Patent Grant
9805893
The present invention relates to an electromagnetic relay including magnetic components with improved wear resistance, corrosion resistance, and magnetic properties.
Magnetic components used in electronic devices such as electromagnetic relays (also referred to as relays) are plated with nickel to provide corrosion resistance.
Thin Ni plating layers can also cause problems. When, for example, an electric contact in a sealed relay is open and closed under high voltage and high current, it generates arc heat, which then produces nitric acid. Such nitric acid can corrode the plating, and can form patina on the surface of the magnetic component. As this reaction proceeds, the relay can malfunction.
Further, a relay including a sliding part (hinge) can have its operating characteristics varying greatly when the hinge part is mechanically worn by sliding. To overcome this, a lubricating oil is applied to the hinge part during assembly of the relay. However, no lubricating oil is added again to the hinge part during the service life of the relay. The hinge part can thus wear with time.
In response to such difficulties associated with the thickness of Ni plating and its corrosion resistance, techniques using chrome have been developed. Patent Literature 1 describes a soft magnetic stainless steel containing chrome used for an iron core of a relay. Patent Literature 2 describes an electromagnetic material containing chrome used for a relay. The stainless steel described in Patent Literature 1 and the electromagnetic material described in Patent Literature 2 contain chrome, and eliminate difficulties associated with the thickness.
Techniques using chrome have also been developed to achieve wear resistance. Patent Literatures 3 to 5 describe chromized chains and chromized pins for chains. The techniques described in Patent Literatures 3 to 5 use diffusion-coating of chrome on the surface of a chain or a chain pin to improve wear resistance. The chromizing allows chrome to diffuse and penetrate into the base material, and thus prevents the thickness from increasing.
Patent Literature 6 describes a method of chromizing. With the technique described in Patent Literature 6, a mixture of chrome metal powder and at least one metal powder of an element selected from the group consisting of Zn, W, Ti, and Mo is used to form a chrome diffusion layer. The technique described in Patent Literature 6 can form a very thick chrome diffusion layer, thus providing improved corrosion resistance.
However, the techniques known in the art cannot provide an electromagnetic relay having high wear resistance, high corrosion resistance, and good magnetic properties.
For example, the techniques described in Patent Literatures 1 and 2 use an alloy containing chrome. With the alloy containing chrome uniformly, the base material has an insufficiently grown metallic structure. Thus, the relay component formed from the alloy described in Patent Literatures 1 and 2 has insufficient magnetic properties, and thus cannot serve intended use.
Also, the chains and the chain pins described in Patent Literatures 3 to 5 are formed from a material containing more carbon to increase hardness. In this case, the metallic structure is grown insufficiently, and cannot provide the material with sufficient magnetic properties.
The technique described in Patent Literature 6 forms a very thick chrome diffusion layer, and thus increases magnetic resistance. The technique described in Patent Literature 6 cannot be used for magnetic components.
In response to the above issue, the present invention is directed to an electromagnetic relay having high wear resistance, high corrosion resistance, and good magnetic properties.
An electromagnetic relay according to embodiments of the invention includes an electromagnetic device and a contact. The electromagnetic device includes a magnetic component and a coil. The magnetic component includes an iron component prepared by processing an iron material. The contact is open and closed in cooperation with magnetization and demagnetization of the electromagnetic device. The iron component includes an alloy layer on a surface thereof, and the alloy layer is formed by diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si. The alloy layer has a thickness in a range of 5 to 60 μm inclusive.
The electromagnetic relay in one or more embodiments of the invention includes a magnetic device and a contact. The magnetic device includes a magnetic component and a coil. The magnetic component includes an iron component prepared by processing an iron material. The contact is open and closed in cooperation with magnetization and demagnetization of the electromagnetic device. The iron component includes an alloy layer on a surface thereof, and the alloy layer is formed by diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si. The alloy layer has a thickness in a range of 5 to 60 μm inclusive.
This provides an electromagnetic relay having high wear resistance, high corrosion resistance, and good magnetic properties.
Although embodiments of the present invention will be described in detail, the invention is not limited to these embodiments. For convenience of explanation, the components with the same functions are given the same reference numerals and are not described. In the figures, x-axis, y-axis, and z-axis define the directions in a three-dimensional space.
Electromagnetic Relay
Although the contact 9 may have any structure, the contact 9 may include a movable contact 9a included in a movable contact piece 8a and a fixed contact 9b included in a fixed contact piece 8b as shown in
The electromagnetic relay according to the embodiment may be, for example, a sealed relay or a hinged relay.
The magnetism or the magnetic properties herein refers to the property of having attraction force and coercive force, which will be described later. The good magnetism or magnetic properties refers to the property of having attraction force and coercive force at least equivalent to or exceeding the attraction force and the coercive force of a Ni-plated magnetic component known in the art.
A magnetic component plated with Ni known in the art herein may be simply referred to as a Ni-plated product or a conventional product.
Magnetic Component
The magnetic component includes an iron component prepared by processing an iron material. The iron component includes an alloy layer on its surface formed by diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si. The alloy layer has a thickness in a range of 5 to 60 μm, inclusive.
