This application relates to the field of energy storage technologies, and in particular, to an electrochemical apparatus and an electronic apparatus including such electrochemical apparatus.
Electrochemical apparatuses (for example, batteries) are widely used in electronic products such as electronic mobile devices, electric tools, and electric vehicles, and increasingly high requirements are imposed on safety performance of the electrochemical apparatuses.
During high-rate charging, an electrochemical apparatus is likely to continuously produce heat and have a temperature rise due to factors such as its internal resistance and polarization accumulation caused by charging. This may accelerate aging of the electrochemical apparatus as well as deterioration of capacity and power performance, and may also cause volumetric expansion, deformation, or the like, affecting the service life of a product.
In view of the deficiencies of the prior art, it is necessary to propose an electrochemical apparatus that can solve the problem of temperature rise during charging.
It is also necessary to provide an electronic apparatus including such electrochemical apparatus.
This application provides an electrochemical apparatus including an electrode assembly and a first conductive plate. The electrode assembly is of a wound structure and includes a first electrode plate. The first electrode plate includes a first conductive layer and a first conductive material layer. The first conductive layer includes a first surface and a second surface opposite to each other. The first conductive material layer is provided on the first surface. The first surface includes a first region, the first conductive material layer includes a first recess, and the first region is exposed from the first recess. The first conductive plate is connected to the first region and extends out of the first electrode plate. The first conductive plate includes a third region and a fourth region connected to each other. A direction perpendicular to the third region is a first direction, and in the first direction, a projection of the third region is located in a projection of the first region, and a projection of the fourth region is located outside the projection of the first region. The third region includes a connection region, and the first conductive plate is connected to the first region through the connection region. Viewed from the first direction, the third region includes a first side, a second side, a third side, and a fourth side, the first side and the second side being opposite to each other, the third side and the fourth side being opposite to each other, and the fourth side being connected to the fourth region. The first region includes a fifth side, a sixth side, and a seventh side. An extension direction of the third region is a second direction, and in the second direction, the seventh side and the third side are arranged in sequence. In a third direction, the fifth side, the first side, the second side, and the sixth side are arranged in sequence. The first direction, the second direction, and the third direction are perpendicular to each other. a size of the third region in the third direction is T1, a size of the third region in the second direction is T2, an area of the projection of the third region in the first direction is S1, an area of a projection of the connection region in the first direction is S2, a distance between the first side and the fifth side is J1, a distance between the second side and the sixth side is J2, and a distance between the third side and the seventh side is J3, where S2/S1+(J1+J2+J3)/(T1+T2)≥30%.
In this application, S2/S1 may reflect a proportion of a current pass area of the first conductive plate. When S2/S1 is large, the current pass area of the first conductive plate increases, and current is distributed more dispersedly and uniformly on the first conductive plate during charging of the electrochemical apparatus, allowing for more dispersive heat production at the first conductive plate during large-current charging, thereby reducing the risk of local overheating of the first conductive plate. Moreover, (J1+J2+J3)/(T1+T2) may reflect a proportion of a heat dissipation area in the first region. When (J1+J2+J3)/(T1+T2) is large, the heat dissipation area of the first conductive plate increases, reducing a temperature rise during large-current charging. Therefore, in this application, a sum of S2/S1 and (J1+J2+J3)/(T1+T2) is defined to be ≥30%, improving the safety and reliability of the electrochemical apparatus.
In some possible implementations, the first electrode plate further includes a second conductive material layer provided on the second surface. The second surface includes a second region, the second conductive material layer includes a second recess, and the second region is exposed from the second recess. In the first direction, the projection of the first region and a projection of the second region at least partially overlap. Thus, heat produced at the first conductive plate may not only be dissipated through the first region exposed from the first conductive plate but also be transferred to the second region through overlapping portions of the first region and second region and dissipated through the second region, thereby further improving the heat dissipation efficiency.
In some possible implementations, the electrochemical apparatus further includes a first layer adhered to the third region, where the first layer contains an insulating material. In the first direction, the projection of the third region is located in a projection of the first layer. The first layer may reduce the risk of generation of a short circuit caused when a burr or welding mark of the connection region punctures a separator, and may also be configured to compensate for a reduced thickness of a position where the first recess is provided on the first conductive material layer, allowing the electrochemical apparatus to have a more uniform overall thickness.
In some possible implementations, the first conductive material layer includes a first conductive material region, where the first conductive material region encloses the first recess. The first layer is further adhered to the first conductive material region. In the first direction, the projection of the first region is located in the projection of the first layer.
In some possible implementations, the electrochemical apparatus further includes a second layer, where the second layer contains an insulating material. The second conductive material layer includes a second conductive material region, where the second conductive material region encloses the second recess. The second layer is adhered to the second conductive material region. In the first direction, the projection of the second region is located in a projection of the second layer. The second layer may be configured to compensate for a reduced thickness of a position where the second recess is provided on the second conductive material layer.
