Patent Grant
11789189
The present disclosure relates to virtual reality and augmented reality imaging and visualization systems.
Modern computing and display technologies have facilitated the development of systems for so called “virtual reality” or “augmented reality” experiences, wherein digitally reproduced images or portions thereof are presented to a user in a manner wherein they seem to be, or may be perceived as, real. A virtual reality, or “VR”, scenario typically involves presentation of digital or virtual image information without transparency to other actual real-world visual input; an augmented reality, or “AR”, scenario typically involves presentation of digital or virtual image information as an augmentation to visualization of the actual world around the user. For example, referring to
Systems and methods disclosed herein address various challenges related to VR and AR technology.
The systems, methods and devices of the disclosure each have several innovative aspects, no single one of which is solely responsible for the desirable attributes disclosed herein.
In some embodiments, a display system is provided. The display system includes a waveguide; and an image injection device configured to direct a multiplexed light stream into the waveguide. The multiplexed light stream includes a plurality of light streams having different light properties. The waveguide includes in-coupling optical elements configured to selectively in-couple a first of the streams of light while being transmissive to one or more other streams of light. In some embodiments, the waveguide is part of a stack of waveguides, which can include a second waveguide including in-coupling optical elements configured to selectively turn a second of the streams of light while being transmissive to one or more other streams of light. In some embodiments, the in-coupling optical elements of the waveguide are configured to transmit at least one of the streams of light to the in-coupling optical elements of the second waveguide.
Various methods of manufacturing liquid crystal devices including jet depositing liquid crystal material on a substrate and using an imprint pattern to align the molecules of the liquid crystal are described herein. Using the methods described herein, devices including one or several layers of liquid crystal material can be manufactured. Liquid crystal devices manufactured using the methods described herein can include liquid crystal gratings including features and/or patterns that have a size less than about a few microns. Liquid crystal devices manufactured using the methods described herein can also include liquid crystal features and/or patterns that have a size less than the wavelength of visible light and may comprise what are referred to as Pancharatnam-Berry Phase Effect (PBPE) structures, metasurfaces, or metamaterials. In some cases, the small patterned features in these structures can be about 10 nm to about 100 nm wide and about 100 nm to about 1 micron high. In some cases, the small patterned features in these structures can be about 10 nm to about 1 micron wide and about 10 nm to about 1 micron high. Structures for manipulating light, such as for beam steering, wavefront shaping, separating wavelengths and/or polarizations, and combining different wavelengths and/or polarizations can include liquid crystal gratings with metasurface, otherwise referred to herein as metamaterials liquid crystal gratings or liquid crystal gratings with Pancharatnam-Berry Phase Effect (PBPE) structures. Liquid crystal gratings with PBPE structures can combine the high diffraction efficiency and low sensitivity to angle of incidence of liquid crystal gratings with the high wavelength sensitivity of the PBPE structures. Using the various methods of manufacturing described herein, liquid crystal gratings with PBPE structures can be mass-produced which may not be possible using the existing methods of disposing PBPE structures on liquid crystal materials. The methods discussed herein can also be used to fabricate polarizers that are more transparent than existing polarizers.
An innovative aspect of the subject matter disclosed herein includes a display system comprising a waveguide and an image injection device configured to direct a multiplexed light stream into the waveguide. The multiplexed light stream provided by the image injection device can comprise a plurality of light streams having different light properties. The waveguide comprises in-coupling optical elements that are configured to selectively in-couple a first of the streams of light while being transmissive to one or more other streams of light. The in-coupling optical elements can comprise at least one of diffractive structures, liquid crystal material, meta-surfaces, metamaterials, PBPE structures, liquid crystal polarization grating comprising PBPE structures or liquid crystal polarization grating comprising metasurface. The in-coupling optical elements can be switchable between transmissive and actively light redirecting states. Various embodiments of the waveguide can be included in an eyepiece of a head mounted display.
In various embodiments of the display system, the waveguide can be a part of a stack of waveguides. The stack of waveguides can include a second waveguide comprising in-coupling optical elements that can be configured to selectively turn a second of the streams of light while being transmissive to one or more other streams of light. In such embodiments, the in-coupling optical elements of the waveguide can be configured to transmit at least one of the streams of light to the in-coupling optical elements of the second waveguide.
The light streams can have different wavelengths, different polarizations, or combinations thereof. In various embodiments, the image injection device can be configured to simultaneously provide all of the light streams of the plurality of light streams to the waveguide. In various embodiments, the image injection device can be configured to provide at least some of the light streams of the plurality of light streams to the waveguide at different times. The image injection device can be a scanning optical fiber. In various embodiments, the image injection device can comprise a light modulating device.
In various embodiments, the waveguide and/or the second waveguide can comprise out-coupling elements that are configured to output the in-coupled first stream of light propagating in the waveguide. The out-coupling elements can comprise a first group of light redirecting elements configured to increase dimensions of an eyebox along at least one axis. The out-coupling element can further comprise a second group of light redirecting elements configured to increase dimensions of the eyebox along an axis that is orthogonal to the at least one axis.
Another innovative aspect of the subject matter disclosed herein includes a display system comprising a plurality of stacked waveguides and an image injection device. The image injection device is configured to direct a multiplexed light stream into the plurality of stacked waveguides. The multiplexed light stream comprises a plurality of light streams having different light properties. Each waveguide in the plurality of stacked waveguides comprises in-coupling optical elements. Each waveguide is configured to selectively in-couple one or more of the plurality of light streams while being transmissive to one or more other of the plurality of light streams. The plurality of stacked waveguides can be included in an eyepiece of a head mounted display. Each waveguide comprises out-coupling elements that are configured to output the in-coupled one or more of the plurality of light streams propagating in the waveguide.
The in-coupling optical elements can comprise at least one of diffractive structures, liquid crystal material, meta-surfaces, metamaterials, PBPE structures, liquid crystal polarization grating comprising PBPE structures or liquid crystal polarization grating comprising metasurface. In various embodiments, the in-coupling optical elements can be switchable between transmissive and actively light redirecting states. The different light properties can have different wavelengths respectively, different polarizations respectively, or combinations thereof. The image injection device can be configured to simultaneously provide all of the light streams of the plurality of light streams to the waveguide. The image injection device can be configured to provide at least some of the light streams of the plurality of light streams to the waveguide at different times. In various embodiments, the image injection device can be a scanning optical fiber. In some embodiments, the image injection device can comprise a light modulating device.
An innovative aspect of the subject matter disclosed herein includes a display system comprising a waveguide; and an image injection device configured to direct a multiplexed light stream into the waveguide. The multiplexed light stream can comprise a plurality of light streams having different light properties. The waveguide comprises first in-coupling optical elements configured to selectively in-couple a first of the stream of light while being transmissive to one or more other streams of light. In some embodiments, the waveguide can comprise second in-coupling optical elements configured to selectively in-couple a second of the stream of light while being transmissive to one or more other streams of light. In some other embodiments, the waveguide can comprise third in-coupling optical elements configured to selectively in-couple a third of the stream of light while being transmissive to one or more other streams of light. In various embodiments, the first, second or third in-coupling optical elements can include a liquid crystal layer comprising a metasurface. Various embodiments of the waveguide can be included in an eyepiece of a head mounted display.
Details of one or more embodiments of the subject matter described in this specification are set forth in the accompanying drawings and the description below. Other features, aspects, and advantages will become apparent from the description, the drawings, and the claims. Note that the relative dimensions of the following figures may not be drawn to scale.
Like reference numbers and designations in the various drawings indicate like elements.
Embodiments disclosed herein include optical systems, including display systems, generally. In some embodiments, the display systems are wearable, which may advantageously provide a more immersive VR or AR experience. For example, displays containing a stack of waveguides may be configured to be worn positioned in front of the eyes of a user, or viewer. In some embodiments, two stacks of waveguides, one for each eye of a viewer, may be utilized to provide different images to each eye.
The local processing and data module (70) may comprise a processor, as well as digital memory, such as non-volatile memory (e.g., flash memory), both of which may be utilized to assist in the processing, caching, and storage of data. The data include data a) captured from sensors (which may be, e.g., operatively coupled to the frame (64) or otherwise attached to the user (60)), such as image capture devices (such as cameras), microphones, inertial measurement units, accelerometers, compasses, GPS units, radio devices, and/or gyros; and/or b) acquired and/or processed using remote processing module (72) and/or remote data repository (74), possibly for passage to the display (62) after such processing or retrieval. The local processing and data module (70) may be operatively coupled by communication links (76, 78), such as via a wired or wireless communication links, to the remote processing module (72) and remote data repository (74) such that these remote modules (72, 74) are operatively coupled to each other and available as resources to the local processing and data module (70).
In some embodiments, the remote processing module (72) may comprise one or more processors configured to analyze and process data and/or image information. In some embodiments, the remote data repository (74) may comprise a digital data storage facility, which may be available through the internet or other networking configuration in a “cloud” resource configuration. In some embodiments, all data is stored and all computations are performed in the local processing and data module, allowing fully autonomous use from a remote module.
The perception of an image as being “three-dimensional” or “3-D” may be achieved by providing slightly different presentations of the image to each eye of the viewer.
It will be appreciated, however, that the human visual system is more complicated and providing a realistic perception of depth is more challenging. For example, many viewers of conventional “3-D” display systems find such systems to be uncomfortable or may not perceive a sense of depth at all. Without being limited by theory, it is believed that viewers of an object may perceive the object as being “three-dimensional” due to a combination of vergence and accommodation. Vergence movements (i.e., rolling movements of the pupils toward or away from each other to converge the lines of sight of the eyes to fixate upon an object) of the two eyes relative to each other are closely associated with focusing (or “accommodation”) of the lenses of the eyes. Under normal conditions, changing the focus of the lenses of the eyes, or accommodating the eyes, to change focus from one object to another object at a different distance will automatically cause a matching change in vergence to the same distance, under a relationship known as the “accommodation-vergence reflex.” Likewise, a change in vergence will trigger a matching change in accommodation, under normal conditions. As noted herein, many stereoscopic or “3-D” display systems display a scene using slightly different presentations (and, so, slightly different images) to each eye such that a three-dimensional perspective is perceived by the human visual system. Such systems are uncomfortable for many viewers, however, since they, among other things, simply provide different presentations of a scene, but with the eyes viewing all the image information at a single accommodated state, and work against the “accommodation-vergence reflex.” Display systems that provide a better match between accommodation and vergence may form more realistic and comfortable simulations of three-dimensional imagery.