The magnetic component may be the yoke 1 (
Iron Component
The magnetic component includes an iron component prepared by processing an iron material. The iron material herein refers to any typical iron alloy mainly composed of iron. The iron material may be, for example, pure iron or steel. The steel may be, for example, a cold-rolled steel plate, a hot-rolled steel plate, or an electromagnetic steel plate. The iron material may contain silicon, and may be, for example, a silicon steel plate. The iron material may be in any form, such as a band or a bar.
The iron component herein refers to a component with an intended shape formed from an iron material. The iron material may be processed into the iron component with any method, such as press work. The shape and the size of the iron component are determined depending on its application.
In some embodiments, the iron material has a carbon content in a range of 0 to 0.15 wt % inclusive, or in a range of 0 to 0.05 wt % inclusive. In some other embodiments, the carbon content is not less than 0 wt % and less than 0.01 wt %. The iron material containing less carbon can be processed into an iron component having a sufficiently grown metallic structure in a magnetic component. This enables the magnetic component to have good magnetic properties.
The iron component may have a ferritic grain size of not more than 1 defined by JIS G0551 (2005). The ferritic grain size of not more than 1 herein refers to, for example, the grain size of 1, 0, −1, −2, or less. This iron component contains large crystal grains and a sufficiently grown metallic structure, and thus provides a magnetic component having good magnetic properties. The grain size of the iron component herein refers to the grain size in an area of the iron component inward from the alloy layer as viewed from the surface of the iron component.
The surface of the iron component herein refers to at least one of all the surfaces of the iron component unless otherwise specified. All the surfaces of the iron component may be coated with an alloy layer. Although a part of each surface of the iron component coated with the alloy layer may be diffusion-coated with the at least one element, the largest possible part or the entire surface may be diffusion-coated with the element. This allows the iron component to have all the surfaces with high wear resistance and corrosion resistance, and allows the magnetic component to have good magnetic properties.
The area inward from the alloy layer or in a layer lower than the alloy layer as viewed from the surface of the iron component herein refers to an area that is not diffusion-coated with the at least one element selected from the group consisting of Cr, V, Ti, Al, and Si. When, for example, all the surfaces of the iron component are coated with an alloy layer, an area inward from the alloy layer or in a layer lower than the alloy layer as viewed from the surface of the iron component is an area surrounded by the alloy layer.
Alloy Layer
In the electromagnetic relay according to embodiments of the present invention, the iron component includes an alloy layer on its surface formed by diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si. The alloy layer has a thickness in a range of 5 to 60 μm, inclusive.
This structure allows the iron component, which is prepared by processing an iron material, to have sufficiently′ high hardness. The resultant magnetic component thus has high wear resistance. This provides an electromagnetic relay that has less wear against mechanical sliding and has a long service life.
When, for example, an electric contact of a sealed relay is open and closed under high voltage and high current, it generates arc heat, which then produces nitric acid. Such nitric acid can corrode the Ni plating of the magnetic component known in the art to form patina on the surface of the magnetic component. However, the above magnetic component includes the alloy layer, and thus reduces such patina. The magnetic component can thus have high corrosion resistance. This provides an electromagnetic relay having high corrosion resistance.
The alloy layer herein refers to a layer of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si formed by diffusing-coating, or the element diffusing and penetrating from the surface into the iron component. The alloy layer may contain a compound of the element and carbon or other elements contained in the iron material.
Unlike Ni plating, the alloy layer formed by diffusion-coating does not greatly increase the thickness of the component. The alloy layer does not affect mating between components.
Although the alloy layer may be as thick as possible to increase wear resistance and corrosion resistance, a thicker alloy layer formed from Cr, V, Ti, Al, and Si, which are non-magnetic materials, will increase magnetic resistance and is unsuited for a magnetic component. A thicker alloy layer will also prevent growth of its internal metallic structure.
The magnetic component includes the alloy layer having a thickness of not less than 5 μm, and thus has high wear resistance and high corrosion resistance. The alloy layer has a thickness of not more than 60 μm, and thus prevents the magnetic resistance from increasing. The alloy layer with a thickness of not more than 60 μm does not prevent growth of its internal metallic structure. This allows the iron component to have a sufficiently grown metallic structure. The resultant magnetic component having good magnetic properties can be used as, for example, an electromagnet in an electromagnetic relay having good magnetic properties. The above structure provides an electromagnetic relay having high wear resistance and high corrosion resistance as well as good magnetic properties.
In some embodiments, the alloy layer has a thickness in a range of 5 to 35 μm, inclusive. The alloy layer with this thickness is less likely to affect the growth of the metallic structure. This provides a magnetic component having high wear resistance and high corrosion resistance, as well as good magnetic properties.
The thickness of the alloy layer can be measured at a cross-section resulting from perpendicularly cutting any surface of the iron component on which the alloy layer is formed. For a rectangular-parallelepiped iron component, the thickness of its alloy layer may be measured on a rectangular cross-section resulting from perpendicularly cutting any surface of the component on which the alloy layer is formed. For a spherical iron component, the thickness of its alloy layer may be measured on a circular cross-section resulting from perpendicularly cutting any surface of the component through the center of the sphere.
