The present disclosure relates generally to an electromagnetic device, particularly to an electromagnetically reflective structure for use in a dielectric resonator antenna (DRA) system, and more particularly to a monolithic electromagnetically reflective structure for use in a DRA system, which is well suited for microwave and millimeter wave applications.
While existing DRA resonators and arrays may be suitable for their intended purpose, the art of DRAs would be advanced with an electromagnetic device useful for building a high gain DRA system with high directionality in the far field that can overcome existing drawbacks, such as limited bandwidth, limited efficiency, limited gain, limited directionality, or complex fabrication techniques, for example.
An embodiment includes an electromagnetic device, having: an electromagnetically reflective structure comprising an electrically conductive structure and a plurality of electrically conductive electromagnetic reflectors that are integrally formed with or are in electrical communication with the electrically conductive structure; wherein the plurality of reflectors are disposed relative to each other in an ordered arrangement; and, wherein each reflector of the plurality of reflectors forms a wall that defines and at least partially circumscribes a recess having an electrically conductive base that forms part of or is in electrical communication with the electrically conductive structure.
The above features and advantages and other features and advantages of the invention are readily apparent from the following detailed description of the invention when taken in connection with the accompanying drawings.
Referring to the exemplary non-limiting drawings wherein like elements are numbered alike in the accompanying Figures:
Although the following detailed description contains many specifics for the purposes of illustration, anyone of ordinary skill in the art will appreciate that many variations and alterations to the following details are within the scope of the claims. Accordingly, the following example embodiments are set forth without any loss of generality to, and without imposing limitations upon, the claimed invention.
Embodiments disclosed herein include different arrangements for an electromagnetic (EM) device useful for building a high gain DRA system with high directionality in the far field. An embodiment of an EM device as disclosed herein includes one or more unitary EM reflective structures having an electrically conductive structure that may serve as an electrical ground structure, and one or more electrically conductive EM reflectors that are integrally formed with or are in electrical communication with the electrically conductive structure.
An embodiment of an EM device as disclosed herein includes one or more DRAs disposed within respective ones of the one or more electrically conductive EM reflectors to provide an EM device in the form of a high gain DRA system.
As used herein, the term unitary means a single arrangement of one or more constituents that are self-supporting with respect to each other, may be joined by any means suitable for a purpose disclosed herein, and may be separable with or without damaging the one or more constituents.
As used herein, the phrase one-piece structure means a single arrangement of one or more constituents that are self-supporting with respect to each other, having no constituent that can be completely separated from another of the one or more constituents during normal use, and having no constituent that can be completely separated from another of the one or more constituents without destroying or damaging some portion of any associated constituent.
As used herein, the phrase integrally formed means a structure formed with material common to the rest of the structure absent material discontinuities from one region of the structure to another, such as a structure produced from a plastic molding process, a 3D printing process, a deposition process, or a machined or forged metal-working process, for example. Alternatively, integrally formed means a unitary one-piece indivisible structure.
As used herein, the term monolithic means a structure integrally formed from a single material composition.
With reference now to
In an embodiment, the unitary electromagnetically reflective structure 102 is a monolithic structure formed from a single material composition absent macroscopic seams or joints. However, and as will be described further herein below, embodiments of the invention are not limited to such a monolithic structure.
While
In an embodiment, and with reference to
In an embodiment and with reference now to
In a 60 GHz application, the EM device 100 may have the following dimensions: a height 122 of the reflector wall 108 of about 1 millimeter (mm); an overall opening dimension 124 of the recess 110 of about 2.2 mm; a minimum wall thickness dimension 126 between adjacent reflectors 106 of about 0.2 mm; an aperture dimension 128 of the aperture 114 of about 0.2 mm; and, a thickness dimension 130 of the dielectric layer 118 of about 0.1 mm.
With reference now to
In an embodiment, an electrically conductive microstrip 116 is disposed on the second side 402.2 of the first non-metallic portion 402, where the microstrip 116 is disposed in signal communication with the aperture 114. In an embodiment, the aperture 114 is a slotted aperture having a lengthwise slot direction disposed orthogonal to the microstrip 116. In another embodiment, and alternative to the microstrip 116, a coaxial cable 120 may be disposed within the aperture 114, where here the aperture 114 would extend through the first non-metallic portion 402 for insertion of the coaxial cable 120 therein (similar to the depiction in
From the foregoing descriptions relating to
Reference is now made to
With reference still to
Each DRA 500 is operational at a defined frequency f with an associated operating wavelength λ, as measured in free space, and the plurality of reflectors 106 and associated DRAs 500 are arranged in an array with a center-to-center spacing (via the overall geometry of a given DRA array) between neighboring reflectors in accordance with any of the following arrangements: the reflectors 106 and associated DRAs 500 are spaced apart relative to each other with a spacing of equal to or less than λ; the reflectors 106 and associated DRAs 500 are spaced apart relative to each other with a spacing equal to or less than λ and equal to or greater than λ/2; or, the reflectors 106 and associated DRAs 500 are spaced apart relative to each other with a spacing equal to or less than λ/2. For example, at λ for a frequency equal to 10 GHz, the spacing from the center of one DRA to the center of a closet adjacent DRA is equal to or less than about 30 mm, or is between about 15 mm to about 30 mm, or is equal to or less than about 15 mm.
In an embodiment, the plurality of reflectors 106 are disposed relative to each other on a planar surface, such as the electrically conductive structure 104 depicted in
In an embodiment of a plurality of DRAs 500 and an EM device 100 as herein disclosed, the DRAs 500 may be singly fed, selectively fed, or multiply fed by one or more of the signal feeds, such as microstrip 116 (or stripline) or coaxial cable 120 for example. While only a microstrip 116 and a coaxial cable 120 have been depicted herein as being example signal feeds, in general, excitation of a given DRA 500 may be provided by any signal feed suitable for a purpose disclosed herein, such as a copper wire, a coaxial cable, a microstrip (e.g., with slotted aperture), a stripline (e.g., with slotted aperture), a waveguide, a surface integrated waveguide, a substrate integrated waveguide, or a conductive ink, for example, that is electromagnetically coupled to the respective DRA 500. As will be appreciated by one skilled in the art, the phrase electromagnetically coupled is a term of art that refers to an intentional transfer of electromagnetic energy from one location to another without necessarily involving physical contact between the two locations, and in reference to an embodiment disclosed herein more particularly refers to an interaction between a signal source having an electromagnetic resonant frequency that coincides with an electromagnetic resonant mode of the associated DRA. In those signal feeds that are directly embedded in a given DRA, the signal feed passes through the ground structure, in non-electrical contact with the ground structure, via an opening in the ground structure into a volume of dielectric material. As used herein, reference to dielectric materials other than non-gaseous dielectric materials includes air, which has a relative permittivity (εr) of approximately one at standard atmospheric pressure (1 atmosphere) and temperature (20 degree Celsius). As used herein, the term “relative permittivity” may be abbreviated to just “permittivity” or may be used interchangeably with the term “dielectric constant”. Regardless of the term used, one skilled in the art would readily appreciate the scope of the invention disclosed herein from a reading of the entire inventive disclosure provided herein.
While embodiments may be described herein as being transmitter antenna systems, it will be appreciated that the scope of the invention is not so limited and also encompasses receiver antenna systems.
In view of the foregoing, it will be appreciated that an embodiment of the EM device 100 disclosed herein, with or without DRAs 500, may be formed on a printed circuit board (PCB) type substrate or at the wafer-level (e.g., semiconductor wafer, such as a silicon-based wafer) of an electronic component. For a PCB, the EM device 100 may be formed using blind fabrication processes, or through-hole vias, to create the recesses 110. The EM device 100 may be disposed over other laminate layers with a microstrip feeding network 116 (or stripline feeding network) sandwiched therebetween, and RF chips and other electronic components may be mounted on backside of the laminate, with apertures 114 electromagnetically connecting to the microstrip feeds 116.
In an embodiment, the recesses 110 may be formed by mechanically drilling or laser drilling, and/or routing or milling, through-hole vias, of about 2 mm diameter for example, through a board or substrate such as the aforementioned second non-metallic portion 452 (see
Also depicted in
Reference is now made to
In method 600: first, the feed substrate is fabricated 602; second, the reflector structure is attached to the feed substrate 604; and lastly, dielectric components such as DRAs are provided onto the feed substrate 606, which may be accomplished via insert molding, 3D printing, pick-and-place, or any other fabrication means suitable for a purpose disclose herein.
