This application relates to the technical field of batteries, and in particular, to an electrochemical device and an electronic device.
An electrode post of a steel-shell battery is typically fixed to a cover of the steel-shell battery by rivet-pressing. An insulation sealing gasket is sandwiched between the electrode post and the cover to implement hermetic insulation. However, during the formation by rivet-pressing, the insulation sealing gasket may slide and be dislocated, thereby resulting in a loose sealing surface, being prone to leakage at the sealing junction, and posing a safety hazard. On the other hand, in order to ensure hermeticity during rivet-pressing, a relatively large rivet pressure is usually applied. However, excessive rivet pressure is prone to cause the electrode post to turn outward, thereby affecting the sealing area. If the rivet pressure is overly small, the pressure on the sealing interface is small, thereby also impairing the sealing effect.
This application is to provide an electrochemical device and an electronic device to improve at least the sealing effect of the electrochemical device.
According to a first aspect of this application, an electrochemical device is provided, including a housing, a first sealing ring, and an electrode post. The housing includes a cover provided with a through-hole. The cover includes a first wall surface and a second wall surface disposed opposite to each other. The first wall surface is facing toward an inner cavity of the housing. The first sealing ring includes a first annular surface and a second annular surface disposed opposite to each other. The first annular surface connects to the first wall surface. The first sealing ring is disposed around a hole axis of the through-hole. The electrode post includes a first part and a second part. The first part is inserted into the through-hole. The second part is connected to an end portion of the first part, the end portion being located in the inner cavity of the housing. The second part includes a third annular surface facing toward the first wall surface. The third annular surface includes a first region connected to the second annular surface. The first region includes a first edge and a second edge that are disposed opposite to each other. The second edge is farther away from the through-hole than the first edge. When viewed in a direction perpendicular to the hole axis of the through-hole, the second edge is located between the first edge and the second wall surface in a direction parallel to the hole axis.
When the electrode post is being rivet-pressed, the second edge can play a role in constraining and blocking the first sealing ring, thereby suppressing the sliding and dislocation of the first sealing ring. At the same time, the slope from the first edge to the second edge reduces the tangential rivet pressure parallel to the first region, and reduces the assembling sliding between the first sealing ring and the electrode post. Moreover, the slope from the first edge to the second edge suppresses the electrode post from being turned out, increasing the sealing area, and increasing the normal-direction rivet pressure perpendicular to the first region, thereby improving the sealing reliability.
In an improved technical solution based on the above technical solution, the first edge intersects a first plane at a first intersection point. The second edge intersects the first plane at a second intersection point. A straight line intersects the hole axis at a third intersection point, where the straight line passes through the first intersection point and the second intersection point. Along a direction of the hole axis, an angle between a line from the third intersection point to the through-hole and a line from the third intersection point to the second intersection point is α, satisfying: 60°≤α≤88°, and the first plane is a plane passing through the hole axis.
The first region is a slope, and the electrode post connects to the first sealing ring through the slope, thereby increasing the sealing region between the first sealing ring and the electrode post. In addition, the tangential force parallel to the first region and exerted on the first sealing ring is reduced, thereby effectively reducing the sliding and dislocation of the first sealing ring. Moreover, the normal force perpendicular to the first region and exerted on the first sealing ring is increased, and the pressure on a sealing interface between the first sealing ring and the electrode post is greater, thereby improving the reliability of sealing between the first sealing ring and the electrode post.
In an improved technical solution based on the above technical solution, the angle α satisfies: 75°≤α≤85°. In this case, the first region has a greater inclination, thereby further suppressing the sliding and dislocation of the first sealing ring, reducing the tangential force parallel to the first region and exerted on the first sealing ring, and increasing the normal force perpendicular to the first region and exerted on the first sealing ring, thereby further improving the sealing reliability.
In an improved technical solution based on the above technical solution, the first wall surface includes a second region connected to the first annular surface. The second region includes a third edge and a fourth edge disposed opposite to each other. The fourth edge is farther away from the through-hole than the third edge. The third edge intersects the first plane at a fourth intersection point, the fourth edge intersects the first plane at a fifth intersection point, and an other straight line intersects the hole axis at a sixth intersection point, where the other straight line passes through the fourth intersection point and the fifth intersection point; along a direction of the hole axis, an angle between a line from the sixth intersection point to the through-hole and a line from the sixth intersection point to the fifth intersection point is β, satisfying: 60°≤β≤88°.
The second region is a slope, and the first sealing ring connects to the cover through the slope, thereby increasing the sealing area between the first sealing ring and the cover. In addition, the tangential force parallel to the second region and exerted on the first sealing ring is reduced, thereby effectively reducing the sliding and dislocation of the first sealing ring. Moreover, the normal force perpendicular to the second region and exerted on the first sealing ring is increased, and the pressure on a sealing interface between the first sealing ring and the cover is greater, thereby improving the reliability of sealing between the first sealing ring and the cover.
