Electronic aerosol provision system and vaporizer therefor

Information

  • Patent Grant
  • 11744964
  • Patent Number
    11,744,964
  • Date Filed
    Tuesday, April 25, 2017
    7 years ago
  • Date Issued
    Tuesday, September 5, 2023
    8 months ago
Abstract
A sub-assembly for an electronic vapor provision system includes a source of liquid for vaporization; and a vaporizer for vaporizing a portion of the liquid for inhalation by a user, the vaporizer including a wick component; and an electrical heating element embedded in the wick component. The wick component includes a sheet of a porous electrically-insulating material and is arranged to wick liquid from the source of liquid to a surface of the wick component adjacent to the embedded electrical heating element for vaporization.
Description
PRIORITY CLAIM

The present application is a National Phase entry of PCT Application No. PCT/GB2017/051139, filed Apr. 25, 2017, which claims priority from U.K. Patent Application No. GB 1607322.3, filed Apr. 27, 2016, each of which is hereby fully incorporated herein by reference.


TECHNICAL FIELD

The present disclosure relates to aerosol provision systems and vaporizers for use in aerosol provision systems.


BACKGROUND

Vapor or aerosol provision systems and devices, such as electronic cigarettes, typically include a reservoir of a source liquid, perhaps including nicotine, and a heater or heating element powered by a battery which acts to vaporize the source liquid for inhalation by a user. A wick may be used to deliver source liquid to the heating element for the vaporization process. For example, the heating element may be a wire coil wrapped around a central wick.


An aim of these arrangements is to maximize the amount of vaporized source liquid delivered with each inhalation (puff). This can be achieved by increasing the heat output of the heating element so that more source liquid is vaporized during the duration of a puff. Reducing the electrical resistance of the heater, for example by using a lower resistance wire to form a heating element, allows more current to flow for a given battery voltage, thereby increasing the power consumed by the heater and generating more heat. This approach leads to particular challenges, however.


To lower the resistance one may increase the diameter of the heating wire. An increased amount of source liquid should be delivered by the wick to feed the higher vaporization rate enabled by the higher heater power; this requires a larger size of wick. These factors can reduce efficiency, however, because of heat conduction from the heater into the wick material, and the requirement to heat a larger mass of heater.


Also, achievable rates of vapor production may be limited by the speed at which vapor moves into the inhalable airstream. Vaporization of the source liquid occurs at the interface of the heater and the wick. With a central wick inside a heater coil, the vapor has to travel from the interface out beyond the heater surface to be collected for inhalation. A reduced heater resistance to increase the power combined with the limited interface area may create a vaporization so intense that the vapor cannot escape quickly enough and instead forms pockets at the interface that impede liquid contact with the heater. This reduces the efficiency of vapor production, causing the heater temperature to rise because the power is not being utilized for vaporization. This can degrade the quality of the vapor and may lead to undesirable by-products.


SUMMARY

Alternative wick and heater arrangements are therefore of interest.


According to a first aspect of some embodiments described herein, there is provided a sub-assembly for an electronic vapor provision system comprising: a source of liquid for vaporization; and a vaporizer for vaporizing a portion of the liquid for inhalation by a user, the vaporizer comprising: a wick component; and an electrical heating element embedded in the wick component; wherein the wick component comprises a sheet of a porous electrically-insulating material and is arranged to wick liquid from the source of liquid to a surface of the wick component adjacent to the embedded electrical heating element for vaporization.


The porous electrically-insulating material may comprise a porous ceramic. The wick component may have a porosity in the range of 30% to 85%, and may have a thickness at least 50 times less than a longest dimension of the wick component.


The heating element may have an embedded shape including one or more bends and a length embedded in the wick component of between 2 and 20 times the longest dimension of the wick component. The one or more bends may define adjacent portions of the heating element that have a centre-to-centre spacing not greater than twice an embedded width of the heating element. The thickness of the wick component may be in the range of 105% to 250% of an embedded width of the heating element. The heating element may be embedded substantially centrally with respect to the thickness of the wick component. The heating element may comprise a metallic wire.


