Driven starter pump and start sequence

Information

  • Patent Grant
  • 9410449
  • Patent Number
    9,410,449
  • Date Filed
    Wednesday, December 11, 2013
    10 years ago
  • Date Issued
    Tuesday, August 9, 2016
    7 years ago
Abstract
Aspects of the disclosure generally provide a heat engine system with a working fluid circuit and a method for starting a turbopump disposed in the working fluid circuit. The turbopump has a main pump and may be started and ramped-up using a starter pump arranged in parallel with the main pump of the turbopump. Once the turbopump reaches a self-sustaining speed of operation, a series of valves may be manipulated to deactivate the starter pump and direct additional working fluid to a power turbine for generating electrical power.
Description
BACKGROUND

Heat is often created as a byproduct of industrial processes where flowing streams of high-temperature liquids, solids, or gases must be exhausted into the environment or removed in some way in an effort to maintain the operating temperatures of the industrial process equipment. Sometimes the industrial process can use heat exchanger devices to capture the heat and recycle it back into the process via other process streams. Other times it is not feasible to capture and recycle this heat either because its temperature is too high or it may contain insufficient mass flow. This heat is referred to as “waste” heat and is typically discharged directly into the environment or indirectly through a cooling medium, such as water or air.


This waste heat can be converted into useful work by a variety of turbine generator systems that employ well-known thermodynamic methods, such as the Rankine cycle. These thermodynamic methods are typically steam-based processes where the waste heat is recovered and used to generate steam from water in a boiler in order to drive a corresponding turbine. Organic Rankine cycles replace the water with a lower boiling-point working fluid, such as a light hydrocarbon like propane or butane, or a HCFC (e.g., R245fa) fluid. More recently, and in view of issues such as thermal instability, toxicity, or flammability of the lower boiling-point working fluids, some thermodynamic cycles have been modified to circulate more greenhouse-friendly and/or neutral working fluids, such as carbon dioxide or ammonia.


A pump is required to pressurize and circulate the working fluid throughout the working fluid circuit. The pump is typically a motor-driven pump, however, these pumps require costly shaft seals to prevent working fluid leakage and often require the implementation of a gearbox and a variable frequency drive which add to the overall cost and complexity of the system. Replacing the motor-driven pump with a turbopump eliminates one or more of these issues, but at the same time introduces problems of starting and “bootstrapping” the turbopump, which relies heavily on the circulation of heated working fluid for proper operation. Unless the turbopump is provided with a successful start sequence, the turbopump will not be able to bootstrap itself and thereafter attain steady-state operation.


What is needed, therefore, is a system and method of operating a waste heat recovery thermodynamic cycle that provides a successful start sequence adapted to start a turbopump and bring it to steady-state operation.


SUMMARY

Embodiments of the disclosure may provide a heat engine system for converting thermal energy into mechanical energy. The heat engine system may include a turbopump comprising a main pump operatively coupled to a drive turbine and hermetically-sealed within a casing, the main pump being configured to circulate a working fluid throughout a working fluid circuit, wherein the working fluid is separated in the working fluid circuit into a first mass flow and a second mass flow. The heat engine system may also include a first heat exchanger in fluid communication with the main pump and in thermal communication with a heat source, the first heat exchanger being configured to receive the first mass flow and transfer thermal energy from the heat source to the first mass flow. The heat engine system may further include a power turbine fluidly coupled to the first heat exchanger and configured to expand the first mass flow, a first recuperator fluidly coupled to the power turbine and configured to receive the first mass flow discharged from the power turbine, and a second recuperator fluidly coupled to the drive turbine, the drive turbine being configured to receive and expand the second mass flow and discharge the second mass flow into the second recuperator. Moreover, the heat engine system may include a starter pump arranged in parallel with the main pump in the working fluid circuit, a first recirculation line fluidly coupling the main pump with a low pressure side of the working fluid circuit and a second recirculation line fluidly coupling the starter pump with the low pressure side of the working fluid circuit.


Embodiments of the disclosure may further provide a method for starting a turbopump in a thermodynamic working fluid circuit. The exemplary method may include circulating a working fluid in the working fluid circuit with a starter pump, the starter pump being in fluid communication with a first heat exchanger that is in thermal communication with a heat source, transferring thermal energy to the working fluid from the heat source in the first heat exchanger, and expanding the working fluid in a drive turbine fluidly coupled to the first heat exchanger, the drive turbine being operatively coupled to a main pump, where the drive turbine and the main pump comprise the turbopump. The method may further include driving the main pump with the drive turbine, diverting the working fluid discharged from the main pump into a first recirculation line fluidly communicating the main pump with a low pressure side of the working fluid circuit, the first recirculation line having a first bypass valve arranged therein, and closing the first bypass valve as the turbopump reaches a self-sustaining speed of operation. The method may also include circulating the working fluid discharged from the main pump through the working fluid circuit, deactivating the starter pump and opening a second bypass valve arranged in a second recirculation line fluidly communicating the starter pump with the low pressure side of the working fluid circuit, and diverting the working fluid discharged from the starter pump into the second recirculation line.


Embodiments of the disclosure may further provide another exemplary heat engine system for converting thermal energy into mechanical energy. The heat engine system may include a turbopump including a main pump operatively coupled to a drive turbine and hermetically-sealed within a casing, the main pump being configured to circulate a working fluid throughout a working fluid circuit, a starter pump arranged in parallel with the main pump in the working fluid circuit, and a first check valve arranged in the working fluid circuit downstream from the main pump. The heat engine system may also include a second check valve arranged in the working fluid circuit downstream from the starter pump and fluidly coupled to the first check valve, a power turbine fluidly coupled to both the main pump and the starter pump, and a shut-off valve arranged in the working fluid circuit to divert the working fluid around the power turbine. The heat engine system may further include a first recirculation line fluidly coupling the main pump with a low pressure side of the working fluid circuit, and a second recirculation line fluidly coupling the starter pump with the low pressure side of the working fluid circuit.





BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure is best understood from the following detailed description when read with the accompanying Figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.



FIG. 1 illustrates a schematic of a cascade thermodynamic waste heat recovery cycle, according to one or more embodiments disclosed.



FIG. 2 illustrates a schematic of a parallel heat engine cycle, according to one or more embodiments disclosed.



FIG. 3 illustrates a schematic of another parallel heat engine cycle, according to one or more embodiments disclosed.



FIG. 4 illustrates a schematic of another parallel heat engine cycle, according to one or more embodiments disclosed.



FIG. 5 is a flowchart of a method for starting a turbopump in a thermodynamic working fluid circuit, according to one or more embodiments disclosed.





DETAILED DESCRIPTION

It is to be understood that the following disclosure describes several exemplary embodiments for implementing different features, structures, or functions of the inventions. Exemplary embodiments of components, arrangements, and configurations are described below to simplify the present disclosure; however, these exemplary embodiments are provided merely as examples and are not intended to limit the scope of the inventions. Additionally, the present disclosure may repeat reference numerals and/or letters in the various exemplary embodiments and across the Figures provided herein. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various exemplary embodiments and/or configurations discussed in the various Figures. Moreover, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the first and second features, such that the first and second features may not be in direct contact. Finally, the exemplary embodiments presented below may be combined in any combination of ways, i.e., any element from one exemplary embodiment may be used in any other exemplary embodiment, without departing from the scope of the disclosure.


Additionally, certain terms are used throughout the following description and claims to refer to particular components. As one skilled in the art will appreciate, various entities may refer to the same component by different names, and as such, the naming convention for the elements described herein is not intended to limit the scope of the inventions, unless otherwise specifically defined herein. Further, the naming convention used herein is not intended to distinguish between components that differ in name but not function. Additionally, in the following discussion and in the claims, the terms “including” and “comprising” are used in an open-ended fashion, and thus should be interpreted to mean “including, but not limited to.” All numerical values in this disclosure may be exact or approximate values unless otherwise specifically stated. Accordingly, various embodiments of the disclosure may deviate from the numbers, values, and ranges disclosed herein without departing from the intended scope. Furthermore, as it is used in the claims or specification, the term “or” is intended to encompass both exclusive and inclusive cases, i.e., “A or B” is intended to be synonymous with “at least one of A and B,” unless otherwise expressly specified herein.



FIG. 1 illustrates an exemplary heat engine system 100, which may also be referred to as a thermal engine, a power generation device, a heat or waste heat recovery system, and/or a heat to electricity system. The heat engine system 100 may encompass one or more elements of a Rankine thermodynamic cycle configured to produce power from a wide range of thermal sources. The terms “thermal engine” or “heat engine” as used herein generally refer to the equipment set that executes the various thermodynamic cycle embodiments described herein. The term “heat recovery system” generally refers to the thermal engine in cooperation with other equipment to deliver/remove heat to and from the thermal engine.


The heat engine system 100 may operate as a closed-loop thermodynamic cycle that circulates a working fluid throughout a working fluid circuit 102. As illustrated, the heat engine system 100 may be characterized as a “cascade” thermodynamic cycle, where residual thermal energy from expanded working fluid is used to preheat additional working fluid before its respective expansion. Other exemplary cascade thermodynamic cycles that may also be implemented into the present disclosure may be found in PCT Pat. App. No. U.S.2011/29486, entitled “Heat Engines with Cascade Cycles,” filed on Mar. 22, 2011, and published as WO2011119650 (A2), the contents of which are hereby incorporated by reference. The working fluid circuit 102 is defined by a variety of conduits adapted to interconnect the various components of the heat engine system 100. Although the heat engine system 100 may be characterized as a closed-loop cycle, the heat engine system 100 as a whole may or may not be hermetically-sealed such that no amount of working fluid is leaked into the surrounding environment.


In one or more embodiments, the working fluid used in the heat engine system 100 may be carbon dioxide (CO2). It should be noted that use of the term CO2 is not intended to be limited to CO2 of any particular type, purity, or grade. For example, industrial grade CO2 may be used without departing from the scope of the disclosure. In other embodiments, the working fluid may a binary, ternary, or other working fluid blend. For example, a working fluid combination can be selected for the unique attributes possessed by the combination within a heat recovery system, as described herein. One such fluid combination includes a liquid absorbent and CO2 mixture enabling the combination to be pumped in a liquid state to high pressure with less energy input than required to compress CO2. In other embodiments, the working fluid may be a combination of CO2 and one or more other miscible fluids. In yet other embodiments, the working fluid may be a combination of CO2 and propane, or CO2 and ammonia, without departing from the scope of the disclosure.


