As used herein, approximating language may be applied to modify any quantitative representation that may vary without resulting in a change in the basic function to which it is related. Accordingly, a value modified by a term or terms, such as “about” and “substantially,” may not to be limited to the precise value specified, in some cases.
As used herein, the term “substrate” and “wafer” may be used interchangeably; referring to the semiconductor wafer substrate being supported/heated by the apparatus of the invention. Also as used herein, the “treating apparatus” may be used interchangeably with “handling apparatus,” “heating apparatus,” “heater,” or “processing apparatus,” referring to an apparatus containing at least one heating element to heat the wafer supported thereon.
As used herein, the term “circuit” may be used interchangeably with “electrode,” and the term “resistance heating element” may be used interchangeably with “resistor,” “heating resistor,” or “heater.” The term “circuit” may be used in either the single or plural form, denoting that at least one unit is present.
As used herein, a component having a closely matched coefficient of thermal expansion (CTE) means that the CTE of the component is between 0.75 to 1.25 of the CTE of the adjacent layer or another component adjacent to it.
Embodiments of the wafer processing apparatus employing resistance heating elements having the optimized circuit design of the invention are illustrated as follows, by way of a description of the materials being employed, the manufacturing process thereof and also with references to the figures.
General Embodiments of the Wafer Processing Apparatus: In one embodiment as illustrated in
With respect to the base substrate of the wafer processing apparatus of the invention, in one embodiment as illustrated in
In one embodiment as illustrated in
In one embodiment as illustrated in
In the embodiments illustrated in
In one embodiment, the sheet resistance of the electrode is controlled within a range of 0.01 to 0.03 Ω/square to meet the electrical resistance requirement for the electrode, while maintaining the optimal path width and space between the paths of the electrode pattern. The sheet resistance is defined as the ratio of electrical resistivity to film thickness.
In
In one embodiment, the protective coating layer 25 comprises at least a nitride, carbide, carbonitride or oxynitride of elements selected from a group consisting of B, Al, Si, Ga, Y, refractory hard metals, transition metals, and combinations thereof, having a CTE ranging from 2.0×10−6/K to 10×10−6/K in a temperature range of 25 to 1000° C.
In a second embodiment, the protective coating layer 25 comprises a high thermal stability zirconium phosphates, having the NZP structure. The term NZP refers to NaZr2 (PO4)3, as well as to related isostructural phosphates and silicophosphates having a similar crystal structure. These materials in one embodiment are prepared by heating a mixture of alkali metal phosphates or carbonates, ammonium dihydrogen phosphate (or diammonium phosphate) and tetravalent metal oxides.
In one embodiment, the NZP-type coating layer 25 has a general formula: (L,M1,M2,Zn,Ag,Ga,In,Ln,Y,Sc)1, (Zr,V,Ta,Nb,Hf,Ti,Al,Cr,Ln)m (P,Si,VAl)n(O,C,N)12 wherein L=alkali, M1=alkaline earth, M2=transition metal, Ln=rare earth and the values of l, m, n are so chosen that a charge balance is maintained. In one embodiment, the NZP-type protective coating layer 25 includes at least one stabilizer selected from the group of alkaline earth oxides, rare earth oxides, and mixtures thereof. Examples include yttria (Y2O3) and calcia (CaO).
In one embodiment, the protective coating layer 25 contains a glass-ceramic composition containing at least one element selected from the group consisting of elements of the group 2a, group 3a and group 4a of the periodic table of element. The group 2a as referred to herein means an alkaline earth metal element including Be, Mg, Ca, Sr and Ba. The group 3a as referred to herein means Sc, Y or a lanthanoid element. The group 4a as referred to herein means Ti, Zr or Hf. Examples of suitable glass-ceramic compositions for use as the coating layer 25 include but are not limited to lanthanum aluminosilicate (LAS), magnesium aluminosilicate (MAS), calcium aluminosilicate (CAS), and yttrium aluminosilicate (YAS).