The distance between an object and the eye (4 or 6) can change the amount of divergence of light from that object, as viewed by that eye.
Without being limited by theory, it is believed that the human eye typically can interpret a finite of depth planes to provide depth perception. Consequently, a highly believable simulation of perceived depth may be achieved by providing, to the eye, different presentations of an image corresponding to each of these limited number of depth planes.
With continued reference to
In some embodiments, the image injection devices (200, 202, 204, 206, 208) are discrete displays that each produce image information for injection into a corresponding waveguide (182, 184, 186, 188, 190, respectively). In some other embodiments, the image injection devices (200, 202, 204, 206, 208) are the output ends of a single multiplexed display which may, e.g., pipe image information via one or more optical conduits (such as fiber optic cables) to each of the image injection devices (200, 202, 204, 206, 208).
A controller 210 controls the operation of the stacked waveguide assembly (178) and the image injection devices (200, 202, 204, 206, 208). In some embodiments, the controller 210 includes programming (e.g., instructions in a non-transitory medium) that regulates the timing and provision of image information to the waveguide (182, 184, 186, 188, 190) according to, e.g., any of the various schemes disclosed herein. In some embodiments, the controller may be a single integral device, or a distributed system connected by wired or wireless communication channels. The controller 210 may be part of the processing modules (70 or 72) (
The waveguides (182, 184, 186, 188, 190) may be configured to propagate light within each respective waveguide by total internal reflection (TIR). The waveguides (182, 184, 186, 188, 190) may each be planar, with major top and bottom surfaces and edges extending between those major top and bottom surfaces. In the illustrated configuration, the waveguides (182, 184, 186, 188, 190) may each include light redirecting elements (282, 284, 286, 288, 290) that are configured to redirect light, propagating within each respective waveguide, out of the waveguide to output image information to the eye 4. A beam of light is outputted by the waveguide at locations at which the light propagating in the waveguide strikes a light redirecting element. The light redirecting elements (282, 284, 286, 288, 290) may be reflective and/or diffractive optical features. While illustrated disposed at the bottom major surfaces of the waveguides (182, 184, 186, 188, 190) for ease of description and drawing clarity, in some embodiments, the light redirecting elements (282, 284, 286, 288, 290) may be disposed at the top and/or bottom major surfaces, and/or may be disposed directly in the volume of the waveguides (182, 184, 186, 188, 190). In some embodiments, the light redirecting elements (282, 284, 286, 288, 290) may be formed in a layer of material that is attached to a transparent substrate to form the waveguides (182, 184, 186, 188, 190). In some other embodiments, the waveguides (182, 184, 186, 188, 190) may be a monolithic piece of material and the light redirecting elements (282, 284, 286, 288, 290) may be formed on a surface and/or in the interior of that piece of material.
With continued reference to
The other waveguide layers (188, 190) and lenses (196, 198) are similarly configured, with the highest waveguide (190) in the stack sending its output through all of the lenses between it and the eye for an aggregate focal power representative of the closest focal plane to the person. To compensate for the stack of lenses (198, 196, 194, 192) when viewing/interpreting light coming from the world (144) on the other side of the stacked waveguide assembly (178), a compensating lens layer (180) may be disposed at the top of the stack to compensate for the aggregate power of the lens stack (198, 196, 194, 192) below. Such a configuration provides as many perceived focal planes as there are available waveguide/lens pairings. Both the light redirecting elements of the waveguides and the focusing aspects of the lenses may be static (i.e., not dynamic or electro-active). In some alternative embodiments, they may be dynamic using electro-active features.
With continued reference to
In some embodiments, the light redirecting elements (282, 284, 286, 288, 290) are diffractive features that form a diffraction pattern, or “diffractive optical element” (also referred to herein as a “DOE”). Preferably, the DOE's have a relatively low diffraction efficiency so that only a portion of the light of the beam is deflected away toward the eye (4) with each intersection of the DOE, while the rest continues to move through a waveguide via total internal reflection. The light carrying the image information is thus divided into a number of related exit beams that exit the waveguide at a multiplicity of locations and the result is a fairly uniform pattern of exit emission toward the eye (4) for this particular collimated beam bouncing around within a waveguide.
In some embodiments, one or more DOEs may be switchable between “on” states in which they actively diffract, and “off” states in which they do not significantly diffract. For instance, a switchable DOE may comprise a layer of polymer dispersed liquid crystal, in which microdroplets comprise a diffraction pattern in a host medium, and the refractive index of the microdroplets can be switched to substantially match the refractive index of the host material (in which case the pattern does not appreciably diffract incident light) or the microdroplet can be switched to an index that does not match that of the host medium (in which case the pattern actively diffracts incident light).
Part I. Multiplexed Image Information
With reference again to
In some embodiments, a smaller form factor may be achieved by using a single image injection device to inject information into a plurality of the waveguides. The image injection device delivers multiple image information streams (also referred to herein as information streams) to the waveguides, and these information streams may be considered to be multiplexed. Each waveguide includes in-coupling optical elements that interact with the information streams to selectively in-couple image information from a particular information stream into that waveguide. In some embodiments, the in-coupling optical elements selectively redirect light from a particular information stream into its associated waveguide, while allowing light for other information streams to continue to propagate to other waveguides. The redirected light is redirected at angles such that it propagates through its associated waveguide by TIR. Thus, in some embodiments, a single image injection device provides a multiplexed information stream to a plurality of waveguides, and each waveguide of that plurality of waveguides has an associated information stream that it selectively in-couples using in-coupling optical elements.
The selective interaction between the in-coupling optical elements and the information streams may be facilitated by utilizing information streams with different optical properties. For example, each information stream may be formed by light of different colors (different wavelengths) and/or different polarizations (preferably different circular polarizations). In turn, the in-coupling optical elements are configured to selectively redirect light of a particular polarization and/or of one or more particular wavelengths, thereby allowing a specific correspondence, e.g., one-to-one correspondence, between an information stream and a waveguide. In some embodiments, the in-coupling optical elements are diffractive optical elements configured to selectively redirect light based upon the properties of that light, e.g., the wavelength and/or polarization of that light.
In some embodiments, each image injection device provides image information to a plurality of two, three, four, or more waveguides by providing, respectively, two, three, four, or more information streams to that plurality of waveguides. In some embodiments, multiple such image injection devices may be used to provide information to each of multiple pluralities of waveguides.
With reference now to
With continued reference to
In some embodiments, the image injection device 3021 includes an actuator 3020 (such as a piezoelectric actuator) that is coupled to an optical fiber 352, which may be used to scan the fiber tip of the fiber 352 across an area of the stack 3000. Examples of such scanning fiber image injection devices are disclosed in U.S. patent application Ser. No. 14/641,376, filed Mar. 7, 2015, which is incorporated by reference herein in its entirety. In some other embodiments, the image injection device 3021 may be stationary and, in some embodiments, may direct light towards the stack 3000 from multiple angles.
In some embodiments, each waveguide includes in-coupling optical elements. For example, waveguide 3002 includes in-coupling optical elements 3012, and waveguide 3004 includes in-coupling optical elements 3014. The in-coupling optical elements 3012 and 3014 are configured to selectively redirect one of light streams A and B. For example, in-coupling optical elements 3012 may selectively redirect at least a portion of light stream A to in-couple that light stream into the light guide 3002. The in-coupled portion of light stream A propagates through the waveguide 3002 as light 3042. In some embodiments, the light 3042 propagates through the waveguide 3002 by TIR off the major surfaces 3002a and 3002b of that waveguide. Similarly, in-coupling optical elements 3014 may selectively redirect at least a portion of light stream B to in-couple that light stream into the light guide 3004. The in-coupled portion of light stream B propagates through the waveguide 3004 as light 3044. In some embodiments, the light 3044 propagates through the waveguide 3004 by TIR off the major surfaces 3004a and 3004b of that waveguide.
As illustrated, in some embodiments, the multiplexed light stream 3040 includes both light streams A and B simultaneously, and light stream A may be in-coupled to waveguide 3002 while light stream B is in-coupled to waveguide 3004, as discuss above. In some other embodiments, light streams A and B may be provided to the waveguide stack 3000 at different times. In such embodiments, only a single waveguide may be utilized to receive these information streams, as discussed herein. In either case, the light streams A and B may be coupled to the optical conduit 3024 by the optical coupler 3050. In some embodiments, the optical coupler 3050 may combine light streams A and B for propagation through the optical conduit 3024.
With continued reference to
It will be appreciated that the in-coupling optical elements 3012 and 3014 are configured to selectively redirect the light streams A and B based upon one or more light properties that differ between those light streams. For example, light stream A may have a different wavelength than light stream B and the in-coupling optical elements 3012 and 3014 may be configured to selectively redirect light based on wavelength. Preferably, the different wavelengths correspond to different colors, which can improve the selectivity of the in-coupling optical elements relative to using different wavelengths of the same color.
In some embodiments, light stream A may have a different polarization than light stream B and the in-coupling optical elements 3012 and 3014 may be configured to selectively redirect light based on polarization. For example, the in-coupling optical elements 3012 and 3014 may be configured to selectively redirect light based on polarization. In some embodiments, the light streams A and B have different circular polarization. In some embodiments, the light streams A and B may have multiple differences in light properties, including, e.g., both different wavelengths and different polarizations.
In some embodiments, in-coupling optical elements 3012 and 3014 are diffractive optical elements, including diffractive gratings (e.g., a grating comprising liquid crystal such as a liquid crystal polarization grating). In some embodiments, the optical element may include a meta-surface (e.g., comprise a PBPE), such as a surface have a pattern with feature sizes on the order of one's or ten's of nanometers. Examples of suitable in-coupling optical elements 3012 and 3014 include the optical elements 2000b, 2000d (
With reference now to
With continued reference to
In some embodiments, each waveguide includes in-coupling optical elements that selectively in-couple light into that waveguide. For example, waveguide 3002 includes in-coupling optical elements 3012, which may be configured to in-couple light stream A into that waveguide, so that it propagates by TIR in that waveguide as light 3042; waveguide 3004 includes in-coupling optical elements 3014, which may be configured to in-couple light stream B into that waveguide, so that it propagates by TIR in that waveguide as light 3044; waveguide 3006 includes in-coupling optical elements 3016, which may be configured to in-couple light stream C into that waveguide, so that it propagates by TIR in that waveguide as light 3046; and waveguide 3008 includes in-coupling optical elements 3018, which may be configured to in-couple light stream D into that waveguide, so that it propagates by TIR in that waveguide as light 3048.
