Patent Grant
9486752
The present invention relates to the field of gas and liquid distribution in fixed bed type catalytic reactors operating in co-current gas/liquid downflow mode. The principal envisaged application is the hydrotreatment of gas oil or other oil cuts, and more generally any processes using one or more reactors operating in gas/liquid downflow mode.
The vast majority of existing distributors are composed of a plate provided with distribution elements such as those described, for example, in the article “Gas-liquid distributors for trickle bed reactors: A Review”, by R N Maiti and K D P Nigam, Ind Eng Chem Res 2007, 46, 6464-6182.
Such chimneys may be of various types and positioned in various configurations on the plate, as described in patents US2002/0127160A1, U.S. Pat. No. 6,093,373, US2004/0197245A1, US2007/0241467A1, GB721247, U.S. Pat. No. 658,738, US2007/145610 and U.S. Pat. No. 5,942,162.
The aim of a distributor plate placed upstream of a catalytic bed in a reactor operating in co-current gas and liquid downflow mode is to distribute the two-phase mixture of gas and liquid as homogeneously as possible over the catalytic bed located downstream thereof. At the outlet from the chimneys of the plate, the flow of two-phase mixture generally forms a concentrated jet.
Prior art distributor plates equipped with perforated chimneys operate on the basis of gravitational flow. The liquid is distributed by passing liquid into orifices generally distributed along the lateral walls of the chimneys and gas is distributed via the opening at the top of the chimney. However, a lack of horizontality may occur in such a plate due to flexing of the plate under its own weight or a shift of said plate with respect to the horizontal plane when it is being installed.
In the presence of a lack of horizontality of the plate, the height of the liquid trap is no longer uniform over the distributor plate, which results in imbalances in the distribution of liquid over the downstream catalytic bed, in particular when the level of the liquid is close to a row of orifices.
Prior art distributor plates provided with “bell-cap” chimneys are also sensitive to a lack of horizontality of the plate. A bell-cap chimney is constituted by a central cylinder surmounted by a bell-cap provided with a plurality of slots. The gas and liquid pass through via the slots and via the bottom of the bell-cap, and also in the space between the bell-cap and the principal cylinder. Other variations on the bell-cap chimney exist, such as “vapour-lift” chimneys (patents US2007/145610, U.S. Pat. No. 5,942,162), but the operating principle remains the same.
The operation of “bell-cap” chimneys is based on entraining liquid by gas across the space between the bell-cap and the cylinder. However, in the presence of a lack of horizontality of the plate, the height of the liquid trap is no longer uniform over the distributor plate. The distance between the surfaces open to gas between two offset chimneys thus becomes relatively large and liquid entrainment is no longer homogeneous between the chimneys, which causes substantial mal-distribution of liquid. The principal aggravating factors of this phenomenon are the opening at the bottom of the bell-cap and the large number of slots.
If it is not controlled, this mal-distribution may substantially degrade the performance of the reactor.
The aim of the present invention is to improve the quality of distribution of prior art distributor plates by providing them with distribution elements with a lower sensitivity to a lack of horizontality than that of perforated chimneys and bell-cap chimneys of the prior art, as well as better flexibility in operation.
The distributor plate of the present invention is composed of a multiplicity of distribution elements distributed regularly over said plate in a rectangular, square or triangular pattern.
The distribution element of the distributor plate of the present invention is composed of two cylindrical tubes which are approximately concentric and vertical, the outer cylindrical tube being provided with one or more slots for the passage of gas and liquid.
The two concentric tubes are intended to determine an annular mixing zone for the gas and liquid and allow the resulting gas/liquid mixture to be reintroduced at different points of the section of the reactor in as homogeneous a manner as possible.
The outer cylindrical tube is raised with respect to the plane of the plate, which means that a height h3 can be defined, forming a protection for the liquid admission slot or slots against possible fouling due to impurities which may be contained in the liquid feed, particularly when it is a heavy hydrocarbon feed. Raising the outer cylinder also means that the bulk in the plane of the plate can be reduced, with the advantage that liquid is distributed better over the distributor plate.
Unlike the operation of prior art plates, the operation of the distribution elements of the invention is principally based on entraining liquid in the rising part of the annular space separating the two coaxial cylinders under the effect of the flow of the gas phase. The flow in the annular space passes exclusively via the surface located on the lateral wall, which ensures better control of the dry slot (section open to the flow of gas) and thus renders the plate of the invention less sensitive to a lack of horizontality.
One of the advantages of the present invention is that the height of the dry slot is always sufficient to allow homogeneous admission of gas into the annular zone and eventually to allow balanced entrainment of liquid between the chimneys.
In practice, the use of this novel distribution element means that on average, over a large liquid range, the sensitivity to a lack of horizontality of the plate can be reduced.
More precisely, the present invention may be defined as a distributor plate for a gas-liquid flow in downflow co-current mode positioned at various levels of a reactor which may comprise a plurality of catalytic beds, in order to ensure homogeneous distribution of the resulting gas-liquid mixture over a catalytic bed located downstream of said plate, said plate being provided with distribution elements distributed regularly over the surface of the plate in a square or triangular pattern.