The alloy layer may be formed by diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si, or of two or more of these elements. The alloy layer may contain two or more of the elements at any ratio.
The maximum total content of Cr, V, Ti, Al, and/or Si in the alloy layer may be in a range of 20 to 65 wt % inclusive in some embodiments, or in a range of 20 to 60 wt % inclusive in some other embodiments. This total content of elements is large enough to provide the alloy layer with wear resistance and corrosion resistance, and is less likely to affect the magnetic properties. This provides a magnetic component having high wear resistance and high corrosion resistance, as well as better magnetic properties.
The maximum total content of the above elements can be calculated through element concentration analysis with, for example, an electron probe micro analyzer (EPMA). The maximum total content of the elements refers to the largest one of the values indicating the total content measured at a plurality of positions in the alloy layer using, for example, an EPMA. When, for example, the content of Cr in the alloy layer measured at a distance of 5 μm from the surface of the iron component is 50 wt % and the Cr content measured at a distance of 10 μm from the surface is 10 wt %, the maximum Cr content is 50 wt %.
When the alloy layer contains two or more of the above elements, the maximum total content of the elements is in a range of 20 to 65 wt % inclusive in some embodiments, and is in a range of 20 to 60 wt % inclusive in some other embodiments. For an alloy layer containing diffusion-coated Cr and V, for example, the maximum total content of Cr and V may fall within the above ranges.
Method for Manufacturing Magnetic Component
The magnetic component includes an iron component prepared by processing an iron material. A method for manufacturing the magnetic component includes alloy layer formation, in which an alloy layer is formed by diffusion-coating the iron component with at least one element selected from the group consisting of Cr, V, Ti, Al, and Si. The diffusion-coating of the elements is performed with a treatment time of 5 to 15 hours inclusive at a treatment temperature of 750 to 950° C. inclusive.
The surface of the iron component, which is formed by processing an iron material, is coated with the alloy layer by diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si. The resultant magnetic component can have sufficiently high hardness. This provides a magnetic component having high wear resistance.
The alloy layer is formed on the surface of the iron component, and allows the magnetic component to have high corrosion resistance against nitric acid or other compounds.
The diffusion-coating process is performed with a predetermined treatment time at a predetermined temperature to control the thickness of the alloy layer as well as to allow the metallic structure to grow. This prevents the alloy layer from increasing the magnetic resistance, and allows the magnetic component to have good magnetic properties.
The above structure allows the magnetic component to have high wear resistance and high corrosion resistance, as well as good magnetic properties. A method for manufacturing a magnetic component included in an electromagnetic relay according to embodiments of the present invention will now be described in detail. The processes associated with the iron component and the alloy layer described above will not be described in detail.
Diffusion-Coating of Elements on Iron Component
The method for manufacturing the magnetic component includes diffusing-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si on the iron component. The diffusion-coating of the element on the iron component forms an alloy layer on the surface of the iron component.
The at least one element selected from the group consisting of Cr, V, Ti, Al, and Si may be in powder form. The powder may be of one element selected from the group consisting of Cr, V, Ti, Al, and Si, or may be of two or more of these elements. The powder may contain two or more of the elements at any ratio that provides high wear resistance and high corrosion resistance and good magnetic properties. The powder may be solely of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si, or may be of a compound or an alloy containing the at least one element. The alloy containing the at least one element may be, for example, an alloy of the at least one element with iron.
The powder containing the at least one element selected from the group consisting of Cr, V, Ti, Al, and Si may be provided as a penetrant further containing other materials. The penetrant may be, for example, a mixture of the powder containing the at least one element, alumina powder, and ammonium chloride powder at any ratio. This penetrant increases the efficiency of the diffusion-coating process.
Alloy Layer Formation
The alloy layer formation process will now be described in detail.
Subsequently, powder 5 containing at least one element selected from the group consisting of Cr, V, Ti, Al, and Si is fed into the box 6. The iron components 4 are completely buried in the powder 5.
The box 6 is then placed inside a furnace 7, and undergoes the treatment time and the treatment temperature (described below), with which the powder 5 can diffuse and penetrate into each iron component 4. The treatment time and the treatment temperature in combination allow diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si onto each iron component to form an alloy layer on each iron component, and further allow the metallic structure of each iron component to grow. The process for diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si on an iron component herein may simply be referred to as the diffusion-coating process. The diffusion-coating of Cr in particular herein refers to chromizing.
After the diffusion-coating process, the box 6 is removed from the furnace 7, and the iron components 4 are removed from the box 6. The iron components 4 are cleaned and dried as appropriate.
Treatment Time and Treatment Temperature
In the diffusion-coating process described above, the treatment time is in a range of 5 to 15 hours inclusive in some embodiments, and is in a range of 8 to 10 hours inclusive in some other embodiments. The treatment temperature is in a range of 750 to 950° C. inclusive in some embodiments, is in a range of 750 to 900° C. inclusive in some other embodiments, is in a range of 750 to 900° C. inclusive in still other embodiments, and is in a range of 750 to 850° C. inclusive in still other embodiments.