It will be appreciated that, in some embodiments, a single light stream (e.g., light stream A, B, C, or D) may be in-coupled to a single waveguide. In some other embodiments, multiple light streams may be in-coupled to the same waveguide. Preferably, in such an arrangement, the light streams are in-coupled at different times. In some embodiments, such temporally separated in-coupling may be achieved using in-coupling optical elements that selectively turn light based on multiple different light properties (e.g., multiple different wavelengths or multiple different polarizations), while the image injection device provides the information streams for a particular waveguide at different times. For example, both light streams A and B may be in-coupled to waveguide 3002, with the in-coupling optical elements 3012 selectively in-coupling light streams A and B while allowing light streams C and D to pass through, and with the light streams A and B providing light to the in-coupling optical elements 3012 at different times while simultaneously providing light streams C and/or D to the in-coupling optical elements 3012. It will be appreciated that one or more other waveguides may be similarly configured to in-couple multiple light streams to those waveguides.
In some other embodiments, multiple light streams (e.g., light streams A and B) may be provided simultaneously to the in-coupling optical elements (e.g., in-coupling optical elements 3012), and the in-coupling optical elements may be configured to change states to choose between in-coupling light stream A or B. For example, in some embodiments, the in-coupling optical elements may be a grating formed of liquid crystal material disposed between electrodes (e.g., transparent electrodes such as ITO). The liquid crystal may change states (e.g., orientations) with the application of a voltage potential, with one state configured to selectively in-couple one light stream (e.g., light stream A) and another state configured to be transparent to all light streams (e.g., both light stream A and B). In some embodiments, another layer of switchable liquid crystal material, forming a different grating, may be provided between electrodes, with one state configured to selectively in-couple a different light stream (e.g., light stream B) and another state configured to be transparent to all light streams (e.g., both light stream A and B). In some other embodiments, both types of liquid crystal material may be disposed on the same level, but in different areas. The liquid crystal material may be configured such that when one type of material is transparent to the light streams, the other type selectively in-couples light of a particular light stream, and vice versa.
Now with reference to
As discussed herein, the waveguides may include light redirecting elements (e.g., light redirecting elements (282, 284, 286, 288, 290)) that output or out-couple light, which has been propagating inside the waveguide, so that the out-coupled light propagates towards the eyes 4 of a viewer (
It will be appreciated that images are formed by the waveguides using information streams with encoded x-y pixel information. For example, the information streams of different colors may each indicate the intensity of light for a particular location on an x-y grid corresponding to the x-y pixel information for the image. Without being limited by theory, it will also be appreciated that the matching of information streams to waveguides is achieved using the properties of light and is not necessarily dependent upon the x-y pixel information provided by that light. Consequently, the x-y pixel information may be encoded at any suitable location using any suitable device along the path of the light before the light impinges on the in-coupling optical elements 3012, 3014, 3016, and 3018.
In some embodiments, if a light source (e.g., LED or OLED) is pixilated and is able to output light having the desired light properties (e.g., desired wavelengths and/or polarizations), then an information stream may be formed having both the desired light properties and encoded x-y pixel information as it is emitted from the light source. In some other embodiments, light having the desired light properties is passed through a light modulation device in which the x-y pixel information is encoded.
Part II. Liquid Crystal Polarization Gratings with Pancharatnam-Berry Phase Effect (PBPE) Structures
This section relates to liquid crystals, polarization gratings, and Pancharatnam-Berry Phase Effect (PBPE) structures, methods of fabrication thereof as well as other structures and methods. In some embodiments, methods and apparatus are provided for manufacturing liquid crystal grating structures that have high diffraction efficiency, low sensitivity to angle of incident and high wavelength sensitivity. Various methods described herein include disposing a layer of liquid crystal material using inkjet technology and using an imprint template to align the liquid crystal material.
In some embodiments, the liquid crystals, polarization gratings, and Pancharatnam-Berry Phase Effect (PBPE) structures disclosed in this Part II may be utilized to form light redirecting elements for the various waveguides of the waveguide stacks 178 (
A variety of imaging systems and optical signal processing systems can include liquid crystal devices to control/manipulate an optical wavefront, wavelength, polarization, phase, intensity, angle and/or other properties of light. Liquid crystals are partly ordered materials whose molecules are often shaped like rods or plates or some other forms that can be aligned along a certain direction. The direction along which the molecules of the liquid crystal are oriented can be manipulated by application of electromagnetic forces which can be used to control/manipulate the properties of light incident on the liquid crystal material.
Methods of manufacturing liquid crystal devices and certain resulting structures are described herein.
The following detailed description is directed to certain embodiments for the purposes of describing the innovative aspects. However, the teachings herein can be applied in a multitude of different ways. As will be apparent from the following description, the innovative aspects may be implemented in any optical component or device that is configured to manipulate one or more characteristics of incident light.
As discussed more fully below, innovative aspects described herein include fabricating liquid crystal devices using jet deposition technology. For example, in an embodiment of a method of manufacturing a liquid crystal device, a layer of liquid crystal material is deposited on a substrate using jet deposition technology (e.g., inkjet technology). Surface relief features (e.g., PBPE structures) can be imprinted in the layer of the jet deposited liquid crystal material using a template. The surface relief features may be configured (e.g., with particular spacing and/or heights) to achieve particular light redirecting properties. In some other embodiments, imprinting can be repeated on different levels to produce successive layered cross-sections that, in combination, can behave as volumetric features such as exists in “bulk” volume-phase materials and devices. In various embodiments, these surface relief features (and the successive layered cross-sections) can be modeled as “Bragg” structures. Generally, such structures can be used to produce binary surface-relief features in which there exists a material-to-air interface, resist-to-air interface, resin-to-air interface or a liquid crystal material-to-air interface that produces diffraction, or a material-to-lower index resist interface, resist-to-lower index resist interface, resin-to-lower index resist interface or a liquid crystal material-to-lower index resist interface that does the same. In these cases the gratings can be modeled as “raman-nath” structures, rather than Bragg structures. The molecules of the liquid crystal material are aligned through the process of imprinting due to the physical shape of the nanostructures and their electrostatic interaction with the liquid crystal (LC) material. Alignment of the liquid crystal layer using the imprint pattern is discussed in greater detail below.
In various embodiments, a layer of material, (e.g., a polymer), to serve as a photo-alignment layer, may be deposited using jet deposition technology (in which a jet or stream of material is directed onto a substrate), e.g., via ink-jet onto a substrate or pre-coated substrate. The photo-alignment layer is patterned by nano-imprinting using a template incorporating the desired LC orientation pattern. In some embodiments, this pattern is a PBPE pattern, and the template, comprising a physical relief, may be made with interferometric and/or lithographic techniques. The template is lowered on to the soft polymer resin and UV light is used to cure the resin to a fixed state. In some embodiments, capillary action fills the template with the polymer material before it is cured. The template is retracted, leaving the patterned, cured resin in place on the substrate. A second step, using a deposition process (e.g., jet or spin coating) applies a layer of LC (e.g., LC suspended in resin) on top of the photo-alignment layer. The LC aligns to the photo-alignment layer pattern below it, and when this occurs, the resin is fixed in place using UV light, heat, or a combination of both. In some other embodiments, LC suspended in solvent (e.g., resin) is deposited (e.g., dispensed using jet or spin coating), and the template containing the nanoimprint pattern (e.g., a PBPE pattern) is lowered into contact with the LC material. to the LC takes up the relief profile of the template (e.g., by capillary action into the openings in the template), and the LC material is fixed in place using a cure process (e.g., UV, heat or a combination of both). The resulting structure may be used directly as a functional element, or in some cases, a low refractive index material can be deposited over the imprinted liquid crystal material to fill the interstitial areas between the surface features imprinted in the liquid crystal material.
The low refractive index material can be configured as a planarization layer by tuning the viscoelastic and chemical properties of the liquid crystals based resist (e.g., a liquid crystal polymer or a resin comprising a liquid crystal) or by contacting the top surface of the low refractive index material with a planarization imprint template (e.g., a template having a substantially planar surface). In some other embodiments, the low refractive index material can be planarized by a chemical and/or mechanical planarization process. The planarization process is preferably chosen to form a planarized surface that is smooth, to reduce optical artifacts that may be caused by a rough surface. Additional layers such as additional liquid crystal layers can be deposited using the jet technology over the liquid crystal layer. The PBPE structures in the different layers of liquid crystal can be configured to diffract, steer, and/or disperse or combine different wavelengths of light. For example, red, green and blue wavelengths can be diffracted, dispersed, or redirected along different directions by the PBPE structures in the different liquid crystal layers.
The different liquid crystal layers are preferably formed with materials that provide sufficient structural stability and adhesion to allow layers to be stacked over one another. In some embodiments, organic or inorganic imprint resist materials, including polymerizable materials that form optically transmissive cured structures, may be used. As an example, the liquid crystal layers can include an acrylic liquid crystal formulation. Acrylic liquid crystal layers can provide adhesive properties that facilitate the stacking of layers on top of each other.
It will be appreciated that, as discussed herein both the liquid crystal material and the low refractive index material may be flowable materials. In some embodiments, these materials may be subjected to a process to immobilize them after contact with the imprint templates and before removing the contacting template. The immobilization process may include a curing process, as discussed herein.
As another example, in another embodiment of a method of manufacturing a liquid crystal device, a layer of a photoresist material (e.g., a resin or a polymer) is deposited on a substrate. The deposition may be accomplished by various deposition methods, including spin coating. More preferably, in some embodiments, the deposition is accomplished using jet technology (e.g., inkjet technology). The photoresist is imprinted with an imprint template or mold having surface relief features (e.g., PBPE structures). A layer of liquid crystal material can be deposited using jet technology on the imprinted layer of photoresist. The imprinted photoresist layer can serve as an aligning layer to align the molecules of the liquid crystal material as it is deposited. Additional layers such as additional liquid crystal layers or layers not comprising liquid crystal can be deposited using the jet technology over the liquid crystal layer. In various embodiments, a planarization layer can be deposited over the deposited liquid crystal layer.