Method 600 may be further described as, a method 600 of fabricating an electromagnetic device having an electromagnetically reflective structure comprising an electrically conductive structure and a plurality of electrically conductive electromagnetic reflectors that are integrally formed with or are in electrical communication with the electrically conductive structure, wherein the plurality of reflectors are disposed relative to each other in an ordered arrangement, wherein each reflector of the plurality of reflectors forms a wall that defines and at least partially circumscribes a recess having an electrically conductive base that forms part of or is in electrical communication with the electrically conductive structure, the method comprising: providing the electromagnetically reflective structure and inserting it into a mold; and, molding one or more dielectric resonator antennas, DRAs, onto the electromagnetically reflective structure, and allowing the DRAs to at least partially cure; wherein the one or more DRAs are disposed in one-to-one relationship with a respective one of the recess.
In method 650: first, the feed substrate is fabricated 652; second, dielectric components such as DRAs are provided onto the feed substrate 654, which may be accomplished via insert molding, 3D printing, pick-and-place, or any other fabrication means suitable for a purpose disclose herein; and lastly, the reflector structure is attached to the feed substrate 656.
Method 650 may be further described as, a method 650 of fabricating an electromagnetic device having an electromagnetically reflective structure comprising an electrically conductive structure and a plurality of electrically conductive electromagnetic reflectors that are integrally formed with or are in electrical communication with the electrically conductive structure, wherein the plurality of reflectors are disposed relative to each other in an ordered arrangement, wherein each reflector of the plurality of reflectors forms a wall that defines and at least partially circumscribes a recess having an electrically conductive base that forms part of or is in electrical communication with the electrically conductive structure, the method comprising: providing a feed structure comprising the electrically conductive structure and inserting the feed structure into a mold; molding one or more dielectric resonator antennas, DRAs, onto the feed structure, and allowing the DRAs to at least partially cure to provide a DRA subcomponent; and, providing a reflector structure comprising the plurality of electrically conductive electromagnetic reflectors and attaching the reflector structure to the DRA subcomponent such that the plurality of electrically conductive electromagnetic reflectors are integrally formed with or are in electrical communication with the electrically conductive structure; wherein the one or more DRAs are disposed in one-to-one relationship with a respective one of the recess.
In either method 600 or method 650, the feed substrate may be a board (e.g., PCB), a wafer (e.g., silicon wafer, or other semiconductor-based wafer), or the first arrangement 400 depicted in either
Reference is now made to
Reference is now made to
With reference now to
While various embodiments of DRAs 500 have been described and illustrated herein above, it will be appreciated that the scope of the invention is not limited to DRAs 500 having only those three-dimensional shapes described and illustrated thus far, but encompasses any 3-D shaped DRA suitable for a purpose disclosed herein, which includes hemi-spherical shaped DRAs 512, cylindrical shaped DRAs 514, and rectangular shaped DRAs 516, as depicted in
The dielectric materials for use herein are selected to provide the desired electrical and mechanical properties for a purpose disclosed herein. The dielectric materials generally comprise a thermoplastic or thermosetting polymer matrix and a filler composition containing a dielectric filler. The dielectric volume can comprise, based on the volume of the dielectric volume, 30 to 100 volume percent (vol %) of a polymer matrix, and 0 to 70 vol % of a filler composition, specifically 30 to 99 vol % of a polymer matrix and 1 to 70 vol % of a filler composition, more specifically 50 to 95 vol % of a polymeric matrix and 5 to 50 vol % of a filler composition. The polymer matrix and the filler are selected to provide a dielectric volume having a dielectric constant consistent for a purpose disclosed herein and a dissipation factor of less than 0.006, specifically, less than or equal to 0.0035 at 10 GigaHertz (GHz). The dissipation factor can be measured by the IPC-TM-650 X-band strip line method or by the Split Resonator method.
The dielectric volume comprises a low polarity, low dielectric constant, and low loss polymer. The polymer can comprise 1,2-polybutadiene (PBD), polyisoprene, polybutadiene-polyisoprene copolymers, polyetherimide (PEI), fluoropolymers such as polytetrafluoroethylene (PTFE), polyimide, polyetheretherketone (PEEK), polyamidimide, polyethylene terephthalate (PET), polyethylene naphthalate, polycyclohexylene terephthalate, polyphenylene ethers, those based on allylated polyphenylene ethers, or a combination comprising at least one of the foregoing. Combinations of low polarity polymers with higher polarity polymers can also be used, non-limiting examples including epoxy and poly(phenylene ether), epoxy and poly(etherimide), cyanate ester and poly(phenylene ether), and 1,2-polybutadiene and polyethylene.
Fluoropolymers include fluorinated homopolymers, e.g., PTFE and polychlorotrifluoroethylene (PCTFE), and fluorinated copolymers, e.g. copolymers of tetrafluoroethylene or chlorotrifluoroethylene with a monomer such as hexafluoropropylene or perfluoroalkylvinylethers, vinylidene fluoride, vinyl fluoride, ethylene, or a combination comprising at least one of the foregoing. The fluoropolymer can comprise a combination of different at least one these fluoropolymers.
The polymer matrix can comprise thermosetting polybutadiene or polyisoprene. As used herein, the term “thermosetting polybutadiene or polyisoprene” includes homopolymers and copolymers comprising units derived from butadiene, isoprene, or combinations thereof. Units derived from other copolymerizable monomers can also be present in the polymer, for example, in the form of grafts. Exemplary copolymerizable monomers include, but are not limited to, vinylaromatic monomers, for example substituted and unsubstituted monovinylaromatic monomers such as styrene, 3-methylstyrene, 3,5-diethylstyrene, 4-n-propylstyrene, alpha-methylstyrene, alpha-methyl vinyltoluene, para-hydroxystyrene, para-methoxystyrene, alpha-chlorostyrene, alpha-bromostyrene, dichlorostyrene, dibromostyrene, tetra-chlorostyrene, and the like; and substituted and unsubstituted divinylaromatic monomers such as divinylbenzene, divinyltoluene, and the like. Combinations comprising at least one of the foregoing copolymerizable monomers can also be used. Exemplary thermosetting polybutadiene or polyisoprenes include, but are not limited to, butadiene homopolymers, isoprene homopolymers, butadiene-vinylaromatic copolymers such as butadiene-styrene, isoprene-vinylaromatic copolymers such as isoprene-styrene copolymers, and the like.
The thermosetting polybutadiene or polyisoprenes can also be modified. For example, the polymers can be hydroxyl-terminated, methacrylate-terminated, carboxylate-terminated, or the like. Post-reacted polymers can be used, such as epoxy-, maleic anhydride-, or urethane-modified polymers of butadiene or isoprene polymers. The polymers can also be crosslinked, for example by divinylaromatic compounds such as divinyl benzene, e.g., a polybutadiene-styrene crosslinked with divinyl benzene. Exemplary materials are broadly classified as “polybutadienes” by their manufacturers, for example, Nippon Soda Co., Tokyo, Japan, and Cray Valley Hydrocarbon Specialty Chemicals, Exton, PA Combinations can also be used, for example, a combination of a polybutadiene homopolymer and a poly(butadiene-isoprene) copolymer. Combinations comprising a syndiotactic polybutadiene can also be useful.
The thermosetting polybutadiene or polyisoprene can be liquid or solid at room temperature. The liquid polymer can have a number average molecular weight (Mn) of greater than or equal to 5,000 g/mol. The liquid polymer can have an Mn of less than 5,000 g/mol, specifically, 1,000 to 3,000 g/mol. Thermosetting polybutadiene or polyisoprenes having at least 90 wt % 1,2 addition, which can exhibit greater crosslink density upon cure due to the large number of pendent vinyl groups available for crosslinking.
The polybutadiene or polyisoprene can be present in the polymer composition in an amount of up to 100 wt %, specifically, up to 75 wt % with respect to the total polymer matrix composition, more specifically, 10 to 70 wt %, even more specifically, 20 to 60 or 70 wt %, based on the total polymer matrix composition.
