This invention relates to an apertured film for use as a topsheet in an absorbent article. Examples of absorbent articles include diapers, incontinent articles, sanitary napkins, and similar articles.
Referring now to
Referring now to
As shown in
The absorbent article 10 has two surfaces, a body-contacting surface or body surface 18 and a garment-contacting surface or garment surface 20. The body surface 18 is intended to be worn adjacent to the body of the wearer. The garment surface 20 of the absorbent article 10 is on the opposite side and is intended to be placed adjacent to the wearer's undergarments or clothing when the absorbent article 10 is worn.
The apertured film of the present invention for use as a topsheet of the absorbent article 10 will now be looked at in greater detail. Throughout the remainder of this application, similar components will share the same numbers for all embodiments of the invention, e.g., “topsheet” will be designated by the numeral 12 in each embodiment.
In a preferred embodiment, the apertured continuous layer 22 is imparted with a repeating pattern. Although a hexagonal pattern is used for purposes of illustration in
As seen more clearly in
Extending upward from the female side 62 of the apertured continuous layer 22 are raised lanes of thermoplastic material 32. These raised lanes 32 come in contact with the skin of the wearer of the absorbent article 10. The raised lanes 32 preferably run substantially parallel to the longitudinal centerline 23 (
As can be seen in
Preferably, the apertured continuous layer 22 is a perforated thermoplastic film with tapered drains 66 which have a run off percent of less than about 10 percent and which has an increased liquid flow rate through the tapered drains 66. Any thermoplastic material which may be formed into flexible films or sheets may be used in the production of the novel topsheets of the present invention.
Exemplary thermoplastic materials include cellulose esters, nylons and mixed polyamides, polyvinyl alcohol, polyvinyl chloride, polyvinyl acetates, polymethyl methacrylate, polyethylene, polypropylene, blends or copolymer polyolefins, polyesters, polyurethanes, polyethers, polyimides, polyurethanes, polylactic acid, polyacrylic acid, polymethacrylatic acid, polyacrylamide, polyethyleneimine, polyethylene oxide, polystyrene sufonate, and polyethylene glycol and ionomers like SURLYN® which may be formed into flexible film or sheet. Particularly preferred perforated films are polyethylene and polypropylene. One preferred suitable material is a low density polyethylene film. Sheets or film made from such materials may be plasticized with suitable plasticizers and other additives known in the art may be added to achieve the desired physical characteristics.
When using a hydrophobic thermoplastic material such as a polyolefin resin to form the apertured continuous layer 22, the continuous layer must be treated so that at least the female side 62 is hydrophilic. For example, a surfactant can be mixed or blended with the resin prior to the layer being formed from the resin. The surfactant provides a surface which has greater polarity than the polyolefin layer would have without the surfactant being added. Higher surface polarity yields higher wettability.
As used herein, the term “hydrophilic” is used to refer to surfaces that are wettable by aqueous fluids (e.g., aqueous body fluids) deposited thereon. Hydrophilicity and wettability are typically defined in terms of contact angle and the surface tension of the fluids and solid surfaces involved. A surface is said to be wetted by an aqueous fluid (hydrophilic) when the fluid tends to spread spontaneously across the surface. Conversely, a surface is considered to be “hydrophobic” if the aqueous fluid does not tend to spread spontaneously across the surface.
In a preferred embodiment, the surfactant is a non-migrating surfactant. Surfactants typically have a molecular weight of 150 to 300 and contain a hydrophilic end (head) which includes a cationic, anionic or nonionic polar group and a hydrophobic end (tail) usually consisting of one or two aliphatic chains. These surfactants migrate to the film surface where they readily dissolve in aqueous fluid that comes in contact with the film surface. These migrating surfactants lower the surface tension of the fluid to a level less than or equal to that of the film surface energy which results in wetting of the film surface. Because these migrating surfactants dissolve into the aqueous fluid they can be washed from the surface which may change the wetting behavior of the film with multiple insults. Conversely, non-migrating surfactants are usually much larger molecules than typical surfactants and are unable to migrate through the film to any significant degree. The non-migrating surfactants, instead, arrange themselves at the surface of the film to concentrate their polar groups (hydrophilic head) as the top most surface of the film thereby giving the film a much higher surface energy and promoting the wetting by aqueous fluids. Typically, non-migrating surfactants are more permanent and durable over multiple insults. By using a non-migrating surfactant, the surfactant is unlikely to be transferred to the raised lanes 32 when the apertured film 12 is rolled for storage thus preserving the hydrophobicity and dry feel of the raised lanes 32.
