Disposal of radiation waste in glacial ice

Information

  • Patent Grant
  • 6342650
  • Patent Number
    6,342,650
  • Date Filed
    Wednesday, June 23, 1999
    25 years ago
  • Date Issued
    Tuesday, January 29, 2002
    22 years ago
  • Inventors
  • Examiners
    • Griffin; Steven P.
    • Nave; Eileen E.
    Agents
    • Zarley, McKee, Thomte, Voorhees & Sease, P.L.C.
Abstract
Encapsulating calcined radioactive waste in strong, corrosion-resistant spheres of dimensions such that heat from the radiation melts the ice at a rate which brings the spheres to the bottom of the permanent icefield in a relatively short time, with the resulting waste ultimately being no more hazardous than natural uranium ore.
Description




FIELD OF THE INVENTION




This invention relates to fission product disposal in permanent icefields.




BACKGROUND OF THE INVENTION




One of the major impediments to the social acceptance of nuclear power is the still unresolved question of the disposal of the radioactive high level waste from nuclear reactors. Presently the spent fuel rods are mostly being stored on site and the solution to the problem being postponed. Meanwhile, spent fuel from most of the world's reactors accumulates and the problem becomes ever more serious. The longer a decision on the method of disposal to be used is postponed, the greater becomes the probability of a serious nuclear related accident or intentionally motivated major incident.




The solution to the disposal problem has to ensure the safe isolation of the radioactive waste from the biosphere while it remains hazardous. Technically this should not be a major problem, but it has to be done in an environmentally and socially acceptable manner, as well as in a manner to insure inaccessibility for security reasons.




Simply put, a debt that is owed to future generations is to minimize the hazard from the radioactive legacy that we have already left them. It takes hundreds of thousands of years for the ingestion hazard index from unreprocessed spent fuel from light water reactors to diminish until it is no more than that from the naturally occurring uranium that the fuel originated from. (See for ex. Benedict, M., Pigford, T. H., Levi H. W.,


Nuclear Chemical Engineering


, McGraw Hill Book Company, New York, 1981, p.573 and p.623). If, on the other hand, the fuel is reprocessed and the actinides removed and disposed of, that time can be shortened to a time span of the order of a thousand years. Hence, for a cleaner future environment one should preferably also reclaim and“burn” the plutonium that presently exists in spent nuclear fuel. For example, according to Albright, F. B., Walker, W.,


World Inventory of Plutonium and Highly Enriched Uranium


1992, Oxford University Press, Oxford, 1993, the sum of already accumulated spent nuclear fuel and that which is projected to the year 2000 is about 220,000 tonnes. At a burnup, roughly estimated, of 30,000 Mwd/tonne (of fuel) this corresponds to thermal energy production of 6,600,000,000 Mwd. Since each Megawatt-day of energy production is accompanied by the formation of just about 1.04 g. of fission products the quantity of fission products accumulated worldwide up to the end of the millenium is close to 7,000 tonnes.




The corresponding Plutonium content of the spent fuel is estimated at 1390 tonnes, if all this is fissioned it corresponds to an additional 1,338,000,000 Mwd or 20% of the energy already realized from the spent fuel. With continuous reprocessing and recycling that converts more Uranium-238 into plutonium that figure roughly doubles adding yet another 20%. Apart from providing energy the recycled Plutonium would be disposed of as a very long lived radiation hazard and potential nuclear weapons material.




Accordingly, it can be seen that there is a real and a continuing need for safe effective disposal of fissile isotopes and fission products in a manner that creates no environmental hazard for present or future generations. This invention has, as its primary objective, helping to fulfill this need.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

shows one a cross section of possible configuration and dimensions for spherical disposal containers useful in the present invention.





FIG. 2

shows a temperature profile for both core and shield for the spheres of the present invention.











SUMMARY OF THE INVENTION




This invention involves radioactive waste disposal in deep permanent ice. Properly carried out, it has the advantage of isolating the high level radioactive waste from the biosphere in remote areas, far from human habitation. The isolation from the environment can last for sufficiently long to ensure that the ingestion hazard index posed by the waste is no more than that associated with the uranium ore that it originated from. Furthermore, disposal in deep permanent ice provides for relatively easy placement of the radioactive waste in its ultimate repository by letting it melt its way to the bottom, while making it exceedingly hard to retrieve from glacial depths as the ice will refreeze over it.




