Embodiments of the present disclosure generally relate to large capacity electric air heater systems capable of heating gases, or other fluids, to temperatures in excess of 343° C.
Electrical heating of gases can be carried out using an intermediate heat transfer fluid, such as hot oil or molten salt. However, such systems have a maximum operating temperature of 400° C. Electrical heating of gases at higher temperatures is typically achieved via one of two types of electrical heater systems.
First, electrical heating may be achieved by using a gas heater assembly, which relies on convective heating of gases. Gas heater assemblies are widely available commercially, however current designs are limited in their ability to heat large volumes of air in a single enclosure to a high temperature with a low pressure drop. Further, currently available gas heater modules are also characterized by small channel sizes, direct contact between heating elements and process gases, and low watt densities due to the high temperature of the heating element which is required to dissipate heat. This, in turn, causes overheating and premature failure of heating elements.
Alternatively, furnace tube assemblies are also currently available commercially. A furnace tube assembly is a modular assembly, which is characterized by discrete heating device sections installed into a casing. Furnace tube assemblies transfer heat radiatively between heating elements and furnace tubes and then from the furnace tubes to the workpiece. Attempts to increase surface area by adding an extended surface offers only modest improvements due to the lower view factor which exists between the extended surface and the radiatively heated workpiece.
Current solutions are typically characterized by a number of undesirable factors. First, process gases are often exposed directly to heating elements. This may limit the number of different process gases that can be heated within the heater assemblies. In particular, process gases which are corrosive, flammable, or otherwise difficult to work with would be excluded from use with such heater assemblies. In addition, direct flow of gases over heating elements can cause heating elements to vibrate or otherwise move. This can lead to short circuiting or breakage at connection points. Further, current solutions also involve flowing process gases directly through tubes within a larger, conventional heater assembly.
Currently available electric heaters are also limited in that they include flow channels with relatively small cross-sections and high flow resistance. This reduces the suitability of the heater for heating large volumes of gas, while maintaining a low pressure drop.
This summary is provided to introduce a selection of concepts that are further described below in the detailed description. This summary is not intended to identify key or essential features of the claimed subject matter, nor is it intended to be used as an aid in limiting the scope of the claimed subject matter.
In one or more aspects, embodiments disclosed herein relate to an electric air heater system including a first electric air heater module. The first electric air heater module including an outer casing having an inner surface, a first end, and a second end; a refractory insulation layer in tight communication with the outer casing; an inner cavity within the refractory insulation layer; and a plurality of tubes extending through the inner cavity from the first end to the second end, the plurality of tubes each having an exterior surface. Each tube is fixed relative to the outer casing at the first end, and each tube has an electrical connection disposed at the first end. The plurality of tubes is arranged into one or more bundles of tubes, where each bundle includes two or more tubes having a plurality of fins extending radially from the exterior surface, and a heating element axially through a hollow interior of the tube, and a sleeve supporting each of the plurality of tubes at the second end of the outer casing.
In other aspect, embodiments disclosed herein relate to an electric air heater. The electric air heater including an outer casing, having an inner surface defining an inner cavity, a first end, and a second end; a refractory insulation layer in tight communication with the outer casing; and a plurality of tubes extending axially through the inner cavity from the first end to the second end, the plurality of tubes each having an exterior surface. The plurality of tubes is arranged radially around an axial center of the inner cavity. Each tube is fixed relative to the outer casing at the first end, and each tube has an electrical connection disposed at the first end. Each tube has a plurality of fins arranged extending radially from the exterior surface, an electrical heating element disposed axially through a hollow interior of the tube, and a sleeve supporting each of the plurality of tubes at the second end of the outer casing.
In yet another aspect, embodiments disclosed herein relate to a method of heating air. The method including directing a volume of air into an electric air heater having an inner cavity, directing the volume of air through the inner cavity, and heating the volume of air.
Other aspects and advantages of the claimed subject matter will be apparent from the following description and the appended claims.
Specific embodiments of the disclosed technology will now be described in detail with reference to the accompanying FIGURES. Like elements in the various FIGURES are denoted by like reference numerals for consistency. The size and relative positions of elements in the drawings are not necessarily drawn to scale. For example, the shapes of various elements and angles are not necessarily drawn to scale, and some of these elements may be arbitrarily enlarged and positioned to improve drawing legibility. Further, the particular shapes of the elements as drawn are not necessarily intended to convey any information regarding the actual shape of the particular elements and have been solely selected for ease of recognition in the drawing. Additionally, a single reference numeral may be used to denote a flow line and the process stream within the flow line.
