Patent Application
20230176264
The present invention relates to a display device, and a cover member included in the display device.
Patent Literature 1 discloses a vehicle-mounted display device. In this display device, a cover glass is fixed to the surface of a display panel via an adhesive layer, thereby improving the adhesion between the display panel and the cover glass.
Patent Literature 1: Japanese Patent No. 6418241
Clearness is required of a display device to allow display on a display panel to be clearly seen. However, such a requirement for clearness has not been met, and further improvement is desired. The present invention was made in order to solve the aforementioned problem, and it is an object thereof to provide a display device capable of improving clearness, and a cover member included in the display device.
Item 1. A display device including:
a display panel; and
a cover member arranged on the display panel,
wherein the cover member includes:
Item 2. The display device according to item 1,
wherein the optical layer contains at least a matrix and particles, and
the particles form protrusions and depressions on a surface of the optical layer on a side opposite to the second surface.
Item 3. The display device according to item 1 or 2, wherein the optical layer includes a first region in which the particles are piled up in a thickness direction of the layer, and a valley-shaped second region that surrounds the first region or is surrounded by the first region.
Item 4. The display device according to item 3, wherein the first region is a plateau-shaped region.
Item 5. The display device according to item 3 or 4, wherein the second region includes a portion in which the particles are not piled up or the particles are not present.
Item 6. The display device according to any one of items 3 to 5, wherein the first region has a width of 7.7 μm or more, and the second region has a width of 7 μm or more.
Item 7. The display device according to item 6, wherein the first region has a width of 10 μm or more, and the second region has a width of 10 μm or more.
Item 8. The display device according to item 1 or 2,
wherein the particles are substantially composed of plate-shaped particles,
each of the plate-shaped particles has a thickness within a range of 0.3 nm to 3 nm and a main surface average diameter within a range of 10 nm to 1,000 nm, and
the main surfaces of the plate-shaped particles are oriented substantially in parallel with the second surface of the glass plate.
Item 9. The display device according to item 1 or 2, wherein the optical layer includes a region in which the particles are piled up in a thickness direction of the optical layer, and a region in which the particles are not piled up or the particles are not present.
Item 10. The display device according to item 9, wherein a difference in height measured from the second surface of the glass plate between the highest portion and the lowest portion of the optical layer is three times or more as large as the average particle diameter of the particles.
Item 11. The display device according to item 9 or 10, wherein Smr1 defined in ISO25178 is 10 to 30%.
Item 12. The display device according to any one of items 9 to 11, wherein a surface height BH20 at a load area ratio of 20% defined in ISO25178 is within a range of 0.04 μm to 0.5 μm.
Item 13. The display device according to any one of items 9 to 12, wherein a surface height BH80 at a load area ratio of 80% defined in ISO25178 is within a range of −0.3 μm to 0 μm.
Item 14. The display device according to any one of items 3 to 7 and 9 to 13, wherein the particles are substantially composed of spherical particles.
Item 15. The display device according to any one of items 1 to 14,
wherein the surface of the optical layer has an Rsm of more than 0 μm to 35 μm or less,
the Rsm being an average length of roughness curve elements determined in accordance with JIS B0601: 2001.
Item 16. The display device according to any one of items 1 to 15,
wherein the surface of the optical layer has an Ra within a range of 20 nm to 120 nm,
the Ra being an arithmetic average roughness of a roughness curve determined in accordance with JIS B0601: 2001.
Item 17. The display device according to any one of items 1 to 16,
wherein the second surface of the glass plate has an Ra of 10 nm or less,
the Ra being an arithmetic average roughness of a roughness curve determined in accordance with JIS B0601: 2001.
Item 18. The display device according to any one of items 1 to 17, wherein the matrix contains silicon oxide as a main component.
Item 19. The display device according to any one of items 1 to 18, wherein the refractive index of the adhesive layer is larger than the refractive index of air and smaller than the refractive index of the glass plate.
Item 20. The display device according to any one of items 1 to 19, wherein the glass plate has a thickness of 0.5 to 3 mm.
Item 21. A cover member to be included in a display device having a display panel, including:
a glass plate having a first surface and a second surface;
an adhesive layer that is layered on the first surface of the glass plate and fixes the glass plate to the display panel; and
an optical layer that is layered on the second surface of the glass plate.
With the present invention, it is possible to improve clearness.
Hereinafter, an embodiment in which a display device according to the present invention is applied to a vehicle-mounted display device will be described with reference to the drawings.
1. Overview of Display Device
As shown in
2. Housing
The housing 4 includes a rectangular bottom wall portion 41, and a side wall portion 42 that rises from the peripheral edge of the bottom wall portion 41, and the above-described display panel 500 and backlight unit 6 are housed in the internal space surrounded by the bottom wall portion 41 and the side wall portion 42. The above-described cover member 100 is attached so as to cover the opening formed by the upper end portion of the side wall portion 42. Although the material of the housing 4 is not particularly limited, the housing 4 can be formed using, for example, a resin material, metal, or the like.
