The present invention relates to an easy-to-disassemble battery pack. More particularly, the present invention relates to an easy-to-disassemble battery pack configured such that a lower part of the battery pack is separable from a battery cell while the lower part of the battery pack is fixed in tight contact with the battery cell for heat transfer.
A secondary battery is constituted by a battery module including a plurality of battery cells connected to each other in series and/or parallel depending on the required output voltage or charge/discharge capacity or a battery pack including battery modules connected to each other.
A pouch-shaped battery having a stacked type electrode assembly or a stacked and folded type electrode assembly mounted in a pouch-shaped battery case made of a laminate sheet is often used in a battery module or a battery pack due to low manufacturing cost and high energy density thereof.
A laminated sheet including an outer covering layer, a metal blocking layer, and an inner adhesive layer is generally shaped so as to be used as a battery case of the pouch-shaped battery. An electrode assembly and an electrolyte solution are received in a receiving portion formed in the laminate sheet, and the laminate sheet is sealed to manufacture the pouch-shaped battery.
As shown in
A general battery pack is manufactured by manufacturing a battery module using a plurality of battery cells and connecting a plurality of battery modules to each other. After battery cells are manufactured, battery modules are manufactured by a separate manufacturer or on a separate assembly line, and the battery modules are connected to each other to constitute battery packs. Each battery module has an individual case for insulation and safety, which occupies space and increases weight.
In recent years, a simplified battery module with partially exposed battery cells or a cell to pack (CTP), in which battery cells are directly assembled to a battery pack, has been used in order to maximize the efficiency of an assembly process and energy. A heat sink is added to a lower part of a battery module and/or a battery pack in order to quickly dissipate heat discharged from the battery module and/or the battery pack during charging and discharging. Such a battery module and/or battery pack uses a thermal resin for thermal conduction and adhesive purposes in order to allow the battery cells and the heat sink to come into tight contact with each other and to fix the battery cells. Although the surface area in contact with the battery cells increases due to fully tight contact therebetween, it is very difficult to separate the battery cells from the battery module and/or the battery pack, since the battery cells are fixed to the lower part of the cell pack. In the case of a pouch-shaped battery cell, it is substantially impossible to separate the battery cell intact, since the thermal resin is cured after being adhered.
Patent Document 1 relates to a battery module, a battery pack including the battery module, and a vehicle including the battery pack. The battery module according to Patent Document 1 includes at least one battery cell, a module case configured to receive the at least one battery cell, a heat sink mounted to one side of the module case, the heat sink being configured to cool the at least one battery cell, and a foam member provided between the heat sink and the at least one battery cell, the foam member being disposed on one surface of the at least one battery cell in contact therewith.
Patent Document 1 needs improvement in the following ways. 1) The contact area is very important for thermal conduction. If a heat transfer medium does not directly contact a heat source, an air layer is formed therebetween, and since the air layer has very low thermal conductivity, heat transfer efficiency is reduced sharply. The foam member must be thick enough to make contact with all unstructured parts of the bottom of the pouch-shaped battery cell 210, as shown in
2) Even though a thick material is used, the foam member must be continuously pressurized at a certain pressure or higher to allow the foam member to be deformed and contact all parts. Without pressurization, the contact area is reduced by the resilience of the foam member. Therefore, the battery cell stack must be pressurized at a certain pressure or higher in the CTP, and a means configured to maintain the pressure must be provided. In the CTP in which assembly up to the upper plate has been completed, if a gap is formed between the upper plate and the battery cell stack, there is no pressurizing pressure or pressurization is not performed to a desired extent, whereby heat transfer efficiency is reduced sharply.
3) Even though the foam member is pressurized at an intended pressure or higher and comes into contact with all parts, there is a difference in the degree of compression of the foam member in each part. Due to the unstructured shape thereof, the foam member is compressed more in some parts and less in others. This results in different densities between the parts, and thermal conduction efficiency is also less uniform. Since the microstructure of the foam member is porous, parts that have been substantially less compressed may have low thermal conduction efficiency. If the thermal conduction efficiency of a part subjected to high heat is lower than the thermal conduction efficiency of the other parts, the likelihood of fire is increased due to the localized heat island effect. In the case of a CTP for energy maximization, all of the battery cells in the battery cell stack are sometimes connected to each other in series, resulting in very high voltage, and therefore the amount of heat generated is much higher than the amount of heat generated in a conventional battery cell stack. The localized heat island effect may lead to a very dangerous situation.