DETAILED DESCRIPTION OF THE INVENTION




It was mentioned above that the hazard index for fission products, after separation from the actinides, declined to the same value as that of natural uranium in a time span of the order of a thousand years. Reprocessing on such a basis leaves less of a radioactive legacy for future generations than the alternative of not reprocessing. Such a process encourages use of nuclear power with a simultaneous suggestion of the means of ultimate disposal of radioactive waste. Recent drillings in the central Greenland icecap have revealed a stability that has a time scale of a hundred thousand years. Encapsulating radioactive waste, preferably in solid form, in such amounts and in sufficiently strong and corrosion-resistant containers of such size that the heat from the radiation should suffice to melt the ice at a rate which brings them relatively quickly to the bottom, is possible. After about 800-1000 years the waste will be no more hazardous than the natural uranium which undoubtedly is to be found in many places underneath the ice cap. Antarctica would be even more suitable for disposal because of its remoteness from any human habitation, now or in the foreseeable future.




The following calculations and configuration description for the spherical capsules demonstrate the feasibility of the invention with respect to the spheres shown in

FIG. 1

which are described below. The example is offered as illustrative, but not limiting.




EXAMPLE




As an example of a disposal site, the central Greenland icecap was chosen. Recent drillings to the bottom of the ice have shown that it has remained stable for 100,000 years. Borehole temperature varies from −35° C. on top to about −10° C. at the bottom.




For the fission product disposal, a typical power reactor, namely a 1000 MWe reactor, was chosen as the reference case. A 1000 MWe reactor operating at 33% efficiency will generate 3.12 kg of fission products per day. Typically about 100 metric tons (i.e. Megagrams, Mg, or tonnes) of fuel will be irradiated in a power reactor to a burnup of 2600 TJ per ton of reactor fuel (30,000 Megawatt days per tonne). One third of the fuel is generally replaced annually, giving a residence time of three years. Annual reactor operation for 330 days will thus generate 330×3.12=1029.6 kg of fission products, or just about one tonne.




From yield tables for the fission of U235 (Benedict, M. and Pigford, T., et al.,


Nuclear Chemical Engineering


, 2nd ed., McGraw Hill, New York, 1981) and density data (Emsley, J., The Elements, Oxford University Press, Oxford, 1989) it can be shown that fission products from one tonne of U235 fissioned will, when Xenon and Krypton are discounted, produce close to 834 kilograms of elemental fission products that have a mean density of 4200 kg/m


3


. If the fission products apart from Xenon and Krypton are in oxide form (assuming the highest oxidation states), one tonne of U235 will generate about one tonne of fission product oxides. These will have a mean density of about 4260 kg/m


3


and occupy a volume of 0.237 m


3


. The results of such a calculation are shown in Table 1.












TABLE 1











DATA PERTAINING TO FISSION PRODUCTS
























YIELD




ATOMIC








MOL.











FISSION




Atoms/




WT.




MASS




DENSITY




VOLUME





WT.




YIELD




MASS




DENSITY




VOLUME






PROD.




fiss




g/g-atom




g




g/cm


3






cm


3






OXIDE




g/mole




mol./fiss.




g




g/cm


3






cm


3






COMM.


























(Light)


















Kr




0.032




 84




(2.668)














































Rb




0.028




 85




2.38




1.5




1.5866667




Rb


2


O




186




0.014




2.604




3.7




0.7037838




d. 400° C.






Sr




0.074




 89




6.586




2.6




2.5330769




SrO




105




0.074




7.77




4.7




1.6531915






Y




0.038




 89




3.382




4.5




0.7515556




Y


2


O


3






226




0.019




4.294




5




0.8588  






Zr




0.281




 91




25.571




6.5




3.934  




ZrO


2






123




0.281




34.563




3.25




10.634769 






Mo




0.241




 96




23.136




10.2




2.2682353




MoO


3






144




0.241




34.704




4.7




7.3838298






Tc




0.058




 98




5.684




11.5




0.4942609




Tc


2


O


7






308




0.029




8.932




3.9




2.2902564






Ru




0.141




101




14.241




1.5




9.494  




RuO


4






165




0.141




23.265




3.3




7.05   






Rh




0.024




103




2.472




21




0.1177143




RhO


2






135




0.024




3.24




7.1




0.456338 






Pd




0.067




106




7.102




12




0.5918333




PdO


2






138




0.067




9.246




6.2




1.4912903






SUM:




0.984




SUM:




90.554




SUM:




21.771343 






SUM:




90.554




SUM:




32.522259 






(Heavy)






Te




0.029




128




3.712




6.2




0.5987097




TeO


3






176




0.029




5.104




5.1




1.0007843






I




0.012




127




1.524




4.9




0.3110204




I


2


O


5






334




0.006




2.004




4.8




0.4175  




d. 300° C.






