Disposable diaper having reduced absorbent core to backsheet gluing

Information

  • Patent Grant
  • 9649232
  • Patent Number
    9,649,232
  • Date Filed
    Friday, September 4, 2015
    8 years ago
  • Date Issued
    Tuesday, May 16, 2017
    7 years ago
Abstract
The present disclosure generally relates to disposable diapers having absorbent cores comprising superabsorbent polymer particles which are immobilized by adhesive. The absorbent cores are attached to the backsheets of the disposable diapers in certain attachment zones to reduce see-through and the formation of tension lines on the backsheets.
Description
FIELD

The present disclosure generally relates to disposable diaper having absorbent cores comprising superabsorbent polymer particles which are immobilized by adhesive. The absorbent core is attached to the backsheet of the disposable diaper only in certain attachment zones to reduce see-through and the formation of tension lines on the backsheet.


BACKGROUND

The use of superabsorbent polymer material in disposable diapers is generally known. The use of superabsorbent polymer material facilitates disposable diapers having a thinner absorbent core versus the use of absorbent materials such as fluff pulp, especially while the disposable diaper is in the dry state.


Today, most disposable diapers which are commercially available still have absorbent cores containing a mixture of so-called airfelt (cellulose fibers) and superabsorbent polymer particles. The cellulose fibers comprised by the absorbent core generally hold the superabsorbent polymer particles in place as the cellulose fibers entangle the particles such that the particles are trapped between the cellulose fibers. This generally does not result in a complete immobilization of the superabsorbent polymer particles, as the particles still may have some degree of freedom to move within the interstices between the cellulose fibers. However, the superabsorbent polymer particles are held in the desired position to a sufficiently satisfying degree.


Using higher amounts of superabsorbent polymer particles is desirable as it enables thinner absorbent cores. However, in absorbent cores having high amounts of superabsorbent polymer particles and little or no airfelt, the superabsorbent polymer particles can no longer be held in place in the interstices between the cellulose fibers, as the ratio of superabsorbent polymer particles to cellulose fibers is too high. Therefore, in absorbent cores having very high amounts of superabsorbent polymer particles (such as >80%), the particles have to be immobilized by some other means. One way to facilitate immobilization is the use of adhesive, such as hot melt adhesive. The hot melt adhesive may be applied as a fine, fibrous network within the absorbent core. Further, in absorbent cores having a high percentage of superabsorbent polymer material and little or no airfelt the superabsorbent polymer material is often sandwiched between carrier substrates. The carrier substrates are typically nonwoven webs.


Absorbent cores having relatively high amounts of superabsorbent polymer particles immobilized by hot melt adhesive and having little or no airfelt have few to no interstices (e.g. those provided between cellulose fibers). Thus, there is no available “free space” within the absorbent core into which the superabsorbent polymer particles can expand upon absorption of liquid. In these absorbent cores the superabsorbent polymer particles, upon swelling, will exert a certain force onto the nonwoven webs, which typically enwrap and encompass the superabsorbent polymer particles. Consequently, the nonwoven webs will also elongate in order to accommodate for the additional space needed by the swelling superabsorbent polymer particles within the absorbent core.


It has been found that an elongated and somewhat strained absorbent core, when incorporated in a disposable diaper, which has been attached onto a wearer, may result in a strained appearance of the backsheet, leading e.g. to the formation of tension lines or wrinkles Such tensed appearance may give raise to concerns by wearers or—if the wearers are babies or toddles—by the caretakers regarding the overall quality and especially the capacity of the disposable diaper. The tensed appearance may be perceived as an indication that the disposable diaper has reached its maximum load and needs to be replaced even if in fact a considerable amount of absorbent capacity is still available. The caretakers or wearers may thus attempt to change the diaper even if the absorbent core may still have the capacity to absorb further gushes of urine.


There is thus a need for disposable diapers with absorbent cores having high amounts of superabsorbent polymer particles and little to no airfelt, wherein, when only partly loaded with liquid, the backsheet may not have a strained appearance, especially when attached onto a wearer.


SUMMARY

The present disclosure generally relates to a disposable diaper comprising a backsheet, a topsheet and therein between an absorbent core. The absorbent core has a longitudinal direction with a longitudinal axis and perpendicular thereto a lateral direction with a transverse axis, and the absorbent core further has a front region, a back region and a crotch region therein between and a front lateral edge, an opposing back lateral edge, and longitudinally extending side edges.


The absorbent core comprises superabsorbent polymer particles, which are immobilized by a first core adhesive. The absorbent core is attached to the backsheet according to one of the following options:


The absorbent core is attached to backsheet of the disposable diaper in attachment zones adjacent to the front lateral edge and the back lateral edge of the absorbent core and the absorbent core is unattached to the backsheet in any other region; or


The absorbent core is attached to the backsheet of the disposable diaper in the crotch region of the absorbent core in one or more than one attachment zone(s) on or adjacent to the longitudinal axis of the absorbent core, wherein the one or more than one attachment zone(s) cover from 0.2% to 3% of the total surface area of the absorbent core, and the absorbent core is unattached to the backsheet in any other region; or


The absorbent core is attached to the backsheet of the disposable diaper in the crotch region of the absorbent core in attachment zones adjacent to the longitudinal side edges of the absorbent core and the absorbent core is unattached to the backsheet in any other region; or


The absorbent core is attached to the backsheet of the disposable diaper in combinations of any of the attachment zones of a) to c) and the absorbent core is unattached to the backsheet in any other region.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a plan view of a schematic drawing of a disposable diaper in accordance with an embodiment of the present disclosure.



FIG. 2 is a cross sectional view of the disposable diaper shown in FIG. 1 taken along the sectional line 2-2 of FIG. 1 in accordance with an embodiment of the present disclosure.



FIG. 3 is a schematic, partial cross sectional view of an absorbent core layer in accordance with an embodiment of the present disclosure.



FIG. 4 is a schematic, partial cross sectional view of an absorbent core in accordance with an embodiment of the present disclosure.



FIG. 5 is a schematic, partial sectional view of an absorbent core in accordance with an embodiment of the present disclosure.



FIG. 6 is a schematic, cross-sectional view of a suitable system for conducting the test method to visualize backsheet see-through in accordance with an embodiment of the present disclosure.



FIG. 7 is a schematic drawing of an apparatus imaging system graphic for conducting the test method to visualize backsheet see-through in accordance with an embodiment of the present disclosure.



FIG. 8 is a schematic drawing of a weight used in the test method to visualize backsheet see-through (front view) in accordance with an embodiment of the present disclosure.



FIG. 9 is a schematic drawing of a weight used in the test method to visualize backsheet see-through (side view) in accordance with an embodiment of the present disclosure.





DETAILED DESCRIPTION

Definitions


“Absorbent core” means a structure that is disposed between a topsheet and a backsheet of a disposable diaper for absorbing and containing liquid received by the disposable diaper.


“Airfelt” is used herein to refer to comminuted wood pulp, which is a form of cellulose fibers (absorbent fibers).


“Diaper” refers to an absorbent article generally worn by infants and incontinent persons about the lower torso so as to encircle the waist and legs of the wearer and which is specifically adapted to receive and contain urinary and fecal waste. For the present disclosure, the term “diaper” is considered to encompass “diaper pants”.


“Diaper-pant”, as used herein, refers to disposable garments having a waist opening and leg openings designed for infant or adult wearers. A diaper-pant may be placed in position on the wearer by inserting the wearer's legs into the leg openings and sliding the pant into position about a wearer's lower torso. A diaper-pant may be preformed by any suitable technique including, but not limited to, joining together portions of the article using refastenable and/or non-refastenable bonds (e.g., seam, weld, adhesive, cohesive bond, fastener, etc.). A diaper-pant may be preformed anywhere along the circumference of the article (e.g., side fastened, front waist fastened). The terms “diaper-pant” is also commonly referred to as “prefastened diaper,” “pull-on diaper,” “training pant,” and “pant”.


“Disposable” is used in its ordinary sense to mean an article that is disposed or discarded after a limited number of usage events over varying lengths of time, for example, less than 10 events, less than 5 events, or less than 2 events. A disposable absorbent article is most often disposed after single use.


“Hot melt adhesive” as used herein refers to adhesives in alignment with the description given in “Adhesion and Adhesives Technology: An Introduction” by Alphonsus V. Pocius (Hanser publishers Munich, 1997). Therein a hot melt is defined as an adhesive applied from the melt and gaining strength upon solidification.


“Non-elastic” as used herein refers to a backsheet which does not recover by more than 20% if subjected to the following test:


A rectangular piece of backsheet material (such as a film or a nonwoven or—if the backsheet comprises a film and a nonwoven web—both materials taken together in the configuration in which they are used as backsheet material) having a width of 2.54 cm and a length of 25.4 cm is maintained in a vertical position by holding the piece along its upper 2.54 cm wide edge along its complete width. A force of 10 N is applied onto the opposite lower edge along the complete width of the material for 1 minute at 25° C.


Immediately after one minute, the length of the piece is measured while the force is still applied and the degree of elongation is calculated by subtracting the initial length (10 inch) from the length measured after one minute.


Immediately after the length of the rectangular piece has been measured, the force is removed and the piece is laid down flat on a table for 5 minutes (at 25° C.) to be able to recover. Immediately after 5 minutes, the length of the piece is measured again and the degree of elongation is calculated by subtracting the initial length (25.4 cm) from the length after 5 minutes.


The elongation after one minute while the force has been is compared to the elongation after the piece has been laid down flat on a table for 5 minutes: If the elongation does not recover by more than 20%, the material or element is considered to be “non-elastic”.


“Highly non-elastic” as used herein refers to a material or element, which is either “non-extensible” or which does not recover by more than 10% if subjected to the test set out above for “non-elastic”.


A “nonwoven web” is a manufactured sheet or web of directionally or randomly orientated fibers, bonded by friction, and/or cohesion and/or adhesion, excluding paper and products which are woven, knitted, tufted, stitch-bonded incorporating binding yarns or filaments, or felted by wet-milling, whether or not additionally needled. The fibers may be of natural or man-made origin and may be staple or continuous filaments or be formed in situ. Commercially available fibers have diameters ranging from less than about 0.001 mm to more than about 0.2 mm and they come in several different forms such as short fibers (known as staple, or chopped), continuous single fibers (filaments or monofilaments), untwisted bundles of continuous filaments, and twisted bundles of continuous filaments (yarn). Nonwoven webs can be formed by many processes such as meltblowing, spunbonding, solvent spinning, electrospinning, carding and airlaying. Nonwoven webs may be bonded by heat and/or pressure or may be adhesively bonded. Bonding may be limited to certain areas of the nonwoven web (point bonding). Nonwoven webs may also be hydro-entangled or needle-punched. The basis weight of nonwoven webs is usually expressed in grams per square meter (gsm).


“Superabsorbent polymer particles” as used herein refers to substantially water-insoluble polymer particles that can absorb at least 5 times their weight of an aqueous 0.9% saline solution as measured using the Centrifuge Retention Capacity test (Edana 441.2-01). “Superabsorbent polymer particles” refer to an absorbent polymer material which is in particulate form so as to be flowable in the dry state.


Disposable Diaper



FIG. 1 is a plan view of a disposable diaper 10 according to a certain embodiment of the present disclosure. The disposable diaper 10 is shown in its flat out, uncontracted state (i.e. without elastic induced contraction) and portions of the disposable diaper 10 are cut away to more clearly show the underlying structure of the disposable diaper 10. A portion of the disposable diaper 10 that contacts a wearer is facing the viewer in FIG. 1. The disposable diaper 10 generally may comprise a chassis 12 and an absorbent core 14 disposed in the chassis 12.


The chassis 12 of the disposable diaper 10 in FIG. 1 comprises the main body of the disposable diaper 10. The chassis 12 may comprise an outer covering 16 including a topsheet 18, which may be liquid pervious, and/or a backsheet 20, which may be liquid impervious. The absorbent core 14 may be encased between the topsheet 18 and the backsheet 20. The chassis 12 may also include side panels 22, elasticized leg cuffs 24, and an elastic waist feature 26.


The leg cuffs 24 and the elastic waist feature 26 may each typically comprise elastic members 28 such as elastic strands. One end portion of the disposable diaper 10 is configured as a front waist region 30 of the disposable diaper 10. An opposite end portion of the disposable diaper 10 is configured as a back waist region 32 of the disposable diaper 10. An intermediate portion of the disposable diaper 10 is configured as a crotch region 34, which extends longitudinally between the first and second waist regions 30 and 32. The waist regions 30 and 32 may include elastic elements such that they gather about the waist of the wearer to provide improved fit and containment (elastic waist feature 26). The crotch region 34 is that portion of the disposable diaper 10 which, when the disposable diaper 10 is worn, is generally positioned between the wearer's legs.


The disposable diaper 10 is depicted in FIG. 1 with its longitudinal axis 36 and its transverse axis 38. The periphery 40 of the disposable diaper 10 is defined by the outer edges of the disposable diaper 10 in which the longitudinal edges 42 run generally parallel to the longitudinal axis 36 of the disposable diaper 10 and the end edges 44 run between the longitudinal edges 42 generally parallel to the transverse axis 38 of the disposable diaper 10. The disposable diaper 20 may also include such other features as are known in the art including front and back ear panels, waist cap features, elastics and the like to provide better fit, containment and aesthetic characteristics.


In order to keep the disposable diaper 10 in place about the wearer, at least a portion of the first waist region 30 may be attached by the fastening member 46 to at least a portion of the second waist region 32 to form leg opening(s) and an article waist. To this end, according to certain embodiments, the disposable diaper 10 may be provided with a re-closable fastening system or may alternatively be provided in the form of a disposable diaper-pant. When the absorbent article is a disposable diaper, it may comprise a re-closable fastening system joined to the chassis for securing the disposable diaper to a wearer. The fastening system may include at least one fastening member 46 and at least one landing zone 48. When the absorbent article is a disposable diaper-pant, the article may comprise two side panels on each waist region 30, 32 joined to the chassis along the longitudinal edges of the side panels which face towards the longitudinal axis 36. The side panels of the front waist region 30 are further joined to the respective side panels of the back waist region 32 along their longitudinal edges facing away from the longitudinal axis 36 to form a pant.


A cross section of FIG. 1 along the sectional line 2-2 of FIG. 1 is shown in FIG. 2: Starting from the wearer facing side, the disposable diaper 10 may comprise the topsheet 18, the components of the absorbent core 14, and the backsheet 20. Disposable diaper 10 may also comprise an acquisition system 50 disposed between the liquid permeable topsheet 18 and the wearer facing side of the absorbent core 14. The acquisition system 50 may be in direct contact with the absorbent core.


The acquisition system 50 may comprise a single layer or multiple layers (not shown), such as an upper acquisition layer facing towards the wearer and a lower acquisition layer facing the garment of the wearer. According to a certain embodiment, the acquisition system 50 may function to receive a surge of liquid, such as a gush of urine. In other words, the acquisition system 50 may serve as a temporary reservoir for liquid until the absorbent core 14 can absorb the liquid.


In a certain embodiment, the acquisition system 50 may comprise chemically cross-linked cellulose fibers and/or nonwoven webs.


Absorbent Core


The absorbent core of the present disclosure has a longitudinal direction with a longitudinal axis and perpendicular thereto a lateral direction with a transverse axis. The longitudinal axis is substantially parallel to the longitudinal axis of the disposable diaper and the lateral direction is substantially parallel to the transverse axis of the disposable diaper. The absorbent core further has a front region, a back region and a crotch region therein between and a front lateral edge, an opposing back lateral edge, and longitudinally extending side edges. The absorbent core may comprise a first, lower and a second, upper carrier substrate, and superabsorbent polymer particles placed onto the first carrier substrate or between the first and second carrier substrate. The superabsorbent polymer particles are immobilized by a first core adhesive.


The front zone of the absorbent core represents one third of the absorbent core extending from the front edge of the absorbent core along the longitudinal axis towards the crotch region. The front zone is placed towards the front waist edge of the disposable diaper. The back zone represents one third of the absorbent core extending from the back edge along the longitudinal axis towards the crotch region. The back zone is placed towards the back waist edge of the disposable diaper. The crotch zone represents the remaining third of the absorbent core and extending between the front zone and the back zone. The complete length of the absorbent core is defined as longest extension of the absorbent core along or parallel to the longitudinal axis of the absorbent core. The absorbent core of the present disclosure may be rectangular. In one embodiment, the crotch region of the laminate absorbent core has a narrower width than the front and back regions of the absorbent core, while the front and back edge of the absorbent core still form a straight line.


In one embodiment superabsorbent polymer particles 66 are disposed on the first carrier substrate 64, and the first core adhesive 94 is disposed on the superabsorbent polymer particles 66. Typically the first core adhesive 94 is a hot melt adhesive. In one embodiment the first core adhesive 94 forms a fibrous layer which is at least partially in contact with the superabsorbent polymer particles 66 and partially in contact with the first carrier substrate 64. A second core adhesive (not shown) may be deposited on the first carrier substrate 64 before the application of the superabsorbent polymer particles 66 for enhancing adhesion of the superabsorbent polymer particles 66 and/or of the first core adhesive 94 to the first carrier substrate 64.


The first carrier substrate 64 may be dimensioned such that, after the superabsorbent polymer particles 66 and the first 94 have been applied, the first carrier substrate 64 is folded over onto itself with the superabsorbent polymer particles 66 and the first core adhesive 94 facing inwardly and the first carrier substrate 64 surrounding the superabsorbent polymer particles 66 and the first core adhesive 94. The area of the first carrier substrate 64, which is folded over, may be free of superabsorbent polymer particles 66 and the first core adhesive 94 prior to being folded over. Alternatively, the area of the first carrier substrate 64, which is folded over, may also comprise superabsorbent polymer particles 66 and a first core adhesive, such that upon folding, the two layers of superabsorbent polymer particles 66 are overlaying each other, with the first core adhesive being sandwiched between the two layers of superabsorbent polymer particles. The superabsorbent polymer particles 66 may be applied in clusters to form land areas 92 and junction areas 96 as is explained below in more detail. Also, the first core adhesive 94 may only be applied to those areas, where the first carrier substrate 64 is folded over. Upon folding, the first core adhesive 94 will also come into contact with the superabsorbent polymer particles 66 of the area, which is not folded over, thus immobilizing the superabsorbent polymer particles 66 of this area.