The wick component may be substantially planar. The vaporizer may be supported in a vaporization chamber by one or more parts of the wick component passing through apertures in one or more walls of the vaporization chamber to extend into the source of liquid. One or more parts of the wick component that pass through apertures in one or more walls of the vaporization chamber may be at opposite sides of the wick component. The vaporizer may be supported in the vaporization chamber such that a thinnest profile of the wick component is presented to a direction of airflow through the vaporization chamber. The source of liquid may comprise a reservoir having an annular shape and surrounding the vaporization chamber. The wall of the vaporization chamber may also be an inner wall of the reservoir.


The sub-assembly may be a cartomizer for an electronic vapor provision system.


According to a second aspect of some embodiments described herein, there is provided an electronic vapor provision system comprising a sub-assembly according to the first aspect.


According to a third aspect of some embodiments described herein, there is provided a method of making a vaporizer for an electronic vapor provision system, the method comprising: forming an electrically conductive heating element; arranging powdered ceramic material around the heating element in a desired shape for a wick component; and sintering the ceramic material to form a porous ceramic wick component with the heating element embedded therein.


According to a fourth aspect of some embodiments described herein, there is provided a method of making a vaporizer for an electronic vapor provision system comprising: forming an electrically conductive heating element; arranging the heating element between a first layer and a second layer of sheet porous electrically-insulating material; and bonding the first layer and the second layer together to form a porous wick component with the heating element embedded therein.


In the method aspects, forming the conductive heating element may comprise shaping a metallic wire or depositing a conductive ink into a path with one or more bends, and a length between 2 and 30 times the intended longest dimension of the wick component. The one or more bends may define adjacent portions of the wire that have a centre-to-centre spacing not greater than twice a width of the wire. The methods may further comprise mounting the completed vaporizer in a vaporization chamber by passing one or more edges of the wick component through one or more apertures in a wall of a vaporization chamber.


According to a fifth aspect of some embodiments described herein, there is provided an electronic vapor provision device including a reservoir for source liquid and a vaporization chamber adjacent the reservoir in which source liquid can be vaporized, the vaporization chamber housing a vaporizer comprising: a porous ceramic wick component; and a metallic heater element embedded in the wick component and connectable to a battery in the electronic vapor provision device; wherein two ends of the wick component pass through apertures in walls of the vaporization chamber to suspend the vaporizer across the vaporization chamber, the two ends penetrating into the reservoir to absorb source liquid and transport it to the heating element by capillary action through pores in the wick component.


These and further aspects of certain embodiments are set out in the appended independent and dependent claims. It will be appreciated that features of the dependent claims may be combined with each other and features of the independent claims in combinations other than those explicitly set out in the claims. Furthermore, the approach described herein is not restricted to specific embodiments such as set out below, but includes and contemplates any appropriate combinations of features presented herein. For example, an electronic cigarette, a sub-assembly or a vaporizer may be provided in accordance with approaches described herein which includes any one or more of the various features described below as appropriate.





BRIEF DESCRIPTION OF THE DRAWINGS

Various embodiments will now be described in detail by way of example only with reference to the accompanying drawings in which:



FIG. 1 shows a schematic representation of an electronic cigarette with which a vaporizer according to embodiments of the disclosure may be used.



FIG. 2 shows a perspective view of an example vaporizer.



FIG. 3 shows a cross-sectional view through the example vaporizer of FIG. 2.



FIGS. 4a, 4b and 4c show schematic plan views of further example vaporizers.



FIG. 5A shows a perspective exploded side view of an example vaporization chamber having a vaporizer.



FIG. 5B shows an end view of the vaporization chamber of FIG. 5A.



FIG. 6A shows a perspective exploded side view of a vapor source comprising the vaporization chamber of FIG. 5A.



FIG. 6B shows a perspective side view of the vapor source of FIG. 6A.



FIG. 7 shows a schematic side view of a further example vaporization chamber.



FIG. 8 shows a schematic side view of a yet further example vaporization chamber.





