This application is a National Stage of International Application No. PCT/JP2010/065526filed Sep. 9, 2010, the contents of all of which are incorporated herein by reference in their entirety.
The present invention relates to an electrically heated catalyst.
There has been known a technique in which a mat of an insulating material is arranged between a carrier of a catalyst which is electrically energized to generate heat, and a case which contains therein the carrier of the catalyst (for example, see a first patent document). According to this mat, when the carrier of the catalyst is electrically energized, it is possible to suppress an electric current from flowing to the case. Incidentally, immediately after engine starting, etc., the temperature of electrodes is low, and hence, when an exhaust gas which has passed through the mat comes in contact with the electrodes, water or moisture in the exhaust gas may condense to the electrodes. Due to this water, insulation resistance between the electrodes and the case will decrease, so there is a fear that electricity may flow to the case from the electrode.
First Patent Document: Japanese patent application laid-open No. H05-269387
The present invention has been made in view of the above-mentioned problem, and an object of the present invention is to suppress electricity from flowing to a case of an electrically heated catalyst.
In order to achieve the above-mentioned object, an electrically heated catalyst according to the present invention is provided with:
a heat generation element that is adapted to be electrically energized to generate heat;
a case that contains said heat generation element therein;
a mat that is arranged between said heat generation element and said case, and serves to insulate electricity and at the same time to support said heat generation element;
an electrode that is connected to said heat generation element from outside of said case;
an insulation part that plugs a gap between said case and said electrode;
an electrode chamber that is a space formed around said electrode at an inner side of said case and at an outer side of said heat generation element, and is formed by providing a gap between said electrode and said mat; and
a partition part that is arranged in said electrode chamber at an upstream side of said electrode in a direction of flow of an exhaust gas, in such a manner that the exhaust gas flowing through the interior of said electrode chamber impinges against said partition part.
The heat generation element may also be a carrier for the catalyst, or may be arranged at an upstream side of the catalyst. By electrically energizing the heat generation element, the heat generation element generates heat, so that the temperature of the catalyst can be raised. Incidentally, moisture is contained in the exhaust gas of an engine, so when the exhaust gas directly impinges against or comes into contact with the electrode or the insulation part at the time the temperature of the electrode or the insulation part is low, such as at the time of cold starting of the engine, etc., water may condense to the electrode or the insulation part. On the other hand, due to the provision of the partition part, the exhaust gas having flowed into the electrode chamber is suppressed from directly impinging against or coming into contact with the electrode and the insulation part. That is, the partition part is arranged at the upstream side of the electrode in the direction of flow of the exhaust gas, so at least a part of the exhaust gas having flowed into the electrode chamber impinges against the partition part before impinging against the electrode. Here, note that the direction of flow of the exhaust gas referred to herein is a direction of flow of the exhaust gas after the exhaust gas has flowed into the electrode chamber and before the exhaust gas impinges against the partition part. This direction of flow of the exhaust gas may also be in parallel to a direction of a central axis of the case or the heat generation element. Then, due to the provision of the partition part, at least a part of the exhaust gas does not directly impinge against the electrode, so it is possible to suppress water from condensing on the electrode and the insulation part. For this reason, it is possible to suppress electricity from flowing to the case. Here, note that a partition part can also be arranged in the electrode chamber at the downstream side of the electrode in the direction of flow of the exhaust gas. In addition, a partition part can also surround a circumference of the electrode.
Moreover, in the present invention, said partition part may be arranged on a path on which the exhaust gas having flowed into said electrode chamber goes straight toward said electrode, in said electrode chamber. That is, the partition part is arranged at a location through which the exhaust gas impinging against the electrode would flow in cases where it is assumed that there is no partition part. According to this, it is possible to suppress the exhaust gas from directly impinging against the electrode.
