The invention relates to an electrodialysis device having
Electrodialysis devices are known in extremely diverse areas of application. They may be found, for example, in the field of lacquering technology, particularly in the field of cataphoretic dip lacquering, where electrodialysis devices are utilised for the purpose of adjusting the acid content of the lacquer liquid. In this connection several electrodialysis cells are generally employed, which for reasons of capacity are connected in parallel.
The manufacture of the known dialysis cells is relatively elaborate: the requisite membrane has had to be fixed in a container, in order to separate the two chambers of the dialysis cell from one another. Furthermore, the electrodes have had to be introduced in suitable form, and a uniform continuous flow both of the feed liquid, which after depletion leaves the dialysis cell as filtrate, and of the exchange liquid, which absorbs the ions extracted from the feed liquid, has had to be guaranteed. The parallel connection of the dialysis cells has been undertaken by external hoses, this being likewise elaborate and space-consuming.
The object of the present invention is to configure an electrodialysis device of the type specified in the introduction in such a way that the number of structural elements to be used is extensively reduced and a compact and space-saving design of the electrodialysis device can be achieved.
According to the invention, this object is achieved in that
As a result of the formation of the electrodialysis cells from substantially only two types of plate-like elements (plus the membranes), the number of structural parts differing from one another is considerably reduced. The overall structure is also clearly simplified by the direct chaining of the individual plate-like elements and also of the electrodialysis cells formed by said elements. The assembly of these electrodialysis cells and of the electrodialysis devices constructed from them becomes cost-effective overall. The electrodialysis device according to the invention can be produced in practically arbitrary capacities, by the appropriate number of individual electrodialysis cells being lined up one after the other.
It is preferred if the electrodialysis cells are terminated by a second plate-like element of the first type, one of the two plate-like elements forming a cathode, and the other plate-like element forming an anode. In this way, the electrodes of the individual electrodialysis cells delimit the chambers thereof on one side, without an additional wall being required.
This embodiment of the invention can be developed further in particularly advantageous manner to the effect that at least some of the electrodialysis cells are arranged in alternating manner in reverse sequence in such a way that the electrodes are assigned, in each instance, to two adjacent electrodialysis cells. With this manner of construction, in which the electrodes belong to two adjacent electrodialysis cells, a reduction in the structural parts required again arises; furthermore, an electrical insulation between adjacent electrodes of different electrodialysis cells becomes superfluous.
The stack of electrodialysis cells formed in this way may be delimited on both sides by terminating plates. These terminating plates protect the structural components situated further inside, for example the adjacent electrodes, and represent, where appropriate, an electrical insulation towards the outside.
On at least one terminating plate, ports for the supply of feed liquid and exchange liquid and also for the drainage of filtrate and of enriched exchange liquid may furthermore be formed. In this way, the electrodialysis device may be linked in simple manner to the external liquid circuits.
In particular, it is possible that one of the terminating plates has all the ports. Alternatively, it is also conceivable that one terminating plate has the ports for the supply of exchange liquid and the drainage of filtrate, and the other terminating plate has the ports for the supply of feed liquid and the drainage of enriched exchange liquid. By this means, a type of countercurrent principle is obtained in which the direction of flow of the exchange liquid is contrary to that of the feed liquid.
But one terminating plate may have the ports for the supply of feed liquid and exchange liquid, and the other terminating plate may have the ports for the drainage of filtrate and enriched exchange liquid. With this configuration, the directions of flow of feed liquid and exchange liquid through the electrodialysis device coincide.
The stack of electrodialysis cells is preferably held together with the aid of fastening elements connecting the two terminating plates to one another. In this case, a compressive stress on the elements situated between the terminating plates is generated, in particular via the fastening elements. By virtue of this measure, a good abutment of the individual plate-like elements against one another and a good effect of the intermediate seals is achieved.
The fastening elements preferably penetrate the plate-like elements in a region outside the chambers, for which purpose the plate-like elements have bores which are orientated in alignment with one another.
In one embodiment of the invention the plate-like elements of the first type, which accordingly form the electrodes, have laterally projecting current-connecting lugs. These current-connecting lugs serve for easy contacting of the electrodes. In particular in this context, the current-connecting lugs may each have bores which are penetrated by an electrical conductor, an electrical contact between the conductor and the plate-like element being established via the abutment of the conductor against the current-connecting lug in the region of the bore. The electrodes having the same polarity are preferably connected to one another via a common electrical conductor which, in particular, may take the form of a rod.