In an improved technical solution based on the above technical solution, the angle β satisfies: 75°≤β≤85°. In this case, the second region has a greater inclination, thereby further suppressing the sliding and dislocation of the first sealing ring, reducing the tangential force parallel to the second region and exerted on the first sealing ring, and increasing the normal force perpendicular to the second region and exerted on the first sealing ring, thereby further improving the sealing reliability.
In an improved technical solution based on the above technical solution, the angles satisfy: 0.7×(90°−α)≤(90°−β)≤1.2×(90°−α), that is, (1.2α−18°)≤β≤(0.7α+27°). In this case, the inclinations of the first and second regions can be better matched, thereby increasing the pressure on the sealing interface between the first sealing ring and the electrode post as well as the sealing interface between the first sealing ring and the cover, and in turn, further improving the sealing reliability.
In an improved technical solution based on the above technical solution, the angles satisfies: α≤β, thereby further improving the sealing effect of the first sealing ring.
In an improved technical solution based on the above technical solution, the electrochemical device further includes a second sealing ring. The second sealing ring is sleeved around an end portion of the first part, the end portion facing away from the second part. The second sealing ring includes a fourth annular surface, and the second wall surface includes a third region connected to the fourth annular surface. The third region includes a fifth edge and a sixth edge that are disposed opposite to each other. The sixth edge is farther away from the through-hole than the fifth edge. The fifth edge intersects the first plane at a seventh intersection point. The sixth edge intersects the first plane at an eighth intersection point. An other straight line intersects the hole axis at a ninth intersection point, where the other straight line passes through the seventh intersection point and the eighth intersection point. Along a direction of the hole axis, an angle between a line from the ninth intersection point to the second sealing ring and a line from the ninth intersection point to the eighth intersection point is λ, satisfying: 60°≤λ≤88°.
The third region is a slope, and the second sealing ring connects to the cover through the slope, thereby increasing the sealing length between the second sealing ring and the cover, and in turn, increasing the sealing area between the second sealing ring and the cover. In addition, the tangential force parallel to the third region and exerted on the second sealing ring is reduced, and the normal force perpendicular to the third region is increased, thereby further improving the reliability of sealing between the second sealing ring and the cover.
In an improved technical solution based on the above technical solution, the first region is an annular region surrounding the hole axis. The first edge is an inner circle of the annular region. The second edge is an outer circle of the annular region. In this case, all the first region around the first part is upward inclined slopes. No matter in which direction the electrode post is bent and rivet-pressed, the second edge can constrain the first sealing ring.
In an improved technical solution based on the above technical solution, a cross-section of the third annular surface at the first plane includes a first line. The first line includes a first straight line segment. The first straight line segment connects the first intersection point and the first part. An angle between the first straight line segment and the hole axis is θ, satisfying: 89°≤θ≤91°. A length of the first line is L, and a length of the first straight line segment is A, satisfying: A≤0.7 L. The sealing structure between the second part of the electrode post and the first sealing ring may be a pure-slope sealing structure or a plane plus slope sealing structure. The plane plus slope sealing structure can also play a role in constraining and blocking the first sealing ring, so as to suppress the sliding and dislocation of the first sealing ring. In addition, this sealing structure can also increase the sealing area between the first sealing ring, thereby ensuring good performance of sealing between the first sealing ring and the electrode post.
In an improved technical solution based on the above technical solution, the second part further includes a fourth region disposed opposite to the first region. The fourth region is facing toward the inner cavity of the housing. The fourth region includes a seventh edge and an eighth edge. The eighth edge is farther away from the through-hole than the seventh edge. When viewed in a direction perpendicular to the hole axis of the through-hole, the eighth edge is located between the seventh edge and the second wall surface in a direction parallel to the hole axis. The first region and the fourth region can be conveniently formed by stamping the straight peripheral edge of the second part and making the peripheral edge of the second part tilt upward.
In an improved technical solution based on the above technical solution, the electrochemical device further includes a gasket. The gasket connects to a surface of the second sealing ring, the surface of the second sealing ring facing away from the inner cavity. The first part includes a bend portion extending out of the through-hole, and the bend portion is bent toward the gasket.
According to a second aspect, this application further provides an electronic device. The electronic device includes the electrochemical device according to any one of the embodiments of the first aspect.
To describe the technical solutions of the embodiments of this application more clearly, the following outlines the drawings used in the embodiments of this application. Evidently, the drawings outlined below are merely a part of embodiments of this application. A person of ordinary skill in the art may derive other drawings from the outlined drawings.