Further, in the present invention, said partition part may be composed of an electrically insulating material in cases where a distance between said partition part and said insulation part is less than a spatial distance which is required for insulation of electricity therebetween. Here, if the partition part is composed of an electrically conductive material, there will be a fear that when the distance between the partition part and the electrode becomes short, electric discharge may take place between the partition part and the electrode. That is, in cases where the distance between the partition part and the insulation part is less than the spatial distance required for insulation of electricity therebetween, there will be a fear that electric discharge may take place between the partition part and the electrode. On the other hand, by composing the partition part with an electrically insulating material, it is possible to suppress the occurrence of electric discharge between the partition part and the electrode.
Furthermore, in the present invention, said partition part may be composed of an electrically conductive material in cases where the distance between said partition part and said insulation part is equal to or larger than the spatial distance required for insulation of electricity therebetween. That is, because there is no fear that electric discharge may take place between the partition part and the electrode, the partition part can be composed of the electrically insulating material. As a result of this, for the partition part, there can be used a highly durable material, for example.
According to the present invention, it is possible to suppress electricity from flowing to the case of the electrically heated catalyst.
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Hereinafter, reference will be made to specific embodiments of an electrically heated catalyst according to the present invention based on the attached drawings. Here, note that the following embodiments can be combined as appropriate.
[First Embodiment]
The electrically heated catalyst 1 shown in
The electrically heated catalyst 1 according to this embodiment is provided with a catalyst carrier 2 which has a cylindrical shape around the central axis A. And, the catalyst carrier 2, an inner pipe 3, and a case 4 are provided sequentially from the side of the central axis A. In addition, a mat 5 is arranged between the catalyst carrier 2 and the inner pipe 3, and between the inner pipe 3 and the case 4.
A material, which has electric resistance and is electrically energized to generate heat, is used for the catalyst carrier 2. SiC is used for the material of the catalyst carrier 2, for example. The catalyst carrier 2 has a plurality of passages which extend in a direction B of the flow of the exhaust gas (i.e., it may be the direction of the central axis A), and which have a cross section of honeycomb shape vertical to the direction in which the exhaust gas flows. The exhaust gas flows through these passages. The catalyst carrier 2 has an outer shape which is a cylindrical shape centering on the central axis A of the exhaust pipe, for example. Here, note that the sectional shape of the catalyst carrier 2 formed by the cross section which is orthogonal to the central axis A may be an elliptical shape, for example. The central axis A is a central axis common to the exhaust pipe, the catalyst carrier 2, the inner pipe 3, and the case 4. Here, note that in this embodiment, the catalyst carrier 2 corresponds to a heat generation element in the present invention. In addition, this embodiment can be applied similarly even in cases where the heat generation element is provided at the upstream side of the catalyst.
The catalyst is carried or supported by the catalyst carrier 2. As the catalyst, there can be mentioned an oxidation catalyst, a three-way catalyst, an NOx storage reduction catalyst, an NOx selective reduction catalyst, etc., for example. Two pieces of electrodes 6 are connected to the catalyst carrier 2, so that the catalyst carrier 2 is electrically energized by applying a voltage between these electrodes 6. The catalyst carrier 2 generates heat due to the electric resistance of this catalyst carrier 2.
As the mat 5, there is used an electrically insulating material such as, for example, ceramic fiber which includes alumina as its main component. The mat 5 is wound around an outer peripheral surface of the catalyst carrier 2 and an outer peripheral surface of the inner pipe 3. The mat 5 covers the outer peripheral surface (the surface parallel to the central axis A) of the catalyst carrier 2, so that when the catalyst carrier 2 is electrically energized, the mat 5 serves to suppress electricity from flowing to the inner pipe 3 and the case 4.
As the material of the inner pipe 3, there is used an electrically insulating material such as, for example, alumina. The inner pipe 3 is formed into a tubular shape with the central axis A being located as a center thereof. The inner pipe 3 has a length in the direction of the central axis A longer than that of the mat 5. As a result, the inner pipe 3 protrudes from the mat 5 to an upstream side thereof and a downstream side thereof, respectively. An inside diameter of the inner pipe 3 is substantially the same as an outside diameter of the mat 5 at the time when the mat 5 is wound around the outer periphery of the catalyst carrier 2. For this reason, when the mat 5 and the catalyst carrier 2 are contained or inserted into the inner pipe 3, the mat 5 is compressed, so the catalyst carrier 2 is fixed into the inner pipe 3 due to a repulsive force or resilience of the mat 5.