Use of the term “working fluid” is not intended to limit the state or phase of matter that the working fluid is in. For instance, the working fluid may be in a fluid phase, a gas phase, a supercritical phase, a subcritical state or any other phase or state at any one or more points within the heat engine system 100 or thermodynamic cycle. In one or more embodiments, the working fluid is in a supercritical state over certain portions of the heat engine system 100 (i.e., a high pressure side), and in a subcritical state at other portions of the heat engine system 100 (i.e., a low pressure side). In other embodiments, the entire thermodynamic cycle may be operated such that the working fluid is maintained in either a supercritical or subcritical state throughout the entire working fluid circuit 102.


The heat engine system 100 may include a main pump 104 for pressurizing and circulating the working fluid throughout the working fluid circuit 102. In its combined state, and as used herein, the working fluid may be characterized as m1+m2, where m1 is a first mass flow and m2 is a second mass flow, but where each mass flow m1, m2 is part of the same working fluid mass coursing throughout the working fluid circuit 102.


After being discharged from the main pump 104, the combined working fluid m1+m2 is split into the first and second mass flows m1 and m2, respectively, at point 106 in the working fluid circuit 102. The first mass flow m1 is directed to a heat exchanger 108 in thermal communication with a heat source Qin. The heat exchanger 108 may be configured to increase the temperature of the first mass flow m1. The respective mass flows m1, m2 may be controlled by the user, control system, or by the configuration of the system, as desired.


The heat source Qin may derive thermal energy from a variety of high temperature sources. For example, the heat source Qin may be a waste heat stream such as, but not limited to, gas turbine exhaust, process stream exhaust, or other combustion product exhaust streams, such as furnace or boiler exhaust streams. Accordingly, the thermodynamic cycle 100 may be configured to transform waste heat into electricity for applications ranging from bottom cycling in gas turbines, stationary diesel engine gensets, industrial waste heat recovery (e.g., in refineries and compression stations), and hybrid alternatives to the internal combustion engine. In other embodiments, the heat source Qin may derive thermal energy from renewable sources of thermal energy such as, but not limited to, solar thermal and geothermal sources.


While the heat source Qin may be a fluid stream of the high temperature source itself, in other embodiments the heat source Qin may be a thermal fluid in contact with the high temperature source. The thermal fluid may deliver the thermal energy to the waste heat exchanger 108 to transfer the energy to the working fluid in the circuit 100.


A power turbine 110 is arranged downstream from the heat exchanger 108 for receiving and expanding the first mass flow m1 discharged from the heat exchanger 108. The power turbine 110 may be any type of expansion device, such as an expander or a turbine, and may be operatively coupled to an alternator, generator 112, or other device or system configured to receive shaft work. The generator 112 converts the mechanical work generated by the power turbine 110 into usable electrical power.


The power turbine 110 discharges the first mass flow m1 into a first recuperator 114 fluidly coupled downstream thereof. The first recuperator 114 may be configured to transfer residual thermal energy in the first mass flow m1 to the second mass flow m2 which also passes through the first recuperator 114. Consequently, the temperature of the first mass flow m1 is decreased and the temperature of the second mass flow m2 is increased. The second mass flow m2 may be subsequently expanded in a drive turbine 116.


The drive turbine 116 discharges the second mass flow m2 into a second recuperator 118 fluidly coupled downstream thereof. The second recuperator 118 may be configured to transfer residual thermal energy from the second mass flow m2 to the combined working fluid m1+m2 originally discharged from the main pump 104. The mass flows m1, m2 discharged from each recuperator 114, 118, respectively, are recombined at point 120 in the circuit 102 and then returned to a lower temperature state at a condenser 122. After passing through the condenser 122, the combined working fluid m1+m2 is returned to the main pump 104 and the cycle is started anew.


The recuperators 114, 118 and the condenser 122 may be any device adapted to reduce the temperature of the working fluid such as, but not limited to, a direct contact heat exchanger, a trim cooler, a mechanical refrigeration unit, and/or any combination thereof. The heat exchanger 108, recuperators 114, 118, and/or the condenser 122 may include or employ one or more printed circuit heat exchange panels. Such heat exchangers and/or panels are known in the art, and are described in U.S. Pat. Nos. 6,921,518; 7,022,294; and 7,033,553, the contents of which are incorporated by reference to the extent consistent with the present disclosure.


The pump 104 and drive turbine 116 may be operatively coupled via a common shaft 123, thereby forming a direct-drive turbopump 124 where the drive turbine 116 expands working fluid to drive the main pump 104. In one embodiment, the turbopump 124 is hermetically-sealed within a housing or casing 126 such that shaft seals are not needed along the shaft 123 between the main pump 104 and drive turbine 116. Eliminating shaft seals may be advantageous since it contributes to a decrease in capital costs for the heat engine system 100. Also, hermetically-sealing the turbopump 124 with the casing 126 presents significant savings by eliminating overboard working fluid leakage. In other embodiments, however, the turbopump 124 need not be hermetically-sealed.


Steady-state operation of the turbopump 124 is at least partially dependent on the mass flow and temperature of the second mass flow m2 expanded within the drive turbine 116. Until the mass flow and temperature of the second mass flow m2 is sufficiently increased, the main pump 104 cannot adequately drive the drive turbine 116 in self-sustaining operation. Accordingly, at heat engine system 100 startup, and until the turbopump 124 “ramps-up” and is able to adequately circulate the working fluid on its own, the heat engine system 100 uses a starter pump 128 to circulate the working fluid. The starter pump 128 may be driven by a motor 130 and operate until the temperature of the second mass flow m2 is sufficient such that the turbopump 124 can “bootstrap” itself into steady-state operation.


In one or more embodiments, the heat source Qin may be at a temperature of approximately 200° C., or a temperature at which the turbopump 124 is able to bootstrap itself. As can be appreciated, higher heat source temperatures can be utilized, without departing from the scope of the disclosure. To keep thermally-induced stresses in a manageable range, however, the working fluid temperature can be “tempered” through the use of liquid CO2 injection upstream of the drive turbine 116.


To facilitate the start sequence of the turbopump 124, the heat engine system 100 may further include a series of check valves, bypass valves, and/or shut-off valves arranged at predetermined locations throughout the circuit 102. These valves may work in concert to direct the working fluid into the appropriate conduits until turbopump 124 steady-state operation is maintained. In one or more embodiments, the various valves may be automated or semi-automated motor-driven valves coupled to an automated control system (not shown). In other embodiments, the valves may be manually-adjustable or may be a combination of automated and manually-adjustable.


For example, a shut-off valve 132 arranged upstream of the power turbine 110 may be closed during heat engine system 100 startup and ramp-up. Consequently, after being heated in the heat exchanger 108, the first mass flow m1 is diverted around the power turbine 110 via a first diverter line 134 and a second diverter line 138. A bypass valve 142 is arranged in the first diverter line 134 and a bypass valve 140 is arranged in the second diverter line 138. The portion of working fluid circulated through the first diverter line 134 may be used to preheat the second mass flow m2 in the first recuperator 114. A check valve 144 allows the second mass flow m2 to flow through to the first recuperator 114. The portion of the working fluid circulated through the second diverter line 138 is combined with the second mass flow m2 discharged from the first recuperator 114 and injected into the drive turbine 116 in its high-temperature condition.


A first check valve 146 may be arranged downstream from the main pump 104 and a second check valve 148 may be arranged downstream from the starter pump 128. The check valves 146, 148 may be configured to prevent the working fluid from flowing upstream toward the respective pumps 104, 128 during various stages of operation of the heat engine system 100. For instance, during startup and ramp-up the starter pump 128 creates an elevated head pressure downstream from the first check valve 146 (e.g., at point 150) as compared to the low pressure discharge of the main pump 104. The first check valve 146 prevents the high pressure working fluid discharged from the starter pump 128 from circulating toward the main pump 104 and thereby impeding the operational progress of the turbopump 124 as it ramps up its speed.


Until the turbopump 124 accelerates past its stall speed, where the main pump 104 can adequately pump against the head pressure created by the starter pump 128, a first recirculation line 152 may be used to divert the low pressure working fluid discharged from the main pump 104. A first bypass valve 154 may be arranged in the first recirculation line 152 and may be fully or partially opened while the turbopump 124 ramps up its speed to allow the low pressure working fluid to recirculate back to a low pressure point in the working fluid circuit 102, such as any point in the working fluid circuit 102 downstream of the power or drive turbines 110, 116 and upstream of the pumps 104, 128. In one embodiment, the first recirculation line 152 may fluidly couple the discharge of the main pump 104 to the inlet of the condenser 122, such as at point 156.


Once the turbopump 124 attains a “bootstrapping” speed (i.e., a self-sustaining speed), the bypass valve 154 in the first recirculation line 152 can be gradually closed. Gradually closing the bypass valve 154 will increase the fluid pressure at the discharge from the main pump 104 and decrease the flow rate through the first recirculation line 152. Eventually, once the turbopump 124 reaches steady-state operating speeds, the bypass valve 154 may be fully closed and the entirety of the working fluid discharged from the main pump 104 may be directed through the first check valve 146.


Once the turbopump 124 reaches steady-state operating speeds, and even once a bootstrapped speed is achieved, the shut-off valve 132 arranged upstream from the power turbine 110 may be opened and the bypass valve 140 may be simultaneously closed. As a result, the heated stream of first mass flow m1 may be directed through the power turbine 110 to commence generation of electrical power.


