Perforated reaction holders, also referred to as perforated flame holders, are disclosed in PCT Patent Application No. PCT/US2014/016632, entitled “FUEL COMBUSTION SYSTEM WITH A PERFORATED REACTION HOLDER,” filed Feb. 14, 2014 (Docket No. 2651-188-04); PCT Patent Application No. PCT/US2014/016626, entitled “SELECTABLE DILUTION LOW NOX BURNER,” filed Feb. 14, 2014 (Docket No. 2651-167-04); PCT Patent Application No. PCT/US2014/016628 entitled “PERFORATED FLAME HOLDER AND BURNER INCLUDING A PERFORATED FLAME HOLDER,” filed Feb. 14, 2014 (Docket No. 2651-172-04); and PCT Patent Application No. PCT/US2014/016622, entitled “STARTUP METHOD AND MECHANISM FOR A BURNER HAVING A PERFORATED FLAME HOLDER,” filed Feb. 14, 2014 (Docket No. 2651-204-04); each of which, to the extent not inconsistent with the disclosure and claims herein, is incorporated by reference in its entirety.
As described variously herein, a combustion system can benefit from utilizing a perforated reaction holder, and more particularly a perforated reaction holder having perforations configured to compensate for non-uniform velocity of a fuel and oxidant mixture received across the perforated reaction holder. Such compensation increases combustion efficiency within the perforated reaction holder.
According to an embodiment, a combustion system includes a combustion chamber, a fuel and oxidant source, and a perforated reaction holder. The fuel and oxidant source is oriented to emit fuel and oxidant into the combustion chamber. The perforated reaction holder is disposed in the combustion chamber and oriented to receive the fuel and oxidant at an input face. The perforated reaction holder defines a plurality of perforations of different sizes, where the perforations are selected arranged by size to accommodate a combustion reaction within each perforation when the fuel and oxidant are received at different velocities across a width of the perforated reaction holder.
According to an embodiment, a method of using a combustion system includes emitting fuel and oxidant from a fuel and oxidant source about a fuel and oxidant propagation axis such that an average velocity of the fuel and oxidant is higher at the fuel and oxidant propagation axis than at locations peripheral to the fuel and oxidant propagation axis. The fuel and oxidant are received at an input face of a perforated reaction holder supported in a combustion chamber, where the perforated reaction holder has a plurality of perforations disposed to extend between the input face and an output face of the perforated reaction holder. A combustion reaction is supported by the fuel and the oxidant at least partially within central perforations, of the plurality of perforations, that have a first dimension and in peripheral perforations, of the plurality of perforations, that have a second dimension different from the first dimension. The central perforations are disposed in a central region of the perforated reaction holder, which central region is aligned substantially coaxial to the fuel and oxidant propagation axis, and the peripheral perforations are disposed in a peripheral region axially peripheral to the central region. The first dimension and the second dimension of the respective central and peripheral perforations are selected to compensate for a difference in average velocity of the fuel and oxidant of the fuel and the oxidant received at the input face at the central perforations and the peripheral perforations.
In the following detailed description, reference is made to the accompanying drawings, which form a part hereof. In the drawings, similar symbols typically identify similar components, unless context dictates otherwise. The illustrative embodiments described in the detailed description, drawings, and claims are not meant to be limiting. Other embodiments may be utilized, and other changes may be made, without departing from the spirit or scope of the subject matter presented here.
According to one interpretation, higher-velocity fuel and oxidant mixture needs more heat within a given distance to ignite and combust compared to a lower-velocity fuel and oxidant. Alternatively, a greater distance at a given temperature may be required to ignite and effectively combust the higher-velocity fuel and oxidant mixture compared to the lower-velocity fuel and oxidant mixture. Accordingly, to compensate for a non-uniform mass flow velocity of fuel and oxidant across the perforated reaction holder 102, the perforated reaction holder 102 may include at least two regions of perforations: (1) a first region about the central axis 106 and having perforations of a first dimension; and (2) a second region axially peripheral to the first region and intended to receive fuel and oxidant of lower average velocity and having perforations of a second dimension that is different than the first dimension. Naturally, intermediate regions may be included to more granularly address velocity differences.
According to an interpretation, at least two variations of perforation dimension may be applied, independently or together, to permit a more uniform heating and ignition of fuel and oxidant across a perforated reaction holder, by compensating for differences in velocity of fuel and oxidant received at different regions of the perforated reaction holder. In a first variation, the different regions of the perforated reaction holder 102 may include perforations having respectively different lateral dimensions. In a second variation, the different regions of the perforated reaction holder 102 may include perforations having respectively different lengths between input and output faces of the perforated reaction holder. A combination of these perforation dimension differences may be applied to amplify the effects in a smaller volume and/or to reach greater effect than can be achieved with a dimensional difference in only one direction.
For a given perforation length, perforations in the first region may have a smaller lateral dimension than perforations in the second region in order that thermal energy from the perforation walls may heat and ignite the higher-velocity fuel and oxidant comparatively more quickly. Ideally, the lateral dimensions of the perforations are such that thermal energy provided to the fuel and oxidant corresponds to the fuel and oxidant velocity while still permitting heat energy from the combustion reaction to be sufficiently absorbed by the perforated reaction holder 102 to self-sustain the combustion reaction. If the lateral dimension of a perforation is such that thermal energy provided from the perforation walls to fuel and oxidant is too high for a given fuel and oxidant velocity, combustion may happen too quickly and the combustion reaction may produce undesired combustion products. Moreover, premature or too-fast combustion may produce much more energy than the perforation walls can thermally absorb or process, potentially damaging the structure and/or wasting the energy. Fortunately, the temperature of the perforated reaction holder 102 can be controlled by changing the rate of fuel and oxidant delivery, and thus the rate of combustion.
