The present invention relates to an at least two shaft reactor/mixer, in particular for process engineering treatment—e.g. for devolatilization (degassing)—of highly viscose and/or solid-containing reaction substance and mixture as well as to a system including an end cap for a reactor/mixer and a discharge screw connector block being connectable with an end cap. This kind or reactors/mixers are applied for example in the production and processing of polymers and/or plastic materials as well as rubber and/or elastomers, i.e. in cases in which a good mixing effect and, if applicable, also a quick regeneration of free surfaces for the purpose of evaporating, respectively, devolatilization (degassing) shall be ensured. Further, such reactors/mixers should comprise a self-cleaning potential as good as possible, in order that as little as possible encrustation occurs at the reactor walls, respectively at the mixing instruments. This may namely lead to disturbing side reactions in the reactor chamber and therefore to contamination and inhomogeneity of the respective product to be produced.
A self-cleaning reactor/mixer is known from EP 0 715 882 A2. This reactor/mixer consists of two or more parallel shafts, which rotate in the same direction on which axially offset discs are arranged which comprise a not necessarily circular circumference. The discs comprise scrapers being distributed on their circumference.
The reactor/mixer is enclosed by a housing. The reactor/mixer shall be constructed in such a way that all surfaces of the scrapers may be cleaned kinematically and that all surfaces of the scrapers of a shaft being directed outwardly are convex in an arbitrary radial section through the mixer and are cleaned by an adjacent shaft or its scrapers or by the housing. Further, all inwardly directed surfaces of the scrapers of a shaft are concave in an arbitrary radial section through the mixer and are cleaned by the scrapers of an adjacent shaft. During the cleaning of the housing through the scrapers between the housing wall and the cleaning surface of the scraper, only angles greater than 90° occur at the product side. Further, during the mutual cleaning of the scrapers, only angles greater than 60°, preferably greater than 90°, occur among one another between the cleaned and the cleaning surface of the scrapers which contact one another.
However, it has been found in practice that in this two shaft reactor/mixer, in particular the cleaning of the housing inner wall, may still be improved and that also areas exist with a relatively small product mixing. In particular, the inner wall of the housing is not fully cleaned kinematicallly through the gap, which is formed by the scrapers being mounted on the discs in axial direction. This was found surprising insofar as in this reactor/mixer relatively great forces are generated due to the two shaft mixing and in particular in such areas in which the mixing elements, respectively kneading bars, meet each other.
The discharge of the respectively mixed products from conventional reactors/mixers usually occurs via a screw apparatus, which is fixedly integrated in the end cap of the housing, i.e. at the non-driven end of the reactor/mixer. The integration of the discharge screw apparatus into the end cap does however lead to expensive forgings, respectively to weldments which are expensive in production.
It is therefore the object of the present invention to provide a two shaft reactor/mixer, by means of which a better mixing through a respective distribution of the flow disturbances across the reaction chamber may occur, without that thereby the fatigue strength of the reactor/mixer is exceeded. In this context, an intensified process shall be achieved and, in particular, also an enhanced cleaning effect for the housing inner wall. Moreover, a system shall be provided, which effects in a simple and inexpensive manner a modular connection of an end cap of a reactor/mixer with a (separate) discharge screw connector block. This object is solved according to the present invention by a rector/mixer, in particular for process engineering treatment of highly viscose and/or solid containing reaction substance and mixture, comprising: a housing with an inner—as well as an outer wall, which defines a reaction chamber and which fully or partially encloses at least two shafts, wherein the shafts are rotatably supported in the housing and/or in lateral attachment parts of the housing, and are driven a motor, wherein on the shafts disc-shaped elements are arranged which are actually offset to one another, wherein the disc-shaped elements respectively comprise at their circumference outwardly directed scrapers, wherein the disc-shaped elements and/or the scrapers of a shaft respectively carry out with the disc-shaped elements and/or the scrapers of an adjacent shaft as well as with the housing a mutual, kinematic cleaning of the disc-shaped elements and/or scrapers, and wherein at the housing inner wall inwardly directed, static mixing elements are arranged, which interact with the scrapers of the at least two shafts in such a way, that in the area of the spaces between the scrapers, the static mixing elements and the housing inner wall, sheer forces, in particular a flow disturbance, are created in an enhanced manner. This object is further solved in accordance with the present invention by a system including an end cap for a one- or multiple shaft reactor/mixer and a discharge screw connector block being connectable with the end cap in a detachable manner, wherein the end cap comprises at least a bearing for receiving at least one shaft end, as well as multiple bores for receiving fastening means, and a mixture outlet opening; and wherein the discharge screw connector block comprises at least one channel for receiving at least one discharge screw, as well as a mixture inlet opening corresponding with the mixture outlet opening of the end cap, and which leads into the at least one channel, and multiple bores, which at least partially correspond with the bores in the end cap.