A distribution element is constituted by two substantially coaxial cylinders termed the inner cylinder 1 with a diameter d1 and height h1, and the outer cylinder 2 with a diameter d2 and height h2, the lower horizontal surface 5 separating the two cylinders being closed.
The lateral wall of the outer cylinder 2 is provided with at least one substantially vertical slot 4 for admitting gas and liquid into the annular zone 3. The gas-liquid mixture is entrained in the annular zone 3 as an upflowing stream, then passes into the inner cylinder 1 via the upper opening 6 thereof and drops inside the inner cylinder 1, then is evacuated via the opening 7 located at the lower end of the inner cylinder 1.
In accordance with the invention, the closed horizontal surface 5 of the distribution element is located above the base of the distributor plate at a height h3 in the range 10 to 100 mm, preferably in the range 20 mm to 60 mm.
The number of vertical slots 4 with height h4 is preferably in the range 1 to 3, and more preferably in the range 1 to 2.
The pitch between the distribution elements is preferably in accordance with a square or triangular pattern in the range 100 to 300 mm, more preferably in the range 100 to 200 mm.
The total height of the distribution elements, counted from the base of the distributor plate, is in the range 100 to 500 mm, preferably in the range 200 to 400 mm.
The principal dimensions of the distribution elements are denoted as follows:
height of outer cylinder, h2:
diameter of outer cylinder, d2:
height of inner cylinder, h1:
diameter of inner cylinder, d1:
height of the admission slot for the gas-liquid mixture, h4:
width of the admission slot for the gas-liquid mixture, ef:
height of the outer cylinder with respect to the base plane of the plate, h3:
The values for these principal dimensions are in the following ranges:
h2 is in the range 100 to 500 mm, preferably in the range 200 to 400 mm;
d2 is in the range 15 to 300 mm, preferably in the range 50 to 200 mm;
h1 is in the range 100 to 500 mm, preferably in the range 200 to 400 mm;
d1 is in the range 10 to 100 mm, preferably in the range 25 to 75 mm;
h4 is in the range 10 to 500 mm, preferably in the range 100 to 300 mm;
ef is in the range 1 to 5 mm, preferably in the range 1 to 3 mm;
h3 is in the range 10 to 100 mm, preferably in the range 20 to 60 mm.
The slots for admitting gas and liquid may have a fairly wide variety of shapes, the simplest and preferred shape being rectangular (h4, ef), or a triangular shape, still characterized by the dimensions h4 and ef, the point of the triangle being directed upwards or downwards.
The distributor plate of the present invention may in some cases have a certain offset between the axes of the two cylinders, inner and outer, which make it up. The expression “substantially” or “approximately” coaxial must be construed in its broadest sense, as the distance between their two axes may be in the range 0 to (d2−d1)/4.
The distributor plate of the present invention may be completed by a set of conical deflectors, each deflector being placed below a distribution element, the wide portion of the cone being directed downwardly.
In general, any type of deflector which is known to the skilled person may be used in the context of the present invention.
The distributor plate of the present invention may also be completed by a set of screen elements placed downstream of the plate at a distance in the range 20 mm to 300 mm, preferably in the range 50 mm to 150 mm from said plate, the various screen elements also being disposed on different planes. When they are present, these deflectors or screen elements form an integral part of the plate of the invention.
The distributor plate of the present invention is of principal application in reactors carrying out hydrotreatment, hydrogenation or oxidation reactions of oil cuts with a number of carbon atoms of 4 to 30, preferably 8 to 20.
More generally, the distributor plate of the present invention is of application in reactors employing a downflowing co-current of gas and liquid in “trickle bed” mode, i.e. with a surface velocity of the liquid in the range 0.1 to 1.5 cm/s.
The invention may be defined as a distributor plate adapted for two-phase gas liquid flows in downflow co-current mode. Such a plate is intended for installation in reactors using this type of two-phase flow, more particularly in “trickle bed” mode, which is defined as a flow in which the continuous phase is the gas phase and the discontinuous phase is the liquid phase, the liquid being present in the form of trickles which are approximately regular, with a surface velocity of the liquid in the range 0.1 to 1.5 cm/s.
The distribution elements are distributed regularly over the distributor plate in a pattern which may be rectangular, square or triangular.
A distribution element is constituted by two approximately coaxial cylinders, the inner cylinder with diameter d1 and the outer cylinder with diameter d2.
These two substantially coaxial cylinders define an annular zone 3 through which the gas and liquid move in upflow mode. The gas and the liquid are in fact admitted into the annular zone 3 via one or more longitudinal slots 4 pierced along the wall of the outer cylinder 2.
The lower portion of the slot in general admits liquid, and the upper portion of the slot in general admits gas. Thus, it is essential that this upper portion of the slot, termed the “dry” slot, is sufficient to admit the gas at the desired flow rate. One of the advantages of the distribution elements of the present invention is that they have low sensitivity to any lack of horizontality due to the height of the dry slot which is always sufficient to allow gas to be admitted into the annular zone 3.
The outer cylinder 2 does not descend to the base of the plate and stops at a height h3 therefrom. The longitudinal slot 4 starts from said height h3 above the plate and extends to a height h3+h4.