According to an embodiment, the perforations may not be straight, and individual perforations may not have uniform cross-sectional dimensions as they extend between the input and output surfaces of the perforated reaction holder. For example, according, to an embodiment the perforated reaction holder may be a reticulated ceramic perforated reaction holder (
Before discussing the details of specific embodiments, the following discussion related to
Experiments performed by the inventors have shown that perforated reaction holders 102 described herein can support very clean combustion. Specifically, in experimental use of systems 200 ranging from pilot scale to full scale, output of oxides of nitrogen (NOx) was measured to range from low single digit parts per million (ppm) down to undetectable (less than 1 ppm) concentration of NOx at the stack. These remarkable results were measured at 3% (dry) oxygen (O2) concentration with undetectable carbon monoxide (CO) at stack temperatures typical of industrial furnace applications (1400-1600° F.). Moreover, these results did not require any extraordinary measures such as selective catalytic reduction (SCR), selective non-catalytic reduction (SNCR), water/steam injection, external flue gas recirculation (FGR), or other heroic extremes that may be required for conventional burners to even approach such clean combustion.
According to embodiments, the burner system 200 includes a fuel and oxidant source 202 disposed to output fuel and oxidant into a combustion volume 204 to form a fuel and oxidant mixture 206. As used herein, the terms “fuel and oxidant mixture” and “fuel stream” may be used interchangeably and considered synonymous depending on the context, unless further definition is provided. As used herein, the terms combustion volume, combustion chamber, furnace volume, and the like shall be considered synonymous unless further definition is provided. The perforated reaction holder 102 is disposed in the combustion volume 204 and positioned to receive the fuel and oxidant mixture 206 across an input face 212.
The fuel can include hydrogen, a hydrocarbon gas, a vaporized hydrocarbon liquid, an atomized hydrocarbon liquid, or a powdered or pulverized solid. The fuel can be a single species or can include a mixture of gas(es), vapor(s), atomized liquid(s), and/or pulverized solid(s). For example, in a process heater application the fuel can include fuel gas or byproducts from the process that include carbon monoxide (CO), hydrogen (H2), and methane (CH4). In another application the fuel can include natural gas (mostly CH4) or propane (C3H8). In another application, the fuel can include #2 fuel oil or #6 fuel oil. Dual fuel applications and flexible fuel applications are similarly contemplated by the inventors. The oxidant can include oxygen carried by air, flue gas, and/or can include another oxidant, either pure or carried by a carrier gas. The terms oxidant and oxidizer shall be considered synonymous herein.
According to an embodiment, the perforated reaction holder body 208 may be bounded by the input face 212 disposed to receive the fuel and oxidant mixture 206, an output face 214 facing away from the fuel and oxidant source 202, and a peripheral surface 216 that defines a lateral extent of the perforated reaction holder 102. The plurality of perforations 210 which are defined by the perforated reaction holder body 208 extend from the input face 212 to the output face 214. The plurality of perforations 210 can receive the fuel and oxidant mixture 206 at the input face 212. The fuel and oxidant mixture 206 can then combust in or near the plurality of perforations 210 and combustion products can exit the plurality of perforations 210 at or near the output face 214.
According to an embodiment, the perforated reaction holder 102 is configured to hold a majority of the combustion reaction 302 within the perforations 210. For example, on a steady-state basis, more than half the molecules of fuel output into the combustion volume 204 by the fuel and oxidant source 202 may be converted to combustion products between the input face 212 and the output face 214 of the perforated reaction holder 102. According to an alternative interpretation, more than half of the heat or thermal energy output by the combustion reaction 302 may be produced between the input face 212 and the output face 214 of the perforated reaction holder 102. As used herein, the terms heat, heat energy, and thermal energy shall be considered synonymous unless further definition is provided. As used above, heat energy and thermal energy refer generally to energy, initially held in chemical form by reactants, that is released as heat during the combustion reaction 302. As used elsewhere herein, heat, heat energy and thermal energy correspond to a detectable temperature rise undergone by real bodies characterized by heat capacities. Under nominal operating conditions, the perforations 210 can be configured to collectively hold at least 80% of the combustion reaction 302 between the input face 212 and the output face 214 of the perforated reaction holder 102. In some experiments, the inventors produced a combustion reaction 302 that was apparently wholly contained in the perforations 210 between the input face 212 and the output face 214 of the perforated reaction holder 102. According to an alternative interpretation, the perforated reaction holder 102 can support combustion between the input face 212 and output face 214 when combustion is “time-averaged.” For example, during transients, such as before the perforated reaction holder 102 is fully heated or if too high a (cooling) load is placed on the system, the combustion may travel somewhat downstream from the output face 214 of the perforated reaction holder 102. Alternatively, if the cooling load is relatively low and/or the furnace temperature reaches a high level, the combustion may travel somewhat upstream of the input face 212 of the perforated reaction holder 102.
While a “flame” is described in a manner intended for ease of description, it should be understood that in some instances, no visible flame is present. Combustion occurs primarily within the perforations 210, but the “glow” of combustion heat is dominated by a visible glow of the perforated reaction holder 102 itself. In other instances, the inventors have noted transient “flashback” or “huffing” wherein a visible flame momentarily ignites in a region lying between the input face 212 of the perforated reaction holder 102 and the fuel nozzle 218, within the dilution region DD. Such transient flashback or huffing is generally short in duration such that, on a time-averaged basis, a majority of combustion occurs within the perforations 210 of the perforated reaction holder 102, between the input face 212 and the output face 214. In still other instances, the inventors have noted apparent combustion occurring downstream from the output face 214 of the perforated reaction holder 102, but still a majority of combustion occurred within the perforated reaction holder 102 as evidenced by continued visible glow from the perforated reaction holder 102 that was observed.
The perforated reaction holder 102 can be configured to receive heat from the combustion reaction 302 and output a portion of the received heat as thermal radiation 304 to heat-receiving structures (e.g., furnace walls and/or radiant section working fluid tubes) in or adjacent to the combustion volume 204. As used herein, terms such as radiation, thermal radiation, radiant heat, heat radiation, etc. are to be construed as being substantially synonymous, unless further definition is provided. Specifically, such terms refer to blackbody-type radiation of electromagnetic energy, primarily at infrared wavelengths, but also at visible wavelengths owing to elevated temperature of the perforated reaction holder body 208.