With the aid of the inventive reactor/mixer, in particular an intensified mixing effect may be achieved, which in particular with regard to devolatilization (degassing) and compounding tasks leads to a reduction of the duration of proceedings, and therefore, to smaller machines. Due to the fact that the plug flow is stronger with two shaft reactors (respectively transport movement of the reaction substance) stronger flow disturbances may be achieved by the static mixing elements and thus, a particularly advantageous surface distribution of the reaction substance, as compared for example with one shaft reactors with static mixing elements, where the latter may be provided for cleaning purposes, if applicable. Further, an enhanced decoupling of rotor rotational speed, axial transport and degree of filling is achieved, which enables a better operational control and more adaptability. In addition, an increase and an adaption of dissipation is achieved in certain regions of the reactor/mixer, which is in particular advantageous during melting, since a better heat input is ensured and thus, the efficiency during devolatilization (degassing) and during reaction of highly viscose products is increased.
By means of the inventive system it is enabled, to screw the discharge screw(s) onto the housing of a reactor/mixer. This results in a significantly facilitated mounting and de-mounting with respective cost advantages. The system may be used with all known large volume, one- or multiple shaft reactors/mixers and enables therefore a great flexibility in use.
It is noted, that the disc-shaped elements are usually formed in the cross-section as approximately ring-shaped disc-elements. The disc-shaped elements may however also comprise gap-like interruptions between the individual scrapers, such that in cross-section an approximately star-shaped configuration results. It is further also conceivable, that the scrapers are arranged directly on the shaft, wherein also in such a configuration the lower connection areas of the scrapers represent disc-shaped elements in the sense of the present invention.
In a preferred embodiment of the inventive reactor/mixer, the at least two shafts are respectively driven with the same rotational speed by the motor. In this manner, a particularly even mixture may be achieved, and simultaneously an even load distribution across the housing wall. This is in particular important with regard to the static mixing elements, which create additional (in addition to the two overlapping shafts) sheer forces and contribute in this manner generally to a higher stress of the housing wall. It seemed inexpedient to apply static mixing elements in two shaft reactors/mixers at all.
Further preferred, the shafts are driven in the same rotational direction. Shafts which rotate in the same rotational direction usually comprise better devolatilization (degassing) characteristics as shafts which rotate in opposite directions, since here a film is created, when the reaction substance is shoveled from one shaft to the other. In addition the shafts are preferably supported horizontally within the reactor housing.
In a further preferred embodiment of the inventive reactor/mixer the reaction chamber comprises in the cross-section approximately the shape of a horizontal eight with a center point P through which a horizontal axis E and a vertical axis F pass. This geometry has proven to be particulary efficient and stable during the process engineering treatment of elastic, highly viscose and solid containing reaction substance and mixture. Through the center point P, respectively also passes the longitudinal axis of the reaction chamber. It was found that with a purely oval shape of the reaction chamber an insufficient mixing above and below the area of overlap of the shafts may occur.