The diffusion-coating process performed for at least 5 hours at 750° C. or higher temperatures will form an alloy layer that is thick enough to provide wear resistance and corrosion resistance, and allow the metallic structure to grow sufficiently. The diffusion-coating process performed for not more than 15 hours at 950° C. or lower temperatures can control the thickness of the alloy layer to a thickness that does not increase the magnetic resistance and does not prevent growth of the metallic structure.
The thickness of the alloy layer that provides wear resistance and corrosion resistance, and does not increase the magnetic resistance and does not prevent growth of the metallic structure is, for example, in a range of 5 to 60 μm inclusive, and is in a range of 5 to 35 μm inclusive in some other embodiments.
The diffusion-coating process performed with the treatment time and the treatment temperature described above allows the crystal grains in the iron component to grow to the ferritic grain size of not more than 1 defined by JIS G0551 (2005). The resultant iron component has a sufficiently grown metallic structure. This provides a magnetic component having good magnetic properties.
Comparison with Ni-Plated Product Manufacturing Method
The manufacturing method described above simplifies the processes for manufacturing the magnetic component, and thus reduces the cost for manufacturing the magnetic component.
The method for manufacturing a Ni-plated product known in the art includes a first process of pressing an iron material, which is mainly an iron plate, into a predetermined shape, and includes a second process of heating the workpiece at 800 to 900° C. for 15 to 30 minutes in a non-oxidizing or reductive environment to provide intended magnetic properties. To increase the size of the metal grains to improve the magnetic properties, the workpiece may be heated for a longer period of time. However, the heat treatment is typically performed for the shortest time of about 15 minutes for the cost effectiveness. The method further includes a third process of plating the workpiece with nickel to increase the corrosion resistance of the component. These three processes have different purposes and are performed with different methods. These are necessary manufacturing processes for magnetic component, and none of them can be omitted.
In contrast, the manufacturing method for the magnetic component included in the electromagnetic relay according to embodiments of the present invention includes the diffusion-coating process involving heating, which grows the metallic structure and forms the alloy layer at the same time. This method thus includes two processes, namely, press and diffusion-coating. This method provides the magnetic component with intended magnetic properties, and wear resistance and corrosion resistance higher than those of a Ni-plated product known in the art, and further simplifies the manufacturing processes.
For the Ni-plating process involving electroplating, components are not plated one by one. To minimize the cost, a predetermined number of components are placed in a cage and are plated together while the cage is being rotated. With this method, the components can deform easily due to the weight of each component or due to their movements during the rotation. This can produce defective components. Further, although the entire surface of each component is plated, the components rub each other on their surfaces as the plating proceeds. This easily causes variations in the plating thickness across the components depending on the shape of the components, and further easily causes variations in the plating thickness across different positions of each component. To provide corrosion resistance across the entire surface of a component, the average plating thickness across the entire component is inevitably thicker than necessary. Further, although this method allows mass plating of components at a time, the resultant plating thickness is relatively small, and can also vary. The plating process is thus usually performed twice to obtain the average thickness of about 5 to 10 μm. This method thus actually involves four processes from processing the material to completing the product.
In contrast, the method for manufacturing the magnetic component included in the electromagnetic relay according to embodiments of the present invention eliminates the process of rotating the components in the cage, which is performed with the Ni plating method, and thus eliminates deformation of the components. Further, the diffusion-coating process forms the alloy layer with substantially uniform thickness across the entire surface of each component, and thus causes less dimensional variations across the individual components. This method thus does not affect mating between components, and eliminates defects in the assembly caused by variations in the plating thickness, which can occur to Ni-plated products known in the art.
The present invention is not limited to the embodiments described above, and may be changed variously within the scope designated by the appended claims. The technical methods described in the embodiments in combination as appropriate also fall within the technical scope of the present invention.
The embodiments of the present invention may be modified in the following forms.
In response to the above issue, an electromagnetic relay according to embodiments of the present invention includes an electromagnetic device and a contact. The electromagnetic device includes a magnetic component and a coil. The magnetic component includes an iron component prepared by processing an iron material. The contact is open and closed in cooperation with magnetization and demagnetization of the electromagnetic device. The iron component includes an alloy layer on a surface thereof formed by diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, and Si. The alloy layer has a thickness in a range of 5 to 60 μm, inclusive.
The iron component prepared by processing an iron material includes an alloy layer on its surface. The alloy layer is formed by diffusion-coating of at least one element selected from the group consisting of Cr, V, Ti, Al, Si. This structure allows the magnetic component to have sufficiently high hardness, and thus have high wear resistance. This provides an electromagnetic relay having less wear against mechanical sliding and having a long service life.
The iron component includes the alloy layer. The resultant magnetic component thus has high corrosion resistance against nitric acid or other compounds. This enables the electromagnetic relay to have high corrosion resistance against nitric acid, which can occur inside the electromagnetic relay due to arc heat generated when the contact is open and closed.
The alloy layer has a thickness of 5 to 60 μm, inclusive. The alloy layer with this thickness does not prevent growth of the metallic structure of the iron material in a layer lower than the alloy layer as viewed from the surface of the iron component. This allows the iron component to have a sufficiently grown metallic structure, and allows the magnetic component to have good magnetic properties, although the alloy layer is formed by non-magnetic elements such as Cr, V, Ti, Al, and Si. This provides an electromagnetic relay having good magnetic properties including the magnetic component as an electromagnet.