Referring to the embodiment 300 in
The perforated reaction holder body 208 can be characterized by a heat capacity. The perforated reaction holder body 208 may hold thermal energy from the combustion reaction 302 in an amount corresponding to the heat capacity multiplied by temperature rise, and transfer the thermal energy from the heat receiving regions 306 to heat output regions 310 of the perforation walls 308. Generally, the heat output regions 310 are nearer to the input face 212 than are the heat receiving regions 306. According to one interpretation, the perforated reaction holder body 208 can transfer heat from the heat receiving regions 306 to the heat output regions 310 via thermal radiation, depicted graphically as 304. According to another interpretation, the perforated reaction holder body 208 can transfer heat from the heat receiving regions 306 to the heat output regions 310 via heat conduction along heat conduction paths 312. The inventors contemplate that multiple heat transfer mechanisms including conduction, radiation, and possibly convection may be operative in transferring heat from the heat receiving regions 306 to the heat output regions 310. In this way, the perforated reaction holder 102 may act as a heat source to maintain the combustion reaction 302, even under conditions where a combustion reaction 302 would not be stable when supported from a conventional reaction holder.
The perforated reaction holder 102 may cause the combustion reaction 302 to begin within thermal boundary layers 314 formed adjacent to walls 308 of the perforations 210. Insofar as combustion is generally understood to include a large number of individual reactions, and since a large portion of combustion energy is released within the perforated reaction holder 102, it is apparent that at least a majority of the individual reactions occur within the perforated reaction holder 102.
As the comparatively cool fuel and oxidant mixture 206 approaches the input face 212, the flow is split into portions that respectively travel through individual perforations 210. The hot perforated reaction holder body 208 transfers heat to the fluid, notably within thermal boundary layers 314 that progressively thicken as more and more heat is transferred to the incoming fuel and oxidant mixture 206. After reaching a combustion temperature (e.g., the auto-ignition temperature of the fuel), the reactants continue to flow while a chemical ignition delay time elapses, over which time the combustion reaction 302 occurs. Accordingly, the combustion reaction 302 is shown as occurring within the thermal boundary layers 314. As flow progresses, the thermal boundary layers 314 merge at a merger point 316. Ideally, the merger point 316 lies between the input face 212 and output face 214 that define the ends of the perforations 210. At some position along the length of a perforation 210, the combustion reaction 302 outputs more heat to the perforated reaction holder body 208 than it receives from the perforated reaction holder body 208. The heat is received at the heat receiving region 306, is held by the perforated reaction holder body 208, and is transported to the heat output region 310 nearer to the input face 212, where the heat is transferred into the cool reactants (and any included diluent) to bring the reactants to the ignition temperature.
In an embodiment, each of the perforations 210 is characterized by a length L defined as a reaction fluid propagation path length between the input face 212 and the output face 214 of the perforated reaction holder 102. As used herein, the term reaction fluid refers to matter that travels through a perforation 210. Near the input face 212, the reaction fluid includes the fuel and oxidant mixture 206 (optionally including nitrogen, flue gas, and/or other “non-reactive” species). Within the combustion reaction region, the reaction fluid may include plasma associated with the combustion reaction 302, molecules of reactants and their constituent parts, any non-reactive species, reaction intermediates (including transition states), and reaction products. Near the output face 214, the reaction fluid may include reaction products and byproducts, non-reactive gas, and excess oxidant.
The plurality of perforations 210 can be each characterized by a transverse dimension D between opposing perforation walls 308. The inventors have found that stable combustion can be maintained in the perforated reaction holder 102 at a particular fuel supply rate if the length L of each perforation 210 is at least four times the transverse dimension D of the perforation 210. In other embodiments, the length L can be greater than six times the transverse dimension D. For example, experiments have been run where L is at least eight, at least twelve, at least sixteen, and at least twenty-four times the transverse dimension D. Preferably, the length L is sufficiently long for thermal boundary layers 314 to form adjacent to the perforation walls 308 in a reaction fluid flowing through the perforations 210 to converge at merger points 316 within the perforations 210 between the input face 212 and the output face 214 of the perforated reaction holder 102. In experiments, the inventors have found L/D ratios between 12 and 48 to work well (i.e., produce low NOx, produce low CO, and maintain stable combustion).
The perforated reaction holder body 208 can be configured to convey heat between adjacent perforations 210. The heat conveyed between adjacent perforations 210 can be selected to cause heat output from the combustion reaction portion 302 in a first perforation 210 to supply heat to stabilize a combustion reaction portion 302 in an adjacent perforation 210.
However, it has been observed that a mass flow velocity of the fuel and air mixture 206 is non-uniform across the input face 212 of the perforated reaction holder 102. For example, the mass flow velocity may be, on average, highest near a nominal fuel or oxidant delivery axis (such as the fuel and oxidant propagation axis), and may decrease with distance away from the fuel/oxidant delivery axis. Thus a combustion reaction 302 in perforations 210 at a periphery of the perforated reaction holder 102 may produce less thermal energy and/or may output more un-combusted reactants than a combustion reaction at or near the fuel/oxidant delivery axis. A combustion reaction 302 might be supported only partially within the perforations 210 in an annular (or peripheral) region of the perforated reaction holder 102 characterized by a mass flow velocity below a higher mass flow velocity through a portion of the perforated reaction holder 102 that is axial to the annular region. Alternatively, during start-up, the combustion reaction may be supported only at least partially within perforations 210 in an elliptical region of the perforated reaction holder 102 characterized by a mass flow velocity below a higher mass flow velocity through a portion of the perforated reaction holder 102 circumferential to the elliptical region. It is acknowledged that, in contrast, if the fuel and oxidant are provided at a sufficient rate to realize efficient combustion in the annular/peripheral region, the combustion reaction 302 at perforations 210 axial to the peripheral region 130 may burn too hot, resulting in undesirable affects such as degradation of the combustion chamber 104, burner, etc., or damage to processed materials or heated fluids.