In embodiments discussed herein, different types of liquid crystal materials, such as, for example, doped liquid crystal, un-doped liquid crystal, and other non-liquid crystal materials can be deposited using inkjet technology. Inkjet technology can provide thin controlled (e.g., uniform) thickness of the deposited liquid crystal layer or planarization layer. Inkjet technology can also provide layers of different thickness such as layers of liquid crystal or other layers having a different thickness in different areas on the surface and can accommodate different pattern height and keep a constant residual layer thickness underneath the imprinted patterns. Inkjet technology is advantageously capable of providing thin layers, for example between about 10 nm and 1 micron; or between about 10 nm and about 10 microns in thickness and can reduce waste in comparison with other techniques such as spin coating. The inkjet technology can facilitate deposition of different liquid crystal compositions on the same substrate. In addition, inkjet nano-imprinting can produce a very thin residual layer thickness. In the illustrated embodiments, the uniform area below the imprint pattern can correspond to the residual layer. PBPE and other diffractive structures can exhibit variable and sometimes enhanced performance with very thin or zero residual layer thickness. Inkjet nano-imprinting approaches can be used to deposit different types of materials across a given substrate simultaneously, and can be used to produce variable thickness materials in different areas of a single substrate simultaneously. This may be beneficial to PBPE structures, particularly when they are combined in a single substrate with more conventional diffractive structures which may require other materials and/or thicknesses of resist.
The liquid crystal layers deposited by jet technology can be cured using UV curing, thermal methods, freezing, annealing and other methods. The imprint template can include complex groove geometries (e.g., grooves with multiple steps, gratings with different orientations, etc.). Liquid crystal devices manufactured using the methods described herein can include liquid crystal layers comprising gratings with different orientations and different PBPE structures.
The manufacturing methods using inkjet technology described herein can also be configured to manufacture polarizers having increased transmissivity and/or wave plates comprising subwavelength features and/or metamaterials. These and other aspects are discussed in detail below.
The layer 2000b of the liquid crystal material can be imprinted with an imprint pattern 2000c including wavelength and sub-wavelength scale surface features, as shown in panel (ii). The surface features can include PBPE structures that can directly manipulate the phase of the incoming light. Without any loss of generality, a PBPE structure can be thought of as a type of polarization grating structure. In various embodiments, the imprint pattern 2000c can include an array of grooves comprising PBPE structures. The array of grooves can form a liquid crystal grating structure that can have high diffraction efficiency and low sensitivity to incident angle. The grooves can have a depth between about 20 nm and about 1 micron and a width between about 20 nm and about 1 micron. In some embodiments, the grooves can have a depth between about 100 nm and about 500 nm and a width between about 200 nm and about 5000 nm. In some embodiments, the grooves can have a depth between about 20 nm and about 500 nm and a width between about 10 nm and about 10 micron. The PBPE structures can include sub-wavelength patterns that encode phase profile directly onto the local orientation of the optical axis. The PBPE structures can be disposed on the surface of the liquid crystal grating structures. The PBPE structures can have feature sizes between about 20 nm and about 1 micron. In some embodiments, the PBPE structures can have feature sizes between about 10 nm and about 200 nm. In some embodiments, the PBPE structures can have feature sizes between about 10 nm and about 800 nm. In various embodiments, an underlying PBPE structure can be used as an alignment layer for volumetric orientation of LC. The volumetric component in this case happens automatically, as the LCs naturally align themselves to the alignment layer. In another embodiment, it may be desirable to differentially align multiple layers containing PBPE alignment and LC layers, to change diffraction properties of the system as a composite—for example to multiplex multiple wavelength operation since each sub-layer would act on only a select subset of wavelengths.
In various embodiments, the imprint pattern 2000c can include a simple geometric pattern, such as, for example, a plurality of grooves or more complicated pattern such as multi-tier geometry including a plurality of grooves and recesses as shown in
Referring to
The liquid crystal devices fabricated using above described methods can be cured using UV curing, thermal curing, freezing or other curing methods.
Another embodiment of a method to fabricate liquid crystal devices includes imprinting a desired alignment structure in UV curable resist using Jet and Flash™ Imprint Lithography (J-FIL); and dispensing a liquid crystal polymer formulation from inkjet. The liquid crystal polymer can have a high solvent content, for example, to provide sufficiently low viscosity to enable efficient egress through the inkjets. In various embodiments, the liquid crystal polymer can be in an isotropic state as it is dispensed. In some embodiments, the liquid crystal polymer can be configured to align along the alignment structure in the resist by driving off the solvent. Additional liquid crystal polymer layers can be disposed on top of the disposed liquid crystal polymer layer by following the method described above. The formulation and the viscosity of the liquid crystal material in the solvent may also be adjusted to achieve rapid drying process for the dispensed liquid crystal materials.
With continued reference to
As discussed above, the liquid crystal layer can be formed with a variety of materials. For example, in some embodiments, an acrylate liquid crystal formulation can be disposed over the polymer align imprint structure using inkjet and imprint technology. Acrylate composition can facilitate stacking different liquid crystal layers on top of each other that can adhere to each other without adhesive layers thereby making process simpler. Different liquid crystal layers can be stacked to achieve a desired effect, for example, the desired polarization, diffraction, steering, or dispersion effect.
The method described above can be used to fabricate liquid crystal polarization gratings and patterned guiding layers using linear submasters with jet dispensing technology (e.g., J-FIL). Different liquid crystal grating structures can be fabricated by combining structure with different shapes, orientations, and/or pitches. This process is described in more detail with reference to
The inkjet and imprint methods discussed herein can be used to fabricate other optical elements such as waveguide plates, optical retarders, polarizers, etc. For example, a polarizer that is more transparent than existing polarizers can be fabricated using the methods described herein. The method includes disposing a transparent or substantially transparent material that is patterned such as a polymer imprint and depositing a polarizer material, such as, for example, an iodine solution containing dichroic dye. The method includes imprinting a pattern on the transparent polymer. The pattern can be linear grooves, chevrons, spirals, arcs, or any other simple or complicated pattern. For example, the pattern can be a periodic linear grating structure. The polarizer material can then be deposited on the patterned transparent polymer using the jet technology (such as, for example, J-FIL) described above, imprint planarization or by spin coating.
Subwavelength scale grating structures can induce birefringence in materials. For example, single dimensional grating can act as artificial negative uniaxial materials whose optical axes are parallel to the grating vector. Such birefringence can be referred to as form birefringence. Accordingly, substrates including subwavelength scale grating structures can function as wave plates. The amount of retardation provided by substrates including subwavelength scale grating structures can depend on the dimension (e.g., height, width, pitch, etc.) of the grating patterns as well as the material refractive index. For example, a material with higher index comprising a pattern of subwavelength scale features can provide higher retardation than a material with lower index comprising a similar pattern of subwavelength scale features. Inkjet and imprint technology, such as, for example, J-FIL allows high throughput Ultra Violet Nano-Imprint Lithography (UV-NIL) patterning capabilities with very low waste of material over any defined area. Inkjet and imprint technology, such as, for example, J-FIL can also facilitate repeated stacking of imprinted layers. Imprint layers (single or multi-layered) with such subwavelength scale grating structures with or without varying geometry/orientation can provide varying degrees of phase-shift. Embodiments of patterned birefringent materials can enhance thin film integration capabilities in various optical applications.
The polarization of light output from substrates including subwavelength scale grating structures can depend on the orientation, shape and/or pitch of the subwavelength scale grating structures. Embodiments of wave plates including subwavelength scale grating structures can also be fabricated using the inkjet and imprint methods described herein.
It is contemplated that the innovative aspects may be implemented in or associated with a variety of applications such as imaging systems and devices, display systems and devices, spatial light modulators, liquid crystal based devices, polarizers, wave guide plates, etc. The structures, devices and methods described herein may particularly find use in displays such as wearable displays (e.g., head mounted displays) that can be used for augmented and/or virtually reality. More generally, the described embodiments may be implemented in any device, apparatus, or system that can be configured to display an image, whether in motion (such as video) or stationary (such as still images), and whether textual, graphical or pictorial. It is contemplated, however, that the described embodiments may be included in or associated with a variety of electronic devices such as, but not limited to: mobile telephones, multimedia Internet enabled cellular telephones, mobile television receivers, wireless devices, smartphones, Bluetooth® devices, personal data assistants (PDAs), wireless electronic mail receivers, hand-held or portable computers, netbooks, notebooks, smartbooks, tablets, printers, copiers, scanners, facsimile devices, global positioning system (GPS) receivers/navigators, cameras, digital media players (such as MP3 players), camcorders, game consoles, wrist watches, clocks, calculators, television monitors, flat panel displays, electronic reading devices (e.g., e-readers), computer monitors, auto displays (including odometer and speedometer displays, etc.), cockpit controls and/or displays, camera view displays (such as the display of a rear view camera in a vehicle), electronic photographs, electronic billboards or signs, projectors, architectural structures, microwaves, refrigerators, stereo systems, cassette recorders or players, DVD players, CD players, VCRs, radios, portable memory chips, washers, dryers, washer/dryers, parking meters, head mounted displays and a variety of imaging systems. Thus, the teachings are not intended to be limited to the embodiments depicted solely in the Figures, but instead have wide applicability as will be readily apparent to one having ordinary skill in the art.
Various modifications to the embodiments described in this disclosure may be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of this disclosure. Thus, the claims are not intended to be limited to the embodiments shown herein, but are to be accorded the widest scope consistent with this disclosure, the principles and the novel features disclosed herein. The word “exemplary” is used exclusively herein to mean “serving as an example, instance, or illustration.” Any embodiment described herein as “exemplary” is not necessarily to be construed as preferred or advantageous over other embodiments. Additionally, a person having ordinary skill in the art will readily appreciate, the terms “upper” and “lower”, “above” and “below”, etc., are sometimes used for ease of describing the figures, and indicate relative positions corresponding to the orientation of the figure on a properly oriented page, and may not reflect the proper orientation of the structures described herein, as those structures are implemented.
Certain features that are described in this specification in the context of separate embodiments also can be implemented in combination in a single embodiment. Conversely, various features that are described in the context of a single embodiment also can be implemented in multiple embodiments separately or in any suitable subcombination. Moreover, although features may be described above as acting in certain combinations and even initially claimed as such, one or more features from a claimed combination can in some cases be excised from the combination, and the claimed combination may be directed to a subcombination or variation of a subcombination.