In the following detailed description of embodiments of the disclosure, numerous specific details are set forth in order to provide a more thorough understanding of the disclosure. However, it will be apparent to one of ordinary skill in the art that the disclosure may be practiced without these specific details. In other instances, well-known features have not been described in detail to avoid unnecessarily complicating the description.
Throughout the application, ordinal numbers (e.g., first, second, third, etc.) may be used as an adjective for an element (i.e., any noun in the application). The use of ordinal numbers is not to imply or create any particular ordering of the elements nor to limit any element to being only a single element unless expressly disclosed, such as using the terms “before,” “after,” “single,” and other such terminology. Rather, the use of ordinal numbers is to distinguish between the elements. By way of an example, a first element is distinct from a second element, and the first element may encompass more than one element and succeed (or precede) the second element in an ordering of elements.
In the following description of
It is to be understood that the singular forms “a,” “an,” and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to “an electric heater module” includes reference to one or more of such electric heater modules.
Terms such as “approximately,” “substantially,” etc., mean that the recited characteristic, parameter, or value need not be achieved exactly, but that deviations or variations, including for example, tolerances, measurement error, measurement accuracy limitations and other factors known to those of skill in the art, may occur in amounts that do not preclude the effect the characteristic was intended to provide.
It is to be understood that one or more of the steps shown in the flowcharts may be omitted, repeated, and/or performed in a different order than the order shown. Accordingly, the scope disclosed herein should not be considered limited to the specific arrangement of steps shown in the flowcharts.
Although multiple dependent claims are not introduced, it would be apparent to one of ordinary skill that the subject matter of the dependent claims of one or more embodiments may be combined with other dependent claims.
Disclosed herein are embodiments of an electric air heater system which may sustain high temperatures, particularly those in excess of 343° C. In one or more embodiments, the electric air heater system may heat large volumes of air, or any other fluid, to temperatures of up to 760° C. In some embodiments, air, steam, or other fluids may be heated to a temperature of up to 900° C., 950° C., 1000° C., 1050° C., 1100° C. or even up to 1400° C. Further, disclosed herein are embodiments of an electric air heater system that combines radiative heat transfer from heating elements to tubes, and convective heat transfer from tubes to a process gas flowing through the electric air heater system.
In addition, disclosed herein are embodiments of an electric air heater system using two or more banks of tubes. Each bank of tubes may have a varying power duty, where the total power of the electric air heater system is significantly higher than commercially available systems. In contrast, currently available systems require multiple heaters to be connected in series or parallel to achieve the same total power.
The central portion 110A, 110B may house the internal components of the electric air heater module. For example, a plurality of rows 108A, 108B of tubes 102A, 102B may be arranged such that the tubes 102A, 102B extend through the central portion 110. In one or more embodiments, there may be 25 rows 108A, 108B of tubes 102A, 102B arranged within the central portion 110A, 110B and more than 5 tubes 102A, 102B in the same row. However, in other embodiments there may be between 5 and 50 rows 108A, 108B arranged within the central portion 110A, 110B. The number of rows used may depend upon the desired temperature rise (heating) of the fluid passing over and around the tubes, and in some embodiments greater than 50 rows may be used, such as 60, 70, 80, 90, 100 or more rows.
Turning now to
In one or more embodiments, a gas, such as air 120 or another process gas, may be directed through the inner cavity 114, where the gas may be heated. In one or more embodiments, the electric air heater module 100 may have geometry that is rectangular, square, cylindrical, or any combination thereof. In embodiments where particularly high pressures are present, the electric air heater module 100 may have more than one outer casing 104 layer, which may cascade the operating pressure and minimizing casing deflection. Further, embodiments with more than one outer casing 104 layer may add an extra safety factor for heater operation and may maintain thermal insulation integrity.
