The present invention relates to an electric arc furnace and to a cooling arrangement for the refractory lining of such a furnace. More particularly, the present invention relates to a pig iron smelting electric arc furnace, which produces pig iron with a strongly stirred bath in order to allow a high specific power input (in the order of magnitude of 1 MW/m2), and to a cooling arrangement for cooling the refractory lining in this specific type of pig iron smelting furnace.
In a pig iron smelting electric arc furnace, pre-reduced iron and other metallic oxides are molten and reduced in order to produce ferroalloys. During operation, the temperature of the bath of molten metal (i.e. pig iron) in the furnace is normally between 1450° C. and 1550° C. In order to ensure a uniform bath temperature and to permit fast smelting of the input material, the electric arc power needs to be rapidly spread throughout the bath. In the aforementioned type of pig iron smelting furnace, this is achieved by strongly stirring the bath e.g. by means of nitrogen injection through porous plugs.
It is well known in the field of electric steel production that one of the zones of most pronounced refractory deterioration is the zone adjacent the interface between the bath of molten metal and the slag layer on top thereof. Refractory deterioration in this critical zone is due to various chemical, thermal and mechanical effects. Irrespective of the effects, it has been found that refractory deterioration increases with increasing temperature of the refractory lining and in particular of its hot face, i.e. where the refractory is in contact with the molten metal bath or the slag layer. Deterioration of the refractory lining being a significant cost factor, various attempts have been made to provide a cooling arrangement for cooling the refractory lining in the aforementioned critical zone.
In addition, besides the cost factor, there is a significant safety risk related to erosion of the refractory lining. In fact, if molten metal enters into direct contact with the furnace shell due to excessive local erosion of the refractory lining, a molten metal leakage may occur, in particular in the critical zone. This risk is specifically but not exclusively known with regard to pig iron smelting furnaces with strongly stirred and overheated bath. In order to avoid possible leakage of molten metal in case of a localised deficiency of the refractory lining, it is desirable to solidify the molten metal in contact with or prior to being in contact with the furnace shell. Since the bath of molten metal (i.e. pig iron) is strongly stirred and overheated by approximately 300° C. (the melting temperature of pig iron being approx. 1190° C.), it is difficult to solidify the molten metal by means of a cooling device in the aforementioned type of furnace.
It is generally accepted in the field that internal forced water cooling of the refractory lining, which is well known in blast furnaces, is not a viable solution for electric arc furnaces. As a matter of fact, the introduction of cooling liquid into the hot interior of the electric arc furnace implies a severe risk of explosion. This problem can be overcome by external spray cooling of the furnace shell, which is described for example in EP 0 044 512. By cooling the furnace shell externally, a temperature reduction of the refractory lining is achieved. There remains however the risk of a molten metal leakage, in case the refractory lining is excessively deteriorated in the critical zone. U.S. Pat. No. 3,777,043 describes an approach where gaseous coolant is circulated through channels which penetrate the refractory lining in the aforementioned critical zone. Besides the limited efficiency of gas type cooling, this solution requires an expensive installation of cooling channels and gas coolant circuitry and significant modifications in the refractory lining are necessary. A different approach is described in U.S. Pat. No. 3,849,587. In this approach, solid cooling members of high thermal conductivity are placed through the furnace shell and into the refractory lining. The length, cross sectional area, spacing and material of these rod-shaped members is chosen to conduct sufficient heat from the refractory lining. The cooling members can be cooled outside the furnace shell, e.g. by forced water cooling. Although cooling of the refractory lining is achieved with this approach, it has the drawbacks of creating considerable temperature gradients in the refractory lining and weakening the structure of the lining due to the penetration of the lining by the cooling members. A comparable approach is put forward in WO 95/22732 where the problem of the temperature gradients is addressed by multiplying the cooling elements and reducing their cross section. In this approach however, the structure of the lining is also weakened and installation and repair of the refractory lining is rendered even more difficult.
It is an object of the present invention to provide an electric arc furnace having an improved cooling arrangement which reduces or overcomes the aforementioned problems.
To achieve this object, the present invention proposes an electric arc furnace which comprises an outer shell and an inner refractory lining and contains a bath of molten metal during its operation. This bath of molten metal has a minimum and a maximum operational level. According to an important aspect of the present invention, a ring of copper slabs is mounted to the outer shell, in the region between the minimum and the maximum operational level and the copper slabs are in thermo-conductive contact with the inner refractory lining in this region between the minimum and the maximum operational level. According to another important aspect, the copper slabs are equipped with spray cooling means. The copper slabs are generally flat and comparatively thick pieces of solid material, i.e. without any cavities and in particular without internal cooling channels. According to the requirements, at least one of the faces of the copper slab may be curved but their longitudinal section is generally square or rectangular. Their height normally exceeds the vertical distance between the minimum and maximum operational level and they are mounted such that these operational levels are situated within an actively cooled area of the copper slabs. The copper slabs are mounted inside the outer shell where they constitute an inner cooling ring. They are in thermo-conductive contact with the refractory lining in the critical zone between the minimum and maximum operational level of the molten metal bath. Heat is dissipated by spray cooling of the copper slabs, such that a significant reduction in the temperature of the refractory lining in the critical zone is insured without creating a risk of explosion due to liquid entering the furnace. As will be appreciated, the present invention is equally applicable to alternating current (AC) and direct current (DC) electric arc furnaces.