Also, once steady-state operating speeds are achieved the starter pump 128 becomes redundant and can therefore be deactivated. To facilitate this without causing damage to the starter pump 128, a second recirculation line 158 having a second bypass valve 160 is arranged therein may direct lower pressure working fluid discharged from the starter pump 128 to a low pressure side of the working fluid circuit 102 (e.g., point 156). The low pressure side of the working fluid circuit 102 may be any point in the working fluid circuit 102 downstream of the power or drive turbines 110, 116 and upstream of the pumps 104, 128. The second bypass valve 160 is generally closed during startup and ramp-up so as to direct all the working fluid discharged from the starter pump 128 through the second check valve 148. However, as the starter pump 128 powers down, the head pressure past the second check valve 148 becomes greater than the starter pump 128 discharge pressure. In order to provide relief to the starter pump 128, the second bypass valve 160 may be gradually opened to allow working fluid to escape to the low pressure side of the working fluid circuit. Eventually, the second bypass valve 160 is completely opened as the speed of the starter pump 128 slows to a stop. Again, the valving may be regulated through the implementation of an automated control system (not shown).


As will be appreciated by those skilled in the art, there are several advantages to the embodiments disclosed herein. For example, the turbopump 124 is able to circulate the fluid to not only generate electricity via the power turbine 110 but also use fluid energy remaining in the working fluid to drive the main pump 104 via the drive turbine 116. Consequently, fluid energy is not required to be converted into mechanical work, then into electricity, and then back into mechanical work, as would be the case with a motor-driven pump. This reduces the required capacity of the generator 112 for the power turbine 110 and therefore provides cost saving on capital investment. Moreover, the turbopump 124 eliminates the need for a variable frequency drive and gearbox that would otherwise be needed for a motor-driven pump. Such components not only introduce energy loss terms and decrease overall system performance, but also increase capital costs and present additional points of failure in the heat engine system 100. Also, the design of the drive turbine 116 and pump 104 can be matched to provide a high degree of performance from a physically small pump, providing cost advantages, small system footprint, and physical arrangement flexibility.


Referring now to FIG. 2, an exemplary heat engine system 200 is shown wherein heat engine system 200 may be similar in several respects to the heat engine system 100 described above. Accordingly, the heat engine system 200 may be further understood with reference to FIG. 1, where like numerals indicate like components that will not be described again in detail. As with the heat engine system 100 described above, the heat engine system 200 in FIG. 2 may be used to convert thermal energy to work by thermal expansion of a working fluid mass flowing through a working fluid circuit 202. The heat engine system 200, however, may be characterized as a parallel-type Rankine thermodynamic cycle.


Specifically, the working fluid circuit 202 may include a first heat exchanger 204 and a second heat exchanger 206 arranged in thermal communication with the heat source Qin. The first and second heat exchangers 204, 206 may correspond generally to the heat exchanger 108 described above with reference to FIG. 1. For example, in one embodiment, the first and second heat exchangers 204, 206 may be first and second stages, respectively, of a single or combined heat exchanger. The first heat exchanger 204 may serve as a high temperature heat exchanger (e.g., a higher temperature relative to the second heat exchanger 206) adapted to receive initial thermal energy from the heat source Qin. The second heat exchanger 206 may then receive additional thermal energy from the heat source Qin via a serial connection downstream from the first heat exchanger 204. The heat exchangers 204, 206 are arranged in series with the heat source Qin, but in parallel in the working fluid circuit 202.


The first heat exchanger 204 may be fluidly coupled to the power turbine 110 and the second heat exchanger 206 may be fluidly coupled to the drive turbine 116. In turn, the power turbine 110 is fluidly coupled to the first recuperator 114 and the drive turbine 116 is fluidly coupled to the second recuperator 118. The recuperators 114, 118 may be arranged in series on a low temperature side of the working fluid circuit 202 and in parallel on a high temperature side of the working fluid circuit 202. For example, the high temperature side of the working fluid circuit 202 includes the portions of the working fluid circuit 202 arranged downstream from each recuperator 114, 118 where the working fluid is directed to the heat exchangers 204, 206. The low temperature side of the working fluid circuit 202 includes the portions of the working fluid circuit 202 downstream from each recuperator 114, 118 where the working fluid is directed away from the heat exchangers 204, 206.


The turbopump 124 is also included in the working fluid circuit 202, where the main pump 104 is operatively coupled to the drive turbine 116 via the shaft 123 (indicated by the dashed line), as described above. The pump 104 is shown separated from the drive turbine 116 only for ease of viewing and describing the working fluid circuit 202. Indeed, although not specifically illustrated, it will be appreciated that both the main pump 104 and the drive turbine 116 may be hermetically-sealed within the casing 126 (FIG. 1). This also applies to FIGS. 3 and 4 below. The starter pump 128 facilitates the start sequence for the turbopump 124 during startup of the heat engine system 200 and ramp-up of the turbopump 124. Once steady-state operation of the turbopump 124 is reached, the starter pump 128 may be deactivated.


The power turbine 110 may operate at a higher relative temperature (e.g., higher turbine inlet temperature) than the drive turbine 116, due to the temperature drop of the heat source Qin experienced across the first heat exchanger 204. Each turbine 110, 116, however, may be configured to operate at the same or substantially the same inlet pressure. The low-pressure discharge mass flow exiting each recuperator 114, 118 may be directed through the condenser 122 to be cooled for return to the low temperature side of the working fluid circuit 202 and to either the main or starter pumps 104, 128, depending on the stage of operation.


During steady-state operation of the heat engine system 200, the turbopump 124 circulates all of the working fluid throughout the working fluid circuit 202 using the main pump 104, and the starter pump 128 does not generally operate nor is needed. The first bypass valve 154 in the first recirculation line 152 is fully closed and the working fluid is separated into the first and second mass flows m1, m2 at point 210. The first mass flow m1 is directed through the first heat exchanger 204 and subsequently expanded in the power turbine 110 to generate electrical power via the generator 112. Following the power turbine 110, the first mass flow m1 passes through the first recuperator 114 and transfers residual thermal energy to the first mass flow m1 as the first mass flow m1 is directed toward the first heat exchanger 204.


The second mass flow m2 is directed through the second heat exchanger 206 and subsequently expanded in the drive turbine 116 to drive the main pump 104 via the shaft 123. Following the drive turbine 116, the second mass flow m2 passes through the second recuperator 118 to transfer residual thermal energy to the second mass flow m2 as the second mass flow m2 courses toward the second heat exchanger 206. The second mass flow m2 is then re-combined with the first mass flow m1 and the combined mass flow m1+m2 is subsequently cooled in the condenser 122 and directed back to the main pump 104 to commence the fluid loop anew.


During startup of the heat engine system 200 or ramp-up of the turbopump 124, the starter pump 128 is engaged and operates to start the turbopump 124 spinning. To help facilitate this, a shut-off valve 214 arranged downstream from point 210 is initially closed such that no working fluid is directed to the first heat exchanger 204 or otherwise expanded in the power turbine 110. Rather, all the working fluid discharged from the starter pump 128 is directed through the second heat exchanger 206 and the drive turbine 116. The heated working fluid expands in the drive turbine 116 and drives the main pump 104, thereby commencing operation of the turbopump 124.


The head pressure generated by the starter pump 128 near point 210 prevents the low pressure working fluid discharged from the main pump 104 during ramp-up from traversing the first check valve 146. Until the main pump 104 is able to accelerate past its stall speed, the first bypass valve 154 in the first recirculation line 152 may be fully opened to recirculate the low pressure working fluid back to a low pressure point in the working fluid circuit 202, such as at point 156 adjacent the inlet of the condenser 122. Once the turbopump 124 reaches its “bootstrapped” speed (e.g., self-sustaining speed), the bypass valve 154 may be gradually closed to increase the discharge pressure of the main pump 104 and also decrease the flow rate through the first recirculation line 152. Once the turbopump 124 reaches steady-state operation, and even once a bootstrapped speed is achieved, the shut-off valve 214 may be gradually opened, thereby allowing the first mass flow m1 to be expanded in the power turbine 110 to commence generating electrical energy. Again, the valving may be regulated through the implementation of an automated control system (not shown).


With the turbopump 124 operating at steady-state operating speeds, the starter pump 128 can gradually be powered down and deactivated. Deactivating the starter pump 128 may include simultaneously opening the second bypass valve 160 arranged in the second recirculation line 158. The second bypass valve 160 allows the increasingly lower pressure working fluid discharged from the starter pump 128 to escape to the low pressure side of the working fluid circuit (e.g., point 156). Eventually the second bypass valve 160 may be completely opened as the speed of the starter pump 128 slows to a stop and the second check valve 148 prevents working fluid discharged by the main pump 104 from advancing toward the discharge of the starter pump 128. At steady-state, the turbopump 124 continuously pressurizes the working fluid circuit 202 in order to drive both the drive turbine 116 and the power turbine 110.



FIG. 3 illustrates an exemplary parallel-type heat engine system 300, which may be similar in some respects to the above-described heat engine systems 100 and 200, and therefore, may be best understood with reference to FIGS. 1 and 2, where like numerals correspond to like elements that will not be described again. The heat engine system 300 includes a working fluid circuit 302 utilizing a third heat exchanger 304 also in thermal communication with the heat source Qin. The heat exchangers 204, 206, 304 are arranged in series with the heat source Qin, but arranged in parallel in the working fluid circuit 302.


The turbopump 124 (i.e., the combination of the main pump 104 and the drive turbine 116 operatively coupled via the shaft 123) is arranged and configured to operate in parallel with the starter pump 128, especially during heat engine system 300 startup and turbopump 124 ramp-up. During steady-state operation of the heat engine system 300, the starter pump 128 does not generally operate. Instead, the main pump 104 solely discharges the working fluid that is subsequently separated into first and second mass flows m1, m2, respectively, at point 306. The third heat exchanger 304 may be configured to transfer thermal energy from the heat source Qin to the first mass flow m1 flowing therethrough. The first mass flow m1 is then directed to the first heat exchanger 204 and the power turbine 110 for expansion power generation. Following expansion in the power turbine 110, the first mass flow m1 passes through the first recuperator 114 to transfer residual thermal energy to the first mass flow m1 discharged from the third heat exchanger 304 and coursing toward the first heat exchanger 204.


The second mass flow m2 is directed through the second heat exchanger 206 and subsequently expanded in the drive turbine 116 to drive the main pump 104. After being discharged from the drive turbine 116, the second mass flow m2 merges with the first mass flow m1 at point 308. The combined mass flow m1+m2 thereafter passes through the second recuperator 118 to provide residual thermal energy to the second mass flow m2 as the second mass flow m2 courses toward the second heat exchanger 206.