In order to make this possible in straightforward manner, the current-connecting lugs may be arranged eccentrically, and the plate-like elements of the first type—that is to say, the elements forming electrodes—that have different polarity may be arranged in mirror-symmetric manner with respect to one another. In this way, it is possible for the current-connecting lugs pertaining to the same polarity to be easily connected to one another by a rectilinear conductor. By way of electrodes of different polarity, it is possible for the same plate-like elements to be inserted, which need to be inserted only “on change-over”.
Particularly preferred is that embodiment of the invention in which the plate-like elements (including the membrane) have four through-bores which are orientated in alignment with one another in a region outside the chambers, whereby in the case of plate-like elements of the second type—that is to say, the spacing elements—two of the through-bores are connected via branch channels to the recess which is formed in the interior region and which constitutes the chamber. In this way, the through-bores, in alignment with one another, of the plate-like elements form flow channels which penetrate the electrodialysis device from one end to the other, without external connections, for example in the form of hoses, being necessary.
In this connection it is particularly advantageous if the through-bores are arranged symmetrically at least with respect to a plane of symmetry of the plate-like elements. In this way, these plate-like elements can also be incorporated “on change-over” into the entire electrodialysis device, reducing the number of different parts.
It is furthermore preferred that, in the case of the plate-like elements of the second type, the spacing elements, two such through-bores are connected to the recess via branch channels arranged in non-mirror-symmetric manner in relation to one another. By this means, it is ensured that the chambers that are laterally delimited by the spacing elements are flowed through substantially diagonally.
The plate-like elements of the second type, which are adjacent to a plate-like element of the first type forming an anode, are preferably arranged in mirror-symmetric manner with respect to a mirror plane in relation to the plate-like elements of the second type, which are adjacent to a plate-like element of the first type forming a cathode. By virtue of the mere manner of orientation of the plate-like elements of the second type within the entire stack, it is accordingly possible to determine whether the interior space surrounded by this plate-like element serves for continuous flow with feed liquid or for continuous flow with exchange liquid.
In this connection it is particularly preferred that, in each electrodialysis cell,
This embodiment of the invention combines in itself, in optimal manner, the advantages of the small number of different structural elements and the preferred diagonal flow through the individual chambers surrounded by the plate-like elements of the second type (spacing elements).
A seal should be arranged between plate-like elements of the first and second types arranged in immediately consecutive manner. This seal serves to prevent an escape of liquid from the interior of the chambers and also from the interior of the various channels formed by the aligned through-bores in the individual plate-like elements. Whether a seal also has to be arranged between the plate-like elements of the second type—that is to say, the spacing elements—and the membrane depends upon the type of membrane.
An exemplary embodiment of the invention will be elucidated in more detail in the following on the basis of the drawing; shown are:
a the top view of a terminating plate of the electrodialysis device of
b the side view of the terminating plate of
b the top view of a spacing element of the electrodialysis device of
The electrodialysis device 10 which is represented in
Each dialysis cell 16, 17 is delimited on both sides by a respective plate-like electrode 20a, 20b. These plate-like electrodes 20a, 20b are also called herein “plate-like elements of the first type”. The arrangement is such that adjacent interior electrodialysis cells 17, which accordingly are not immediately adjacent to a terminating plate 24, each share an electrode 20a, 20b. The dialysis cells 16, 17 comprise, in addition, two frame-like spacing elements 22a, 22b, between which an ion-specific membrane 34 is arranged. The spacing elements 22a, 22b are also called herein “plate-like elements of the second type”. Between the front ends of the spacing elements 22a, 22b facing away from the membrane 34 and the electrodes 20a, 20b adjacent to said spacing elements a seal 36 is inserted in each instance. A similar seal 36 is situated between the external electrodes 20a of the two external electrodialysis cells 16 and the terminating plates 24a, 24b adjacent thereto.
a shows the top view of the terminating plate 24a of the electrodialysis device 10 which is on the left in
Along the edges of the terminating plate 24a there are provided, in addition, several through-bores 28 of smaller diameter, which, as will likewise become clear, serve for connection of the various elements of the electrodialysis device 10 with the aid of screws.