The embodiment 300 in
Referring again to
The perforated reaction holder 102 can be held by a perforated reaction holder support structure 222 configured to hold the perforated reaction holder 102 at a dilution distance DD away from the fuel nozzle 218. In some embodiments, the perforated reaction holder 102 may be supported in the combustion chamber 104 by a plurality of rails, as described in parent international publication WO 2016/007564 incorporated by reference herein. The fuel nozzle 218 can be configured to emit a fuel jet selected to entrain the oxidant to form the fuel and oxidant mixture 206 as the fuel jet and oxidant travel along a path to the perforated reaction holder 102 through the dilution distance DD between the fuel nozzle 218 and the perforated reaction holder 102. Additionally or alternatively (particularly when a blower is used to deliver oxidant contained in combustion air), the oxidant or combustion air source 220 can be configured to entrain the fuel and the fuel and oxidant 206 travel through the dilution distance DD. In some embodiments, a flue gas recirculation path 224 can be provided. Additionally or alternatively, the fuel nozzle 218 can be configured to emit a fuel jet selected to entrain the oxidant and to entrain flue gas as the fuel jet travels through the dilution distance DD between the fuel nozzle 218 and the input face 212 of the perforated reaction holder 102.
The fuel nozzle 218 can be configured to emit the fuel through one or more fuel orifices 226 having an inside diameter dimension that is referred to as “nozzle diameter.” The perforated reaction holder support structure 222 can support the perforated reaction holder 102 to receive the fuel and oxidant mixture 206 at the distance DD away from the fuel nozzle 218 greater than 20 times the nozzle diameter. In another embodiment, the perforated reaction holder 102 is disposed to receive the fuel and oxidant mixture 206 at the distance DD away from the fuel nozzle 218 between 100 times and 1100 times the nozzle diameter. Preferably, the perforated reaction holder support structure 222 is configured to hold the perforated reaction holder 102 at a distance about 200 or more times of the nozzle diameter away from the fuel nozzle 218. When the fuel and oxidant mixture 206 travels about 200 times the nozzle diameter or more, the mixture is sufficiently homogenized to permit the combustion reaction 302 to produce minimal NOx.
The fuel and oxidant source 202 can alternatively include a premix fuel and oxidant source, according to an embodiment. A premix fuel and oxidant source can include a premix chamber (not shown), a fuel nozzle configured to output fuel into the premix chamber, and an oxidant (e.g., combustion air) channel configured to output the oxidant into the premix chamber. A flame arrestor (not shown) can be disposed between the premix fuel and oxidant source and the perforated reaction holder 102 and be configured to prevent flame flashback into the premix fuel and oxidant source.
The oxidant source 220, whether configured for entrainment in the combustion volume 204 or for premixing, can include a blower configured to force the oxidant through the fuel and oxidant source 202.
The support structure 222 can be configured to support the perforated reaction holder 102 from a floor or wall (not shown) of the combustion volume 204, for example. In another embodiment, the support structure 222 supports the perforated reaction holder 102 from the fuel and oxidant source 202. Alternatively, the support structure 222 can suspend the perforated reaction holder 102 from an overhead structure (such as a flue, in the case of an up-fired system). The support structure 222 can support the perforated reaction holder 102 in various orientations and directions.
The perforated reaction holder 102 can include a single perforated reaction holder body 208. In another embodiment, the perforated reaction holder 102 can include a plurality of adjacent perforated reaction holder sections (e.g., tiles) that collectively provide a tiled perforated reaction holder 102.
The perforated reaction holder support structure 222 can be configured to support the plurality of perforated reaction holder sections. The perforated reaction holder support structure 222 can include a metal superalloy, a cementatious, and/or ceramic refractory material. In an embodiment, the plurality of adjacent perforated reaction holder sections can be joined with a fiber reinforced refractory cement.
The perforated reaction holder 102 can have a width dimension W between opposite sides of the peripheral surface 216 at least twice a thickness dimension T between the input face 212 and the output face 214. In another embodiment, the perforated reaction holder 102 can have a width dimension W between opposite sides of the peripheral surface 216 at least three times, at least six times, or at least nine times the thickness dimension T between the input face 212 and the output face 214 of the perforated reaction holder 102.
In an embodiment, the perforated reaction holder 102 can have a width dimension W less than a width of the combustion volume 204. This can allow the flue gas circulation path 224 from above to below the perforated reaction holder 102 to lie between the peripheral surface 216 of the perforated reaction holder 102 and the combustion volume wall (not shown in
Referring again to both
In one range of embodiments, each of the plurality of perforations 210 has a lateral dimension D between 0.05 inch and 1.0 inch. Preferably, each of the plurality of perforations 210 has a lateral dimension D between 0.1 inch and 0.5 inch. For example the plurality of perforations 210 can each have a lateral dimension D of about 0.2 to 0.4 inch.
The void fraction of a perforated reaction holder 102 is defined as the total volume of all perforations 210 in a section of the perforated reaction holder 102 divided by a total volume of the perforated reaction holder 102 including body 208 and perforations 210. The perforated reaction holder 102 should have a void fraction between 0.10 and 0.90. In an embodiment, the perforated reaction holder 102 can have a void fraction between 0.30 and 0.80. In another embodiment, the perforated reaction holder 102 can have a void fraction of about 0.70. Using a void fraction of about 0.70 was found to be especially effective for producing very low NOx.
The perforated reaction holder 102 can be formed from a fiber reinforced cast refractory material and/or a refractory material such as an aluminum silicate material. For example, the perforated reaction holder 102 can be formed to include mullite or cordierite. Additionally or alternatively, the perforated reaction holder body 208 can include a metal superalloy such as INCONEL or HASTELLOY. The perforated reaction holder body 208 can define a honeycomb. For example, the perforated reaction holder 102 can be formed from VERSAGRID ceramic honeycomb, available from Applied Ceramics, Inc. of Doraville, S.C. Honeycomb is an industrial term of art that need not strictly refer to a hexagonal cross section and most usually includes cells of square cross section. Honeycombs of other cross sectional areas are also known.
