Claims
- 1. An electrochemical cell having a controlled electrode surface comprising:
- a first electrode and a second electrode wherein at least one of the first and second electrodes includes a carbonaceous surface;
- an electrolyte including at least one solvent;
- a reduced additive associated with the carbonaceous surface of at least one of the first and second electrodes, wherein the reduced additive is at least one of substantially insoluble in the electrolyte or associated with the carbonaceous surface of the electrode, and, wherein the reduced additive includes an additive which is either soluble or insoluble in the electrolyte prior to reduction;
- passivating means including at least one of the additive and reduced additive for substantially precluding contact between the at least one solvent of the electrolyte and the carbonaceous surface of at least one of the first and second electrodes to, in turn, substantially prevent gas formation within the cell, which would otherwise result from decomposition of the solvent upon contact with the carbonaceous surface; and
- means associated with at least one of the additive and reduced additive for substantially precluding gas formation within the electrochemical cell as a result of decomposition of the additive or reduced additive at the electrode with the carbonaceous surface during cell cycling and storage.
- 2. The electrochemical cell according to claim 1, wherein the reduced additive includes a multi-dentate complex with at least one metal cation.
- 3. The electrochemical cell according to claim 2, wherein the at least one metal cation is Li.sup.+.
- 4. The electrochemical cell according to claim 1, wherein the reduced additive is insoluble in the electrolyte.
- 5. The electrochemical cell according to claim 1, wherein the additive is applied directly onto the carbonaceous surface of the at least one electrode.
- 6. A process for manufacturing an electrochemical cell comprising the steps of:
- fabricating a first and a second electrode wherein at least one of the electrodes includes a carbonaceous surface;
- associating at least one electrolyte, having at least one solvent, with the first and second electrodes; and
- associating either an insoluble or soluble additive with at least one of the electrolyte or the at least one electrode with the carbonaceous surface, wherein the additive is insoluble with the electrolyte in its reduced state.
- 7. The process according to claim 6, wherein the manufactured electrochemical cell exhibits a first cycle coulombic efficiency greater than 23%.
- 8. The process according to claim 6, wherein the reduced additive includes a multi-dentate complex with at least one metal cation.
- 9. The process according to claim 8, wherein the at least one metal cation is Li.sup.+.
- 10. The process according to claim 6, wherein additive is insoluble in the electrolyte.
- 11. The process according to claim 10, wherein the additive is applied directly onto the carbonaceous surface of the at least one electrode.
- 12. A chemical process for an electrochemical cell comprising the steps of:
- fabricating a first and a second electrode wherein at least one of the electrodes includes a carbonaceous surface;
- associating at least one electrolyte, having at least one solvent, with the first and second electrodes;
- associating either an insoluble or soluble additive with at least one of the electrolyte or the at least one electrode with the carbonaceous surface, wherein the additive is insoluble with the electrolyte in its reduced state; and
- forming a passivating layer between the carbonaceous surface of the at least one electrode and the electrolyte; wherein the step of forming the passivating layer includes the steps of:
- charging the electrochemical cell;
- reducing the additive at the carbonaceous surface so that the reduced additive is substantially insoluble with the electrolyte;
- blocking the at least one solvent in the electrolyte from chemical interaction with the carbonaceous surface of the at least one electrode; and
- substantially precluding gas formation within the electrochemical cell as a result of decomposition of at least one of the additive and reduced additive during cell cycling and storage.
- 13. The chemical process according to claim 12, wherein the electrochemical cell exhibits a first cycle coulombic efficiency greater than 23%.
- 14. The chemical process according to claim 12, wherein the reduced additive includes a multi-dentate complex with at least one metal cation.
- 15. The process according to claim 14, wherein the at least one metal cation is Li.sup.+.
- 16. The process according to claim 12, wherein additive is insoluble in the electrolyte.
- 17. The process according to claim 16, wherein the additive is applied directly onto the carbonaceous surface of the at least one electrode.
Parent Case Info
This is a Continuation-In-Part of U.S. patent application Ser. No. 08/812,021, filed Mar. 6, 1997, now U.S. Pat. No. 5,853,917 the entirety of which is incorporated herein by reference.
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5529859 |
Shu et al. |
Jun 1996 |
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5626981 |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
812021 |
Mar 1997 |
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