During the heat engine system 300 startup and/or the turbopump 124 ramp-up, the starter pump 128 circulates the working fluid to commence the turbopump 124 spinning. The shut-off valve 214 may be initially closed to prevent working fluid from circulating through the first and third heat exchangers 204, 304 and being expanded in the power turbine 110. The working fluid discharged from the starter pump 128 is directed through the second heat exchanger 206 and the drive turbine 116. The heated working fluid expands in the drive turbine 116 and drives the main pump 104, thereby commencing operation of the turbopump 124.


Until the discharge pressure of the main pump 104 accelerates past its stall speed and can withstand the head pressure generated by the starter pump 128, any working fluid discharged from the main pump 104 is generally recirculated via the first recirculation line 152 back to a low pressure point in the working fluid circuit 202 (e.g., point 156). Once the turbopump 124 becomes self-sustaining, the bypass valve 154 may be gradually closed to increase the main pump 104 discharge pressure and decrease the flow rate in the first recirculation line 152. At that point, the shut-off valve 214 may also be gradually opened to begin circulation of the first mass flow m1 through the power turbine 110 to generate electrical energy. Also, at this point the starter pump 128 can be gradually deactivated while simultaneously opening the second bypass valve 160 arranged in the second recirculation line 158. Eventually the second bypass valve 160 is completely opened and the starter pump 128 can be slowed to a stop. Again, the valving may be regulated through the implementation of an automated control system (not shown).



FIG. 4 illustrates an exemplary parallel-type heat engine system 400, wherein the heat engine system 400 may be similar to the system 300 above, and as such, may be best understood with reference to FIG. 3 where like numerals correspond to like elements that will not be described again. The working fluid circuit 402 in FIG. 4 is substantially similar to the working fluid circuit 302 of FIG. 3 but with the exception of an additional, third recuperator 404 adapted to extract additional thermal energy from the combined mass flow m1+m2 discharged from the second recuperator 118. Accordingly, the temperature of the first mass flow m1 entering the third heat exchanger 304 may be preheated in the third recuperator 404 prior to receiving thermal energy transferred from the heat source Qin.


As illustrated, the recuperators 114, 118, 404 may operate as separate heat exchanging devices. In other embodiments, however, the recuperators 114, 118, 404 may be combined as a single, integral recuperator. Steady-state operation, system startup, and turbopump 124 ramp-up may operate substantially similar as described above in FIG. 3, and therefore will not be described again.


Each of the described heat engine systems 100, 200, 300, and 400, as depicted in FIGS. 1-4, may be implemented in a variety of physical embodiments, including but not limited to fixed or integrated installations, or as a self-contained device such as a portable waste heat engine “skid.” The waste heat engine skid may be configured to arrange each working fluid circuit 102, 202, 302, and 402 and related components (e.g., turbines 110, 116, recuperators 114, 118, 404, condenser 122, pumps 104, 128, etc.) in a consolidated, single unit. An exemplary waste heat engine skid is described and illustrated in U.S. application Ser. No. 12/631,412, entitled “Thermal Energy Conversion Device,” filed on Dec. 4, 2009, and published as U.S. 2011-0185729, the contents of which are hereby incorporated by reference to the extent consistent with the present disclosure.


Referring now to FIG. 5, illustrated is a flowchart of a method 500 for starting a turbopump in a thermodynamic working fluid circuit. The method 500 includes circulating a working fluid in the working fluid circuit with a starter pump, as at 502. The starter pump may be in fluid communication with a first heat exchanger, and the first heat exchanger may be in thermal communication with a heat source. Thermal energy is transferred to the working fluid from the heat source in the first heat exchanger, as at 504. The method 500 further includes expanding the working fluid in a drive turbine, as at 506. The drive turbine is fluidly coupled to the first heat exchanger, and the drive turbine is operatively coupled to a main pump, such that the combination of the drive turbine and main pump is the turbopump.


The main pump is driven with the drive turbine, as at 508. Until the main pump accelerates past its stall point, the working fluid discharged from the main pump is diverted into a first recirculation line, as at 510. The first recirculation line may fluidly communicate the main pump with a low pressure side of the working fluid circuit. Moreover, a first bypass valve may be arranged in the first recirculation line. As the turbopump reaches a self-sustaining speed of operation, the first bypass valve may gradually begin to close, as at 512. Consequently, the main pump begins circulating the working fluid discharged from the main pump through the working fluid circuit, as at 514.


The method 500 may also include deactivating the starter pump and opening a second bypass valve arranged in a second recirculation line, as at 516. The second recirculation line may fluidly communicate the starter pump with the low pressure side of the working fluid circuit. The low pressure working fluid discharged from the starter pump may be diverted into the second recirculation line until the starter pump comes to a stop, as at 518.


The foregoing has outlined features of several embodiments so that those skilled in the art may better understand the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions and alterations herein without departing from the spirit and scope of the present disclosure.

Claims
  • 1. A method for starting a turbopump in a working fluid circuit, comprising: circulating a working fluid in the working fluid circuit with a starter pump, the working fluid comprising carbon dioxide and the starter pump being in fluid communication with a first heat exchanger in thermal communication with a heat source;transferring thermal energy to the working fluid from the heat source in the first heat exchanger;expanding the working fluid in a drive turbine in fluid communication with the first heat exchanger, wherein the turbopump comprises the drive turbine operatively coupled to a main pump;driving the main pump with the drive turbine;diverting the working fluid discharged from the main pump into a first recirculation line disposed in the working fluid circuit, the first recirculation line having a first bypass valve arranged therein;closing the first bypass valve as the turbopump reaches a self-sustaining speed of operation;circulating the working fluid discharged from the main pump through the working fluid circuit;deactivating the starter pump and opening a second bypass valve arranged in a second recirculation line disposed in the working fluid circuit; anddiverting the working fluid discharged from the starter pump into the second recirculation line.
  • 2. The method of claim 1, wherein circulating the working fluid in the working fluid circuit with the starter pump is preceded by closing a shut-off valve to divert the working fluid around a power turbine arranged in the working fluid circuit.
  • 3. The method of claim 2, further comprising: opening the shut-off valve once the turbopump reaches the self-sustaining speed of operation, thereby directing the working fluid into the power turbine;expanding the working fluid in the power turbine; anddriving a generator operatively coupled to the power turbine to generate electrical power.
  • 4. The method of claim 2, further comprising: opening the shut-off valve once the turbopump reaches the self-sustaining speed of operation;directing the working fluid into a second heat exchanger fluidly coupled to the power turbine and in thermal communication with the heat source;transferring additional thermal energy from the heat source to the working fluid in the second heat exchanger;expanding the working fluid received from the second heat exchanger in the power turbine; anddriving a generator operatively coupled to the power turbine, whereby the generator is operable to generate electrical power.
  • 5. The method of claim 2, further comprising: opening the shut-off valve once the turbopump reaches the self-sustaining speed of operation;directing the working fluid into a second heat exchanger in thermal communication with the heat source;directing the working fluid from the second heat exchanger into a third heat exchanger fluidly coupled to the power turbine and in thermal communication with the heat source, wherein the first heat exchanger, the second heat exchanger, and the third heat exchanger are fluidly arranged in series with the heat source;transferring additional thermal energy from the heat source to the working fluid in the third heat exchanger;expanding the working fluid received from the third heat exchanger in the power turbine; anddriving a generator operatively coupled to the power turbine, whereby the generator is operable to generate electrical power.
  • 6. A heat engine system, comprising: a working fluid comprising carbon dioxide;a working fluid circuit containing the working fluid and at least a portion of the working fluid circuit is configured to contain the working fluid in a supercritical state;a turbopump comprising a main pump and a drive turbine operatively coupled together and hermetically-sealed within a casing, the main pump being configured to circulate the working fluid throughout the working fluid circuit;a starter pump fluidly arranged in parallel with the main pump in the working fluid circuit;a first check valve arranged in the working fluid circuit downstream of the main pump;a power turbine fluidly coupled to both the main pump and the starter pump via the working fluid circuit;a shut-off valve arranged in the working fluid circuit to divert the working fluid around the power turbine;a condenser fluidly coupled to the working fluid circuit, disposed downstream of at least one recuperator and upstream of the main pump and the starter pump, and configured to remove thermal energy from the working fluid;a first recirculation line disposed downstream of the main pump and upstream of the condenser within the working fluid circuit; anda second recirculation line disposed downstream of the starter pump and upstream of the condenser within the working fluid circuit.
  • 7. The heat engine system of claim 6, further comprising a second check valve arranged in the working fluid circuit downstream of the starter pump.
  • 8. The heat engine system of claim 6, wherein the at least one recuperator comprises: a first recuperator fluidly coupled to the power turbine via the working fluid circuit; anda second recuperator fluidly coupled to the drive turbine via the working fluid circuit.
  • 9. The heat engine system of claim 8, further comprising a third recuperator fluidly coupled to the second recuperator via the working fluid circuit, wherein the first recuperator, the second recuperator, and the third recuperator are fluidly arranged in series within the working fluid circuit.
  • 10. The heat engine system of claim 6, further comprising a first heat exchanger, a second heat exchanger, and a third heat exchanger configured to be fluidly arranged in series and in thermal communication with a heat source and the first heat exchanger and the second heat exchanger are fluidly arranged in parallel within the working fluid circuit.
  • 11. The heat engine system of claim 6, wherein the working fluid is in a supercritical state within working fluid circuit downstream from the power turbine and the drive turbine and upstream of the starter pump and the main pump.
  • 12. A heat engine system, comprising: a working fluid comprising carbon dioxide;a working fluid circuit containing the working fluid and separating the working fluid into a first mass flow and a second mass flow, and at least a portion of the working fluid circuit is configured to contain the working fluid in a supercritical state;a turbopump comprising a main pump and a drive turbine operatively coupled together and arranged within a casing, the main pump being configured to circulate the working fluid throughout the working fluid circuit and the drive turbine being configured to expand the working fluid;a starter pump fluidly arranged in parallel with the main pump in the working fluid circuit;a first heat exchanger in fluid communication with the main pump via the working fluid circuit and configured to be in thermal communication with a heat source, the first heat exchanger receiving the first mass flow and configured to transfer thermal energy from the heat source to the first mass flow;a second heat exchanger in fluid communication with the main pump and the starter pump via the working fluid circuit and configured to be in thermal communication with the heat source, the second heat exchanger receiving the second mass flow and configured to transfer thermal energy from the heat source to the second mass flow;a power turbine fluidly coupled to the first heat exchanger via the working fluid circuit and configured to expand the first mass flow;a first recuperator fluidly coupled to the power turbine via the working fluid circuit and receiving the first mass flow discharged from the power turbine;a condenser fluidly coupled to the working fluid circuit downstream of the first recuperator and upstream of the main pump and configured to remove thermal energy from the working fluid;a first recirculation line disposed downstream of the main pump and upstream of the condenser within the working fluid circuit; anda second recirculation line disposed downstream of the starter pump and upstream of the condenser within the working fluid circuit.
  • 13. The heat engine system of claim 12, wherein the first heat exchanger and the second heat exchanger are configured to be fluidly arranged in series and in thermal communication with the heat source and the first heat exchanger and the second heat exchanger are fluidly arranged in parallel within the working fluid circuit.
  • 14. The heat engine system of claim 12, wherein the first recuperator is configured to transfer residual thermal energy from the first mass flow to the second mass flow upstream of the drive turbine for the second mass flow.
  • 15. The heat engine system of claim 12, wherein the first recuperator is configured to transfer residual thermal energy from the first mass flow discharged from the power turbine to the first mass flow directed to the first heat exchanger.
  • 16. The heat engine system of claim 12, further comprising a second recuperator fluidly coupled to the drive turbine via the working fluid circuit and configured to receive the working fluid discharged from the drive turbine.
  • 17. The heat engine system of claim 16, wherein the second recuperator is configured to transfer residual thermal energy from the second mass flow to a combination of the first and second mass flows.
  • 18. The heat engine system of claim 16, wherein the second recuperator is configured to transfer residual thermal energy from the second mass flow discharged from the drive turbine to the second mass flow directed to the second heat exchanger.
  • 19. The heat engine system of claim 12, wherein the working fluid is in a supercritical state within working fluid circuit downstream from the power turbine and the drive turbine and upstream of the starter pump and the main pump.
  • 20. The heat engine system of claim 1, further comprising: a first bypass valve arranged in the first recirculation line; anda second bypass valve arranged in the second recirculation line.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No. 13/205,082, entitled “Driven Starter Pump and Start Sequence,” and filed on Aug. 8, 2011, which claims benefit of U.S. Prov. Appl. No. 61/417,789, entitled “Parallel Cycle Heat Engines,” and filed on Nov. 29, 2010, and which claims priority to PCT Appl. No. US2011/029486, entitled “Heat Engines with Cascade Cycles,” and filed on Mar. 22, 2011, the contents of which are hereby incorporated by reference to the extent not inconsistent with the present disclosure.