3. Display Panel and Backlight Unit
A known liquid crystal panel can be used as the display panel 500. The backlight unit 6 is configured to emit light toward the liquid crystal panel, and some backlight units formed by layering a diffusion sheet, a light-guiding plate, a light source such as an LED, a reflection sheet, and the like are known. Note that an organic EL panel, a plasma display panel, an electronic ink-type panel, and the like can be employed as the display panel 500 instead of a liquid crystal panel, for example. If the display panel 500 is constituted by a display panel other than a liquid crystal panel, there is no need to provide the backlight unit.
4. Cover Member
The cover member 100 includes a glass plate 10 having a first surface and a second surface, an adhesive layer 3 layered on the first surface of the glass plate 10, and an optical layer 20 layered on the second surface. A more detailed description will be given below.
4-1. Glass Plate
The glass plate 10 can be made of, for example, general-purpose soda-lime glass, borosilicate glass, aluminosilicate glass, alkali-free glass, or other types of glass. Moreover, the glass plate 10 can be formed using a known production process such as a float process or a down-draw process. These production processes make it possible to obtain a glass plate 10 having a flat and smooth surface. However, the glass plate 10 may have protrusions and depressions on a main surface thereof, and may be made of, for example, figured glass. Figured glass can be formed using a process known as a roll-out process. Figured glass that is formed using this production process usually has periodic protrusions and depressions in one direction along the main surface of the glass plate.
Although the thickness of the glass plate 10 is not particularly limited, a thin glass plate is better for weight reduction. For example, the thickness thereof is preferably 0.5 to 3 mm, and more preferably 0.6 to 2.5 mm. The reason for this is that, if the glass plate 10 is excessively thin, the strength is reduced, whereas, if the glass plate 10 is excessively thick, an image on the display panel 500 may be distorted when seen through the cover member 100. The surface roughness Ra of the second surface of the glass plate 10 is preferably 10 nm or less, more preferably 5 nm or less, even more preferably 2 nm or less, and particularly preferably 1 nm or less. With this configuration, in a case where an anti-glare film is used as the optical layer 20 as described later, anti-glare properties become prominent.
Typically, the glass plate 10 is preferably a flat plate, but may also be a curved plate. In particular, in the case where the image display surface of the display panel 500 to be combined with the glass plate 10 has a non-flat surface shape such as a curved surface, it is preferable that the glass plate 10 has a main surface with a non-flat surface shape that fits the non-flat surface shape of the image display surface. In this case, the entire glass plate 10 may be curved so as to have a certain curvature, or the glass plate 10 may be locally curved. A main surface 10s of the glass plate 10 may be constituted by, for example, a plurality of flat surfaces being connected via curved surfaces. The radius of curvature of the glass plate 10 is, for example, 5,000 mm or less. This radius of curvature is, for example, 10 mm or more, but in particular, a locally curved portion may have an even smaller radius of curvature (e.g., 1 mm or more).
The optical layer 20 may be configured to cover the second surface of the glass plate 10 entirely or partially. In the latter case, it is sufficient that the optical layer 20 is formed on at least a portion of the second surface that covers the image display surface of the display panel 500.
The glass plate 10 is preferably made of strengthened glass. The glass plate 10 may be strengthened through air-cooling strengthening treatment or chemical strengthening treatment, and chemical strengthening treatment is suitable for a thin glass plate 10. In the chemical strengthening treatment, the glass plate 10 is immersed in a molten salt containing alkali metal ions at a temperature lower than or equal to the strain point of glass constituting the glass plate, and thus alkali metal ions (e.g., sodium ions) in the surface layer of the glass plate 10 are substituted with alkali metal ions having a relatively large ion radius (e.g., potassium ions) to cause compressive stress in the surface layer of the glass plate 10. The chemical strengthening treatment may be performed on the glass plate 10 before or after the optical layer is formed. Moreover, the air-cooling strengthening treatment can also be performed in accordance with a known procedure.
4-2. Adhesive Layer
The adhesive layer 3 need only be capable of fixing the glass plate 10 to the display panel 500 with sufficient strength. Specifically, it is possible to use an adhesive layer constituted by a resin having tackiness at an ordinary temperature such as an acrylic resin, a rubber-based resin, or a resin having a desired glass transition temperature formed through copolymerization of a methacrylic monomer and an acrylic monomer. Examples of the acrylic monomer include methyl acrylate, ethyl acrylate, butyl acrylate, stearyl acrylate, and 2-ethylhexyl acrylate, and examples of the methacrylic monomer include ethyl methacrylate, butyl methacrylate, isobutyl methacrylate, and stearyl methacrylate. If the adhesive layer is applied through heat lamination or the like, an organic substance that softens at the lamination temperature may be used. When a resin formed through copolymerization of a methacrylic monomer and an acrylic monomer is used, the glass transition temperature thereof can be adjusted by changing the blend ratio of the monomers. The adhesive layer 71 may contain an ultraviolet absorber.
