Patent Application
20100212180
The present invention relates to a process for reducing water content in wood material. The present invention also relates to wood material drying means to be used in the process.
In connection with the desire to limit the use of poisonous impregnation chemicals for the impregnation of wood for i.a. outdoor use, new products containing 30-70% of thermoplastic has been developed, so called bio-composites. These bio-composites put a very much less environmental stress on its surrounding are thus regarded as a more feasible material in terms of their life cycle.
By mixing almost completely dry wood particles, having a moisture content of less than 0.5%, with a thermoplastic into granules, a board can be extruded in a machine, or moulded just like PVC or any other plastic. This way different profiles, even with hollow sections, may be produced and used for i.a. window and door frames. The bio-composites do not absorb water and therefore swelling and shrinking does not take place as it does with normal wood. The boards may be used also for building dams or in direct contact with the ground where the board is also in direct contact with water. Other shapes and designs of the bio-composite may be achieved, or other manners of production may be utilised.
One of the problems producing bio-composite products is to find an economical process for drying the wood particles to less than 0.5% moisture content. Normal wood, when recently taken out of the forest, may have a moisture content of between 60 and 30% based on weight, and this amount of water is very energy consuming to remove. Conventional dryers use hot air or flue gas for their heating and are very energy consuming. Another problem when drying wood, and especially when drying it to such low moisture contents as is the case here, is that there is a not negligible risk for fire or for dust explosions. At least for the wood material normally get charred. The very high temperatures that are required to achieve the high dryness of more than 99.5% of the wood raw material induces these risks. Not only is it a risk for loosing a batch of raw material, but it is also a risk for the apparatus and operators.
When drying the wood raw material, not only evaporation of water but also volatile hydrocarbons, terpenes, will be released and found in the exhaust gases from the dryer installation. These volatiles are found naturally in the wood raw material and are vaporised due to the high temperatures in the drying process. Not only do they represent a risk of explosions as discussed above, but these volatiles reacts photo-chemically with nitrogen oxides which exist naturally in the air. Thereby they form ground level ozone O3 which is unhealthy to humans, animals and plants. This way the environmentally friendliness of the bio-composites is reduced.
It is thus an object of the present invention to design a wood drying apparatus which at least partly overcomes the above-mentioned problems and which increases the environmentally friendliness of the bio-composites thus produced.
The problem discussed above has been at least partly solved by the present invention. According to a first aspect of the present invention a process for reducing water content in wood material is disclosed, which process comprises the steps of:
In this way an environmentally friendly process of drying wood material, especially wood materials for bio-composites, is disclosed. The combination of drying in an atmosphere of overheated vapour, but yet oxygen free, leads to the possibility to remove so much water from the wet wood material that the moisture content may be lowered below 10%. This is necessary when using the wood material in the production of bio-composites.
It is advantageous to let the step of discharging the dried wood material not to be performed until the wood material has reached a moisture content of preferably less than 5%, more preferably less than 1%, most preferably less than 0.5%. The more dry the wood is needed to be, the better the inventive process is for the environment, and the less risk for fire and explosions proportionately.
It is advantageous for the process to comprise the step of:
It is advantageous for the process to comprise the step of:
It is advantageous that said separation means are condensing means.
It is advantageous that the process comprises the steps of:
It is advantageous that the process comprises the step of:
It is advantageous that said turbine is a steam turbine.
It is advantageous that said turbine is a NH3-driven turbine.
It is advantageous that the process comprises the step of:
Such a two-step drying process reduces the amount of material to be dried in the second step, thus reducing energy consumption.
It is advantageous that the process comprises the step of:
It is advantageous that the process comprises the step of:
It is advantageous that the process comprises the step of:
It is advantageous that the below described wood material drying means are used in the present process.
According to a second aspect of the present invention wood material drying means are disclosed, comprising:
It is advantageous that the drying means comprise:
It is advantageous that said separation means are condensation means.
It is advantageous that said combustible substances are hydrocarbons (HC), such as terpenes, tars and lignin.
It is advantageous that the drying means comprise incineration means, wherein said combustible substances are recovered and incinerated in said incineration means.
It is advantageous that any heat energy from said incineration means is restored into said drying apparatus via said heating means.
It is advantageous that the drying means comprise second wood material drying means, whereby said wood material in a first step is dried to a moisture content of less than 10% in said first drying means, and said wood material in a second step is dried to a moisture content of less than 1% in said second drying means.
It is advantageous that said drying means are adapted in use to operate at a pressure between 0.5 and 4 bar.
It is advantageous that said drying means are adapted in use to operate at a vapour temperature between 110 and 400° C.
It is advantageous that said drying means are a rotary dryer, pneumatic dryer or a fluid bed dryer.
It is advantageous that said heating means are adapted in use to operate using condensing steam at 8-25 bar, cooling of flue gases or using thermal oil.
The present invention will be described in more detail using exemplary embodiments thereof which are disclosed in the accompanying drawings, in which:
Before mixing and granulation with thermo-plastic material and producing the bio-composites, wood fibres have to be almost absolutely dry with a maximum of 0.5% water content calculated by weight. It is very difficult to achieve this and the risk for fire and explosion is obvious.
