protection portion 29e includes a pair of the second holes (holes) 29e1, 29e2. The second holes 29e1, 29e2 are located between the second source electrode 29b and the second channel 29d and between the second drain electrode 29c and the second channel 29d, respectively. The second holes 29e1, 29e2 are formed at the positions overlapping the second source electrode 29b and the second drain electrode 29c, respectively. The second source electrode 29b and the second drain electrode 29c are connected to the second channel 29d via the second holes 29e1, 29e2, respectively. With this configuration, when etching is performed during the formation of the second source electrode 29b and the second drain electrode 29c in the fabrication process, the second channel 29d is protected from being etched by the second protection portion 29e formed from the protection film 37 in the upper layer. In the fabrication process, the second channel 29d formed from the oxide semiconductor film 36 is protected by the second protection portion 29e formed from the protection film 37. The hydrogen is further less likely to enter the second channel 29d formed from the oxide semiconductor film 36 and thus the malfunction of the non-display area TFT 29 is less likely to occur. The second protection portion 29e formed from the protection film 37 includes a pair of the second holes 29e1, 29e2 formed at the positions overlapping the second source electrode 29b and the second drain electrode 29c in a plan view. The second source electrode 29b and the second drain electrode 29c are connected to the second channel 29d formed from the oxide semiconductor film 36 via the holes.
Each second protection portion 29e formed from the protection film 37 contains at least silicon and oxygen. The second protection portion 29e formed from the protection film 37 has such a configuration, that is, contains at least silicon and oxygen. According to the configuration, the amount of the hydrogen desorbed from the protection film 37 is small. Therefore, the second channel 28d formed from the oxide semiconductor film 36 is less likely to take the hydrogen therein and thus the malfunction of the non-display area TFT 29 is further less likely to occur.
Each second channel 29d formed from the oxide semiconductor film 36 contains at least indium, gallium, and zinc. Such a second channel 29d formed from the oxide semiconductor film 36 and containing at least indium, gallium, and zinc tends to deteriorate due to the moisture and the hydrogen. As described above, the first interlayer insulator 39 has the multilayer structure including the upper first interlayer insulator 39b and the lower first interlayer insulator 39a. Furthermore, the thickness of the upper first interlayer insulator 39b is in the range from 35 nm to 75 nm. According to the configuration, the second channel 29d formed from the oxide semiconductor film 36 is less likely to take the moisture and the hydrogen therein. Therefore, the malfunction of the non-display area TFT 29 is less likely to occur.
The liquid crystal panel 11 includes the gate lines (scan signal lines) 19 and the buffer circuit 26. The gate lines 29 are disposed in the display area AA and connected to the display area TFTs 17 to transmit the scan signals to the display area TFTs 17. The buffer circuit 26 is disposed in the non-display area NAA and connected to the gate lines 19. The buffer circuit 26 supplies the scan signals. The non-display area TFTs 29 are included in the buffer circuit 26. According to the configuration, the current that flows between the second source electrode 29b and the second drain electrode 29c in each non-display TFT 29 in the buffer circuit 26 is larger in comparison to the display area TFT 17. Therefore, if the second channel 29d deteriorates due to the moisture or the hydrogen taken therein and the electrical characteristics of the second channel 29d formed from the oxide semiconductor film 36 in the non-display area TFT 29 change, the malfunction of the second channel 29d is more likely to occur. As described above, the first interlayer insulator 39 has the multilayer structure including the upper first interlayer insulator 39b and the lower first interlayer insulator 39a. Furthermore, the thickness of the upper first interlayer insulator 39b is in the range from 35 nm to 75 nm. According to the configuration, the second channel 29d formed from the oxide semiconductor film 36 is less likely to take the moisture and the hydrogen therein. Therefore, the malfunctions of the non-display TFTs 29 in the buffer circuit 26 are less likely to occur.
Each of the second source electrodes 29b and the second drain electrodes 29c contains at least copper. In comparison to a configuration in which each of those containing aluminum, each of the second source electrodes 29b and the second drain electrodes 29c containing copper has higher electrical conductivity but tends to be corroded by the moisture. As described above, the first interlayer insulator 39 has the multilayer structure including the upper first interlayer insulator 39b and the lower first interlayer insulator 39a. Furthermore, the thickness of the upper first interlayer insulator 39b is in the range from 35 nm to 75 nm. According to the configuration, the moisture from the outside is less likely to permeate through the first interlayer insulator 39 and to reach the second source electrode 29b and the second drain electrode 29c. Therefore, the second source electrode 29b and the second drain electrode 29c are less likely to be corroded by the moisture.