Similarly, while operations are depicted in the drawings in a particular order, this should not be understood as requiring that such operations be performed in the particular order shown or in sequential order, or that all illustrated operations be performed, to achieve desirable results. Further, the drawings may schematically depict one more example processes in the form of a flow diagram. However, other operations that are not depicted can be incorporated in the example processes that are schematically illustrated. For example, one or more additional operations can be performed before, after, simultaneously, or between any of the illustrated operations. In certain circumstances, multitasking and parallel processing may be advantageous. Moreover, the separation of various system components in the embodiments described above should not be understood as requiring such separation in all embodiments, and it should be understood that the described program components and systems can generally be integrated together in a single software product or packaged into multiple software products. Additionally, other embodiments are within the scope of the following claims. In some cases, the actions recited in the claims can be performed in a different order and still achieve desirable results.
Various example embodiments of the invention are described herein. Reference is made to these examples in a non-limiting sense. They are provided to illustrate more broadly applicable aspects of the invention. Various changes may be made to the invention described and equivalents may be substituted without departing from the true spirit and scope of the invention. In addition, many modifications may be made to adapt a particular situation, material, composition of matter, process, process act(s) or step(s) to the objective(s), spirit or scope of the present invention. Further, as will be appreciated by those with skill in the art that each of the individual variations described and illustrated herein has discrete components and features which may be readily separated from or combined with the features of any of the other several embodiments without departing from the scope or spirit of the present inventions. All such modifications are intend22ed to be within the scope of claims associated with this disclosure.
The invention includes methods that may be performed using the subject devices. The methods may comprise the act of providing such a suitable device. Such provision may be performed by the end user. In other words, the “providing” act merely requires the end user obtain, access, approach, position, set-up, activate, power-up or otherwise act to provide the requisite device in the subject method. Methods recited herein may be carried out in any order of the recited events which is logically possible, as well as in the recited order of events.
Example aspects of the invention, together with details regarding material selection and manufacture have been set forth above. As for other details of the present invention, these may be appreciated in connection with the above-referenced patents and publications as well as generally known or appreciated by those with skill in the art. The same may hold true with respect to method-based aspects of the invention in terms of additional acts as commonly or logically employed.
In addition, though the invention has been described in reference to several examples optionally incorporating various features, the invention is not to be limited to that which is described or indicated as contemplated with respect to each variation of the invention. Various changes may be made to the invention described and equivalents (whether recited herein or not included for the sake of some brevity) may be substituted without departing from the true spirit and scope of the invention. In addition, where a range of values is provided, it is understood that every intervening value, between the upper and lower limit of that range and any other stated or intervening value in that stated range, is encompassed within the invention.
Also, it is contemplated that any optional feature of the inventive variations described may be set forth and claimed independently, or in combination with any one or more of the features described herein. Reference to a singular item, includes the possibility that there are plural of the same items present. More specifically, as used herein and in claims associated hereto, the singular forms “a,” “an,” “said,” and “the” include plural referents unless the specifically stated otherwise. In other words, use of the articles allow for “at least one” of the subject item in the description above as well as claims associated with this disclosure. It is further noted that such claims may be drafted to exclude any optional element. As such, this statement is intended to serve as antecedent basis for use of such exclusive terminology as “solely,” “only” and the like in connection with the recitation of claim elements, or use of a “negative” limitation.
Without the use of such exclusive terminology, the term “comprising” in claims associated with this disclosure shall allow for the inclusion of any additional element—irrespective of whether a given number of elements are enumerated in such claims, or the addition of a feature could be regarded as transforming the nature of an element set forth in such claims. Except as specifically defined herein, all technical and scientific terms used herein are to be given as broad a commonly understood meaning as possible while maintaining claim validity.
The breadth of the present invention is not to be limited to the examples provided and/or the subject specification, but rather only by the scope of claim language associated with this disclosure.
This application is a continuation of U.S. application Ser. No. 16/369,890 filed on Mar. 29, 2019 which is a continuation of U.S. application Ser. No. 15/182,528 filed on Jun. 14, 2016 which claims the benefit of priority under 35 USC § 119(e) of U.S. Provisional Application No. 62/175,994 filed on Jun. 15, 2015 and of U.S. Provisional Application No. 62/180,551 filed on Jun. 16, 2015. Each of the above-identified applications is incorporated by reference herein in its entirety. This application incorporates by reference in its entirety each of the following U.S. patents and patent applications: U.S. Pat. No. 6,334,960, issued on Jan. 1, 2002, titled “Step and Flash Imprint Technology;” U.S. Pat. No. 6,873,087, issued on Mar. 29, 2005, titled “High-Precision Orientation, Alignment and Gap control Stages for Imprint Lithography Processes;” U.S. Pat. No. 6,900,881, issued on May 31, 2005, titled “Step and Repeat Imprint Lithography;” U.S. Pat. No. 7,070,405, issued on Jul. 4, 2006, titled “Alignment Systems for Imprint Lithography;” U.S. Pat. No. 7,122,482, issued on Oct. 17, 2006, titled “Methods for Fabricating Patterned Features Utilizing Imprint Lithography;” U.S. Pat. No. 7,140,861, issued on Nov. 28, 2006, titled “Compliant Hard Template for UV Imprinting;” U.S. Pat. No. 8,076,386, issued on Dec. 13, 2011, titled “Materials for Imprint Lithography;” U.S. Pat. No. 7,098,572, issued on Aug. 29, 2006, titled “Apparatus to Control Displacement of a Body Spaced Apart from a Surface;” U.S. application Ser. No. 14/641,376 filed on Mar. 7, 2015; U.S. application Ser. No. 14/555,585 filed on Nov. 27, 2014; U.S. application Ser. No. 14/690,401 filed on Apr. 18, 2015; U.S. application Ser. No. 14/212,961 filed on Mar. 14, 2014; and U.S. application Ser. No. 14/331,218 filed on Jul. 14, 2014.
| Number | Name | Date | Kind |
|---|---|---|---|
| 4693544 | Yamasaki et al. | Sep 1987 | A |
| 4991924 | Shankar et al. | Feb 1991 | A |
| 5187372 | Clube | Feb 1993 | A |
| 5544268 | Bishel et al. | Aug 1996 | A |
| 5566982 | Lehureau et al. | Oct 1996 | A |
| 5808797 | Bloom et al. | Sep 1998 | A |
| 5825448 | Bos et al. | Oct 1998 | A |
| 5915051 | Damask et al. | Jun 1999 | A |
| 6014197 | Hikmet | Jan 2000 | A |
| 6040885 | Koike et al. | Mar 2000 | A |
| 6181393 | Enomoto et al. | Jan 2001 | B1 |
| 6188462 | Lavrentovich et al. | Feb 2001 | B1 |
| 6334960 | Willson et al. | Jan 2002 | B1 |
| 6542671 | Ma et al. | Apr 2003 | B1 |
| 6577365 | Chaudhari et al. | Jun 2003 | B1 |
| 6680767 | Coates et al. | Jan 2004 | B2 |