In Patent Document 1, the foam member may be impregnated with a thermal resin, but this case also inherently has the disadvantages of the foam member.
Patent Document 2 relates to a cooling structure of a battery. In Patent Document 2, a cooling surface of a battery module including a plurality of stacked battery cells may be supported by a cooling plate to cool the battery cells by transferring heat of the battery module from the cooling surface to the cooling plate. A non-conductive insulating sheet is disposed between the cooling surface of the battery module and the cooling plate. Patent Document 2 does not recognize the contact area that Patent Document 1 recognizes as a problem, and therefore the above configuration is not suitable for a CTP configured for energy maximization. Patent Document 2 considers the cooling surface and only considers contact of a flat surface.
Patent Document 3 relates to a battery module having secured insulation performance and a battery pack including the same. Patent Document 3 includes a battery cell stack constituted by a plurality of stacked battery cells, a module frame configured to receive the battery cell stack, and first and second thermal resin layers formed between a bottom portion of the module frame and the battery cell stack so as to be spaced apart from each other, wherein a first insulating coating layer is formed between the first thermal resin layer and the second thermal resin layer.
In Patent Document 3, insulation performance is focused, and the thermal resin layer is formed on the bottom portion of the module frame while the insulating coating layer is formed on the part where no thermal resin layer is formed, i.e., the part where no resin is applied, to secure insulation performance. Patent Document 3 is applied to a general battery module, as shown in
Patent Document 4 relates to a composite sheet and a battery pack using the same. In Patent Document 4, a plurality of thermally conductive sheets and a plurality of insulating sheets are provided. Patent Document 4 has an area of good thermal conductivity and an area of good insulation, which is not suitable for a CTP for energy maximization.
Patent Document 5 relates to a battery module and a battery pack including the same. Patent Document 5 includes a battery cell stack constituted by a plurality of stacked battery cells, a module frame configured to receive the battery cell stack, a thermal resin layer located between a lower surface of the module frame and the battery cell stack, and a first adhesive layer located between neighboring ones of the plurality of battery cells, wherein the module frame is provided in a lower surface thereof with an injection hole configured to allow a thermal resin to be injected therethrough, and the first adhesive layer is formed adjacent to the thermal resin layer. Patent Document 5 has a configuration as shown in
Configurations are not yet available for a simplified battery module with partially exposed battery cells or a cell to pack (CTP), in which battery cells are directly assembled to a battery pack, in order to maximize efficiency of an assembly process and energy, and wherein 1) a uniform density of contact on all surfaces of unstructured battery cells is achieved to provide uniform thermal conduction efficiency, 2) it is not necessary to apply separate pressure for contact with the surfaces of the unstructured battery cells, 3) the distance from a heat sink is minimized while the above conditions are maintained, 4) insulation performance is maintained even with minimal thickness, and 5) the entirety of a battery cell stack is easily removed from a battery pack.
The present invention has been made in view of the above problems, and it is an object of the present invention to provide configurations wherein 1) a uniform density of contact on all surfaces of unstructured battery cells is achieved to provide uniform thermal conduction efficiency, 2) it is not necessary to apply separate pressure for contact with the surfaces of the unstructured battery cells, 3) the distance from a heat sink is minimized while the above conditions are maintained, 4) insulation performance is maintained even with minimal thickness, and 5) the entirety of a battery cell stack is easily removed from a battery pack for a simplified battery module with partially exposed battery cells or a cell to pack (CTP), in which battery cells are directly assembled to a battery pack, in order to maximize efficiency of an assembly process and energy.
In order to accomplish the above object, the present invention provides a battery pack including a battery cell stack including at least one battery cell, a heat transfer portion disposed in direct contact with the battery cell of the battery cell stack, the heat transfer portion being configured to transfer heat, and a heat sink disposed so as to face the heat transfer portion, the heat sink being configured to discharge the heat, wherein an insulating film is disposed between the heat transfer portion and the heat sink, and the heat transfer portion includes a thermal resin.
In addition to the thermal resin, a material configured to improve heat conduction, such as carbon nanotubes, may be further added to the heat transfer portion. The additional material may improve heat conduction while exhibiting low electrical conductivity.
The thermal resin may be bonded to at least one surface of the battery cell stack, and specifically the thermal resin may be bonded to a lower surface of the battery cell stack. The thermal resin may also be bonded to an upper surface of the battery cell stack. In this case, the insulating film may be disposed at an upper surface of the thermal resin, and the heat sink may be disposed at an upper surface of insulating film.