Xe




0.276




131




(36.156)














































Cs




0.135




133




17.955




1.8




9.975  




Cs


2


O




282




0.067




18.894




4.3




4.3939535






Ba




0.067




137




9.179




3.7




2.4808108




BaO




153




0.067




10.251




5.7




1.7984211






La




0.062




139




8.618




6.1




1.4127869




La


2


O


3






326




0.031




10.106




6.5




1.5547692






Ce




0.133




140




18.62




6.7




2.7791045




CeO


2






172




0.133




22.876




7.1




3.2219718






Pr




0.059




141




8.319




6.7




1.2416418




PrO


2






173




0.059




10.207




6.8




1.5010294






Nd




0.184




144




26.496




7




3.7851429




Nd


2


O


3






336




0.184




61.824




7.2




8.5866667






Sm




0.035




150




5.25




7.5




0.7000000




Sm


2


O


3






348




0.017




5.916




8.3




0.7127711






SUM:




0.992




SUM:




99.673




SUM:




23.284217 






SUM:




147.182




SUM:




23.187867











Mean density of solid fission products: 4.22 g/cm


3












Mean density of oxides approximately 4.26 g/cm


3












For every 235 g. U-235 fissioned Xe and Kr account for 39 g. leaving 196 g. of other fission products. Thus 1 ton of f.p. formed leaves 834 kg. of elemental f.p.'s other than Xe and Kr.










For every 235 g. U 235 fissioned the fission product oxides (assuming highest oxidation state) amount to approximately 240 g. Thus one ton of fission products will generate about 1 ton of fission product oxides (Xe and Kr discounted). At a mean density of 4.26 kg/l this will occupy 0.235 m


3


.













It is given that the actinides should be separated from the fission products to the maximum feasible extent because of their long life. They can be reprocessed to be used mostly as fuel. The remaining fission products will have to be isolated from the environment for 800-1000 years, after which they are no more hazardous than the uranium ore from which they originated, or the uranium ore that must also exist naturally under such large icecaps as the Greenland icecap.





FIG. 1

shows a typical disposal capsule (spherical in this example) configuration and its dimensions. The constraints on the design of a capsule


10


, which consists of a core matrix


11


in which the fission products


12


are embedded and a radiation shield


13


, to transport them through the ice are: (1) the temperature at the center


14


, which limits both the amount and the concentration of the fission products


12


which can be encapsulated in one unit


10


; (2) the radiation outside the capsule


10


, which must not exceed safety limits while being handled and transported prior to burial in the ice; and (3) the outside surface


16


temperature of the capsule which must be sufficient to melt the ice while it is reaching bottom, yet not sufficiently high to seriously enhance corrosion of the capsule.




The constraint that the fission products (in oxide form in this example)


12


at the center of the container shall remain solid and preferably none to decompose, puts very strict limitations on how high the temperature can be allowed to rise at the center


14


. Ultimately this depends on the rate of heat generation per unit volume in the core


11


that the fission products


12


are embedded in, the volume they occupy, their age, the material they may be mixed with, and the rate of heat removal. The heat removal rate, in turn, depends upon the size of the container


10


, the thermal conductivity of the core


11


and shield


13


, as well as the thermal conductivity of the surrounding environment (i.e., whether it is air, water, or ice). The second criterion listed above also depends upon the core volume containing the fission products


12


, the materials they are mixed with, and the thickness of the shield


13


, as well as its material. The same factors apply to the third criterion. The restrictions that these criteria impose may overlap, yet all three have to be met.