In some possible implementation, viewed from the first direction, the first layer includes an eighth side. In the second direction, the seventh side is disposed between the eighth side and the third side. A distance between an edge of the first region in the second direction and the eighth side is L1, and a distance between the seventh side and the eighth side is L3, where L3/L1≤30%. Thus, in the second direction, a size of the first conductive material region covered by the first layer is reduced, that is, an active material covered by the first layer and unlikely to contribute to capacity is reduced, thereby reducing the impact of the first layer on the capacity of the electrochemical apparatus.
In some possible implementations, a third recess is provided at an edge of the first region in the second direction. The first conductive material region includes a first extension region and a second extension region extending toward the third recess. Viewed in the first direction, the first extension region and the second extension region are disposed on two sides of the third recess. Thus, when an electrode plate is slitted, a uniform thickness at an incision of the electrode plate helps to reduce the risk of formation of a wavy edge at the incision of the electrode plate.
In some possible implementations, a distance between an edge of the first region in the second direction and the eighth side is L1, the first extension region and the second extension region have a same size of L2 in the second direction, and a distance between the seventh side and the eighth side is L3, where (L2+L3)/L1≤30%. Thus, in the second direction, a size of the first conductive material region covered by the first layer is reduced, that is, an active material covered by the first layer and incapable of contributing to capacity is reduced, thereby reducing the impact of the first layer on the capacity of the electrochemical apparatus.
In some possible implementations, a size of the first extension region in the third direction is W1, and a size of the second extension region in the third direction is W2, where (W1+W2)/T1≥20%. Thus, reduction of the heat dissipation area of the first region caused by provision of the third recess is alleviated.
In some possible implementations, a size of the first extension region in the third direction is W1, a size of the second extension region in the third direction is W2, a distance between the first extension region and the first conductive plate in the third direction is W3, and a distance between the second extension region and the first conductive plate in the third direction is W4. In some possible implementations, W3<W1. In some possible implementations, W2<W4. In some possible implementations, W3<W4.
In some possible implementations, in the third direction, the first extension region and the second extension region respectively include a ninth side and a tenth side. The first region is connected to the ninth side and the tenth side. The ninth side and the tenth side are in a straight line shape or an arc shape.
In some possible implementations, in the second direction, the first extension region and/or the second extension region has a size of L2, and a distance between the ninth side and the fourth side is L4, where L2<L4. The relatively large L4 helps to further increase the heat dissipation area of the first conductive plate, thereby reducing a temperature rise during large-current charging.
In some possible implementations, L1 ranges from 10 mm to 50 mm. When L1 is large, the first conductive material layer covered by the first layer in the second direction has a relatively large size, and therefore has a greater impact on the capacity of the electrochemical apparatus. When L1 is small, the first region also has a small size in the second direction, so that the distance J3 between the third side and the seventh side is also small, and thus heat dissipation capability of the first region is also reduced.
In some possible implementations, the electrochemical apparatus further includes a third layer and a fourth layer, where the third layer and the fourth layer each contain an insulating material. In the first direction, the first layer is disposed between the first conductive plate and the third layer, and the second layer is disposed between the first conductive plate and the fourth layer. The third layer and the fourth layer may further compensate for the reduced thickness of the electrode plate at the first recess and the second recess. When the first electrode plate is a negative electrode plate and the second electrode plate is a positive electrode plate, the third layer may also be configured to hinder movement, toward the second recess, of lithium ions deintercalated from a part of the third conductive material layer corresponding to the third layer in the first direction, thereby reducing the risks of excessive accumulation of lithium ions and formation of lithium dendrites due to the lack of lithium ions that may be embedded in the second recess. Similarly, the fourth layer may also reduce the risk of formation of lithium dendrites.
In some implementations, the electrode assembly further includes a second electrode plate, and at least one of the third layer or the fourth layer is adhered to the second electrode plate. Thus, the third layer and the fourth layer are fixed in the electrochemical apparatus and serves to compensate for thickness or reduce the risk of formation of lithium dendrites.
In some possible implementations, in the second direction, an edge of at least one of the first layer or the second layer extends beyond an edge of the first electrode plate.
In some possible implementations, the connection region is welded to the first region, thereby providing a higher connection strength between the first conductive plate and the first region. The connection region includes a plurality of welding spots. The area S2 is a sum of projection areas of a plurality of welding spots in the first direction.
In some possible implementations, the electrode assembly further includes a second electrode plate and a separator. The first electrode plate, the separator, and the second electrode plate are stacked and wound to form the electrode assembly. In the winding direction, the electrode assembly includes a first section, a first bent section, a second section, and a second bent section connected in sequence. The first conductive plate is located in the first section, thereby improving the flatness of the first conductive plate when the first conductive plate is connected to the first region.
In some possible implementations, the housing includes a body for accommodating the electrode assembly and an sealing edge connected to the body. The sealing edge includes a polymer layer, and the fourth region extends out of the housing from the polymer layer.