The alloy layer formed by diffusion-coating does not greatly increase the thickness of the component. The alloy layer does not affect mating between components.
The above structure provides an electromagnetic relay having high wear resistance and high corrosion resistance, as well as good magnetic properties.
A method for manufacturing a magnetic component included in the electromagnetic relay according to embodiments of the present invention includes forming an alloy layer and growing a metallic structure in a single process. This method simplifies the manufacturing processes, and thus reduces the cost for manufacturing the magnetic component.
In the electromagnetic relay according to embodiments of the present invention, the alloy layer has a total of a maximum content of the at least one element selected from the group consisting of Cr, V, Ti, Al, and Si in a range of 20 to 65 wt %, inclusive.
The total content of the at least one element in the alloy layer is large enough to provide wear resistance and corrosion resistance, and is less likely to affect the growth of the metallic structure. This structure thus allows the electromagnetic relay to have high wear resistance and high corrosion resistance, as well as good magnetic properties.
The maximum content of the at least one element refers to the largest one of the values indicating the total content of the at least one element measured at a plurality of positions in the alloy layer.
In the electromagnetic relay according to embodiments of the present invention, the alloy layer may be formed by diffusion-coating of the at least one element selected from the group consisting of Cr, V, Ti, Al, and Si on the iron component with a treatment time in a range of 5 to 15 hours inclusive at a treatment temperature in a range of 750 to 950° C. inclusive.
The diffusion-coating process performed under the predetermined time and temperature conditions allows the alloy layer to have a controlled thickness, and allows the metallic structure of the iron component to grow. This structure thus provides an electromagnetic relay having high wear resistance and high corrosion resistance, as well as good magnetic properties.
In the electromagnetic relay according to embodiments of the present invention, the iron material may have a carbon content in a range of not less than 0 wt % and less than 0.15 wt %.
The iron material containing less carbon can be processed into an iron component having a sufficiently grown metallic structure in a magnetic component. This enables the magnetic component to have better magnetic properties.
In the electromagnetic relay according to embodiments of the present invention, the iron component may have a ferritic grain size of not more than 1 defined by JIS G0551 (2005).
The iron component has a large grain size and has a sufficiently grown metallic structure. This provides an electromagnetic relay having better magnetic properties.
Examples of the present invention will now be described. The examples may be modified variously without deviating from the scope of the present invention. In these examples, the maximum content of the element A may be referred to as the surface A concentration. For example, the maximum content of chrome in the alloy layer may be referred to as the surface chrome concentration. The at least one element distributes to decrease its amount gradually from the surface of the iron component toward the inside. The concentration is in wt %, although the unit of the concentration may hereafter be referred to as %.
A yoke having a thickness of 1.5 mm, a width of 15 mm, and a length of 28 mm, and a ring having an outer diameter of 45 mm, an inner diameter of 33 mm, and a thickness of 1.2 mm were prepared using electromagnetic soft iron (SUYP) having a carbon content of 0.01 wt %.
In examples 1 to 5 and comparative examples 1 and 2, the yokes and the rings prepared as described above underwent the diffusion-coating process under different temperature conditions to form test pieces. In the diffusion-coating process, the yokes and the rings were buried in a penetrant containing 40 to 80 wt % of chrome powder, 19.5 to 59.5 wt % of alumina powder, and 0.5 wt % of ammonium chloride powder in an incompletely sealed container. While the container is being supplied with hydrogen gas, the yokes and the rings were heated for 10 hours at 700° C. (comparative example 1), 750° C. (example 1), 800° C. (example 2), 850° C. (example 3), 900° C. (example 4), 950° C. (example 5), and 1000° C. (comparative example 2). In comparative example 3, the yokes and the rings plated with Ni were used as the test pieces. The yokes were used to examine the thickness of the alloy layer, the concentration of the at least one element used in diffusion-coating, the corrosion resistance, wear resistance, and attraction force to determine the effect of the diffusion-coating process in improving the quality of the components. The rings were used to test the coercive force.
Alloy Layer Thickness and Surface Chrome Concentration
Each yoke was cut, and the resultant cross-section was observed to measure the thickness of the alloy layer. The average of the measurement results at 10 positions was used as the thickness of the alloy layer. The surface chrome concentration was determined by element surface analysis with a scanning electron microscope (SEM) and by element concentration analysis with an electron probe micro analyzer (EPMA).
Surface Hardness of Alloy Layer
The surface hardness of the alloy layer was determined by measuring the Vickers hardness in accordance with JIS Z 2244 (1992). This test was conducted under a test load of 25 gf.
Corrosion Resistance Test (Salt-Spray Test)
A salt-spray test was used as a corrosion resistance test to determine the percentage of a corroded area on the surface of each test piece. In the salt-spray test tank maintained at 35° C., salt water with a salt concentration of 5±1% (mass ratio) and the pH of 6.5 to 7.2 (the water temperature of 20±2° C.) was continuously sprayed onto the test piece for 2 hours, and then the test piece was left in the tank for 20 to 22 hours. This single test cycle was repeated three times (three cycles). This corrosion resistance test was conducted in accordance with JIS C 0024 (2000) (IEC 60068-2-52 (1996)) and JIS C 5442 (1996).