In one example, the protective coating layer 25 contains a mixture of SiO2 and a plasma-resistant material comprising an oxide of Y, Sc, La, Ce, Gd, Eu, Dy, or the like, or a fluoride of one of these metals, or yttrium-aluminum-garnet (YAG). Combinations of the oxides of such metals, and/or combinations of the metal oxides with aluminum oxide, may be used. In a third embodiment, the protective coating layer 25 comprises from 1 to 30 atomic % of the element of the group 2a, group 3a or group 4a and from 20 to 99 atomic % of the Si element in terms of an atomic ratio of metal atoms exclusive of oxygen. In one example, the layer 25 includes aluminosilicate glasses comprising from 20 to 98 atomic % of the Si element, from 1 to 30 atomic % of the Y, La or Ce element, and from 1 to 50 atomic % of the Al element, and zirconia silicate glasses comprising from 20 to 98 atomic % of the Si element, from 1 to 30 atomic % of the Y, La or Ce element, and from 1 to 50 atomic % of the Zr element.
In another embodiment, the protective coating layer 25 is based on Y2O3—Al2O3—SiO2 (YAS), with the yttria content varying from 25 to 55 wt. % for a melting point of less than 1600° C. and a glass transition temperature (Tg) in a narrow range of 884 to 895° C., with optional dopants added to adjust the CTE to match that of the adjacent substrate. Examples of dopants include BaO, La2O3, or NiO to increase the CTE of the glass, and ZrO2 to decrease the CTE of the glass. In yet another embodiment, the protective coating layer 25 is based on BaO—Al2O3—B2O3—SiO2 glasses, wherein La2O3, ZrO2, or NiO is optionally added to adjust the CTE of the glass to appropriate match the CTE of the substrate. In one example, the coating layer 25 comprises 30-40 mol % BaO, 5-15 mole % Al2O3; 10-25 mole % B2O3, 25-40 mole % SiO2; 0-10 mole % of La2O3; 0-10 mole % ZrO2; 0-10 mole % NiO with a molar ratio B2O3/SiO2 ranging from 0.25 to 0.75.
The protective coating layer 25 can accommodate small concentrations of other non-metallic elements such as nitrogen, oxygen and/or hydrogen without any deleterious effects on corrosion resistance or etch resistance. In one embodiment, the coating layer contains up to about 20 atomic percent (atom %) of hydrogen and/or oxygen. In another embodiment, the protective coating 25 comprises hydrogen and/or oxygen up to about 10 atom %.
The protective coating layer 25 is deposited onto the wafer processing apparatus by processes known in the art, including thermal/flame spray, plasma discharge spray, sputtering (particularly for glass-based compositions), expanding thermal plasma (ETP), ion plating, chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), metal organic chemical vapor deposition (MOCVD) (also called Organometallic Chemical Vapor Deposition (OMCVD)), metal organic vapor phase epitaxy (MOVPE), physical vapor deposition processes such as sputtering, reactive electron beam (e-beam) deposition, and plasma spray. Exemplary processes are thermal spray, ETP, CVD, and ion plating.
The thickness of the protective coating layer 25 varies depending upon the application and the process used, e.g., CVD, ion plating, ETP, etc, varying from 1 μm to a few hundred μm, depending on the application. Longer life cycles are generally expected when thicker protective layers are used.
Optimized Electrode Pattern Design: The electrode pattern design of heating elements in a wafer processing apparatus directly affects the performance of the heating unit, which is defined as ramp rate, operating temperature, and most importantly temperature uniformity. In one embodiment, the wafer processing apparatus electrode is designed for highly uniform heating and minimal localized non-uniform conditions, accommodating design variables such as tabs and through-holes, pin holes, support holes, etc. By uniform heating, it means the temperature variation of the surface area where the wafer would be placed is limited to <=5° C. for a heater having an operating temperature of >=600° C. in one embodiment, and in a second embodiment <=3° C. Temperature variation means the difference between a maximum temperature point and a minimum temperature point on the wafer surface area.
In a typical wafer processing apparatus, locally cold areas may occur on the heater surface, e.g., around contact areas, electrical connections, and through-holes, due to the lack of heat generated by the electrode. In one embodiment of the present invention, the electrode is designed to compensate for the heat loss by generating more heat near or around those areas, providing maximum temperature uniformity without the typical local hot spots due to over-compensation and electric current concentration at locations where large curvatures, or sharp corners, occur in the heating element patterns of the prior art. In another embodiment of the optimized design, the resistance of heating element closely matches the impedance of the power supply for higher efficiency, especially when higher operating temperature or higher electrical power is required.