This application further provides an electronic apparatus including the foregoing electrochemical apparatus.
The following clearly describes in detail the technical solutions in some embodiments of this application. Apparently, the described embodiments are merely some rather than all of the embodiments of this application. Unless otherwise defined, all technical and scientific terms used herein shall have the same meanings as commonly understood by persons skilled in the art to which this application belongs. The terms used in the specification of this application are merely intended to describe specific embodiments rather than to constitute any limitation on this application.
The following describes some embodiments of this application in detail. However, this application may be embodied in many different implementations and should not be construed as being limited to the example embodiments set forth herein. Rather, these example embodiments are provided so that this application may be conveyed to persons skilled in the art thoroughly and in detail.
In addition, in the accompanying drawings, sizes or thicknesses of various components and layers may be exaggerated for brevity and clarity. Throughout the text, the same numerical values represent the same elements. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. In addition, it should be understood that when an element A is referred to as being “connected to” an element B, the element A may be directly connected to the element B or an intervening element C may be present therebetween such that the element A and the element B may be indirectly connected to each other.
Further, the use of “may” for describing some embodiments of this application relates to “one or more embodiments of this application.”
The terminology used herein is merely intended to describe specific embodiments rather than to constitute any limitation on this application. As used herein, the singular forms are intended to include the plural forms as well, unless the context clearly indicates otherwise. It should be further understood that the term “comprise” or “include”, when used in this specification, specifies the presence of stated features, numbers, steps, operations, elements, and/or components but do not preclude the presence or addition of one or more other features, numbers, steps, operations, elements, components, and/or combinations thereof.
Spatial related terms such as “above” may be used herein for ease of description to describe the relationship between one element or feature and another element (a plurality of elements) or feature (a plurality of features) as illustrated in the figure. It should be understood that spatial related terms are intended to encompass different orientations of a device or an apparatus in use or operation in addition to the orientations depicted in the figures. For example, if the device in the figures is turned over, elements described as “above” or “over” other elements or features would then be oriented “below” or “beneath” the other elements or features. Thus, the example term “above” may encompass both an orientation of above and below. It should be understood that although the terms first, second, third, or the like may be used herein to describe various elements, components, regions, layers, and/or portions, these elements, components, regions, layers, and/or portions should not be limited by these terms. These terms are used to distinguish one element, component, region, layer, or portion from another element, component, region, layer, or portion. Therefore, the first element, component, region, layer, or portion discussed below may be referred to as the second element, component, region, layer, or portion without departing from the teachings of the example embodiments.
Referring to
In this application, a first three-dimensional coordinate system is established based on the first direction D1, the second direction D2, and the third direction D3 perpendicular to each other. The first direction D1 is a direction perpendicular to the third region 31 of the first conductive plate 30. The second direction D2 is an extension direction of the third region 31 of the first conductive plate 30. When the electrode plate is unfolded, a second three-dimensional coordinate system is established based on the first direction D1, the second direction D2, and a fourth direction D4 perpendicular to each other. The fourth direction D4 is a direction from a winding start end to a winding stop end of the electrode plate before winding. For example, the fourth direction D4 is a direction from a first winding start end 21a to a first winding stop end 21b of the first electrode plate 21, and also a direction from a second winding start end 22a to a second winding stop end 22b of the second electrode plate 22.
In some embodiments, in the winding direction D, the electrode assembly 20 includes a first section 201, a first bent section 202, a second section 203, and a second bent section 204 that are connected in sequence. The first direction D1 is a direction in which the first electrode plate 21 in the first section 201 or second section 203 is stacked. The electrode assembly 20 may include a plurality of first sections 201, a plurality of first bent sections 202, a plurality of second sections 203, and a plurality of second bent sections 204. In some embodiments, the first section 201 and the second section 203 may be flat and straight sections. In some other embodiments, in the winding direction D, the electrode assembly 20 may alternatively include four bent sections that are connected in sequence.
The first section 201 has a first outer surface 201a, and the second section 203 has a second outer surface 203a. A joint between the outermost first section 201 of the electrode assembly 20 and the outermost first bent section 202 of the electrode assembly 20 is a first end 205. The first end 205 is a start portion of a rightmost bent side of the first bent section 202 in
Referring to
The first electrode plate 21 may be a positive electrode plate or a negative electrode plate. Correspondingly, the first conductive layer 210 may be a positive electrode conductive layer or a negative electrode conductive layer, and the first conductive material layer 211 and the second conductive material layer 212 may each be a positive electrode active material layer or a negative electrode active material layer. The first conductive layer 210 may have a current collection function. The second electrode plate 22 may be a positive electrode plate or a negative electrode plate. Correspondingly, the second conductive layer 220 may be a negative electrode conductive layer or a positive electrode conductive layer, and the third conductive material layer 221 and the fourth conductive material layer 222 may each be a negative electrode active material layer or a positive electrode active material layer. The second conductive layer 220 may have a current collection function. In some embodiments, the first electrode plate 21 is a positive electrode plate, and the second electrode plate 22 is a negative electrode plate. The positive electrode conductive layer may be an aluminum foil or a nickel foil, and the negative electrode conductive layer may be at least one of a copper foil, a nickel foil, or a carbon-based conductive layer.
