Dyeing textile substrates, such as yarn, with indigo dye is well known. This includes the applying of indigo dye in a leuco state to a traveling textile substrate in an inert atmosphere in which the dye is allowed to fully penetrate the substrate, and then exposing the dyed substrate to the ambient atmosphere in which the oxygen in the ambient atmosphere (approximately 20%) reacts with the dye to oxidize and thereby fix the dye in the substrate.
Indigo dyed yarn is commonly used to weave fabric for the manufacture of blue jeans, overalls, and other items of clothing. It has become fashionable for blue jeans to be manufactured with areas having the appearance of the dye having been worn off leaving white or undyed areas. To provide this appearance, fabric is commonly completely dyed throughout and then purposely subjected to wearing down the fabric in selected areas to remove the dye, which often results in the fabric being worn through, leaving open areas.
The present invention is directed to rapidly fixing or setting foamed leuco state indigo dye in a traveling sheet of textile substrate, such as a sheet of yarns, before the dye fully penetrates the substrate. The leuco state indigo dye is applied to the substrate in an inert atmosphere and travels through a dwell chamber in an inert atmosphere to allow the dye to begin penetrating into the substrate. Before the dye completely penetrates the substrate, the substrate leaves the dwell chamber and is subjected to commercially pure oxygen that quickly fixes or sets the indigo dye at the level of penetration obtained as it left the dwell chamber, resulting in the substrate having a dyed outer ring and an undyed core.
The preferred embodiment of the dye fixing section S of the present invention is illustrated in
A second pair of driven nip rollers 22, 14 is mounted in the housing 10 parallel to and in nip forming engagement with the first pair of nip rollers 14, 16, thereby defining a confined limited space 26 therebetween. The upper rollers 14, 22 of the pairs of driven rollers rotate in opposite directions to form a nip 30 having an entry in the confined space 26 for the sheet of yarns Y and an exit exteriorly of the space 26 for travel of the sheet of yarns Y in the confined space 26 around the upper roller 14 of the first pair 14, 16 and through the nip 28 formed by the two upper rollers 14, 22 to the ambient atmosphere to expose the sheet of yarns Y for drying the moisture resulting from the dissipation of the applied foam.
The confined space 26 contains commercially pure oxygen 30 (
The extent of travel of the sheet of yarns Y through the dwell chamber D is selected in relation to the speed of travel of the traveling sheet of yarns Y, which conventionally may be about 50 meters per minute, to allow the dye to only partially penetrate the interior of the individual yarns to a desired extent as it enters the confined space 26 in which the yarns of the traveling sheet of yarn Y are subjected to oxygen that fixes the indigo dye into a solid state affixed to the yarns Y at the level of desired penetration obtained in the dwell chamber, as illustrated in
The upper roller 14 of the first pair of rollers 14, 16 and the lower roller 24 of the second pair of rollers 22, 24 have outer circumferential layers 46 of rubber (
Sealing elements, illustrated in
As seen in
A second preferred embodiment of the present invention is illustrated in
A third preferred embodiment of the dye fixing section S of the present invention is illustrated in
Having the dye fixed in a small space by an arrangement of nip rollers or by spraying directly on the substrate has the significant advantage of limiting the amount of expensive pure oxygen necessary to obtain satisfactory results.
The method performed with each of the foregoing preferred embodiments involves applying oxygen to a traveling sheet of textile substrate, such as a sheet of yarn, to which indigo dye in a leuco state has been applied and allowed to partially penetrate in an inert atmosphere. The oxygen is applied to fix the indigo dye on the substrate at the partially penetrated extent, leaving an undyed core.
While the preferred embodiments are specific to dyeing sheets of textile yarn, it should be understood that the present invention is applicable as well to other forms of sheets of textile material, such as woven or knitted textile fabrics.
In view of the aforesaid written description of the present invention, it will be readily understood by those skilled in the art that the present invention is susceptible of broad utility and application. Many embodiments and adaptations of the present invention other than those herein described, as well as many variations, applications, modifications, and equivalent arrangements, will be apparent from or reasonably suggested by the present invention and the foregoing description thereof, without departing from the substance or scope of the present invention. Accordingly, while the present invention has been described herein in detail in relation to preferred embodiments, it is to be understood that this disclosure is only illustrative of examples of the present invention, and is made merely for purposes of providing a full and enabling disclosure of the invention. The foregoing disclosure is not intended nor is it to be construed to limit the present invention or otherwise to exclude any other embodiment, adaptations, variations, modifications, and the equivalent arrangements, the present invention being limited only by the claims appended hereto and the equivalents thereof.
The present non-provisional patent application claims the benefit of the filing date of Mar. 12, 2018 of Provisional U.S. Patent Application Ser. No. 62/641,764.
Number | Name | Date | Kind |
---|---|---|---|
3067758 | Hersh | Dec 1962 | A |
3969780 | Henderson | Jul 1976 | A |
4023526 | Atshmus et al. | May 1977 | A |
4061001 | von der Eltz et al. | Dec 1977 | A |
4099913 | Walter et al. | Jul 1978 | A |
4118183 | Godau | Oct 1978 | A |
4193762 | Namboodri | Mar 1980 | A |
4237818 | Clifford et al. | Dec 1980 | A |
4283198 | Fletcher | Aug 1981 | A |
4305169 | Vidalis | Dec 1981 | A |
4365968 | Gregorian et al. | Dec 1982 | A |
4402200 | Clifford et al. | Sep 1983 | A |
4435965 | Sasseville et al. | Mar 1984 | A |
4532782 | Sellers | Aug 1985 | A |
4562097 | Walter et al. | Dec 1985 | A |
4613335 | Berendt et al. | Sep 1986 | A |
4655056 | Zeiffer | Apr 1987 | A |
4884893 | Zeiffer et al. | Dec 1989 | A |
5063646 | Zeiffer et al. | Nov 1991 | A |
5168731 | Vidalis | Dec 1992 | A |
5195225 | Zeiffer et al. | Mar 1993 | A |
5201959 | Fuller | Apr 1993 | A |
5219620 | Potter et al. | Jun 1993 | A |
5323629 | Aurich et al. | Jun 1994 | A |
5337586 | Ronchi | Aug 1994 | A |
5494491 | Gurley | Feb 1996 | A |
6355073 | Godau | Mar 2002 | B1 |
6395088 | Zeiffer | May 2002 | B1 |
6432202 | Aurich | Aug 2002 | B1 |
6852196 | Capizzi | Feb 2005 | B2 |
6858256 | Zeiffer | Feb 2005 | B2 |
7913524 | Aurich et al. | Mar 2011 | B2 |
10704174 | Aurich et al. | Jul 2020 | B2 |
20050241078 | Aurich et al. | Nov 2005 | A1 |
20070266505 | Aurich et al. | Nov 2007 | A1 |
20090282621 | Kennedy | Nov 2009 | A1 |
20190136430 | Aurich et al. | May 2019 | A1 |
20200165774 | Malpass | May 2020 | A1 |
Number | Date | Country |
---|---|---|
3034803 | Mar 1982 | DE |
0525434 | Feb 1993 | EP |
0799924 | Oct 1997 | EP |
0995826 | Apr 2000 | EP |
1065308 | Jan 2001 | EP |
1657338 | May 2006 | EP |
2006013458 | Feb 2006 | WO |
Number | Date | Country | |
---|---|---|---|
20200224347 A1 | Jul 2020 | US |
Number | Date | Country | |
---|---|---|---|
62641764 | Mar 2018 | US |