US Referenced Citations (398)
Number Name Date Kind
2575478 Wilson Nov 1951 A
2634375 Guimbal Apr 1953 A
2691280 Albert Oct 1954 A
3095274 Crawford Jun 1963 A
3105748 Stahl Oct 1963 A
3237403 Feher Mar 1966 A
3277955 Laszlo Oct 1966 A
3401277 Larson Sep 1968 A
3622767 Koepcke Nov 1971 A
3630022 Jubb Dec 1971 A
3736745 Karig Jun 1973 A
3772879 Engdahl Nov 1973 A
3791137 Jubb Feb 1974 A
3830062 Morgan et al. Aug 1974 A
3939328 Davis Feb 1976 A
3971211 Wethe Jul 1976 A
3982379 Gilli Sep 1976 A
3998058 Park Dec 1976 A
4009575 Hartman, Jr. Mar 1977 A
4029255 Heiser Jun 1977 A
4030312 Wallin Jun 1977 A
4049407 Bottum Sep 1977 A
4070870 Bahel Jan 1978 A
4099381 Rappoport Jul 1978 A
4119140 Cates Oct 1978 A
4150547 Hobson Apr 1979 A
4152901 Munters May 1979 A
4164848 Gilli Aug 1979 A
4164849 Mangus Aug 1979 A
4170435 Swearingen Oct 1979 A
4182960 Reuyl Jan 1980 A
4183220 Shaw Jan 1980 A
4198827 Terry et al. Apr 1980 A
4208882 Lopes Jun 1980 A
4221185 Scholes Sep 1980 A
4233085 Roderick Nov 1980 A
4236869 Laurello Dec 1980 A
4248049 Briley Feb 1981 A
4257232 Bell Mar 1981 A
4287430 Guido Sep 1981 A
4336692 Ecker Jun 1982 A
4347711 Noe Sep 1982 A
4347714 Kinsell Sep 1982 A
4372125 Dickenson Feb 1983 A
4384568 Palmatier May 1983 A
4391101 Labbe Jul 1983 A
4420947 Yoshino Dec 1983 A
4428190 Bronicki Jan 1984 A
4433554 Rojey Feb 1984 A
4439687 Wood Mar 1984 A
4439994 Briley Apr 1984 A
4448033 Briccetti May 1984 A
4450363 Russell May 1984 A
4455836 Binstock Jun 1984 A
4467609 Loomis Aug 1984 A
4467621 O'Brien Aug 1984 A
4475353 Lazare Oct 1984 A
4489562 Snyder Dec 1984 A
4489563 Kalina Dec 1984 A
4498289 Osgerby Feb 1985 A
4516403 Tanaka May 1985 A
4538960 Iino et al. Sep 1985 A
4549401 Spliethoff Oct 1985 A
4555905 Endou Dec 1985 A
4558228 Larjola Dec 1985 A
4573321 Knaebel Mar 1986 A
4578953 Krieger Apr 1986 A
4589255 Martens May 1986 A
4636578 Feinberg Jan 1987 A
4674297 Vobach Jun 1987 A
4694189 Haraguchi Sep 1987 A
4697981 Brown et al. Oct 1987 A
4700543 Krieger Oct 1987 A
4730977 Haaser Mar 1988 A
4756162 Dayan Jul 1988 A
4765143 Crawford Aug 1988 A
4773212 Griffin Sep 1988 A
4798056 Franklin Jan 1989 A
4813242 Wicks Mar 1989 A
4821514 Schmidt Apr 1989 A
4867633 Gravelle Sep 1989 A
4892459 Guelich Jan 1990 A
4986071 Voss Jan 1991 A
4993483 Harris Feb 1991 A
5000003 Wicks Mar 1991 A
5050375 Dickinson Sep 1991 A
5083425 Hendriks et al. Jan 1992 A
5098194 Kuo Mar 1992 A
5102295 Pope Apr 1992 A
5104284 Hustak, Jr. Apr 1992 A
5164020 Wagner Nov 1992 A
5176321 Doherty Jan 1993 A
5203159 Koizumi et al. Apr 1993 A
5228310 Vandenberg Jul 1993 A
5291960 Brandenburg Mar 1994 A
5320482 Palmer et al. Jun 1994 A
5335510 Rockenfeller Aug 1994 A
5358378 Holscher Oct 1994 A
5360057 Rockenfeller Nov 1994 A
5392606 Labinov Feb 1995 A
5440882 Kalina Aug 1995 A
5444972 Moore Aug 1995 A
5483797 Rigal et al. Jan 1996 A
5488828 Brossard Feb 1996 A
5490386 Keller Feb 1996 A
5503222 Dunne Apr 1996 A
5531073 Bronicki Jul 1996 A
5538564 Kaschmitter Jul 1996 A
5542203 Luoma Aug 1996 A
5570578 Saujet Nov 1996 A
5588298 Kalina Dec 1996 A
5600967 Meckler Feb 1997 A
5634340 Grennan Jun 1997 A
5647221 Garris, Jr. Jul 1997 A
5649426 Kalina Jul 1997 A
5676382 Dahlheimer Oct 1997 A
5680753 Hollinger Oct 1997 A
5738164 Hildebrand Apr 1998 A
5754613 Hashiguchi May 1998 A
5771700 Cochran Jun 1998 A
5789822 Calistrat Aug 1998 A
5813215 Weisser Sep 1998 A
5833876 Schnur Nov 1998 A
5862666 Liu Jan 1999 A
5873260 Linhardt Feb 1999 A
5874039 Edelson Feb 1999 A
5894836 Wu Apr 1999 A
5899067 Hageman May 1999 A
5903060 Norton May 1999 A
5918460 Connell Jul 1999 A
5941238 Tracy Aug 1999 A
5943869 Cheng Aug 1999 A
5946931 Lomax Sep 1999 A
5973050 Johnson Oct 1999 A
6037683 Lulay Mar 2000 A
6041604 Nicodemus Mar 2000 A
6058930 Shingleton May 2000 A
6062815 Holt May 2000 A
6065280 Ranasinghe May 2000 A
6066797 Toyomura May 2000 A
6070405 Jerye Jun 2000 A
6082110 Rosenblatt Jul 2000 A
6105368 Hansen Aug 2000 A
6112547 Spauschus Sep 2000 A
6129507 Ganelin Oct 2000 A
6158237 Riffat Dec 2000 A
6164655 Bothien Dec 2000 A
6202782 Hatanaka Mar 2001 B1
6223846 Schechter May 2001 B1
6233938 Nicodemus May 2001 B1
6282900 Bell Sep 2001 B1
6282917 Mongan Sep 2001 B1
6295818 Ansley Oct 2001 B1
6299690 Mongeon Oct 2001 B1
6341781 Matz Jan 2002 B1
6374630 Jones Apr 2002 B1
6393851 Wightman May 2002 B1
6432320 Bonsignore Aug 2002 B1
6434955 Ng Aug 2002 B1
6442951 Maeda Sep 2002 B1
6446425 Lawlor Sep 2002 B1
6446465 Dubar Sep 2002 B1
6463730 Keller Oct 2002 B1
6484490 Olsen Nov 2002 B1
6539720 Rouse et al. Apr 2003 B2
6539728 Korin Apr 2003 B2
6571548 Bronicki Jun 2003 B1
6581384 Benson Jun 2003 B1
6598397 Hanna Jul 2003 B2
6644062 Hays Nov 2003 B1
6657849 Andresakis Dec 2003 B1
6668554 Brown Dec 2003 B1
6684625 Kline Feb 2004 B2
6695974 Withers Feb 2004 B2
6715294 Anderson Apr 2004 B2
6734585 Tornquist May 2004 B2
6735948 Kalina May 2004 B1
6739142 Korin May 2004 B2
6751959 McClanahan et al. Jun 2004 B1
6769256 Kalina Aug 2004 B1
6799892 Leuthold Oct 2004 B2
6808179 Bhattacharyya Oct 2004 B1
6810335 Lysaght Oct 2004 B2
6817185 Coney Nov 2004 B2
6857268 Stinger Feb 2005 B2
6910334 Kalina Jun 2005 B2
6918254 Baker Jul 2005 B2
6921518 Johnston Jul 2005 B2
6941757 Kalina Sep 2005 B2
6960839 Zimron Nov 2005 B2
6960840 Willis Nov 2005 B2
6962054 Linney Nov 2005 B1
6964168 Pierson Nov 2005 B1
6968690 Kalina Nov 2005 B2
6986251 Radcliff Jan 2006 B2
7013205 Hafner et al. Mar 2006 B1
7021060 Kalina Apr 2006 B1
7022294 Johnston Apr 2006 B2
7033553 Johnston et al. Apr 2006 B2
7036315 Kang May 2006 B2
7041272 Keefer May 2006 B2
7047744 Robertson May 2006 B1
7048782 Couch May 2006 B1
7062913 Christensen Jun 2006 B2
7096665 Stinger Aug 2006 B2
7096679 Manole Aug 2006 B2
7124587 Linney Oct 2006 B1
7174715 Armitage Feb 2007 B2
7194863 Ganev Mar 2007 B2
7197876 Kalina Apr 2007 B1
7200996 Cogswell Apr 2007 B2
7234314 Wiggs Jun 2007 B1
7249588 Russell Jul 2007 B2
7278267 Yamada Oct 2007 B2
7279800 Bassett Oct 2007 B2
7287381 Pierson Oct 2007 B1
7305829 Mirolli Dec 2007 B2
7313926 Gurin Jan 2008 B2
7340894 Miyahara et al. Mar 2008 B2
7340897 Zimron Mar 2008 B2
7406830 Valentian Aug 2008 B2
7416137 Hagen et al. Aug 2008 B2
7453242 Ichinose Nov 2008 B2
7458217 Kalina Dec 2008 B2
7458218 Kalina Dec 2008 B2
7464551 Althaus et al. Dec 2008 B2
7469542 Kalina Dec 2008 B2
7516619 Pelletier Apr 2009 B2
7600394 Kalina Oct 2009 B2
7621133 Tomlinson Nov 2009 B2
7654354 Otterstrom Feb 2010 B1
7665291 Anand Feb 2010 B2
7665304 Sundel Feb 2010 B2
7685821 Kalina Mar 2010 B2
7730713 Nakano Jun 2010 B2
7735335 Uno Jun 2010 B2
7770376 Brostmeyer Aug 2010 B1
7775758 Legare Aug 2010 B2
7827791 Pierson Nov 2010 B2
7838470 Shaw Nov 2010 B2
7841179 Kalina Nov 2010 B2
7841306 Myers Nov 2010 B2
7854587 Ito Dec 2010 B2
7866157 Ernst Jan 2011 B2
7900450 Gurin Mar 2011 B2
7950230 Nishikawa May 2011 B2
7950243 Gurin May 2011 B2
7972529 Machado Jul 2011 B2
7997076 Ernst Aug 2011 B2
8096128 Held et al. Jan 2012 B2
8099198 Gurin Jan 2012 B2
8146360 Myers Apr 2012 B2
8281593 Held Oct 2012 B2
8419936 Berger et al. Apr 2013 B2
8616001 Held et al. Dec 2013 B2
20010015061 Viteri et al. Aug 2001 A1
20010020444 Johnston Sep 2001 A1