Wear Resistance Test
In the wear resistance test, each test piece was actually mounted onto a relay. The relay was open and closed 20 million times, and then the appearance of the surface portion with metallic wear was observed. The metallic wear was evaluated based on the amount of the generated wear powder. The relay was open and closed 1800 times per minute. This wear resistance test was conducted in accordance with JIS C 4530 (1996), JIS C 5442 (1996), and NECA C 5440 (1999).
Attraction Force Test
Coercive Force Test
The coercive force of the circular ring, which was prepared as the test piece, was measured.
The coercive force is the intensity of the reversing magnetic field to demagnetize a magnetized magnetic material. A smaller value of the coercive force indicates better magnetic properties. The coercive force was measured by using a B-H curve tracer. The coercive force values were determined from the measured B-H curves.
Test Results for Examples 1 to 5 and Comparative Examples 1 to 3
Table 1 shows the test results for examples 1 to 5 and comparative examples 1 to 3. The results of the wear resistance test indicate the percentage of the amount of wear powder generated in each of the examples and each of the comparative examples when the amount of wear powder generated in comparative example 3 (Ni-plated product) is assumed to be 100%. A smaller value of the amount of wear powder indicates higher wear resistance. The results of the attraction force test indicate the percentage of the attraction force in each of the examples and each of the comparative examples when the attraction force in comparative example 3 is assumed to be 100%.
Results of Alloy Layer Surface Hardness
The alloy layer of chrome and iron is harder than the electromagnetic soft iron of the base material (with a Vickers hardness of 90 to 150 mHv), and has a Vickers hardness of 160 to 630 mHv as shown in Table 1. The alloy layer in comparative example 1 has a Vickers hardness of 160 mHv, which is lower than that of comparative example 3. The thickness of the alloy layer in comparative example 1 is 3 μm, which is thin.
Results of Corrosion Resistance Test
Although comparative example 1 shows a larger corroded area of 50 to 60% indicating more corrosion than the Ni-plated product of comparative example 3 with the corroded area of 40 to 50%, examples 1 to 5 all show less corrosion than comparative example 3. In particular, examples 3 to 5 (with an alloy layer thickness of 20 to 60 μm and a chrome concentration of 37 to 61 wt %) show no corrosion. These results indicate that a thicker alloy layer with a higher chrome concentration provides higher corrosion resistance. Also, the alloy layer with a controlled thickness will improve the corrosion resistance without degrading the magnetic properties, although the coating uses Cr, which is an antiferromagnetic substance, instead of Ni, which is a ferromagnetic substance.
Results of Wear Resistance Test
Although the wear resistance in comparative example 1 is lower than that of the Ni-plated product of comparative example 3, the wear resistance in examples 1 to 5 and comparative example 2 is equivalent to or exceeds the wear resistance in comparative example 3. In particular, examples 3 to 5 with a high Vickers hardness shows almost no wear.
Results of Wear Resistance Test
Although the use of chrome, which is an antiferromagnetic material, for forming the alloy layer could lower the magnetic properties, the attraction force in comparative examples 1 and 2 and examples 1 to 5 is higher than or equivalent to that obtained in comparative example 3 when the alloy layer has a thickness of not more than 60 μm as shown in Table 1. However, the attraction force in comparative example 2 (with an alloy layer thickness of 80 μm) is too low to use this test piece for a magnetic component.
Results of Coercive Force Test
In the coercive force test, the coercive force obtained in comparative example 1 and examples 1 to 5 is equivalent to or better than that of comparative example 3 shown in Table 1 when the alloy layer has a thickness of not more than 50 μm. When the coercive force is within the range of +10 Nm from the coercive force of comparative example 3, the test piece is determined usable for a magnetic component. The coercive force in comparative example 2 (with an alloy layer thickness of 80 μm) is too poor to use this test piece for a magnetic component.
With the heating temperature (800 to 900° C.) and the treatment time (15 to 30 minutes) used conventionally for Ni-plating to improve the magnetic properties, the ferritic grain size of the base material is not less than 2 defined in JIS G0551 (2005) (not more than about 32 crystal grains per square millimeter of the cross-section: refer to
The alloy layer having a thickness of not more than 60 μm (examples 1 to 5 and comparative example 1) provides good magnetic properties when the ferritic grain size is not more than −1. For the alloy layer having a thickness reaching 80 μm (comparative example 2), the magnetic properties deteriorate even with the diffusion-coating process performed under the heating conditions that can maximize the grain size of the base material, or specifically at 1000° C. for 10 hours.
NSSMAG1 (soft magnetic stainless steel) (comparative examples 4 to 5) and SUYP (electromagnetic soft iron) (comparative example 6) also underwent the coercive force test described above. The results were compared with those of chromized SUYP (examples 1 to 5 and comparative examples 1 and 2) and Ni-plated SUYP (comparative example 3). Table 2 shows the test results.