Alternatively to folding the first carrier substrate 64 over, the absorbent core 14 may also include a second carrier substrate 72. In still another embodiment, the absorbent core may not comprise a second carrier substrate. In this embodiment, the components of the disposable diaper 10 being placed on top of the absorbent core 14 are in direct contact with the superabsorbent polymer particles 66 and the first core adhesive 94.


The first carrier substrate 64, in use of the disposable diaper 10, is facing towards the garment of the wearer and the optional second carrier substrate 72, in use of the disposable diaper, is facing towards the wearer. The optional second carrier substrate 72 may be a nonwoven web or may, alternatively, be a tissue. The first carrier substrate 64 may be a nonwoven web, or may, alternatively be a tissue or a film. The first and second carrier substrate 64, 72 may be made of the same material or they may be made of different material. In embodiments wherein the first and second carrier substrate 64, 72 are both nonwoven webs, these nonwoven webs may be the same nonwoven webs ore they may differ from each other, e.g. with regard to their basis weight, hydrophilicity, air permeability or number and/or type of layers comprised by the nonwoven webs. The type of layers may be spunbonded layers or meltblown layers. The nonwoven webs may also be carded webs made of staple fibers, and the carded webs may or may not comprise binder material. The nonwoven webs may also be hydro-entangled or needle-punched.


The absorbent core 14 may be substantially free of airfelt. The absorbent core 14 typically comprises less than 5% by weight of airfelt, more typically less than 2% by weight and most typically is airfelt free. The absorbent core may not include an acquisition system 50, a topsheet 18, or a backsheet 20 of the disposable diaper 10. In one embodiment, the absorbent core 14 would consist essentially of the first and optional second carrier substrate 64, 72, the superabsorbent polymer particles 66, the first core adhesive 94, and optionally the second core adhesive. “Consist essentially of” in this respect means that these components make up at least 98% by weight of the absorbent core, alternatively at least 99% by weight.


The superabsorbent polymer particles 66 may be substantially continuously distributed within the superabsorbent polymer particles area of the absorbent core 14. “Superabsorbent polymer particle area” as used herein refers to the area (on the wearer facing surface) of the absorbent core which is comprises superabsorbent polymer particles. The areas adjacent the longitudinal side edges and the areas adjacent to the front and back lateral edges of the absorbent core may be free of superabsorbent polymer particles to allow for attaching the edges of the first carrier substrate 64 to the edges of the optional second carrier substrate 72 (or, in the absence of a second carrier substrate 64, the edges of the first carrier substrate may be attached to a layer above the absorbent core 14, such as a layer of the acquisition system 50). Also, the absorbent core 14 may comprise channels, i.e. areas which are substantially free of superabsorbent polymer particles 66 and which are not provided adjacent the edges of the absorbent core 14 but in some other location. “Substantially free of superabsorbent polymer particles”, as used herein, means that e.g. due to process-related reasons, a small, negligible amount of superabsorbent polymer particles may be present in the gaps, which however does not contribute to the overall functionality. The term “substantially free of superabsorbent polymer particles” encompasses “free of superabsorbent polymer particles”. However, for the present disclosure, the “superabsorbent polymer particle area” comprises at least 80% of the surface area of the absorbent core, alternatively at least 85% or at least 90%.


“Substantially continuously distributed” as used herein means that within the superabsorbent polymer particle area, the first carrier substrate 64 and optional second carrier substrate 72 (or the first substrate and the layer provided on top of the absorbent core 14 towards the wearer, such as a layer of the acquisition system 50) are separated by a multiplicity of superabsorbent polymer particles 66. It is recognized that there may be minor incidental contact areas between the first carrier substrate 64 and second carrier substrate 72 (or the first carrier substrate 64 and the component provided on top of the absorbent core 14 towards the wearer, such as the acquisition system 50) within the superabsorbent polymer particle area. Such incidental contact areas are due to unintentional manufacturing artifacts.


The absorbent core of the present disclosure may comprise—or may consist of—two layers. A first absorbent core layer 60 is shown in FIG. 3. FIG. 4 shows an embodiment of an absorbent core, wherein the first and second absorbent core layer 60, 62 have been combined to form the absorbent core 14. FIG. 5 shows an embodiment of an absorbent core consisting of only one layer


In embodiments having a first and a second absorbent core layer, the first absorbent core layer 60 may comprise the first carrier substrate 64 and a first layer of superabsorbent polymer particles 66, wherein the superabsorbent polymer particles 66 are immobilized by a first core adhesive 94. Optionally, the first absorbent core layer 60 may comprise a second core adhesive (not shown). A second core adhesive may be deposited on the first carrier substrate 64 before the application of the superabsorbent polymer particles 66 for enhancing adhesion of the superabsorbent polymer particles 66 and/or of the first core adhesive 94 to the first carrier substrate 64. The first core adhesive 94 may be applied on the superabsorbent polymer particle layer as a fibrous layer, such that a fibrous network is formed.


The second absorbent core layer 62 of such embodiments comprises a second carrier substrate 72 and a second layer of superabsorbent polymer particles 66, wherein the superabsorbent polymer particles 66 may be immobilized by a first core adhesive 94. Optionally, the second absorbent core layer 62 may comprise a second core adhesive (not shown). A second core adhesive may be deposited on the second carrier substrate 72 before the application of the superabsorbent polymer particles 66 for enhancing adhesion of the superabsorbent polymer particles 66 and/or of the first core adhesive 94 to the second carrier substrate 72. The first core adhesive 94 may be applied on the superabsorbent polymer particle layer as a fibrous layer, such that a fibrous network is formed.


Once the first and second absorbent core layer 60, 62 is formed, the two absorbent core layers are combined with their respective carrier substrates 64, 72 facing outwardly and sandwiching the superabsorbent polymer particles 66 between them to form the absorbent core 14.


In one embodiment, a further substrate (not shown), such as a tissue or nonwoven web is positioned in between the first and second absorbent core layer. However, it is desired that no such substrates are positioned between the first and second absorbent core layer and that the first layer of superabsorbent polymer particles is separated from the second layer of superabsorbent polymer particles only the a fibrous layer of first core adhesive.



FIG. 3 shows a single absorbent core layer. The superabsorbent polymer particles 66 are deposited on the first carrier substrate 64 in clusters 90 of particles comprising land areas 92 and junction areas 96 between the land areas 94. In the land areas 94, the first core adhesive 94 may not contact the first carrier substrate 64 or the optional second core adhesive directly; junction areas 96 are areas where the first core adhesive 94 contacts the first carrier substrate 64 or the optional second core adhesive directly. The junction areas 96 contain little or no superabsorbent polymer material 66. The land areas 94 and junction areas 96 can have a variety of shapes including, but not limited to, circular, oval, square, rectangular, triangular, and the like.


By applying the first core adhesive 94 as a fibrous layer, the first core adhesive 94 entangles the superabsorbent polymer particles 66, and thereby immobilizes the particles. In a further aspect, the first core adhesive 94 bonds to the carrier substrate 64 and thus affixes the superabsorbent polymer particles 66 to the carrier substrate 64. In another embodiment, the first core adhesive 68 may also penetrate to a certain extent into the carrier substrate 64, thus providing for further immobilization and affixation.


As already explained above, the first and second carrier substrates 64 and 72 may be adhered to one another with adhesive about the periphery to form an envelope about the superabsorbent polymer particles 66 to hold the superabsorbent polymer particles 66 within the absorbent core 14.


As best seen in FIG. 4, the first and second absorbent core layers 60 and 62 are combined to form the absorbent core 14.


The first and second absorbent core layers 60 and 62 may be combined together to form the absorbent core 14 with the absorbent core layers being offset such that the superabsorbent polymer particles 66 on the first carrier substrate 64 and the superabsorbent polymer particles 66 on the second carrier substrate 72 taken in combination are substantially continuously distributed across the superabsorbent polymer particle area. In a certain embodiment, the superabsorbent polymer particles 66 are substantially continuously distributed across the superabsorbent polymer particle area while the superabsorbent polymer particles 66 of the respective first and second absorbent core layer alone are discontinuously distributed across the first and second carrier substrates 64 and 72 in clusters 90. In a certain embodiment, the absorbent core layers may be offset such that the land areas 92 of the first absorbent core layer 60 face the junction areas 96 of the second absorbent core layer 62 and the land areas 92 of the second absorbent core layer 62 face the junction areas 96 of the first absorbent core layer 60. When the land areas 92 and junction areas 96 are appropriately sized and arranged, the resulting combination of superabsorbent polymer particles 66 are a substantially continuous layer of superabsorbent polymer particles across the superabsorbent polymer particle area of the absorbent core 14.


According to the present disclosure, the superabsorbent polymer particles is typically present in an amount greater than about 85% by weight of the absorbent core, or greater than about 90% by weight of the absorbent core, or greater than about 95% by weight of the absorbent core. Also, the superabsorbent polymer particles may present more than 95% of the absorbent material comprised by the absorbent core. The absorbent core may comprise less than 5% of airfelt (i.e. cellulose fibers). Typical absorbent materials are superabsorbent polymer particles, airfelt (i.e. cellulose fibers) and—less frequently used—absorbent foams. Typically, the absorbent core comprises from 50 g/m2 to 2200 g/m2 of the superabsorbent polymer particles, from 100 g/m2 to 1500 g/m2 or even from 200 g/m2 to 1200 g/m2.


According to the present disclosure, the amount of superabsorbent polymer particles may or may not vary along the length of the absorbent core, typically the absorbent core being profiled in its longitudinal direction. It has been found that, for disposable diapers, the liquid discharge occurs predominately in the front half of the disposable diaper. The front half of the absorbent core 14 should therefore comprise most of the absorbent capacity of the absorbent core. Thus, the front half of the absorbent core 14 may comprise more than about 60% by weight of the total amount of superabsorbent polymer particles comprised by the absorbent core, or more than about 65% by weight, 70% by weight, 75% by weight, 80% by weight, 85% by weight, or 90% by weight of the superabsorbent polymer particles.


Typically the first core adhesive may serve to at least partially immobilize the superabsorbent polymer particles both in dry and wet state. The first core adhesive can be disposed essentially uniformly within the absorbent particulate polymer particles between the superabsorbent polymer particles. However, typically the first core adhesive 94 may be provided as a fibrous layer which is at least partially in contact with the superabsorbent polymer particles 66 and partially in contact with the first carrier substrate 64 and—if present—the optional second carrier substrate 72. Typically, the first core adhesive 94 forms a fibrous network over the superabsorbent polymer particles 66 of each absorbent core layer. As for example illustrated in FIG. 4, the superabsorbent polymer particles 66 may be provided as a discontinuous layer, and a layer of first core adhesive 94 is laid down onto the layer of superabsorbent polymer particles 66 and 74, such that the first core adhesive 94 is in direct contact with the superabsorbent polymer particles 66, but also in direct contact with the surfaces 80 and 84 of the carrier substrates 64 and 72 facing towards the superabsorbent polymer particles 66 of the absorbent core 14, in locations where the carrier substrates 64, 72 are not covered by the superabsorbent polymer particles 66. This imparts an essentially three-dimensional structure to the fibrous layer of first core adhesive 94, which in itself is essentially a two-dimensional structure of relatively small thickness, as compared to the dimension in length and width directions. In other words, the first core adhesive 94 undulates between the superabsorbent polymer particles 66 and the surfaces 80, 84 of the carrier substrates 64 and 72 facing towards the superabsorbent polymer particles of the absorbent core 14.


The first core adhesive may 94 provide cavities to cover the superabsorbent polymer particles, and thereby immobilizes this material. In a further aspect, the first core adhesive bonds to the carrier substrate(s) and thus affixes the superabsorbent polymer particles to the carrier substrate(s). Of course, while the first core adhesives disclosed herein provide an improved wet immobilization (i.e., immobilization of superabsorbent polymer particles when the disposable diaper and thus the absorbent core at least partially is wetted), these first core adhesives may also provide a good immobilization of superabsorbent polymer particles when the absorbent core is dry.


Superabsorbent Polymer Particles


The superabsorbent polymer particles may be of numerous shapes. The term “particles” refers to granules, fibers, flakes, spheres, powders, platelets and other shapes and forms known to persons skilled in the art of superabsorbent polymer particles. E.g. the particles can be in the form of granules or beads, having a particle size from about 10 μm to about 1000 μm, alternatively from about 100 μm to about 1000 μm, alternatively from about 150 μm to about 850 μm and alternatively from about 150 μm to about 500 μm. In another embodiment, the superabsorbent polymer particles can be in the shape of fibers, i.e. elongated, acicular superabsorbent polymer particles. In those embodiments, the superabsorbent polymer fibers have a minor dimension (i.e. diameter of the fiber) of less than about 1 mm, usually less than about 500 μm, and alternatively less than 250 μm down to 50 μm. The length of the fibers may be about 3 mm to about 100 mm. The fibers can also be in the form of a long filament that can be woven.


Some superabsorbent polymer particles of the present disclosure are spherical-like particles. According to the present disclosure and in contrast to fibers, “spherical-like particles” have a longest and a smallest dimension with a particulate ratio of longest to smallest particle dimension in the range of 1-5, where a value of 1 would equate a perfectly spherical particle and 5 would allow for some deviation from such a spherical particle.


The superabsorbent polymer particle materials useful in the present disclosure include a variety of water-insoluble, but water-swellable polymers capable of absorbing large quantities of fluids. Such polymers materials are generally known in the art and include all those well-known polymers used or deemed useful in the context of disposable absorbent article technology.


Example polymer materials for use in making superabsorbent polymer particles are slightly network cross linked polymers of partially neutralized polyacrylic acids and starch derivatives thereof. Starch-based superabsorbent polymer particles are also encompassed in the present disclosure. The superabsorbent polymer particles may comprise from 25% to 95% by weight, alternatively from 50% to 80% by weight neutralized, slightly network cross-linked, polyacrylic acid. Network cross-linking renders the polymer substantially water-insoluble and, in part, determines the absorptive capacity and extractable polymer content characteristics of the superabsorbent polymer particles.


While the superabsorbent polymer particles may be of one type (i.e., homogeneous), mixtures of polymers can also be used in the present disclosure. The superabsorbent polymer particles can also comprise mixtures with low levels of one or more additives, such as for example powdered silica, surfactants, adhesive, binders, and the like. Furthermore, the superabsorbent polymer particles can comprise a gradient in particle size or can comprise a certain range of particle size.


Many of the formerly known superabsorbent polymer particles exhibited gel blocking “Gel blocking” occurs when particles made of the superabsorbent polymer materials are wetted and the particles swell so as to inhibit fluid transmission to other zones or regions of the absorbent structure. Wetting of these other regions of the absorbent core therefore takes place via a very slow diffusion process. In practical terms, this means acquisition of fluids by the absorbent structure is much slower than the rate at which fluids are discharged, especially in gush situations. Leakage from the disposable diaper can take place well before the superabsorbent polymer particles in the absorbent core are even close to being fully saturated or before the fluid can diffuse or wick past the “blocking” particles into the rest of the absorbent core.


One commonly applied way to reduce gel blocking is to make the particles stiffer, which enables the superabsorbent polymer particles to retain their original shape thus creating or maintaining void spaces between the particles. A well-known method to increase stiffness is to covalently and/or ionically cross-link the carboxyl groups exposed on the surface of the superabsorbent polymer particles. This method is commonly referred to as surface cross-linking


First and Second Core Adhesive


The first and optional second core adhesive comprised by the absorbent core may be a hot melt adhesive. In certain embodiments, the first core adhesive is a hot melt adhesive whereas the second core adhesive may be another type of adhesive. The average basis weight of first plus optional second core adhesive in the absorbent core may be from 0.5 g/m2 to 30 g/m2, between 1 g/m2 to 15 g/m2, between 1 g/m2 and 10 g/m2 or even between 1.5 g/m2 and 5 g/m2.


The first core adhesive serves to at least partially immobilize the superabsorbent polymer particles of the absorbent core, both in dry and wet condition.


Without wishing to be bound by theory, it has been found that those hot melt adhesives which are most useful for immobilizing the superabsorbent polymer particles combine good cohesion and good adhesion behavior. Good adhesion may promote good contact between the hot melt adhesive and the superabsorbent polymer particles and the carrier substrates. Good cohesion reduces the likelihood that the adhesive breaks, in particular in response to external forces, and namely in response to strain. When the absorbent core absorbs liquid, the superabsorbent polymer particles swells and subjects the hot melt adhesive to external forces. The hot melt adhesive may allow for such swelling, without breaking and without imparting too many compressive forces, which would restrain the absorbent particulate polymer particles from swelling.


In accordance with present disclosure the hot melt adhesive may comprise, in its entirety, a single thermoplastic polymer or a blend of thermoplastic polymers, having a softening point, as determined by the ASTM Method D-36-95 “Ring and Ball”, in the range between 50° C. and 300° C., or alternatively the hot melt adhesive may comprise at least one thermoplastic polymer in combination with other thermoplastic diluents such as tackifying resins, plasticizers and additives such as antioxidants.


In certain embodiments, the thermoplastic polymer typically has a weight average molecular weight (Mw) of more than 10,000 and a glass transition temperature (Tg) usually below room temperature (25° C.), or of less than 22° C., or less than 18° C., or less than 15° C. In certain embodiments Tg may be above 0° C.>Tg. In embodiments where the thermoplastic polymer has more than one Tg the values given refer to the lowest glass transition temperature. The thermoplastic polymer may also have a softening point, as determined by the ASTM Method D-36-95 “Ring and Ball”, in the range between 50° C. and 300° C. In some embodiments the Mw of the thermoplastic polymer is less than 10000000.