The thermal resin may be bonded to the entirety of the lower surface of the battery cell stack, and the outermost part of the lower surface of the battery cell stack having the thermal resin bonded thereto may be flat.
The insulating film may face each of the heat transfer portion and the heat sink and may be bonded to only one thereof. Specifically, the insulating film may be bonded to only the heat transfer portion.
The thermal resin may be a liquid adhesive and may be at least one of a urethane-based, a silicone-based, an acrylic-based, and an epoxy-based resin.
The insulating film may be a film including at least one of PET, PE, and urethane.
The battery cell may be one of a cylindrical battery cell, a prismatic battery cell, and a pouch-shaped battery cell.
The battery pack may be a cell to pack (CTP) configured such that a battery cell is directly assembled to a battery pack or a simplified battery module with a partially exposed battery cell.
In addition, the present invention may provide combinations of the above solving means.
For a simplified battery module with partially exposed battery cells or a cell to pack (CTP), in which battery cells are directly assembled to a battery pack, in order to maximize efficiency of an assembly process and energy, the present invention has the following effects.
1) A uniform density of contact on all surfaces of unstructured battery cells is achieved to provide uniform thermal conduction efficiency.
2) It is not necessary to apply separate pressure for contact with the surfaces of the unstructured battery cells. In a CTP in which assembly up to an upper plate has been completed, heat transfer efficiency is not affected even though there is a gap between the upper plate and a battery cell stack.
3) The distance from a heat sink is minimized while the above conditions are maintained, whereby it is possible to reduce the size and to improve heat transfer efficiency.
4) Insulation performance between the battery cell stack and a pack frame and a pack plate may be maintained even with minimal thickness.
5) It is possible to easily separate the battery cell stack from the battery pack in an intact form without damage to the battery cell stack. This facilitates future repair and maintenance.
Now, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings such that the preferred embodiments of the present invention can be easily implemented by a person having ordinary skill in the art to which the present invention pertains. In describing the principle of operation of the preferred embodiments of the present invention in detail, however, a detailed description of known functions and configurations incorporated herein will be omitted when the same may obscure the subject matter of the present invention.
In addition, the same reference numbers will be used throughout the drawings to refer to parts that perform similar functions or operations. In the case in which one part is said to be connected to another part throughout the specification, not only may the one part be directly connected to the other part, but also, the one part may be indirectly connected to the other part via a further part. In addition, that a certain element is included does not mean that other elements are excluded, but means that such elements may be further included unless mentioned otherwise.
In addition, any limitations or additions to any embodiment described herein are not limited to a specific embodiment but are equally applicable to all embodiments described herein.
Also, in the description of the invention and the claims of the present application, singular forms are intended to include plural forms unless mentioned otherwise.
Also, in the description of the invention and the claims of the present application, “or” includes “and” unless mentioned otherwise. Therefore, “including A or B” means three cases, namely, the case including A, the case including B, and the case including A and B.
In addition, all numeric ranges include the lowest value, the highest value, and all intermediate values therebetween unless the context clearly indicates otherwise.
Embodiments of the present invention will be described in detail with reference to the drawings.
Specifically, each of the upper cell case part 62 and the lower cell case part 61 is provided with a pouch-shaped space portion configured to receive the electrode assembly.
The space portion configured to receive the electrode assembly is formed in the cell case using a laminate sheet constituted by an outer covering layer, a metal layer, and an inner covering layer.
The inner covering layer is disposed in direct contact with the electrode assembly, and therefore the inner covering layer must exhibit high insulation properties and high electrolytic resistance. In addition, the inner covering layer must exhibit high sealability in order to hermetically isolate the cell case from the outside, i.e., a thermally-bonded sealed portion between inner layers must exhibit excellent bonding strength.
The inner covering layer may be made of a material selected from among a polyolefin-based resin, such as polypropylene, polyethylene, polyethylene acrylic acid, or polybutylene, a polyurethane resin, and a polyimide resin, which exhibit excellent chemical resistance and high sealability; however, the present invention is not limited thereto, and polypropylene, which exhibits excellent mechanical properties, such as tensile strength, rigidity, surface hardness, and impact resistance, and excellent chemical resistance, is preferably used.