The terminating plate 24b on the right in
a shows the top view of an electrode plate 20. The latter has the basic shape of a rectangle, with a likewise rectangular connecting lug 30 being attached onto the upper, narrow side of the rectangle. In alignment with the connecting sockets 26a to 26d of the terminating plate 24a, four through-bores 38a to 38d which are approximately rectangular in cross-section extend through the electrode plate 20. In addition, in the electrode plate 20 in
b shows the top view of a spacer 22. Said spacer has the form of a rectangular frame, the external dimensions of which correspond to the external dimensions of the base plates 24a and 24b and of the electrode plates 20 (with the exception of the connecting lugs 30). Once again, in alignment with the connecting sockets 26a to 26d and in alignment with the through-bores 38a to 38d of the electrode plate 20, four through-bores 38a to 38d are to be found. Whereas the through-bores 38a and 38d represented at the top left and bottom right in
In addition to the terminating plate 24a bearing the connecting sockets 26, a first electrode 20 is fitted, with interposition of a seal 36, specifically in such a way that the connecting lug 30 is vertically upright. This electrode 20a is connected, in a manner to be described later, as an anode. To the anode 20a a spacing element 22a is applied, with interposition of a seal 36, specifically in such an orientation that the through-bore 38c communicating with the inner recess of the spacing element 22a is connected to the connecting socket 26a, and the through-bore 38b which likewise communicates with the recess is connected to the connecting socket 26b of the terminating plate 24a. The recess of the spacing element 22a is accordingly flowed through diagonally by exchange liquid.
The spacing element 22a is followed by a membrane 34, and this is followed in turn by a second spacing element 22b. But the latter is now inserted in a manner that is a mirror image in relation to the installed position of the first spacing element 22a: care is taken to ensure that the through-bore 38b of the spacing element is connected to the connecting socket 26a serving for the drainage of the filtrate, and the through-bore 38c is connected to the connecting socket 26d of the terminating plate 24a serving for the supply of the feed liquid. The recess of the spacing element 22b is accordingly flowed through by feed liquid, which leaves the spacing element 22b as filtrate.
The second spacing element 22b is followed, with interposition of a further seal 36b, by a second electrode plate 20b. The latter is now arranged in such a way that its connecting lug 30b points downwards. As will be elucidated later, it is connected as a cathode.
With the cathode 30b the first dialysis cell 16 is complete. Now the second dialysis cell 17 is attached alongside, to the right in
The terminating plate 24b, which has no connecting sockets, is joined onto the final electrode 20a of the sequence of double cells 18, on the right in
All the connecting lugs 30a which project on one side from the stack of the structural elements and which pertain to anodes 20a are electrically connected to one another by a line (not represented) which is passed through the through-bore 32 of the connecting lugs 30 and is connected to the positive pole of a source of d.c. voltage.
Correspondingly, all the connecting lugs 30b projecting outwards on the opposite side and pertaining to the electrode plates 20b connected as cathodes are electrically connected to one another by a line which is not represented and which is passed through the through-bores 32 of these connecting lugs 30b and which is connected to the negative pole of the source of d.c. voltage.
The flow paths of the various liquids within the electrodialysis device 10 described above are represented schematically in
The exchange liquid flowing in via the connecting socket 26c arrives via the channel 48c in the interior spaces of all those spacing elements 22a which are adjacent to an electrode plate 20a connected as an anode. The interior spaces 14 of these spacing elements 22a are flowed through in the diagonal direction. After ion absorption has taken place, the exchange liquid enters the channel 48b and leaves the electrodialysis device 10 via the connecting socket 26b.
The feed liquid, on the other hand, is introduced into the channel 48d via the connecting socket 26d of the terminating plate 24a. It flows through the interior spaces 14 of all those spacing elements 22b which are adjacent to an electrode plate 20b connected as a cathode. The feed liquid which has been depleted of ions is then conducted out of the electrodialysis device 10 via the channel 48a and the connecting socket 26a.
As can be discerned from the above description, the capacity of the electrodialysis device 10 can be enlarged as desired by appropriately frequent chaining of few structural components. All the liquid-conducting flow paths are formed within the electrodialysis device 10 itself, without any hose connections or other couplings being required for this purpose.
Number | Date | Country | Kind |
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102 61 275.7 | Dec 2002 | DE | national |