In certain embodiments, typical concentrations of the thermoplastic polymer in a hot melt adhesive are in the range of about 20% to about 40% by weight of the hot melt adhesive.


Exemplary polymers are (styrenic) block copolymers including A-B-A triblock structures, A-B diblock structures and (A-B)n radial block copolymer structures wherein the A blocks are non-elastomeric polymer blocks, typically comprising polystyrene, and the B blocks are unsaturated conjugated diene or (partly) hydrogenated versions of such. The B block is typically isoprene, butadiene, ethylene/butylene (hydrogenated butadiene), ethylene/propylene (hydrogenated isoprene), and mixtures thereof.


Other suitable thermoplastic polymers that may be employed are metallocene polyolefins, which are ethylene polymers prepared using single-site or metallocene catalysts. Therein, at least one comonomer can be polymerized with ethylene to make a copolymer, terpolymer or higher order polymer. Also applicable are amorphous polyolefins or amorphous polyalphaolefins (APAO) which are homopolymers, copolymers or terpolymers of C2 to C8 alpha olefins.


In exemplary embodiments, the tackifying resin has typically a Mw below 5,000 and a Tg usually above room temperature (25° C.), typical concentrations of the tackifying resin in a hot melt are in the range of about 30% to about 60% by weight of the hot melt adhesive. In certain embodiments the tackifying resin has an Mw of more than 1,000.


The plasticizer has a low Mw of typically less than 1,000 and a Tg below room temperature, with a typical concentration of about 0% to about 15% by weight of the hot melt adhesive. In certain embodiments the plasticizer has an Mw of more than 100.


In certain embodiments, the first and/or second core adhesive is hot melt adhesive present in the form of fibers. In some embodiments, the fibers will have an average thickness of about 1 to about 50 micrometers or about 1 to about 35 micrometers and an average length of about 5 mm to about 50 mm or about 5 mm to about 30 mm.


The absorbent core may also comprise a second core adhesive which is not illustrated in the figures. The second core adhesive may be deposited on the carrier substrate before application of the superabsorbent polymer particles on the carrier substrate for enhancing adhesion of the superabsorbent polymer particles and the first core adhesive to the respective carrier substrate. The second core adhesive may also aid in immobilizing the superabsorbent polymer particles and may be the same adhesive as the first core adhesive or may be different from the first core adhesive. The second core adhesive may also be a hot melt adhesive. An example of commercially available second core adhesive is H. B. Fuller Co. (St. Paul, Minn.) Product No. HL-1620-B. The second core adhesive may be applied to the carrier substrate(s) by any suitable means, but according to certain embodiments, may be applied in about 0.5 to about 1 mm wide slots spaced about 0.5 to about 2 mm apart.


Attachment of Absorbent Core to Backsheet


If a disposable diaper is applied onto a wearer, the disposable diaper will take a curved shape in order to conform to the wearer (i.e. the diaper will not be flattened out but will be bent with the front and back waist regions of the diaper lying against the waist of the wearer and the crotch region of the diaper being placed against the crotch region of the wearer). Moreover, the diaper is subjected to a certain degree of bending along lines which are substantially parallel to the longitudinal axis of the diaper between the wearer legs and towards the front waist region. Such bending results in buckling of the diaper, i.e. the diaper is bulged outwardly in the crotch region and in at least parts of the front waist region.


Upon applying the disposable diaper onto a wearer by bending it, the surface areas of the disposable diaper is altered as follows versus a flattened out diaper: While the upper, wearer-facing surface (i.e. the topsheet) is upset and upended, the lower, garment-facing surface (i.e. the backsheet) is elongated. The same applies for the absorbent core within the disposable diaper: The upper, wearer-facing surface (such as the second, upper carrier substrate) is upset and upended while the lower, garment-facing surface (such as the first, lower carrier substrate) is elongated.


In the vast majority of disposable diapers on the market today, the absorbent core comprises a considerable amount of cellulose fibers (airfelt). The superabsorbent polymer particles comprised in these absorbent cores are mixed with the cellulose fibers and the particles are thus held in place in the interstices between the cellulose fibers. Generally, no adhesive is used to immobilize the superabsorbent polymer particles. Overall, these absorbent cores have a rather plastic characteristic. If such diapers undergo the bending described above when the disposable diaper is applied onto a wearer, the material within the absorbent core is able to compensate at least some of the upending of the upper surface and the elongation of the lower surface by migration of cellulose fibers and superabsorbent polymer particles within the core.


Also, when the disposable diaper gets wetted and the superabsorbent polymer particles swell and expand, the superabsorbent polymer particles can to a certain extent swell within the interstices of the cellulose fibers. Hence, the volume increase of the absorbent core as a whole is less than the volume increase of the superabsorbent polymer particles because the dry absorbent core provides some free space into which the particles can expand.


In an absorbent core of the present disclosure, which comprises little or no airfelt and wherein the superabsorbent polymer particles are immobilized by an adhesive, the absorbent core has a much more elastic characteristic compared to the conventional absorbent core described above. As the superabsorbent polymer particles are immobilized much stronger than superabsorbent polymer particles which are simply mixed within a cellulose fiber matrix, the superabsorbent polymer particles cannot migrate within the absorbent core when the disposable diaper is applied onto a wearer. Therefore, the buckling of the upper, wearer-facing surface as well as the elongation of the lower, garment-facing surface is much more pronounced as in conventional, airfelt-containing disposable diapers.


Also, as the disposable diaper is wetted, the superabsorbent polymer particles swell and expand. Contrary to a conventional, airfelt-containing absorbent core, an absorbent core having little or no airfelt may not provide any “free space” in the interstices between the cellulose fibers, into which the superabsorbent polymer particles can expand. Thus, the absorbent core as a whole will expand and swell much earlier (i.e. much longer before the absorption capacity limit of the absorbent core is reached) and will expand much more compared to a conventional absorbent core. Such expansion increases the strain applied onto the lower, garment-facing surface (such as the lower carrier substrate) of the absorbent core and, in turn, increases the strain applied onto the backsheet. Consequently, the lower, garment-facing surface of the absorbent core as well as the backsheet will elongate further upon wetting of the diaper.


As a consequence of the elongation of the wearer-facing surface, the absorbent core is firmly pressed against the backsheet of the disposable diaper. Upon absorption of urine and runny feces, the absorbent core is stained and, due to the dense contact between the absorbent core and the backsheet, the staining may be visible through the backsheet, especially if the basis weight of the backsheet material is low and/or if the backsheet has a little or no printing. This see-through of stains has a negative impact on consumer acceptance of the disposable diaper, as it is perceived as low quality. Moreover, the see-through is often interpreted as indicating wet-through, i.e. the absorbent core is perceived as being soaked with liquid, signaling that the absorbent core has reached its capacity maximum—even if in fact the diaper is far from reaching its maximum capacity. Also the backsheet may be perceived as being wet upon visual inspection of the disposable diaper.


Furthermore, upon elongation and straining of the backsheet, the backsheet tends to buckle and form wrinkles and tension lines. These tension lines and wrinkles are interpreted by consumers as signals that the absorbent capacity of the disposable diaper is exhausted and the diaper needs to be changed. This effect may occur long before the actual capacity limit of the diaper is reached.


The inventors have found that the above explained disadvantages can be reduced if the attachment of absorbent core to backsheet is altered: In conventional, airfelt-containing disposable diapers as well as in commercially available disposable diapers having little or no airfelt (e.g. Pampers “Active Fit” sold in Germany in May 2011), the absorbent core is adhesively attached to the backsheet over the complete garment-facing surface of the absorbent core (hence, e.g. the first carrier substrate of the absorbent core). This does not necessarily mean that 100% of the surface area of the carrier substrate are covered with adhesive but it may be that the adhesive, such as hot melt adhesive, is applied in small spirals and these spirals are applied all over the carrier substrate.


If the absorbent core is adhesively attached to the backsheet over essentially the whole area of the absorbent core, the absorbent core cannot move and expand independently from the backsheet. Consequently, as the absorbent core expands upon swelling of the superabsorbent polymer particles, the backsheet will also have to expand.


It has been found that this drawback can be reduced if the absorbent core is not attached to the backsheet over the whole absorbent core surface. If the absorbent core is attached to the backsheet only in certain, limited areas, and if these areas are carefully and meaningfully chosen, the formation of buckles and wrinkles in the backsheet can be reduced. Also, see-through of urine stains from the absorbent core through the backsheet can be reduced.


According to the present disclosure, the absorbent core is attached to the backsheet in any of the following locations:

    • a) The absorbent core is attached to the backsheet of the disposable diaper in attachment zones adjacent to the front lateral edge and the back lateral edge of the absorbent core and the absorbent core is unattached to the backsheet in any other region; or
    • b) the absorbent core is attached to the backsheet of the disposable diaper in the crotch region of the absorbent core in one or more attachment zone(s) on or adjacent to the longitudinal axis of the absorbent core, wherein the one or more attachment zone(s) cover from 0.2% to 3% of the total surface area of the absorbent core, and the absorbent core is unattached to the backsheet in any other region; or
    • c) the absorbent core is attached to the backsheet of the disposable diaper in the crotch region of the absorbent core in attachment zones adjacent to the longitudinal side edges of the absorbent core and the absorbent core is unattached to the backsheet in any other region; or
    • d) the absorbent core is attached to the backsheet of the disposable diaper in combinations of any of the attachment zones defined in a) to c) and the absorbent core is unattached to the backsheet in any other region.


If the absorbent core is attached to the backsheet according to option a), the attachment zones adjacent the front lateral edge and the back lateral edge of the absorbent core may be provided only in the corners of the absorbent core, leaving the remaining area adjacent the front lateral edge and the back lateral edge of the absorbent core unattached to the backsheet. The “remaining area” refers to 70%, or 80% of the width of the absorbent core in the area adjacent to the front and back lateral edges. The one or more attachment zone(s) of option a) or d) may cover from 0.2% to 3%, alternatively from 0.5% to 2%, or from 0.5% to 1.5%, or from 0.2% to 1.5% or from 0.2% to 1% of the total surface area of the absorbent core. These percentages refer to the totality of all attachment zones taken together.


In embodiments according to option a), the absorbent core may be attached to the backsheet in one attachment zone adjacent to the front lateral edge and in one attachment zone adjacent to the back lateral edge of the absorbent core and may be unattached to the backsheet in any other region. Alternatively, the absorbent core may be attached to the backsheet in two, three or more attachment zones adjacent to the front lateral edge and in two, three or more attachment zones adjacent to the back lateral edge of the absorbent core and may be unattached to the backsheet in any other region. In still another alternative, the absorbent core may be attached to the backsheet in one attachment zone adjacent to the front lateral edge of the absorbent core and in two, three or more attachment zones adjacent to the back lateral edge and be unattached to the backsheet in any other region; or may be attached to the backsheet in two, three or more attachment zones adjacent to the front lateral edge of the absorbent core and in one attachment zone adjacent to the back lateral edge and be unattached to the backsheet in any other region.


In embodiments according to option c), the absorbent core may be attached to the backsheet in one attachment zone adjacent to one longitudinal side edge and in one attachment zone adjacent to the respective other longitudinal side edge and may be unattached to the backsheet in any other region. Alternatively, the absorbent core may be attached to the backsheet in two, three or more attachment zones adjacent to one longitudinal side edge and in two, three or more attachment zones adjacent to the respective other longitudinal side edge of the absorbent core and may be unattached to the backsheet in any other region. In still another alternative, the absorbent core may be attached to the backsheet in one attachment zone adjacent to one longitudinal side edge of the absorbent core and in two, three or more attachment zones adjacent to the respective other longitudinal side edge and be unattached to the backsheet in any other region.


If the absorbent core is attached to the backsheet according to option b), the one or more attachment zone(s) in the crotch region may have a longitudinal direction substantially parallel to the longitudinal direction of the absorbent core and may have a lateral direction substantially parallel to the lateral direction of the absorbent core. The ratio between longitudinal direction and lateral direction of the one or more attachment zone(s) may be from 0.5 to 2.0, or from 2.0 to 0.5, or from 0.5 to 1.0, or from 1.0 to 0.5. The one or more attachment zone(s) of option b) cover from 0.2% to 3%, alternatively from 0.5% to 2%, or from 0.5% to 1.5%, or from 0.2% to 1.5% or from 0.2% to 1% of the total surface area of the absorbent core. These percentages refer to the totality of all attachment zones taken together. Also, if the absorbent core is attached to the backsheet according to option b), the disposable diaper may further comprise a wetness indicator with the wetness indicator being placed between the absorbent core and the backsheet in at least one of the one or more attachment zone(s) in the crotch region of the absorbent core on or adjacent to the longitudinal axis of the absorbent core.


The term “adjacent to the front lateral edge and the back lateral edge of the absorbent core”, as used herein, means a distance of less than 15%, or less than 10%, or less than 5% (based on the total length of the absorbent core) inwardly, starting from the front lateral edge (for attachment zone(s) adjacent to the front lateral edge) and back lateral edge (for attachment zone(s) adjacent to the back lateral edge), respectively, and extending along or parallel to the longitudinal axis of the absorbent core towards the crotch zone.


The term “adjacent to the longitudinal axis of the absorbent core”, as used herein, means that the attachment zone is either on the longitudinal axis or is at a distance of less than 15%, or less than 10%, or less than 5% (based on the total width of the absorbent core) away from the longitudinal axis towards the left or right longitudinal side edge. For embodiments having more than one attachment zone adjacent to the longitudinal axis of the absorbent core, the attachment zones may be at a distance of less than 15%, or less than 10%, or less than 5% (based on the total width of the absorbent core) away from the longitudinal axis towards the left and right longitudinal side edge.


The term “adjacent to the longitudinal side edges of the absorbent core” as used herein, means a distance of less than 15%, or less than 10%, or less than 5% (based on the total width of the absorbent core) inwardly, starting from the left and right longitudinal edge, respectively, and extending along or parallel to the transverse axis of the absorbent core towards the crotch zone.


The total surface area of the absorbent core is defined by the x- and y-dimension of the absorbent core. Any potential unevenness of the surface and irregularities of thickness (i.e. in the z-direction) is not taken into account. The x-,y-dimension of the absorbent core is determined while the absorbent core is lying flat on a table with not stress or strain applied (this also applies for potentially extensible absorbent cores). If needed, elastically contracting elements that otherwise would apply strain to the absorbent core can be carefully removed prior to lying the absorbent core flat on a table.


Attaching the absorbent core to the backsheet according to any of options a) to d) above, the absorbent core, while expanding upon liquid absorption, may slide relative to the backsheet, thus the absorbent core may expand largely independently from the backsheet and not forcing the backsheet to expand together with the absorbent core. Hence, the formation of wrinkles and tension lines in the backsheet can be reduced. Also, see-through of urine strains through the backsheet can be reduced (as the absorbent core is not held as closely against the backsheet as in embodiments where the absorbent core is attached to the backsheet over the whole absorbent core area). This is believed to be due to the formation of a small air-cushion between the absorbent core and the backsheet, which cannot be formed in areas, where the absorbent core is closely attached (e.g. by adhesive) to the backsheet. To reduce see-through, a very small air-cushion is believed to be sufficient. For visualizing the reduction of see-through, the test method set out below can be used. This test method allows a qualitative visualization with the naked eye (i.e. without the need for microscope or the like).


In the disposable diapers of the present disclosure, the topsheet may be sealed to the backsheet along the perimeter of the topsheet and backsheet, i.e. outside the areas, where the absorbent core is encased between the topsheet and backsheet. To allow the absorbent core to expand between the topsheet and backsheet, the topsheet may be sealed to the backsheet at a distance away from the perimeter of the absorbent core, especially in the transverse direction, i.e. along the longitudinal side edges of the absorbent core. The seal between the topsheet and the backsheet along the longitudinal side edges of the absorbent core may be such, that the width of the absorbent core is less than 90%, alternatively less than 85% of the width between the longitudinal side edge seals between the topsheet and the backsheet. If the width of the absorbent core and/or the width between the longitudinal side edge seals between the topsheet and the backsheet varies along the length of the disposable diaper, the width of the absorbent core may be less than 90%, alternatively less than 85% of the width between the longitudinal side edge seals between the topsheet and the backsheet at every location along the length of the disposable diaper.


Attaching the absorbent core to the backsheet in attachment zones adjacent to the front lateral edge and the back lateral edge of the absorbent core or in attachment zones adjacent to the longitudinal side edges of the absorbent core has the benefit, that the absorbent core cannot twist or even roll over in the disposable diaper, as it is held in place in more than one location. This is especially advantageous for certain manufacturing processes, where individual absorbent cores are placed onto an endless web of backsheet material (which is cut into individual backsheets only at a later stage in the manufacturing process). The topsheet is placed on top of the absorbent core only after the absorbent core has been placed onto the endless backsheet material, typically in form of an endless web of topsheet material, which is cut into individual topsheets at a later stage together with the backsheet. Hence, at a certain stage, the absorbent core is lying on top of the backsheet with no overlying components. The absorbent core, besides being attached to the endless web of backsheet material in the attachment zones, is typically held onto the backsheet by a vacuum, which is underneath the backsheet. However, at this stage, there is a risk that the absorbent core lifts from the backsheet especially in high speed manufacturing processes. Thus, attaching the absorbent core to the backsheet in more than one attachment zone, as is the case in option a), c) and d) set out above, bears a reduced risk of absorbent core lift up versus option b), wherein the absorbent core is attached to the backsheet only in one location.