Other polymers that can co-cure with the thermosetting polybutadiene or polyisoprenes can be added for specific property or processing modifications. For example, in order to improve the stability of the dielectric strength and mechanical properties of the dielectric material over time, a lower molecular weight ethylene-propylene elastomer can be used in the systems. An ethylene-propylene elastomer as used herein is a copolymer, terpolymer, or other polymer comprising primarily ethylene and propylene. Ethylene-propylene elastomers can be further classified as EPM copolymers (i.e., copolymers of ethylene and propylene monomers) or EPDM terpolymers (i.e., terpolymers of ethylene, propylene, and diene monomers). Ethylene-propylene-diene terpolymer rubbers, in particular, have saturated main chains, with unsaturation available off the main chain for facile cross-linking. Liquid ethylene-propylene-diene terpolymer rubbers, in which the diene is dicyclopentadiene, can be used.
The molecular weights of the ethylene-propylene rubbers can be less than 10,000 g/mol viscosity average molecular weight (Mv). The ethylene-propylene rubber can include an ethylene-propylene rubber having an Mv of 7,200 g/mol, which is available from Lion Copolymer, Baton Rouge, LA, under the trade name TRILENE™ CP80; a liquid ethylene-propylene-dicyclopentadiene terpolymer rubbers having an Mv of 7,000 g/mol, which is available from Lion Copolymer under the trade name of TRILENE™ 65; and a liquid ethylene-propylene-ethylidene norbornene terpolymer having an Mv of 7,500 g/mol, which is available from Lion Copolymer under the name TRILENE™ 67.
The ethylene-propylene rubber can be present in an amount effective to maintain the stability of the properties of the dielectric material over time, in particular the dielectric strength and mechanical properties. Typically, such amounts are up to 20 wt % with respect to the total weight of the polymer matrix composition, specifically, 4 to 20 wt %, more specifically, 6 to 12 wt %.
Another type of co-curable polymer is an unsaturated polybutadiene- or polyisoprene-containing elastomer. This component can be a random or block copolymer of primarily 1,3-addition butadiene or isoprene with an ethylenically unsaturated monomer, for example, a vinylaromatic compound such as styrene or alpha-methyl styrene, an acrylate or methacrylate such a methyl methacrylate, or acrylonitrile. The elastomer can be a solid, thermoplastic elastomer comprising a linear or graft-type block copolymer having a polybutadiene or polyisoprene block and a thermoplastic block that can be derived from a monovinylaromatic monomer such as styrene or alpha-methyl styrene. Block copolymers of this type include styrene-butadiene-styrene triblock copolymers, for example, those available from Dexco Polymers, Houston, TX under the trade name VECTOR 8508M™, from Enichem Elastomers America, Houston, TX under the trade name SOL-T-6302™, and those from Dynasol Elastomers under the trade name CALPRENE™ 401; and styrene-butadiene diblock copolymers and mixed triblock and diblock copolymers containing styrene and butadiene, for example, those available from Kraton Polymers (Houston, TX) under the trade name KRATON D1118. KRATON D1118 is a mixed diblock/triblock styrene and butadiene containing copolymer that contains 33 wt % styrene.
The optional polybutadiene- or polyisoprene-containing elastomer can further comprise a second block copolymer similar to that described above, except that the polybutadiene or polyisoprene block is hydrogenated, thereby forming a polyethylene block (in the case of polybutadiene) or an ethylene-propylene copolymer block (in the case of polyisoprene). When used in conjunction with the above-described copolymer, materials with greater toughness can be produced. An exemplary second block copolymer of this type is KRATON GX1855 (commercially available from Kraton Polymers, which is believed to be a combination of a styrene-high 1,2-butadiene-styrene block copolymer and a styrene-(ethylene-propylene)-styrene block copolymer.
The unsaturated polybutadiene- or polyisoprene-containing elastomer component can be present in the polymer matrix composition in an amount of 2 to 60 wt % with respect to the total weight of the polymer matrix composition, specifically, 5 to 50 wt %, more specifically, 10 to 40 or 50 wt %.
Still other co-curable polymers that can be added for specific property or processing modifications include, but are not limited to, homopolymers or copolymers of ethylene such as polyethylene and ethylene oxide copolymers; natural rubber; norbornene polymers such as polydicyclopentadiene; hydrogenated styrene-isoprene-styrene copolymers and butadiene-acrylonitrile copolymers; unsaturated polyesters; and the like. Levels of these copolymers are generally less than 50 wt % of the total polymer in the polymer matrix composition.
Free radical-curable monomers can also be added for specific property or processing modifications, for example to increase the crosslink density of the system after cure. Exemplary monomers that can be suitable crosslinking agents include, for example, di, tri-, or higher ethylenically unsaturated monomers such as divinyl benzene, triallyl cyanurate, diallyl phthalate, and multifunctional acrylate monomers (e.g., SARTOMER™ polymers available from Sartomer USA, Newtown Square, PA), or combinations thereof, all of which are commercially available. The crosslinking agent, when used, can be present in the polymer matrix composition in an amount of up to 20 wt %, specifically, 1 to 15 wt %, based on the total weight of the total polymer in the polymer matrix composition.
A curing agent can be added to the polymer matrix composition to accelerate the curing reaction of polyenes having olefinic reactive sites. Curing agents can comprise organic peroxides, for example, dicumyl peroxide, t-butyl perbenzoate, 2,5-dimethyl-2,5-di(t-butyl peroxy)hexane, α,α-di-bis(t-butyl peroxy)diisopropylbenzene, 2,5-dimethyl-2,5-di(t-butyl peroxy) hexyne-3, or a combination comprising at least one of the foregoing. Carbon-carbon initiators, for example, 2,3-dimethyl-2,3 diphenylbutane can be used. Curing agents or initiators can be used alone or in combination. The amount of curing agent can be 1.5 to 10 wt % based on the total weight of the polymer in the polymer matrix composition.
In some embodiments, the polybutadiene or polyisoprene polymer is carboxy-functionalized. Functionalization can be accomplished using a polyfunctional compound having in the molecule both (i) a carbon-carbon double bond or a carbon-carbon triple bond, and (ii) at least one of a carboxy group, including a carboxylic acid, anhydride, amide, ester, or acid halide. A specific carboxy group is a carboxylic acid or ester. Examples of polyfunctional compounds that can provide a carboxylic acid functional group include maleic acid, maleic anhydride, fumaric acid, and citric acid. In particular, polybutadienes adducted with maleic anhydride can be used in the thermosetting composition. Suitable maleinized polybutadiene polymers are commercially available, for example from Cray Valley under the trade names RICON 130MA8, RICON 130MA13, RICON 130MA20, RICON 131MA5, RICON 131MA10, RICON 131MA17, RICON 131MA20, and RICON 156MA17. Suitable maleinized polybutadiene-styrene copolymers are commercially available, for example, from Sartomer under the trade names RICON 184MA6. RICON 184MA6 is a butadiene-styrene copolymer adducted with maleic anhydride having styrene content of 17 to 27 wt % and Mn of 9,900 g/mol.
The relative amounts of the various polymers in the polymer matrix composition, for example, the polybutadiene or polyisoprene polymer and other polymers, can depend on the particular conductive metal ground plate layer used, the desired properties of the circuit materials, and like considerations. For example, use of a poly(arylene ether) can provide increased bond strength to a conductive metal component, for example, a copper or aluminum component such as a signal feed, ground, or reflector component. Use of a polybutadiene or polyisoprene polymer can increase high temperature resistance of the composites, for example, when these polymers are carboxy-functionalized. Use of an elastomeric block copolymer can function to compatibilize the components of the polymer matrix material. Determination of the appropriate quantities of each component can be done without undue experimentation, depending on the desired properties for a particular application.
The dielectric volume can further include a particulate dielectric filler selected to adjust the dielectric constant, dissipation factor, coefficient of thermal expansion, and other properties of the dielectric volume. The dielectric filler can comprise, for example, titanium dioxide (rutile and anatase), barium titanate, strontium titanate, silica (including fused amorphous silica), corundum, wollastonite, Ba2Ti9O20, solid glass spheres, synthetic glass or ceramic hollow spheres, quartz, boron nitride, aluminum nitride, silicon carbide, beryllia, alumina, alumina trihydrate, magnesia, mica, talcs, nanoclays, magnesium hydroxide, or a combination comprising at least one of the foregoing. A single secondary filler, or a combination of secondary fillers, can be used to provide a desired balance of properties.