The metal layer, which abuts the inner covering layer, corresponds to a barrier layer configured to prevent moisture or various kinds of gas from permeating into the battery from the outside. An aluminum thin film, which is lightweight and easily shapeable, may be used as a preferred material for the metal layer.
The outer covering layer is located at the other surface of the metal layer, and the outer covering layer may be made of a heat-resistant polymer that exhibits excellent tensile strength, resistance to moisture permeation, and resistance to air transmission such that the outer covering layer exhibits high heat resistance and chemical resistance while protecting the electrode assembly. As an example, the outer resin layer may be made of nylon or polyethylene terephthalate; however, the present invention is not limited thereto.
The electrode assembly, which is received in the upper cell case part 62 and the lower cell case part 61, may be classified as a stacked type electrode assembly, which is configured to have a structure in which a plurality of electrodes is stacked, a jelly-roll type electrode assembly, which is configured to have a structure in which a positive electrode and a negative electrode are wound in the state in which a separator is interposed therebetween, a laminated and stacked type electrode assembly, which is configured to have a structure in which a plurality of unit cells is stacked, or a stacked and folded type electrode assembly, which is configured to have a structure in which a unit cell is wound in a state of being located on a separator sheet.
In order to manufacture the laminated and stacked type electrode assembly and the stacked and folded type electrode assembly, a unit cell is manufactured, wherein the unit cell may be a mono-cell, which is configured to have a structure in which a separator is interposed between a positive electrode and a negative electrode, or a bi-cell, which is configured to have a structure in which a positive electrode, a negative electrode, and a positive electrode are stacked, or a negative electrode, a positive electrode, and a negative electrode are stacked, and a separator is interposed between the positive electrode and the negative electrode.
The electrode assembly according to the present invention may have a structure in which a negative electrode, a separator, a positive electrode, a separator, and a negative electrode are stacked. In addition, the number of positive electrodes and negative electrodes constituting the electrode assembly may be freely set. Furthermore, a laminated and stacked type electrode assembly, in which a plurality of unit cells is laminated, may be used. The structure of the electrode assembly may be applied to any of the electrode assemblies described herein.
A positive electrode tab and a negative electrode tab are provided respectively at the positive electrode and the negative electrode of the electrode assembly, and the pair of tabs is disposed so as to protrude outward from the cell case by a predetermined length in a state of being connected respectively to a positive electrode lead 66 and a negative electrode lead 67 by spot welding or the like.
The insulating film is located on an upper surface and a lower surface of each of the pair of electrode leads, more specifically on the sealed portion 65 at which the upper cell case part 62 and the lower cell case part 61 are thermally fused. The insulating film prevents electricity generated by the electrode assembly from flowing to the cell case through the electrode leads, and maintains a seal between the electrode leads and the cell case. The insulating film is preferably a non-conductive material that does not conduct electricity well, and an insulating tape, which is easily attached to the electrode leads and is relatively thin, is commonly used; however, the present invention is not limited thereto.
A pouch-shaped battery having electrode tabs located at opposite sides of an electrode assembly is mainly used in a battery module or a battery pack. A plurality of pouch-shaped batteries each having a positive electrode tab and a negative electrode tab located at opposite sides is vertically disposed to constitute a pouch-shaped battery assembly, and busbars configured to electrically connect the positive electrode tabs and the negative electrode tabs, specifically the positive electrode leads and the negative electrode leads, to each other is disposed at opposite ends of the pouch-shaped battery assembly. The busbars disposed at the opposite ends of the pouch-shaped battery assembly may be electrically connected to each other.
The thermal resin 260 is bonded to at least one surface of the battery cell stack 220, specifically to a lower surface of the battery cell stack 220.
The thermal resin is a liquid adhesive, which has similar thermal conductivity to a conventional foam pad. This is because the thermal resin may be manufactured using a material identical or similar to the material used in the foam pad. Since the liquid adhesive is used, it is possible to fully fill all unstructured parts of a lower surface of the battery cell stack with the liquid adhesive.
It may take about 24 or 48 hours to fully harden the liquid adhesive. This is the time until the liquid adhesive is fully hardened, and the liquid adhesive is initially hardened while the shape of the liquid adhesive is maintained for 2 to 8 hours. Some products may be fully hardened in 2 to 8 hours.
The thermal resin 260 is bonded to the entirety of the lower surface of the battery cell stack 220, and the outermost part of the lower surface of the battery cell stack 220 having the thermal resin 260 bonded thereto is flat.