The thickness of the adhesive layer 3 can be set to, for example, 10 to 500 μm, and is preferably 20 to 350 μm. In particular, when the adhesive layer 3 has a small thickness, the distance from the display panel 500 to the outermost surface of the cover member 100 is small, and thus an image displayed on the display panel 500 can be clearly seen. On the other hand, it is not preferable that the thickness of the adhesive layer 3 is excessively small because the glass plate and the display panel 500 will be fixed to each other with reduced strength.
It is preferable that the refractive index of the adhesive layer 3 is larger than the refractive index of air and smaller than the refractive index of the glass plate 10. This makes it possible to suppress distortion of an image displayed on the display panel 500.
4-3. Optical Layer
Next, the optical layer will be described. Hereinafter, three types of anti-glare films will be described as examples of the optical layer. In the following description, the wording “substantially in parallel with” means that the angle formed between two planes of interest is 30° or less, 20° or less, or particularly 10° or less. The wording “main component” means a component that is contained in an amount of 50% or more or 80% or more in terms of mass. The wording “substantially composed of” means that a component is contained in an amount of 80% or more, 90% or more, or particularly 95% or more, in terms of mass. The wording “main surfaces” refers to surfaces on the front and back sides other than side surfaces, and more specifically to surfaces on which films are to be formed. The same applies to the “main surfaces” of a plate-like particle, and the wording “main surfaces” refers to a pair of surfaces on the front and back sides of the plate-shaped particle. The definition of “plateau-shaped” will be described later with reference to
4-3-1. First Anti-Glare Film
First, a first anti-glare film 20 will be described with reference to
4-3-1-1. Particles
The particles 1 may be plate-shaped particles. The particles 1 may be substantially composed of plate-shaped particles. Note that some of the particles 1 may have a shape other than a plate shape such as a spherical shape, but the particles 1 may include no spherical particles and the like and be composed of only plate-shaped particles.
The thickness 1t of the particle 1 corresponds to the distance between the pair of main surfaces 1s and is within a range of 0.3 nm to 3 nm. The thickness 1t is preferably 0.5 nm or more and more preferably 0.7 nm or more, and is also preferably 2 nm or less and more preferably 1.5 nm or less. In a case where the thickness 1t varies depending on location, it is sufficient that the average of the maximum thickness and the minimum thickness is taken as the thickness 1t.
The average diameter d of the main surface 1s of the particle 1 is within a range of 10 nm to 1,000 nm. The average diameter d of the main surface is preferably 20 nm or more, and more preferably 30 nm or more. Also, the average diameter d is preferably 700 nm or less, and more preferably 500 nm or less. The average of the minimum value and the maximum value of the values of diameters passing through the center of gravity of the main surface 1s can be taken as the average diameter d of the main surface 1s.
The average aspect ratio of the particle 1 can be calculated as d/t. Although the average aspect ratio is not particularly limited, it is preferably 30 or more, and more preferably 50 or more. The average aspect ratio may also be 1,000 or less, or 700 or less.
The particle 1 may be a phyllosilicate mineral particle. A phyllosilicate mineral contained in the phyllosilicate mineral particle is also called a layered silicate mineral. Examples of the phyllosilicate mineral include: kaolin minerals such as kaolinite, dickite, nacrite, and halloysite; serpentines such as chrysotile, lizardite, and amesite; dioctahedral smectites such as montmorillonite and beidellite; trioctahedral smectites such as saponite, hectorite, and sauconite; dioctahedral micas such as white mica, palagonite, illite, and celadonite; trioctahedral micas such as phlogopite, annite, and lepidolite; dioctahedral brittle micas such as margarite; trioctahedral brittle micas such as clintonite and anandite; dioctahedral chlorites such as donbassite; di-tri-octahedral chlorites such as cookeite and sudoite; trioctahedral chlorites such as clinochlore and chamosite; pyrophyllite; talc; dioctahedral vermiculite; and trioctahedral vermiculite. It is preferable that the phyllosilicate mineral particle contains a mineral belonging to smectites, kaolins, and talc. Among minerals belonging to smectites, montmorillonite is favorable. Note that montmorillonite belongs to the monoclinic system, kaolins belong to the triclinic system, and talc belongs to the monoclinic system or triclinic system.
In the anti-glare film 20, the main surfaces 1s of the particles 1 are oriented substantially in parallel with the second surface of the glass plate 10. The particles 1 are considered to be oriented substantially in parallel as a whole as long as 80% or more, 85% or more, or particularly 90% or more, of the particles in terms of the number of particles are oriented substantially in parallel, even if the rest of particles are not oriented substantially in parallel. When it is determined whether or not the particles 1 are arranged substantially in parallel, it is desirable to confirm the orientations of thirty, preferably fifty, plate-shaped particles.