A plurality of tubes 102 may be arranged in several rows throughout the inner cavity 114. The tubes may be of a similar or different outer diameter and may be disposed within the inner housing of the heater module using a uniform or a non-uniform spacing. In one or more embodiments, the tubes 102 may be made from an alloy suited for high furnace temperatures. However, since the gas flow through the electric air heater module 100 may cool the tubes 102, the alloy may be selected for a lower design temperature than would be needed if the tube 102 itself were the resistance heating element. For example, in one or more embodiments, the tubes 102 may be made from 304 stainless steel or an INCONEL alloy. For modules having a curved geometry, such as a cylindrical inner housing, the effective length of the tubes disposed within the inner housing may vary, such as where a length of the tube traversing proximate the center of the cylindrical housing are longer than tubes traversing proximate a side of the cylindrical housing.
Each tube 102 may have a plurality of fins 103 arranged circumferentially on a tube exterior surface. In one or more embodiments, the plurality of fins 103 extends radially from the exterior surface of each tube 102. Alternatively, there may be embodiments in which the plurality of fins 103 are arranged in a tight helical pattern around the exterior surface of each tube 102. The plurality of fins 103 may increase the surface area for convective heat transfer between each tube 102 and the gas directed into the electric air heater module 100 for heating. In one or more embodiments, the fins 103 may be circular fins. However, in other embodiments the fins 103 may be solid fins, serrated fins, or stud fins. In one or more embodiments, the fins may have an outer diameter, a fin frequency, a fin height and a fin thickness, all of which may be selected to fit situational heating needs and promote turbulent flow within the heater. The fin height, fin thickness, number of fins per unit length, and other fin variables may vary between the tubes. For example, fins provided on tubes proximate an inlet of the heater module may be different than fins proximate an outlet of the heater module. In some embodiments, for example, the fins may be made from an 18-chromium-8-nickel alloy or a 11-13 chromium alloy. However, it should be understood that these are only examples, and there are many other alloys which may also be used without departing from the scope of this disclosure.
Each tube 102 may also have a heating element 101 extending axially through the interior of the tube 102. There may be many different types of heating elements 101 which may be utilized within the tubes 102. In one or more embodiments, the heating elements 101 may be iron-chromium-aluminum metallic wires or nickel-chromium metallic wires. However, in other embodiments the heating elements 101 may be silicon carbide rod-type heating elements or molybdenum disilicide heating elements. In one or more embodiments, the heating elements 101 may be bent into a U-shape or a hairpin shape such that an electrical circuit is formed between the two ends of the element. Further, individual heating elements 101 may be grouped into bundles, which may be supported by ceramic spacers installed along the length of the tubes 102. The individual heating elements 101 may be grouped together in a parallel configuration, a series configuration, or both configurations simultaneously depending on the element types and situational needs.
In one or more embodiments, the heating elements 101 may radiatively heat the tubes 102. The tubes 102 may convectively dissipate heat as the cooler, process gas passes over the tubes 102, lowering the temperature of the tubes 102. Heat dissipation may also be enhanced by the installation of fins 103, which increase the effective surface area for convective heat transfer. Further, convective heat transfer may reduce the temperature of both the tube 102 and the heating element 101, allowing for the heating elements 101 to maintain a higher watt density than would otherwise be possible.
Turning now to
In one or more embodiments, a variety of sensors and connections may be installed within the electric air heater module 100. For example, in some embodiments, thermocouples and/or pressure sensors/connections may be installed as needed within the electric air heater modules.
At a first end 116, the tube 102 may be fixed with a seal flange 222, which may be welded to the tube 102 and the sleeve 209. A cable 107a may extend from the seal flange 222 to the heating element 101. The seal flange 222 may have a central opening which may be sufficient in size to insert and withdraw the heating element 101. An end cap 223 may be provided to maintain heating elements in position. In one or more embodiments, the end cap 223 may be external to the refractory insulation layer 106. An electrical pass-through connection 221 may be provided through the end cap 223 and into the tube 102. The portion of the tube 102 through which the cable 107a extends may be referred to as an unheated length 224.
In one or more embodiments, a plurality of ceramic element supports 213 may be spaced throughout the tube 102 such that the heating element 101 is supported within the tube 102. The ceramic element supports 213 may be equally spaced throughout the tube 102, though there may also be embodiments in which the ceramic element supports 213 are not equally spaced.
In one or more embodiments, a plurality of fins 103 may be arranged circumferentially around the exterior surface of the tube 102. The plurality of fins 103 may assist in dissipating heat away from the heating elements, thus improving heating of the air within the electric air heater module.