Metal is used for the material of the case 4, and for example, a stainless steel material can be used. Inside the case 4, there are contained the catalyst carrier 2, the inner pipe 3, and the mat 5. An inside diameter of the case 4 is substantially the same as the outside diameter of the mat 5 at the time when the mat 5 is wound around the outer periphery of the inner pipe 3, and the mat 5 is compressed when the mat 5 and the inner pipe 3 is contained in the case 4, so the inner pipe 3 is fixed into the case 4 due to the repulsive force of the mat 5.
The two pieces of electrodes 6 are connected to the catalyst carrier 2. Holes 31, 41, 51 are opened in the inner pipe 3, the case 4, and the mat 5, respectively, in order to pass these electrodes 6 therethrough. The diameter of each of these holes 31, 41, 51 is larger than the diameter of each of the electrodes 6. For this reason, the inner pipe 3, the case 4 and the mat 5 are separated from the electrodes 6. Then, insulation parts 7, which serve to support the electrodes 6, respectively, are arranged in the holes 41, respectively, which are opened in the case 4. An electrically insulating material is used for the material of the insulation parts 7. In addition, the insulation parts 7 are arranged with no gap between the case 4 and the electrodes 6, respectively. In this manner, inside the case 4, there is formed an electrode chamber 8 in the form of a closed space around each of the electrodes 6.
In addition, the diameter of each hole 31, which is opened in the inner pipe 3, is smaller than the diameter of each hole 51, which is opened in the mat 5. As a result, the inner pipe 3 protrudes from the mat 5 into the interior of each of the electrode chambers 8. Then, the inner pipe 3 is provided with a plate 9 at an upstream side of each of the electrodes 6 in the direction of flow of the exhaust gas.
Each of the plates 9 serves to divide a part of a corresponding electrode chamber 8 at the upstream side of a corresponding electrode 6 into an upstream side chamber and a downstream side chamber. In an end of the inner pipe 3 which forms the holes 31, each plate 9 extends toward an inner side and an outer side of the inner pipe 3 vertically with respect to the central axis A. Each plate 9 may be of a flat plane, or may be of a curved plane. In addition, the shape of each plate 9 may be conformed to the shape of a corresponding hole 31 which is opened in the inner pipe 3. The material of the plates 9 may be the same as that of the inner pipe 3, or may be different therefrom.
These plates 9 are arranged in order that the exhaust gas flowing into the electrode chambers 8 is suppressed from directly impinging against or coming into contact with the electrodes 6 and the insulation parts 7. For example, each plate 9 is arranged in such a manner that it exists at the upstream side of a tip portion of a corresponding insulation part 7, i.e., at the upstream side of a location at which a corresponding electrode 6 is exposed from the insulation part 7. In addition, for example, the shape and the position of each plate 9 may be decided in such a manner that when the tip portion of the corresponding insulation part 7 is projected on the plate 9 in the direction B of the flow of the exhaust gas (which may also be the direction of the central axis A), at least a part of the tip portion of the insulation part 7 is projected on the plate 9. Moreover, each plate 9 may be arranged on a path on which the exhaust gas having flowed into a corresponding electrode chamber 8 goes straight toward a corresponding electrode 6 in the electrode chamber 8. The plates 9 need only be arranged in a manner as to interrupt at least a part of the exhaust gas which would impinge against the electrodes 6 or the insulation parts 7 when it is assumed that the plates 9 do not exist. That is, the size of each plate 9 may be smaller than that of a corresponding electrode 6 or a corresponding insulation part 7. In addition, the plates 9 are arranged in such a manner that they are not in contact with the case 4, the catalyst carrier 2, and the mat 5. Here, note that in this embodiment, each plate 9 corresponds to a partition part in the present invention.