The perforations 210 can be parallel to one another and normal to the input and output faces 212, 214. In another embodiment, the perforations 210 can be parallel to one another and formed at an angle relative to the input and output faces 212, 214. In another embodiment, the perforations 210 can be non-parallel to one another. In another embodiment, the perforations 210 can be non-parallel to one another and non-intersecting. In another embodiment, the perforations 210 can be intersecting. The body 208 can be one piece or can be formed from a plurality of sections.
In another embodiment, the perforated reaction holder 102 may be formed from reticulated ceramic material. The term “reticulated” refers to a netlike structure. Reticulated ceramic material is often made by dissolving a slurry into a sponge of specified porosity, allowing the slurry to harden, and burning away the sponge and curing the ceramic.
In another embodiment, which is not necessarily preferred, the perforated reaction holder 102 may be formed from a ceramic material that has been punched, bored or cast to create channels.
In another embodiment, the perforated reaction holder 102 can include a plurality of tubes or pipes bundled together. The plurality of perforations 210 can include hollow cylinders and can optionally also include interstitial spaces between the bundled tubes. In an embodiment, the plurality of tubes can include ceramic tubes. Refractory cement can be included between the tubes and configured to adhere the tubes together. In another embodiment, the plurality of tubes can include metal (e.g., superalloy) tubes. The plurality of tubes can be held together by a metal tension member circumferential to the plurality of tubes and arranged to hold the plurality of tubes together. The metal tension member can include stainless steel, a superalloy metal wire, and/or a superalloy metal band.
The perforated reaction holder body 208 can alternatively include stacked or layered perforated sheets of material, each sheet having openings that connect with openings of subjacent and superjacent sheets. The perforated sheets can include perforated metal sheets, ceramic sheets and/or expanded sheets. In another embodiment, the perforated reaction holder body 208 can include discontinuous packing bodies such that the perforations 210 are formed in the interstitial spaces between the discontinuous packing bodies. In one example, the discontinuous packing bodies include structured packing shapes. In another example, the discontinuous packing bodies include random packing shapes. For example, the discontinuous packing bodies can include ceramic RASCHIG ring, ceramic Berl saddles, ceramic INTALOX saddles, and/or metal rings or other shapes (e.g. RASCHIG SUPER-RINGs) that may be held together by a metal cage.
The inventors contemplate various explanations for why burner systems including the perforated reaction holder 102 provide such clean combustion.
According to an embodiment, the perforated reaction holder 102 may act as a heat source to maintain a combustion reaction 302 even under conditions where a combustion reaction 302 would not be stable when supported by a conventional flame holder. This capability can be leveraged to support combustion using a leaner fuel-to-oxidant mixture than is typically feasible. Thus, according to an embodiment, at the point where the fuel stream 206 contacts the input face 212 of the perforated reaction holder 102, an average fuel-to-oxidant ratio of the fuel stream 206 is below a (conventional) lower combustion limit of the fuel component of the fuel stream 206. Lower combustion limit defines the lowest concentration of fuel at which a fuel and oxidant mixture 206 will burn when exposed to a momentary ignition source under normal atmospheric pressure and an ambient temperature of 25° C. (77° F.).
The perforated reaction holder 102 and systems including the perforated reaction holder 102 described herein were found to provide substantially complete combustion of CO (single digit ppm down to undetectable, depending on experimental conditions), while supporting low NOx. According to one interpretation, such a performance can be achieved due to a sufficient mixing used to lower peak flame temperatures (among other strategies). Flame temperatures tend to peak under slightly rich conditions, which can be evident in any diffusion flame that is insufficiently mixed. By sufficiently mixing, a homogenous and slightly lean mixture can be achieved prior to combustion. This combination can result in reduced flame temperatures, and thus reduced NOx formation. In one embodiment, “slightly lean” may refer to 3% O2, i.e. an equivalence ratio of ˜0.87. Use of even leaner mixtures is possible, but may result in elevated levels of O2. Moreover, the inventors believe perforation walls 308 may act as a heat sink for the combustion fluid. This effect may alternatively or additionally reduce combustion temperatures and lower NOx.
According to another interpretation, production of NOx can be reduced if the combustion reaction 302 occurs over a very short duration of time. Rapid combustion causes the reactants (including oxygen and entrained nitrogen) to be exposed to NOx-formation temperature for a time too short for NOx formation kinetics to cause significant production of NOx. The time required for the reactants to pass through the perforated reaction holder 102 is very short compared to a conventional flame. The low NOx production associated with perforated reaction holder combustion may thus be related to the short duration of time required for the reactants (and entrained nitrogen) to pass through the perforated reaction holder 102.
According to a simplified description, the method 400 begins with step 402, wherein the perforated reaction holder is preheated to a start-up temperature, TS. After the perforated reaction holder is raised to the start-up temperature, the method proceeds to step 404, wherein the fuel and oxidant are provided to the perforated reaction holder and combustion is held by the perforated reaction holder.
According to a more detailed description, step 402 begins with step 406, wherein start-up energy is provided at the perforated reaction holder. Simultaneously or following providing start-up energy, a decision step 408 determines whether the temperature T of the perforated reaction holder is at or above the start-up temperature, T. As long as the temperature of the perforated reaction holder is below its start-up temperature, the method loops between steps 406 and 408 within the preheat step 402. In step 408, if the temperature T of at least a predetermined portion of the perforated reaction holder is greater than or equal to the start-up temperature, the method 400 proceeds to overall step 404, wherein fuel and oxidant is supplied to and combustion is held by the perforated reaction holder.
Step 404 may be broken down into several discrete steps, at least some of which may occur simultaneously. Proceeding from step 408, a fuel and oxidant mixture is provided to the perforated reaction holder, as shown in step 410. The fuel and oxidant may be provided by a fuel and oxidant source that includes a separate fuel nozzle and oxidant (e.g., combustion air) source, for example. In this approach, the fuel and oxidant are output in one or more directions selected to cause the fuel and oxidant mixture to be received by the input face of the perforated reaction holder. The fuel may entrain the combustion air (or alternatively, the combustion air may dilute the fuel) to provide a fuel and oxidant mixture at the input face of the perforated reaction holder at a fuel dilution selected for a stable combustion reaction that can be held within the perforations of the perforated reaction holder.