The best solution is to start by storing the spent fuel for a period to let the short lived fission products decay. All things considered, a period of ten years seems desirable. Then the fuel should be reprocessed and the fission products separated from the actinides. The latter should be recycled and fissioned or transmuted into shorter lived isotopes. The extended storage and the removal of the actinides greatly relaxes both the shielding and thermal constraints. None the less, it was found that the thermal restrictions still necessitated dividing the ton of fission product oxides into smaller portions to be individually encapsulated. The size of the portions depends on the core temperature restrictions which, in turn, depend on whether the fission products (or their oxides in this example) are mixed with another material or not and, if so, which material. A conservative approach would be to embed the calcined fission products


12


in a metal matrix , similar to what is done in the PAMELA process (Benedict, M., Pigford, T. H., Levi H. W.,


Nuclear Chemical Engineering


, McGraw Hill Book Company, New York, 1981), which is incorporated herein by reference. This entails a lead content of 33% by volume. A lead alloy, such as a tin lead alloy, or some other metal may also be used. However, lead's or the lead alloy's low melting point and poor thermal conductivity limit the total energy released by radiation within each sphere to much lesser values than a metal with a higher melting point, or thermal conductivity such as copper. Copper, on the other hand, may be incompatible with some of the more volatile fission products or their unstable oxides when molten copper is applied to form the embedding matrix. This might require separate handling for the volatile fission products such as iodine. However, the embedding matrix may also be deposited by electrochemical means. Copper also has a lower linear absorption coefficient for gamma rays than does lead.




During the storage period many fission products with short half lives become insignificant as radiation sources. The more pertinent ones from a shielding point of view are listed in Table 2. Because of the low penetrating power of beta radiation, only gamma shielding needs consideration. The shield can be made of a variety of corrosion resistant materials that have good radiation shielding and thermal characteristics, certain grades of stainless steel being among them.




An accurate shield


13


design, of for example stainless steel (other known corrosion resistant materials can also be used), requires a multigroup-multiregion calculation, but a less precise analytical approach will be used here which none the less is sufficiently accurate for illustrative design purposes. The basis for the capsule design in this example will be 100 kg of fission products embedded in oxide form in a lead matrix where the fission product oxide content is 67% by volume. The volume occupied by the oxides and the lead is referred to as the core volume. Averaging of density data from Table 1 and the density of lead will give an average density of 6600 kg/m


3


for the core volume. For 100 kg of fission products this volume will be 0.036 m


3


which corresponds to a radius of just about 0.2 m. From Table 2 it is seen that the average gamma energy is 0.72 Mev. This gives the core a mass absorption coefficient of 0.085 cm


2


/g, which at the given density corresponds to a linear absorption coefficient of 0.563 cm


−1


. The reciprocal, namely the relaxation length, λ


c


, will be 1.77 cm or 0.0177 m for the core volume. For the stainless steel encapsulating the core, with a density of 7800 kg/m


3


and a corresponding mass absorption coefficient of 0.073 cm


2


/g, the value of the relaxation length turns out to be almost the same, or 0.0176 m.




From Table 2 it is seen that the gamma flux for the ton or so of fission product oxides that stem from 33 tons of spent fuel that has been stored for ten years is 1.042×10


17


photons/s. When the fission product oxides are subdivided into the 100 kg lots as are contained in the core volume, it is seen that the gamma radiation from the core is 1.042×10


17


×0.1=1.042×10


16


photons/s. Given the core volume of 0.036 m


3


, this will give a core volume unit strength, S(ν,γ), of:






S(ν,γ)=1.042×10


16


/0.036×2.894×10


17


photons/s m


3


  (1)






The corresponding surface flux, S(a,γ), from the core will be:






S(a,γ)=λ


c


S(ν,γ)=0.0177×2.894×10


17


=5.123×10


15


photons/s m


2


  (2)














TABLE 2











ACTIVITY OF MAJOR FISSION PRODUCTS AFTER TEN YEARS OF COOLING




















HALF LIFE





A(10 yr.)





A(10)*E




A(10 yr)





A(10)*E






FISSION




effective,




A(6 yr.)




beta




E(beta)




Beta




gamma




E(gamma)




gamma






PROD.




yr.