The principle of the drying apparatus according to the present invention is shown in
Any type of indirectly heated drying apparatus can be used, rotary drum dryers, pneumatic dryers, fluid bed dryers etc. It is however important that the indirectly heated drying apparatus can operate without admittance of any oxygen and that it may be pressurised above normal atmospheric pressure levels. Compared to how these dryers normally operate with air or flue gas, the drying apparatus according to the present invention is closed in the way being described below. No air or flue gas is introduced since the drying apparatus operates at a pressure above atmospheric pressure. When introducing the wet wood particles, normally with 50-60% water content based on weight, water vapour is formed by evaporation. With proper feeding and discharge equipment, such as rotary valves or plug screws etc. as described above, the system will not contain any air and therefore no oxygen. The apparatus can be pressurized up to 3-5 bar (g) in order to recover heat. Since no oxygen is present, the risk for fire or dust explosions is reduced or even removed.
The principle of wood drying in overheated aqueous vapour, is that initially overheated steam—and later vapour from the wood material—is trying to become saturated with water. It thus collects water from any objects present. In this case water is collected from the wet wood material, i.e. the wet wood material that is fed into the drying apparatus. When water passes from the wood material, the temperature of the steam/vapour is simultaneously lowered. Consequently the moisture content of the wood material is reduced. Again the steam, which now thus contains vapour from the wood, needs to be overheated by the heat exchanger in order to collect more water from the wood material. The fan circulates the steam/vapour to keep the process running.
When starting up the dryer, water is sprayed into the system and with heat from the heat exchanger it will evaporate into steam. When reaching the right process parameters, pressure and temperatures, the wet material is introduced. The steam will soon be replaced by the vapours from drying the wet wood as described above. These vapours will mainly consist of water vapour but also volatiles and extractable chemical compounds present in the wood. Table 1 gives some examples of the composition of the dryer vapour from drying different species of softwood. As may be seen the vapours comprises mainly of water, but also of other substances. The volatiles are ether or benzene extractables.
Picea abies, Scandinavian spruce
Ponderosa pine
Pinus taeda, loblolly pine
The vapours are circulated by the fan and re-heated indirectly by the heat exchanger. As drying continues the pressure in the dryer will increase due to the release of water and volatiles from the wet wood material, and the excess of vapours will be purged through the pressure control valve into the condensor 2.
The generated vapours can be used for heating either the drying process self or for heating another process or be sold on the energy market. By closing the drying process, the vapours will be contained and can be used for both recovering heat, but also for collecting volatile hydrocarbons contained therein and released from the wood material in the drying process. These volatile hydrocarbons consist mainly of terpenes which are toxic and produce ozone when emitted to the atmosphere. They also contain tars and lignin from the wood. Using the process according to the present invention the terpenes (turpentine) can be used as a fuel in the process self, be used in another process or be sold on the energy market. Either way, energy is recovered and may be restored into the process self making the process less energy consuming in terms of net energy use.
The vapours are preferable extracted by condensation in said condensor 2. The vapours can also be used for power production from a condensing steam turbine or any other Rankine-cycle.
Table 2 shows the difference in gross and net heat consumption between conventional open type dryers compared to the present invention. It is noticed that the net energy consumption is reduced considerably in the process according to the embodiment of the present invention in which energy from the vapours is recovered.
Table 3 shows typical process parameters for drying wet wood material according to another embodiment of the present invention, in which two steps of drying the wet wood material is utilised. In the first step the moisture content is reduced from approximately 50% to approximately 10-15%. In the second step the moisture content is reduced from approximately 10-15% down to the wanted 0.5% using its own vapours. In between the first and the second drying step, the partly wet wood material is removed from the drying apparatus 1 and may be sieved. For instance too small and too large wood particles may be removed. They may not be wanted in the final product.
Especially for the production of bio-composites removal of unwanted wood particle-sizes is useful. Oversized (>about 3 mm) particles and dust (<about 0.5 mm) are thus removed. These dried by-products can be used and recovered as bio-fuels. Oversized particles can be used also for energy-pellet production, and the dust fraction may be used and restored as fuel for heating the dryers 1. Flue gas is generated from burning the dust in incineration means such as a dust burner, instead of, or in combination with, the use of natural gas.
In connection with condensation in the condenser 2 of the vapours, volatiles, both condensed and incondensable, can be separated from the condensed water. Condensed volatiles are insoluble in cold water and can easily be separated. In-condensable gaseous hydrocarbons are being evacuated from the condenser 2, see
Both condensed and in-condensed volatile hydrocarbons can be used as fuel and will not be emitted as hazardous gases to the atmosphere. This fuel may again be used in incineration means and the heat thereby produced may be used as heat energy in the drying apparatus.
It is obvious from the description of the present invention that not only are the risks of hazardous accidents very much reduced, but also the energy consumption for performing the drying process is considerably reduced. Furthermore, environmentally unfriendly substances are collected and not released to nature. This is emphasised when also taking into account the environmentally friendliness of the bio-composites produced by the wood dried according to the inventive process in comparison to the poisonous substances such as arsenic, copper and chrome that used to be the standard impregnation method for outdoor wood only a decade ago. Therefore a lifecycle analysis of the process and of the bio-composite thereby produced is improved in terms of their environmental load.
| Number | Date | Country | Kind |
|---|---|---|---|
| 06112331.1 | Apr 2006 | EP | regional |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2007/003057 | 4/4/2007 | WO | 00 | 10/3/2008 |