In the electrically heated catalyst 1 as constructed in this manner, the water condensed at the upstream side of the catalyst carrier 2 may flow on the inner wall of the case 4, and may adhere to the mat 5. This water adheres to a portion of the mat 5 between the inner pipe 3 and the case 4. That is, because the inner pipe 3 protrudes to the upstream side and the downstream side of the mat 5, it is possible to suppress the water from coming into the inner side of the inner pipe 3. As a result of this, it is possible to suppress the case 4 and the catalyst carrier 2 from being short-circuited to each other by means of the water at an upstream end and a downstream end of the mat 5.
In addition, when particulate matter (hereinafter also referred to as PM) in the exhaust gas adheres to the mat 5 and/ or the inner pipe 3, there is a fear that a short circuit may be formed between the case 4 and the catalyst carrier 2 by means of the particulate matter. However, because the inner pipe 3 protrudes from the mat 5, the protruded portions of the inner pipe 3 receive the heat of the exhaust gas, and become high in temperature, so the PM adhered to the inner pipe 3 can be removed by the oxidation thereof. According to this, it is possible to suppress the short circuit between the case 4 and the catalyst carrier 2 through the PM.
Incidentally, the water adhered to the mat 5 evaporates due to the heat of the exhaust gas and the heat of the catalyst carrier 2. However, as the amount of water adhered increases, a part thereof will stay in the interior of the mat 5, without evaporating immediately. Then, the water may reach up to the electrode chambers 8 around the electrodes 6 while passing through the interior of the mat 5. At the time of cold starting of the engine, the temperatures of the electrodes 6 and the insulation parts 7 are low, so when the exhaust gas impinges against the electrodes 6 and the insulation parts 7, water will condense on the surfaces of the electrodes 6 and the insulation parts 7. Thus, there will be a fear that when water condenses on the surfaces of the electrodes 6 and the insulation parts 7 in this manner, electricity may flow to the case 4 from the electrodes 6. Then, there will also be a fear that when there is a request to raise the temperature of the catalyst carrier 2, electrical energization thereof may become impossible.
On the other hand, due to the provision of the plates 9, the exhaust gas is suppressed from directly impinging against or coming into contact with the electrodes 6 and the insulation parts 7. In the electrodes 6 and the insulation parts 7, water is less prone to condense in places where the exhaust gas does not directly impinge, than in places where the exhaust gas directly impinges. That is, because of the provision of the plates 9, it is possible to suppress water from condensing on the electrodes 6 and the insulation parts 7.
Because water can be suppressed from condensing on the electrodes 6 and the insulation parts 7 in this manner, it is possible to suppress electricity from flowing to the case 4 from the electrodes 6.
Here, note that in this embodiment, it has been explained that the holes 31, 51 are opened in the inner pipe 3 and the mat 5, respectively, but instead of this, the inner pipe 3 and the mat 5 may each be divided into an upstream side portion and a downstream side portion on opposite sides of the electrodes 6. That is, the inner pipe 3 and the mat 5 may each be arranged around the catalyst carrier 2 separately at the upstream side and at the downstream side of the electrodes 6, respectively. According to such an arrangement, the electrode chambers 8 are formed in such a manner that they extend around the circumference of the catalyst carrier 2. Even in such a case, with the provision of the plates 9 which are arranged at the upstream side of the electrodes 6, the exhaust gas is suppressed from directly impinging against or coming into contact with the electrodes 6 and the insulation parts 7, so it is possible to suppress electricity from flowing to the case 4.
[Second Embodiment]
That is, the plates 90 extend in a direction toward the central axis A from the case 4. Each of the plates 90 has one end thereof at the side of the central axis A located at an outer side of the outer peripheral surface of the catalyst carrier 2 inside the electrode chambers 8, in such a manner as not to be in contact with the catalyst carrier 2. In addition, the plates 90 are arranged in a manner such that they are not in contact with the inner pipe 3 and the mat 5. The material of the plates 9 may be the same as that of the case 4, or may be different therefrom.