A sleeve 209 may be tightly fitted around the tube 102 in the unheated length 205. In one or more embodiments, the sleeve 209 may define an outer portion of the insulation layer 106, which may be positioned at the first end 116 of the outer casing 104. The sleeve 209 may extend from the outer casing 104 and through an insulation layer 106. In one or more embodiments, the insulation layer 106 may be a refractory type insulation such as castable, ceramic fiber, insulating board, or any other type of high temperature insulating material.
Turning now to
Radial expansion of the tube 102 may causes an increase in tube radius. In one or more embodiments, expansion may be on the order of millimeters. However, the order of expansion may differ based on the specific application and use of the electric air heater module.
In one or more embodiments, a vibration dampener 411 may be used to support the tube 102 at the second end 118. Further, the vibration dampener 411 may allow for thermal expansion of the tube 102, as well as reducing or preventing vibration of the tube 102 due to flow induced vibration. In one or more embodiments, a casing section or a cap 410 may be installed to seal the furnace environment from the external environment. The casing section or cap 410 may have assorted designs and geometry and may be insulated either externally or internally depending on situational needs.
Turning now to
A vibration dampener 411 may be installed at the end of the first section 102a and at the end of the second section 102b. Further, a sleeve 209 may be installed from the end of the first section 102a to the beginning of the second section 102b to provide support for each section. In one or more embodiments, the tube 102 may have an electrical connection 107 installed at both the first end 116 and the second end 118, such that the tube 102 is fixed at both the first end 116 and the second end 118. Embodiments such as that depicted in
In one or more embodiments, a baffle 708 may be installed in the center of the outer casing 704 and the inner cavity 714, such that air flow from one side of the radial electric air heater module 700 to the other side is prevented. In such embodiments, air 120 may be directed into either end of the inner cavity 714, where each inner cavity 706 opening may act as an inlet 716, 718. The positioning of the baffle 708 may force air entering each inlet 716, 718 to flow through the plurality of rows 702 to reach an outlet 710. The air temperature in the upper half of the radial electric air heater module 700, i.e., the half closest to the outlet, may be higher than that in the lower half. However, there may be additional internal baffles installed in one or more embodiments to promote air flow around the entirety of the tubes 702, rather than just those in the upper half of the radial electric air heater module 700.
A baffle 808 may be installed in a center of the radial electric air heater module 800. In one or more embodiments, the baffle 808 may extend completely through the interior of the outer casing 804 and the inner cavity 814. In such embodiments, the baffle 808 may have a number of perforations in the surface area surrounding the inner cavity 806, such that air may flow through the perforations. In other embodiments, the baffle 808 may be disposed only in the inner cavity 814, such that air 120 may be free to flow through the interior of the outer casing 804 outside of the inner cavity 814.
In one or more embodiments, air 120 may be directed into the inlet 807 of the inner cavity 814, before being forced out of axial perforations 811 by the presence of the baffle 808 blocking air flow directly through the inner cavity 814. Air 120 may then be forced through the rows of tubes 802, such that air may flow through the entire interior of the outer casing 804. In one or more embodiments, there may be additional internal baffles (not pictured) installed within the interior of the outer casing 804 to ensure equitable air flow through the entire interior of the outer casing 804, avoiding a concentration of air flow through a given segment of the outer casing interior.
After air has been forced through the rows of tubes 802, it may re-enter the inner cavity 814 after the baffle 808 through several axial perforations 811. Air 120 may then flow out of the radial electric air heater module 800 via the outlet 810.
Turning now to
In one or more embodiments, several rows 902 may be grouped together in a bundle 906. Within a bundle 906, the row spacing 904 may refer to the distance between each row 908. The bundle spacing 910 may refer to the distance between each bundle 906. Rows 902 and bundles 906 may be spaced and arranged to provide a tortuous flow path through the cavity, while additionally providing for sufficient spacing for expansion of the tubes 902 and fins and maintaining a relatively low pressure drop.
The electric air heater module 900 may have a height 912, which may be defined as the distance between the entry 914 and the exit 916. Further, the electric air heater module 900 may have a width 918, which may be defined as the distance between refractory insulation layers 920. The effective row height 922 may refer to the distance between the first and the last row 908 arranged within the electric air heater module 900. Similarly, the effective tube length 924 may refer to the length of each tube 902.