In a preferred embodiment, the copper slabs are solid bodies having a smooth front face in contact with the inner refractory lining and a curved rear face for external rear cooling by the spray cooling means. The front and the rear face, which are respectively turned to the inside and the outside of the furnace, form the large faces of the body which has approximately the shape of a hexahedron or parallelepiped (except for the curved rear face). The copper slabs are mounted such that their front and rear faces are essentially vertical. The smooth front face allows for an efficient thermo-conductive contact with the refractory lining. The smooth front face is conjugated to the outer surface of the refractory lining and more specifically with to the normally flat or curved outer surface of the refractory bricks of the lining. As will be appreciated, both during construction and during repair, the refractory bricks can be easily placed contiguous to the smooth front face and no cutting or drilling of the refractory bricks is required. The curved rear face is adapted to the curvature of the normally cylindrical outer furnace shell.
Advantageously, the outer shell is provided with a corresponding rear cooling aperture for each of the copper slabs. The individual rear cooling apertures are dimensioned such that the copper slabs can be directly mounted to the remaining portion of the outer shell so as to overlap the aperture. Although larger apertures for a plurality of copper slabs could be envisaged, least possible weakening of the shell structure and facilitated sealing is insured by individual rear cooling apertures. In case of retrofitting an existing electric arc furnace, reinforcement means for reinforcing the outer steel shell may be installed prior to providing the rear cooling apertures.
In a preferred embodiment, a plurality of copper slabs are adjacently mounted to the inside of the outer shell so as to form a substantially continuous ring. Normally, the ring needs to be interrupted only at the location of the slag notch and the taphole of the electric arc furnace. With only these interruptions, maximum peripheral coverage by the inner cooling ring is obtained. In combination with the given height of the copper slabs, temperature gradients in the critical region of the refractory lining are reduced.
A temperature sensor is preferably associated to each of the copper slabs for monitoring the effective temperature of the copper slabs, in particular during operation of the furnace. Temperature information allows to obtain information on the condition of the refractory lining beforehand, without the need for an inspection shutdown. Using temperature measurements on each of the copper slabs, a circumferential profile regarding the state of thermal isolation of the furnace in general, and the condition of the remaining refractory lining in particular, can be established. Temperature information can also be used in process control of the electric arc furnace and the cooling arrangement in particular.
Advantageously, the width of the copper slabs is less than or equal to lm. Refractory deterioration is relatively unpredictable today, in particular in electric arc furnaces of the type with strongly stirred and/or overheated bath. Providing a sufficient number of copper slabs over the circumference of the furnace, each having a dedicated temperature sensor, insures a reliable detection of any local temperature increase on the furnace periphery. In fact, such an increase is indicative of refractory deterioration and thus of an imminent molten metal leakage. Since deterioration of the refractory is unpredictable, a local heating of the furnace shell known as “hot spot” can occur in furnaces devoid of the cooling ring as herein described. Until now such “hot spots” have often resulted in molten metal leakage and the related dangerous consequences. Detection of a temperature increase allows to establish an early warning system in order to avoid possible accidents. Moreover, preventive measures such as repair measures (e.g. gunning or “shotcreting” of the refractory lining) can be carried out effectively and in targeted manner since a detected temperature increase is well located.
In order to collect the spray cooling fluid and in order to warrant minimal pollution thereof, e.g. by flue dust, each of said copper slabs is preferably provided with a cooling box. Use of closed boxes on the rear face of the copper slabs is particularly advantageous where a closed cycle cooling circuit is required. The cooling boxes may be openable for inspection and maintenance purposes. The cooling boxes are preferably mounted to said copper slabs so as to protrude to the outside of said outer shell. This arrangement renders the rear face of the copper slabs and the associated spray cooling means easily accessible from outside the furnace, e.g. for inspection or maintenance purposes.
Beneficially, a spray cooling nozzle is removably mounted to a rear cover of said cooling box. The cooling box thus provides the dual function of protective housing and mounting structure for the spray cooling nozzle. In order to warrant free flowing discharge of the spray cooling fluid, the cooling box preferably comprises a discharge connection and an air admission.
Advantageously, the copper slabs have a thickness of 20 to 80 mm and preferably 50 to 60 mm. It may be noted that this thickness indication refers to the spot of maximum wall thickness, e.g. in case the front or rear face has been machined to present a certain curvature. This range is chosen as a compromise between maximizing the thickness for safety and constructive reasons and minimizing the thickness for efficient heat transfer. In fact, a thin slab is in favour of a desirable minimal thermal resistance whereas a thick slab is in favour of an equally desirable maximum instantaneous thermal absorption capacity, e.g. for solidifying molten metal, in particular (overheated) pig iron.