Proceeding to step 412, the combustion reaction is held by the perforated reaction holder.
In step 414, heat may be output from the perforated reaction holder. The heat output from the perforated reaction holder may be used to power an industrial process, heat a working fluid, generate electricity, or provide motive power, for example.
In optional step 416, the presence of combustion may be sensed. Various sensing approaches have been used and are contemplated by the inventors. Generally, combustion held by the perforated reaction holder is very stable and no unusual sensing requirement is placed on the system. Combustion sensing may be performed using an infrared sensor, a video sensor, an ultraviolet sensor, a charged species sensor, thermocouple, thermopile, flame rod, and/or other combustion sensing apparatuses. In an additional or alternative variant of step 416, a pilot flame or other ignition source may be provided to cause ignition of the fuel and oxidant mixture in the event combustion is lost at the perforated reaction holder.
Proceeding to decision step 418, if combustion is sensed not to be stable, the method 400 may exit to step 424, wherein an error procedure is executed. For example, the error procedure may include turning off fuel flow, re-executing the preheating step 402, outputting an alarm signal, igniting a stand-by combustion system, or other steps. If, in step 418, combustion in the perforated reaction holder is determined to be stable, the method 400 proceeds to decision step 420, wherein it is determined if combustion parameters should be changed. If no combustion parameters are to be changed, the method loops (within step 404) back to step 410, and the combustion process continues. If a change in combustion parameters is indicated, the method 400 proceeds to step 422, wherein the combustion parameter change is executed. After changing the combustion parameter(s), the method loops (within step 404) back to step 410, and combustion continues.
Combustion parameters may be scheduled to be changed, for example, if a change in heat demand is encountered. For example, if less heat is required (e.g., due to decreased electricity demand, decreased motive power requirement, or lower industrial process throughput), the fuel and oxidant flow rate may be decreased in step 422. Conversely, if heat demand is increased, then fuel and oxidant flow may be increased. Additionally or alternatively, if the combustion system is in a start-up mode, then fuel and oxidant flow may be gradually increased to the perforated reaction holder over one or more iterations of the loop within step 404.
Referring again to
Various heating apparatuses have been used and are contemplated by the inventors. In some embodiments, the heater 228 can include a flame holder configured to support a flame disposed to heat the perforated reaction holder 102. The fuel and oxidant source 202 can include a fuel nozzle 218 configured to emit a fuel stream 206 and an oxidant source 220 configured to output oxidant (e.g., combustion air) adjacent to the fuel stream 206. The fuel nozzle 218 and oxidant source 220 can be configured to output the fuel stream 206 to be progressively diluted by the oxidant (e.g., combustion air). The perforated reaction holder 102 can be disposed to receive a diluted fuel and oxidant mixture 206 that supports a combustion reaction 302 that is stabilized by the perforated reaction holder 102 when the perforated reaction holder 102 is at an operating temperature. A start-up flame holder, in contrast, can be configured to support a start-up flame that is stable at a location corresponding to a relatively unmixed fuel and oxidant mixture without stabilization provided by the heated perforated reaction holder 102.
The burner system 200 can further include a controller 230 operatively coupled to the heater 228 and to a data interface 232. For example, the controller 230 can be configured to control a start-up reaction holder actuator configured to cause the start-up flame holder to hold the start-up flame when the perforated flame holder 102 needs to be pre-heated and to not hold the start-up flame when the perforated flame holder 102 is at an operating temperature (e.g., when T≧TS).
Various approaches for actuating a start-up flame are contemplated. In one embodiment, the start-up flame holder includes a mechanically-actuated bluff body configured to be actuated to intercept the fuel and oxidant mixture 206 to cause heat-recycling and/or stabilizing vortices and thereby hold a start-up flame; or to be actuated to not intercept the fuel and oxidant mixture 206 to cause the fuel and oxidant mixture 206 to proceed to the perforated flame holder 102. In another embodiment, a fuel control valve, blower, and/or damper may be used to select a fuel and oxidant mixture flow rate that is sufficiently low for a start-up flame to be jet-stabilized; and upon reaching a perforated flame holder 102 operating temperature, the flow rate may be increased to “blow out” the start-up flame. In another embodiment, the heater 228 may include an electrical power supply operatively coupled to the controller 230 and configured to apply an electrical charge or voltage to the fuel and oxidant mixture 206. An electrically conductive start-up flame holder may be selectively coupled to a voltage ground or other voltage selected to attract the electrical charge in the fuel and oxidant mixture 206. The attraction of the electrical charge was found by the inventors to cause a start-up flame to be held by the electrically conductive start-up flame holder.
In another embodiment, the heater 228 may include an electrical resistance heater configured to output heat to the perforated flame holder 102 and/or to the fuel and oxidant mixture 206. The electrical resistance heater 228 can be configured to heat up the perforated flame holder 102 to an operating temperature. The heater 228 can further include a power supply and a switch operable, under control of the controller 230, to selectively couple the power supply to the electrical resistance heater 228.
An electrical resistance heater 228 can be formed in various ways. For example, the electrical resistance heater 228 can be formed from KANTHAL® wire (available from Sandvik Materials Technology division of Sandvik AB of Hallstaham mar, Sweden) threaded through at least a portion of the perforations 210 defined by the perforated flame holder body 208. Alternatively, the heater 228 can include an inductive heater, a high-energy beam heater (e.g. microwave or laser), a frictional heater, electro-resistive ceramic coatings, or other types of heating technologies.
Other forms of start-up apparatuses are contemplated. For example, the heater 228 can include an electrical discharge igniter or hot surface igniter configured to output a pulsed ignition to the oxidant and fuel 206. Additionally or alternatively, a start-up apparatus can include a pilot flame apparatus disposed to ignite the fuel and oxidant mixture 206 that would otherwise enter the perforated flame holder 102. The electrical discharge igniter, hot surface igniter, and/or pilot flame apparatus can be operatively coupled to the controller 230, which can cause the electrical discharge igniter or pilot flame apparatus to maintain combustion of the fuel and oxidant mixture 206 in or upstream from the perforated flame holder 102 before the perforated flame holder 102 is heated sufficiently to maintain combustion.