The positive electrode active material layer includes a positive electrode active material, and the positive electrode active material includes a compound that reversibly intercalates and deintercalates lithium ions (that is, a lithiated intercalation compound). In some embodiments, the positive electrode active material may include a lithium transition metal composite oxide. The lithium transition metal composite oxide contains lithium and at least one element selected from cobalt, manganese, and nickel. In some embodiments, the positive electrode active material is selected from at least one of lithium cobalt oxide (LiCoO2), a lithium nickel manganese cobalt ternary material (NCM), lithium manganese oxide (LiMn2O4), lithium nickel manganese oxide (LiNi0.5Mn1.5O4), or lithium iron phosphate (LiFePO4).
The negative electrode active material layer contains a negative electrode active material. A negative electrode active material that is known in the art and that may reversibly intercalate and deintercalate active ions may be used. This is not limited in this application. For example, the negative electrode active material may be but is not limited to one or a combination of more of graphite, soft carbon, hard carbon, carbon fiber, meso-carbon microbeads, a silicon-based material, a tin-based material, lithium titanate, another metal that may form an alloy with lithium, or the like. The graphite may be selected from one or a combination of more of artificial graphite, natural graphite, or modified graphite. The silicon-based material may be selected from one or a combination of more of elemental silicon, a silicon-oxygen compound, a silicon-carbon composite, or a silicon alloy. The tin-based material may be selected from one or a combination of more of elemental tin, a tin-oxygen compound, a tin alloy, or the like.
The separator 23 includes at least one of polyethylene, polypropylene, polyvinylidene fluoride, polyethylene terephthalate, polyimide, or aramid. For example, polyethylene is selected from at least one of high-density polyethylene, low-density polyethylene, or ultrahigh-molecular-weight polyethylene. Polyethylene and polypropylene have a good effect on alleviating short circuits and may improve the stability of a battery through a shutdown effect.
Referring to
In some embodiments, the housing 10 may be a package bag obtained using a package film (for example, an aluminum-plastic film) for packaging, which means that the electrochemical apparatus 100 may be a soft pack battery. Referring to
Referring to
In some other embodiments, the electrochemical apparatus 100 is not limited to a soft pack battery and may alternatively be a steel-shell battery, an aluminum-shell battery, or the like, which is not limited in this application.
An electrochemical apparatus 200 includes an electrode assembly 20 and a first conductive plate 30; the electrode assembly 20 includes a first electrode plate 21; the first electrode plate 21 includes a first conductive layer 210 and a first conductive material layer 212; where
In the electrochemical apparatus described above, viewed along the first direction D1, the first conductive material layer 212 includes a portion connected to the second end edge 211a and the third recess R.
In the electrochemical apparatus described above, viewed along the first direction D1, in a third direction D3 perpendicular to a second direction D2, the first conductive material layer 212 includes a first lateral side R1 connected to the second end edge 211a and opposite the first conductive plate 30.
In the electrochemical apparatus described above, viewed along the first direction D1, in the third direction D3, the first conductive material layer 212 includes a fifth side 2101 separated from the first lateral side R1 and opposite the first conductive plate 30.
In the electrochemical apparatus described above, the first conductive material layer 212 includes a ninth side 2114 connected to the first lateral side R1 and the fifth side 2101.
In the electrochemical apparatus described above, a distance W3 from the first conductive plate 30 to the first lateral side R1 in the third direction D3 is shorter than a distance W1 from the first lateral side R1 to the fifth side 2101 in the third direction D3.
In the electrochemical apparatus described above, viewed along the first direction D1, the first conductive material layer 212 includes a portion connected to the second end edge 210a and the third recess R; and viewed along the first direction D1, in the third direction D3 perpendicular to the second direction D2, the first conductive material layer 212 further includes a second lateral side R2 connected to the second end edge 211a and opposite the first conductive plate 30, and a sixth side 2102 separated from the second lateral side R2 and opposite the first conductive plate 30.
In the electrochemical apparatus described above, the first conductive material layer 212 includes a tenth side 2115 connected to the second lateral side R2 and the sixth side 2102.
In the electrochemical apparatus described above, a distance W4 from the first conductive plate 30 to the second lateral side R2 is shorter than a distance W2 from the second lateral side R2 to the tenth side 2115 in the third direction D3.
In the electrochemical apparatus described above, in the third direction D3, the distance W3 from the first conductive plate 30 to the first lateral side R1 is shorter than a distance W4 from the first conductive plate 30 to the second lateral side R2.