In the case where the particle 1 is a phyllosilicate mineral particle, the (001) plane among the crystal planes of the phyllosilicate mineral may be oriented along the second surface of the glass plate 10. Such a plane orientation can be confirmed through X-ray diffraction analysis.
4-3-1-2. Matrix
It is preferable that the matrix 2 contains silicon oxide, which is an oxide of Si, as the main component. The matrix 2 containing silicon oxide as the main component is suitable for reducing the refractive index of the film and reducing the reflectivity of the film. The matrix 2 may also contain other components in addition to silicon oxide, and may also contain a component that contains silicon oxide as a portion thereof.
The component that contains silicon oxide as a portion thereof is, for example, a component that includes a portion constituted by silicon atoms and oxygen atoms and in which an atom other than a silicon atom and an oxygen atom, a functional group, or the like is linked to a silicon atom or oxygen atom in this portion. Examples of the atom other than a silicon atom and an oxygen atom include a nitrogen atom, a carbon atom, a hydrogen atom, and metallic elements listed in the next paragraph. Examples of the functional group include organic groups that are listed as R in a paragraph below. Strictly speaking, such a component is not silicon oxide because it is not composed only of a silicon atom and an oxygen atom. However, in describing the characteristics of the matrix 2, treating a silicon oxide portion that is composed of a silicon atom and an oxygen atom as a “silicon oxide” is appropriate and is also consistent with usage in the field. In this specification, the silicon oxide portion is also treated as a silicon oxide. As is clear from the above description, the atomic ratio between silicon atoms and oxygen atoms in a silicon oxide need not be stoichiometric (1:2).
The matrix 2 can contain a metal oxide other than silicon oxide, or specifically, a metal oxide component or a metal oxide portion that contains an element other than silicon. Although metal oxides that can be contained in the matrix 2 are not particularly limited, examples thereof include oxides of at least one metallic element selected from the group consisting of Ti, Zr, Ta, Nb, Nd, La, Ce, and Sn. The matrix 2 may contain an inorganic compound component other than an oxide, examples of which include a nitride, a carbide, and a halide, or may contain an organic compound component.
A metal oxide such as silicon oxide can be formed from a hydrolyzable organic metal compound. An example of a hydrolyzable silicon compound is a compound represented by Formula (1).
RnSiY4-n (1)
R is an organic group including at least one selected from an alkyl group, a vinyl group, an epoxy group, a styryl group, a methacryloyl group, and an acryloyl group. Y is a hydrolyzable organic group that is at least one selected from an alkoxy group, an acetoxy group, an alkenyloxy group, and an amino group, or a halogen atom. The halogen atom is preferably Cl. n is an integer from 0 to 3 and is preferably 0 or 1.
R is preferably an alkyl group. For example, an alkyl group having 1 to 3 carbon atoms is preferable, and a methyl group is particularly preferable. Y is preferably an alkoxy group. For example, an alkoxy group having 1 to 4 carbon atoms is preferable, and a methoxy group and an ethoxy group are particularly preferable. Two or more compounds represented by the formula above may also be used in combination. As an example of this combination, a tetraalkoxysilane, where n is 0, and a monoalkyltrialkoxysilane, where n is 1, may be used together.
After hydrolysis and polycondensation, the compound represented by Formula (1) forms a network structure in which silicon atoms are linked to one another via oxygen atoms. In this structure, the organic groups represented by R are contained in a state of being directly linked to silicon atoms.
4-3-1-3. Physical Properties of First Anti-Glare Film
The ratio of the particles 1 to the matrix 2 in the anti-glare film 20 in terms of mass is, for example, 0.05 to 10, 0.05 to 7, or preferably 0.05 to 5. Although the volume ratio of the voids in the anti-glare film 20 is not particularly limited, it may be 10% or more, or 10 to 20%. However, the voids need not necessarily be present.
Although the thickness of the anti-glare film 20 is not particularly limited, it is suitable that the anti-glare film 20 has a thickness of, for example, 50 nm to 1,000 nm, 100 nm to 700 nm, or particularly 100 nm to 500 nm, from the viewpoint that the anti-glare properties are likely to be appropriately obtained, for example. It is preferable that the anti-glare film 20 has a thickness that is smaller than or equal to the above-described upper limit in order to orient the main surfaces of the plate-shaped particles substantially in parallel with a substrate. In the case of a thick film, there is a strong tendency for plate-shaped particles to be oriented in a random manner.