Potentially useful non-migrating surfactants may include low molecular weight polyvinyl alcohol, poly acrylic acid, polyethylene oxide, poly methacrylic acid, polyethylene glycol, polyacrylamide, polystyrene sulfonate and ionomers, oligomers of polyethoxy alkanes, and high molecular weight (>450) anionic, cationic, or nonionic surfactants. Particularly preferred non-migrating surfactants are oligomeric ethoxylates such as UNITHOX® 450 from Baker Petrolite.
The raised lanes 32 of the apertured film 12 are preferably made of a hydrophobic thermoplastic material. Exemplary thermoplastic materials include cellulose esters, polyvinyl chloride, polyvinyl acetate, polymethyl methacrylate, polyethylene, polypropylene, blends and copolymers of polyolefins, polyesters, polyimides, and polyurethanes which may be formed into lanes. Particularly preferred thermoplastic materials are polyethylene and polypropylene.
The raised lanes are applied such that the distance from the female side 62 of the apertured continuous layer 22 to the upper surface of the raised lanes 32 is preferably about 25 microns to about 100 microns. As will be understood by those of skill in the art, the height of the raised lanes will be determined by balancing aesthetic, tactile, and functional considerations. In any event, the raised lanes 32 should be of a height to substantially help prevent the contact of the wearer's skin with the hydrophilic surface of the apertured continuous layer 22. The number of raised lanes 32 and the thickness of the raised lanes 32 is determined so that the wearer's skin does not come in contact with the female side 62 of the apertured continuous layer 22 while still allowing the topsheet 12 to rapidly transmit fluid. Preferably the number of raised lanes 32 and the thickness of the raised lanes 32 is such that the upper surface of the raised lanes 32 cover about 5% to about 60%, more preferably about 10% to about 45%, and most preferably about 15% to about 35%, of the female side 62 of the continuous layer 22.
Alternatively or additionally, a surface treatment can be applied to the upper surface of the raised lanes 32 to make them more hydrophobic. A suitable surface treatment is a silicone release coating or a UV curable silicone. Other suitable treatment materials include, but are not limited to, fluorinated materials such as fluoropolymers (e.g., polytetrafluoroethylene (PTFE), commercially available under the trade name TEFLON®) and chlorofluoropolymers. Other materials which may prove suitable include hydrocarbons such as petrolatum, latexes, paraffins. Silicone materials are presently preferred for use in the absorbent article context for their biocompatibility properties because they have a low affinity for biological materials such as gluco-proteins, blood platelets, and the like. As such, silicone materials tend to resist deposition of biological matter to a greater extent than other materials under in-use conditions. This property enables them to better retain their hydrophobicity as needed for subsequent fluid insults.
In a preferred embodiment, microstructures may be imparted on the raised lanes 32 to improve the tactile impression of the topsheet 12. Referring to
Referring now to
As seen in
In a preferred embodiment, the raised lanes 32 are applied to the raised ridges 78 such that the distance from the female side 62 of the apertured continuous layer 22 to the upper surface of the raised lanes 32 is preferably about 25 microns to about 100 microns. The number, height, and thickness of the raised ridges 78 in conjunction with the raised lanes 32 are the same as discussed above with respect to
The topsheet 12 of
The thermoplastic materials for use in forming the apertured continuous layer 22 and raised lanes 32 for this embodiment are the same as discussed above. As in the first embodiment, if a hydrophobic thermoplastic material such as a polyolefin resin is used to form the apertured continuous layer 22, then the film must be treated so that at least the female side 62 is hydrophilic. The same methods, as discussed above, may be employed.
Another aspect of the present invention relates to a method for making an apertured film for use as a topsheet for an absorbent article. Accordingly, an embodiment of the invention is a method for making an apertured film for use as a topsheet for an absorbent article, comprising (a) extruding a flat continuous layer of a polymer melt having an upper and lower surface onto a screen assembly; (b) coextruding lanes of a hydrophobic polymer melt having a top surface onto the upper surface of the continuous layer; (c) applying a pressure differential across the screen assembly to form apertures in the continuous layer, wherein the upper surface of the continuous layer is hydrophilic.
In a preferred embodiment a cast coextrusion process is used. In a cast coextrusion process, lanes of a hydrophobic thermoplastic material are extruded through notched zone portals above a flat continuous layer extruded from a slot die. The lanes and flat continuous layer may be extruded from the same die or separate dies used in close proximity to one another. As used herein, the terms “coextrusion” or “coextruding” refers to extruding two or more layers or lanes of thermoplastic material from either a single die or multiple dies used in close proximity to one another.