DETAILED DESCRIPTION

Aspects and features of certain examples and embodiments are discussed/described herein. Some aspects and features of certain examples and embodiments may be implemented conventionally and these are not discussed/described in detail in the interests of brevity. It will thus be appreciated that aspects and features of apparatus and methods discussed herein which are not described in detail may be implemented in accordance with any conventional techniques for implementing such aspects and features.


The present disclosure relates to aerosol provision systems, also referred to as vapor provision systems, such as e-cigarettes. Throughout the following description the term “e-cigarette” or “electronic cigarette” may sometimes be used; however, it will be appreciated this term may be used interchangeably with aerosol (vapor) provision system or device.



FIG. 1 is a highly schematic diagram (not to scale) of an example aerosol/vapor provision system such as an e-cigarette 10 to which embodiments are applicable. The e-cigarette 10 has a generally cylindrical shape, extending along a longitudinal axis indicated by a dashed line (although aspects of the disclosure are applicable to e-cigarettes configured in other shapes and arrangements), and comprises two main components, namely a body 20 and a cartridge assembly 30.


The cartridge assembly 30 includes a reservoir or source of liquid 38 containing a source liquid comprising a liquid formulation from which an aerosol is to be generated, for example containing nicotine, and a heating element or heater 36 for heating source liquid to generate the aerosol. A wicking element or component or wick 37 is provided to deliver source liquid from the reservoir 38 to the heating element 36. A part or parts of the wick 37 are in fluid communication with source liquid in the reservoir 38 and by a wicking or capillary action source liquid is drawn along or through the wick 37 to a part or parts of the wick 37 which are in contact with the heater 36. Vaporization of the source liquid occurs at the interface between the wick 37 and the heater 36 by the provision of heat energy to the source liquid to cause evaporation, thus generating the aerosol. The source liquid, the wick 37 and the heater 36 may be collectively referred to as an aerosol or vapor source. The wick 37 and the heater 36 may be collectively referred to as a vaporizer or an atomizer 15. An atomizer/vaporizer may be arranged in a chamber or housing which is substantially sealed from the reservoir of source liquid to prevent or limit leakage of the source liquid into the chamber. The wick is the intended path for liquid from the reservoir to the heater. The inclusion of the vaporizer/atomizer within the cartridge assembly leads to the term “cartomizer” which is sometimes applied to this component of an electronic cigarette.


The cartridge assembly 30 further includes a mouthpiece 35 having an opening through which a user may inhale the aerosol generated by the vaporizer 15. The aerosol for inhalation may be described as an aerosol stream or inhalable airstream. As an example, the source liquid may comprise around 1 to 3% nicotine and 50% glycerol, with the remainder comprising roughly equal measures of water and propylene glycol, and possibly also comprising other components.


The body 20 includes a re-chargeable cell or battery 14 (referred to herein after as a battery) to provide power for the e-cigarette 10, and a printed circuit board (PCB) 28 and/or other electronics for generally controlling the e-cigarette 10. The body can therefore also be considered as a battery section, or a control unit or section. In use, when the heater 36 receives power from the battery 14, as controlled by the circuit board 28 possibly in response to pressure changes detected by an air pressure sensor (not shown), the heater 36 vaporizes source liquid delivered by the wick 37 to generate the aerosol, and this aerosol stream is then inhaled by a user through the opening in the mouthpiece 35. The aerosol is carried from the aerosol source to the mouthpiece 35 along an air channel (not shown in FIG. 1) that connects the aerosol source to the mouthpiece opening as a user inhales on the mouthpiece. To this end, the vaporizer 15 may be accommodated in a vaporizer chamber (not shown) that is comprised within, or otherwise connected to, an airflow pathway through the e-cigarette 10.


In this particular example, the body 20 and cartridge assembly 30 are detachable from one another by separation in a direction parallel to the longitudinal axis, as shown in FIG. 1, but are joined together when the device 10 is in use by cooperating engagement elements 21, 31 (for example, a screw or bayonet fitting) to provide mechanical and electrical connectivity between the body 20 and the cartridge assembly 30, in particular connecting the heater 36 to the battery 14. An electrical connector interface on the body 20 used to connect to the cartridge assembly 30 may also serve as an interface for connecting the body 20 to a charging device (not shown) when the body 20 is detached from the cartridge assembly 30. The other end of the charging device can be plugged into an external power supply, for example a USB socket, to charge or to re-charge the battery 14 in the body 20 of the e-cigarette. In other implementations, a separate charging interface may be provided, for example so the battery 14 can be charged when still connected to the cartridge assembly 30.