The burner system 200 can further include a sensor 234 operatively coupled to the control circuit 230. The sensor 234 can include a heat sensor configured to detect infrared radiation or a temperature of the perforated flame holder 102. The control circuit 230 can be configured to control the heating apparatus 228 responsive to input from the sensor 234. Optionally, a fuel control valve 236 can be operatively coupled to the controller 230 and configured to control a flow of fuel to the fuel and oxidant source 202. Additionally or alternatively, an oxidant blower or damper 238 can be operatively coupled to the controller 230 and configured to control flow of the oxidant (or combustion air).
The sensor 234 can further include a combustion sensor operatively coupled to the control circuit 230, the combustion sensor being configured to detect a temperature, video image, and/or spectral characteristic of a combustion reaction 302 held by the perforated reaction holder 102. The fuel control valve 236 can be configured to control a flow of fuel from a fuel source to the fuel and oxidant source 202. The controller 230 can be configured to control the fuel control valve 236 responsive to input from the combustion sensor 234. The controller 230 can be configured to control the fuel control valve 236 and/or oxidant blower or damper 238 to control a preheat flame type of heater 228 to heat the perforated reaction holder 102 to an operating temperature. The controller 230 can similarly control the fuel control valve 236 and/or the oxidant blower or damper 238 to change the fuel and oxidant mixture 206 flow responsive to a heat demand change received as data via the data interface 232.
In the embodiment 300 of
Optionally, the perforated reaction holder 102 can be formed from one or more pieces of material, and the perforations 210 can be branching or non-branching. Non-branching perforations 210 can be referred to as elongated apertures.
The perforated reaction holder body 208 defines a plurality of perforations 210 configured to convey the fuel and oxidant 206 and to hold the oxidation reaction supported by the fuel and oxidant 206. The perforated reaction holder body 208 is configured to receive heat from the combustion reaction 302, hold the heat, and output the heat to the fuel and oxidant 206 entering the perforations 210. The perforations 210 can maintain a substantially complete combustion reaction 302 of a leaner mixture of fuel and oxidant 206 than can be maintained outside of the perforations 210. An embodiment utilizing branching perforations 210 is discussed with respect to
The inventors have recognized a need to compensate for the non-uniform speed of the fuel and/or oxidant mixture 206 reaching the perforated reaction holder 102. The following disclosure details structures and methods for such compensation.
According to an embodiment, in the case of a reticulated ceramic perforated reaction holder 102 (
According to an embodiment, in the case of a reticulated ceramic perforated reaction holder 102 (
In all the embodiments disclosed herein the central axis 106 may correspond with the center of a single perforation (e.g., 210), or the central axis 106 may correspond to a non-perforation location of the perforated reaction holder(s) 902. For example, the central axis 106 may correspond to a perforation wall (e.g., 308) or with material otherwise disposed between perforations 910.
The velocity compensation features described herein may be mixed and matched to address different fuel and/or oxidant features, velocities, chemical constitution or the like. For example,
The perforated reaction holder 1102 may be formed from a plurality of adjacently disposed tiles 1124, 1134. In some instances, a cross-section of the perforated reaction holder 1102 may be very similar to the cross-sections shown in
In some embodiments, rows of tiles 1124, 1134 may be offset with respect to each other, e.g., by an offset distance DO as illustrated in
In yet other embodiments, tiles constituting the perforated reaction holder 1102 may form layers in a thickness direction of the perforated reaction holder 1102, e.g., as discussed with respect to
In
The central region 1220 may, according to an embodiment, be comprised of a continuous structure having two portions, in which each perforation 1210 in the first layer 1260 of the central region 1220 branches into one or more perforations 1222 without a break in the material forming the perforations 1210, 1222. In another embodiment, the first layer 1260 and the second layer 1270 may be distinct structures. Furthermore, each of the layers 1260, 1270 may be formed from pluralities of individual tiles similar, for one or more of the layers 1260, 1270, to what is described with respect to
Also as shown in
According to an embodiment, the perforated reaction holder 1202c in
Each perforated reaction holder 1302(a,b,c) may be formed of tiles having a width dimension WFT less than the width dimension WFH of the perforated reaction holder 1302(a,b,c). For instance, the modular perforated reaction holder tiles 1303 in
It will be acknowledged that other perforated reaction holder structures described above may be incorporated in a tiled perforated reaction holder. For example, the left-hand tile 1305 of
In some embodiments, each tile (1303, 1305, 1307) may be uniform in design and size as illustrated in
According to an embodiment, perforated reaction holder tiles may be arranged for correspondence with fuel and oxidant propagation axes from fuel nozzles spatially clustered in a central location. A fuel and oxidant propagation axis corresponding to at least one of the fuel nozzles may be at a non-orthogonal angle with respect to the input face of such a tiled perforated reaction holder 1302. Accordingly, the tiled perforated reaction holder (not illustrated) may include tiles with perforations angled to accommodate the non-orthogonal fuel and oxidant propagation axis. Other tiles, closer to a central location directly opposite the fuel nozzles, may have perforations that are comparatively orthogonal to the input face of the perforated reaction holder 1302.
According to another embodiment, a perforated reaction holder (not shown) can define a central aperture, about which a first set of apertures or perforations may be arranged in a concentric arrangement relative to the central aperture and having a selected spacing and size. A second set of apertures or perforations may be arranged in concentric arrangement relative to the central aperture and having a different selected spacing and size. The perforated reaction holder can be configured to hold the fuel combustion reaction 302 between an input surface and an output surface of the perforated reaction holder.
Supporting the combustion reaction within the central perforations may include supporting transit of the fuel and oxidant along a greater length distance within the central perforations than within the peripheral perforations. Additionally, or alternatively, supporting the combustion reaction within the central perforations may include supporting the transit of fuel and oxidant through a smaller lateral dimension within the central perforations than within the peripheral perforations.