Optionally, the fillers can be surface treated with a silicon-containing coating, for example, an organofunctional alkoxy silane coupling agent. A zirconate or titanate coupling agent can be used. Such coupling agents can improve the dispersion of the filler in the polymeric matrix and reduce water absorption of the finished DRA. The filler component can comprise 5 to 50 vol % of the microspheres and 70 to 30 vol % of fused amorphous silica as secondary filler based on the weight of the filler.
The dielectric volume can also optionally contain a flame retardant useful for making the volume resistant to flame. These flame retardant can be halogenated or unhalogenated. The flame retardant can be present in in the dielectric volume in an amount of 0 to 30 vol % based on the volume of the dielectric volume.
In an embodiment, the flame retardant is inorganic and is present in the form of particles. An exemplary inorganic flame retardant is a metal hydrate, having, for example, a volume average particle diameter of 1 nm to 500 nm, preferably 1 to 200 nm, or 5 to 200 nm, or 10 to 200 nm; alternatively the volume average particle diameter is 500 nm to 15 micrometer, for example 1 to 5 micrometer. The metal hydrate is a hydrate of a metal such as Mg, Ca, Al, Fe, Zn, Ba, Cu, Ni, or a combination comprising at least one of the foregoing. Hydrates of Mg, Al, or Ca are particularly preferred, for example aluminum hydroxide, magnesium hydroxide, calcium hydroxide, iron hydroxide, zinc hydroxide, copper hydroxide and nickel hydroxide; and hydrates of calcium aluminate, gypsum dihydrate, zinc borate and barium metaborate. Composites of these hydrates can be used, for example a hydrate containing Mg and one or more of Ca, Al, Fe, Zn, Ba, Cu and Ni. A preferred composite metal hydrate has the formula MgMx·(OH)y wherein M is Ca, Al, Fe, Zn, Ba, Cu, or Ni, x is 0.1 to 10, and y is from 2 to 32. The flame retardant particles can be coated or otherwise treated to improve dispersion and other properties.
Organic flame retardants can be used, alternatively or in addition to the inorganic flame retardants. Examples of inorganic flame retardants include melamine cyanurate, fine particle size melamine polyphosphate, various other phosphorus-containing compounds such as aromatic phosphinates, diphosphinates, phosphonates, and phosphates, certain polysilsesquioxanes, siloxanes, and halogenated compounds such as hexachloroendomethylenetetrahydrophthalic acid (HET acid), tetrabromophthalic acid and dibromoneopentyl glycol A flame retardant (such as a bromine-containing flame retardant) can be present in an amount of 20 phr (parts per hundred parts of resin) to 60 phr, specifically, 30 to 45 phr. Examples of brominated flame retardants include Saytex BT93W (ethylene bistetrabromophthalimide), Saytex 120 (tetradecabromodiphenoxy benzene), and Saytex 102 (decabromodiphenyl oxide). The flame retardant can be used in combination with a synergist, for example a halogenated flame retardant can be used in combination with a synergists such as antimony trioxide, and a phosphorus-containing flame retardant can be used in combination with a nitrogen-containing compound such as melamine.
The volume of dielectric material may be formed from a dielectric composition comprising the polymer matrix composition and the filler composition. The volume can be formed by casting a dielectric composition directly onto the ground structure layer, or a dielectric volume can be produced that can be deposited onto the ground structure layer. The method to produce the dielectric volume can be based on the polymer selected. For example, where the polymer comprises a fluoropolymer such as PTFE, the polymer can be mixed with a first carrier liquid. The combination can comprise a dispersion of polymeric particles in the first carrier liquid, e.g., an emulsion of liquid droplets of the polymer or of a monomeric or oligomeric precursor of the polymer in the first carrier liquid, or a solution of the polymer in the first carrier liquid. If the polymer is liquid, then no first carrier liquid may be necessary.
The choice of the first carrier liquid, if present, can be based on the particular polymeric and the form in which the polymeric is to be introduced to the dielectric volume. If it is desired to introduce the polymeric as a solution, a solvent for the particular polymer is chosen as the carrier liquid, e.g., N-methyl pyrrolidone (NMP) would be a suitable carrier liquid for a solution of a polyimide. If it is desired to introduce the polymer as a dispersion, then the carrier liquid can comprise a liquid in which the is not soluble, e.g., water would be a suitable carrier liquid for a dispersion of PTFE particles and would be a suitable carrier liquid for an emulsion of polyamic acid or an emulsion of butadiene monomer.
The dielectric filler component can optionally be dispersed in a second carrier liquid, or mixed with the first carrier liquid (or liquid polymer where no first carrier is used). The second carrier liquid can be the same liquid or can be a liquid other than the first carrier liquid that is miscible with the first carrier liquid. For example, if the first carrier liquid is water, the second carrier liquid can comprise water or an alcohol. The second carrier liquid can comprise water.
The filler dispersion can comprise a surfactant in an amount effective to modify the surface tension of the second carrier liquid to enable the second carrier liquid to wet the borosilicate microspheres. Exemplary surfactant compounds include ionic surfactants and nonionic surfactants. TRITON X-100™, has been found to be an exemplary surfactant for use in aqueous filler dispersions. The filler dispersion can comprise 10 to 70 vol % of filler and 0.1 to 10 vol % of surfactant, with the remainder comprising the second carrier liquid.
The combination of the polymer and first carrier liquid and the filler dispersion in the second carrier liquid can be combined to form a casting mixture. In an embodiment, the casting mixture comprises 10 to 60 vol % of the combined polymer and filler and 40 to 90 vol % combined first and second carrier liquids. The relative amounts of the polymer and the filler component in the casting mixture can be selected to provide the desired amounts in the final composition as described below.
The viscosity of the casting mixture can be adjusted by the addition of a viscosity modifier, selected on the basis of its compatibility in a particular carrier liquid or combination of carrier liquids, to retard separation, i.e. sedimentation or flotation, of the hollow sphere filler from the dielectric composite material and to provide a dielectric composite material having a viscosity compatible with conventional manufacturing equipment. Exemplary viscosity modifiers suitable for use in aqueous casting mixtures include, e.g., polyacrylic acid compounds, vegetable gums, and cellulose based compounds. Specific examples of suitable viscosity modifiers include polyacrylic acid, methyl cellulose, polyethyleneoxide, guar gum, locust bean gum, sodium carboxymethylcellulose, sodium alginate, and gum tragacanth. The viscosity of the viscosity-adjusted casting mixture can be further increased, i.e., beyond the minimum viscosity, on an application by application basis to adapt the dielectric composite material to the selected manufacturing technique. In an embodiment, the viscosity-adjusted casting mixture can exhibit a viscosity of 10 to 100,000 centipoise (cp); specifically, 100 cp and 10,000 cp measured at room temperature value.
Alternatively, the viscosity modifier can be omitted if the viscosity of the carrier liquid is sufficient to provide a casting mixture that does not separate during the time period of interest. Specifically, in the case of extremely small particles, e.g., particles having an equivalent spherical diameter less than 0.1 micrometers, the use of a viscosity modifier may not be necessary.
A layer of the viscosity-adjusted casting mixture can be cast onto the ground structure layer, or can be dip-coated and then shaped. The casting can be achieved by, for example, dip coating, flow coating, reverse roll coating, knife-over-roll, knife-over-plate, metering rod coating, and the like.
The carrier liquid and processing aids, i.e., the surfactant and viscosity modifier, can be removed from the cast volume, for example, by evaporation or by thermal decomposition in order to consolidate a dielectric volume of the polymer and the filler comprising the microspheres.
The volume of the polymeric matrix material and filler component can be further heated to modify the physical properties of the volume, e.g., to sinter a thermoplastic or to cure or post cure a thermosetting composition.
In another method, a PTFE composite dielectric volume can be made by a paste extrusion and calendaring process.
In still another embodiment, the dielectric volume can be cast and then partially cured (“B-staged”). Such B-staged volumes can be stored and used subsequently.