When the liquid adhesive is used for the battery cell stack, the viscosity of the liquid adhesive is preferably 150 to 300 cP. In order to flatten the lower surface having the thermal resin bonded thereto, 1) a method of placing an insulating film on a flat floor, applying a liquid adhesive thereto, placing a battery cell stack thereon, and pressing the battery cell stack or 2) a method of applying a liquid adhesive to only a region of an unstructured part of a battery cell stack that is in contact with a floor, disposing insulating film thereon, and disposing the same on a flat floor may be used.
Although the pouch-shaped battery cell has been described in the present invention, the present invention is not limited thereto, and a cylindrical battery cell or a prismatic battery cell may be used.
In order to reduce the thickness of the thermal resin, the thermal resin may be flattened from the most downwardly protruding region of the unstructured part of the battery cell stack to the outermost side thereof. If a large amount of liquid adhesive is used at once, the liquid adhesive may flow down before the liquid adhesive takes shape, and therefore the amount of the liquid adhesive may be adjusted or the shape of the liquid adhesive may be formed after partial hardening.
In general, the application thickness of the adhesive is, but is not limited to, 0.5 mm to 3.0 mm. For a pouch-shaped battery cell, the center of a lower part of each individual battery cell is convex, and therefore the application thickness of the adhesive may be varied to fill all unstructured spaces caused by such a shape. Referring to
The lower surface of the battery cell stack may or may not be flat. The thermal resin is attached to the lower surface of the battery cell stack to flatten the outermost part of the lower surface of the battery cell stack. The thermal resin also serves to fill the irregular outer surface or the empty space of the battery cell stack or the battery. An insulating film 290 is attached the thermal resin 260. A planar heat sink 280 is disposed under the insulating film 290 so as to face the insulating film, whereby face-to-face contact therebetween is facilitated. In addition, the insulating film 290 is not adhesive or sticky, and therefore the insulating film 290 is easily separated from the heat sink 280 for future separation.
The insulating film 290 faces each of the thermal resin 260 and the heat sink 280, and is bonded to only one of the thermal resin 260 and the heat sink. Specifically, the insulating film 290 is bonded to only the thermal resin 260. Although only the thermal resin 260 is shown here, this is an example of a heat transfer portion according to the present invention. The heat transfer portion according to the present invention includes a thermal resin, and may be constituted by only the thermal resin or may further include another thermally conductive material in addition to the thermal resin.
The thermal resin 260, which is a liquid adhesive, is at least one of a urethane-based, a silicone-based, an acrylic-based, and an epoxy-based resin. The silicone-based adhesive is not suitable for products such as a vehicle because siloxane may be generated therefrom. The preferred liquid adhesive is the urethane-based adhesive because the urethane-based adhesive basically exhibits insulation performance and can be used in an enclosed space of a vehicle. In addition, the urethane-based adhesive exhibits high adhesion and high thermal conductivity. In order to further increase thermal conductivity, metal particles having high thermal conductivity may be added to the liquid adhesive.
The insulating film 290 is a film including at least one of polyethylene terephthalate (PET), polyethylene (PE), and urethane. Any thin film may be used as the insulating film, and the insulating film may include at least one of PET, PE, and urethane. Since urethane is an insulating material, a urethane film is preferably used as the insulating film; however, the present invention is not limited thereto. In practice, the thickness of the film is less than the thickness of the thermal resin, and the thermal conductivity of the insulating film is not significantly different from the thermal conductivity of the thermal resin, whereby an insulating film having a thickness of 0.5 mm or less, preferably 0.2 mm or less, more preferably 0.1 mm or less, does not significantly affect thermal conduction.
As another configuration, an adhesive pad having a film already attached to the outside thereof may be used. The adhesive pad may be directly attached to the battery cell stack. However, the adhesive pad is preferably applied to the flat lower part of the battery cell stack.
Those skilled in the art to which the present invention pertains will appreciate that various applications and modifications are possible within the category of the present invention based on the above description.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2022-0182832 | Dec 2022 | KR | national |
The present application is a National Phase entry pursuant to 35 U.S.C. § 371 of International Application No. PCT/KR2023/021246 filed Dec. 21, 2023, and claims priority to and the benefit of Korean Patent Application No. 2022-0182832 filed on Dec. 23, 2022, the disclosures of which are incorporated herein by reference in their entirety.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/KR2023/021246 | 12/21/2023 | WO |