| 6690845 | Yoshimura et al. | Feb 2004 | B1 |
| 6735224 | Murry et al. | May 2004 | B2 |
| 6750941 | Satoh et al. | Jun 2004 | B2 |
| 6850221 | Tickle | Feb 2005 | B1 |
| 6873087 | Choi et al. | Mar 2005 | B1 |
| 6900881 | Sreenivasan et al. | May 2005 | B2 |
| 6982818 | Riza et al. | Jan 2006 | B2 |
| D514570 | Ohta | Feb 2006 | S |
| 7023466 | Favalora et al. | Apr 2006 | B2 |
| 7070405 | Sreenivasan et al. | Jul 2006 | B2 |
| 7098572 | Choi et al. | Aug 2006 | B2 |
| 7122482 | Xu et al. | Oct 2006 | B2 |
| 7140861 | Watts et al. | Nov 2006 | B2 |
| 7206107 | Levola | Apr 2007 | B2 |
| 7341348 | Eagan | Mar 2008 | B2 |
| 7375784 | Smith et al. | May 2008 | B2 |
| 7471362 | Jones | Dec 2008 | B1 |
| 7519096 | Bouma et al. | Apr 2009 | B2 |
| 7573640 | Nivon et al. | Aug 2009 | B2 |
| 7692759 | Escuti et al. | Apr 2010 | B2 |
| 7705943 | Kume et al. | Apr 2010 | B2 |
| 8064035 | Escuti et al. | Nov 2011 | B2 |
| 8076386 | Xu et al. | Dec 2011 | B2 |
| 8160411 | Levola et al. | Apr 2012 | B2 |
| 8233204 | Robbins et al. | Jul 2012 | B1 |
| 8248458 | Schowengerdt et al. | Aug 2012 | B2 |
| 8264623 | Marrucci | Sep 2012 | B2 |
| 8339566 | Escuti et al. | Dec 2012 | B2 |
| 8508848 | Saarikko | Aug 2013 | B2 |
| 8757812 | Melville et al. | Jun 2014 | B2 |
| 8885161 | Scheeline et al. | Nov 2014 | B2 |
| 8885997 | Nguyen et al. | Nov 2014 | B2 |
| 8903207 | Brown et al. | Dec 2014 | B1 |
| 8950867 | Macnamara | Feb 2015 | B2 |
| 9081426 | Armstrong | Jul 2015 | B2 |
| 9195092 | Escuti et al. | Nov 2015 | B2 |
| 9215293 | Miller | Dec 2015 | B2 |
| D752529 | Loretan et al. | Mar 2016 | S |
| 9310559 | Macnamara | Apr 2016 | B2 |
| 9345402 | Gao | May 2016 | B2 |
| 9348143 | Gao et al. | May 2016 | B2 |
| D758367 | Natsume | Jun 2016 | S |
| D759657 | Kujawski et al. | Jun 2016 | S |
| 9417452 | Schowengerdt et al. | Aug 2016 | B2 |
| 9470906 | Kaji et al. | Oct 2016 | B2 |
| 9547174 | Gao et al. | Jan 2017 | B2 |
| 9575366 | Srivastava et al. | Feb 2017 | B2 |
| 9664905 | Bohn et al. | May 2017 | B2 |
| 9671566 | Abovitz et al. | Jun 2017 | B2 |
| D794288 | Beers et al. | Aug 2017 | S |
| 9740006 | Gao | Aug 2017 | B2 |
| 9791700 | Schowengerdt et al. | Oct 2017 | B2 |
| D805734 | Fisher et al. | Dec 2017 | S |
| 9846967 | Schowengerdt et al. | Dec 2017 | B2 |
| 9851563 | Gao et al. | Dec 2017 | B2 |
| 9857591 | Welch et al. | Jan 2018 | B2 |
| 9874749 | Bradski | Jan 2018 | B2 |
| 9933684 | Brown et al. | Apr 2018 | B2 |
| 10025160 | Park et al. | Jul 2018 | B2 |
| 10156725 | TeKolste et al. | Dec 2018 | B2 |
| 10191288 | Singer et al. | Jan 2019 | B2 |
| 10254454 | Klug et al. | Apr 2019 | B2 |
| 10260864 | Edwin et al. | Apr 2019 | B2 |
| 10261318 | TeKolste et al. | Apr 2019 | B2 |
| 10345592 | Samec et al. | Jul 2019 | B2 |
| 10466478 | Klug et al. | Nov 2019 | B2 |
| 10466561 | Oh | Nov 2019 | B2 |
| 10690826 | Klug et al. | Jun 2020 | B2 |
| 10895784 | Oh et al. | Jan 2021 | B2 |
| 10948642 | Klug et al. | Mar 2021 | B2 |
| 11067732 | Klug et al. | Jul 2021 | B2 |
| 20020097962 | Yoshimura et al. | Jul 2002 | A1 |
| 20020126249 | Liang et al. | Sep 2002 | A1 |
| 20020167638 | Byun et al. | Nov 2002 | A1 |
| 20020172237 | Murry et al. | Nov 2002 | A1 |
| 20030147112 | Mukawa | Aug 2003 | A1 |
| 20030161573 | Ishida | Aug 2003 | A1 |
| 20040007465 | Goldberg et al. | Jan 2004 | A1 |
| 20040022888 | Sreenivasan et al. | Feb 2004 | A1 |
| 20040120647 | Sakata et al. | Jun 2004 | A1 |
| 20040150141 | Chao et al. | Aug 2004 | A1 |
| 20040184163 | Nishioka et al. | Sep 2004 | A1 |
| 20040191429 | Patrick | Sep 2004 | A1 |
| 20040224261 | Resnick et al. | Nov 2004 | A1 |
| 20050042391 | Ryan et al. | Feb 2005 | A1 |
| 20050072959 | Moia et al. | Apr 2005 | A1 |
| 20050073577 | Sudo et al. | Apr 2005 | A1 |
| 20050151906 | Yoshimi et al. | Jul 2005 | A1 |
| 20050158665 | Maekawa et al. | Jul 2005 | A1 |
| 20050232530 | Kekas | Oct 2005 | A1 |
| 20050238801 | Lin et al. | Oct 2005 | A1 |
| 20050253112 | Kelly et al. | Nov 2005 | A1 |
| 20050270312 | Lad et al. | Dec 2005 | A1 |
| 20050270461 | Kitson et al. | Dec 2005 | A1 |
| 20060028436 | Armstrong | Feb 2006 | A1 |
| 20060061725 | Chiu et al. | Mar 2006 | A1 |
| 20060120247 | Noda et al. | Jun 2006 | A1 |
| 20060121358 | Rich et al. | Jun 2006 | A1 |
| 20060126179 | Levola | Jun 2006 | A1 |
| 20060157443 | Mei | Jul 2006 | A1 |
| 20060221448 | Nivon et al. | Oct 2006 | A1 |
| 20060227283 | Ooi et al. | Oct 2006 | A1 |
| 20070031097 | Heikenfeld et al. | Feb 2007 | A1 |
| 20070081123 | Lewis | Apr 2007 | A1 |
| 20070229955 | Kawamura et al. | Oct 2007 | A1 |
| 20070273957 | Zalevsky et al. | Nov 2007 | A1 |
| 20080043166 | Liu et al. | Feb 2008 | A1 |
| 20080043334 | Itzkovitch et al. | Feb 2008 | A1 |
| 20080169479 | Xu et al. | Jul 2008 | A1 |
| 20080278675 | Escuti et al. | Nov 2008 | A1 |
| 20090122412 | Steenblik et al. | May 2009 | A1 |
| 20090141216 | Marrucci | Jun 2009 | A1 |
| 20100026930 | Jepsen | Feb 2010 | A1 |
| 20100142570 | Konttinen et al. | Jun 2010 | A1 |
| 20100207964 | Kimmel et al. | Aug 2010 | A1 |
| 20100225876 | Escuti et al. | Sep 2010 | A1 |
| 20100277803 | Pockett et al. | Nov 2010 | A1 |
| 20100284090 | Simmonds | Nov 2010 | A1 |
| 20100302644 | Yalov | Dec 2010 | A1 |
| 20100321781 | Levola et al. | Dec 2010 | A1 |
| 20110002143 | Saarikko et al. | Jan 2011 | A1 |
| 20110024950 | Kruglick | Feb 2011 | A1 |
| 20110049761 | Mataki | Mar 2011 | A1 |
| 20110194058 | Amos et al. | Aug 2011 | A1 |
| 20110213664 | Osterhout et al. | Sep 2011 | A1 |
| 20110242461 | Escuti et al. | Oct 2011 | A1 |
| 20110242661 | Simmonds | Oct 2011 | A1 |
| 20120021140 | Dijksman et al. | Jan 2012 | A1 |
| 20120033306 | Valera et al. | Feb 2012 | A1 |
| 20120123074 | Okada et al. | May 2012 | A1 |
| 20120127062 | Bar-Zeev et al. | May 2012 | A1 |
| 20120162549 | Gao et al. | Jun 2012 | A1 |
| 20120206485 | Osterhout et al. | Aug 2012 | A1 |
| 20120206812 | Saito et al. | Aug 2012 | A1 |
| 20120218301 | Miller | Aug 2012 | A1 |
| 20120242918 | Valyukh et al. | Sep 2012 | A1 |
| 20120287674 | Nichol et al. | Nov 2012 | A1 |
| 20120327330 | Takahashi et al. | Dec 2012 | A1 |
| 20130016318 | Yamamoto et al. | Jan 2013 | A1 |
| 20130051730 | Travers et al. | Feb 2013 | A1 |
| 20130070198 | Willey | Mar 2013 | A1 |
| 20130082922 | Miller | Apr 2013 | A1 |
| 20130107190 | Chiou et al. | May 2013 | A1 |
| 20130117377 | Miller | May 2013 | A1 |
| 20130125027 | Abovitz | May 2013 | A1 |
| 20130208234 | Lewis | Aug 2013 | A1 |
| 20130222384 | Futterer | Aug 2013 | A1 |
| 20130235440 | Takeda et al. | Sep 2013 | A1 |
| 20130242262 | Lewis | Sep 2013 | A1 |
| 20130242392 | Amirparviz et al. | Sep 2013 | A1 |
| 20130299796 | Masuyama et al. | Nov 2013 | A1 |
| 20130314765 | Padilla et al. | Nov 2013 | A1 |
| 20130314789 | Saarikko et al. | Nov 2013 | A1 |
| 20130321747 | Kondo et al. | Dec 2013 | A1 |
| 20130322810 | Robbins | Dec 2013 | A1 |
| 20140055740 | Spaulding et al. | Feb 2014 | A1 |
| 20140057200 | Lin et al. | Feb 2014 | A1 |
| 20140064655 | Nguyen et al. | Mar 2014 | A1 |
| 20140071539 | Gao | Mar 2014 | A1 |
| 20140104665 | Popovich et al. | Apr 2014 | A1 |
| 20140140653 | Brown et al. | May 2014 | A1 |
| 20140140654 | Brown et al. | May 2014 | A1 |
| 20140168224 | Chleirigh et al. | Jun 2014 | A1 |
| 20140177023 | Gao et al. | Jun 2014 | A1 |
| 20140211322 | Bohn et al. | Jul 2014 | A1 |
| 20140218468 | Gao et al. | Aug 2014 | A1 |
| 20140232993 | Kim | Aug 2014 | A1 |
| 20140233879 | Gibson et al. | Aug 2014 | A1 |
| 20140267420 | Schowengerdt | Sep 2014 | A1 |
| 20140300695 | Smalley et al. | Oct 2014 | A1 |
| 20140306866 | Miller et al. | Oct 2014 | A1 |
| 20150015879 | Papadopoulos et al. | Jan 2015 | A1 |
| 20150016777 | Abovitz et al. | Jan 2015 | A1 |
| 20150062500 | Park et al. | Mar 2015 | A1 |
| 20150103306 | Kaji et al. | Apr 2015 | A1 |
| 20150146147 | Choi et al. | May 2015 | A1 |
| 20150168731 | Robbins | Jun 2015 | A1 |
| 20150177591 | Sugiyama et al. | Jun 2015 | A1 |
| 20150178939 | Bradski et al. | Jun 2015 | A1 |
| 20150205126 | Schowengerdt | Jul 2015 | A1 |
| 20150205182 | Leister | Jul 2015 | A1 |
| 20150222883 | Welch | Aug 2015 | A1 |
| 20150222884 | Cheng | Aug 2015 | A1 |
| 20150234205 | Schowengerdt | Aug 2015 | A1 |
| 20150241705 | Abovitz et al. | Aug 2015 | A1 |
| 20150268415 | Schowengerdt et al. | Sep 2015 | A1 |