An adhesion layer can be disposed between the conductive ground layer and the dielectric volume. The adhesion layer can comprise a poly(arylene ether); and a carboxy-functionalized polybutadiene or polyisoprene polymer comprising butadiene, isoprene, or butadiene and isoprene units, and zero to less than or equal to 50 wt % of co-curable monomer units; wherein the composition of the adhesive layer is not the same as the composition of the dielectric volume. The adhesive layer can be present in an amount of 2 to 15 grams per square meter. The poly(arylene ether) can comprise a carboxy-functionalized poly(arylene ether). The poly(arylene ether) can be the reaction product of a poly(arylene ether) and a cyclic anhydride or the reaction product of a poly(arylene ether) and maleic anhydride. The carboxy-functionalized polybutadiene or polyisoprene polymer can be a carboxy-functionalized butadiene-styrene copolymer. The carboxy-functionalized polybutadiene or polyisoprene polymer can be the reaction product of a polybutadiene or polyisoprene polymer and a cyclic anhydride. The carboxy-functionalized polybutadiene or polyisoprene polymer can be a maleinized polybutadiene-styrene or maleinized polyisoprene-styrene copolymer.
In an embodiment, a multiple-step process suitable for thermosetting materials such as polybutadiene or polyisoprene can comprise a peroxide cure step at temperatures of 150 to 200° C., and the partially cured (B-staged) stack can then be subjected to a high-energy electron beam irradiation cure (E-beam cure) or a high temperature cure step under an inert atmosphere. Use of a two-stage cure can impart an unusually high degree of cross-linking to the resulting composite. The temperature used in the second stage can be 250 to 300° C., or the decomposition temperature of the polymer. This high temperature cure can be carried out in an oven but can also be performed in a press, namely as a continuation of the initial fabrication and cure step. Particular fabrication temperatures and pressures will depend upon the particular adhesive composition and the dielectric composition, and are readily ascertainable by one of ordinary skill in the art without undue experimentation.
Molding allows rapid and efficient manufacture of the dielectric volume, optionally together with another DRA component(s) as an embedded feature or a surface feature. For example, a metal, ceramic, or other insert can be placed in the mold to provide a component of the DRA, such as a signal feed, ground component, or reflector component as embedded or surface feature. Alternatively, an embedded feature can be 3D printed or inkjet printed onto a volume, followed by further molding; or a surface feature can be 3D printed or inkjet printed onto an outermost surface of the DRA. It is also possible to mold the volume directly onto the ground structure, or into a container comprising a material having a dielectric constant between 1 and 3.
The mold can have a mold insert comprising a molded or machined ceramic to provide the package or volume. Use of a ceramic insert can lead to lower loss resulting in higher efficiency; reduced cost due to low direct material cost for molded alumina; ease of manufactured and controlled (constrained) thermal expansion of the polymer. It can also provide a balanced coefficient of thermal expansion (CTE) such that the overall structure matches the CTE of copper or aluminum.
The injectable composition can be prepared by first combining the ceramic filler and the silane to form a filler composition and then mixing the filler composition with the thermoplastic polymer or thermosetting composition. For a thermoplastic polymer, the polymer can be melted prior to, after, or during the mixing with one or both of the ceramic filler and the silane. The injectable composition can then be injection molded in a mold. The melt temperature, the injection temperature, and the mold temperature used depend on the melt and glass transition temperature of the thermoplastic polymer, and can be, for example, 150 to 350° C., or 200 to 300° C. The molding can occur at a pressure of 65 to 350 kiloPascal (kPa).
In some embodiments, the dielectric volume can be prepared by reaction injection molding a thermosetting composition. The reaction injection molding can comprise mixing at least two streams to form a thermosetting composition, and injecting the thermosetting composition into the mold, wherein a first stream comprises the catalyst and the second stream optionally comprises an activating agent. One or both of the first stream and the second stream or a third stream can comprise a monomer or a curable composition. One or both of the first stream and the second stream or a third stream can comprise one or both of a dielectric filler and an additive. One or both of the dielectric filler and the additive can be added to the mold prior to injecting the thermosetting composition.
For example, a method of preparing the volume can comprise mixing a first stream comprising the catalyst and a first monomer or curable composition and a second stream comprising the optional activating agent and a second monomer or curable composition. The first and second monomer or curable composition can be the same or different. One or both of the first stream and the second stream can comprise the dielectric filler. The dielectric filler can be added as a third stream, for example, further comprising a third monomer. The dielectric filler can be in the mold prior to injection of the first and second streams. The introducing of one or more of the streams can occur under an inert gas, for example, nitrogen or argon.
The mixing can occur in a head space of an injection molding machine, or in an inline mixer, or during injecting into the mold. The mixing can occur at a temperature of greater than or equal to 0 to 200 degrees Celsius (° C.), specifically, 15 to 130° C., or 0 to 45° C., more specifically, 23 to 45° C.
The mold can be maintained at a temperature of greater than or equal to 0 to 250° C., specifically, 23 to 200° C. or 45 to 250° C., more specifically, 30 to 130° C. or 50 to 70° C. It can take 0.25 to 0.5 minutes to fill a mold, during which time, the mold temperature can drop. After the mold is filled, the temperature of the thermosetting composition can increase, for example, from a first temperature of 0° to 45° C. to a second temperature of 45 to 250° C. The molding can occur at a pressure of 65 to 350 kiloPascal (kPa). The molding can occur for less than or equal to 5 minutes, specifically, less than or equal to 2 minutes, more specifically, 2 to 30 seconds. After the polymerization is complete, the substrate can be removed at the mold temperature or at a decreased mold temperature. For example, the release temperature, Tr, can be less than or equal to 10° C. less than the molding temperature, Tm (Tr≤Tm−10° C.).
After the volume is removed from the mold, it can be post-cured. Post-curing can occur at a temperature of 100 to 150° C., specifically, 140 to 200° C. for greater than or equal to 5 minutes.
Compression molding can be used with either thermoplastic or thermosetting materials. Conditions for compression molding a thermoplastic material, such as mold temperature, depend on the melt and glass transition temperature of the thermoplastic polymer, and can be, for example, 150 to 350° C., or 200 to 300° C. The molding can occur at a pressure of 65 to 350 kiloPascal (kPa). The molding can occur for less than or equal to 5 minutes, specifically, less than or equal to 2 minutes, more specifically, 2 to 30 seconds. A thermosetting material can be compression molded before B-staging to produce a B-stated material or a fully cured material; or it can be compression molded after it has been B-staged, and fully cured in the mold or after molding.
3D printing allows rapid and efficient manufacture of the dielectric volume, optionally together with another DRA component(s) as an embedded feature or a surface feature. For example, a metal, ceramic, or other insert can be placed during printing provide a component of the DRA, such as a signal feed, ground component, or reflector component as embedded or surface feature. Alternatively, an embedded feature can be 3D printed or inkjet printed onto a volume, followed by further printing; or a surface feature can be 3D printed or inkjet printed onto an outermost surface of the DRA. It is also possible to 3D print the volume directly onto the ground structure, or into the container comprising a material having a dielectric constant between 1 and 3, where the container may be useful for embedding a unit cells of an array.
A wide variety of 3D printing methods can be used, for example fused deposition modeling (FDM), selective laser sintering (SLS), selective laser melting (SLM), electronic beam melting (EBM), Big Area Additive Manufacturing (BAAM), ARBURG plastic free forming technology, laminated object manufacturing (LOM), pumped deposition (also known as controlled paste extrusion, as described, for example, at: http://nscrypt.com/micro-dispensing), or other 3D printing methods. 3D printing can be used in the manufacture of prototypes or as a production process. In some embodiments the volume or the DRA is manufactured only by 3D or inkjet printing, such that the method of forming the dielectric volume or the DRA is free of an extrusion, molding, or lamination process.
Material extrusion techniques are particularly useful with thermoplastics, and can be used to provide intricate features. Material extrusion techniques include techniques such as FDM, pumped deposition, and fused filament fabrication, as well as others as described in ASTM F2792-12a. In fused material extrusion techniques, an article can be produced by heating a thermoplastic material to a flowable state that can be deposited to form a layer. The layer can have a predetermined shape in the x-y axis and a predetermined thickness in the z-axis. The flowable material can be deposited as roads as described above, or through a die to provide a specific profile. The layer cools and solidifies as it is deposited. A subsequent layer of melted thermoplastic material fuses to the previously deposited layer, and solidifies upon a drop in temperature. Extrusion of multiple subsequent layers builds the desired shape of the volume. In particular, an article can be formed from a three-dimensional digital representation of the article by depositing the flowable material as one or more roads on a substrate in an x-y plane to form the layer. The position of the dispenser (e.g., a nozzle) relative to the substrate is then incremented along a z-axis (perpendicular to the x-y plane), and the process is then repeated to form an article from the digital representation. The dispensed material is thus also referred to as a “modeling material” as well as a “build material.”