Curries




Becquerels




Mev




W




Becquerels




Mev




W






















Sr 90




28.1




5.940 × 10


4






1.991 × 10


15






0.546




1.742 × 10


2







0




0.000






Y 90




28.1




5.940 × 10


4






1.991 × 10


15






2.27




7.242 × 10


2







0




0.000






Ru 106




1




6.120 × 10


3






1.416 × 10


13






0.0394









8.938 × 10


−2







0




0.000






Rh 106




1




6.120 × 10


3






1.416 × 10


13






1.43




3.244




1.416 × 10


13






0.34









7.713 × 10


−1








Cs 134




2.05




2.450 × 10


4






2.345 × 10


14






0.502




1.886 × 10


1






2.345 × 10


14






1.56




5.860 × 10


1








Cs 137




30.23




8.470 × 10


4






2.859 × 10


15






1.176




5.387 × 10


2







0




0.000






Ba 137m




30.23




7.920 × 10


4






2.674 × 10


15






0




0.000




2.674 × 10


15






0.662




2.835 × 10


2








Ce 144




0.78




3.320 × 10


3






3.515 × 10


12






0.138









7.771 × 10


−2







0




0.000






Pr 144




0.78




3.320 × 10


3






3.515 × 10


12






1.276









7.185 × 10


−1






3.515 × 10


12






0.031









1.746 × 10


−2








Pm 147




2.5




1.900 × 10


4






2.320 × 10


14






0.225




8.361




2.320 × 10


14






0.622




2.311 × 10


1








Sm 151




93




1.120 × 10


3






4.022 × 10


13






0.03









1.933 × 10


−1







0




0.000






Eu 154




16




4.710 × 10


3






1.465 × 10


14






0.142




3.334





0




0.000






SUMS:





3.509 × 10


5






1.020 × 10


16







1.472 × 10


3






3.158 × 10


15







3.660 × 10


2



















E(beta) av.: = 0.9004001 Mev;




E(gamma) av.: = 0.7235982 Mev







A(10,beta): = 1.02 × 10


16


particles/s;




A(10,gamma): = 3.158 × 10


15


photons/s






Watts:




betawatts: = 1470.0592




gammawatts: = 365.59223








Tot. watts: = 1836 W/Mg of fuel






Conv. fact.:




Bq/Ci = 3.7 × 10


10






J/Mev = 1.602 × 10


−13








Total activity for 33 tons of fuel:




beta dis/s: = 3.367 × 10


17






gamma phot./s: = 1.042 × 10


17













Total heat generated for 33 tons of fuel: = 60576 W






BASIS IS PER TONNE OF HEAVY METAL (FUEL) TEN YEARS AFTER DISCHARGE











If the criterion is set that the gamma energy flux outside the shield should not exceed five nanowatts/m


2


, this would correspond to a flux of about 50,000 photons/s m


2


as the average gamma photon energy is 0.7 Mev. For a reasonable approximation for the necessary shield thickness for a spherical surface source one can use the expression (See Glasstone, S. and Sesonsky, A.,


Nuclear Reactor Engineering


, D. Van Nostrand and Co., New York, 1963, Chapter 10).






φ(z)=B(z)(S(a,γ)(r/r(i))E


1


(z/λ)/2  (3)






where:




φ(z)=gamma flux outside the shield=50,000 photons/s m


2


.




B(z)=Buildup factor here taken as=1.




r=distance from center of the sphere to the detector, m.




r(i)=radius of spherical source=0.2 m.




z=distance from surface of the source to the detector, m.




λ=relaxation length of gamma photons in shield=0.0177 m.




E


1


(z/λ)=the exponential integral of the first order of z/λ.




For large values, such as here, the approximation E


1


(x)=exp(−x)/x may be used. If the detector is at the outer surface of the shield 16, z=r-r(i). With the above established numbers the solution to eq'n (3) then gives a value of r=0.6 m., i.e. the shield thickness will be 0.4 m.




Whereas the beta activity could be ignored for the purposes of shielding calculations, it is a major contributor to the generation of thermal power in the core


11


. From Table 2 it is seen that the beta activity of the major fission products after ten years of storage contributes 1470 W. per tonne of spent fuel, or 3.3×1470=4851 W. for the 3.3 tonnes that correspond to the 100 kg of fission product oxides in the core volume. Corresponding gamma energy is 365×3.3=1205 W. This gives a total heat rate of 4851+1205=6056 W. for the core volume.