However, attaching the absorbent core to the backsheet only in one location is nevertheless possible, if the manufacturing process is adapted accordingly (i.e. higher vacuum, slower speed of manufacturing line, or joining the absorbent core and the topsheet onto the backsheet at the same time.). Attaching the absorbent core to the backsheet according to option b), i.e. only in one attachment zone has the advantage that expansion of the wetted absorbent core is not hindered both parallel to the longitudinal axis and parallel to the transverse axis of the absorbent core.


Once the topsheet has been placed on top of the absorbent core, the topsheet can be sealed to the backsheet around the perimeter of the topsheet and backsheet, which can be done prior to or after cutting the endless topsheet and backsheet material into individual topsheets and backsheets. Also, the topsheet may be attached to the absorbent core once the topsheet has been put onto the absorbent core.


As see—through is reduced, the present disclosure allow using low basis weight backsheet materials. The backsheet of the disposable diaper of the present disclosure may consist of a film and optionally one or more nonwoven webs. The basis weight of the backsheet including film and optional nonwoven webs may be less than 70 g/m2, or may be from 25 g/m2 to 70 g/m2, or from 25 g/m2 to 60 g/m2 or from 25 g/m2 to 50 g/m2. The film (without nonwoven webs) may have a basis weight of less than 25 g/m2, or from 10 g/m2 to 25 g/m2, or from 10 g/m2 to 20 g/m2. The optional nonwoven webs may have a basis weight of less than 40 g/m2, or from 10 g/m2 to 30 g/m2, or from 10 g/m2 to 25 g/m2 (in embodiments having more than one nonwoven web, these values represent the sum for all nonwoven webs taken together).


Also, according to the present disclosure, the backsheet may be white and may have a printed area (with non-white colors) of less than 50%, or less than 30% in the area which is coincident with the front region and crotch region of the absorbent core.


The backsheet of the disposable diaper of the present disclosure may not be elastic. Non-elastic materials are generally less expensive compared to elastic materials and given that the absorbent core is able to expand independently from the backsheet to some extent, it is not necessary that the backsheet is elastic. Hence, the backsheet of the present disclosure may be non-elastic or highly non-elastic.


The absorbent core may be attached to the topsheet of the disposable diaper. As the topsheet is typically only attached to the backsheet at the perimeter of the topsheet and backsheet, such attachment to the topsheet will not adversely affect the advantages of the present disclosure, namely reduced see-through and reduced formation of wrinkles and tension lines in the backsheet. The absorbent core may be attached to the topsheet at least in the front region and in the crotch region of the absorbent core. The absorbent core may be directly attached to the topsheet. Alternatively, in disposable diapers having an acquisition system between the topsheet and the absorbent core, the absorbent core may be attached to the acquisition system, which in turn is attached to the topsheet. Attachment of absorbent core to the topsheet or acquisition system may be done adhesively, for example using hot melt adhesive.


Attachment of the absorbent core to the backsheet according to the present disclosure may be done with adhesive, optionally a hot melt adhesive. The attachment is directly between the absorbent core and the backsheet. If the absorbent core has a first carrier substrate, the attachment is between the garment-facing surface of the lower carrier substrate and the wearer-facing surface of the backsheet.


The absorbent core of the present disclosure may comprise one or more channels, i.e. areas which are substantially free of superabsorbent polymer particles and which are not provided adjacent the edges of the absorbent core but in some other location. “Substantially free of superabsorbent polymer particles”, as used herein, means that e.g. due to process-related reasons, a small, negligible amount of superabsorbent polymer particles may be present in the gaps, which however does not contribute to the overall functionality. The term “substantially free of superabsorbent polymer particles” encompasses “free of superabsorbent polymer particles”. The channels may be provided in the crotch region and/or in the front region of the absorbent core. The channels are elongated and may have a width to length ratio of 1 to 20, or 1 to 15, or 1 to 10, or 1 to 5, or 1 to 3. The channels may be straight or may be curved. Such channels can further help to improve the conformity of the disposable diaper, i.e. the diaper conforms better to the wearer. This can further help to reduce the tension lines and wrinkles of the backsheet discussed above. If the absorbent core comprises one or more channels, the attachment zones, where the absorbent core is attached to the backsheet, may be outside the area(s) which is (are) provided with the one or more channels. The channels may not extend onto the front and back lateral edges and longitudinal edges of the absorbent core.


The absorbent core of the present disclosure may further have a first carrier substrate, which is the substrate of the absorbent core that is lying directly on top of the backsheet. If the absorbent core comprises one or more channels, first carrier substrate may be water permeable (at 25° C. and 50% RH) (such as a tissue web or a water permeable nonwoven web). In such embodiments, a certain amount of liquid (urine) may penetrate through the complete thickness of the absorbent core and may be distributed in the space between the absorbent core and the backsheet. Thus, liquid distribution may be improved, as the liquid may spread between the absorbent core and the backsheet to other, more remote areas where it can be absorbed by the absorbent core. Taken in combination with the attachment zones of the present disclosure, where the absorbent core is attached to the backsheet and is left unattached to the backsheet in any other region, the liquid between the absorbent core and the backsheet can spread relatively unobstructed. However, in these absorbent cores, the size of the one or more channels has to be chosen carefully to ensure that the amount of liquid passing through the thickness of the absorbent core in the space between the absorbent core and the backsheet does not become too extensive.


Test Method to Visualize Backsheet See-Through


This method visualizes the see-through of stains through the backsheet of a disposable diaper. The test can be carried out with disposable diapers having different pattern and extent absorbent core attachment to backsheet to qualitatively visualize the differences. The load protocol used is for disposable diapers typically designated for wearers having a weight in the range of 8 to 13 kg±20% (such as Pampers “Active Fit”, Size 4 or other Pampers baby diapers Size 4, Huggies baby diapers Size 4 and baby diapers Size 4 of most other tradenames).


Apparatus Load Protocol


The test apparatus is shown in FIG. 6 and comprises a trough 111 made of polycarbonate (e.g. Lexan®) nominally 12.5 mm (0.5 inch) in thickness. The trough 111 comprises a rectilinear horizontal base 112 having a length of 508 mm (20.0 inches), and a width of 152 mm (6.0 inches). Two rectilinear vertical sides 113 64 mm (2.5 inches) tall×508 mm (20 inches) in length are affixed to the long edges of the base 112 to form a U-shaped trough 111 having a length of 508 mm (20.0 inches), an internal width of 152 mm (6.0 inches), and an internal depth of 51 mm (2.0 inches). The front and back ends of the trough 111 are not enclosed.


A slab of open-cell polyurethane foam 114 with dimensions 508×152×25 mm is wrapped in polyethylene film and placed in the bottom of the trough 111 in such a way that the edges of the foam 114 and the trough 111 are aligned, and the upper surface of the polyethylene film is smooth and free of seams, wrinkles or imperfections. The polyurethane foam 114 has a compressive modulus of 0.48 psi. A reference line is drawn across the width of the upper surface of the polyethylene cover 152 mm (6.0 inches) from one end (the front edge) parallel to the transverse centerline using an indelible marker.


A rectilinear polycarbonate top plate 115 has a nominal thickness of 12.5 mm (0.5 inch), a length of 508 mm (20.0 inches), and a width of 146 mm (5.75 inches). A 51 mm (2.0 inch) diameter hole is bored in the center of the top plate 115 (i.e. the center of the hole is located at the intersection of the longitudinal and transverse axes of the upper surface of the top plate 115). A polycarbonate cylinder 116 with an outside diameter of 51 mm (2.0 inches), an internal diameter of 37.5 mm (1.5 inches) and a height of 102 mm (4.0 inches) is glued into the hole in the top plate 115 so that the bottom edge of the cylinder 116 is flush with the lower surface of the top plate 115 and the cylinder 116 protrudes vertically 89 mm (3.5 inches) above the upper surface of the top plate 115, and the seam between the cylinder 116 and the top plate 115 is watertight. An annular recess 117 with a height of 2 mm and a diameter of 44.5 mm (1.75 inches) is machined into the bottom internal edge of the cylinder 116. Two 1 mm diameter holes are drilled at a 45° angle to the upper surface of the top plate 115 so that the holes intersect the inner surface of the cylinder 116 immediately above the recess 117 and are at opposite sides of the cylinder 116 (i.e. 180° apart). Two stainless steel wires 118 having a diameter of 1 mm are glued into the holes in a watertight fashion so that one end of each wire is flush with the inner cylinder wall and the other end protrudes from the upper surface of the top plate 115. These wires are referred to as electrodes herein below. A reference line is scribed across the width of the top plate 115 152 mm (6.0 inches) from the front edge parallel to the transverse centerline. The top plate 1415/cylinder 116 assembly has a weight of approximately 1180 grams.


Two steel weights each weighing 0.9 Kg and measuring 127 mm (5 inches) wide, 50 mm (1.97 inches) deep, and approximately 16 mm (0.63 inches tall) are also required.


Procedure


All testing is carried out at 23±2° C. and 35±15% relative humidity.


The polycarbonate trough 111 containing the wrapped foam slab 114 is placed on a suitable flat horizontal surface. A disposable absorbent product is removed from its packaging and the cuff elastics are cut at suitable intervals to allow the product to lay flat. The product is weighed to within ±0.1 grams on a suitable top-loading balance then placed on the covered foam slab 114 in the acquisition apparatus with the front waist edge of the product aligned with the reference mark on the polyethylene cover. The product is centered along the longitudinal centerline of the apparatus with the topsheet (body-side) of the product facing upwards and the rear waist edge toward the rear end of the foam slab 114. The top plate 115 is placed on top of the product with the protruding cylinder facing upwards. The scribed reference line is aligned with the front waist edge of the product and the rear end of the top plate 115 is aligned with the rear edge of the foam slab 114. The two 0.9 Kg weights are then gently placed onto the top plate 115 so that the width of each weight is parallel to the transverse centerline of the top plate, and each weight is 83 mm (3.25 inches) from the front or rear edge of the top plate 115.


A suitable electrical circuit is connected to the two electrodes to detect the presence of an electrically conductive fluid between them.


A suitable pump; e.g. Model 7520-00 supplied by Cole Parmer Instruments, Chicago, USA, or equivalent; is set up to discharge a 0.9 mass % aqueous solution of sodium chloride through a flexible plastic tube having an internal diameter of 4.8 mm ( 3/16 inch), e.g. Tygon® R-3603 or equivalent. The 0.9% NaCl solution is stained with Indigo carmine (C16H8N2Na2O8S2) by Merck (104724 Indigocarmin C.I. 73015), using 40 mg per liter of 0.9% NaCl solution. The end portion of the tube is clamped vertically so that it is centered within the cylinder 116 attached to the top plate 115 with the discharge end of the tube facing downwards and located 50 mm (2 inches) below the upper edge of the cylinder 116. The pump is operated via a timer and is pre-calibrated to discharge a gush of 90.0 ml of the 0.9% saline solution at a rate of 15 ml/sec.


The pump is activated and a timer started immediately upon activation. The pump delivers 90 mL of 0.9% NaCl solution to the cylinder 116 at a rate of 15 ml/sec, then stops. As test fluid is introduced to the cylinder 116, it typically builds up on top of the absorbent structure to some extent. This fluid completes an electrical circuit between the two electrodes in the cylinder. After the gush has been delivered, the meniscus of the solution drops as the fluid is absorbed into the structure. When the electrical circuit is broken due to the absence of free fluid between the electrodes in the cylinder, the time is noted.


The acquisition time for a particular gush is the time interval between activation of the pump for that gush, and the point at which the electrical circuit is broken.


Four gushes are delivered to the product in this fashion; each gush is 90 ml and is delivered at 15 ml/sec. The time interval between the beginnings of each gush is 300 seconds.


Apparatus Imaging System (For Optional Use in Sample Preparation and Setups Step 10)


Image Acquisition Hardware


The image acquisition hardware consists of a computer, and lighting rigs 213 that contains a digital camera 211, such as a Fuji HC2500 (211) or Sony DFW-X700 (211). The color calibration chart is a standard 8.5″×11″ Gretag-Macbeth color chart, and two lights 212.


Connecting the Peripherals


The Fuji HC2500 camera has a PCI interface card that is installed in PCI slot 2 of the computer. The Sony DFW-X700 plugs into any Firewire (IEEE-1348) port of the computer.


Lighting Rig


The lighting rig 213 is shown in FIG. 7. The light 212 should fulfill the requirements of D65 such as an OSRAM OSDULUXL36W12 or equivalent (CC temperature/Kelvin 5400K; color daylight; CRI 90CRI). The angle αbetween the base 214 and the lighting rig 213 is 70° . The angle β between the lighting rig 213 and the light 212 should be adjusted to achieve even illumination of base 214.


Sample Preparation and Setup




  • 1. Directly after all liquid is absorbed by the diaper the diaper must be removed from the test apparatus.

  • 2. Immediately open the product with topsheet facing upwardly.

  • 3. Unfold the diaper and tear off the elastics from the diaper along the continuous bond.

  • 4. Lay the diaper flat and rectangular with the topsheet facing downwardly onto the table surface without any folds.

  • 5. Use one hand to hold the front waist edge of the diaper down onto the table surface to avoid any movement.

  • 6. Gently place the weight 312 (9 Kg and measuring 148 mm (5.83 inches) wide, 38 mm (1.5 inches) deep, and approximately 101 mm (3.98 inches tall)) at the front waist edge of the diaper in an angle of 45° or less onto the baby diaper front waist edge next to your hand. The side of the weight 312 should be parallel to the transverse axis of the diaper. Now slide the weight towards the back waist edge of the diaper, by keeping the angle of 45° or lower such that the weight is sliding over the diaper with only one of its edges 313, by gripping the weight with handle 311. This should take approximately 1 to 2 sec for a diaper having a longitudinal extension of 400 mm to 500 mm.

  • 7. Take the front and waist edges of the diaper, lift them up and fold the diaper in a way that it builds a circle. During that procedure the crotch region of the diaper should still be in contact with the table.

  • 8. Release the diaper ends and lay down the diaper flat and rectangular with the topsheet facing downwardly onto the table surface without any folds.

  • 9. Slightly touch the back-sheet surface with your flat hand and move your hands three times gently in cross direction (i.e. parallel to the transverse axis of the diaper) back and forth.

  • 10. Visually inspect with the naked eye the diaper: Areas, where the backsheet closely sticks to the absorbent core can be recognized as darker areas where the stained absorbent core shines through the backsheet to a certain extent. Areas where the backsheet has separated from the absorbent core can be identified by lighter colors. The difference between a backsheet with large areas being adhesively attached to the core and a backsheet with only small areas being adhesively attached to the core is typically readily apparent.



To archive the result, the diapers can be photographed using the equipment described under “Apparatus imaging system”.


The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”


Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.