In the electrochemical apparatus described above, a distance L2 from the second end edge 211a to the ninth side 2114 in the second direction D2 is shorter than a distance L4 from the ninth side 2114 to a bottom edge R3 of the third recess R in the second direction D2.
In the electrochemical apparatus described above, the third recess R includes a slope edge Ru extending from the second end edge 211a to the bottom edge R3 of the third recess.
In the electrochemical apparatus described above, the electrode assembly 20 includes a first layer 50 that at least covers a part of the first conductive plate 30 and the first lateral side R1 and that includes an insulating material.
As shown in
The third region 31 includes a connection region 311 and an edge region 312 provided around the connection region 311. The first conductive plate 30 is connected to the first region 2100 through the connection region 311, that is, the connection region 311 is a position through which current flows during charging of the electrochemical apparatus 100. In some embodiments, the first conductive plate 30 is welded to the first region 2100 through the connection region 311, thereby providing a high connection strength between the first conductive plate 30 and the first region 2100. A plurality of welding spots 3110 may be formed after the connection region 311 and the first region 2100 are welded, and the connection region 311 and the first region 2100 are fixed through the welding spots 3110. When there are a large number of welding spots 3110, contact resistance between the first conductive plate 30 and the first electrode plate 21 may be reduced, thereby reducing heat production during charging of the electrochemical apparatus 100. In other embodiments, the first conductive plate 30 may alternatively be connected to the first region 2100 through a conductive adhesive or in other manners.
In some embodiments, as shown in
As shown in
The first region 2100 includes a fifth side 2101, a sixth side 2102, and a seventh side 2103. The fifth side 2101 and sixth side 2102 face each other in the third direction D3. The seventh side 2103 connects two connecting end portions of the fifth side 2101 and the sixth side 2102. Viewed in the first direction D1, the seventh side 2103 faces a third end edge 2104 of the first region 2100 in the second direction D2. It can be understood that the first recess 2110 is a three-dimensional structure. However, viewed from the first direction D1, the first recess 2110 includes a plurality of sequentially connected sides (not shown in the figure). In addition, viewed from the first direction D1, the fifth side 2101, the sixth side 2102, and the seventh side 2103 of the first region 2100 overlap with the sides of the first recess 2110, respectively. In some embodiments, the fifth side 2101 and the sixth side 2102 extend along the second direction D2, respectively; and the seventh side 2103 extends along the third direction D3. In the second direction D2, the seventh side 2103 and the third side 3103 are arranged in sequence, and the seventh side 2103 and the third side 3103 at least partially face each other. In some embodiments, the seventh side 2103 and the third side 3103 may be parallel to each other. In the third direction D3, the fifth side 2101, the first side 3101, the second side 3102, and the sixth side 2102 are arranged in sequence; the fifth side 2101 and the first side 3101 at least partially face each other; and the second side 3102 and the sixth side 2102 at least partially face each other. In some embodiments, the fifth side 2101, the first side 3101, the second side 3102, and the sixth side 2102 may be parallel to each other.
In the second direction D2, the seventh side 2103 and the third side 3103 are arranged in sequence, meaning that a virtual straight line provided along the second direction D2 runs through the seventh side 2103 and the third side 3103 in sequence. In the third direction D3, the fifth side 2101, the first side 3101, the second side 3102, and the sixth side 2102 are arranged in sequence, meaning that a virtual straight line provided along the third direction D3 runs through the fifth side 2101, the first side 3101, the second side 3102, and the sixth side 2102. In some embodiments, the second direction D2 is the direction of the winding center axis C, and the third direction D3 is perpendicular to the second direction D2.
In some embodiments, as shown in
As shown in
A size of the third region 31 in the third direction D3 is T1, a size of the third region 31 in the second direction D2 is T2, an area of the projection of the third region 31 in the first direction D1 is S1 (shown in
S2/S1 may reflect an area proportion of the connection region 311 in the third region 31, that is, a proportion of a current pass area of the first conductive plate 30. When S2/S1 is large, the current pass area of the first conductive plate 30 increases, and current is distributed more dispersedly and uniformly on the first conductive plate 30 during charging of the electrochemical apparatus 100, allowing for more dispersive heat production at the first conductive plate 30 during large-current charging, thereby reducing the risk of local overheating of the first conductive plate 30. Moreover, J1 may reflect a length of a portion of the first region 2100 exposed from a side of the first side 3101 of the first conductive plate 30; J2 may reflect a length of a portion of the first region 2100 exposed from a side of the second side 3102 of the first conductive plate 30; and J3 may reflect a length of a portion of the first region 2100 exposed from a side of the third side 3103 of the first conductive plate 30. Therefore, (J1+J2+J3)/(T1+T2) may reflect a proportion of an area of the first region 2100 exposed from the first conductive plate 30, that is, a proportion of a heat dissipation area in the first region 2100. When (J1+J2+J3)/(T1+T2) is large, the heat dissipation area of the first conductive plate 30 increases, reducing a temperature rise during large-current charging. Therefore, in this application, the heat dissipation coefficient K of the first region 2100 is a sum of S2/S1 and (J1+J2+J3)/(T1+T2), and the heat dissipation coefficient K is set to be ≥30%, improving the safety and reliability of the electrochemical apparatus 100.