With the electrically heated catalyst 100 as constructed in this manner, too, it is possible to suppress the exhaust gas from directly impinging against the electrodes 6 and the insulation parts 7. That is, due to the provision of the plates 90, it is possible to suppress water from condensing on the electrodes 6 and the insulation parts 7. Because water can be suppressed from condensing on the electrodes 6 and the insulation parts 7 in this manner, it is possible to suppress electricity from flowing to the case 4 from the electrodes 6.
[Third Embodiment]
The plates 91 at the downstream side of the electrodes 6, respectively, extend in a direction toward the central axis A from the case 4. The plates 91 have their one end at the side of the central axis A located at an outer side of the outer peripheral surface of the catalyst carrier 2 inside the electrode chambers 8, in such a manner as not to be in contact with the catalyst carrier 2. In addition, the plates 91 are arranged in a manner such that they are not in contact with the inner pipe 3 and the mat 5. The shapes of the plates 91 at the downstream side of the electrodes 6, and the shapes of the plates 90 at the upstream side of the electrodes 6 are in line symmetry with respect to the central axes of the electrodes 6, respectively. Here, note that the plates 90, 91 may be mounted on the inner pipe 3, similarly to the plates 9 in the first embodiment.
Thus, by providing the plates 91 at the downstream side of the electrodes 6, too, it becomes more difficult for the exhaust gas to impinge against the electrodes 6 and the insulation parts 7, and hence, it is possible to suppress water from condensing on the electrodes 6 and the insulation parts 7 in a more effective manner. For this reason, it is possible to suppress electricity from flowing to the case 4 from the electrodes 6.
[Fourth Embodiment]
Here, in cases where the distances from the electrodes 6 and the insulation parts 7 to the plates 9 are short, there will be a fear that when the electrodes 6 are electrically energized, electric discharge may occur between the electrodes 6 and the plates 9, and between the insulation parts 7 and the plates 9. On the other hand, it is possible to suppress the occurrence of electric discharge by using an electrically insulating material for the material of the plates 9. Accordingly, in this fourth embodiment, in cases where the spatial distances of the electrodes 6 and the insulation parts 7 to the plates 9 are shorter than a lower limit value of a distance (hereinafter referred to as a required spatial distance) at which electric discharge does not occur, an electrically insulating material is used for the material of the plates 9. The required spatial distance can also be said as a spatial distance which is required for insulation of electricity.
In this manner, in cases where electric discharge can occur between the electrode 6 and the plate 9, and between the insulation part 7 and the plate 9, it is possible to suppress electricity from flowing to the case 4 from the electrode 6, by the use of an insulating material for the material of the plate 9. In addition, in cases where electric discharge can never occur, the durability of the plate 9 can be improved by the use of an electrically conductive material for the material of the plate 9.
Similarly, in cases where the distance from the plate 9, 90 or 91 to the case 4 or the catalyst carrier 2 is short, there will be a fear that when the electrodes 6 are electrically energized, electric discharge may occur between the case 4 and the plate 9, 90 or 91, or between the catalyst carrier 2 and the plate 9, 90 or 91. Accordingly, in this embodiment, in cases where an electrically conductive material is used for the plate 9, 90, or 91, the spatial distance between the case 4 and the plate 9, 90, or 91 or between the catalyst carrier 2 and the plate 9, 90, or 91 may be made longer than the required spatial distance D.
In addition,
In this manner, it is possible to suppress electricity from flowing to the case 4 through the plate 9, 90 or 91.
Explanation of Reference Numerals and Characters
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2010/065526 | 9/9/2010 | WO | 00 | 3/8/2013 |
Publishing Document | Publishing Date | Country | Kind |
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WO2012/032635 | 3/15/2012 | WO | A |
Number | Name | Date | Kind |
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5384099 | Sheller | Jan 1995 | A |
5651906 | Whittenberger et al. | Jul 1997 | A |
Number | Date | Country |
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5-269387 | Oct 1993 | JP |
05-096421 | Dec 1993 | JP |
2005-240634 | Sep 2005 | JP |
9516110 | Jun 1995 | WO |
Number | Date | Country | |
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20130164188 A1 | Jun 2013 | US |