The e-cigarette 10 is provided with one or more holes (not shown in FIG. 1) for air intake, indicated by the arrows A. These holes, which are in an outer wall of the body 20 (but which in other examples may be in an outer wall of the cartridge assembly 30), connect to an airflow path through the e-cigarette 10 to the mouthpiece 35. The airflow path may include a pressure sensing region (not shown in FIG. 1) in the body 20, and then connects from the body 20 into cartridge assembly 30 to a region (such as the vaporizer chamber) around the heating element 36 so that when a user inhales through the mouthpiece 35, air is drawn into the airflow path through the one or more air inlet holes. This airflow (or the resulting change in pressure) is detected by a pressure sensor (not shown in FIG. 1) in communication with the airflow path that in turn activates the heater 36 (via operation of the circuit board 28) to vaporize a portion of the source liquid at the wick-heater interface to generate the aerosol. The airflow passes through the airflow path, and combines with the vapor in the region around the heater 36, and the resulting aerosol (combination of airflow and condensed vapor) travels as an aerosol stream along the airflow path connecting from the region of the heater 36 to the mouthpiece 35 to be inhaled by a user.


In some examples, the detachable cartridge assembly 30 may be disposed of when the supply of source liquid is exhausted, and replaced with another cartridge assembly if so desired. In other examples the reservoir may be refillable with more source liquid. The body 20 may be intended to be reusable by recharging of the battery, for example to provide operation for a year or more by connection to a series of disposable detachable cartridges assemblies. In other examples, both the cartridge assembly 30 and the body 20 may be disposable, and may not be detachable from each other. Also, the various components may be located differently from the FIG. 1 example, and the cartridge assembly 30 and the body 20 may be connectable in a different configuration such as a side-by-side arrangement instead of the longitudinal arrangement of FIG. 1. Embodiments of the disclosure are applicable to these and other various alternatives.


According to embodiments of the disclosure, it is proposed to configure the vaporizer (atomizer) by embedding the heating element inside a porous wick component.



FIG. 2 shows a perspective view of a vaporizer 15 according to a first example embodiment. The wick or wicking element or component 37 is a thin flat planar substrate of an electrically-insulating porous material such as porous ceramic, having a thickness t, a length l and a width w. Embedded within the wick 37 is a heating element 36 in the form of a conductive (metallic) wire 39. This is shown in a phantom dotted line to indicate its position inside the wick. Each end 36a of the heating element 36 terminates at an edge of the wick 37 in a connecting lead 40 by means of which the heating element 36 can be connected (typically via an arrangement of contacts and other electrical wires and connections, and under control of a PCB or other control electronics) to an electrical power supply within an e-cigarette, such as the battery 14 in FIG. 1. The leads 40 and the wire 39 can be formed from a single length of wire, or may be separately fabricated and then connected for example by welding (such as for ease of fabrication or to utilize particular properties of different wires).


The heating element wire 39 is formed into a serpentine or zigzag shape between its two ends 36a. The wire formation occupies a single plane which is arranged substantially mid-way through the thickness t of the wick 37 so as to be substantially equidistant from the upper 37a and lower 37b (with reference to the illustrated orientation) surfaces of the wick 37 (main surfaces). In this way, heat from the heating element 36 when powered by electric current can be delivered roughly equally to each main surface 37a, 37b. If the zig-zags or adjacent turns of the wire 39 are closely spaced so that all parts of the wick substrate are relatively close to part of the wire, heat can be delivered rapidly to all parts of the wick. A larger spacing between wire turns may lead to a wasted volume of wick material that takes up heat energy but does not attain a sufficient temperature for vaporization.