| 20150293409 | Usukura et al. | Oct 2015 | A1 |
| 20150301249 | Pau et al. | Oct 2015 | A1 |
| 20150302652 | Miller et al. | Oct 2015 | A1 |
| 20150309263 | Abovitz et al. | Oct 2015 | A2 |
| 20150326570 | Publicover et al. | Nov 2015 | A1 |
| 20150331167 | Excuti et al. | Nov 2015 | A1 |
| 20150346490 | TeKolste et al. | Dec 2015 | A1 |
| 20150346495 | Welch et al. | Dec 2015 | A1 |
| 20160011419 | Gao | Jan 2016 | A1 |
| 20160026253 | Bradski et al. | Jan 2016 | A1 |
| 20160033698 | Escuti et al. | Feb 2016 | A1 |
| 20160033771 | Tremblay et al. | Feb 2016 | A1 |
| 20160041390 | Poon et al. | Feb 2016 | A1 |
| 20160055801 | Kim et al. | Feb 2016 | A1 |
| 20160077338 | Robbins et al. | Mar 2016 | A1 |
| 20160085300 | Robbins et al. | Mar 2016 | A1 |
| 20160097930 | Robbins et al. | Apr 2016 | A1 |
| 20160116739 | TeKolste et al. | Apr 2016 | A1 |
| 20160116979 | Border | Apr 2016 | A1 |
| 20160161648 | Gu et al. | Jun 2016 | A1 |
| 20160167422 | Brehm et al. | Jun 2016 | A1 |
| 20160209648 | Haddick et al. | Jul 2016 | A1 |
| 20160270656 | Samec et al. | Sep 2016 | A1 |
| 20160282808 | Smalley | Sep 2016 | A1 |
| 20160320536 | Simmonds et al. | Nov 2016 | A1 |
| 20170010466 | Klug et al. | Jan 2017 | A1 |
| 20170010488 | Klug et al. | Jan 2017 | A1 |
| 20170131595 | Yim et al. | May 2017 | A1 |
| 20170322419 | TeKolste et al. | Nov 2017 | A1 |
| 20170373459 | Weng et al. | Dec 2017 | A1 |
| 20180004289 | Wilson et al. | Jan 2018 | A1 |
| 20180046859 | Jarvenpaa | Feb 2018 | A1 |
| 20180113309 | Robbins et al. | Apr 2018 | A1 |
| 20180113310 | Rolland et al. | Apr 2018 | A1 |
| 20180143438 | Oh | May 2018 | A1 |
| 20180143470 | Oh et al. | May 2018 | A1 |
| 20180143485 | Oh | May 2018 | A1 |
| 20180143509 | Oh | May 2018 | A1 |
| 20180164645 | Oh et al. | Jun 2018 | A1 |
| 20180188528 | Browy | Jul 2018 | A1 |
| 20180188542 | Waldern et al. | Jul 2018 | A1 |
| 20180217395 | Lin et al. | Aug 2018 | A1 |
| 20180239177 | Oh | Aug 2018 | A1 |
| 20180275350 | Oh | Sep 2018 | A1 |
| 20180275409 | Gao | Sep 2018 | A1 |
| 20190033684 | Favalora et al. | Jan 2019 | A1 |
| 20190086674 | Sinay et al. | Mar 2019 | A1 |
| 20190121142 | Tekolste | Apr 2019 | A1 |
| 20190227211 | Klug et al. | Jul 2019 | A1 |
| 20190243141 | TeKolste | Aug 2019 | A1 |
| 20190243142 | Tekolste | Aug 2019 | A1 |
| 20200174304 | Oh | Jun 2020 | A1 |
| 20200271840 | Klug | Aug 2020 | A1 |
| 20200285120 | Oh | Sep 2020 | A1 |
| 20210341661 | Klug | Nov 2021 | A1 |
| Number | Date | Country |
|---|---|---|
| 1916726 | Feb 2007 | CN |
| 101133348 | Feb 2008 | CN |
| 101133348 | Feb 2008 | CN |
| 101441367 | May 2009 | CN |
| 101556356 | Oct 2009 | CN |
| 101573665 | Nov 2009 | CN |
| 101133348 | Sep 2010 | CN |
| 102683803 | Sep 2012 | CN |
| 102683803 | Sep 2012 | CN |
| 102768439 | Nov 2012 | CN |
| 103384841 | Nov 2013 | CN |
| 104145208 | Nov 2014 | CN |
| 104145208 | Nov 2014 | CN |
| 103328176 | Jul 2015 | CN |
| 105842897 | Aug 2016 | CN |
| 105934902 | Sep 2016 | CN |
| 0 107 092 | May 1984 | EP |
| 0 132 077 | Jan 1985 | EP |
| 0 415 735 | Mar 1991 | EP |
| 0 549 283 | Jun 1993 | EP |
| 2 065 750 | Jun 2009 | EP |
| 2 664 430 | Nov 2013 | EP |
| 55006384 | Jan 1980 | JP |
| 59-131285 | Jul 1984 | JP |
| 62-269174 | Nov 1987 | JP |
| 62-269174 | Nov 1987 | JP |
| 1991-84516 | Apr 1991 | JP |
| 1991-084516 | Apr 1991 | JP |
| H07-56183 | Mar 1995 | JP |
| 2000-075405 | Mar 2000 | JP |
| 2003-522444 | Jul 2003 | JP |
| 2004-226974 | Aug 2004 | JP |
| 2005-316304 | Nov 2005 | JP |
| 2005-316304 | Nov 2005 | JP |
| 2005-316314 | Nov 2005 | JP |
| 2005-316314 | Nov 2005 | JP |
| 2005352321 | Dec 2005 | JP |
| 2006-030752 | Feb 2006 | JP |
| 2006-095722 | Apr 2006 | JP |
| 2006-261088 | Sep 2006 | JP |
| 2006-269770 | Oct 2006 | JP |
| 2007-521645 | Aug 2007 | JP |
| WO 2006-064834 | Jun 2008 | JP |
| 2008-523434 | Jul 2008 | JP |
| 2008-523434 | Jul 2008 | JP |
| 2008-532085 | Aug 2008 | JP |
| 2008-535032 | Aug 2008 | JP |
| 2008-209710 | Sep 2008 | JP |
| 2009-181104 | Aug 2009 | JP |
| 2009-271216 | Nov 2009 | JP |
| 2009-296000 | Dec 2009 | JP |
| 2010-165450 | Jul 2010 | JP |
| 2010-237649 | Oct 2010 | JP |
| 2010-271565 | Dec 2010 | JP |
| 2010-271565 | Dec 2010 | JP |
| WO 2009-084604 | May 2011 | JP |
| 2011-112831 | Jun 2011 | JP |
| 2011-186092 | Sep 2011 | JP |
| WO 2011129404 | Oct 2011 | JP |
| 2012-009126 | Jan 2012 | JP |
| 2012-159802 | Aug 2012 | JP |
| 2012-198261 | Oct 2012 | JP |
| 2012-198261 | Oct 2012 | JP |
| 2013-120350 | Jun 2013 | JP |
| 2013167835 | Aug 2013 | JP |
| 2014092611 | May 2014 | JP |
| 2014-132328 | Jul 2014 | JP |
| WO 2014156167 | Oct 2014 | JP |
| 2014-224846 | Dec 2014 | JP |
| 2014-224846 | Dec 2014 | JP |
| 2015-089638 | May 2015 | JP |
| 2015-099238 | May 2015 | JP |
| 2015-532468 | Nov 2015 | JP |
| 2016-051177 | Apr 2016 | JP |
| 2016-170315 | Sep 2016 | JP |
| 20040101315 | Dec 2004 | KR |
| 2011-0034035 | Apr 2011 | KR |
| 2014-0023896 | Feb 2014 | KR |
| 20140101385 | Aug 2014 | KR |
| 2015-0099799 | Sep 2015 | KR |
| 556031 | Aug 2004 | TW |
| WO 2001010138 | Feb 2001 | WO |
| WO 2005024469 | Mar 2005 | WO |
| WO 2006064301 | Jun 2006 | WO |
| WO 2006092758 | Sep 2006 | WO |
| WO 2006106501 | Oct 2006 | WO |
| WO 2008130555 | Oct 2008 | WO |
| WO 2008130561 | Oct 2008 | WO |
| WO 2010067114 | Jun 2010 | WO |
| WO 2012092443 | Jul 2012 | WO |
| WO 2013054115 | Apr 2013 | WO |
| WO 2014016403 | Jan 2014 | WO |
| WO 2014036537 | Mar 2014 | WO |
| WO 2014091204 | Jun 2014 | WO |
| WO 2014172252 | Oct 2014 | WO |
| WO 2015081313 | Jun 2015 | WO |
| WO 2016054092 | Apr 2016 | WO |
| WO 2016082031 | Jun 2016 | WO |
| WO 2016113533 | Jul 2016 | WO |
| WO 2016205249 | Dec 2016 | WO |
| WO 2016205256 | Dec 2016 | WO |
| WO 2018093730 | May 2018 | WO |
| WO 2018094079 | May 2018 | WO |
| WO 2018094093 | May 2018 | WO |
| WO 2018106963 | Jun 2018 | WO |
| WO 2018112101 | Jun 2018 | WO |
| WO 2018156779 | Aug 2018 | WO |
| WO 2018156784 | Aug 2018 | WO |
| WO 2018175343 | Sep 2018 | WO |
| WO 2018175488 | Sep 2018 | WO |
| WO 2020069026 | Apr 2020 | WO |
| Entry |
|---|
| Weng, et al., “Anchoring energy enhancement and pretilt angle control of liquid crystal alignment on polymerized surfaces,” AIP Advances 5, 097218 (2015); https://doi.org/10.1063/1.4932153. Submitted: Aug. 2, 2015 ⋅ Accepted: Sep. 21, 2015 ⋅ Published Online: Sep. 28, 2015. |
| Buchnev, et al., “Electrically Controlled Nanostructured Metasurface Loaded with Liquid Crystal: Toward Multifunctional Photonic Switch,” Adv.OpticalMater.2015, 3, 674-679. |
| Decker, et al., “Electro-optical switching by liquid-crystal controlled metasurfaces,” Apr. 8, 2013 | vol. 21, No. 7 | DOI:10.1364/OE.21.008879 | Optics Express 8879-8885. |
| Shen, et al., “Optimizing the diffraction efficiency of LCOS-based Holography with anomalous reflection by gradient meta-surface,” Proc. SPIE 9495, Three-Dimensional Imaging, Visualization, and Display 2015. |
| European Extended Search Report for EP Application No. 16812263.8, dated Dec. 7, 2018. |
| International Search Report and Written Opinion for PCT Application No. PCT/US2016/037452, dated Sep. 1, 2016. |
| International Search Report and Written Opinion for PCT Application No. PCT/US2016/037443, dated Nov. 3, 2016. |
| Invitation to Pay Additional Fees for PCT Application No. PCT/US2016/037443, dated Aug. 5, 2016. |
| International Preliminary Report on Patentability for PCT Application No. PCT/US2015/053016, dated Apr. 13, 2017. |
| International Search Report and Written Opinion for PCT Application No. PCT/US15/53016, dated Dec. 30, 2015. |
| Taiwanese Office Action for TW Application No. 105118766, dated Feb. 21, 2018. |
| Chiu et al.: “P-33: Large Area Self-aligning of Liquid Crystal Molecules induced by Nanoimprinting Lithography and a Multiple Function Film Made Therein,” Eurodisplay, Sep. 20, 2005-Sep. 22, 2020, pp. 323-325. |
| Aieta, F. et al., “Multiwavelength achromatic metasurfaces by dispersive phase compensation,” Science, vol. 347, Issue 6228, Mar. 20, 2015, in 5 pages. URL: www.sciencemag.org. |
| Arbabi, A. et al., “Dielectric metasurfaces for complete control of phase and polarization with subwavelength spatial resolution and high transmission,” Nature Nanotechnology, published online Aug. 31, 2015, in 8 pages. URL: www.nature.com/naturenanotechnology. |