As shown in Table 2, the coercive force value is larger for comparative example 3 with Ni-plating than for comparative example 6 with no Ni-plating. Among the examples using chromizing, the coercive force of examples 1 and 2 is better than that of comparative examples 4 and 5, in which the test pieces contain chrome uniformly.
A yoke prepared by processing low-carbon steel (SPCC with a carbon content of 0.01 wt %) (with maximum lengths of 22 mm in z-direction and 11 mm in x-direction and a width, or length in y-direction, of 11.5 mm in
The resultant yoke includes an alloy layer with a thickness of 15 μm and a surface chrome concentration of 30%.
The yoke then underwent the tests for the magnetic properties (the attraction force test and the coercive force test), the corrosion resistance test, and the wear resistance test in the same manner as in example 1. Like the conventional Ni-plated product (comparative example 3), this yoke has good magnetic properties. The corroded area in this yoke determined in the corrosion resistance test is 10 to 20%, which is lower than in comparative example 3 (40 to 50%), demonstrating the advantageous effect of the present invention. In the wear resistance test, the yoke was mounted on a relay, and the relay was open and closed 20 million times. After this wear resistance test, the sliding surface of the yoke showed almost no wear, indicating good resistance.
A yoke prepared by processing low-carbon steel (SPCC with a carbon content of 0.01 wt %) (with maximum lengths of 22 mm in z-direction and 11 mm in x-direction and a width, or length in y-direction, of 11.5 mm in
The resultant yoke includes an alloy layer with a thickness of 20 μm and a surface vanadium concentration of 49%.
The yoke then underwent the magnetic properties tests, the corrosion resistance test, and the wear resistance test in the same manner as in example 1. This yoke has good magnetic properties, like in comparative example 3. In the corrosion resistance, no corrosion was observed. This shows corrosion resistance far higher than that of comparative example 3 (40 to 50%), demonstrating the advantageous effect of the present invention. In the wear resistance test, the yoke was mounted on a relay, and the relay was open and closed 20 million times. After this wear resistance test, the sliding surface of the yoke showed almost no wear, indicating high wear resistance.
A yoke prepared by processing low-carbon steel (SPCC with a carbon content of 0.01 wt %) (with maximum lengths of 22 mm in z-direction and 11 mm in x-direction and a width, or length in y-direction, of 11.5 mm in
The resultant yoke includes an alloy layer having a thickness of 30 μm and a surface aluminum concentration of 33%.
The yoke then underwent the magnetic properties tests, the corrosion resistance test, and the wear resistance test in the same manner as in example 1. This yoke has good magnetic properties, like in comparative example 3. In the corrosion resistance, no corrosion was observed. This shows corrosion resistance far higher than that of comparative example 3 (40 to 50%), demonstrating the advantageous effect of the present invention. In the wear resistance test, the yoke was mounted on a relay, and the relay was open and closed 20 million times. After this wear resistance test, the sliding surface of the yoke showed almost no wear, indicating high wear resistance.
A yoke prepared by processing low-carbon steel (SPCC with a carbon content of 0.01 wt %) (with maximum lengths of 22 mm in z-direction and 11 mm in x-direction and a width, or length in y-direction, of 11.5 mm in
The resultant yoke includes an alloy layer having a thickness of 15 μm, a surface hardness of 270 mHv, and a surface chrome concentration of 33%.
The yoke then underwent the tests for the magnetic properties (the attraction force test and the coercive force test), the corrosion resistance test, and the wear resistance test in the same manner as in example 1. Like the conventional Ni-plated product (comparative example 3), this yoke has good magnetic properties. The corroded area in this yoke determined in the corrosion resistance test is 10 to 20%, which is lower than in comparative example 3 (40 to 50%), demonstrating the advantageous effect of the present invention. In the wear resistance test, the yoke was mounted on a relay, and the relay was open and closed 20 million times. After this wear resistance test, the sliding surface of the yoke showed almost no wear, indicating good resistance.
An iron piece prepared by processing low-carbon steel (SPCC with a carbon content of 0.12 wt %) (with maximum lengths of 13.5 mm in x-direction and 8.5 mm in z-direction and a width, or length in y-direction, of 11.5 mm in
The resultant iron piece has an alloy layer having a thickness of 29 μm, a surface hardness of 310 mHv, and a surface chrome concentration of 42%.
The iron piece then underwent the tests for the magnetic properties (the attraction force test and the coercive force test), the corrosion resistance test, and the wear resistance test in the same manner as in example 1. Like the conventional Ni-plated product (comparative example 3), the iron piece has good magnetic properties. In the corrosion resistance test, no corrosion was observed. This shows corrosion resistance far higher than that of comparative example 3 (40 to 50%), demonstrating the advantageous effect of the present invention. In the wear resistance test, the iron piece was mounted on a relay, and the relay was open and closed 20 million times. After this wear resistance test, the sliding surface of the iron piece showed almost no wear, indicating high wear resistance.