20010030952 Roy Oct 2001 A1
20020029558 Tamaro Mar 2002 A1
20020066270 Rouse et al. Jun 2002 A1
20020078696 Korin Jun 2002 A1
20020078697 Lifson Jun 2002 A1
20020082747 Kramer Jun 2002 A1
20030000213 Christensen Jan 2003 A1
20030061823 Alden Apr 2003 A1
20030154718 Nayar Aug 2003 A1
20030182946 Sami Oct 2003 A1
20030213246 Coll et al. Nov 2003 A1
20030221438 Rane et al. Dec 2003 A1
20040011038 Stinger Jan 2004 A1
20040011039 Stinger et al. Jan 2004 A1
20040020185 Brouillette et al. Feb 2004 A1
20040020206 Sullivan et al. Feb 2004 A1
20040021182 Green et al. Feb 2004 A1
20040035117 Rosen Feb 2004 A1
20040083731 Lasker May 2004 A1
20040083732 Hanna et al. May 2004 A1
20040088992 Brasz et al. May 2004 A1
20040097388 Brask et al. May 2004 A1
20040105980 Sudarshan et al. Jun 2004 A1
20040107700 McClanahan et al. Jun 2004 A1
20040159110 Janssen Aug 2004 A1
20040211182 Gould Oct 2004 A1
20050022963 Garrabrant et al. Feb 2005 A1
20050056001 Frutschi Mar 2005 A1
20050096676 Gifford, III et al. May 2005 A1
20050109387 Marshall May 2005 A1
20050137777 Kolavennu et al. Jun 2005 A1
20050162018 Realmuto et al. Jul 2005 A1
20050167169 Gering et al. Aug 2005 A1
20050183421 Vaynberg et al. Aug 2005 A1
20050196676 Singh et al. Sep 2005 A1
20050198959 Schubert Sep 2005 A1
20050227187 Schilling Oct 2005 A1
20050252235 Critoph et al. Nov 2005 A1
20050257812 Wright et al. Nov 2005 A1
20060010868 Smith Jan 2006 A1
20060060333 Chordia et al. Mar 2006 A1
20060066113 Ebrahim et al. Mar 2006 A1
20060080960 Rajendran et al. Apr 2006 A1
20060112693 Sundel Jun 2006 A1
20060182680 Keefer et al. Aug 2006 A1
20060211871 Dai et al. Sep 2006 A1
20060213218 Uno et al. Sep 2006 A1
20060225421 Yamanaka et al. Oct 2006 A1
20060225459 Meyer Oct 2006 A1
20060249020 Tonkovich et al. Nov 2006 A1
20060254281 Badeer et al. Nov 2006 A1
20070001766 Ripley et al. Jan 2007 A1
20070017192 Bednarek et al. Jan 2007 A1
20070019708 Shiflett et al. Jan 2007 A1
20070027038 Kamimura et al. Feb 2007 A1
20070056290 Dahm Mar 2007 A1
20070089449 Gurin Apr 2007 A1
20070108200 McKinzie, II May 2007 A1
20070119175 Ruggieri et al. May 2007 A1
20070130952 Copen Jun 2007 A1
20070151244 Gurin Jul 2007 A1
20070161095 Gurin Jul 2007 A1
20070163261 Strathman Jul 2007 A1
20070195152 Kawai et al. Aug 2007 A1
20070204620 Pronske et al. Sep 2007 A1
20070227472 Takeuchi et al. Oct 2007 A1
20070234722 Kalina Oct 2007 A1
20070245733 Pierson et al. Oct 2007 A1
20070246206 Gong et al. Oct 2007 A1
20080000225 Kalina Jan 2008 A1
20080006040 Peterson et al. Jan 2008 A1
20080010967 Griffin et al. Jan 2008 A1
20080023666 Gurin Jan 2008 A1
20080053095 Kalina Mar 2008 A1
20080066470 MacKnight Mar 2008 A1
20080135253 Vinegar et al. Jun 2008 A1
20080163625 O'Brien Jul 2008 A1
20080173450 Goldberg et al. Jul 2008 A1
20080211230 Gurin Sep 2008 A1
20080250789 Myers et al. Oct 2008 A1
20080252078 Myers Oct 2008 A1
20090021251 Simon Jan 2009 A1
20090085709 Meinke Apr 2009 A1
20090107144 Moghtaderi et al. Apr 2009 A1
20090139234 Gurin Jun 2009 A1
20090139781 Straubel Jun 2009 A1
20090173337 Tamaura et al. Jul 2009 A1
20090173486 Copeland Jul 2009 A1
20090180903 Martin et al. Jul 2009 A1
20090205892 Jensen et al. Aug 2009 A1
20090211251 Petersen et al. Aug 2009 A1
20090211253 Radcliff et al. Aug 2009 A1
20090266075 Westmeier et al. Oct 2009 A1
20090293503 Vandor Dec 2009 A1
20100024421 Litwin Feb 2010 A1
20100077792 Gurin Apr 2010 A1
20100083662 Kalina Apr 2010 A1
20100102008 Hedberg Apr 2010 A1
20100122533 Kalina May 2010 A1
20100146949 Stobart et al. Jun 2010 A1
20100146973 Kalina Jun 2010 A1
20100156112 Held et al. Jun 2010 A1
20100162721 Welch et al. Jul 2010 A1
20100205962 Kalina Aug 2010 A1
20100218513 Vaisman et al. Sep 2010 A1
20100218930 Proeschel Sep 2010 A1
20100263380 Biederman et al. Oct 2010 A1
20100287934 Glynn et al. Nov 2010 A1
20100300093 Doty Dec 2010 A1
20100326076 Ast et al. Dec 2010 A1
20110027064 Pal et al. Feb 2011 A1
20110030404 Gurin Feb 2011 A1
20110048012 Ernst et al. Mar 2011 A1
20110061384 Held et al. Mar 2011 A1
20110061387 Held et al. Mar 2011 A1
20110088399 Briesch et al. Apr 2011 A1
20110179799 Allam et al. Jul 2011 A1
20110185729 Held Aug 2011 A1
20110192163 Kasuya Aug 2011 A1
20110203278 Kopecek et al. Aug 2011 A1
20110259010 Bronicki et al. Oct 2011 A1
20110299972 Morris Dec 2011 A1
20110308253 Ritter Dec 2011 A1
20120047892 Held et al. Mar 2012 A1
20120067055 Held Mar 2012 A1
20120128463 Held May 2012 A1
20120131918 Held May 2012 A1
20120131919 Held May 2012 A1
20120131920 Held May 2012 A1
20120131921 Held May 2012 A1
20120159922 Gurin Jun 2012 A1
20120159956 Gurin Jun 2012 A1
20120174558 Gurin Jul 2012 A1
20120186219 Gurin Jul 2012 A1
20120247134 Gurin Oct 2012 A1
20120247455 Gurin et al. Oct 2012 A1
20120261090 Durmaz et al. Oct 2012 A1
20130019597 Kalina Jan 2013 A1
20130033037 Held et al. Feb 2013 A1
20130036736 Hart et al. Feb 2013 A1
20130113221 Held May 2013 A1
Foreign Referenced Citations (91)
Number Date Country
2794150 Nov 2011 CA
1165238 Nov 1997 CN
1432102 Jul 2003 CN
101614139 Dec 2009 CN
202055876 Nov 2011 CN
202544943 Nov 2012 CN
202718721 Feb 2013 CN
2632777 Feb 1977 DE
19906087 Aug 2000 DE
10052993 May 2002 DE
1977174 Oct 2008 EP
1998013 Dec 2008 EP
2419621 Feb 2012 EP
2446122 May 2012 EP
2478201 Jul 2012 EP
2500530 Sep 2012 EP
2550436 Jan 2013 EP
856985 Dec 1960 GB
2010974 Jul 1979 GB
2075608 Nov 1981 GB
58-193051 Nov 1983 JP
60-040707 Mar 1985 JP
61-152914 Jul 1986 JP
01-240705 Sep 1989 JP
05-321612 Dec 1993 JP
06-331225 Nov 1994 JP
08-028805 Feb 1996 JP
09-100702 Apr 1997 JP
2641581 May 1997 JP
09-209716 Aug 1997 JP
2858750 Dec 1998 JP
H11-270352 May 1999 JP
2000-257407 Sep 2000 JP
2001-193419 Jul 2001 JP
2002-097965 Apr 2002 JP
2003-529715 Oct 2003 JP
2004-239250 Aug 2004 JP
2004-332626 Nov 2004 JP
2005-030727 Feb 2005 JP
2005-533972 Nov 2005 JP
2006-037760 Feb 2006 JP
2006-177266 Jul 2006 JP
2007-198200 Sep 2007 JP
4343738 Oct 2009 JP
2011-017268 Jan 2011 JP
10-0191080 Jun 1999 KR
10-20070086244 Aug 2007 KR
10-0766101 Oct 2007 KR
10-0844634 Jul 2008 KR
10-20100067927 Jun 2010 KR
10-20110018769 Feb 2011 KR
1069914 Sep 2011 KR
1103549 Jan 2012 KR
10-20120058582 Jun 2012 KR
2012-0068670 Jun 2012 KR
2012-0128753 Nov 2012 KR
2012-0128755 Nov 2012 KR
91-05145 Apr 1991 WO
96-09500 Mar 1996 WO
00-71944 Nov 2000 WO
01-44658 Jun 2001 WO
2006-060253 Jun 2006 WO
2006-137957 Dec 2006 WO
2007-056241 May 2007 WO
2007-079245 Jul 2007 WO
2007-082103 Jul 2007 WO
2007-112090 Oct 2007 WO
2008-039725 Apr 2008 WO
2008-101711 Aug 2008 WO
2009-045196 Apr 2009 WO
2009-058992 May 2009 WO
2010-074173 Jul 2010 WO
2010-083198 Jul 2010 WO
2010-121255 Oct 2010 WO
2010-126980 Nov 2010 WO
2010-151560 Dec 2010 WO
2011-017450 Feb 2011 WO
2011-017476 Feb 2011 WO
2011-017599 Feb 2011 WO
2011-034984 Mar 2011 WO
2011-094294 Aug 2011 WO
2011-119650 Sep 2011 WO
2012-074905 Jun 2012 WO
2012-074907 Jun 2012 WO
2012-074911 Jun 2012 WO
2012-074940 Jun 2012 WO
2013-055391 Apr 2013 WO
2013-059687 Apr 2013 WO
2013-059695 Apr 2013 WO
2013-070249 May 2013 WO
2013-074907 May 2013 WO
Non-Patent Literature Citations (89)
Entry