As essentially all the beta radiation is absorbed within the core volume because of its low penetrating power, all the associated heating may be considered arising there. The gamma radiation penetrates into the shield, as was borne out by the shielding calculations. However, the bulk (i.e. 95%) of the gamma heat energy is deposited in the first three relaxation lengths of shield enclosing the core (and much of that in the first cm or so). For the present case the gamma heating in the shield may be ignored for heat transmission purposes and all the gamma heat also considered to stem from the core volume. (The incurred error should not exceed 3%). Using the previously calculated figures for heat generation rate and core volume, the specific rate of heat generation in the core, S(v,q), is found to be 6056/0.036=168,222 W/m


3


.




The Poisson equation describes the relationship between heat generation, thermal conductivity, k, and the temperature profile for the steady state case:









2


T+S(v, q)/k=0  (4)






In spherical coordinates, with the boundary conditions that T(c) is the temperature at the center and T(i) its value at the surface of the fission product sphere of radius r(i), the solution is:




 T(c)−T(i)=S(v,q)r(i)


2


/(6k)  (5)




The value of k for the core is taken as 10 W/m deg. C (Benedict, M. and Pigford, T., et al.,


Nuclear Chemical Engineering


, 2nd ed., McGraw Hill, New York, 1981 p. 584). Then using the values calculated above, i.e. S(v,q)=168,222 W/m


3


and r(i)=0.2 m:






T(c)−T(i)=168,222×0.2


2


/(6×10)=112 deg. C  (6)






For the shield, when S(v,q) becomes zero, the Poisson equation simplifies to the Laplace equation:









2


T=0  (7)






the solution of which is:






T(i)−T(o)=(q/4πk)(1/r(i)−1/r(o))  (8)






where r(o) signifies the outer radius of the shield and T(o) the corresponding temperature and q the rate of heat transfer through the shield. The value of k, the heat transfer coefficient, for the stainless steel is taken as 18 W/m deg C. With the appropriate numbers introduced into the equation, the temperature drop across the shield is found to be:






T(i)−T(o)=(6056/4π×18)(1/0.2−1/0.6)=89 deg C  (9)






The temperature profile for both core and shield is shown in FIG.


2


. The temperature drop from the center of the core to the outer surface of the shield is 89+112=201 deg C.




The ratio of the thermal conductivities of ice (2.24 W/m deg C) and stainless steel are such that even if the surface ice is at −35° C., it cannot conduct the heat away fast enough to prevent melting at the rate of heat generation under consideration. The temperature gradient in the water boundary layer adjacent to the surface of the sphere will be steeper than in the shield and raise the sphere surface temperature somewhat above the freezing point. Once an icemelt is formed, convection will also play a part in cooling the sphere but the exact calculation is quite complicated and will not be undertaken here.




In the central region of the Greenland Icecap (or Antarctica) the sphere will have to melt a volume of ice that equals its own diameter and is 3000 m in height. Given the density of ice at 900 kg/m


3


and the radius of the sphere of 0.6 m, the mass of ice, m, that the sphere will have to melt will be:






m=900×π×0.6


2


×3000=3.053×10


6


kg  (10)






Besides melting the ice the sphere has to heat the ice from the ambient temperature to the melting point. The former varies from −35° C. at the surface to −10° C. or so at the bottom, as mentioned earlier, and the melting point somewhat because of pressure increase with depth. Nonetheless, for a conservative estimate the temperature will be considered constant at −35° C. and the melting point also constant. The heat of fusion of water is 334 kJ/kg and the specific heat of ice just about 2 kJ/kg deg C. The total heat required to heat the ice from −35° C. and melt the sphere to the bottom, Q, will thus be:






Q=3.053×10


6


×(2×35+334)=1.233×10


9


kJ  (11)






or 1.233×10


12


J.




