Patent Application
20100072079
FRANCE No. 0856462 filed Sep. 25, 2008
The present patent application relates to the electrochemical detection of boron, most often in very low doses, or even in the state of traces (i.e. generally a few units to a few hundred ppb—parts per billion—, by weight) in liquid, generally water.
Generally, the detection of boron in a liquid which is generally aqueous, most often water, can be carried out using numerous techniques, most often by electrochemical methods such as polarography.
Boron is a substance which is particularly difficult to detect in that it must be detected when present in very small quantities in water, and, above all, in that it is necessarily detected as a complex with a complexing agent.
Thus the publication “Voltammetric determination of boron by using Alizarin Red S” (Analytica Chimica Acta 572 (2006) 253-258) describes a novel voltammetric method for determining the presence of boron in water in the trace state, i.e. most often at a level of a few ppb. In this publication, the complexes of boron with Alizarin Red S (ARS) are detected in a buffer solution using a work electrode, which is a hanging mercury drop electrode, by the presence of an anodic peak.
However, apart from the fact that mercury is a substance which is difficult to handle and can present problems as regards safety and the environment, the use of mercury as a work electrode material is tricky, and the equipment is relatively bulky. Consequently, this method can prove complex to implement, and inflexible to use.
The present patent application aims to remedy the drawbacks of the prior art, and in particular the difficulty of implementing a measurement method which does not have the drawbacks of the prior art.
To this end, the invention relates to a method for detecting the presence of boron in water comprising the production of a conductive buffer solution comprising water and at least one boron complexing agent, the introduction into an electrochemical cell of said solution in the presence of at least one work electrode, and the measurement of an anodic peak of the boron complex and complexing agent by voltammetry, said method being characterized in that the work electrode is a solid microelectrode, and in that the measurement is carried out continuously with respect to the flow of water.
Advantageously, the use of such a microelectrode makes it possible to have a measurement method with low environmental toxicity.
On the other hand, the fact of using a solid microelectrode makes it possible to have a method which is easy to carry out by means of particularly compact and inexpensive apparatus.
The use according to the invention of a continuous measurement, in line with respect to the flow of the water in which the presence of boron is measured, is particularly advantageous.
Preferably, the voltammetry measurement is a Differential Pulse Voltammetry (DPV), or a Square Wave Absorptive Stripping Voltammetry Method (SWASVM), or an Absorptive Stripping Voltammetry Method (ASVM) Measurement.
The anodic peak measurement is carried out in the presence of a conductive buffer solution, in general at a given pH. For example, the measurement of anodic peak is carried out according to the following parameters: the conductive buffer solution, for example, comprises an acetate and/or phosphate solution, and the pH can be chosen at 7.4. But any other combination of parameters can also be envisaged by a person skilled in the art, who can use any buffer solution and any appropriate pH. The pH generally depends on various parameters including the concentration and nature of the electrolyte, and its choice must make it possible to optimize the detection of the appearance peak of boron.
Preferably, the boron complexing agent is at a concentration of 10−9 M to 10−3 M, preferably 10−9 M to 10−4 M.
For example in the case of the use of the method according to the invention within the context of a water treatment process, typically downstream of a stage of deionization on a resin bed, not only is the detection method according to the invention perfectly integrated into the treatment process, without slowing it down, but it also makes it possible to have an indication of the depletion of the resin, by detection of the presence of boron.
According to the invention, the boron complexing agent is generally chosen from the group formed by the Alizarin Red S (or ARS, (3,4-dihydroxy-9,10-dioxo)-2-anthracenesulphonic) acid sodium salt) and beryllium (III). But any other complexing agent can also be envisaged by a person skilled in the art within the scope of the invention.
The work microelectrode according to the invention is generally chosen from carbon microelectrodes (i.e. generally vitreous carbon microelectrodes or carbon nanotubes), bismuth microelectrodes (i.e. generally microelectrodes made of bismuth, or microelectrodes coated with a bismuth film), diamond microelectrodes, doped or not doped with boron, and microelectrodes coated with a mercury film, for example. But any other microelectrode can also be envisaged by a person skilled in the art within the scope of the invention. The person skilled in the art is able to choose the parameters defining the work microelectrode, such as the material or materials which form it and its geometry, according to the conditions of implementation.
Advantageously according to the invention, it is possible to calibrate the boron concentration measurement as a function of the anodic peak height. This is conventionally done with a passing through the apparatus of a “blank” solution, i.e. a solution without boron and with the passing through of at least one solution of water, containing boron, at a known concentration of boron.
According to such a calibration, the boron is generally able to be detected at a concentration of at least 5 ppb, generally from 5 to 1000 ppb, preferably from 5 to 400 ppb.