In one embodiment to achieve required temperature uniformity, the electrode pattern is designed such that the power density generated by the electrode matches the heat loss defined by the heat transfer boundary conditions of the heater. An example of a typical heat transfer boundary condition is the additional edge heat loss of the heater. In the present invention, the heat loss is addressed by providing higher power density near the edge of the heater, taking into account heat losses by functional members of a heater including but not limited to, holes, tabs on the edge of the heater, contacts to the electrode, or inserts in the substrate to meet other functional requirements of the heater.
Besides the heat loss issue, the stress concentration sometimes becomes elevated in the areas adjacent to the functional members such as tabs, through-holes, etc., where the electrode pattern path widths change and with sharp turns for better uniform temperature. The stress concentration is also aggravated by locally higher temperature gradient in and around these areas. In one embodiment of the invention, the electrode pattern is optimized by increasing the radius of the upper corners of the electrode pattern in manufacturing processes, thus alleviating the stress concentration to avoid possible failures downstream in operation due to cracks and peeling in the overcoating layer 25.
Embodiments of the optimized electrode design of the invention are further illustrated as follows with references to the figures.
In the figures, the functional members in the form of contacts 4 and 5 and the through-holes 6 and 7 are circular in shape. However, they can be of any suitable geometry depending on their function, location, and the heater application. The shortest dimension of each of the functional member is defined as “X,” which is the diameter of the circular functional members or the width of the tabs as illustrated in the figures. A segment is meant a position on the electrode path.
In one embodiment, the ratio of F:C and E:D ranges from 0.40 to 0.75. In a second embodiment, the ratio of F:C or E:D is in the range of 0.50 to 0.65. With the optimized design of the invention, cold spots at the holes thus are eliminated through thermal conduction to the hole areas and thermal diffusion through the heater thickness.
The width of E or F used ratios herein refers to the width of any segment of E or F, which segment is meant any position of electrode path E or F that is within 2X from the edge of the hole in one embodiment, and within 1X in another embodiment.
In one embodiment where the lift hole 7 is located near the corner of the path bend, the ratio of the reduced width G over the normal-path width H ranges from 0.35 to 0.70. H is the width of the electrode path leading to the lift hole 7, at a distance of at least 3X from the edge of the lift hole 7. In a second embodiment, the ratio G:H ranges from 0.45 to 0.65.
In one embodiment wherein the pin hole 7 is more toward the center of the path bend, the ratio of the reduced width I over the normal width H ranges from 0.30 to 0.60. In a second embodiment, the ratio I:H ranges from 0.40 to 0.50.
The width of G or I used ratios herein refers to the width of any segment of G or I, which segment is meant any position of electrode path G or I that is within 2X from the edge of the hole in one embodiment, and within 1X from the edge of the hole in another embodiment.
In a typical heater, the parallel paths of the electrode are not symmetric or not identical to each other due to their electrical contact locations. In one embodiment of the heater with a parallel path design having balanced electrical resistance in the parallel paths, the electrical resistance of the electrode is optimized to match the impedance of a typical power supply for higher efficiency. Furthermore, the relatively balanced resistances (or equal resistance) of the two parallel paths by adjusting at least one location where two paths meet from opposite directions allows uniform temperature and heating of the wafer substrate.
In computer simulations, i.e., Finite Element Analysis (FEA) thermal modeling, of the top surface of ceramic heaters having the optimized electrode pattern on the backside, temperature variation of the surface area where the wafer would be placed is limited to <=2° C. for a heater having an operating temperature of 600° C.
This written description uses examples to disclose the invention, including the best mode, and also to enable any person skilled in the art to make and use the invention. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal languages of the claims.
All citations referred herein are expressly incorporated herein by reference.
This application claims the benefits of U.S. 60/806,620 filed Jul. 5, 2006, which patent application is fully incorporated herein by reference.
Number | Date | Country | |
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60806620 | Jul 2006 | US |