J1, J2, J3, T1, and T2 may be directly measured using a direct measurement method, respectively. Measurement steps include: disassembling the electrochemical apparatus 100, and taking the first electrode plate 21 as a test sample; and directly measuring values of J1, J2, J3, T1, and T2 using a caliper or another appropriate measuring instrument, or acquiring an image of the first electrode plate 21, and performing measurement in the image.
S1 may be calculated according to T1 and T2 in combination with a specific shape of the third region 31. It can be understood that when the third region 31 is rectangular, S1 is a product of T1 and T2.
In some embodiments, when the connection region 311 is welded to the first region 2100, S2 is a sum of projection areas of the plurality of welding spots 3110 in the first direction D1. As shown in
Referring to
It can be understood that when the first conductive plate 30 is welded to the first region 2100 through the connection region 311, a burr or welding mark may be formed at the connection region 311, and the burr or welding mark may puncture the separator 23, causing a short circuit. As shown in
In some embodiments, the first layer 50 may extend beyond the first region 2100 as well as cover and be adhered to a part of the first conductive material layer 211. Specifically, the first conductive material layer 211 includes a first conductive material region 2111, where the first conductive material region 2111 encloses the first recess 2110. The first layer 50 is further adhered to the first conductive material region 2111. For ease of distinction, the first conductive material region 2111 and other regions of the first conductive material layer 211 are shown in different filling manners in
As shown in
In some embodiments, L1 ranges from 10 mm to 50 mm. When L1 is large, the first conductive material layer 211 covered by the first layer 50 in the second direction D2 has a relatively large size, and therefore has a greater impact on the capacity of the electrochemical apparatus 100. When L1 is small, the first region 2100 also has a small size in the second direction D2, so that the distance J3 between the third side 3103 and the seventh side 2103 is also small, and thus the heat dissipation coefficient K of the first region 2100 is reduced, and the heat dissipation capability is relatively reduced.
As shown in
As shown in
As shown in
As shown in
In some other embodiments, when the first electrode plate 21 is a negative electrode plate and the second electrode plate 22 is a positive electrode plate, the third layer 70 may also be configured to hinder movement, toward the second recess 2120, of lithium ions deintercalated from a part of the third conductive material layer 221 corresponding to the third layer 70 in the first direction D1, thereby reducing the risks of excessive accumulation of lithium ions and formation of lithium dendrites due to the lack of lithium ions that may be embedded in the second recess 2120. Similarly, the fourth layer 80 may also be configured to hinder movement, toward the first recess 2110, of lithium ions deintercalated from a part of the fourth conductive material layer 222 corresponding to the fourth layer 80 in the first direction D1, thereby reducing the risks of excessive accumulation of lithium ions and formation of lithium dendrites due to the lack of lithium ions that may be embedded in the first recess 2110.
As shown in
As shown in
As shown in
Referring to
A first conductive material region 2111 includes a first extension region 2112 and a second extension region 2113 extending toward the third recess R in the third direction D3. Viewed in the first direction D1, the first extension region 2112 and the second extension region 2113 are disposed on two sides of the third recess R and are connected to the third recess R. Viewed in the first direction D1, the first extension region 2112 is connected between the fifth side 2101 and the first lateral side R1 of the third recess R, and the second extension region 2113 is connected between the sixth side 2102 and the second lateral side R2 of the third recess R. In some other embodiments, as shown in
Further, a size of the first extension region 2112 in the third direction D3 is W1, and a size of the second extension region 2113 in the third direction D3 is W2, where (W1+W2)/T1≥20%. (W1+W2)/T1 may reflect a size proportion of the third recess R in the third direction D3, and larger (W1+W2)/T1 indicates a smaller size proportion of the third recess R. Therefore, limiting the value of (W1+W2)/T1 may alleviate reduction of the heat dissipation area of the first region 2100 caused by provision of the third recess R. As shown in
In this embodiment, the first conductive material region 2111 further includes the first extension region 2112 and the second extension region 2113. Therefore, if the size of the first conductive material region 2111 covered by the first layer 50 needs to be limited, in some embodiments, in addition to defining the distance between the third end edge 2104 of the first region 2100 in the second direction D2 and the eighth side 51 as L1 and defining the distance between the seventh side 2103 and the eighth side 51 as L3, sizes of the first extension region 2112 and the second extension region 2113 covered by the first layer 50 may be further limited. Therefore, the first extension region 2112 and the second extension region 2113 are further defined to have a same size of L2 in the second direction D2, and (L2+L3)/L1 is set to be ≤30%. (L2+L3)/L1 is limited, so that in the second direction D2, a size of the first conductive material region 2111 covered by the first layer 50 is reduced, that is, an active material covered by the first layer 50 and unlikely to contribute to capacity is reduced, thereby reducing the impact of the first layer 50 on the capacity of the electrochemical apparatus 200.