While particular embodiments of the present disclosure have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims
  • 1. A disposable diaper comprising a backsheet, a topsheet and therein between an absorbent core, the absorbent core having a longitudinal direction with a longitudinal axis and perpendicular thereto a lateral direction with a transverse axis, the absorbent core comprising a front region, a back region and a crotch region therein between and a front lateral edge, an opposing back lateral edge, and longitudinally extending side edges, wherein the absorbent core comprises superabsorbent polymer particles and wherein the absorbent core comprises less than 5% of airfelt, and wherein a) the absorbent core is attached to the backsheet of the disposable diaper in attachment zones adjacent to the front lateral edge and the back lateral edge of the absorbent core; andb) the absorbent core is attached to the backsheet of the disposable diaper in the crotch region of the absorbent core in attachment zones adjacent to the longitudinal side edges of the absorbent core, wherein the attachment zones adjacent to the longitudinal sides edges extend less than 15% inwardly from the longitudinal side edges;c) wherein the absorbent core is unattached to the backsheet in any other region besides those defined in a) and b).
  • 2. The disposable diaper of claim 1, wherein the backsheet comprises a film and one or more nonwoven webs, wherein the basis weight of the backsheet including the film and the one or more nonwoven webs is less than 70 g/m2, and wherein the film has a basis weight of less than 25 g/m2.
  • 3. The disposable diaper of claim 1, wherein the backsheet is non-elastic.
  • 4. The disposable diaper of claim 1, wherein the backsheet is highly non-elastic.
  • 5. The disposable diaper of claim 1, wherein the absorbent core is attached to the topsheet at least in the front region and in the crotch region of the absorbent core.
  • 6. The disposable diaper of claim 1, wherein absorbent material of the absorbent core comprises more than 95% of the superabsorbent polymer particles.
  • 7. The disposable diaper of claim 1, wherein the absorbent core comprises first and second carrier substrates, and wherein the superabsorbent polymer particles are provided between the first and second carrier substrates.
  • 8. The disposable diaper of claim 1, wherein the superabsorbent polymer particles are immobilized by a first core adhesive, wherein the first core adhesive is a hot melt adhesive.
  • 9. The disposable diaper of claim 1, wherein the absorbent core is attached to the backsheet by an adhesive.
  • 10. The disposable diaper of claim 9, wherein the adhesive is a hot melt adhesive.
  • 11. The disposable diaper of claim 1, wherein the absorbent core is not attached to the backsheet over the entire absorbent core surface.
  • 12. The disposable diaper of claim 1, wherein the absorbent core comprises one or more channels which are free of the superabsorbent polymer particles.
  • 13. A disposable diaper comprising a backsheet, a topsheet and therein between an absorbent core, the absorbent core having a longitudinal direction with a longitudinal axis and perpendicular thereto a lateral direction with a transverse axis, the absorbent core comprising a front region, a back region and a crotch region therein between and a front lateral edge, an opposing back lateral edge, and longitudinally extending side edges, wherein the absorbent core comprises superabsorbent polymer particles and wherein the absorbent core comprises less than 5% of airfelt, and wherein a) the absorbent core is attached to the backsheet of the disposable diaper in attachment zones adjacent to the front lateral edge and the back lateral edge of the absorbent core; andb) the absorbent core is attached to the backsheet of the disposable diaper in the crotch region of the absorbent core in attachment zones adjacent to the longitudinal side edges of the absorbent core, wherein the attachment zones adjacent to the longitudinal side edges extend less than 15% inwardly from the longitudinal side edges; andc) the absorbent core is attached to the backsheet of the disposable diaper in the crotch region of the absorbent core through a wetness indicator;d) wherein the absorbent core is unattached to the backsheet in any other region besides those defined in a), b), and c).
  • 14. The disposable diaper of claim 13, wherein the backsheet comprises a film and one or more nonwoven webs, wherein the basis weight of the backsheet including the film and the one or more nonwoven webs is less than 70 g/m2, and wherein the film has a basis weight of less than 25 g/m2.
  • 15. The disposable diaper of claim 13, wherein the backsheet is non-elastic.
  • 16. The disposable diaper of claim 13, wherein the backsheet is highly non-elastic.
  • 17. The disposable diaper of claim 13, wherein the absorbent core is attached to the topsheet at least in the front region and in the crotch region of the absorbent core.
  • 18. The disposable diaper of claim 13, wherein absorbent material of the absorbent core comprises more than 95% of the superabsorbent polymer particles.
  • 19. The disposable diaper of claim 13, wherein the absorbent core comprises first and second carrier substrates, and wherein the superabsorbent polymer particles are provided between the first and second carrier substrates.
  • 20. The disposable diaper of claim 13, wherein the superabsorbent polymer particles are immobilized by a first core adhesive, wherein the first core adhesive is a hot melt adhesive.
  • 21. The disposable diaper of claim 13, wherein the absorbent core is attached to the backsheet by an adhesive.
  • 22. The disposable diaper of claim 21, wherein the adhesive is a hot melt adhesive.
  • 23. The disposable diaper of claim 13, wherein the absorbent core comprises one or more channels which are free of the superabsorbent polymer particles.
  • 24. A disposable diaper comprising a backsheet, a topsheet and therein between an absorbent core, the absorbent core having a longitudinal direction with a longitudinal axis and perpendicular thereto a lateral direction with a transverse axis, the absorbent core comprising a front region, a back region and a crotch region therein between and a front lateral edge, an opposing back lateral edge, and longitudinally extending side edges, wherein the absorbent core comprises superabsorbent polymer particles and wherein the absorbent core comprises less than 5% of airfelt; wherein the absorbent core is attached to the backsheet in one or more attachment zones that cover only from 0.2% to 3% of the total surface area of the absorbent core; and wherein the absorbent core comprises one or more channels which are free of the superabsorbent polymer particles.
Priority Claims (1)
Number Date Country Kind
11169528 Jun 2011 EP regional
US Referenced Citations (1043)
Number Name Date Kind
1733997 Marr Oct 1929 A
1734499 Marinsky Nov 1929 A
1989283 Limacher Jan 1935 A
2058509 Rose Oct 1936 A
2271676 Bjornbak Feb 1942 A
2450789 Frieman Oct 1948 A
2508811 Best et al. May 1950 A
2568910 Condylis Sep 1951 A
2570796 Gross Oct 1951 A
2570963 Mesmer Oct 1951 A
2583553 Faure Jan 1952 A
2705957 Mauro Apr 1955 A
2788003 Morin Apr 1957 A
2788786 Dexter Apr 1957 A
2798489 Behrman Jul 1957 A
2807263 Newton Sep 1957 A
2830589 Doner Apr 1958 A
2890700 Lönberg-Holm Jun 1959 A
2890701 Weinman Jun 1959 A
2898912 Adams Aug 1959 A
2931361 Sostsrin Apr 1960 A
2977957 Clyne Apr 1961 A
3071138 Gustavo Jan 1963 A
3180335 Duncan et al. Apr 1965 A
3207158 Yoshitake et al. Sep 1965 A
3227160 Joy Jan 1966 A
3386442 Sabee Jun 1968 A
3561446 Jones Feb 1971 A
3572342 Lindquist et al. Mar 1971 A
3572432 Burton Mar 1971 A
3575174 Mogor Apr 1971 A
3578155 Small et al. May 1971 A
3606887 Roeder Sep 1971 A
3610244 Jones Oct 1971 A
3618608 Brink Nov 1971 A
3642001 Sabee Feb 1972 A
3653381 Warnken Apr 1972 A
3670731 Harmon Jun 1972 A
3688767 Goldstein Sep 1972 A
3710797 Marsan Jan 1973 A
3731688 Litt et al. May 1973 A
3756878 Willot Sep 1973 A
3774241 Zerkle Nov 1973 A
3776233 Schaar Dec 1973 A
3814100 Nystrand et al. Jun 1974 A
3828784 Zoephel Aug 1974 A
3840418 Sabee Oct 1974 A
3847702 Jones Nov 1974 A
3848594 Buell Nov 1974 A
3848595 Endres Nov 1974 A
3848597 Endres Nov 1974 A
3860003 Buell Jan 1975 A
3863637 MacDonald et al. Feb 1975 A
3882870 Hathaway May 1975 A
3884234 Taylor May 1975 A
3900032 Heurlen Aug 1975 A
3911173 Sprague, Jr. Oct 1975 A
3920017 Karami Nov 1975 A
3924626 Lee et al. Dec 1975 A
3926189 Taylor Dec 1975 A
3929134 Karami Dec 1975 A
3929135 Thompson Dec 1975 A
3930501 Schaar Jan 1976 A
3938523 Gilliland et al. Feb 1976 A
3968799 Schrading Jul 1976 A
3978861 Schaar Sep 1976 A
3981306 Krusko Sep 1976 A
3987794 Schaar Oct 1976 A
3995637 Schaar Dec 1976 A
3995640 Schaar Dec 1976 A
3999547 Hernandez Dec 1976 A
4014338 Schaar Mar 1977 A
4034760 Amirsakis Jul 1977 A
4055180 Karami Oct 1977 A
4074508 Reid Feb 1978 A
4079739 Whitehead Mar 1978 A
4084592 Tritsch Apr 1978 A
4100922 Hernandez Jul 1978 A
4232674 Melican Nov 1980 A
4257418 Hessner Mar 1981 A
4259220 Bunnelle et al. Mar 1981 A
4296750 Woon et al. Oct 1981 A
4315508 Bolick Feb 1982 A
4324246 Mullane et al. Apr 1982 A
4340706 Obayashi et al. Jul 1982 A
4341216 Obenour Jul 1982 A
4342314 Radel et al. Aug 1982 A
4360021 Stima Nov 1982 A
4381783 Elias May 1983 A
4388075 Mesek et al. Jun 1983 A
4410571 Korpman Oct 1983 A
4461621 Karami et al. Jul 1984 A
4463045 Ahr et al. Jul 1984 A
4469710 Rielley et al. Sep 1984 A
4475912 Coates Oct 1984 A
4490148 Beckeström Dec 1984 A
4507438 Obayashi et al. Mar 1985 A
4515595 Kievet et al. May 1985 A
4527990 Sigl Jul 1985 A
4541871 Obayashi et al. Sep 1985 A
4551191 Kock et al. Nov 1985 A
4578072 Lancaster Mar 1986 A
4578702 Campbell Mar 1986 A
4585448 Enloe Apr 1986 A
4585450 Rosch et al. Apr 1986 A
4589878 Mitrani May 1986 A
4596568 Flug Jun 1986 A
4601717 Blevins Jul 1986 A
4606964 Wideman Aug 1986 A
4609518 Curro et al. Sep 1986 A
4610678 Weisman et al. Sep 1986 A
4623342 Ito et al. Nov 1986 A
4624666 Derossett Nov 1986 A
4629643 Curro et al. Dec 1986 A
4636207 Buell Jan 1987 A
4641381 Heran et al. Feb 1987 A
4646510 McIntyre Mar 1987 A
4662875 Hirotsu et al. May 1987 A
4666983 Tsubakimoto et al. May 1987 A
4670011 Mesek Jun 1987 A
4670012 Johnson Jun 1987 A
4680030 Coates et al. Jul 1987 A
4681579 Toussant et al. Jul 1987 A
4681581 Coates Jul 1987 A
4681793 Linman et al. Jul 1987 A
4690680 Higgins Sep 1987 A
4695278 Lawson Sep 1987 A
4699622 Toussant et al. Oct 1987 A
4704115 Buell Nov 1987 A
4704116 Enloe Nov 1987 A
4710189 Lash Dec 1987 A
4720321 Smith Jan 1988 A
4731066 Korpman Mar 1988 A
4731070 Koci Mar 1988 A
RE32649 Brandt et al. Apr 1988 E
4741941 Englebert et al. May 1988 A
4747846 Boland et al. May 1988 A
4753648 Jackson Jun 1988 A
4773905 Molee Sep 1988 A
4784892 Storey et al. Nov 1988 A
4785996 Ziecker et al. Nov 1988 A
4787896 Houghton et al. Nov 1988 A
4795454 Dragoo Jan 1989 A
4800102 Takada Jan 1989 A
4802884 Fröidh et al. Feb 1989 A
4806598 Morman Feb 1989 A
4808176 Kielpikowski Feb 1989 A
4808178 Aziz Feb 1989 A
4826880 Lesniak et al. May 1989 A
4834735 Alemany et al. May 1989 A
4834740 Suzuki et al. May 1989 A
4834742 Wilson et al. May 1989 A
4838886 Kent Jun 1989 A
4842666 Werenicz Jun 1989 A
4846815 Scripps Jul 1989 A
4846825 Enloe et al. Jul 1989 A
4848815 Molloy Jul 1989 A
4861652 Lippert et al. Aug 1989 A
4869724 Scripps Sep 1989 A
4886697 Perdelwitz, Jr. et al. Dec 1989 A
4888231 Angstadt Dec 1989 A
4892528 Suzuki et al. Jan 1990 A
4892535 Bjornberg Jan 1990 A
4892536 DesMarais et al. Jan 1990 A
4894060 Nestegard Jan 1990 A
4894277 Akasaki Jan 1990 A
4900317 Buell Feb 1990 A
4904251 Igaue et al. Feb 1990 A
4909802 Ahr et al. Mar 1990 A
4909803 Aziz et al. Mar 1990 A
4936839 Molee Jun 1990 A
4940463 Leathers et al. Jul 1990 A
4940464 Van Gompel et al. Jul 1990 A
4946527 Battrell Aug 1990 A
4950264 Osborn Aug 1990 A
4960477 Mesek Oct 1990 A
4963140 Robertson et al. Oct 1990 A
4966809 Tanaka et al. Oct 1990 A
4968313 Sabee Nov 1990 A
4990147 Freeland Feb 1991 A
4994053 Lang Feb 1991 A
5006394 Baird Apr 1991 A
5019063 Marsan et al. May 1991 A
5019072 Polski May 1991 A
5021051 Hiuke Jun 1991 A
5030314 Lang Jul 1991 A
5032120 Freeland et al. Jul 1991 A
5034008 Breitkopf Jul 1991 A
5037416 Allen et al. Aug 1991 A
5071414 Elliott Dec 1991 A
5072687 Mitchell Dec 1991 A
5085654 Buell Feb 1992 A
5087255 Sims et al. Feb 1992 A
5092861 Nomura et al. Mar 1992 A
5102597 Roe et al. Apr 1992 A
5114420 Igaue et al. May 1992 A
5124188 Roe et al. Jun 1992 A
5135522 Fahrenkrug et al. Aug 1992 A
5137537 Herron et al. Aug 1992 A
D329697 Fahrenkrug et al. Sep 1992 S
5143679 Weber et al. Sep 1992 A
5147343 Kellenberger Sep 1992 A
5147345 Young et al. Sep 1992 A
5149334 Lahrman et al. Sep 1992 A
5149335 Kellenberger et al. Sep 1992 A
5151091 Glaug Sep 1992 A
5151092 Buell et al. Sep 1992 A
5156793 Buell et al. Oct 1992 A