PCT/US2010/044681—International Search Report and Written Opinion dated Oct. 7, 2010, 10 pages.
PCT/US2010/044681—International Preliminary Report on Patentability dated Feb. 16, 2012, 9 pages.
PCT/US2010/049042—International Search Report and Written Opinion dated Nov. 17, 2010, 11 pages.
PCT/US2010/049042—International Preliminary Report on Patentability dated Mar. 29, 2012, 18 pages.
PCT/US2011/029486—International Preliminary Report on Patentability dated Sep. 25, 2012, 6 pages.
PCT/US2011/029486—International Search Report and Written Opinion dated Nov. 16, 2011, 9 pages.
PCT/US2011/062266—International Search Report and Written Opinion dated Jul. 9, 2012, 12 pages.
PCT/US2011/062198—International Search Report and Written Opinion dated Jul. 2, 2012, 9 pages.
PCT/US2011/062198—Extended European Search Report dated May 6, 2014, 9 pages.
PCT/US2011/062201—International Search Report and Written Opinion dated Jun. 26, 2012, 9 pages.
PCT/US2011/062201—Extended European Search Report dated May 28, 2014, 8 pages.
PCT/US2011/062204—International Search Report dated Nov. 1, 2012, 10 pages.
PCT/US2011/62207—International Search Report and Written Opinion dated Jun. 28, 2012, 7 pages.
PCT/US2012/000470—International Search Report dated Mar. 8, 2013, 10 pages.
PCT/US2012/061151—International Search Report and Written Opinion dated Feb. 25, 2013, 9 pages.
PCT/US2012/061159—International Search Report dated Mar. 2, 2013, 10 pages.
PCT/US2013/055547—Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration dated Jan. 24, 2014, 11 pages.
PCT/US2013/064470—Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration dated Jan. 22, 2014, 10 pages.
PCT/US2013/064471—Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration dated Jan. 24, 2014, 10 pages.
PCT/US2014/013154—International Search Report dated May 23, 2014, 4 pages.
PCT/US2014/013170—Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration, dated May 9, 2014, 12 pages.
PCT/US2014/023026—Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration dated Jul. 22, 2014, 11 pages.
PCT/US2014/023990—Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration dated Jul. 17, 2014, 10 pages.
PCT/US2014/026173—Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration dated Jul. 9, 2014, 10 pages.
Persichilli, Michael, et al., “Supercritical CO2 Power Cycle Developments and Commercialization: Why SCO2 can Displace Steam”, Echogen Power Systems, LLC, Power-Gen India & Central Asia 2012, Apr. 19-21, 2012, New Delhi, India, 15 pages.
Renz, Manfred, “The New Generation Kalina Cycle”, Contribution to the Conference: Electricity Generation from Enhanced Geothermal Systems, Sep. 14, 2006, Strasbourg, France, 18 pages.
Saari, Henry, et al., “Supercritical CO2 Advanced Brayton Cycle Design”, Presentation, Carleton University, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 21 pages.
San Andres, Luis, “Start-Up Response of Fluid Film Lubricated Cryogenic Turbopumps (Preprint)”, AIAA/ASME/SAE/ASEE Joint Propulsion Conference, Cincinnati, OH, Jul. 8-11, 2007, 38 pages.
Sarkar, J. and Bhattacharyya, Souvik, “Optimization of Recompression S-CO2 Power Cycle with Reheating”, Energy Conversion and Management 50, May 17, 2009, pp. 1939-1945.
Thorin, Eva, “Power Cycles with Ammonia-Water Mixtures as Working Fluid”, Doctoral Thesis, Department of Chemical Engineering and Technology Energy Processes, Royal Institute of Technology, Stockholm, Sweden, 2000, 66 pages.
Tom, Samsun Kwok Sun, “The Feasibility of Using Supercritical Carbon Dioxide as a Coolant for the Candu Reactor”, The University of British Columbia, Jan. 1978, 156 pages.
VGB Powertech Service Gmbh, “CO2 Capture and Storage”, A VGB Report on the State of the Art, Aug. 25, 2004, 112 pages.
Vidhi, Rachana, et al., “Study of Supercritical Carbon Dioxide Power Cycle for Power Conversion from Low Grade Heat Sources”, Presentation, University of South Florida and Oak Ridge National Laboratory, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 17 pages.
Vidhi, Rachana, et al., “Study of Supercritical Carbon Dioxide Power Cycle for Power Conversion from Low Grade Heat Sources”, Paper, University of South Florida and Oak Ridge National Laboratory, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 8 pages.
Wright, Steven A., et al., “Modeling and Experimental Results for Condensing Supercritical CO2 Power Cycles”, Sandia Report, Jan. 2011, 47 pages.
Wright, Steven A., et al., “Supercritical CO2 Power Cycle Development Summary at Sandia National Laboratories”, May 24-25, 2011, 1 page, (Abstract Only).
Wright, Steven, “Mighty Mite”, Mechanical Engineering, Jan. 2012, pp. 41-43.
Yoon, Ho Joon, et al., “Preliminary Results of Optimal Pressure Ratio for Supercritical CO2 Brayton Cycle Coupled with Small Modular Water Cooled Reactor”, Presentation, Korea Advanced Institute of Science and Technology and Khalifa University of Science, Technology and Research, Boulder, CO, May 25, 2011, 18 pages.
Yoon, Ho Joon, et al., “Preliminary Results of Optimal Pressure Ratio for Supercritical CO2 Brayton Cycle Coupled with Small Modular Water Cooled Reactor”, Paper, Korea Advanced Institute of Science and Technology and Khalifa University of Science, Technology and Research, May 24-25, 2011, Boulder, CO, 7 pages.
Alpy, N., et al., “French Atomic Energy Commission views as regards to SCO2 Cycle Development priorities and related R&D approach”, Presentation, Symposium on SCO2 Power Cycles, Apr. 29-30, 2009, Troy, NY, 20 pages.
Angelino, G. and Invernizzi, C.M., “Carbon Dioxide Power Cycles using Liquid Natural Gas as Heat Sink”, Applied Thermal Engineering, Mar. 3, 2009, 43 pages.
Bryant, John C., Saari, Henry, and Zanganeh, Kourosh, “An Analysis and Comparison of the Simple and Recompression Supercritical CO2 Cycles”, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 8 pages.
Chapman, Daniel J., Arias, Diego A., “An Assessment of the Supercritical Carbon Dioxide Cycle for Use in a Solar Parabolic Trough Power Plant”, Presentation, Abengoa Solar, Apr. 29-30, 2009, Troy, NY, 20 pages.
Chapman, Daniel J., Arias, Diego A., “An Assessment of the Supercritical Carbon Dioxide Cycle for Use in a Solar Parabolic Trough Power Plant”, Paper, Abengoa Solar, Apr. 29-30, 2009, Troy, NY, 5 pages.
Chen, Yang, Lundqvist, P., Johansson, A., Platell, P., “A Comparative Study of the Carbon Dioxide Transcritical Power Cycle Compared with an Organic Rankine Cycle with R123 as Working Fluid in Waste Heat Recovery”, Science Direct, Applied Thermal Engineering, Jun. 12, 2006, 6 pages.
Chen, Yang, “Thermodynamic Cycles Using Carbon Dioxide as Working Fluid”, Doctoral Thesis, School of Industrial Engineering and Management, Stockholm, Oct. 2011, 150 pages, (3 parts).
Chinese Search Report for Application No. 201080035382.1, 2 pages.
Chinese Search Report for Application No. 201080050795.7, 2 pages.
Chordia, Lalit, “Optimizing Equipment for Supercritical Applications”, Thar Energy LLC, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 7 pages.
Combs, Osie V., “An Investigation of the Supercritical CO2 Cycle (Feher cycle) for Shipboard Application”, Massachusetts Institute of Technology, May 1977, 290 pages.