As shown in
As shown in
As shown in
In some embodiments, in the second direction D2, the first extension region 2112 and the second extension region 2113 both have a size of L2, and a distance between the ninth side 2114 and the fourth side 3104 is L4, where L2<L4. L4 represents a distance between the end portion of the ninth side 2114 connected to the first lateral side R1 and the fourth side 3104. L4 may reflect a length of a portion of the first region 2100 exposed from a side of the fourth side 3104 of the first conductive plate 30. L2 is defined to be <L4, so that the relatively large L4 helps to further increase the heat dissipation area of the first conductive plate 30, thereby reducing a temperature rise during large-current charging.
Referring to
The electrochemical apparatus 100 (or the electrochemical apparatus 200 or 300) of this application includes all apparatuses in which an electrochemical reaction may take place. Specifically, the electrochemical apparatus 100 includes all kinds of primary batteries, secondary batteries, fuel batteries, solar batteries, or capacitors (for example, super capacitors). Optionally, the electrochemical apparatus 100 may be a lithium secondary battery, including a lithium metal secondary battery, a lithium-ion secondary battery, a lithium polymer secondary battery, and a lithium-ion polymer secondary battery.
Referring to
The electrochemical apparatus 100 of this application is applicable to the electronic apparatuses 1 in various fields. In an embodiment, the electronic apparatus 1 of this application may be but is not limited to a notebook computer, a pen-input computer, a mobile computer, an electronic book player, a portable telephone, a portable fax machine, a portable copier, a portable printer, a stereo headset, a video recorder, a liquid crystal television, a portable cleaner, a portable CD player, a mini-disc, a transceiver, an electronic notebook, a calculator, a memory card, a portable recorder, a radio, a standby power source, a motor, an automobile, a motorcycle, a motor bicycle, a bicycle, a lighting appliance, a toy, a game console, a clock, an electric tool, a flash lamp, a camera, a large household battery, and a lithium-ion capacitor.
The following describes this application in detail with reference to specific examples and comparative examples. An example in which the electrochemical apparatus is a battery is used for describing this application with reference to specific test methods.
On a cold-pressed first electrode plate, a first recess was formed by laser cleaning in a first conductive material layer, so that a first region was exposed from the first recess. No third recess was provided in the first region. Then, a first conductive plate was welded to the first region, with one welding spot. The area of the welding spot was S2. Specific values of T1, T2, S1, S2, J1, J2, J3, and L3/L1 were recorded in Table 1. The second electrode plate, the separator, the electrolyte, and the like adopted a conventional design.
In each of examples 1 to 4 and comparative example 1, the first electrode plate, the separator, and the second electrode plate were stacked, wound, and put into a housing. Then, the electrolyte was injected into the housing to obtain a battery with a size of 5.2 mm×65.4 mm×82.5 mm and a capacity of 5.0 Ah. Subsequently, each battery was quickly charged. Specifically, the charging process included: (1) the battery was constant-current charged to 4.25 V at 2.0 C and constant-voltage discharged to 1.5 C; (2) the battery was left standing for 5 min; (3) the battery was constant-current charged to 4.38 V at 1.5 C and constant-voltage discharged to 1.0 C; (4) the battery was left standing for 5 min; (5) the battery was constant-current charged to 4.43 V at 1.0 C and constant-voltage discharged to 0.05 C; and (6) the battery was left standing for 5 min. Before charging, a multi-channel thermometer was used to measure a temperature close to the position of the first conductive plate as t1. After charging was completed, the multi-channel thermometer was used to measure a temperature close to the position of the first conductive plate as t2, and a temperature rise Δt=t2−t1, which was recorded in Table 1. In addition, it should be additionally noted that for a charging current of the battery, reference is generally made to rate C, where C is a value corresponding to the capacity of the battery. For example, when the capacity of the battery is 5.0 Ah, corresponding 1 C is 5.0 A, and 2 C is equal to 10.0 A.
It may be learned from the data of Table 1 that as compared with comparative example 1, the batteries in examples 1 to 4 satisfy that the heat dissipation coefficient K≥30%, so each battery has a small temperature rise after quickly charged. Moreover, a larger heat dissipation coefficient indicates a smaller temperature rise of the battery. In addition, in examples 2 and 3, the heat dissipation coefficients are the same; however, L3/L1 in example 2 is smaller, and therefore the temperature rise is smaller.
Examples 5 to 9 differ from examples 1 to 4 in that the first regions in examples 5 to 9 were each provided with a third recess, and specific values of T1, T2, S1, S2, J1, J2, J3, and (L2+L3)/L1 were different and were recorded in Table 2, respectively.