5167653 Igaue et al. Dec 1992 A
5167897 Weber et al. Dec 1992 A
5175046 Nguyen Dec 1992 A
5180622 Berg et al. Jan 1993 A
5190563 Herron et al. Mar 1993 A
5190606 Merkatoris et al. Mar 1993 A
5204997 Suzuki et al. Apr 1993 A
5213817 Pelley May 1993 A
5221274 Buell et al. Jun 1993 A
5235515 Ungpiyakul et al. Aug 1993 A
5242436 Weil et al. Sep 1993 A
5246431 Minetola et al. Sep 1993 A
5246432 Suzuki et al. Sep 1993 A
5246433 Hasse et al. Sep 1993 A
5248309 Serbiak et al. Sep 1993 A
5260345 Desmarais et al. Nov 1993 A
5269775 Freeland et al. Dec 1993 A
5281683 Yano et al. Jan 1994 A
H1298 Ahr Apr 1994 H
5300565 Berg et al. Apr 1994 A
5312386 Correa et al. May 1994 A
5331059 Engelhardt et al. Jul 1994 A
5336552 Strack et al. Aug 1994 A
5348547 Payne et al. Sep 1994 A
5358500 LaVon et al. Oct 1994 A
5366782 Curro et al. Nov 1994 A
5382610 Harada et al. Jan 1995 A
5387207 Dyer et al. Feb 1995 A
5387208 Ashton et al. Feb 1995 A
5387209 Yamamoto et al. Feb 1995 A
5389095 Suzuki Feb 1995 A
5397316 Lavon et al. Mar 1995 A
5397317 Thomas Mar 1995 A
5399175 Glaug Mar 1995 A
5401792 Babu et al. Mar 1995 A
5409771 Dahmen et al. Apr 1995 A
H1440 New et al. May 1995 H
5411497 Tanzer et al. May 1995 A
5415644 Enloe May 1995 A
5425725 Tanzer et al. Jun 1995 A
5429630 Beal et al. Jul 1995 A
5433715 Tanzer et al. Jul 1995 A
5451219 Suzuki Sep 1995 A
5451442 Pieniak Sep 1995 A
5460622 Dragoo et al. Oct 1995 A
5462541 Bruemmer et al. Oct 1995 A
5476458 Glaug et al. Dec 1995 A
5486166 Bishop et al. Jan 1996 A
5486167 Dragoo et al. Jan 1996 A
5490846 Ellis et al. Feb 1996 A
5492962 Lahrman et al. Feb 1996 A
5494622 Heath et al. Feb 1996 A
5499978 Buell et al. Mar 1996 A
5507736 Clear et al. Apr 1996 A
5507895 Suekane Apr 1996 A
5509915 Hanson et al. Apr 1996 A
5514104 Cole May 1996 A
5518801 Chappell et al. May 1996 A
5520674 Hines et al. May 1996 A
5522810 Allen, Jr. Jun 1996 A
5527300 Sauer Jun 1996 A
5531730 Dreier Jul 1996 A
5532323 Yano et al. Jul 1996 A
5542943 Sageser Aug 1996 A
5549592 Fries et al. Aug 1996 A
5549593 Ygge et al. Aug 1996 A
5549791 Herron et al. Aug 1996 A
5554145 Roe et al. Sep 1996 A
5559335 Zing et al. Sep 1996 A
5560878 Dragoo et al. Oct 1996 A
5562634 Flumene et al. Oct 1996 A
5562646 Goldman et al. Oct 1996 A
5569234 Buell et al. Oct 1996 A
5571096 Dobrin et al. Nov 1996 A
5574121 Irie et al. Nov 1996 A
5580411 Nease et al. Dec 1996 A
5584829 Lavash et al. Dec 1996 A
5586979 Thomas Dec 1996 A
5591152 Buell et al. Jan 1997 A
5591155 Nishikawa et al. Jan 1997 A
5593399 Tanzer et al. Jan 1997 A
5599335 Goldman et al. Feb 1997 A
5601542 Melius et al. Feb 1997 A
5607414 Richards et al. Mar 1997 A
5607416 Yamamoto et al. Mar 1997 A
5607537 Johnson et al. Mar 1997 A
5607760 Roe Mar 1997 A
5609587 Roe Mar 1997 A
5609588 DiPalma et al. Mar 1997 A
5611879 Morman Mar 1997 A
5613959 Roessler et al. Mar 1997 A
5613960 Mizutani Mar 1997 A
5614283 Potnis et al. Mar 1997 A
5622589 Johnson et al. Apr 1997 A
5624423 Anjur Apr 1997 A
5624424 Saisaka et al. Apr 1997 A
5625222 Yoneda et al. Apr 1997 A
5626571 Young et al. May 1997 A
5628741 Buell et al. May 1997 A
5628845 Murray et al. May 1997 A
5635191 Roe et al. Jun 1997 A
5635271 Zafiroglu Jun 1997 A
5637106 Mitchell Jun 1997 A
5643238 Baker Jul 1997 A
5643243 Klemp Jul 1997 A
5643588 Roe et al. Jul 1997 A
5649914 Glaug Jul 1997 A
5650214 Anderson Jul 1997 A
H1674 Ames et al. Aug 1997 H
5658268 Johns et al. Aug 1997 A
5662634 Yamamoto et al. Sep 1997 A
5662638 Johnson et al. Sep 1997 A
5662758 Hamilton et al. Sep 1997 A
5669894 Goldman et al. Sep 1997 A
5674215 Ronnberg Oct 1997 A
5683374 Yamamoto Nov 1997 A
5685874 Buell et al. Nov 1997 A
5690627 Clear et al. Nov 1997 A
5691035 Chappell et al. Nov 1997 A
5691036 Lin et al. Nov 1997 A
5695488 Sosalla Dec 1997 A
5700254 McDowall et al. Dec 1997 A
5702376 Glaug Dec 1997 A
5714156 Schmidt et al. Feb 1998 A
5723087 Chappell et al. Mar 1998 A
5733275 Davis et al. Mar 1998 A
5749866 Roe et al. May 1998 A
5752947 Awolin May 1998 A
5756039 Mcfall et al. May 1998 A
H1732 Johnson Jun 1998 H
5762641 Bewick Sonntag et al. Jun 1998 A
5766388 Pelley Jun 1998 A
5766389 Brandon et al. Jun 1998 A
5772825 Schmitz Jun 1998 A
5776121 Roe et al. Jul 1998 A
5779831 Schmitz Jul 1998 A
5788684 Abuto et al. Aug 1998 A
5795345 Mizutani Aug 1998 A
5797892 Glaug Aug 1998 A
5797894 Cadieux et al. Aug 1998 A
5807365 Luceri Sep 1998 A
5810796 Kimura et al. Sep 1998 A
5810800 Hunter et al. Sep 1998 A
5814035 Gryskiewicz et al. Sep 1998 A
5820618 Roberts et al. Oct 1998 A
5827257 Fujioka Oct 1998 A
5830202 Bogdanski et al. Nov 1998 A
5833678 Ashton et al. Nov 1998 A
5837789 Stockhausen et al. Nov 1998 A
5840404 Graff Nov 1998 A
5843059 Niemeyer et al. Dec 1998 A
5846231 Fujioka et al. Dec 1998 A
5846232 Serbiak et al. Dec 1998 A
5849816 Suskind et al. Dec 1998 A
5851204 Mitzutani Dec 1998 A
5855572 Schmidt Jan 1999 A
5858013 Kling Jan 1999 A
5865823 Curro Feb 1999 A
5865824 Chen Feb 1999 A
5873868 Nakahata Feb 1999 A
5876391 Roe et al. Mar 1999 A
5879751 Bogdanski Mar 1999 A
5891118 Toyoshima Apr 1999 A
5891544 Chappell et al. Apr 1999 A
5897545 Kline et al. Apr 1999 A
5904673 Roe et al. May 1999 A
5925439 Haubach Jul 1999 A
5928184 Etheredge Jul 1999 A
5931825 Kuen et al. Aug 1999 A
5938648 Lavon et al. Aug 1999 A
5938650 Baer et al. Aug 1999 A
5941862 Haynes et al. Aug 1999 A
5944706 Palumbo et al. Aug 1999 A
5947949 Inoue et al. Sep 1999 A
5951536 Osborn, III et al. Sep 1999 A
5957908 Kline et al. Sep 1999 A
5968025 Roe et al. Oct 1999 A
5968029 Chappell et al. Oct 1999 A
5981824 Luceri Nov 1999 A
5989236 Roe et al. Nov 1999 A
6004306 Robles et al. Dec 1999 A
6022430 Blenke et al. Feb 2000 A
6022431 Blenke et al. Feb 2000 A
6042673 Johnson et al. Mar 2000 A
6050984 Fujioka Apr 2000 A
6054631 Gent Apr 2000 A
6060115 Borowski et al. May 2000 A
6068620 Chmielewski May 2000 A
6080909 Osterdahl et al. Jun 2000 A
6083210 Young et al. Jul 2000 A
6090994 Chen Jul 2000 A
6091336 Zand Jul 2000 A
6099515 Sugito Aug 2000 A
6102892 Putzer et al. Aug 2000 A
6103814 Van Drongelen et al. Aug 2000 A
6107537 Elder et al. Aug 2000 A
6110157 Schmidt Aug 2000 A
6117121 Faulks et al. Sep 2000 A
6117803 Morman et al. Sep 2000 A
6120486 Toyoda et al. Sep 2000 A
6120487 Ashton Sep 2000 A
6120489 Johnson et al. Sep 2000 A
6120866 Arakawa et al. Sep 2000 A
6121509 Ashraf et al. Sep 2000 A
6129717 Fujioka et al. Oct 2000 A
6129720 Blenke et al. Oct 2000 A
6132411 Huber et al. Oct 2000 A
6139912 Onuschak Oct 2000 A
6143821 Houben Nov 2000 A
6152908 Widlund Nov 2000 A
6156023 Yoshioka Dec 2000 A
6156424 Taylor Dec 2000 A
6160197 Lassen Dec 2000 A
6165160 Suzuki et al. Dec 2000 A
6174302 Kumasaka Jan 2001 B1
6177606 Etheredge Jan 2001 B1
6177607 Blaney et al. Jan 2001 B1
6186996 Martin Feb 2001 B1
6210386 Inoue Apr 2001 B1
6210390 Karlsson Apr 2001 B1
6231556 Osborn, III May 2001 B1
6231566 Lai May 2001 B1
6238380 Sasaki May 2001 B1
6241716 Rönnberg Jun 2001 B1
6254294 Muhar Jul 2001 B1
6258996 Goldman Jul 2001 B1
6265488 Fujino et al. Jul 2001 B1
6290686 Tanzer et al. Sep 2001 B1
6306122 Narawa et al. Oct 2001 B1
6315765 Datta Nov 2001 B1
6319239 Daniels et al. Nov 2001 B1
6322552 Blenke et al. Nov 2001 B1
6325787 Roe et al. Dec 2001 B1
6326525 Hamajima Dec 2001 B1
6330735 Hahn et al. Dec 2001 B1
6334858 Rönnberg et al. Jan 2002 B1
6336922 Van Gompel et al. Jan 2002 B1
6340611 Shimizu Jan 2002 B1
6342715 Shimizu Jan 2002 B1
6350332 Thomas et al. Feb 2002 B1
6368687 Joseph et al. Apr 2002 B1
6371948 Mizutani Apr 2002 B1
6372952 Lash et al. Apr 2002 B1
6375644 Mizutani Apr 2002 B2
6376034 Brander Apr 2002 B1
6383431 Dobrin et al. May 2002 B1
6383960 Everett et al. May 2002 B1
6394989 Mizutani May 2002 B2
6402729 Boberg et al. Jun 2002 B1
6402731 Suprise et al. Jun 2002 B1
6403857 Gross et al. Jun 2002 B1
6409883 Makolin Jun 2002 B1
6410820 McFall et al. Jun 2002 B1
6410822 Mizutani Jun 2002 B1
6413248 Mizutani Jul 2002 B1
6413249 Turi et al. Jul 2002 B1
6414214 Engelhardt et al. Jul 2002 B1
6416502 Connelly et al. Jul 2002 B1
6416697 Venturino et al. Jul 2002 B1
6419667 Avalon et al. Jul 2002 B1
6423046 Fujioka et al. Jul 2002 B1
6423048 Suzuki et al. Jul 2002 B1
6423884 Oehmen Jul 2002 B1
6429350 Tanzer et al. Aug 2002 B1
6432094 Fujioka et al. Aug 2002 B1
6432098 Kline et al. Aug 2002 B1
6432099 Rönnberg Aug 2002 B2
6437214 Everett et al. Aug 2002 B1
6441268 Edwardsson Aug 2002 B1
6443933 Suzuki et al. Sep 2002 B1
6444064 Henry et al. Sep 2002 B1
6447496 Mizutani Sep 2002 B1
6458111 Onishi et al. Oct 2002 B1
6458877 Ahmed et al. Oct 2002 B1
6459016 Rosenfeld et al. Oct 2002 B1
6461342 Tanji et al. Oct 2002 B2
6461343 Schaefer et al. Oct 2002 B1
6472478 Funk et al. Oct 2002 B1
6475201 Saito et al. Nov 2002 B2
6494872 Suzuki et al. Dec 2002 B1
6494873 Karlsson et al. Dec 2002 B2
6500159 Carvalho Dec 2002 B1
6503233 Chen Jan 2003 B1
6503979 Funk et al. Jan 2003 B1
6506186 Roessler Jan 2003 B1
6506961 Levy Jan 2003 B1
6515195 Lariviere Feb 2003 B1
6517525 Berthou Feb 2003 B1
6518479 Graef Feb 2003 B1
6520947 Tilly et al. Feb 2003 B1
6521811 Lassen Feb 2003 B1
6521812 Graef Feb 2003 B1
6524294 Hilston et al. Feb 2003 B1
6525240 Graef Feb 2003 B1
6528698 Mizutani et al. Mar 2003 B2
6529860 Strumolo et al. Mar 2003 B1
6531025 Lender et al. Mar 2003 B1
6531027 Lender et al. Mar 2003 B1
6534149 Daley et al. Mar 2003 B1
6559081 Erspamer May 2003 B1
6559239 Riegel et al. May 2003 B1
6562168 Schmitt May 2003 B1
6562192 Hamilton May 2003 B1
6569137 Suzuki et al. May 2003 B2
6573422 Rosenfeld Jun 2003 B1
6585713 LeMahieu et al. Jul 2003 B1
6585858 Otto et al. Jul 2003 B1
6602234 Klemp et al. Aug 2003 B2
6605070 Ludwig et al. Aug 2003 B2
6605172 Anderson et al. Aug 2003 B1
6605752 Magnusson et al. Aug 2003 B2
6610900 Tanzer Aug 2003 B1
6630054 Graef Oct 2003 B1
6632209 Chmielewski Oct 2003 B1
6632504 Gillespie et al. Oct 2003 B1
6645569 Cramer et al. Nov 2003 B2
6646180 Chmielewski Nov 2003 B1
6648869 Gillies et al. Nov 2003 B1
6648870 Itoh et al. Nov 2003 B2
6648871 Kusibojoska et al. Nov 2003 B2
6649807 Mizutani Nov 2003 B2
6649810 Minato et al. Nov 2003 B1
6657015 Riegel et al. Dec 2003 B1
6657102 Furuya Dec 2003 B2
6667424 Hamilton Dec 2003 B1
6670522 Graef Dec 2003 B1
6673982 Chen Jan 2004 B1
6673983 Graef Jan 2004 B1
6673985 Mizutani Jan 2004 B2
6682515 Mizutani et al. Jan 2004 B1
6682516 Johnston Jan 2004 B2
6689115 Popp et al. Feb 2004 B1
6689934 Dodge, II et al. Feb 2004 B2
6695827 Chen Feb 2004 B2
6700034 Lindsay et al. Mar 2004 B1
6703538 Lassen Mar 2004 B2
6705465 Ling et al. Mar 2004 B2
6706129 Ando et al. Mar 2004 B2
6706943 Onishi Mar 2004 B2
6710224 Chmielewski et al. Mar 2004 B2
6710225 Everett et al. Mar 2004 B1
6716204 Roe et al. Apr 2004 B1
6716205 Popp et al. Apr 2004 B2
6717029 Baker Apr 2004 B2
6726668 Underhill et al. Apr 2004 B2
6726792 Johnson et al. Apr 2004 B1
6730387 Rezai et al. May 2004 B2
6734335 Graef May 2004 B1
6790798 Suzuki et al. Sep 2004 B1
6802834 Melius et al. Oct 2004 B2
6809158 Ikeuchi et al. Oct 2004 B2
6811642 Ochi Nov 2004 B2
6818083 Mcamish et al. Nov 2004 B2
6818166 Edwardson et al. Nov 2004 B2
6830800 Curro et al. Dec 2004 B2
6832905 Delzer et al. Dec 2004 B2
6840929 Kurata Jan 2005 B2
6846374 Popp Jan 2005 B2
6858771 Yoshimasa Feb 2005 B2
6863933 Cramer et al. Mar 2005 B2
6863960 Curro et al. Mar 2005 B2
6867345 Shimoe et al. Mar 2005 B2
6867346 Dopps Mar 2005 B1
6878433 Curro et al. Apr 2005 B2
6880211 Jackson et al. Apr 2005 B2
6891080 Minato May 2005 B2
6904865 Klofta Jun 2005 B2
6911574 Mizutani Jun 2005 B1
6923797 Shinohara et al. Aug 2005 B2
6923926 Walter et al. Aug 2005 B2
6926703 Sugito Aug 2005 B2
6929629 Drevik et al. Aug 2005 B2
6939914 Qin et al. Sep 2005 B2
6946585 Brown Sep 2005 B2
6953451 Berba Oct 2005 B2
6955733 Henry et al. Oct 2005 B2
6962645 Graef Nov 2005 B2
6965058 Raidel Nov 2005 B1
6969781 Graef Nov 2005 B2
6972010 Pesce et al. Dec 2005 B2
6972011 Maeda et al. Dec 2005 B2
6979564 Glucksmann et al. Dec 2005 B2
6982052 Daniels et al. Jan 2006 B2
7001167 Venturino Feb 2006 B2
7014632 Takino et al. Mar 2006 B2
7015370 Watanabe Mar 2006 B2
7037299 Turi et al. May 2006 B2
7037571 Fish et al. May 2006 B2
7048726 Kusagawa et al. May 2006 B2
7056311 Kinoshita Jun 2006 B2
7067711 Kinoshita et al. Jun 2006 B2
7073373 La Fortune Jul 2006 B2
7078583 Kudo Jul 2006 B2
7090665 Ohashi Aug 2006 B2
7108759 You Sep 2006 B2
7108916 Ehrnsperger et al. Sep 2006 B2
7112621 Rohrbaugh et al. Sep 2006 B2
7122713 Komatsu Oct 2006 B2
7125470 Graef Oct 2006 B2
7132585 Kudo Nov 2006 B2
7147628 Drevik Dec 2006 B2
7150729 Shimada Dec 2006 B2
7160281 Leminh et al. Jan 2007 B2
7163528 Christon et al. Jan 2007 B2
7166190 Graef Jan 2007 B2
7169136 Otsubo Jan 2007 B2
7183360 Daniel et al. Feb 2007 B2
7189888 Wang et al. Mar 2007 B2
7196241 Kinoshita Mar 2007 B2
7199211 Popp et al. Apr 2007 B2
7204830 Mishima Apr 2007 B2
7207978 Takino Apr 2007 B2
7219403 Miyamoto et al. May 2007 B2
7220251 Otsubo et al. May 2007 B2
7241280 Christen et al. Jul 2007 B2
