Ceramic components, as well as methods for their production, are known, e.g., from the publications DE 4029681 A1, DE 10218154 A1, and DE 4207915 A1.
An electrical PTC thermistor element is specified with a base body, e.g., made from PTC ceramic. PTC stands for Positive Temperature Coefficient. The component comprises a first and a second conductive layer that are arranged on an end face of the base body. The peripheral surface of the base body is free from the first conductive layer. The second conductive layer forms a cap that covers the end face of the base body, overlapping the edges, wherein this second layer lies partially on the peripheral surface of the base body.
In one variant, a first and a second conductive layer are provided on each end face. The component has mirror symmetry.
The first conductive layer is limited to the corresponding end face of the base body. In contrast to the second conductive layer, the first conductive layer does not overlap the edges. The first layer contacts the base body. An end-face region of the second conductive layer is arranged on the first conductive layer and another region of the second conductive layer contacts the peripheral surface of the base body.
The first conductive layer is a barrier layer breaking down the depletion layer. In contrast to the first conductive layer, the second conductive layer is not provided as a barrier layer, but instead as an electrical terminal of the component. This terminal is provided for soldering, e.g., with a printed circuit board, and is suitable for surface mounting.
Thus the component can be surface mounted. The base body has a rectangular cross section, or its peripheral surface has at least one flat side surface.
Both the first and also the second conductive layer can have several sub-layers made from various materials. The bottom layer, i.e., the layer facing the base body, in each conductive layer is a bonding layer. The first conductive layer can have, e.g., a chromium-containing sub-layer as a bonding layer. A nickel-containing bonding layer is deposited onto this chromium-containing layer.
The second conductive layer can have, e.g., a silver-containing bottom sub-layer, a nickel-containing middle sub-layer, and, in particular, a tin-containing upper sub-layer that can be soldered. The bottom silver layer can be activated with a Pd activator before the nickel plating.
The lowermost sub-layer of the first conductive layer is sputtered and optionally reinforced galvanically. Additional sub-layers of the first conductive layer can be deposited, e.g., chemically or galvanically. The sub-layers of the first conductive layer, however, can also be generated by screen printing with subsequent burn-in.
The second conductive layer has at least one layer, e.g., a silver-containing layer, deposited through a dipping process. This is the lowermost layer of the second conductive layer. As mentioned above, at least one additional layer that can also be generated in a dipping process, through screen printing, or through chemical or galvanic processes can be deposited on the lowermost layer.
Furthermore, a method for producing a PTC thermistor component is specified, in which:
A) a barrier layer (first conductive layer) is deposited by sputtering on primary surfaces of a large area substrate that comprises regions provided as component regions,
B) the substrate is partitioned according to component regions, wherein each partitioned component region comprises a base body, with the barrier layer being arranged on the two end faces of the base body, and
C) conductive caps (second conductive layer) arranged on the end face are generated in a dipping process at the partitioned component regions.
The large area substrate is generated by pressing a ceramic-containing material with given properties and subsequent sintering. In one variant, 50% ceramic material ML151 and 50% ceramic material ML251 are homogenized with a dry or wet method. The mixture is pressed and sintered on a uniaxial dry press. The substrate is lapped—in one variant only after sintering—to a prescribed thickness, held for a given time period in a solution containing sulfuric acid to improve the bonding strength of the sputtering layer, and then washed.
For generating the barrier layer, the primary surfaces of the substrate are metalized. In one variant, a chromium-containing layer is initially deposited by sputtering. The Cr layer can be generated, e.g., in a thickness of 0.1 to 1.0 μm. Then a nickel-containing layer, e.g., with a thickness of 0.1-1.0 μm, is also deposited through sputtering and reinforced galvanically or chemically up to a thickness that advantageously exceeds 1 μm and equals, e.g., 2-10 μm. After metallization, the substrate is cut to form partitioned component regions.
Before caps are applied, the edges between the end faces and the peripheral surface of the base body are rounded or at least flattened through abrasion with the addition of water and SiC powder.
The conductive caps are deposited in a dipping process wherein each base body is dipped in a metal-containing, silver-containing paste that is burned in after the dipping, in an air atmosphere and at a temperature of max. 900° C. The metal layer generated in this way is abraded and/or polished to generate a uniform layer thickness, e.g., also with the addition of water and SiC powder.
The conductive caps are activated with Pd activator, nickel-plated, and tin-plated after polishing, advantageously in the specified sequence. The nickel plating is performed chemically, i.e., currentless. The tin plating is performed galvanically. In principle, the Pd activation can be eliminated if the nickel plating is performed galvanically.
The described method generates PTC thermistor components that are then measured, evaluated, and, while excluding defective components, taped.
Because the barrier layer is generated in a dipping process before rather than after the partitioning of the component regions, there is the advantage that the geometric dimensions—defining the electrical properties of the component—and thus also the production tolerances with respect to the electrical properties of the components can be kept small. The conductive caps indeed directly contact the base body, but they have essentially no influence on the electrical resistance of the component.
The processing steps for the production of specified components will now be explained with reference to schematic figures, not drawn to scale.
Each component region comprises a base body 1 and barrier layers 21, 22 arranged on its end faces.
In
In
A completed component after the tin plating of caps 31, 32 is shown in
A tin-containing layer 41, 42 that can be soldered is arranged on the silver-containing cap 31, 32 that can be generated through dipping. The regions of the caps 31, 32 facing downward form component contacts (SMD contacts) that are suitable for surface mounting.
The specified component and method as well as the number and material of sub-layers are not limited to the constructions shown in the figures, and especially the shown form of the base body. All of the layers deposited by sputtering can also be generated in a dipping process or a screen-printing method with subsequent burn-in.
Number | Date | Country | Kind |
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10 2006 017 796 | Apr 2006 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/DE2007/000696 | 4/18/2007 | WO | 00 | 2/12/2009 |
Publishing Document | Publishing Date | Country | Kind |
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WO2007/118472 | 10/25/2007 | WO | A |
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