Examples 10 and 11 differ from example 5 in that values of (L2+L3)/L1 in examples 10 and 11 were different and were recorded in Table 3, respectively.
In each of examples 5 to 9, the first electrode plate, the separator, and the second electrode plate were stacked, wound, and put into a housing. Then, the electrolyte was injected into the housing to obtain a battery with a size of 5.40 mm×80.3 mm×70.7 mm and a capacity of 5.2 Ah. Subsequently, each battery was quickly charged. Specifically, the charging process included: (1) the battery was constant-current charged to 4.25 V at 2.0 C and constant-voltage discharged to 1.5 C; (2) the battery was left standing for 5 min; (3) the battery was constant-current charged to 4.38 V at 1.5 C and constant-voltage discharged to 1.0 C; (4) the battery was left standing for 5 min; (5) the battery was constant-current charged to 4.43 V at 1.0 C and constant-voltage discharged to 0.05 C; and (6) the battery was left standing for 5 min. A temperature rise Δt at a position close to the first conductive plate before and after charging was measured, and the result was recorded in Table 2.
It may be learned from the data of Table 2 that the batteries in examples 5 to 9 satisfy that the heat dissipation coefficient K≥30%, so each battery has a small temperature rise after quickly charged. Moreover, a larger heat dissipation coefficient indicates a smaller temperature rise of the battery.
In each of examples 5, 10, and 11, the first electrode plate, the separator, and the second electrode plate were stacked, wound, and put into a housing. Then, the electrolyte was injected into the housing to obtain a battery with a size of 5.2 mm×65.4 mm×82.5 mm and a capacity of 5.0 Ah. Subsequently, each battery was quickly charged. Specifically, the charging process included: (1) the battery was constant-current charged to 4.05 V at 2.0 C and constant-voltage discharged to 1.6 C; (2) the battery was left standing for 5 min; (3) the battery was constant-current charged to 4.25 V at 1.6 C and constant-voltage discharged to 1.2 C; (4) the battery was left standing for 5 min; (5) the battery was constant-current charged to 4.35 V at 1.2 C and constant-voltage discharged to 0.8 C; (6) the battery was left standing for 5 min; (7) the battery was constant-current charged to 4.45 V at 0.8 C, and constant-voltage discharged to 0.05 C; and (8) the battery was left standing for 5 min. A temperature rise Δt at a position close to the first conductive plate before and after charging was measured, and the result was recorded in Table 3.
It may be learned from the data of Table 3 that in examples 5, 10, and 11, the heat dissipation coefficients are the same; however, compared with example 10, examples 5 and 11 satisfy that (L2+L3)/L1≤30%, so the temperature rise is smaller; and the value of (L2+L3)/L1 in example 5 is the smallest, so the temperature rise is accordingly the smallest.
Examples 12 to 14 differ from example 5 in that the specific values of T1, T2, S1, S2, J1, J2, J3, (L2+L3)/L1, and (W1+W2)/T1 in examples 12 to 14 were different and were recorded in Table 4, respectively.
In each of examples 5 and 12 to 14, the first electrode plate, the separator, and the second electrode plate were stacked, wound, and put into a housing. Then, the electrolyte was injected into the housing to obtain a battery with a size of 3.77 mm×62.0 mm×141.0 mm and a capacity of 5.2 Ah. Subsequently, each battery was quickly charged. Specifically, the charging process included: (1) the battery was constant-current charged to 4.2 Vat 1.8 C and constant-voltage discharged to 0.7 C; (2) the battery was left standing for 5 min; (3) the battery was constant-current charged to 4.4 V at 0.7 C and constant-voltage discharged to 0.05 C; and (4) the battery was left standing for 5 min. A temperature rise Δt at a position close to the first conductive plate before and after charging was measured, and the result was recorded in Table 4.
It may be learned from the data of Table 4 that compared with example 12, example 5 has the same heat dissipation coefficient K and same value of (L2+L3)/L1, but has a larger value of (W1+W2)/T1, and therefore has a smaller temperature rise. Compared with example 14, example 13 has the same heat dissipation coefficient K and same value of (L2+L3)/L1, but has a larger value of (W1+W2)/T1, and therefore has a smaller temperature rise.
In conclusion, it should be noted that the foregoing examples are merely intended to describe the technical solutions of this application, but not intended to constitute any limitation. Although this application is described in detail with reference to preferred embodiments, persons of ordinary skill in the art should understand that modifications or equivalent replacements may be made to the technical solutions of this application, without departing from the spirit and scope of the technical solutions of this application.
This application is a continuation application of PCT application No. PCT/CN2021/136523, filed on Dec. 8, 2021, the content of which is incorporated herein by reference in its entirety.
Number | Date | Country | |
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Parent | PCT/CN2021/136523 | Dec 2021 | US |
Child | 18400146 | US |