The number of tubes per row may vary within a bundle, such as a greater or fewer number of tubes in a first row as compared to a second row. For example, a row proximate an inlet of the heater may have a small number of central rows, accounting for eddies and development of flow within the heater from the inlet to a region of fully developed flow that may have a greater number of tubes per row. Further, the number of tubes, the number of tubes per row, may vary between a first bundle and a second bundle within the electric air heater module, similarly accounting for development of flow and changing flow dynamics and fluid properties as the gas passing through the heater is being heated.
The row spacing within a bundle may be uniform or non-uniform, and may vary, such as closer proximate an inlet of a heater and more spaced apart proximate an outlet of the heater, or vice versa. Similarly, the row spacing in the multiple bundles may be similar or different. As noted above, the bundle configurations may be varied from heater inlet to heater outlet to account not only for flow development, but to also account for changes in flow dynamics and fluid properties through the heater.
For embodiments having fins on the tubes, the fin height, fin thickness, number of fins per unit length, and other fin variables may vary between the tubes within a row, between rows of a bundle, or between bundles. For example, a first row or first bundle within a heating module may have a different fin configuration than a second row or second bundle within a heating module, respectively.
For heaters having two or more modules disposed in series, the modules may be of a similar design or of different design, accounting for fluid flow and properties, as noted above. Each module may be designed with an appropriate configuration with respect to one or more of module height, module width, row height, tube spacing, tube height, tube diameter, tube length, number of tubes per row, number of tubes per module, number of fins per unit length of tubes, fin height, fin thickness, materials of construction, etc., so as to provide the desired heat exchange.
In one or more embodiments, there may be several spare rows 926 installed. In one or more embodiments, spare rows 926 may also be referred to as empty rows. A spare row 926 may refer to a row 908 of tubes 902 which do not have installed heating elements, or in which the heating elements are not powered. For example, in some embodiments, there may be three spare rows 926 installed, where the spare rows 926 are interspersed amongst the bundles 906. Spare rows 926 may be utilized in case of failure of one or more heating elements within a row 908. For example, if a row 908 has one or more tubes 902 with failed heating elements, new heating elements can be inserted into the tubes 902 of one of the spare rows 926, or the un-powered heating elements may be powered. The spare row 926 can then act in the same manner as any other row 908. Further, the failed heating elements may be removed, creating a new spare row 926. In such a manner, heating elements may be repaired, including installation and removal, while the electric air heater module 900 is still in operation at full capacity. In embodiments where the heating element is to be removed, the weld on the seal flange may need to be cut and rewelding according to techniques known in the art.
Turning now to
The first bundle 1014 may have a tube metal temperature (TMT), which refers to the temperature of the tube 1002. The first bundle 1014 may also have an inside temperature (Inside T), which may refer to the temperature of the heating element (such as 101 in
Similarly, each of the second through the fifth bundles 1016, 1018, 1020, 1022 may have a TMT values, an inside T value, and a power value. In one or more embodiments, the respective TMT values, inside T values, and power values for each of the bundles 1014, 1016, 1018, 1020, 1022 may be different. However, there may be some embodiments in which one or more of the values are the same or substantially similar. In one or more embodiments, the electric air heater module 1000 may have a defined air flow rate in order to ensure maximum heating, as well as a total duty.
Table 1 displays an exemplary example of the electric air heater module 1000, with approximate ranges for each parameter related to the various components within the electric air heater module 1000. Though Table 1 describes one exemplary example, there may be many exemplary examples which may exist, each with varying parameter ranges, without departing from the scope of this disclosure.
In one particular example, the electric air heater module 1200 may have an air flow rate of 313,800 kg/h and a total duty of 25.8 MMkcal/h. In the same example, the entry temperature 1210 may be 394° C. and the exit temperature 1212 may be 714° C. The first bundle 1214 may have a TMT of 635° C., an Inside T of 660° C., and a power of 80 kW per heating element. The second bundle 1216 may have a TMT of 700° C., an Inside T of 725° C., and a power of 80 kW per heating element. The third bundle 1218 may have a TMT of 765° C., an Inside T of 790° C., and a power of 80 kW per heating element. The fourth bundle 1220 may have a TMT of 800° C., an Inside T of 840° C., and a power of 80 kW per heating element. The fifth bundle 1222 may have a TMT of 830° C., and Inside T of 850° C., and a power of 60 kW per heating element.