7250481 Jaworek et al. Jul 2007 B2
7252657 Mishima Aug 2007 B2
7265258 Hamilton Sep 2007 B2
7270651 Adams et al. Sep 2007 B2
7285178 Mischler et al. Oct 2007 B2
RE39919 Dodge, II et al. Nov 2007 E
7306582 Adams et al. Dec 2007 B2
7311696 Christen et al. Dec 2007 B2
7311968 Ehrnsperger et al. Dec 2007 B2
7312372 Miyama Dec 2007 B2
7318820 LaVon et al. Jan 2008 B2
7329244 Otsubo Feb 2008 B2
7329246 Kinoshita Feb 2008 B2
7335810 Yoshimasa et al. Feb 2008 B2
7377914 LaVon May 2008 B2
7429689 Chen Sep 2008 B2
7435244 Schroer et al. Oct 2008 B2
7465373 Graef Dec 2008 B2
7500969 Mishima Mar 2009 B2
7504552 Tamura Mar 2009 B2
7521109 Suzuki et al. Apr 2009 B2
7521587 Busam et al. Apr 2009 B2
7537832 Carlucci et al. May 2009 B2
7547815 Ohashi Jun 2009 B2
7550646 Tamura Jun 2009 B2
7563257 Nakajima Jul 2009 B2
7588561 Kenmochi Sep 2009 B2
7594904 Rosenfeld Sep 2009 B2
7598428 Gustavsson et al. Oct 2009 B2
7625363 Yoshimasa Dec 2009 B2
7641642 Murai et al. Jan 2010 B2
7648490 Kuroda Jan 2010 B2
7652111 Hermeling et al. Jan 2010 B2
7666173 Mishima Feb 2010 B2
7666174 Kawakami et al. Feb 2010 B2
7686790 Rasmussen et al. Mar 2010 B2
7687596 Hermeling et al. Mar 2010 B2
7695461 Rosenfeld Apr 2010 B2
7696402 Nishikawa Apr 2010 B2
7708725 Tamagawa May 2010 B2
7717150 Manabe May 2010 B2
7722587 Suzuki et al. May 2010 B2
7722590 Tsuji May 2010 B2
7727217 Hancock-Cooke Jun 2010 B2
7736351 Nigam Jun 2010 B2
7737324 LaVon et al. Jun 2010 B2
7744576 Busam et al. Jun 2010 B2
7744578 Tanio et al. Jun 2010 B2
7750203 Busam et al. Jul 2010 B2
7754822 Daniel et al. Jul 2010 B2
7754940 Brisebois Jul 2010 B2
7759540 Litvay et al. Jul 2010 B2
7763004 Beck Jul 2010 B2
7767875 Olson Aug 2010 B2
7767878 Suzuki Aug 2010 B2
7772420 Hermeling et al. Aug 2010 B2
7786341 Schneider et al. Aug 2010 B2
7795492 Vartiainen Sep 2010 B2
7803145 Rosenfeld Sep 2010 B2
7825291 Elfsberg et al. Nov 2010 B2
7838722 Blessing et al. Nov 2010 B2
7850672 Guidotti et al. Dec 2010 B2
7851667 Becker et al. Dec 2010 B2
7855314 Hanao Dec 2010 B2
7857797 Kudo Dec 2010 B2
7858842 Komatsu Dec 2010 B2
7884259 Hanao Feb 2011 B2
7888549 Jansson et al. Feb 2011 B2
7910797 Nandrea Mar 2011 B2
7931636 LaVon et al. Apr 2011 B2
7935207 Zhao May 2011 B2
7935861 Suzuki May 2011 B2
7938813 Wang et al. May 2011 B2
7942858 Francoeur May 2011 B2
7951126 Nanjyo May 2011 B2
7982091 Konawa Jul 2011 B2
7993319 Sperl Aug 2011 B2
8017827 Hundorf et al. Sep 2011 B2
8029486 Nakajima Oct 2011 B2
8034991 Bruzadin et al. Oct 2011 B2
8039684 Guidotti et al. Oct 2011 B2
8052454 Polnyi Nov 2011 B2
8057620 Perego et al. Nov 2011 B2
8109915 Shimoe Feb 2012 B2
8133212 Takada Mar 2012 B2
8148598 Tsang et al. Apr 2012 B2
8163124 Moriura et al. Apr 2012 B2
8167862 Digiacomantonio et al. May 2012 B2
8173858 Kuroda May 2012 B2
8178747 Venturino et al. May 2012 B2
8183430 Hakansson et al. May 2012 B2
8186296 Brown et al. May 2012 B2
8187239 LaVon et al. May 2012 B2
8187240 Busam et al. May 2012 B2
8198506 Venturino et al. Jun 2012 B2
8211815 Baker Jul 2012 B2
8236715 Schmidt et al. Aug 2012 B2
8237012 Miyama Aug 2012 B2
8246594 Sperl Aug 2012 B2
8258367 Lawson et al. Sep 2012 B2
8268424 Suzuki Sep 2012 B1
8273943 Noda Sep 2012 B2
8283516 Litvay Oct 2012 B2
8317766 Naoto Nov 2012 B2
8317768 Larsson Nov 2012 B2
8319005 Becker et al. Nov 2012 B2
8343123 Noda Jan 2013 B2
8343296 Blessing et al. Jan 2013 B2
8360977 Marttila Jan 2013 B2
8361047 Mukai Jan 2013 B2
8377025 Nakajima Feb 2013 B2
8450555 Nahn et al. May 2013 B2
8496637 Hundorf et al. Jul 2013 B2
8519213 Venturino et al. Aug 2013 B2
8524355 Nakaoka Sep 2013 B2
8552252 Hundorf et al. Oct 2013 B2
8568566 Jackels et al. Oct 2013 B2
8581019 Carlucci et al. Nov 2013 B2
8603058 Sprerl et al. Dec 2013 B2
8604270 Venturino et al. Dec 2013 B2
8633347 Bianco et al. Jan 2014 B2
8664468 Lawson et al. Mar 2014 B2
8674170 Busam et al. Mar 2014 B2
8734417 LaVon et al. May 2014 B2
8766031 Becker et al. Jul 2014 B2
8772570 Kawakami et al. Jul 2014 B2
8784594 Blessing et al. Jul 2014 B2
8785715 Wright et al. Jul 2014 B2
8791318 Becker et al. Jul 2014 B2
20010007065 Blanchard Jul 2001 A1
20010016548 Kugler et al. Aug 2001 A1
20010020157 Mizutani Sep 2001 A1
20010037101 Allan et al. Nov 2001 A1
20010044610 Kim Nov 2001 A1
20020007167 Dan Jan 2002 A1
20020007169 Graef et al. Jan 2002 A1
20020016122 Curro et al. Feb 2002 A1
20020045881 Kusibojoska et al. Apr 2002 A1
20020056516 Ochi May 2002 A1
20020058919 Hamilton et al. May 2002 A1
20020062112 Mizutani May 2002 A1
20020062115 Wada et al. May 2002 A1
20020062116 Mizutani et al. May 2002 A1
20020065498 Ohashi May 2002 A1
20020072471 Ikeuchi et al. Jun 2002 A1
20020082575 Dan Jun 2002 A1
20020087139 Popp et al. Jul 2002 A1
20020095127 Fish et al. Jul 2002 A1
20020102392 Fish et al. Aug 2002 A1
20020115969 Maeda et al. Aug 2002 A1
20020123728 Graef et al. Sep 2002 A1
20020123848 Schneiderman et al. Sep 2002 A1
20020151634 Rohrbaugh et al. Oct 2002 A1
20020151861 Klemp et al. Oct 2002 A1
20020173767 Popp et al. Nov 2002 A1
20020192366 Cramer et al. Dec 2002 A1
20020197695 Glucksmann et al. Dec 2002 A1
20030036741 Abba et al. Feb 2003 A1
20030078553 Wada Apr 2003 A1
20030084983 Rangachari et al. May 2003 A1
20030088223 Vogt et al. May 2003 A1
20030105190 Diehl et al. Jun 2003 A1
20030109839 Costae et al. Jun 2003 A1
20030114811 Christen et al. Jun 2003 A1
20030114816 Underhill Jun 2003 A1
20030114818 Benecke et al. Jun 2003 A1
20030115969 Koyano et al. Jun 2003 A1
20030120235 Boulanger Jun 2003 A1
20030120249 Wulz et al. Jun 2003 A1
20030135176 Delzer et al. Jul 2003 A1
20030135181 Chen et al. Jul 2003 A1
20030135182 Woon et al. Jul 2003 A1
20030139712 Dodge Jul 2003 A1
20030139715 Dodge Jul 2003 A1
20030139718 Graef Jul 2003 A1
20030144642 Dopps Jul 2003 A1
20030144644 Murai et al. Jul 2003 A1
20030148684 Cramer et al. Aug 2003 A1
20030148694 Ghiam Aug 2003 A1
20030158531 Chmielewski Aug 2003 A1
20030167045 Graef Sep 2003 A1
20030171727 Graef Sep 2003 A1
20030208175 Gross Nov 2003 A1
20030225385 Glaug Dec 2003 A1
20030233082 Kline et al. Dec 2003 A1
20030236512 Baker Dec 2003 A1
20040019338 Litvay et al. Jan 2004 A1
20040022998 Miyamoto et al. Feb 2004 A1
20040033750 Everett Feb 2004 A1
20040063367 Dodge Apr 2004 A1
20040064115 Arora Apr 2004 A1
20040064116 Arora Apr 2004 A1
20040065420 Graef Apr 2004 A1
20040082928 Pesce et al. Apr 2004 A1
20040097895 Busam et al. May 2004 A1
20040122411 Hancock-Cooke Jun 2004 A1
20040127131 Potnis Jul 2004 A1
20040127871 Odorzynski Jul 2004 A1
20040127872 Petryk Jul 2004 A1
20040134596 Rosati et al. Jul 2004 A1
20040147890 Nakahata et al. Jul 2004 A1
20040158212 Ponomarenko et al. Aug 2004 A1
20040167486 Busam et al. Aug 2004 A1
20040167489 Kellenberger et al. Aug 2004 A1
20040170813 Digiacomantonio et al. Sep 2004 A1
20040193127 Hansson Sep 2004 A1
20040215160 Chmielewski Oct 2004 A1
20040220541 Suzuki et al. Nov 2004 A1
20040225271 Datta et al. Nov 2004 A1
20040231065 Daniel et al. Nov 2004 A1
20040236299 Tsang et al. Nov 2004 A1
20040236455 Woltman et al. Nov 2004 A1
20040249355 Tanio et al. Dec 2004 A1
20040260259 Baker Dec 2004 A1
20050004543 Schroer et al. Jan 2005 A1
20050004548 Otsubo et al. Jan 2005 A1
20050008839 Cramer et al. Jan 2005 A1
20050018258 Miyagi Jan 2005 A1
20050038401 Suzuki et al. Feb 2005 A1
20050070867 Beruda et al. Mar 2005 A1
20050085784 LeMinh et al. Apr 2005 A1
20050090789 Graef Apr 2005 A1
20050101929 Waksmundzki et al. May 2005 A1
20050137543 Underhill et al. Jun 2005 A1
20050148258 Chakravarty Jul 2005 A1
20050148990 Shimoe Jul 2005 A1
20050154363 Minato Jul 2005 A1
20050159720 Gentilcore Jul 2005 A1
20050165208 Popp et al. Jul 2005 A1
20050171499 Nigam et al. Aug 2005 A1
20050176910 Jaworek et al. Aug 2005 A1
20050203475 LaVon et al. Sep 2005 A1
20050215752 Popp et al. Sep 2005 A1
20050229543 Tippey Oct 2005 A1
20050245684 Daniel et al. Nov 2005 A1
20050288645 LaVon Dec 2005 A1
20050288646 LaVon Dec 2005 A1
20060004334 Schlinz et al. Jan 2006 A1
20060021695 Blessing et al. Feb 2006 A1
20060024433 Blessing et al. Feb 2006 A1
20060069367 Waksmundzki et al. Mar 2006 A1
20060069371 Ohashi et al. Mar 2006 A1
20060073969 Torli et al. Apr 2006 A1
20060081348 Graef Apr 2006 A1
20060129114 Mason et al. Jun 2006 A1
20060142724 Watanabe Jun 2006 A1
20060155057 Hermeling et al. Jul 2006 A1
20060155254 Sanz et al. Jul 2006 A1
20060167215 Hermeling et al. Jul 2006 A1
20060177647 Schmidt et al. Aug 2006 A1
20060178071 Schmidt et al. Aug 2006 A1
20060184146 Suzuki Aug 2006 A1
20060184149 Kasai et al. Aug 2006 A1
20060189954 Kudo Aug 2006 A1
20060202380 Bentley Sep 2006 A1
20060206091 Cole Sep 2006 A1
20060211828 Daniel et al. Sep 2006 A1
20060240229 Ehrnsperger et al. Oct 2006 A1
20060264860 Beck Nov 2006 A1
20060264861 Lavon et al. Nov 2006 A1
20060271010 LaVon et al. Nov 2006 A1
20070027436 Nakagawa et al. Feb 2007 A1
20070032770 Lavon et al. Feb 2007 A1
20070043191 Hermeling et al. Feb 2007 A1
20070043330 Lankhof et al. Feb 2007 A1
20070049892 Lord et al. Mar 2007 A1
20070049897 LaVon et al. Mar 2007 A1
20070073253 Miyama Mar 2007 A1
20070078422 Glaug Apr 2007 A1
20070088308 Ehrnsperger et al. Apr 2007 A1
20070093164 Nakaoka Apr 2007 A1
20070093767 Carlucci et al. Apr 2007 A1
20070100307 Nomoto May 2007 A1
20070118087 Flohr et al. May 2007 A1
20070156108 Becker et al. Jul 2007 A1
20070156110 Thyfault Jul 2007 A1
20070167928 Becker et al. Jul 2007 A1
20070179464 Becker et al. Aug 2007 A1
20070179469 Takahashi et al. Aug 2007 A1
20070191798 Glaug Aug 2007 A1
20070219521 Hird et al. Sep 2007 A1
20070219523 Bruun Sep 2007 A1
20070244455 Hansson et al. Oct 2007 A1
20070246147 Venturino et al. Oct 2007 A1
20070282288 Noda Dec 2007 A1
20070282290 Cole Dec 2007 A1
20070282291 Cole Dec 2007 A1
20080027402 Schmidt et al. Jan 2008 A1
20080032035 Schmidt et al. Feb 2008 A1
20080091159 Carlucci et al. Apr 2008 A1
20080119810 Kuroda May 2008 A1
20080125735 Busam et al. May 2008 A1
20080132864 Lawson et al. Jun 2008 A1
20080221538 Zhao Sep 2008 A1
20080221539 Zhao Sep 2008 A1
20080262459 Kamoto Oct 2008 A1
20080268194 Kim et al. Oct 2008 A1
20080274227 Boatman et al. Nov 2008 A1
20080281287 Marcelo Nov 2008 A1
20080294140 Ecker et al. Nov 2008 A1
20080312619 Hundorf et al. Dec 2008 A1
20080312620 Ashton et al. Dec 2008 A1
20080312621 Hundorf et al. Dec 2008 A1
20080312622 Hundorf et al. Dec 2008 A1
20080312623 Hundorf et al. Dec 2008 A1
20080312624 Hundorf et al. Dec 2008 A1
20080312625 Hundorf et al. Dec 2008 A1
20080312627 Takeuchi Dec 2008 A1
20080312628 Hundorf et al. Dec 2008 A1
20090023848 Ahmed et al. Jan 2009 A1
20090056867 Moriura et al. Mar 2009 A1
20090062760 Wright et al. Mar 2009 A1
20090112173 Bissah Apr 2009 A1
20090112175 Bissah et al. Apr 2009 A1
20090157022 Macdonald Jun 2009 A1
20090192035 Stueven et al. Jul 2009 A1
20090240220 Macdonald Sep 2009 A1
20090247977 Takeuchi Oct 2009 A1
20090258994 Stueven et al. Oct 2009 A1
20090270825 Wciorka et al. Oct 2009 A1
20090298963 Matsumoto et al. Dec 2009 A1
20090299312 Macdonald Dec 2009 A1
20090306618 Kudo Dec 2009 A1
20090318884 Meyer et al. Dec 2009 A1
20100062165 Suzuki Mar 2010 A1
20100062934 Suzuki Mar 2010 A1
20100063470 Suzuki Mar 2010 A1
20100068520 Stueven et al. Mar 2010 A1
20100100065 Bianco Apr 2010 A1
20100115237 Brewer et al. May 2010 A1
20100121296 Noda May 2010 A1
20100137773 Gross Jun 2010 A1
20100137823 Corneliusson Jun 2010 A1
20100198179 Noda Aug 2010 A1
20100228210 Busam et al. Sep 2010 A1
20100241096 LaVon et al. Sep 2010 A1
20100241097 Nigam et al. Sep 2010 A1
20100262099 Klofta Oct 2010 A1
20100274208 Gabrielii Oct 2010 A1
20100274210 Noda Oct 2010 A1
20100312208 Bond et al. Dec 2010 A1
20100324521 Mukai Dec 2010 A1
20100324523 Mukai Dec 2010 A1
20110041999 Hundorf et al. Feb 2011 A1
20110060303 Bissah Mar 2011 A1
20110066127 Kuwano Mar 2011 A1
20110071486 Harada Mar 2011 A1
20110092944 Sagisaka Apr 2011 A1
20110112498 Nhan et al. May 2011 A1
20110125120 Nishitani May 2011 A1
20110130732 Jackels et al. Jun 2011 A1
20110130737 Sagisaka Jun 2011 A1
20110137276 Yoshikawa Jun 2011 A1
20110144602 Long Jun 2011 A1
20110144604 Noda Jun 2011 A1
20110144606 Nandrea Jun 2011 A1
20110152813 Ellingson Jun 2011 A1
20110166540 Yang et al. Jul 2011 A1
20110172630 Nomoto Jul 2011 A1
20110174430 Zhao Jul 2011 A1
20110208147 Kawakami et al. Aug 2011 A1
20110250413 Lu et al. Oct 2011 A1
20110268932 Catalan et al. Nov 2011 A1
20110274834 Brown et al. Nov 2011 A1
20110288513 Hundorf et al. Nov 2011 A1
20110288514 Kuroda Nov 2011 A1
20110295222 Becker et al. Dec 2011 A1
20110319846 Rinnert et al. Dec 2011 A1
20110319848 McKiernan et al. Dec 2011 A1
20110319851 Kudo Dec 2011 A1
20120004633 Marcelo Jan 2012 A1
20120016326 Brennan et al. Jan 2012 A1
20120022479 Cotton Jan 2012 A1
20120035566 Sagisaka Feb 2012 A1
20120035576 Ichikawa Feb 2012 A1
20120064792 Bauduin Mar 2012 A1
20120071848 Zhang Mar 2012 A1
20120165771 Ruman et al. Jun 2012 A1
20120165776 McGregor et al. Jun 2012 A1
20120175056 Tsang Jul 2012 A1
20120184934 Venturino Jul 2012 A1
20120232514 Baker Sep 2012 A1