According to a still further preferred embodiment of the inventive reactor/mixer the static mixing elements are arranged, departing from the center point P, in an angular area a of approximately 180°, preferably approximately 150° and particularly preferred approximately 120° in the lower area of the housing inner wall. In this manner, a particularly effective process engineering intensification of the mixture, respectively exchange ratio may be achieved in the lower area of the reactor/mixer, i.e. in the filled portion of the reaction chamber. Generally, it is however also possible to distribute the mixing elements across the entire circumference of the reactor/mixer. Since highly viscose media do not remain lying (bath tub effect) in contrast to low viscose media, but are distributed by the rotors across the entire circumference of the reactor/mixer, a corresponding arrangement is meaningful for many applications. The above mentioned angular areas are in particular suited for two shaft reactors/mixers with the above described cross sectional shape, since here the greatest potential exists for a process intensification.
According to another preferred embodiment of the inventive reactor/mixer, the static mixing elements are arranged in even circumferential distances at the housing inner wall. Particularly preferred are hereby distances of 45° and still further preferred of 30°. If the static mixing elements are for example arranged in an angular area a of 180°, respectively three or four static mixing elements are arranged in the left as well as in the right part of the horizontal eight, wherein the lower most static mixing elements are aligned respectively parallel to the vertical axis F. The respectively laterally outermost static mixing elements are preferably aligned along the horizontal axis F.
In a still other preferred embodiment of the inventive reactor/mixer the static mixing elements are aligned in the longitudinal direction, respectively in a row. In this manner, a particularly advantageous operational control may be ensured. However, the static mixing elements may only be arranged in the area of particularly critical zones, as may be the case for example with very high viscosities, shortly before a phase change or after the addition of additional components as for example reactants, additives etc. Regularly, the static mixing elements are however arranged across the entire length of the reactor/mixer. In this way, the overall efficiency of the mixing operation may be enhanced.
In a further preferred embodiment of the inventive reactor/mixer the static mixing elements are formed as rhombical rods. However, also round rods or T-shaped static mixing elements (with e.g. round or rhombical cross-section) are conceivable. In the case of rod-shaped static mixing elements, the latter protrude approximately as far into the inner of the reaction chamber, that they are flush with the underside of the regularly T-shaped mixing elements on the shafts, respectively discs. In the case of T-shaped, static mixing elements, the T-beams of the static mixing elements engage just behind the T-beams of the mixing elements on the shafts, respectively discs. In this way, as small as possible distances are achieved between the static mixing elements and the (dynamic) mixing elements among themselves as well as also with regard to the housing inner wall. The sheer forces created in this manner improve the cleaning effect with regard to the housing wall and in addition also the mutual cleaning effect. The exact geometric configuration of the static mixing elements depends however, respectively, on the goods respectively products to be mixed as well as on the respective pressures and temperatures. For each mixing row in the longitudinal direction or within a mixing row, the static mixing elements may be shaped in a different manner. The static mixing elements may however also be omitted in sections.
In a still other preferred embodiment of the inventive reactor/mixer, the static mixing elements comprise one or multiple bores. Through these bores, for example liquid additives, catalysts or other easy-flowing aggregates may be dosed directly into the mixture. Preferably, the one or multiples bores are provided with measuring devices. The measuring devices may include measuring elements for temperature, pressure, concentrations etc.
In a further preferred embodiment of the inventive reactor/mixer, the static mixing elements are respectively inserted through an opening in the housing wall into the reactor/mixer and are mounted by means of a pressure fitting—i.e. in particular a detachable screw connection—at the housing. In this manner, a particularly high stability of the entire reactor/mixer may be ensured.
In a still other preferred embodiment of the inventive reactor/mixer, the reactor/mixer comprises an at least partly open housing. This also depends regularly on the pressure and/or temperature conditions, which are present during the mixing of the respective reaction substances/mixtures.