It is preferable that minute protrusions and depressions are present on a surface 20s of the anti-glare film 20. The anti-glare properties can be expected to be increased due to the minute protrusions and depressions. However, the development of the protrusions and depressions on the surface 20s is suppressed due to the particles 1 being oriented along the second surface of the glass plate 10. The surface roughness of the surface 20s of the anti-glare film 20, which is determined as Ra, is 20 nm to 120 nm, 30 nm to 110 nm, or preferably 40 nm to 100 nm. Ra is the arithmetic average roughness of a roughness curve determined in accordance with JIS B0601: 2001. For example, if particles are oriented in a random manner, the surface roughness Ra will be larger than the above-described range.
The surface 20s has an Rsm of more than 0 μm and 35 μm or less, 1 μm to 30 μm, or preferably 2 μm to 20 μm. Rsm is the average length of roughness curve elements determined in accordance with JIS B0601: 2001. If Rsm is not excessively large, the appearance of what is known as sparkles can be favorably suppressed.
Sparkles are bright spots that appear depending on the relationship between the minute protrusions and depressions for imparting the anti-glare properties and the pixel size of the display panel 500. The sparkles are observed as light that irregularly flickers with a change in the relative positions between a display device and the user's eyes. The sparkles have become apparent with an increase in resolution of display devices. The anti-glare film 20 having an Ra and an Rsm that are within the above-described ranges is particularly suitable for reducing gloss and haze with good balance while suppressing the appearance of sparkles.
4-3-1-4. Optical Properties of Cover Member
The gloss can be evaluated based on the specular gloss. The 60° specular gloss of the glass plate 10 is, for example, 60 to 130%, 70 to 120%, or particularly 80 to 110%. These specular gloss values are measured on the surface 10s on which the anti-glare film 20 is formed. The haze ratio of the glass plate 10 is, for example, 20% or less, 15% or less, or particularly 10% or less, or may be 1 to 8%, 1 to 6%, or particularly 1 to 5%, in certain cases.
The 60° specular gloss G and the haze ratio H (%) preferably satisfy Relational Expression (a), more preferably Relational Expression (b), and even more preferably Relational Expression (c). G and H may satisfy Relational Expression (d).
H≤−0.2G+25 (a)
H≤−0.2G+24.5 (b)
H≤−0.2G+24 (c)
H≤−0.15G+18 (d)
Note that the gloss can be measured in conformity with “Method 3 (Specular gloss at 60 degrees)” of “Specular glossiness—Methods of measurement” in JIS Z8741-1997, and the haze can be measured in conformity with JIS K7136: 2000.
4-3-2. Second Anti-Glare Film
Next, a second anti-glare film will be described with reference to
In the anti-glare film 30, the particles 5 are piled up in the thickness direction of the film in all the regions, whereas the anti-glare film 40 includes a region 40a in which the particles 5 are piled up in the thickness direction of the film and a region 40b in which the particles 5 are not piled up in that direction or the particles 5 are not present. The region 40b may be a region having a surface 40s that is substantially in parallel with the second surface of the glass plate 10 and from which the particles 5 are not exposed, instead of a region in which the particles 5 are not piled up in that direction or the particles 5 are not present. The region 40b may spread over, for example, 0.25 μm2 or more, 0.5 μm2 or more, or particularly 1 μm2 or more. Note that, in at least some of the regions 40a of the anti-glare films 30 and 40, the particles 5 are piled up to a height that is 5 times or more, or 7 times or more, as high as the average particle diameter of the particles 5.
4-3-2-1. Particles
Although the shape of the particle 5 is not particularly limited, a spherical shape is preferable. The particles 5 may be substantially composed of spherical particles. However, some of the particles 5 may have a shape other than a spherical shape such as a plate shape. The particles 5 may be composed of only spherical particles. Here, the spherical particles are particles in which a ratio of the longest diameter passing through the center of gravity to the shortest diameter passing through the center of gravity is 1 or more and 1.8 or less, or particularly 1 or more and 1.5 or less, and its surface is constituted by a curved surface. The average particle diameter of the spherical particles may be 5 nm to 200 nm, 10 nm to 100 nm, or particularly 20 nm to 60 nm. The average particle diameter of the spherical particles is determined as an average of the diameters of the particles (specifically, the diameter of the particle is an average value of the above-described shortest diameter and longest diameter), and it is desirable that the average particle diameter is determined using thirty, preferably fifty, particles based on an SEM image.
Preferable ranges of the thickness t, main surface average diameter d, and aspect ratio d/t of a plate-shaped particle that may be included as a portion of the particles 5 are the same as those in the case of the first anti-glare film.
Although a material for forming the particles 5 is not particularly limited, it is preferable that a metal oxide, particularly silicon oxide. However, the metal oxide may include an oxide of at least one metallic element selected from the group consisting of Ti, Zr, Ta, Nb, Nd, La, Ce, and Sn, for example.