20120238977 Oku Sep 2012 A1
20120253306 Otsubo Oct 2012 A1
20120256750 Novak Oct 2012 A1
20120271262 Venturino Oct 2012 A1
20120312491 Jackels et al. Dec 2012 A1
20120316046 Jackels et al. Dec 2012 A1
20120316523 Hippe et al. Dec 2012 A1
20120316526 Rosati et al. Dec 2012 A1
20120316527 Rosati et al. Dec 2012 A1
20120316528 Kreuzer et al. Dec 2012 A1
20120316529 Kreuzer et al. Dec 2012 A1
20120323195 Ehrnsperger et al. Dec 2012 A1
20120323201 Bissah Dec 2012 A1
20120323202 Bissah Dec 2012 A1
20130035656 Moriya et al. Feb 2013 A1
20130041334 Prioleau Feb 2013 A1
20130211354 Tsuji et al. Aug 2013 A1
20130218115 Katsuragawa et al. Aug 2013 A1
20130226119 Katsuragawa et al. Aug 2013 A1
20130226120 Van De Maele Aug 2013 A1
20140005622 Wirtz et al. Jan 2014 A1
20140005623 Wirtz et al. Jan 2014 A1
20140027066 Jackels et al. Jan 2014 A1
20140039437 Van De Maele Feb 2014 A1
20140045683 Loick et al. Feb 2014 A1
20140135726 Busam et al. May 2014 A1
20140142531 Sasayama et al. May 2014 A1
20140163500 Roe et al. Jun 2014 A1
20140163501 Ehrnsperger et al. Jun 2014 A1
20140163502 Arizti et al. Jun 2014 A1
20140163503 Arizti et al. Jun 2014 A1
20140163506 Roe et al. Jun 2014 A1
20140163511 Roe et al. Jun 2014 A1
20140171893 Lawson et al. Jun 2014 A1
20140318694 Blessing et al. Oct 2014 A1
20140324007 Hundorf et al. Oct 2014 A1
20140324008 Hundorf et al. Oct 2014 A1
20150065986 Blessing et al. Mar 2015 A1
Foreign Referenced Citations (523)
Number Date Country
2001370 Apr 1990 CA
2291997 Jun 2000 CA
2308961 Nov 2000 CA
2487027 Dec 2003 CA
2561521 Mar 2007 CA
2630713 Nov 2008 CA
2636673 Jan 2009 CA
2712563 Aug 2010 CA
2702001 Oct 2010 CA
1238171 Dec 1999 CN
2362468 Feb 2000 CN
1371671 Feb 2001 CN
2527254 Dec 2002 CN
2535020 Feb 2003 CN
2548609 May 2003 CN
1539391 Oct 2004 CN
1939242 Apr 2007 CN
101292930 Oct 2008 CN
201263750 Jul 2009 CN
201591689 Sep 2010 CN
201855366 Jun 2011 CN
3205931 Sep 1983 DE
3608114 Sep 1987 DE
19732499 Feb 1999 DE
10204937 Aug 2003 DE
149880 Jul 1985 EP
0149880 Jul 1985 EP
0203289 Dec 1986 EP
0203289 Dec 1986 EP
0206208 Dec 1986 EP
209561 Jan 1987 EP
297411 Jan 1989 EP
304957 Mar 1989 EP
374542 Jun 1990 EP
394274 Oct 1990 EP
0403832 Dec 1990 EP
481322 Apr 1992 EP
530438 Mar 1993 EP
547847 Jun 1993 EP
083022 Jul 1993 EP
555346 Aug 1993 EP
559476 Sep 1993 EP
591647 Apr 1994 EP
597273 May 1994 EP
601610 Jun 1994 EP
632068 Jan 1995 EP
0640330 Mar 1995 EP
0668066 Sep 1995 EP
685214 Dec 1995 EP
687453 Dec 1995 EP
0689817 Jan 1996 EP
0691133 Jan 1996 EP
0394274 Jul 1996 EP
724418 Aug 1996 EP
725613 Aug 1996 EP
725615 Aug 1996 EP
725616 Aug 1996 EP
758543 Feb 1997 EP
0761194 Mar 1997 EP
769284 Apr 1997 EP
0781537 Jul 1997 EP
783877 Jul 1997 EP
787472 Aug 1997 EP
788874 Aug 1997 EP
796068 Sep 1997 EP
799004 Oct 1997 EP
822794 Feb 1998 EP
826351 Mar 1998 EP
844861 Jun 1998 EP
0737055 Aug 1998 EP
863733 Sep 1998 EP
971751 Sep 1998 EP
0875224 Nov 1998 EP
875224 Nov 1998 EP
880955 Dec 1998 EP
891758 Jan 1999 EP
0893115 Jan 1999 EP
0724418 Mar 1999 EP
0725613 Mar 1999 EP
0725616 Mar 1999 EP
904755 Mar 1999 EP
0916327 May 1999 EP
925769 Jun 1999 EP
933074 Aug 1999 EP
937736 Aug 1999 EP
941157 Sep 1999 EP
947549 Oct 1999 EP
951887 Oct 1999 EP
0951890 Oct 1999 EP
2295493 Oct 1999 EP
2305749 Oct 1999 EP
2330152 Oct 1999 EP
953326 Nov 1999 EP
0978263 Feb 2000 EP
985397 Mar 2000 EP
0778762 Apr 2000 EP
1005847 Jun 2000 EP
1008333 Jun 2000 EP
1013252 Jun 2000 EP
1018999 Jul 2000 EP
1019002 Jul 2000 EP
1019003 Jul 2000 EP
1022008 Jul 2000 EP
1023884 Aug 2000 EP
1053729 Nov 2000 EP
1059072 Dec 2000 EP
1063954 Jan 2001 EP
1071388 Jan 2001 EP
1078618 Feb 2001 EP
1088537 Apr 2001 EP
0796068 May 2001 EP
0752892 Jul 2001 EP
1116479 Jul 2001 EP
0790839 Aug 2001 EP
1132069 Sep 2001 EP
1173128 Jan 2002 EP
1175194 Jan 2002 EP
1184018 Mar 2002 EP
1192312 Apr 2002 EP
1196122 Apr 2002 EP
1199059 Apr 2002 EP
1199327 Apr 2002 EP
1208824 May 2002 EP
0793469 Jun 2002 EP
1210925 Jun 2002 EP
1224922 Jul 2002 EP
1225857 Jul 2002 EP
1253231 Oct 2002 EP
1262531 Dec 2002 EP
1263374 Dec 2002 EP
0737056 Jan 2003 EP
1275358 Jan 2003 EP
1275361 Jan 2003 EP
1293187 Mar 2003 EP
1304986 May 2003 EP
1332742 Aug 2003 EP
1339368 Sep 2003 EP
1374817 Jan 2004 EP
1388334 Feb 2004 EP
1402863 Mar 2004 EP
962208 Aug 2004 EP
1447066 Aug 2004 EP
1447067 Aug 2004 EP
1460987 Sep 2004 EP
963749 Nov 2004 EP
1495739 Jan 2005 EP
1524955 Apr 2005 EP
1920743 Apr 2005 EP
1541103 Jun 2005 EP
1551344 Jul 2005 EP
1586289 Oct 2005 EP
1588723 Oct 2005 EP
1605882 Dec 2005 EP
1609448 Dec 2005 EP
1621166 Feb 2006 EP
1621167 Feb 2006 EP
1632206 Mar 2006 EP
1642556 Apr 2006 EP
1403419 May 2006 EP
1656162 May 2006 EP
1669046 Jun 2006 EP
1688114 Aug 2006 EP
2314265 Aug 2006 EP
1723939 Nov 2006 EP
1738727 Jan 2007 EP
1754461 Feb 2007 EP
1787611 May 2007 EP
1813238 Aug 2007 EP
2008626 Dec 2008 EP
2055279 May 2009 EP
2093049 Aug 2009 EP
2130522 Dec 2009 EP
1621165 Apr 2010 EP
2444046 Apr 2012 EP
2532328 Dec 2012 EP
2532329 Dec 2012 EP
2532332 Dec 2012 EP
2679210 Jan 2014 EP
2740449 Jun 2014 EP
2740450 Jun 2014 EP
2740452 Jun 2014 EP
2213491 Aug 2004 ES
2566631 Jan 1986 FR
2583377 Dec 1986 FR
2612770 Sep 1988 FR
2810234 Dec 2001 FR
1333081 Aug 1971 GB
1307441 Feb 1973 GB
1513055 Jun 1978 GB
2101468 Jan 1983 GB
2170108 Jul 1986 GB
2262873 Jul 1993 GB
2288540 Jun 1994 GB
2354449 Mar 2001 GB
2452260 Oct 2007 GB
851769 Nov 1985 GR
0984KOL1999 Oct 2005 IN
212479 Mar 2007 IN
208543 Aug 2007 IN
0980MUM2009 Jun 2009 IN
2107250 Apr 1990 JP
03224481 Oct 1991 JP
04122256 Apr 1992 JP
04341368 Nov 1992 JP
06191505 Jul 1994 JP
06269475 Sep 1994 JP
07124193 May 1995 JP
08215629 Aug 1996 JP
10328232 Dec 1998 JP
11318980 Nov 1999 JP
11320742 Nov 1999 JP
2000232985 Aug 2000 JP
2000238161 Sep 2000 JP
2001046435 Feb 2001 JP
2001037810 Feb 2001 JP
2001120597 May 2001 JP
2001158074 Jun 2001 JP
2001178768 Jul 2001 JP
2001198157 Jul 2001 JP
2001224626 Aug 2001 JP
2001277394 Oct 2001 JP
03420481 Nov 2001 JP
2001321397 Nov 2001 JP
2001353174 Dec 2001 JP
2002052042 Feb 2002 JP
2002065718 Mar 2002 JP
2002113800 Apr 2002 JP
2002165832 Jun 2002 JP
2002165836 Jun 2002 JP
2002178429 Jun 2002 JP
2002272769 Sep 2002 JP
2002320641 Nov 2002 JP
2002325792 Nov 2002 JP
2002325799 Nov 2002 JP
2003144486 May 2003 JP
2003126140 May 2003 JP
2003153955 May 2003 JP
2003210522 Jul 2003 JP
2003265523 Sep 2003 JP
2003265524 Sep 2003 JP
2003275237 Sep 2003 JP
2004089269 Mar 2004 JP
03566012 Jun 2004 JP
03568146 Jun 2004 JP
03616077 Nov 2004 JP
2004337385 Dec 2004 JP
2004337314 Dec 2004 JP
2004350864 Dec 2004 JP
03640475 Jan 2005 JP
2005000312 Jan 2005 JP
03660816 Mar 2005 JP
03676219 May 2005 JP
03688403 Jun 2005 JP
03705943 Aug 2005 JP
03719819 Sep 2005 JP
03724963 Sep 2005 JP
03725008 Sep 2005 JP
03737376 Nov 2005 JP
2006014792 Jan 2006 JP
03781617 Mar 2006 JP
2006110329 Apr 2006 JP
2006513824 Apr 2006 JP
03801449 May 2006 JP
2006116036 May 2006 JP
03850102 Sep 2006 JP
03850207 Sep 2006 JP
03856941 Sep 2006 JP
03868628 Oct 2006 JP
03874499 Nov 2006 JP
03877702 Nov 2006 JP
2006325639 Dec 2006 JP
2006346021 Dec 2006 JP
03904356 Jan 2007 JP
2007007455 Jan 2007 JP
2007007456 Jan 2007 JP
03926042 Mar 2007 JP
03934855 Mar 2007 JP
2007089906 Apr 2007 JP
2007105198 Apr 2007 JP
2007152033 Jun 2007 JP
03986210 Jul 2007 JP
03986222 Jul 2007 JP
2007167453 Jul 2007 JP
2007175515 Jul 2007 JP
2007195665 Aug 2007 JP
2007267763 Oct 2007 JP
2007275491 Oct 2007 JP
04035341 Nov 2007 JP
04058281 Dec 2007 JP
04061086 Dec 2007 JP
04092319 Mar 2008 JP
2008080150 Apr 2008 JP
2008093289 Apr 2008 JP
04124322 May 2008 JP
2008119081 May 2008 JP
2008136739 Jun 2008 JP
2008136877 Jun 2008 JP
04148594 Jul 2008 JP
04148620 Jul 2008 JP
2008154606 Jul 2008 JP
04162609 Aug 2008 JP
04162637 Aug 2008 JP
04166923 Aug 2008 JP
04167406 Aug 2008 JP
04173723 Aug 2008 JP
04190675 Sep 2008 JP
04190693 Sep 2008 JP
04208338 Oct 2008 JP
2008246089 Oct 2008 JP
04230971 Dec 2008 JP
2008295475 Dec 2008 JP
2008295713 Dec 2008 JP
04261593 Feb 2009 JP
2009112590 May 2009 JP
04322228 Jun 2009 JP
2009136601 Jun 2009 JP
2009142401 Jul 2009 JP
2009201878 Sep 2009 JP
04392936 Oct 2009 JP
2009261777 Nov 2009 JP
2009291473 Dec 2009 JP
2009297048 Dec 2009 JP
2010017342 Jan 2010 JP
04458702 Feb 2010 JP
04459013 Feb 2010 JP
2010022560 Feb 2010 JP
04481325 Mar 2010 JP
2010051654 Mar 2010 JP
2010063814 Mar 2010 JP
2010063944 Mar 2010 JP
2010075462 Apr 2010 JP
04492957 Apr 2010 JP
2010068954 Apr 2010 JP
2010082059 Apr 2010 JP
2010104545 May 2010 JP
2010104547 May 2010 JP
2010110535 May 2010 JP
2010119454 Jun 2010 JP
2010119605 Jun 2010 JP
2010119743 Jun 2010 JP
2010131131 Jun 2010 JP
2010131132 Jun 2010 JP
2010131206 Jun 2010 JP
2010131297 Jun 2010 JP
2010136917 Jun 2010 JP
2010136973 Jun 2010 JP
04540563 Jul 2010 JP
04587947 Sep 2010 JP
2010201093 Sep 2010 JP
2010221067 Oct 2010 JP
04620299 Nov 2010 JP
04627472 Nov 2010 JP
04627473 Nov 2010 JP
04638087 Dec 2010 JP
04652626 Dec 2010 JP
2010273842 Dec 2010 JP
2010284418 Dec 2010 JP
2011000480 Jan 2011 JP
2011030700 Feb 2011 JP
04693574 Mar 2011 JP
2011067484 Apr 2011 JP
2011072720 Apr 2011 JP
2011104014 Jun 2011 JP
2011104122 Jun 2011 JP
2011120661 Jun 2011 JP
2011125360 Jun 2011 JP
2011125537 Jun 2011 JP
04776516 Jul 2011 JP
2011130797 Jul 2011 JP
2011130799 Jul 2011 JP
2011156032 Aug 2011 JP
2011156070 Aug 2011 JP
2011156254 Aug 2011 JP
04824882 Sep 2011 JP
4850272 Oct 2011 JP
04855533 Nov 2011 JP
2011239858 Dec 2011 JP
04931572 Feb 2012 JP
04937225 Mar 2012 JP
04953618 Mar 2012 JP
04969437 Apr 2012 JP
04969640 Apr 2012 JP
4971491 Apr 2012 JP
04974524 Apr 2012 JP
04979780 Apr 2012 JP
05016020 Jun 2012 JP
05027364 Jun 2012 JP
05031082 Jul 2012 JP
05042351 Jul 2012 JP
05043569 Jul 2012 JP
05043591 Jul 2012 JP
05046488 Jul 2012 JP
2012125625 Jul 2012 JP
05053765 Aug 2012 JP
05070275 Aug 2012 JP
05079931 Sep 2012 JP
05080189 Sep 2012 JP
05084442 Sep 2012 JP
05084476 Sep 2012 JP
5085770 Sep 2012 JP
05089269 Sep 2012 JP
05113146 Oct 2012 JP
05129536 Nov 2012 JP
05105884 Dec 2012 JP
20010005620 Jan 2001 KR
20020035634 May 2002 KR
20080028771 Apr 2008 KR
9400916 Mar 1994 SE
9704893 Dec 1997 SE
WO9015830 Dec 1990 WO
WO9219198 Nov 1992 WO
WO9321237 Oct 1993 WO
WO9321879 Nov 1993 WO
WO9510996 Apr 1995 WO
WO9511652 May 1995 WO
WO9514453 Jun 1995 WO
WO9515139 Jun 1995 WO
WO9516424 Jun 1995 WO
WO9516746 Jun 1995 WO
WO9519753 Jul 1995 WO
WO9521596 Aug 1995 WO
WO9524173 Sep 1995 WO
WO9526209 Oct 1995 WO
WO9529657 Nov 1995 WO
WO9532698 Dec 1995 WO
WO9534329 Dec 1995 WO
WO9616624 Jun 1996 WO
WO9619173 Jun 1996 WO
WO9629967 Oct 1996 WO
WO9711659 Apr 1997 WO
WO9717922 May 1997 WO
WO9816179 Apr 1998 WO
WO9816180 Apr 1998 WO
WO9843684 Oct 1998 WO
WO9913813 Mar 1999 WO
WO9934841 Jul 1999 WO
WO9951178 Oct 1999 WO
WO0000235 Jan 2000 WO
WO0032145 Jun 2000 WO
WO0059430 Oct 2000 WO
WO0115647 Mar 2001 WO
WO0126596 Apr 2001 WO
WO0207663 Jan 2002 WO
WO0232962 Apr 2002 WO
WO02064877 Aug 2002 WO
WO02067809 Sep 2002 WO
WO03009794 Feb 2003 WO
WO03039402 May 2003 WO
WO03053297 Jul 2003 WO
WO03079946 Oct 2003 WO
WO03101622 Dec 2003 WO
WO03105738 Dec 2003 WO
WO2004021946 Mar 2004 WO
WO2004049995 Jun 2004 WO
WO2004071539 Aug 2004 WO
WO2004084784 Oct 2004 WO
WO2004105664 Dec 2004 WO
WO2005018694 Mar 2005 WO
WO2005087164 Sep 2005 WO
WO2006104024 May 2006 WO
WO2006059922 Jun 2006 WO
WO2006062258 Jun 2006 WO
WO2006066029 Jun 2006 WO
WO2006083584 Aug 2006 WO
WO2006134904 Dec 2006 WO
WO2006134906 Dec 2006 WO
WO2007000315 Jan 2007 WO
WO2007046052 Apr 2007 WO
WO2007047598 Apr 2007 WO
WO2007049725 May 2007 WO
WO2007061035 May 2007 WO
WO2007142145 Dec 2007 WO
WO2007148502 Dec 2007 WO
WO2008018922 Feb 2008 WO
WO2008065945 Jun 2008 WO
WO2008146749 Dec 2008 WO
WO2008155699 Dec 2008 WO
WO2009004941 Jan 2009 WO
WO2009005431 Jan 2009 WO
WO2009139248 Jan 2009 WO
WO2009139255 Jan 2009 WO
WO2009041223 Apr 2009 WO
WO2009096108 Aug 2009 WO
WO2009107435 Sep 2009 WO
WO2009122830 Oct 2009 WO
WO2009152018 Dec 2009 WO
WO2009155264 Dec 2009 WO
WO2009155265 Dec 2009 WO
WO2010071508 Jun 2010 WO
WO2010074319 Jul 2010 WO
WO2010107096 Sep 2010 WO
WO2010114052 Oct 2010 WO
WO2010117015 Oct 2010 WO
WO2011053044 May 2011 WO
WO2011118725 Sep 2011 WO
WO2011118842 Sep 2011 WO
WO2011145653 Nov 2011 WO
WO2011162582 Dec 2011 WO
WO2012002252 Jan 2012 WO
WO2012014436 Feb 2012 WO
WO2012042908 Apr 2012 WO
WO2012043077 Apr 2012 WO
WO2012043078 Apr 2012 WO
WO2012052172 Apr 2012 WO
WO2012043082 May 2012 WO
WO2012067216 May 2012 WO
WO2012073499 Jun 2012 WO
WO2012074466 Jun 2012 WO
WO2012090508 Jul 2012 WO
WO2012091016 Jul 2012 WO
WO2012101934 Aug 2012 WO
WO2012102034 Aug 2012 WO
WO2012117824 Sep 2012 WO
WO2012132460 Oct 2012 WO
2012170779 Dec 2012 WO
WO2012170778 Dec 2012 WO
WO2012170779 Dec 2012 WO
WO2012170781 Dec 2012 WO
WO2012170808 Dec 2012 WO
WO2012174026 Dec 2012 WO
WO2013001788 Jan 2013 WO
WO2013060733 May 2013 WO
WO2014078247 May 2014 WO
Related Publications (1)
Number Date Country
20150374562 A1 Dec 2015 US
Continuations (2)
Number Date Country
Parent 14485836 Sep 2014 US
Child 14845743 US
Parent 13491987 Jun 2012 US
Child 14485836 US