A second embodiment according to the present invention will be described with reference to
As illustrated in
A third embodiment according to the present invention will be described with reference to
As illustrated in
The present invention is not limited to the embodiments described above and illustrated by the drawings. For examples, the following embodiments will be included in the technical scope of the present invention.
(1) In each of the above embodiments, the refractive index of the upper first interlayer insulator is in the range from 1.5 to 1.9. If production technologies improve and the upper first interlayer insulator having the refractive index equal to or higher than 1.9 is formable by general fabrication equipment, the refractive index of the upper first interlayer insulator may be set to 1.9 or higher.
(2) In each of the above embodiments, mixed gas of silane (SiH4) and ammonia (NH3) is used as an example in the formation of the upper first interlayer insulator. However, other mixed gas may be used. For example, mixed gas of silane (SiH4) and nitrogen (N2) may be used, or dichlorosilane (SiH2Cl2) may be used instead of silane (SiH4). Furthermore, mixed gas of silane, ammonia, and nitrogen may be used to form the upper first interlayer insulator.
(3) In each of the above embodiment, the non-display area TFTs disposed in the non-display area are configured to output scan signals at the final stage of the signal processing in the scanning circuits. However, the scope of the present invention is applicable to non-display area TFTs having other functions.
(4) Non-display area TFTs having different functions are disposed in the non-display area other than the non-display area TFTs in the buffer circuit. It is not necessary to limit thicknesses and refractive indexes of upper first interlayer insulators to the ranges described above. The liquid crystal panel may include the non-display area TFTs each including the upper first interlayer insulator having a thickness and a refractive index in the ranges described above and the non-display area TFTs each including the upper first interlayer insulator having a thickness and a refractive index out of the ranges.
(5) In each of the above embodiments, the thickness and the refractive index of the upper first interlayer insulator in each of the display area TFTs and the non-display area TFTs are within the ranges. However, the upper first interlayer insulator may be configured such that the thickness and the refractive index are out of the ranges.
(6) Each of the above embodiments includes the non-display area TFTs in the row control circuit disposed in the non-display area. The scope of the present invention is applicable to the non-display area TFTs in the column control circuit disposed in the non-display area.
(7) The arrangement and the number of the row control circuit on the array board may be altered from those of the above embodiments. For example, the row control circuit may be disposed adjacent to the display area on the right in
(8) The materials of the gate insulators, the protection films, the organic insulators, and the second interlayer insulators may be altered from those of the above embodiments as appropriate.
(9) The gate insulator in each of the above embodiments is the single layered film. However, the gate insulator may include multi layers made of different materials. For example, the gate insulator may have a multilayer structure including a lower gate insulator made of silicon nitride (SiNx) and an upper gate insulator made of silicon oxide (SiO2), which are layered in sequence opposite from the first interlayer insulator.
(10) In each of the above embodiments, the oxide semiconductor film is the oxide thin film that contains indium (In), gallium (Ga), and zinc (Zn). However, other types of oxide semiconductors may be used. Examples of oxides include an oxide that contains indium (In), silicon (Si), and zinc (Zn), an oxide that contains indium (In), aluminum (Al), and zinc (Zn), an oxide that contains tin (Sn), silicon (Si), and zinc (Zn), an oxide that contains tin (Sn), aluminum (Al), and zinc (Zn), an oxide that contains tin (Sn), gallium (Ga), and zinc (Zn), an oxide that contains gallium (Ga), silicon (Si), and zinc (Zn), an oxide that contains gallium (Ga), aluminum (Al), and zinc (Zn), an oxide that contains indium (In), copper (Cu), and zinc (Zn), and an oxide that contains tin (Sn), copper (Cu), and zinc (Zn).
(11) During formation of contact holes in the display transistor in each of the above embodiments, the first interlayer insulator and the organic insulator are etched using the second interlayer insulator having the hole as a resist. However, the holes of the first interlayer insulator, the organic insulator, and the second interlayer insulator may be formed, respectively, by patterning during formation thereof. The arrangement of the contact holes in a plan view may be altered as appropriate.
(12) Each of the above embodiments includes the liquid crystal panel that includes the FFS mode or the VA mode as an operation mode. However, the scope of the present invention is applicable to other liquid crystal panels that include an in-plane switching (IPS) mode as an operation mode.
(13) In the liquid crystal panel in each of the above embodiments, the display area is arranged medially with respect to the short-side direction but closer to one of the ends with respect to the long-side direction. However, the display area of the liquid crystal panel may be arranged medially with respect to the long-side direction but closer to one of the ends with respect to the short-side direction. The display area of the liquid crystal panel may be arranged closes to one of the ends with respect to the long-side direction and to one of the ends with respect to the short-side direction. The display area of the liquid crystal panel may be arranged medially with respect to the long-side direction and at the middle with respect to the short-side direction.