The particles 5 can be supplied to the anti-glare films 30 and 40 from a dispersion liquid of particles 5. In this case, it is preferable to use a dispersion liquid in which the particles 5 are dispersed in a state of being separate from one another. Use of a dispersion liquid in which the particles do not aggregate rather than a dispersion liquid in which the particles are linked together in a chain shape is suitable for achieving desirable aggregation of the particles in the anti-glare films 30 and 40. The reason for this is that the particles 5 that are separate from one another are likely to move along with volatilization of a liquid such as a dispersion medium and are likely to form, in the film, an aggregate that is suitable for achieving favorable properties.
4-3-2-2. Matrix
The matrix 2 is the same as that of the above-described first anti-glare film 20. However, it is preferable that the matrix 2 of the second anti-glare films 30 and 40 contains a nitrogen atom. It is preferable that a nitrogen atom is contained as a portion of an organic compound component or a functional group, particularly a nitrogen-atom-containing functional group. The nitrogen-atom-containing functional group is preferably an amino group. A nitrogen atom can make up a portion of a highly reactive functional group particularly in a raw material for forming a matrix that contains a metal oxide such as silicon oxide as a main component. Such a functional group can promote aggregation of the particles 5 during film formation and play a role in achieving a desirable form of the aggregate of the particles 5.
A metal oxide such as silicon oxide can be formed from a hydrolyzable organic metal compound. An example of a hydrolyzable silicon compound is a compound represented by Formula (1).
A nitrogen atom can also be supplied to the anti-glare films 30 and 40 from a silicon-atom-containing compound, specifically an amino-group-containing silane coupling agent. This compound can be represented by, for example, Formula (2).
AkBmSiY4-k-m (2)
A is an organic group containing an amino group. The amino group may be a primary, secondary, or tertiary amino group. A is an amino-group-containing hydrocarbon, for example, preferably an alkyl group or alkenyl group in which some atoms are substituted with an amino group, more preferably an alkyl group or alkenyl group in which a hydrogen atom is substituted with an amino group, and particularly preferably an alkyl group or alkenyl group having an amino group at its terminus. The alkyl group and the alkenyl group may be linear or branched. Preferable specific examples of A include ω-aminoalkyl groups having an amino group at the terminus of an alkyl group, and N-ω′-(aminoalkyl)-ω-aminoalkyl groups obtained by substituting a hydrogen atom of the amino group of the ω-aminoalkyl group with another aminoalkyl group. It is preferable that A contains a carbon atom as an atom to be linked to the silicon atom. In this case, a hydrocarbon group typified by alkyl groups and alkenyl groups can be provided between the nitrogen atom and the silicon atom. In other words, the nitrogen atom may be linked to the silicon atom contained in silicon oxide via a hydrocarbon group. A is particularly preferably a γ-aminopropyl group or an N-(2-aminoethyl)-3-aminopropyl group.
B may be one of the organic groups listed above as R, or an alkyl group or alkenyl group. The alkyl group or alkenyl group may be branched, and some of hydrogen atoms thereof may be substituted. B is preferably a non-substituted alkyl group, more preferably a linear alkyl group whose carbon chain has 1 to 3 carbon atoms, and even more preferably a methyl group. Y is as described above. k is an integer from 1 to 3, m is an integer from 0 to 2, and k+m is an integer from 1 to 3. k is 1, and m is 0 or 1. Note that, when A is a γ-aminopropyl group, it is preferable that k is 1 and m is 0, and when A is N-(2-aminoethyl)-3-aminopropyl group, it is preferable that k is 1 and m is 0 or 1.
After hydrolysis and polycondensation, the compound represented by Formula (2) forms a network structure in which silicon atoms are linked to one another via oxygen atoms. When used together with the compound represented by Formula (1), the compound represented by Formula (2) makes up a portion of the network structure. In this structure, the organic groups represented by A are contained in a state of being directly linked to silicon atoms.
It is considered that the organic group represented by A attracts particles and promotes aggregation of the particles during volatilization of a solvent of a coating solution.
4-3-2-3. Physical Properties of Second Anti-Glare Film
Although the ratios of the particles 5 to the matrix 2 in the anti-glare films 30 and 40, the film thicknesses of the anti-glare films 30 and 40, the Ra of the surfaces 30s and 40s, and the Rsm of the surfaces 30s and 40s are not particularly limited, the ranges therefor may be the same as those in the case of the above-described first anti-glare film 20.
In the anti-glare films 30 and 40, the particles 5 locally aggregate and lie on top of one another, and thus this portion of the film has an increased thickness, whereas the particles 5 do not lie on top of one another in another portion, and thus the thickness of the film is locally reduced. In the anti-glare films 30 and 40, a difference in height measured from the second surface of the glass plate 10 between the highest portion and the lowest portion may be three times or more, or four times or more, as large as the average particle diameter of the particles 5.
In the region 40b of the anti-glare film 40, the particles are not piled up in the thickness direction of the film, or the particles are not present. In the latter case, the region 40b of the film 40 may be composed of only the matrix 2. The area ratio of the region 40b to the region on which the anti-glare film 40 is formed may be, for example, 5 to 90%, 10 to 70%, or particularly 20 to 50%.