After ten years of storage the dominant fission products are Sr 90 and Cs 137 in secular equilibrium with their daughter nuclides, Y 90 and Ba 137m. Sr 90 and Cs 137 decay with very similar half lifes, namely nearly 29 years for both. For these reasons the ten year old mixture of fission products under consideration here may be considered to have a half life of 29 years for heat generation purposes. (This can change with time as the strontium and cesium isotopes decay further over a period of centuries, which leaves some longer lived nuclides dominant). Hence the effective decay constant for the fission product mixture, λ


d


, will have the value:






λ


d


=1n(2)/t


1/2


=0.693/30=0.0231 per year  (12)






To be commensurate with watts λ


d


should be expressed in reciprocal seconds, that is λ


d


=0.0231/3.156×10


7


=7.320×10


10


per second where the denominator is the number of seconds in a year. The rate of heat generation, q, as a function of time will then be given by q(t)=q


10


exp(−λ


d


t). The heat output must be integrated over the time that it takes the radwaste sphere to reach the bottom of the glacier, t(b). This has to equal the total heat requirements, Q, calculated above. Hence:









Q
=



0

t


(
b
)






q
10



exp


(


-

λ
d



t

)








(
13
)













where, as before:




λ


d


=effective decay constant at ten years=7.320×10


10


s


−1






q


10


=decay heat rate of ten year old fission products=6056 w.




Q=total heat requirements for reaching bottom=1.233×10


12


J.




Solving for t(b) yields the expression:






t (b)=(1/λ


d


)ln(l−λ


d


Q/q


10


)  (14)






or, when the numbers are substituted:






t(b)=(1/7.32×10


10


)ln(1−7.32×10


−10


×1.233×10


12


/6056)=2.205×10


8


s  (15)






which is equivalent to 2.205×10


8


/3.156×10


7


=7.0 years.




This example and its calculations demonstrate the feasibility of storing nuclear wastes in a safe manner in deep permanent icefields. It should be recalled that the assumption was made that spent fuel reprocessing would be undertaken and the long lived actinides recycled, or disposed of by other means. That is not to say that ice burial might not be considered for them as well, whether separately or unseparated from the fission products. Although separation and recycling of the actinides is preferable, an assured storage of the actinides for 100,000 years would diminish the activity of the plutonium by a factor of 16.




Although the Greenland glacier was taken as an example in this study, it should be borne in mind that from a disposal point of view Antarctica would be even better because of its remoteness and greater depth of the ice.




The disposal of fission products in deep permanent icefields as is described here is a technically feasible solution to the worrisome problem of accumulating nuclear waste in many countries. Apart from providing permanent storage (in any case long enough for the fission product activity to cease being a hazard and a time period of the order of 100,000 years), the fission products are adequately shielded in remote unpopulated areas. Furthermore, they are easily placed in storage but become inaccessible a few years if not months after they are placed on the ice. This holds the promise of making it a much more cost effective solution than deep geological burial, or shooting the nuclear wastes into space, as has been proposed. It therefore can be seen that the invention accomplishes all of its stated objectives.



Claims
  • 1. A method of fission product disposal in permanent icefields, comprising:storing nuclear reactor waste for a period of time sufficient to let short life materials decay leaving other fission products and actinides; separating the other fission products from the actinides; embedding the separated other fission products in a metal matrix having a sufficient thermal conductivity and a sufficiently high melting point to successfully store the other fission products, and thereafter placing the other fission products in a capsule container having a container core to hold the other fission products and an outer cover to encase the other fission products, said outer cover being a corrosion resistant material with sufficient strength, density, and thermal conductivity to avoid environmental corrosion over time, and being of a dimensional configuration such that radiation outside the container does not exceed safety limits, and such that the outside surface of the container is of a sufficiently high temperature to melt ice found in permanent icefields, yet is not sufficiently high to seriously enhance corrosion of the container.
  • 2. The method of claim 1 wherein said metal matrix is selected from the group consisting of lead, copper and tin alloys.
  • 3. The method of claim 1 wherein the other fission products are oxides in a lead matrix.
  • 4. The method of claim 1 wherein the storing for a time sufficient to let short life materials decay is at least ten years.
  • 5. The method of claim 1 wherein the actinides are recycled for fuel use.
  • 6. The method of claim 1 wherein the capsule container is solid stainless steel, surrounding a core of fission products embedded in a metal matrix.
  • 7. The method of claim 1 wherein the outer cover is stainless steel.
US Referenced Citations (2)
Number Name Date Kind
4115311 Sump Sep 1978 A
4320028 Leuchtag Mar 1982 A
Non-Patent Literature Citations (1)
Entry
Valfells, Agust, et al., Certain Aspects of Utilizing Some of the World's Energy Resources for Sustainable Development, pp. 1-22, presented at 16th Congress of the World Energy Council (WEC) in Tokyo Oct. 8-13, 1995.