10. housing; 11. inner cavity; 12. cover; 121. first wall surface; 1211. second region; 1211a. third edge; 1211b. fourth edge; 122. second wall surface; 1221. third region; 1221a. fifth edge; 1221b. sixth edge; 13. through-hole; 131. hole axis;
20. first sealing ring; 21. first annular surface; 22. second annular surface; 221. second straight line segment;
30. electrode post; 31. first part; 311. bend portion; 312. snap slot; 32. second part; 321. third annular surface; 3211. first region; 3211a. first edge; 3211b. second edge; 3212. first straight line segment; 33. fourth region; 33a. seventh edge; 33b. eighth edge;
40
a. first intersection point; 40b. second intersection point; 40c. third intersection point; 40d. fourth intersection point; 40e. fifth intersection point; 40f. sixth intersection point; 40g. seventh intersection point; 40h. eighth intersection point; 40i. ninth intersection point; 40j. tenth intersection point; 40k. eleventh intersection point; 401. twelfth intersection point;
50. second sealing ring; 51. fourth annular surface; 52. extension portion;
60. gasket.
For ease of understanding this application, the following describes this application in more detail with reference to drawings and specific embodiments. It is hereby noted that an element referred to herein as being “fixed to”, “fastened to”, or “mounted to” another element may be directly disposed on the other element, or may be fixed or fastened to the other element with one or more elements in between. An element referred to herein as “connected to” another element may be connected to the other element directly or with one or more elements in between. The terms “up”, “down”, “in”, “out”, and other similar expressions used herein are merely for ease of description.
Unless otherwise defined, all technical and scientific terms used herein bear the same meanings as what is normally understood by a person skilled in the technical field of this application. The terms used in the specification of this application are merely intended to describe specific embodiments but not to limit this application.
In addition, to the extent that no mutual conflict occurs, the technical features described below in different embodiments of this application may be combined with each other.
In this specification, the meanings of “mounting” or “installation” include fixing or confining an element or unit to a specific position or place by welding/soldering, screwing, snap-fit connection, bonding, or other means, where the element or unit may be held stationary in the specific position or place or may move within a limited range, and the element or unit may be detachable or undetachable after being fixed or confined to the specific position or place, without being limited in embodiments of this application.
An embodiment of this application discloses an electrochemical device. Referring to
With respect to the housing 10, referring to
With respect to the first sealing ring 20, referring to
With respect to the electrode post 30, in this embodiment, the electrode post 30 may serve as a positive lead-out piece of the steel-shell battery. The steel-shell battery differs from an aluminum laminated film battery in that the steel shell includes only one layer, that is, a layer of steel sheet, but the aluminum laminated film is a three-layer structure including a nylon layer, an aluminum layer, and a PP layer. Because the steel shell includes no nylon layer or PP layer, the steel shell itself may be used as a negative electrode, and a positive electrode may be isolated from the steel shell body by dielectric and hermetical riveting.
Referring to
Referring to
Referring to
To alleviate the above problem, in an embodiment, referring to
According to some embodiments of this application, referring to
According to some embodiments of this application, referring to
In this embodiment, the third region 1221 is a slope, and the second sealing ring 50 connects to the cover 12 through the slope, thereby increasing the sealing length between the second sealing ring 50 and the cover 12, and in turn, increasing the sealing area between the second sealing ring 50 and the cover 12. In addition, the tangential force between the cover 12 and the second sealing ring 50 is reduced, and the normal force is increased, thereby further improving the reliability of sealing between the second sealing ring 50 and the cover 12. In some embodiments, the angle satisfies: (1.2α−18°)≤λ≤(0.7α+27)°. In order to facilitate the third region 1221 to abut and constrain the second sealing ring 50, the angle λ may be set to be less than the angle β.
According to some embodiments of this application, the first region 3211 is an annular region surrounding the hole axis 131, the first edge 3211a is an inner circle of the annular region, and the second edge 3211b is an outer circle of the annular region. In this embodiment, the first region 3211 around the first part 31 is an upward inclined slope. No matter in which direction the bend portion 311 is bent and rivet-pressed, the second edge 3211b can constrain the first sealing ring 20. In actual operation, the bend portion 311 is usually bent away from the hole axis 131. Therefore, in some optional embodiments, on just one side in the bending direction of the bend portion 311, when viewed in a direction perpendicular to the hole axis 131, the second edge 3211b is located between the first edge 3211a and the second wall surface 122 in a direction parallel to the hole axis 131.