In some embodiments the volume may be extruded from two or more nozzles, each extruding the same dielectric composition. If multiple nozzles are used, the method can produce the product objects faster than methods that use a single nozzle, and can allow increased flexibility in terms of using different polymers or blends of polymers, different colors, or textures, and the like. Accordingly, in an embodiment, a composition or property of a single volume can be varied during deposition using two nozzles.
Material extrusion techniques can further be used of the deposition of thermosetting compositions. For example, at least two streams can be mixed and deposited to form the volume. A first stream can include catalyst and a second stream can optionally comprise an activating agent. One or both of the first stream and the second stream or a third stream can comprise the monomer or curable composition (e.g., resin). One or both of the first stream and the second stream or a third stream can comprise one or both of a dielectric filler and an additive. One or both of the dielectric filler and the additive can be added to the mold prior to injecting the thermosetting composition.
For example, a method of preparing the volume can comprise mixing a first stream comprising the catalyst and a first monomer or curable composition and a second stream comprising the optional activating agent and a second monomer or curable composition. The first and second monomer or curable composition can be the same or different. One or both of the first stream and the second stream can comprise the dielectric filler. The dielectric filler can be added as a third stream, for example, further comprising a third monomer. The depositing of one or more of the streams can occur under an inert gas, for example, nitrogen or argon. The mixing can occur prior to deposition, in an inline mixer, or during deposition of the layer. Full or partial curing (polymerization or crosslinking) can be initiated prior to deposition, during deposition of the layer, or after deposition. In an embodiment, partial curing is initiated prior to or during deposition of the layer, and full curing is initiated after deposition of the layer or after deposition of the plurality of layers that provides the volume.
In some embodiments a support material as is known in the art can optionally be used to form a support structure. In these embodiments, the build material and the support material can be selectively dispensed during manufacture of the article to provide the article and a support structure. The support material can be present in the form of a support structure, for example a scaffolding that can be mechanically removed or washed away when the layering process is completed to the desired degree.
Stereolithographic techniques can also be used, such as selective laser sintering (SLS), selective laser melting (SLM), electronic beam melting (EBM), and powder bed jetting of binder or solvents to form successive layers in a preset pattern. Stereolithographic techniques are especially useful with thermosetting compositions, as the layer-by-layer buildup can occur by polymerizing or crosslinking each layer.
As described above, the dielectric composition can comprise a thermoplastic polymer or a thermosetting composition. The thermoplastic can be melted, or dissolved in a suitable solvent. The thermosetting composition can be a liquid thermosetting composition, or dissolved in a solvent. The solvent can be removed after applying the dielectric composition by heat, air drying, or other technique. The thermosetting composition can be B-staged, or fully polymerized or cured after applying to form the second volume. Polymerization or cure can be initiated during applying the dielectric composition.
While the invention has been described with reference to exemplary embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the claims. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best or only mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims. Also, in the drawings and the description, there have been disclosed exemplary embodiments and, although specific terms and/or dimensions may have been employed, they are unless otherwise stated used in a generic, exemplary and/or descriptive sense only and not for purposes of limitation, the scope of the claims therefore not being so limited. Moreover, the use of the terms first, second, etc. do not denote any order or importance, but rather the terms first, second, etc. are used to distinguish one element from another. Furthermore, the use of the terms a, an, etc. do not denote a limitation of quantity, but rather denote the presence of at least one of the referenced item. Additionally, the term “comprising” as used herein does not exclude the possible inclusion of one or more additional features.
This application claims the benefit of U.S. Provisional Application Ser. No. 62/569,051, filed Oct. 6, 2017, which is incorporated herein by reference in its entirety. This application also claims the benefit of U.S. Provisional Application Ser. No. 62/500,065, filed May 2, 2017, which is incorporated herein by reference in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
2624002 | Bouix | Oct 1952 | A |
3212454 | Ringenbach | Oct 1965 | A |
3321765 | Peters et al. | May 1967 | A |
4366484 | Weiss et al. | Dec 1982 | A |
4743915 | Rammos | May 1988 | A |
5071359 | Arnio | Dec 1991 | A |
5227749 | Raguenet et al. | Jul 1993 | A |
5453754 | Fray | Sep 1995 | A |
5589842 | Wang et al. | Dec 1996 | A |
5667796 | Otten | Sep 1997 | A |
5767808 | Robbins | Jun 1998 | A |
5825271 | Stitzer | Oct 1998 | A |
5854608 | Leisten | Dec 1998 | A |
5867120 | Ishikawa et al. | Feb 1999 | A |
5940036 | Oliver et al. | Aug 1999 | A |
5952972 | Ittipiboon et al. | Sep 1999 | A |
6031433 | Tanizaki et al. | Feb 2000 | A |
6052087 | Ishikawa et al. | Apr 2000 | A |
6061026 | Ochi | May 2000 | A |
6061031 | Cosenza et al. | May 2000 | A |
6075485 | Lilly et al. | Jun 2000 | A |
6147647 | Tassoudji et al. | Nov 2000 | A |
6181297 | Leisten | Jan 2001 | B1 |
6188360 | Kato et al. | Feb 2001 | B1 |
6198450 | Adachi et al. | Mar 2001 | B1 |
6268833 | Tanizaki et al. | Jul 2001 | B1 |
6292141 | Lim | Sep 2001 | B1 |
6314276 | Hilgers et al. | Nov 2001 | B1 |
6317095 | Teshirogi et al. | Nov 2001 | B1 |
6323808 | Heinrichs et al. | Nov 2001 | B1 |
6323824 | Heinrichs et al. | Nov 2001 | B1 |
6344833 | Lin et al. | Feb 2002 | B1 |
6373441 | Porath et al. | Apr 2002 | B1 |