The invention also relates to a detection device for the implementation of a method as described previously. Such a device is characterized in that said device comprises at least one electrochemical cell comprising a liquid inlet means and a separate liquid outlet means, the cell comprises moreover a cell tightness means and a reference electrode, a counter electrode and a work microelectrode, said work microelectrode being able to be introduced in the electrochemical cell in the presence of a conductive buffer solution comprising water and at least one boron complexing agent, and said work mini-electrode being chosen from the carbon microelectrodes, bismuth microelectrodes, boron-doped or non-doped diamond microelectrodes, and microelectrodes coated with a mercury film, said device being able to measure an anodic peak of the boron complex and complexing agent by voltammetry, and to carry out this measurement continuously with respect to the flow of water.
Particularly preferably the three electrodes are microelectrodes.
The device according to the invention also comprises, preferably, a means of processing the signal picked up by the work electrode, said processing means preferably comprising a means for measuring the boron concentration of the liquid present in the cell. Generally such means comprise electronic and/or computer means which allow the storage of the calibration, comparison with the calibration and retransmission of the measurement information.
The device according to the invention can be integrated within a water purification system or be used in an autonomous “stand alone” type module, i.e. generally with no link to the outside and self-sufficient (being able to operate without any outside action or information).
The invention will be better understood on reading the following figures, among which;
The first device 10 for the detection of boron according to the invention is as it is represented in
The cover 2 and the base 1 each comprise threaded openings for fixing the assembly of these two parts by screwing respectively the openings 1B, 1C, 1D, 1E of the base 1 and 2B, 2C, 2D, 2E of the cover 2, assembled by the screws 22B, 22C, 22A, 22D, said assembly producing the electrochemical cell.
The cover 2 comprises two liquid inlet 2A and outlet 2F orifices respectively on which end pieces 3 and 4 are placed respectively and partially, allowing the passage of liquid and ensuring tightness. The ends of the end pieces 3 and 4 which are not immobilized in the wall of the cover 2 are intended to receive flexible pipes with positive locking for the flow of liquid.
The device 10 comprises a plate 7 generally constituted by a support most often made of ceramic, plastic of PDMS (polydimethylsiloxane) type or a silicon wafer type substrate, to which are cemented the three electrodes which are according to the invention microelectrodes 7A, 7B and 7C, namely the reference electrode, the work electrode and the counter electrode. The nature of these electrodes is in general chosen by a person skilled in the art according to the electrolytic medium and other usual parameters.
According to the invention, other types of support plates can be envisaged, for example support plates made of plastic of PTFE (PolyTetraFluoroEthylene), PVDF (Poly Vinylidene Fluoride) or PE (PolyEthylene) type, but also support plates made of other material(s) such as quartz or even stainless steel (insulated). Similarly the geometry of the microelectrodes, in this case in the form of a thin rectangular plate, can be different, for example circular or spiral in shape instead of rectangular. Generally, the person skilled in the art is able to adapt the device used according to the conditions of implementation without exceeding the scope of the invention.
The plate 7 can be inserted into or removed from the device 10 at will, by a simple translation movement, this possibility of movement advantageously giving flexibility of use of said device. The plate 7 is in contact, in particular via the three microelectrodes, with a flexible part 8, of chosen length, which transmits the three electric signals to a rigid plate 9 which allows connection to any electric or electronic detection or even measurement device. The assembly of the support plate 7 and the three microelectrodes, the flexible part 8 and the connection plate 9 constitutes a detachable part of the device 10.
In
The elements for fixing the cover 12 onto the base 11 are not shown here. These are for example welding or cementing means.
In
The invention was implemented according to an illustrative, and non-limitative example, for measuring boron in water by the second device 20 according to the invention, the mixture of the water to be measured and the elements of electrolytic solution (buffer, boron complexing agent) being carried out in line in a liquid access pipe section, for example in the form of a coil.
The device 20 as shown in
The work microelectrode is made of bismuth, more precisely of carbon coated with a bismuth film. The support plate is made of PDMS. The reference electrode is made of Hg/HgCl paste, and the counter electrode is made of carbon.
The calibration curve measured is given in
The measurements were carried out with a 0.1M acetate buffer and 0.1M phosphate buffer and at a pH of 7.4. The accumulation voltage is E=−0.70V over 120 seconds with stirring, the amplitude is 50 mV and the step is 4 mV.
The method and the device according to the invention thus illustrated exhibit a certain advantage in the detection of boron by a reliable, non-toxic, safe measurement method which can be used very effectively in line.
| Number | Date | Country | Kind |
|---|---|---|---|
| 0856462 | Sep 2008 | FR | national |