4-3-2-4. Optical Properties of Cover Member
The gloss can be evaluated based on the specular gloss. The 60° specular gloss of the glass plate 10 is, for example, 60 to 130%, 70 to 120%, or particularly 80 to 110% or 85 to 110%. These specular gloss values are measured on the second surfaces of the glass plates on which the anti-glare films 30 and 40 are formed. The haze ratio of the glass plate 10 is, for example, 20% or less, 15% or less, or particularly 10% or less, or may be 1 to 8%, 1 to 6%, or particularly 1 to 5%, in certain cases.
The 60° specular gloss G and the haze ratio H (%) preferably satisfy Relational Expression (a), and more preferably Relational Expression (b).
H≤−0.2G+25 (a)
H≤−0.2G+24.5 (b)
The numbers of Japanese Industrial Standards that are referred to for measurement of the gloss and haze are as described above.
4-3-2-5. Load Curve Parameters
Cover members 200 and 300 in which the second anti-glare film is layered can have the following characteristics regarding load curve parameters in conformity with ISO25178. Note that, as specified in ISO25178, in a load curve, the frequencies at certain heights are accumulated from a higher side and are expressed in percentage with the total number of pieces of data at all the heights being taken as 100. Based on the load curve, a load area ratio at a certain height C is given as Smr(C). A line having the smallest slope among lines on which a difference between the Smr values at any two heights is 40% is defined as an equivalent line. At this time, a difference in height between a point on the equivalent line at a load area ratio of 0% and a point on the equivalent line at a load area ratio of 100% is defined as a level difference Sk in a core portion. A load area ratio at which a peak above the core portion is divided from the core portion is defined as Smr1, and a load area ratio at which a valley below the core portion is conversely divided from the core portion is defined as Smr2. Surface heights at load area ratios of 20, 40, 60, and 80% are respectively defined as BH20, BH40, BH60, and BH80.
Smr1 may be 1 to 40% or 3 to 35%, or 10 to 30% in certain cases. BH20 is, for example, 0.04 μm to 0.5 μm, 0.06 μm to 0.5 μm, or preferably 0.12 μm to 0.3 μm. BH80 is, for example, −0.3 μm to 0 μm, −0.3 μm to −0.05 μm, or preferably −0.25 μm to −0.12 μm.
4-3-3. Third Anti-Glare Film
Next, a third anti-glare film will be described with reference to
The anti-glare films 50 and 60 include first regions 50p and 60p, respectively, and also include second regions 50v and 60v, respectively. In the first regions 50p and 60p, the particles 5 are piled up in the thickness direction of the anti-glare films 50 and 60. When the anti-glare films 50 and 60 are observed from the front side thereof in the thickness direction, the second regions 50v and 60v respectively surround the first regions 50p and 60p. However, the second regions 50v and 60v may be respectively surrounded by the first regions 50p and 60p. The first regions 50p and 60p and the second regions 50v and 60v are arranged such that, for example, one of the first region and the second region is provided between a plurality of the other regions that are separated from each other. This structure may also be referred to as a sea-island structure. The second regions 50v and 60v are valley-shaped regions whose surfaces are recessed relative to the surrounding first regions. Accordingly, the island portions in the sea-island structure protrude from the sea portions when the first regions 50p and 60p correspond to the island portions, whereas the island portions are recessed from the sea portions when the second regions 50v and 60v correspond to the island portions. Fewer particles 5 are piled up in the second regions 50v and 60v compared with the first regions 50p and 60p. The second regions 50v and 60v may include a portion 50t in which the particles 5 are piled up (see
The term “plateau-shaped” means that, when the film is observed under an SEM, the upper portion of a protrusion on the anti-glare films 50 and 60 seems to have a plateau shape. Strictly speaking, this term means that a relationship L2/L1≥0.75, particularly L2/L1≥0.8, is satisfied in the cross section of the film. Here, as shown in
Boundaries 50b and 60b between the first regions 50p and 60p and the second regions 50v and 60v can be determined based on average thicknesses T of the anti-glare films 50 and 60 (see
The width Wp may be 5 μm or more, 7.7 μm or more, or preferably 10 μm or more. The width Wv may be 3.5 μm or more, 7 μm or more, or preferably 10 μm or more. When the width Wp is large, the haze ratio tends to decrease because the anti-glare film is likely to directly transmit visible light incident thereon. When the width Wv is large, gloss tends to decrease because the anti-glare film moderately scatters visible light incident thereon. A film having a width Wp of 10 μm or more and a width Wv of 10 μm or more is particularly suitable for achieving both low haze ratio and low gloss.
The first regions 50p and 60p and the second regions 50v and 60v each may spread over an area of, for example, 0.25 μm2 or more, 0.5 μm2 or more, or particularly 1 μm2 or more, or 5 μm2 or more or 10 μm2 or more in certain cases.