High cooling efficiency is obtained with copper slabs made of pure copper or a copper alloy having a thermal conductivity exceeding that of the outer shell by a factor of at least five.
The aforementioned embodiments are particularly applicable to a pig iron smelting electric arc furnace of the type with strongly stirred and/or overheated bath. In such furnaces refractory erosion and the related risk of molten metal (i.e. molten pig iron) leakage are particularly pronounced inter alia because of the high thermal load inherent to these types of furnace. In fact, the ring of copper slabs as described hereinbefore is capable of withstanding the adverse conditions in these furnaces.
As will be appreciated by those skilled in the art, the cooling arrangement with the ring of copper slabs as described above can be retrofitted to virtually any existing electric arc furnace without requiring excessive modifications. In particular, installation of the inner cooling ring requires only small modifications in the structure of the refractory lining.
Further details and advantages of the present invention will be apparent from the following description of a not limiting embodiment with reference to the attached drawings, wherein:
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The configuration of the copper slabs 20, 20′ and their associated spray cooling means will be more apparent from
The copper slab 20 shown in
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The temperature measurements obtained by means of the temperature sensor 47 allow controlling the cooling effectiveness in function of the effective temperature of the copper slab 20, 20′. Since every copper slab 20, 20′ is provided with a dedicated temperature sensor 47, the cooling effectiveness can be locally adapted according to the circumferential temperature profile of the electric arc furnace 10. Moreover the total cooling fluid flow can be optimised according to the current operating conditions. In addition, the temperature measurements allow to obtain (a priori) information on the current condition of the refractory lining 24 during operation. Control equipment for the above purposes is well known in the field of automatic control engineering and will not be detailed here.
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In
Electric arc furnaces equipped with a movable furnace hearth, i.e. in which the lower furnace shell that is inwardly lined with refractory lining is movable, are well known. Among others, they allow the hearth to be replaced e.g. when refurbishment of the refractory lining is required. Obviously, cooling action by means of the cooling ring 23 should also be available during transportation of the furnace hearth, during cooling-down prior to refurbishment and/or during preheating after refurbishment. If water supply of the spray cooling nozzles 40 and guided discharge from the discharge connections 44 were to be ensured also during transportation of the hearth, transportation would be impeded and an expensive and complex conduit system capable of adapting to the transportation path would be required. Therefore, two supplementary cooling procedures shall be presented below, which are intended to be employed in case the electric arc furnace 10 has a movable furnace hearth, i.e. a movable lower furnace shell 12, and take advantage of the cooling ring 23 according to the present invention.
A first possible method comprises the following aspects. A common discharge conduit, which forms the outlet of a collector (not shown) that is connected the discharge connections 44, is shut and disconnected. As a result, the cooling boxes 22 form a ring of communicating containers. The cooling boxes 22 are filled with water. Filling the cooling boxes 22 with water does not represent a safety risk in this case, because the movable furnace hearth is emptied of molten metal prior to transportation. The amount of water contained in the filled cooling boxes 22 is normally sufficient to warrant cooling during transportation. Optionally, e.g. in case considerable time is required for transportation, the cooling boxes 22 may operate in an evaporation cooling mode. To this effect, some of the cooling boxes are equipped with a low level detector, a high level detector and a water supply conduit. When the water level in the cooling boxes drops below the low level, the cooling ring 23 will be supplied with additional water through the one or more supply conduits until the high level is reached. The above method may also be used during transportation of the furnace hearth from its refurbishment position back to its operating position. During the cooling-down phase, e.g. prior to refurbishment, and the heating-up or preheating phase, e.g. after refurbishment, the cooling ring 23 can be operated in spray cooling mode as described above.
In a second possible method, the cooling boxes 22 are filled with water during transportation and during the cooling-down and the preheating phases. As described above, the one or more common discharge conduit(s) are shut such that the cooling boxes 22 form communicating containers and the cooling boxes 22 are filled with water. In addition to a low level detector and a high level detector, some of the cooling boxes are equipped with temperature sensors for measuring the water temperature inside the cooling boxes 22. An auxiliary water supply conduit and an auxiliary discharge conduit of reduced diameter are provided for filling respectively emptying the communicating cooling boxes 22. In this second method, the water temperature in the cooling boxes is controlled so as to have a value within a certain range e.g. in between 60°-80° C. When the upper temperature limit is reached, hot water in the cooling boxes 22 is discharged until the water level reaches the low level, preferably set well below half the height of the cooling boxes 22. Cool water is added to the cooling boxes 22 until the high level is reached whereby the water temperature is reduced. Since the thermal loads during cooling-down and preheating are significantly lower than during operation, it will be appreciated that the required supply and discharge flow rates remain relatively small.
Number | Date | Country | Kind |
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91 142 | Feb 2005 | LU | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP06/60337 | 2/28/2006 | WO | 00 | 10/23/2007 |