The first dimension and the second dimension may be average lengths respectively of the central perforations and the peripheral perforations through a thickness of the perforated reaction holder (i.e., between an input face and an output face). The lengths of respective perforations of the plurality of perforations may decrease continuously with distance from a central axis of the PFH.
The first dimension and the second dimension may be average lateral dimensions respectively of the central perforations and the peripheral perforations, and are transverse to the thickness (between the input and output faces) of the perforated reaction holder. The lateral dimension of respective perforations of the plurality of perforations may be successively larger with distance from the central axis. The average lateral dimension of the central perforations may be smaller than the average lateral dimension of the peripheral perforations, and the lateral dimensions of the central perforations support the combustion reaction within the central perforations via transit of fuel and oxidant through smaller lateral dimensions than within the peripheral perforations.
According to an embodiment, the perforated reaction holder body 208 can include reticulated fibers 1539. The reticulated fibers 1539 can define branching perforations 210 that weave around and through the reticulated fibers 1539. According to an embodiment, the perforations 210 are formed as passages through the reticulated ceramic fibers 1539.
According to an embodiment, the reticulated fibers 1539 can include alumina silicate. According to an embodiment, the reticulated fibers 1539 can be formed from extruded mullite or cordierite. According to an embodiment, the reticulated fibers 1539 can include Zirconia. According to an embodiment, the reticulated fibers 1539 can include silicon carbide.
The term “reticulated fibers” refers to a netlike structure. According to an embodiment, the reticulated fibers 1539 are formed from an extruded ceramic material. In reticulated fiber embodiments, the interaction between the fuel and oxidant 206, the combustion reaction, and heat transfer to and from the perforated reaction holder body 208 can function similarly to the embodiment shown and described above with respect to
According to an embodiment, the reticulated fiber network is sufficiently open for downstream reticulated fibers 1539 to emit radiation for receipt by upstream reticulated fibers 1539 for the purpose of heating the upstream reticulated fibers 1539 sufficiently to maintain combustion of a fuel and oxidant 206. Compared to a continuous perforated reaction holder body 208, heat conduction paths 312 between fibers 1539 are reduced due to separation of the fibers 1539. This may cause relatively more heat to be transferred from the heat-receiving region 306 (heat receiving area) to the heat-output region 310 (heat output area) of the reticulated fibers 1539 via thermal radiation.
According to an embodiment, individual perforations 210 may extend from an input face 212 to an output face 214 of the perforated reaction holder 102. Perforations 210 may have varying lengths L. According to an embodiment, because the perforations 210 branch into and out of each other, individual perforations 210 are not clearly defined by a length L.
According to an embodiment, the perforated reaction holder 102 is configured to support or hold a combustion reaction or a flame at least partially between the input face 212 and the output face 214. According to an embodiment, the input face 212 corresponds to a surface of the perforated reaction holder 102 proximal to the fuel nozzle 218 or to a surface that first receives fuel. According to an embodiment, the input face 212 corresponds to an extent of the reticulated fibers 1539 proximal to the fuel nozzle 218. According to an embodiment, the output face 214 corresponds to a surface distal to the fuel nozzle 218 or opposite the input face 212. According to an embodiment, the input face 212 corresponds to an extent of the reticulated fibers 1539 distal to the fuel nozzle 218 or opposite to the input face 212.
According to an embodiment, the formation of boundary layers 314, transfer of heat between the perforated reaction holder body 208 and the gases flowing through the perforations 210, a characteristic perforation width dimension D, and the length L can be regarded as related to an average or overall path through the perforated reaction holder 102. In other words, the dimension D can be determined as a root-mean-square of individual Dn values determined at each point along a flow path. Similarly, the length L can be a length that includes length contributed by tortuosity of the flow path, which may be somewhat longer than a straight line distance TRH from the input face 212 to the output face 214 through the perforated reaction holder 102. According to an embodiment, the void fraction (expressed as total perforated reaction holder 102 volume−fiber 1539 volume)/total volume)) can vary at different regions of the perforated reaction holder 102. An individual reticulated ceramic perforated flame holder 102 can include a central region with different characteristics than a peripheral region, such that average dimensions of the central perforations in the central region are different than average dimensions of the central perforations in the peripheral region.
According to an embodiment, the reticulated ceramic perforated reaction holder 102 can include shapes and dimensions other than those described herein. For example, the perforated reaction holder 102 can include reticulated ceramic tiles that are larger or smaller than the dimensions set forth above. Additionally, the reticulated ceramic perforated reaction holder 102 can include shapes other than generally cuboid shapes.
According to an embodiment, the reticulated ceramic perforated reaction holder 102 can include multiple reticulated ceramic tiles. The multiple reticulated ceramic tiles can be joined together such that each ceramic tile is in direct contact with one or more adjacent reticulated ceramic tiles. The multiple reticulated ceramic tiles can collectively form a single perforated reaction holder 102. The multiple reticulated ceramic tiles can have perforations 210 characterized by differing average dimensions, can have differing void fractions, differing densities of reticulated fibers 1539, differing numbers of pores per square inch of surface area of the input and output faces 212 and 214, differing thicknesses, differing average distances between adjacent reticulated fibers 1539, or other average dimensions.
According to an embodiment, a perforated flame holder 102 may include one or more central reticulated ceramic tiles corresponding to a central region and one or more peripheral reticulated ceramic tiles corresponding to a peripheral region. The central reticulated ceramic tiles may have differing dimensions and characteristics than the peripheral reticulated ceramic tiles. The central region may include a stack of two or more reticulated ceramic tiles.
While various aspects and embodiments have been disclosed herein, other aspects and embodiments are contemplated. The various aspects and embodiments disclosed herein are for purposes of illustration and are not intended to be limiting, with the true scope and spirit being indicated by the following claims.
The present application claims priority benefit from U.S. Provisional Patent Application No. 62/384,696, entitled “DUPLEX BURNER WITH VELOCITY-COMPENSATED MESH AND THICKNESS,” filed Sep. 7, 2016 (docket number 2651-217-02); which, to the extent not inconsistent with the disclosure herein, is incorporated by reference.
Number | Date | Country | |
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62384696 | Sep 2016 | US |