An iron core prepared by processing low-carbon steel (SPCC with a carbon content of 0.07 wt %) (with a diameter of φ7 mm and a maximum length of 20.5 mm) underwent the diffusion-coating process under the conditions below:
The resultant iron core has an alloy layer having a thickness of 38 μm, a surface hardness of 360 mHv, and a surface chrome concentration of 49%.
The iron core then underwent the tests for the magnetic properties (the attraction force test and the coercive force test), the corrosion resistance test, and the wear resistance test in the same manner as in example 1. Like the conventional Ni-plated product (comparative example 3), this iron core has good magnetic properties. The corroded area in this iron core determined in the corrosion resistance test is 10 to 20%. This shows corrosion resistance far higher than that of comparative example 3 (40 to 50%), demonstrating the advantageous effect of the present invention. In the wear resistance test, the iron core was mounted on a relay, and the relay was open and closed 20 million times. After this wear resistance test, the sliding surface of the iron core showed almost no wear, indicating high wear resistance.
An iron core prepared by processing low-carbon steel (SPCC with a carbon content of 0.01 wt %) (with a diameter of φ7 mm and a maximum length of 20.5 mm) underwent the diffusion-coating process under the conditions described below:
The resultant iron core has an alloy layer having a thickness of 16 μm, a surface hardness of 410 mHv, and a surface vanadium concentration of 43%.
The iron core then underwent the magnetic properties tests, the corrosion resistance test, and the wear resistance test in the same manner as in example 1. This iron core has good magnetic properties, like in comparative example 3. In the corrosion resistance, no corrosion was observed. This shows corrosion resistance far higher than that of comparative example 3 (40 to 50%), demonstrating the advantageous effect of the present invention. In the wear resistance test, the iron core was mounted on a relay, and the relay was open and closed 20 million times. After this wear resistance test, the sliding surface of the iron core showed almost no wear, indicating high wear resistance.
An iron piece prepared by processing low-carbon steel (SPCC with a carbon content of 0.10 wt %) (with maximum lengths of 13.5 mm in x-direction and 8.5 mm in z-direction and a width, or length in the y-direction, of 11.5 mm in
The resultant iron piece has an alloy layer having a thickness of 31 μm, a surface hardness of 250 mHv, and a surface aluminum concentration of 29%.
The iron piece then underwent the tests for the magnetic properties, the corrosion resistance test, and the wear resistance test in the same manner as in example 1. The iron piece has good magnetic properties, like in comparative example 3. In the corrosion resistance test, no corrosion was observed. This shows corrosion resistance far higher than that of comparative example 3 (40 to 50%), demonstrating the advantageous effect of the present invention. In the wear resistance test, the iron piece was mounted on a relay, and the relay was open and closed 20 million times. After this wear resistance test, the sliding surface of the iron piece showed almost no wear, indicating high wear resistance.
The results in examples 6 to 13 indicate that the alloy layer with a controlled thickness will improve the corrosion resistance without degrading the magnetic properties when the coating uses Cr, V, or Al, which is either an antiferromagnetic substance, a diamagnetic or paramagnetic substance, instead of Ni, which is a ferromagnetic substance.
The metallic structure of the test pieces prepared by processing SPCC was observed. The test pieces used in example 14 and comparative examples 7 and 8 have a thickness of 1.2 mm. The test pieces used in example 15 and comparative examples 9 and 10 have a thickness of 1.6 mm. In examples 14 and 15, the test pieces were treated at 840° C. for 9 hours using a penetrant (40 wt % of chrome powder, 59.5 wt % of alumina powder, and 0.5 wt % of ammonium chloride powder) to form an alloy layer. In comparative examples 7 and 9, no heat treatment was performed. In comparative examples 8 to 10, heat treatment at 850° C. was performed. In comparative examples 7 to 10, no diffusion-coating nor Ni plating was performed.
Yokes prepared by processing pure iron underwent the salt-spray test in the same manner as in example 1. The yokes used in examples 16 to 19 were chromized using a penetrant (40 wt % of chrome powder, 59.5 wt % of alumina powder, and 0.5 wt % of ammonium chloride powder) with the treatment time of 8 hours at different treatment temperatures: 765° C. in example 16; 800° C. in example 17; 850° C. in example 18; and 950° C. in example 19. The yokes used in comparative example 11 were plated with Ni. Three yokes were prepared for each of the examples and the comparative examples.
For iron pieces and yokes prepared by processing SPCC, the corrosion resistance against nitric acid was examined. The iron pieces and the yokes used in example 20 were chromized using a penetrant (40 wt % of chrome powder, 59.5 wt % of alumina powder, and 0.5 wt % of ammonium chloride powder) at the treatment temperature of 860° C. for the treatment time of 9 hours. The iron pieces and the yokes used in comparative example 12 were plated with Ni. The iron piece and the yoke were mounted onto a relay, and the contact of the relay was opened and closed to generate arc heat, which then produced nitric acid gas inside the relay.
The present invention is applicable to electromagnetic relays that particularly need wear resistance, corrosion resistance, and magnetic properties.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2013-089831 | Apr 2013 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2013/070803 | 7/31/2013 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2014/174694 | 10/30/2014 | WO | A |
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| Number | Date | Country | |
|---|---|---|---|
| 20160086754 A1 | Mar 2016 | US |