Di Bella, Francis A., “A Gas Turbine Engine Exhaust Waste Heat Recovery Navy Shipboard Module Development”, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 8 pages.
Dostal, V., et al., “A Supercritical Carbon Dioxide Cycle for Next Generation Nuclear Reactors”, Mar. 10, 2004, 326 pages, (7 parts).
Dostal, Vaclav and Kulhanek, Martin, “Research on the Supercritical Carbon Dioxide Cycles in the Czech Republic”, Czech Technical University in Prague, Symposium on SCO2 Power Cycles, Apr. 29-30, Troy, NY, 8 pages.
Dostal, Vaclav, and Dostal, Jan, “Supercritical CO2 Regeneration Bypass Cycle—Comparison to Traditional Layouts”, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 5 pages.
Eisemann, Kevin, and Fuller, Robert L., “Supercritical CO2 Brayton Cycle Design and System Start-up Options”, Barber Nichols, Inc., Paper, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 7 pages.
Eisemann, Kevin, and Fuller, Robert L., “Supercritical CO2 Brayton Cycle Design and System Start-up Options”, Presentation, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 11 pages.
Feher, E.G., et al. “Investigation of Supercritical (Feher) Cycle”, Astropower Laboratory, Missile & Space Systems Division, Oct. 1968, 152 pages.
Fuller, Robert L. and Eisemann, Kevin, “Centrifugal Compressor Off-Design Performance for Super-Critical CO2”, Barber Nichols, Inc. Presentation, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 20 pages.
Fuller, Robert L. and Eisemann, Kevin, “Centrifugal Compressor Off-Design Performance for Super-Critical CO2”, Paper, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 12 pages.
Gokhstein, D.P. and Verkhivker, G.P., “Use of Carbon Dioxide as a Heat Carrier and Working Substance in Atomic Power Stations”, Soviet Atomic Energy, Apr. 1969, vol. 26, Issue 4, pp. 430-432.
Gokhstein, D.P., Taubman, E.I., Konyaeva, G.P., “Thermodynamic Cycles of Carbon Dioxide Plant with an Additional Turbine After the Regenerator”, Energy Citations Database, Mar. 1973, 1 page, Abstract only.
Hejzlar, R, et al., “Assessment of Gas Cooled Gas Reactor with Indirect Supercritical CO2 Cycle”, Massachusetts Institute of Technology, Jan. 2006, 10 pages.
Hoffman, John R. and Feher, E.G., “150 kwe Supercritical Closed Cycle System”, Transactions of the ASME, Jan. 1971, pp. 70-80.
Jeong, Woo Seok, et al., “Performance of S-CO2 Brayton Cycle with Additive Gases for SFR Application”, Korea Advanced Institute of Science and Technology, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 5 pages.
Johnson, Gregory A. & McDowell, Michael, “Issues Associated with Coupling Supercritical CO2 Power Cycles to Nuclear, Solar and Fossil Fuel Heat Sources”, Hamilton Sundstrand, Energy Space & Defense-Rocketdyne, Apr. 29-30, 2009, Troy, NY, Presentation, 18 pages.
Kawakubo, Tomoki, “Unsteady Roto-Stator Interaction of a Radial-Inflow Turbine with Variable Nozzle Vanes”, ASME Turbo Expo 2010: Power for Land, Sea, and Air; vol. 7: Turbomachinery, Parts A, B, and C; Glasgow, UK, Jun. 14-18, 2010, Paper No. GT2010-23677, pp. 2075-2084, 1 page, (Abstract only).
Kulhanek, Martin, “Thermodynamic Analysis and Comparison of S-CO2 Cycles”, Presentation, Czech Technical University in Prague, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 14 pages.
Kulhanek, Martin, “Thermodynamic Analysis and Comparison of S-CO2 Cycles”, Paper, Czech Technical University in Prague, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 7 pages.
Kulhanek, Martin and Dostal, Vaclav, “Supercritical Carbon Dioxide Cycles Thermodynamic Analysis and Comparison”, Abstract, Faculty Conference held in Prague, Mar. 24, 2009, 13 pages.
Ma, Zhiwen and Turchi, Craig S., “Advanced Supercritical Carbon Dioxide Power Cycle Configurations for Use in Concentrating Solar Power Systems”, National Renewable Energy Laboratory, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 4 pages.
Moisseytsev, Anton and Sienicki, Jim, “Investigation of Alternative Layouts for the Supercritical Carbon Dioxide Brayton Cycle for a Sodium-Cooled Fast Reactor”, Supercritical CO2 Power Cycle Symposium, Troy, NY, Apr. 29, 2009, 26 pages.
Munoz De Escalona, Jose M., “The Potential of the Supercritical Carbon Dioxide Cycle in High Temperature Fuel Cell Hybrid Systems”, Paper, Thermal Power Group, University of Seville, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 6 pages.
Munoz De Escalona, Jose M., et al., “The Potential of the Supercritical Carbon Dioxide Cycle in High Temperature Fuel Cell Hybrid Systems”, Presentation, Thermal Power Group, University of Seville, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 19 pages.
Muto, Y., et al., “Application of Supercritical CO2 Gas Turbine for the Fossil Fired Thermal Plant”, Journal of Energy and Power Engineering, Sep. 30, 2010, vol. 4, No. 9, 9 pages.
Muto, Yasushi and Kato, Yasuyoshi, “Optimal Cycle Scheme of Direct Cycle Supercritical CO2 Gas Turbine for Nuclear Power Generation Systems”, International Conference on Power Engineering-2007, Oct. 23-27, 2007, Hangzhou, China, pp. 86-87.
Noriega, Bahamonde J.S., “Design Method for S-CO2 Gas Turbine Power Plants”, Master of Science Thesis, Delft University of Technology, Oct. 2012, 122 pages, (3 parts).
Oh, Chang, et al., “Development of a Supercritical Carbon Dioxide Brayton Cycle: Improving PBR Efficiency and Testing Material Compatibility”, Presentation, Nuclear Energy Initiative Report, Oct. 2004, 38 pages.
Oh, Chang, et al., “Development of a Supercritical Carbon Dioxide Brayton Cycle: Improving VHTR Efficiency and Testing Material Compatibility”, Presentation, Nuclear Energy Research Initiative Report, Final Report, Mar. 2006, 97 pages.
Parma, Ed, et al., “Supercritical CO2 Direct Cycle Gas Fast Reactor (SC-GFR) Concept”, Presentation for Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 40 pages.
Parma, Ed, et al., “Supercritical CO2 Direct Cycle Gas Fast Reactor (SC-GFR) Concept”, Supercritical CO2 Power Cycle Symposium, May 24-25, 2011, Boulder, CO, 9 pages.
Parma, Edward J., et al., “Supercritical CO2 Direct Cycle Gas Fast Reactor (SC-GFR) Concept”, Presentation, Sandia National Laboratories, May 2011, 55 pages.
PCT/US2006/049623—Written Opinion of ISA dated Jan. 4, 2008, 4 pages.
PCT/US2007/001120—International Search Report dated Apr. 25, 2008, 7 pages.
PCT/US2007/079318—International Preliminary Report on Patentability dated Jul. 7, 2008, 5 pages.
PCT/US2010/0131614—International Search Report dated Jul. 12, 2010, 3 pages.
PCT/US2010/031614—International Preliminary Report on Patentability dated Oct. 27, 2011, 9 pages.
PCT/US2010/039559—International Preliminary Report on Patentability dated Jan. 12, 2012, 7 pages.
PCT/US2010/039559—Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration dated Sep. 1, 2010, 6 pages.
PCT/US2010/044476—International Search Report dated Sep. 29, 2010, 23 pages.
Related Publications (1)
Number Date Country
20140096521 A1 Apr 2014 US
Provisional Applications (1)
Number Date Country
61417789 Nov 2010 US
Continuations (1)
Number Date Country
Parent 13205082 Aug 2011 US
Child 14102677 US