6437747 | Stoiljkovic et al. | Aug 2002 | B1 |
6476774 | Davidson et al. | Nov 2002 | B1 |
6528145 | Berger et al. | Mar 2003 | B1 |
6552687 | Rawnick et al. | Apr 2003 | B1 |
6556169 | Fukuura et al. | Apr 2003 | B1 |
6621381 | Kundu et al. | Sep 2003 | B1 |
6743744 | Kim et al. | Jun 2004 | B1 |
6794324 | Kim et al. | Sep 2004 | B1 |
6816118 | Kingsley et al. | Nov 2004 | B2 |
6816128 | Jennings | Nov 2004 | B1 |
7161535 | Palmer et al. | Jan 2007 | B2 |
7179844 | Aki et al. | Feb 2007 | B2 |
7183975 | Thomas et al. | Feb 2007 | B2 |
7196663 | Bozer et al. | Mar 2007 | B2 |
7253789 | Kingsley et al. | Aug 2007 | B2 |
7279030 | Kurowski | Oct 2007 | B2 |
7292204 | Chang et al. | Nov 2007 | B1 |
7310031 | Pance et al. | Dec 2007 | B2 |
7379030 | Lier | May 2008 | B1 |
7382322 | Yang et al. | Jun 2008 | B1 |
7405698 | De Rochemont | Jul 2008 | B2 |
7443363 | Ying | Oct 2008 | B2 |
7498969 | Paulsen et al. | Mar 2009 | B1 |
7545327 | Iellici et al. | Jun 2009 | B2 |
7570219 | Paulsen et al. | Aug 2009 | B1 |
7595765 | Hirsch et al. | Sep 2009 | B1 |
7636063 | Channabasappa | Dec 2009 | B2 |
7663553 | Chang et al. | Feb 2010 | B2 |
7710325 | Cheng | May 2010 | B2 |
7835600 | Yap et al. | Nov 2010 | B1 |
7876283 | Bouche et al. | Jan 2011 | B2 |
7961148 | Goldberger | Jun 2011 | B2 |
8018397 | Jow et al. | Sep 2011 | B2 |
8098197 | Herting et al. | Jan 2012 | B1 |
8497804 | Haubrich et al. | Jul 2013 | B2 |
8498539 | Ilchenko et al. | Jul 2013 | B1 |
8736502 | Langfield et al. | May 2014 | B1 |
8773319 | Anderson et al. | Jul 2014 | B1 |
8902115 | Loui et al. | Dec 2014 | B1 |
9112273 | Christie et al. | Aug 2015 | B2 |
9184697 | Sekiguchi et al. | Nov 2015 | B2 |
9225070 | Zeweri et al. | Dec 2015 | B1 |
9455488 | Chirila | Sep 2016 | B2 |
9608330 | Singleton et al. | Mar 2017 | B2 |
9825373 | Smith | Nov 2017 | B1 |
9917044 | Zhou et al. | Mar 2018 | B2 |
9930668 | Barzegar et al. | Mar 2018 | B2 |
10355361 | Pance et al. | Jul 2019 | B2 |
10476164 | Pance et al. | Nov 2019 | B2 |
10522917 | Pance et al. | Dec 2019 | B2 |
10587039 | Pance et al. | Mar 2020 | B2 |
10601137 | Pance et al. | Mar 2020 | B2 |
20010013842 | Ishikawa et al. | Aug 2001 | A1 |
20010043158 | Adachi et al. | Nov 2001 | A1 |
20020000947 | Al-Rawi et al. | Jan 2002 | A1 |
20020057138 | Takagi et al. | May 2002 | A1 |
20020180646 | Kivekas et al. | Dec 2002 | A1 |
20020196190 | Lim | Dec 2002 | A1 |
20030016176 | Kingsley et al. | Jan 2003 | A1 |
20030034922 | Isaacs et al. | Feb 2003 | A1 |
20030043075 | Bit-Babik et al. | Mar 2003 | A1 |
20030122729 | Diaz et al. | Jul 2003 | A1 |
20030151548 | Kingsley | Aug 2003 | A1 |
20030181312 | Mailadil et al. | Sep 2003 | A1 |
20040029709 | Oba et al. | Feb 2004 | A1 |
20040036148 | Block et al. | Feb 2004 | A1 |
20040051602 | Pance et al. | Mar 2004 | A1 |
20040080455 | Lee | Apr 2004 | A1 |
20040113843 | Le Bolzer et al. | Jun 2004 | A1 |
20040119646 | Ohno et al. | Jun 2004 | A1 |
20040127248 | Lin et al. | Jul 2004 | A1 |
20040130489 | Le Bolzer et al. | Jul 2004 | A1 |
20040155817 | Kingsley et al. | Aug 2004 | A1 |
20040233107 | Popov et al. | Nov 2004 | A1 |
20040257176 | Pance et al. | Dec 2004 | A1 |
20040263422 | Lynch | Dec 2004 | A1 |
20050017903 | Ittipiboon et al. | Jan 2005 | A1 |
20050024271 | Ying et al. | Feb 2005 | A1 |
20050057402 | Ohno | Mar 2005 | A1 |
20050099348 | Pendry | May 2005 | A1 |
20050122273 | Legay et al. | Jun 2005 | A1 |
20050162316 | Thomas et al. | Jul 2005 | A1 |
20050162733 | Cho et al. | Jul 2005 | A1 |
20050179598 | Legay et al. | Aug 2005 | A1 |
20050200531 | Huang | Sep 2005 | A1 |
20050219130 | Koch et al. | Oct 2005 | A1 |
20050225499 | Kingsley et al. | Oct 2005 | A1 |
20050242996 | Palmer et al. | Nov 2005 | A1 |
20050264449 | Strickland | Dec 2005 | A1 |
20050264451 | Aikawa et al. | Dec 2005 | A1 |
20050264452 | Fujishima | Dec 2005 | A1 |
20060022875 | Pidwerbetsky et al. | Feb 2006 | A1 |
20060119518 | Ohmi et al. | Jun 2006 | A1 |
20060145705 | Raja | Jul 2006 | A1 |
20060194690 | Osuzu | Aug 2006 | A1 |
20060220958 | Saegrov | Oct 2006 | A1 |
20060232474 | Fox | Oct 2006 | A1 |
20060293651 | Cronin | Dec 2006 | A1 |
20070152884 | Bouche et al. | Jul 2007 | A1 |
20070164420 | Chen et al. | Jul 2007 | A1 |
20070252778 | Ide et al. | Nov 2007 | A1 |
20080036675 | Fujieda | Feb 2008 | A1 |
20080042903 | Cheng | Feb 2008 | A1 |
20080048915 | Chang et al. | Feb 2008 | A1 |
20080079182 | Thompson et al. | Apr 2008 | A1 |
20080094309 | Pance et al. | Apr 2008 | A1 |
20080122703 | Ying | May 2008 | A1 |
20080129616 | Li et al. | Jun 2008 | A1 |
20080129617 | Li et al. | Jun 2008 | A1 |
20080193749 | Thompson et al. | Aug 2008 | A1 |
20080260323 | Jalali et al. | Oct 2008 | A1 |
20080272963 | Chang et al. | Nov 2008 | A1 |
20080278378 | Chang et al. | Nov 2008 | A1 |
20090040131 | Mosallaei | Feb 2009 | A1 |
20090073332 | Irie | Mar 2009 | A1 |
20090102739 | Chang | Apr 2009 | A1 |
20090128262 | Lee et al. | May 2009 | A1 |
20090128434 | Chang et al. | May 2009 | A1 |
20090140944 | Chang et al. | Jun 2009 | A1 |
20090153403 | Chang et al. | Jun 2009 | A1 |
20090179810 | Kato et al. | Jul 2009 | A1 |
20090184875 | Chang et al. | Jul 2009 | A1 |
20090206957 | Hiroshima et al. | Aug 2009 | A1 |
20090262022 | Ying | Oct 2009 | A1 |
20090270244 | Chen et al. | Oct 2009 | A1 |
20090305652 | Boffa et al. | Dec 2009 | A1 |
20100002312 | Duparre et al. | Jan 2010 | A1 |
20100051340 | Yang et al. | Mar 2010 | A1 |
20100065314 | Lin | Mar 2010 | A1 |
20100103052 | Ying | Apr 2010 | A1 |
20100156754 | Kondou | Jun 2010 | A1 |
20100215840 | Grunwald | Aug 2010 | A1 |
20100220024 | Snow et al. | Sep 2010 | A1 |
20100231452 | Babakhani et al. | Sep 2010 | A1 |
20100309089 | Collinson | Dec 2010 | A1 |
20110040300 | Brannan | Feb 2011 | A1 |
20110050367 | Yen et al. | Mar 2011 | A1 |
20110121258 | Hanein et al. | May 2011 | A1 |
20110122036 | Leung et al. | May 2011 | A1 |
20110133991 | Lee et al. | Jun 2011 | A1 |
20110204531 | Hara et al. | Aug 2011 | A1 |
20110248890 | Lee et al. | Oct 2011 | A1 |
20120045619 | Ando et al. | Feb 2012 | A1 |
20120092219 | Kim | Apr 2012 | A1 |
20120212386 | Massie et al. | Aug 2012 | A1 |
20120242553 | Leung et al. | Sep 2012 | A1 |
20120245016 | Curry et al. | Sep 2012 | A1 |
20120256796 | Leiba | Oct 2012 | A1 |
20120274523 | Ayatollahi | Nov 2012 | A1 |
20120276311 | Chirila | Nov 2012 | A1 |
20120280380 | Kamgaing | Nov 2012 | A1 |
20120287008 | Kim | Nov 2012 | A1 |
20120306713 | Raj et al. | Dec 2012 | A1 |
20120329635 | Hill | Dec 2012 | A1 |