(14) Each of the above embodiments includes the second metal film that is formed from a multilayer film of titanium (Ti) and copper (Cu). However, the following materials may be used instead of titanium: molybdenum (Mo), molybdenum nitride (MoN), titanium nitride (TiN), tungsten (W), niobium (Nb), molybdenum-titanium alloy (MoTi), and molybdenum-tungsten (MoW) alloy. Furthermore, aluminum (Al) may be used instead of copper. Still furthermore, a single-layered metal film such as a titanium film, a cupper film, or an aluminum film may be used.
(15) Each of the above embodiments includes the driver that is directly mounted on the array board through the COG method. A driver that is mounted on a flexible printed circuit board that is connected to the array board via an ACF is also included in the scope of the present invention.
(16) Each of the above embodiments includes the column control circuit and the row control circuit dispose in the non-display area of the array board. However, any one of the column control circuit and the row control circuit may be omitted, and the driver may be configured to perform the functions of the omitted circuit.
(17) Each of the above embodiments includes the liquid crystal panel having a vertically-long rectangular shape. However, liquid crystal panels having a horizontally-long rectangular shape of a square shape are also included in the scope of the present invention.
(18) Each of the above embodiments may further include a functional panel that are layered on and attached to the liquid crystal panel, such as a touch panel and a parallax barrier panel (a switching liquid crystal panel). Furthermore, a liquid crystal panel including touch panel patterns directly formed thereon is also included in the scope of the present invention.
(19) The liquid crystal display device according to the above embodiments includes the edge-light type backlight unit. However, the liquid crystal display device may include a direct backlight unit.
(20) The transmission type liquid crystal display devices each including the backlight unit, which is an external light source, are described as the embodiments. However, reflection type liquid crystal display devices that use outside light to display images are also included in the scope of the present invention. The reflection type liquid crystal display devices do not require backlight units.
(21) Each of the above embodiments includes the TFTs as switching components of the liquid crystal display device. However, liquid crystal display devices that include switching components other than TFTs (e.g., thin film diodes (TFDs)) may be included in the scope of the present invention. Furthermore, black-and-white liquid crystal display devices, other than color liquid crystal display device, are also included in the scope of the present invention.
(22) The liquid crystal display devices including the liquid crystal panels as the display panels are described as the embodiments. However, display devices that include other types of display panels (e.g., plasma display panels (PDPs) and organic EL panels) are also included in the scope of the present invention. Such display devices do not require backlight units.
(23) The above embodiments include the liquid crystal panels that are classified as small sized or small to middle sized panels. Such liquid crystal panels are used in electronic devices including PDAs, mobile phones, notebook computers, digital photo frames, portable video games, and electronic ink papers. However, liquid crystal panels that are classified as middle sized or large sized (or supersized) panels having screen sizes from 20 inches to 90 inches are also included in the scope of the present invention. Such display panels may be used in electronic devices including television devices, digital signage, and electronic blackboard.
(24) In the first and the second embodiments, the first channel of each display area TFT includes the first extending portion that does not overlap the first gate electrode in a plan view. The second channel of each non-display area TFT includes the second extending portion that does not overlap the second gate electrode in a plan view. While the first channel of each display area TFT may have the same arrangement as the first and the second embodiment, each non-display area TFT may include the second channel, an entire area of which is over the second gate electrode in a plan view (i.e., the same arrangement as the third embodiment). While the second channel of each non-display area TFT may have the same arrangement as the first and the second embodiment, each display area TFT may include the first channel, an entire area of which is over the first gate electrode (i.e., the same arrangement as the third embodiment).
(25) The gate electrode of each TFT in the first and the second embodiments includes the gate electrode that is branched off the gate line and the channel that includes the extending portion overlapping the gate electrode in a plan view. The channel may be configured such that an entire area thereof overlaps the gate electrode that is branched off the gate line. This configuration is applicable to one of the display area TFT and the non-display area TFT or to both of them. If the configuration is applied to one of the display area TFT and the non-display area TFT, the TFTs to which the configuration may have not applied may be disposed similar to the first and the second embodiment.
(26) The first metal film in each of the above embodiment is the single layer film of copper (Cu). Titanium (Ti) or aluminum (Al) may be used instead of copper. The first metal film may be a multilayer film of titanium (Ti) and copper (Cu), similar to the second metal film. If the first metal film is the multilayer film, molybdenum (Mo), molybdenum nitride (MoN), titanium nitride (TiN), tungsten (W), niobium (Nb), molybdenum-titanium alloy (MoTi), and molybdenum-tungsten (MoW) alloy may be used instead of titanium in the lower layer.
Number | Date | Country | Kind |
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2012-255514 | Nov 2012 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2013/080752 | 11/14/2013 | WO | 00 |