Referring to
According to some embodiments of this application, referring to
The seventh edge 33a intersects the first plane at a tenth intersection point 40j. The eighth edge 33b intersects the first plane at an eleventh intersection point 40k. An other straight line intersects the hole axis 131 at a twelfth intersection point 40l, where the other straight line passes through the tenth intersection point 40j and the eleventh intersection point 40k. Along the direction of the hole axis 131, an angle between a line from the twelfth intersection point 40l to the through-hole 13 and a line from the twelfth intersection point 40l to the eleventh intersection point 40k is δ, satisfying: 60°≤δ≤88°. In some embodiments, 8≤a.
According to some embodiments of this application, referring to
In these embodiments of this application, the first region 3211 is a set to be a slope, and the electrode post 30 connects to the first sealing ring 20 through the slope, thereby increasing the sealing area between the first sealing ring 20 and the electrode post 30. Similarly, the tangential force exerted on the first sealing ring 20 is reduced, thereby effectively reducing the sliding and dislocation of the first sealing ring 20. Moreover, the normal force exerted on the first sealing ring 20 is increased, and the pressure on a sealing interface between the first sealing ring 20 and the electrode post 30 is greater, thereby improving the sealing reliability of the first sealing ring 20. Based on the same inventive concept, the cover 12 connects to the first sealing ring 20 through a slope, and the second sealing ring 50 connects to the cover 12 through a slope. The connection implemented through the three slopes can further improve the reliability of the sealing of the electrode post 30.
The sealing effect is tested by using a steel-shell lithium-ion battery as an example. Both sides of the cover of the steel-shell lithium-ion battery are planar structures. A rivet pressure is applied in a direction that is at an angle of 45° to the hole axis direction during the rivet-pressing. The sealing length L between the first sealing ring 20 on one side of the electrode post 30 and the second part 32 of the electrode post 30 is 2 mm. Examples 1 to 8 differ from Comparative Example 1 in that the peripheral edge of the second part 32 of the electrode post 30 is bent upward in full or in part by stamping, so as to form a pure-slope sealing structure or a plane plus slope sealing structure. The length of the plane region is A. The method for verifying the sealing effect is to store a steel-shell lithium-ion battery in a 60° C. high temperature and 90% relative humidity environment for 7 days. If there is no rupture or leakage occurs, the battery passes the test without failure. If any rupture or leakage occurs, the battery fails the test. The number of specimens of the steel-shell lithium-ion battery in each test is set to 5. The failure rate is required to be 20% or less. The test results are shown in Table 1 below.
The test results show that the steel-shell lithium-ion battery that employs a pure slope sealing structure or a plane plus slope sealing structure exhibits a relatively good sealing effect and a relatively low failure rate when stored in a high temperature and high humidity environment. By contrast, the steel-shell lithium-ion battery that employs a conventional pure-plane sealing structure exhibits a relatively high failure rate and fails to meet the requirements.
As can be further seen from the corresponding test results in Table 1, when the width A of the plane region satisfies A≤0.5 L and the angle satisfies 75°≤α≤85°, the failure rate of steel-shell lithium-ion batteries stored in a high temperature and high humidity environment is further significantly reduced, and the sealing performance is significantly improved. Therefore, the sealing reliability of the steel-shell lithium-ion batteries with A and a falling within the specified ranges is obviously superior.
An embodiment of this application further discloses an electronic device. The electronic device includes the electrochemical device disclosed in any one of the above embodiments.
An embodiment of this application provides an electronic device that uses an electrochemical device as a power supply. The electronic device may be, but is not limited to, a Bluetooth headset, mobile phone, tablet, laptop computer, electric toy, electric tool, electric power cart, electric vehicle, ship, spacecraft, or the like. The electric toy may include stationary or mobile electric toys, such as game console, electric car toy, electric ship toy, electric airplane toy, and the like. The spacecraft may include airplane, rocket, space shuttle, spaceship, and the like.
Finally, it is hereby noted that the foregoing embodiments are merely intended to describe the technical solutions of this application but not to limit this application. Based on the concept of this application, the technical features in the foregoing embodiments or different embodiments may be combined, the steps may be implemented in any order, and many variations may be made to this application in different aspects, which, for brevity, are not provided in detail. Although this application has been described in detail with reference to the foregoing embodiments, a person of ordinary skill in the art understands that modifications may still be made to the technical solutions described in the foregoing embodiments, or equivalent replacements may still be made to some technical features in the technical solutions. Such modifications and replacements do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of this application.
This application is a continuation application of International Application No. PCT/CN2022/089925, filed on Apr. 28, 2022, the content of which is incorporated herein by reference in its entirety.
Number | Date | Country | |
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Parent | PCT/CN2022/089925 | Apr 2022 | WO |
Child | 18928529 | US |