20130076570 | Lee et al. | Mar 2013 | A1 |
20130088396 | Han | Apr 2013 | A1 |
20130113674 | Ryu | May 2013 | A1 |
20130120193 | Hoppe et al. | May 2013 | A1 |
20130234898 | Leung et al. | Sep 2013 | A1 |
20130278610 | Stephanou | Oct 2013 | A1 |
20140043189 | Lee et al. | Feb 2014 | A1 |
20140091103 | Neitzel | Apr 2014 | A1 |
20140327591 | Kokkinos | Nov 2014 | A1 |
20140327597 | Rashidian et al. | Nov 2014 | A1 |
20150035714 | Zhou | Feb 2015 | A1 |
20150077198 | Yatabe | Mar 2015 | A1 |
20150138036 | Harper | Apr 2015 | A1 |
20150183167 | Molinari et al. | Jul 2015 | A1 |
20150207233 | Kim et al. | Jul 2015 | A1 |
20150207234 | Ganchrow et al. | Jul 2015 | A1 |
20150236428 | Caratelli et al. | Aug 2015 | A1 |
20150244082 | Caratelli et al. | Aug 2015 | A1 |
20150266244 | Page | Sep 2015 | A1 |
20150303546 | Rashidian et al. | Oct 2015 | A1 |
20150314526 | Cohen | Nov 2015 | A1 |
20150346334 | Nagaishi et al. | Dec 2015 | A1 |
20150380824 | Tayfeh Aligodarz et al. | Dec 2015 | A1 |
20160006118 | Maruyama | Jan 2016 | A1 |
20160107290 | Bajaj et al. | Apr 2016 | A1 |
20160111769 | Pance | Apr 2016 | A1 |
20160218437 | Guntupalli et al. | Jul 2016 | A1 |
20160294066 | Djerafi et al. | Oct 2016 | A1 |
20160294068 | Djerafi et al. | Oct 2016 | A1 |
20160313306 | Ingber et al. | Oct 2016 | A1 |
20160314431 | Quezada | Oct 2016 | A1 |
20160322708 | Tayfeh Aligodarz | Nov 2016 | A1 |
20160351996 | Ou | Dec 2016 | A1 |
20160372955 | Fackelmeier et al. | Dec 2016 | A1 |
20170018851 | Henry et al. | Jan 2017 | A1 |
20170040700 | Leung et al. | Feb 2017 | A1 |
20170069958 | Ko | Mar 2017 | A1 |
20170125901 | Sharawi et al. | May 2017 | A1 |
20170125908 | Pance et al. | May 2017 | A1 |
20170125909 | Pance et al. | May 2017 | A1 |
20170125910 | Pance et al. | May 2017 | A1 |
20170179569 | Kim et al. | Jun 2017 | A1 |
20170188874 | Suhami | Jul 2017 | A1 |
20170201026 | Werner et al. | Jul 2017 | A1 |
20170225395 | Boydston et al. | Aug 2017 | A1 |
20170256847 | Vollmer et al. | Sep 2017 | A1 |
20170271772 | Miraftab et al. | Sep 2017 | A1 |
20170272149 | Michaels | Sep 2017 | A1 |
20180054234 | Stuckman et al. | Feb 2018 | A1 |
20180069594 | Henry et al. | Mar 2018 | A1 |
20180090815 | Shirinfar | Mar 2018 | A1 |
20180115072 | Pance et al. | Apr 2018 | A1 |
20180183150 | Sienkiewicz | Jun 2018 | A1 |
20180241129 | Pance | Aug 2018 | A1 |
20180309202 | Pance et al. | Oct 2018 | A1 |
20180323514 | Pance et al. | Nov 2018 | A1 |
20190020105 | Pance et al. | Jan 2019 | A1 |
20190128624 | Cohen et al. | May 2019 | A1 |
20190214732 | Leung et al. | Jul 2019 | A1 |
20190221926 | Pance et al. | Jul 2019 | A1 |
20190221939 | George et al. | Jul 2019 | A1 |
20190221940 | Pance et al. | Jul 2019 | A1 |
20190319357 | Pance et al. | Oct 2019 | A1 |
20190319358 | Pance et al. | Oct 2019 | A1 |
20190379123 | Leung et al. | Dec 2019 | A1 |
20190393607 | Pance et al. | Dec 2019 | A1 |
20200083602 | Sethumadhavan et al. | Mar 2020 | A1 |
20200083609 | Pance et al. | Mar 2020 | A1 |
20200099136 | Pance et al. | Mar 2020 | A1 |
20200194881 | Pance et al. | Jun 2020 | A1 |
20200227827 | Vollmer et al. | Jul 2020 | A1 |
Number | Date | Country |
---|---|---|
0468413 | Jan 1992 | EP |
0587247 | Mar 1994 | EP |
0801436 | Oct 1997 | EP |
1783516 | May 2007 | EP |
2905632 | Aug 2015 | EP |
2050231 | Jan 1981 | GB |
2004112131 | Apr 2004 | JP |
2011195444 | Oct 2011 | JP |
2017075184 | May 2017 | WO |
Entry |
---|
Nasimuddin et al., “Antennas with dielectric resonators and surface mounted short horns for high gain and large bandwidth,” IET Microwaves Antennas & Propagation, July (Year: 2007). |
Buerkle, A. et al; “Fabrication of a DRA Array Using Ceramic Stereolithography”; IEEE Antennas and Wireless Popagation Letters; IEEE; vol. 5,, No. 1, Jan. 2007; pp. 479-481. |
Zainud-Deen, S H et al; “Dielectric Resonator Antenna Phased Array for Fixed RFID Reader in Near Field Region”, IEEE; Mar. 6, 2012; pp. 102-107. |
Guo, Yomg-Xin, et al.,; “Wide-Band Stacked Double Annular-Ring Dielectric Resonator Antenna at the End-Fire Mode Operation”; IEEE Transacions on Antennas and Propagation; vol. 53; No. 10; 2005; 3394-3397 pages. |
Kakade, A.B., et al; “Analysis of the Rectangular Waveguide Slot Coupled Multilayer hemispherical Dielectric Resonator Antenna”; IET Microwaves, Antennas & Propagation, The Institution of Engineering and Technology; vol. 6; No. 3; 2012; 338-347 pages. |
Kishk, A. Ahmed, et al.,; “Analysis of Dielectric-Resonator with Emphasis on Hemispherical Structures”; IEEE Antennas & Propagation Magazine; vol. 36; No. 2; 1994; 20-31 pages. |
Notification of Transmittal of the International Search Report and the Wrritten Opinion of the International Searching Authority, or the Declaration for International Application No. PCT/US2018/029003 dated Jul. 6, 2018 and dated Jul. 9, 2018, which is related to U.S. Appl. No. 15/957,078; 1-6 pages. |
Petosa, Aldo, et al.; “Dielectric Resonator Antennas: A Historical Review and the Current State of the Art”; IEEE Antennas and Propagation Magazine; vol. 52, No. 5, Oct. 2010; 91-116 pages. |
Ruan, Yu-Feng, et al; “Antenna Effects Consideration for Space-Time Coding UWB-Impulse Radio System in IEEE 802.15 Multipath Channel”; Wireless Communications, Networking and Mobile Computing; 2006; 1-4 pages. |
Wong, Kin-Lu, et al.,; “Analysis of a Hemispherical Dielectric Resonator Antenna with an Airgap”; IEEE Microwave and Guided Wave Letters; vol. 3; No. 9; 1993; 355-357 pages. |
Written Opinion of the International Searching Authority for International Application No. PCT/US2018/029003 dated Jul. 6, 2018 and dated Jul. 9, 2018, which is related to U.S. Appl. No. 15/957,078; 1-14 pages. |
Kakade, Anandrao, et al.; Mode Excitation in the Coaxial Probe Coupled Three-Layer Hemispherical Dielectric Resonator Antenna; IEEE Transactions on Antennas and Propagation; vol. 59; No. 12; Dec. 2011; 7 pages. |
Raghvendra Kumar Chaudhary et al; Variation of Permittivity in Radial Direction in Concentric Half-Split Cylindrical Dielectric Resonator Antenna for Wideband Application: Permittivity Variation in R-Dir. in CDRA; International Journal of RF and Microwave Computer-Aided Engineering; vol. 25; No. 4; May 1, 2015; pp. 321-329. |
Zhang Shiyu et al.; “3D-Printed Graded Index Lenses for RF Applications”; ISAP 2016 International Symposium on Antennas and Propagation, Okinawa, Japan.; pp. 1-27. |
Number | Date | Country | |
---|---|---|---|
20190123448 A1 | Apr 2019 | US |
Number | Date | Country | |
---|---|---|---|
62569051 | Oct 2017 | US | |
62500065 | May 2017 | US |