The anti-glare films 50 and 60 include the first regions 50p and 60p, respectively, and also include the second regions 50v and 60v, respectively. The area ratio of the second regions 50v and 60v to the region on which the anti-glare film 40 is formed may be, for example, 5 to 90%, 10 to 70%, or particularly 20 to 50%. The anti-glare films 50 and 60 may be composed of only the first regions 50p and 60p and the second regions 50v and 60v.
4-3-3-1. Particles
The particles 5 are the same as those in the description of the second anti-glare film.
4-3-3-2. Matrix
The matrix 2 is the same as those in the descriptions of the first and second anti-glare films. However, unlike the second anti-glare film, it is less necessary to add a nitrogen atom to promote aggregation of the particles 5 in the third anti-glare film. Accordingly, it is preferable to form a metal oxide such as silicon oxide used to form the matrix 2 from a hydrolyzable organic metal compound, particularly a compound represented by Formula (1). The matrix 2 may be substantially composed of silicon oxide.
4-3-3-3. Physical Properties of Third Anti-Glare Film
Although, in the anti-glare films 50 and 60, the ratios of the particles 5 to the matrix 2, the film thicknesses, the Ra of the surfaces 50s and 60s, and the Rsm of the surfaces 50s and 60s are not particularly limited, the ranges therefor may be the same as those in the descriptions of the first and second anti-glare films. In the anti-glare films 50 and 60, a difference in height measured from the main surface 10s of the glass plate 10 between the highest portion and the lowest portion may be three times or more, or four times or more, as large as the average particle diameter of the particles 5.
4-3-3-4. Optical Properties of Cover Member
The gloss can be evaluated based on the specular gloss. The 60° specular gloss of the glass plate 10 is, for example, 60 to 130%, 70 to 120%, or particularly 80 to 110% or 85 to 100%. These specular gloss values are measured on the surfaces 10s on which the anti-glare films 50 and 60 are formed. The haze ratio of the glass plate 10 is, for example, 20% or less, 15% or less, or particularly 10% or less, or may be 1 to 8%, 1 to 6%, or particularly 1 to 5%, in certain cases.
The 60° specular gloss G and the haze ratio H (%) preferably satisfy Relational Expression (a), more preferably Relational Expression (b), and even more preferably Relational Expression (c). G and H may satisfy Relational Expression (d).
H≤−0.2G+25 (a)
H≤−0.2G+24.5 (b)
H≤−0.2G+24 (c)
H≤−0.15G+18 (d)
The numbers of Japanese Industrial Standards that are referred to for measurement of the gloss and haze are as described above.
5. Features
The display device according to this embodiment can exhibit the following effects. That is, the anti-glare films 20, 30, 40, 50, and 60 are layered as an optical layer in the cover members 100, 200, and 300, and this enables an image displayed on the display panel 500 to be clearly seen. The glass plate 10 and the display panel 500 are directly fixed to each other using the adhesive layer 3 with no air layer being located therebetween, and this also enables an image displayed on the display panel 500 to be clearly seen.
6. Modified Examples
Although an embodiment of the present invention has been described above, the present invention is not limited to the embodiment above, and various modifications can be carried out without departing from the gist of the invention. Note that the following modified examples can be combined as appropriate.
6-1
The configuration of the housing 4 is not particularly limited, and it is sufficient that the display panel 500 and the backlight unit 6 can be housed therein. An organic EL panel, a plasma display panel, an electronic ink-type panel, and the like, for example, can also be used as the display panel 500 instead of employing the above-described liquid crystal panel. If the display panel 500 is constituted by a display panel other than a liquid crystal panel, there is no need to use the backlight unit 6.
6-2
Although the cover member is configured to come into contact with the housing 4 in the embodiment above, the cover member may also be configured to come into contact with only the display panel.
6-3
The glass plate 10 can also be provided with, for example, a shield layer 9 as shown in
6-4
Although the anti-glare films have been described as an example of the optical layer in the embodiment above, another functional film may also be used as the optical layer. Examples thereof include known anti-reflection films, anti-fogging films, and heat reflection films. In the case where an anti-reflection film is used as the optical layer, when protrusions and depressions are formed on the surface as described above, the anti-reflection effect is also enhanced.
6-5
Although the display device of the present invention is applied to a vehicle-mounted display device in the description of the embodiment above, there is no limitation thereto. The display device of the present invention can be applied to display devices in general that are used together with the above-described display panel. The display device can also be used as a touch panel display by providing a touch panel thereon. Accordingly, the above-described cover member can also be applied to various display devices.
10 Glass Plate
20, 30, 40, 50, 60 Anti-glare film (optical layer)
3 Adhesive layer
5 Display panel
| Number | Date | Country | Kind |
|---|---|---|---|
| 2020-080048 | Apr 2020 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2021/017309 | 4/30/2021 | WO |