In a further preferred embodiment of the inventive reactor/mixer, the reactor/mixer comprises a large volume vapor collection space above the at least partly open housing. Such a construction may in particular serve for providing a deep pressure or a high vacuum at the product surface. Further preferred, there is arranged a baffle in the large volume vapor collection space. The baffle shall direct the resulting vapor in the direction of the vapor outlet. Further, the baffle shall avoid the formation of depositions in the lower area of the vapor collection space, which adjoins the reactor wall. Preferably, the vapor collection space housing, inclusive connector flange and vapor outlet is heatable in order to avoid condensation.
In a preferred embodiment of the inventive system, a drive for the one or the multiple discharge screws may be arranged in a detachable manner at the discharge screw connector block. For this purpose, the discharge screw connector block regularly comprises a connector flange with multiple circumferential bores, at which the drive, respectively the motor for the at least one discharge screw may be screwed on. In this way, a particularly efficient modular assembly of these components is provided.
In an again different preferred embodiment of the inventive system, the discharge screw connector block comprises in the area of the mixture inlet opening a fitting-like fixing piece. This fitting-like fixing piece generally serves for the mounting of the discharge screw connector block at the end cap, which again is screwed onto the housing of the respective reactor/mixer.
In a still further preferred embodiment of the inventive system, the fitting-like fixing piece comprises an inner frame area, which encloses the mixture inlet opening of the discharge screw connector block and into which openings for receiving fastening means are introduced, by means of which the end cap is mountable at the discharge screw connector block. In this manner, a particularly good sealing in the area of the mixture inlet opening may be achieved. In a still further different preferred embodiment of the inventive system, the fitting-like fixing piece comprises an outer frame area, into which openings for receiving fastening means are introduced, by means of which the discharge screw connector block may be mounted at the end cap. In this way, an optimal mutual mounting of the discharge screw connector block at the end cap may be guaranteed.
In a further preferred embodiment of the inventive system, the outer frame area additionally comprises laterally open bores, which are aligned with respective blind hole bores in the end cap outer side which faces the discharge screw connector block. Further preferred sealing bolts may be introduced into the blind hole bores in the end cap outer side. This configuration provides the basis for a particularly well-sealed mounting.
In a still further preferred embodiment of the inventive system, there is provided in the inside of the end cap, which is directed away from the discharge screw connector block, a recess is introduced, which essentially corresponds with the inner frame area of the fitting-like fixing piece. In this recess, preferably a screen is inserted. The screen thereby covers the heads of the fastening means, which are introduced through respective openings in the recess through the end cap into the corresponding openings in the inner frame area of the fitting-like fixing piece.
In a still different preferred embodiment of the present invention, the screen is pulled into the recess in the end cap inner side by means of screw bolts, which are screwed into the blind hole bores in the end cap outer side with a respective screw nut, such that a particularly efficient sealing relative to the reactor inner space occurs.
In a still other preferred embodiment of the present invention, the screen comprises an opening, which is smaller than the mixture inlet opening of the discharge screw connector block. In this manner, an enlargement of the flow cross section in flow direction is created, which enables a better transportation of the mixture through the one or more discharge screws.
The inventive system may be used for all sorts of one or multiple shaft reactors/mixers. Preferably, it is used in connection with the inventive reactor/mixer.
An inventive reactor/mixer as well as an inventive system are illustrated by means of the attached drawings which show:
In
They may however also be arranged at the circumference offset relative to the shafts 4, 4′ wherein the tilting in the longitudinal direction of the shafts 4, 4′ may increase or decrease. In a similar manner, the scrapers 9, 9′ may, seen in the longitudinal direction, take an increasing slope relative to the shaft 4, 4′, such that the latter comprise an inclined, respectively distorted course. Regularly, the T-beams of the scrapers 9, 9′ are aligned with one another; they may however also be arranged offset to one another in the circumferential direction.
In
In
An exterior view of the inventive system including end cap 30 and discharge screw connector block 40 is illustrated in
In
The inventive system, respectively the discharge screw connector block is preferably used together with an inventive reactor/mixer.
Number | Date | Country | Kind |
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13 002 207.2 | Apr 2013 | EP | regional |