In one or more embodiments, the Inside T value may be higher than the TMT value. Further, the power value may vary between bundles. Though one example is presented above, it should be understood that there are many other examples which may also be implemented in an electric air heater module such as that shown in
Turning now to
In one or more embodiments, the first and second electric air heater portions 1104, 1106 may be stacked at an angle, such that one electric air heater portion faces in one direction and the second electric air heater portion faces in another direction. In one or more embodiments, the first and second electric air heater portions may be offset by 90 degrees. In these embodiments, the tubes of the first electric air heater portion 1104 may be oriented at a 90-degree angle to the tubes of the second electric air heater portion 1106. However, it should be understood that this angle is simply an example, and the first and second electric air heater portions 1104, 1106 may be arranged with an offset of any angle between 0 degrees to 90 degrees without departing from the scope of this disclosure. Further, the tubes of the first electric air heater portion 1103 may be oriented at a 180° angle to the tubes of the second electric air heater portion 1106. The power connection of the portion 1104 and 1106 may then be at the opposite ends. Arranging successive electric air heater portions at an angle from the previous portion may provide more open space for the electrical power connection and more room for heater maintenance activities.
In one or more embodiments, the bundles of tubes 1102, particularly how many tubes are included in a bundle, may be determined based on desired total power. For example, each bundle of tubes 1102 may be a 5 MW unit, such that the power supply connected to the bundle of tubes 1102 is associated with a 5 MW transformer. This, however, is simply an example, and there may be many different transformers with varying power outputs which may be associated with each bundle of tubes 1102. By powering each bundle of tubes 1102 independently, the single electric air heater system 1100 may provide more than 170 MW of energy in some embodiments.
In one or more embodiments, the tubes 1102 located in the first electric air heater module 1104 may be made from the same material as the tubes 1102 located in the second electric air heater module 1106. However, in other embodiments the tube material may vary between the first and second electric air heater modules 1104, 1106.
Turning now to
In one or more embodiments, the electric air heater module may be a radial electric air heater module, such as those depicted in
In one or more embodiments, the electric air heater module may include one or more bundles of tubes, such as the bundle 906 depicted in
Embodiments of the present disclosure may provide at least one of the following advantages. In currently available commercial heaters, maximum temperature must be limited to avoid overheating of heating elements. Further, as gas flows over successive elements, the gas heats to a temperature where it is less able to dissipate heat. As such, the heater elements at the hottest part of the heater assembly must operate at much lower watt densities than is desired. Further, in many currently available air heaters, the heating elements are exposed within the heater, such that the gas flows directly over the elements.
In comparison, embodiments of the present disclosure allow for much higher temperatures and watt densities without causing overheating or failure of heating elements. Further, embodiments of the present disclosure allow for easy repair and replacement of heating elements during operation of the electric air heater. Since the heating elements are fully enclosed within tubes, which may be considered controlled environments, a stable oxide layer may be maintained on the heating element surface, prolonging the life of the element. In addition, positioning the heating elements within controlled environments allows for the heating of corrosive, flammable, or otherwise difficult product gases.
Embodiments of the present disclosure may also allow for a large volume flow of gas (for example, a mass flow rate of greater than 100,000 kg/h) to be heated at a low pressure from a nominal preheat temperature of 343° C. to over 760° C. However, embodiments of the present disclosure are not limited to a maximum inlet or minimum inlet temperature of 343° C. Further, embodiments of the present disclosure may allow for large volume heating, while maintaining a pressure drop of less than 13.8 kPa. In some embodiments, this pressure drop may also be limited to less than 7 kPa.
Embodiments of the present disclosure may also allow for avoidance of overheating of heating elements. The heat transfer induced from the heating elements to the tubes is primarily radiative and is controlled by the cooling of the tube by gas flowing through the inner cavity of the electric air heater module. Heat transfer may be further improved by adding fins to the outer circumference of the tube, thereby increasing the effective surface area for convective heat transfer, which improves dissipation of heat away from the tubes and cooling of the tubes.
Although only a few example embodiments have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the example embodiments without materially departing from this invention. Accordingly, all such modifications are intended to be included within the scope of this disclosure as defined in the following claims.
Number | Date | Country | |
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63379577 | Oct 2022 | US |