The lanes and flat continuous layer anneal together as they are subsequently cooled and set by a variety of chilling roller means. In a further embodiment, additional flat continuous layers are extruded between the first continuous layer and the raised lanes, wherein the upper most continuous layer is hydrophilic.
In a preferred embodiment, the topsheet 12 is formed in a direct melt vacuum formed film (VFF) process. In a vacuum formed film process, a pressure differential is applied across a forming screen. In the case of a direct melt VFF process, a molten web is extruded onto a forming area of a forming screen. Alternatively, the web may be reheated and partially melted while the web is over the forming area of the forming screen as taught in U.S. Pat. No. 4,151,240. A melted polymer is desirable to form three-dimensional apertures since a melted polymer is more easily pulled into the apertures in a forming screen. Preferably, the apertures of the forming screen are spaced so as not to create apertures in the raised lanes 32 of the topsheet 12. Both U.S. Pat. Nos. 4,456,570 and 4,151,240 teach primarily using a vacuum to change a two dimensional web into a three-dimensional cell structure and to create apertures in the film. During the formation of a VFF, the polymer of the film typically undergoes a phase change from molten state in a flat form to a crystalline state in the new three dimensional form.
In a preferred embodiment, the screen assembly is able to form the raised ridges 78 (
The wire-like members may be a continuous wire that is wrapped in a spiral fashion from end to end of the screen assembly with a desired setting of space between the spirals. In a preferred embodiment for use in the present invention, a plurality of individual wires or rings are used and slid over the screen assembly into a desired spatial relationship. Preferably, the wire-like members are spaced so that they are in registration with the raised lanes 32 of the present invention. A variety of metals can be utilized for the wire-like members. For example, nickel, copper, aluminum, stainless steel, carbon steel, brass, bronze, and others are appropriate. It is preferable to match the thermal expansion of the wire metal with that of the base screen.
In addition to metal wires, wires of other materials may be used. An example of another material that may be used is a high temperature engineering polymer material such as polyamide-imide, polyester, polyetheretherketone, polyacetal, polyetherimide, polyethersulfone, polyphenylenesulfide, or polytetrafluoroethylene. Regardless of the material selected for the wire-like member, it is necessary that its softening temperature exceeds the temperature of the molten resin being extruded onto the screen assembly.
In a further embodiment, the method further comprises forming microstructures on the upper surface of the lanes of hydrophobic polymer. Any known method for imparting such microstructures may be used including the use of a microtextured screen or by cloth embossing.
In practice, the apertured film 12 may be used as a topsheet in an absorbent article 10. Absorbent article 10 is used for applications where fluid absorption is desirable. In use, body exudates, such as urine, are deposited on the absorbent article 10. As the urine contacts the hydrophobic raised lanes 32, it will run-off the lanes and be drawn toward the hydrophilic surface of the apertured continuous layer and through the topsheet to the absorbent core 16. Any residual fluid that remains on the female side or body side 62 of the apertured continuous layer 22 is unlikely to come in contact with the wearer's skin because the raised lanes 32 substantially help prevent the skin from contacting the apertured continuous layer 22. As an additional benefit, the space created between the wearer's skin and the body side 62 of the apertured continuous layer allows air to flow which can aid in the drying of the topsheet 12.
As each urine insult is typically delivered to the same spot on the absorbent article, upon repeated insults, an undesirable leakage or undesirable feeling of wetness by the wearer may occur due to the core material 16 becoming saturated in the repeat insult region. In other words, the absorbent core 16 may experience an inability to absorb repeated insults in a particular region. As a result, additional fluid insults that are delivered to the absorbent article 10 may be unabsorbed by the core 16 and remain on the upper or body-facing side 17 of the core layer 16. In addition to providing a dry top, applicant's topsheet 12 provides a way for the unabsorbed fluid from the core layer 16 to be directed to unsaturated zones of the core layer 16.
For example, when the topsheet 12 of
A further advantage of the raised lanes 32, independent of or in conjunction with the raised ridges 78, is that the raised lanes 32 direct unabsorbed fluids in a desired direction, such as in the longitudinal direction, i.e., parallel to longitudinal centerline 23 of disposable diaper 10 (
Additionally, various embodiments of applicant's topsheet 12 can be combined with acquisition distribution layers to provide a further enlarged void volume space to accommodate unabsorbed fluids. Referring to
While certain of the preferred embodiments of the present invention have been described and specifically exemplified above, it is not intended that the invention be limited to such embodiments. Various modifications may be made thereto without departing from the scope and spirit of the present invention, as set forth in the following claims.