The horizontal surface 5 separating the outer cylinder 2 and the inner cylinder 1 is closed.
The number of longitudinal slots 4 is limited to 2 or 3 per distribution element. These various characteristics mean that the function of the distribution elements is substantially improved, in particular in the presence of a lack of horizontality. The fact that the number of slots is reduced and the bottom of the distribution element is closed means that the height of the liquid trap is better controlled, so as to ensure a sufficient dry slot height so that in the event of a lack of horizontality, the distance between the surfaces open to gas between two distribution elements having a certain variation is small.
In contrast to patents US2007/145610 and U.S. Pat. No. 5,942,162, the system does not necessitate confining the two-phase flow in the portion located between the two concentric tubes where the flow is of the gas lift type, as in contact with gas and liquid at the slot, a two-phase emulsion is formed which occupies all of the annular space defined by the substantially coaxial cylinders.
The two comparative examples below illustrate the advantages of the distribution system of the present invention compared with two prior art devices.
Compares the distribution efficiency of the distribution device of the invention with a standard distributor plate provided with chimneys.
When the plate (of the prior art or of the invention) is subjected to a lack of horizontality of ΔH=1 cm, the sensitivity to the lack of horizontality of the plate is quantified by defining the liquid imbalance index as follows:
where:
QL.chimney1,2 is the volume flow rate of liquid leaving the two chimneys with index 1 and 2 of the plate located at a height difference corresponding to the lack of horizontality of ΔH=1 cm.
A low value for the liquid imbalance index indicates a low sensitivity to a lack of horizontality. In contrast, a high value for IqL indicates a large imbalance in the distribution.
The standard plate is provided with chimneys pierced with orifices for the passage of liquid distributed over several rows.
The principal characteristics of these standard chimneys were as follows:
The configuration of the holes of the chimneys was defined for a range of liquid velocities in the range 0.2 to 1.3 cm/s and for a gas velocity of 15 cm/s.
The distribution elements of the invention had the characteristics given in Table 1 below.
The index 1 refers to the inner cylinder and the index 2 to the outer cylinder.
For the prior art plate, the liquid imbalance index varied between 5% and 40% over the whole range of VSL under consideration (from 0.1 to 1.3 cm/s) with peaks corresponding to VSL which entrain opening up or obstruction of an orifice.
Thus, there is a highly disadvantageous effect of peaks linked to the discontinuities in the orifices for the passage of gas and liquid.
In contrast, the plate of the invention exhibited stable performance with a liquid imbalance index IqL≈13% over the whole functional range of VSL.
This example shows that the device of the invention can be used to obtain a significant gain in flexibility and efficiency of distribution in the presence of a lack of horizontality of the plate.
Compares the distribution efficiency of the plate of the invention with that of a plate provided with bell-cap chimneys in accordance with the prior art for a lack of horizontality of ΔH=1 cm.
The distribution efficiency was again quantified by the liquid imbalance index IqL; the surface velocity of the liquid varied from 0.1 to 1.3 cm/s.
The characteristics of the bell-cap chimney plate are given in Table 2 below.
The characteristics of the plate provided with distribution elements in accordance with the invention are given in Table 3 below.
The index 1 again refers to the inner cylinder; the index 2 refers to the outer cylinder.
The variation in the liquid imbalance index IqL as a function of the surface velocity of the liquid VSL for the two plates is shown in
The results show a large sensitivity to a lack of horizontality for the “bell-cap chimney” chimney plates (solid line curve).
In fact, the degree of mal-distribution was more than 100% over the whole functional range of VSL.
In contrast, the plate of the invention was less sensitive to an imposed lack of horizontality, the liquid imbalance index over the range of VSL being practically constant around a value of 13% (dotted line curve).
These two examples clearly show the advantage of the plate of the present invention, the latter allowing the effect of a lack of horizontality during installation of the distributor plate to be greatly attenuated, over a range of surface velocity of the liquid of 0.1 to 1.3 cm/s, i.e. corresponding to the “trickle bed” mode for which the plate of the invention is particularly well suited.
| Number | Date | Country | Kind |
|---|---|---|---|
| 11 03336 | Nov 2011 | FR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/FR2012/000407 | 10/9/2012 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2013/064756 | 5/10/2013 | WO | A |
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|---|---|---|---|
| 6769672 | Muller | Aug 2004 | B2 |
| 7600742 | Breivik | Oct 2009 | B2 |
| 8329974 | Koudil et al. | Dec 2012 | B2 |
| 20060163758 | Muller et al. | Jul 2006 | A1 |
| 20070145610 | Breivik | Jun 2007 | A1 |
| 20090177023 | Koudil et al. | Jul 2009 | A1 |
| 20130064727 | Koudil et al. | Mar 2013 | A1 |
| Number | Date | Country |
|---|---|---|
| 2005068039 | Jul 2005 | WO |
| 2007023225 | Mar 2007 | WO |
| Entry |
|---|
| International Search Report for PCT/FR2012/000407 dated Jan. 24, 2013. |
| Number | Date | Country | |
|---|---|---|---|
| 20140364650 A1 | Dec 2014 | US |