| ARToolKit: https://web.archive.org/web/20051013062315/http://www.hitl.washington.edu:80/artoolkit/documentation/hardware.htm, archived Oct. 13, 2005. |
| Azuma, “A Survey of Augmented Reality,” Teleoperators and Virtual Environments 6, 4 (Aug. 1997), pp. 355-385. https://web.archive.org/web/20010604100006/http://www.cs.unc.edu/˜azuma/ARpresence.pdf. |
| Azuma, “Predictive Tracking for Augmented Realty,” TR95-007, Department of Computer Science, UNC—Chapel Hill, NC, Feb. 1995. |
| Bimber, et al., “Spatial Augmented Reality—Merging Real and Virtual Worlds,” 2005 https://web.media.mit.edu/˜raskar/book/BimberRaskarAugmentedRealityBook.pdf. |
| Chigrinov, V.: Photoaligning and Photopatterning Technology: Applications in Displays and Photonics, Proceedings of SPIE, Emerging Liquid Crystal Technologies I, vol. 9769, Mar. 7, 2016, in 11 pages. |
| Choi, Y. et al.: “Determination of Surface Nematic Liquid Crystal Anchoring Strength Using Nano-scale Surface Grooves,” Optical Society of America, May 2013, in 10 pages. |
| Crawford, et al.: “Liquid-crystal diffraction gratings using polarization holography alignment techniques,” Journal of Applied Physics 98, 123102, 2005. |
| Cunningham et al., “A plastic colorimetric resonant optical biosensor for multiparallel detection of label-free biochemical interactions,” Sensors and Actuators B, vol. 85, 2190226, Jul. 2002, in 8 pages. |
| Dierking, I.: “Chiral Liquid Crystals: Structures, Phases, Effects,” Symmetry, (Jun. 2014) 6(2): 444-472. |
| “Metamaterials”. Duke University. Center for Metamaterials and Integrated Plasmonics. May 11, 2015 (Retrieved from the internet Aug. 12, 2016). URL: http://web.archive.org/web/20150511045547/http://metamaterials.duke.edu/research/metamaterials. |
| Escuti, M. et al., “39.4: Polarization-independent switching with high contrast from a liquid crystal polarization grating”, SID Symposium Digest, vol. 37, pp. 1443-1446, Jun. 2006, in 5 pages. |
| Escuti, M. et al., “Polarization-Independent LC Microdisplays Using Liquid Crystal Polarization Gratings: A Viable Solution”, ILCC presentation, Jul. 1, 2008, in 15 pages. |
| Escuti J., “Polarization-Independent Modulation & Simplified Spectropolarimetry Using LC Polarization Gratings,” paper #39.4, posters P-209, P-167, SID Symposium Digest, 2006. |
| Gear, C. et al.: “Engineered Liquid Crystal Anchoring Energies with Nanopatterned Surfaces,” Optical Society of America, Jan. 2015, in 8 pages. |
| Jacob, “Eye Tracking in Advanced Interface Design,” Human-Computer Interaction Lab Naval Research Laboratory, Washington, D.C. / paper/ in Virtual Environments and Advanced Interface Design, ed. by W. Barfield and T.A. Furness, pp. 258-288, Oxford University Press, New York (1995). |
| Kim, J. et al., “Wide-angle, nonmechanical beam steering with high throughput utilizing polarization gratings”, Applied Optics, vol. 50, No. 17, Jun. 10, 2011, in 4 pages. |
| Komanduri, et al., “Multi-twist retarders: broadband retadation control using self-aligning reactive liquid crystal layers,” Optical Society of America, Optics Express 404, vol. 21, No. 1, Jan. 14, 2013. |
| Komanduri, R. et al., “18:3: Late-News Paper: Polarization Independent Liquid Crystal Microdisplays”, SID Digest, vol. 39, No. 1, pp. 236-239, May 2008, in 4 pages. |
| Komanduri, R. et al., “34.4L: Late-News Paper: Polarization Independent Projection Systems using Thin Film Polymer Polarization Gratings and Standard Liquid Crystal Microdisplays”, SID Digest, vol. 40, No. 1, Jun. 2009, in 4 pages. |
| Komanduri, R. et al., “Elastic Continuum Analysis of the Liquid Crystal Polarization Grating”, Physical review. E, Statistical, nonlinear, and soft matter physics, May 25, 2007, in 8 pages. |
| Komanduri, R. et al., “Polarization Independent Projection Systems using Thin Film Polymer Polarization Gratings and Standard Liquid Crystal Microdisplays”, SID—Display week presentation, Jun. 3, 2009, in 12 pages. |
| Komanduri, R. et al., “Polarization-independent modulation for projection displays using small-period LC polarization gratings”, Journal of the Society for information display, vol. 15, No. 8, pp. 589-594, Aug. 2007, in 7 pages. |
| Kurioz, Y. et al.: “P-128: Orientation of a Reactive Mesogen on Photosensitive Surface,” Society for Information Display (SID) Symposium Digest of Technical Papers, May 2007, in 3 pages. |
| Lee, et al., Negative dispersion of birefringence in two-dimensionally self-organized smectic liquid crystal and monomer thin film, Optics Letters, vol. 39, No. 17, Sep. 1, 2014. |
| Lim, Y. et al., “Anisotropic Nano-Imprinting Technique for Fabricating a Patterned Optical Film of a Liquid Crystalline Polymer”, Journal of Nanoscience and Nanotechnology, vol. 8, pp. 4775-4778, Oct. 2008, in 4 pages. |
| Lin, D. et al., “Dielectric gradient metasurface optical elements”, Science, vol. 345, Issue 6194, Jul. 18, 2014, in 6 pages. |
| Lin, D. et al., “Supplementary Materials for Dielectric gradient metasurface optical elements”, Science, vol. 345, Issue 6194, Jul. 18, 2014, in 22 pages. |
| Lin, R. et al. Molecular-Scale soft imprint lithography for alignment layers in liquid crystal devices; Nano Letters, vol. 7, No. 6; Publication [online]. May 23, 2007 [retrieved Feb. 7, 2018]. Retrieved from the Internet: URL:https://pubs.acs.org/doi/abs/10.1021/nl070559y; pp. 1613-1621. |
| Lub J. et al.: “Formation of Optical Films by Photo-Polymerisation of Liquid Crystalline Acrylates and Application of These Films in Liquid Crystal Display Technology,” Mol Cryst Liq Cryst., (May 2005) 429(1):77-99. |
| Nikolova et al., “Diffraction Efficiency and Selectivity of Polarization Holographic Recording”, Optica Acta: Int'l J Optics (1984) 31(5):579-588. |
| Oh C. et al.: “Achromatic Diffraction from Polarization Gratings with High Efficiency”, Opt Lett. (Oct. 2008) 33(20):2287-2289 & Erratum Opt Lett. (Dec. 2009) 34(23):3637. |
| Oh C., Thesis: “Broadband Polarization Gratings for Efficient Liquid Crystal Display, Beam Steering, Spectropolarimetry, and Fresnel Zone Plate”, N. C. State University, Electrical Engineering (2009) in 190 pages. |
| Oh, C. et al., “Numerical analysis of polarization gratings using the finite-difference time-domain method”, Physical review A, vol. 76, Oct. 12, 2007, in 8 pages. |
| Oh, C. et al., “Polarization-Independent Modulation using Standard LCDs and Polymer PGs”, 2008, in 6 pages. |
| Oh, C. et al., 16.2: Polarization-Independent Modulation Using Standard Liquid Crystal Microdisplays and Polymer Polarization Gratings, IDRC, 2008, in 4 pages. |
| Oh et al., “Polarization-Independent Modulation Using Standard Liquid Crystal Microdisplays and Polymer Polarization Gratings,” NC State University; International Display Research Conference, vol. 28, pp. 298-301, 2008. in 16 pages. |
| Rongsheng, et al., “Molecular-Scale Soft Imprint Litography for Alignment: Layers in Liquid Crystal Devices,” NANO Letters, vol. 7, No. 6, May 23, 2007. |
| Scheeline, et al., “Stacked Mutually Rotated Diffraction Gratings as Enablers of Portable Visible Spectrometry,” Appl. Spectrosc. 70, 766-777, May 11, 2016. |
| Tanriverdi and Jacob, “Interacting With Eye Movements in Virtual Environments,” Department of Electrical Engineering and Computer Science, Tufts University, Medford, MA—paper/Proc. ACM CHI 2000 Human Factors in Computing Systems Conference, pp. 265-272, Addison-Wesley/ACM Press (2000). |
| Wikipedia Blind spot (vision), archived Jun. 9, 2016, in 2 pages. URL: https://web.archive.org/web/20160609224858/https:en.wikipedia.org/wiki/Blind_spot(vision). |
| Yang et al. “Negative dispersion of birefringence of smectic liquid crystal-polymer compostie: dependence on the constituent molecules and temperature,” Optical Society of America, Optics Express 2466, vol. 23, No. 3, Feb. 9, 2015. |
| Yu, N. et al., “Flat optics with designer metasurfaces”, Review Article; Nature Materials, (Feb. 2014) 13: 139-150. |
| Yu, N. et al., “Light Propagation with Phase Discontinuities: Generalized Laws of Reflection and Refraction,” Science, vol. 334, No. 333, Oct. 21, 2011, in 6 pages. URL: www.sciencemag.org. |
| BASF, “Wetting Agents and Surface Modifiers,” downloaded from internet, 2021. |
| KR2022-7033592 Office Action dated Jun. 15, 2023. |
| JP2022-209705 Office Action dated Aug. 2, 2023. |
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