FIG. 3 shows a cross-sectional view through the vaporizer of FIG. 2, along the line III. From this, the dense packing of the adjacent sections of the wire 39 inside the volume of the wick 37 is apparent. The wire 39 occupies a substantial proportion of the total volume of the vaporizer. Adjacent portions of the wire are separated by a distance d2 less than the width d1 (diameter) of the wire. Hence, the center-to-center spacing d3 between adjacent wire portions is less than twice the wire width (2×d1). Also, the depth or thickness d4 of wick material between the main surfaces and the wire surface is less than the width of the wire d1. This thickness can be chosen having regard to the vaporization rate; if there is too great a depth of wick material vaporization will be impeded and insufficient vapor will escape from the wick surface. The disclosure is not limited to the above proportions, however, and greater or lesser size ratios may be used. The relative volumes and dimensions of the heater and the wick, the depth of wick material overlying the heater wire and the porosity of the wick material can be variously selected to deliver a sufficient volume of source liquid to feed the available vaporization rate while also allowing the vapor to escape from the wick material at a fast enough rate. For example, the embedded heater may have a volume that is at least 50% of the combined volume of the embedded heater and the wick (defined by the outer dimensions of the wick element), or between 40% and 60%, or between 30% and 70%. Alternatively, the combined volume may be confined to a zone of the wick over which the heater extends, for example a central zone or an end zone, with a relatively large further amount of the wick extending beyond this zone such as to ensure a significant wick volume reaching into a reservoir, or to reach the walls of the vaporization chamber if it is desired for vaporization to be kept remote from the walls. The part of the wick within which the heater is embedded (the combined volume) can be considered as a heating zone, where all or most of the vaporization occurs. The heating zone may comprise all or most of the wick, or just a part of it.


In this example the wick 37 is formed from a rigid porous ceramic material. The pores of the ceramic allow a wicking action so that when part of the wick is placed in fluid communication with a source liquid reservoir, source liquid in the reservoir is drawn through the pores to the wire 39. When the heater 37 is activated, heat is transferred to source liquid in direct contact with the wire 39 and also via intervening wick material. The resulting vapor passes through the pores to the wick surfaces 37a, 37b and out into the surrounding air to be collected by air flowing in the airflow path.


The wire 39 is embedded within the wick substrate 37. By “embedded” is meant that the material of the wick wholly covers and is in contact with substantially all the outer surface of the wire within the volume of the wick (subject to gaps where pores in the wick material are immediately adjacent to the wire). At each axial cross-sectional position along the wire, the porous ceramic material is in contact with the wire around its full circumference; the wire is wholly enveloped in the wick material. This contact between the wire and the wick is the interface at which the majority of the vapor formation happens, so an embedded configuration maximizes the interface area for a given length of wire, and greatly increases the interface area compared with vaporizer arrangements in which a coiled heater wire is wrapped around a central wick, for example. A thinner wire with more turns or bends (to increase the length) might provide a larger interface area but this may need to be balanced against the beneficial lower resistance and higher power output of a thicker wire.


Although a fully embedded arrangement in which the wick material covers the wire completely gives a maximum vaporization interface, a partially embedded configuration in which the heating element is at least partly exposed at one or both main surfaces of the wick substrate might be considered useful in some circumstances.


The heating element in the form of a wire 39 can be fabricated in any shape between the two ends 36a. A shape which maximizes the length of the wire that can be accommodated within the wick volume gives a largest vaporization interface; this might be achieved by any convoluted path between the two ends. Such a path has a non-linear shape. For example, the shape may be an angular or a curved serpentine shape, an angular or curved zig-zag, or an angular or curved spiral, and the shape may be regular (repeating) or irregular. Incorporation of a plurality of turns, bends or corners into the shape will increase the available length. In some embodiments, the embedded conductive length of the heating element between its two ends is several or many times the longest dimension of wick element, achieved by including a plurality of turns, bends, corners or folds along the length in the heating element. For example, the heating element may have a length which is between 2 and 20 times or between 5 and 10 times the length of the longest dimension (edge) of the wick element. The two ends may be located at edge surfaces of the wick (the same edge, as in FIG. 2, or different edges) or on one or both main surfaces (which may be convenient for a spiral or other shape where the heating element terminates away from a wick edge). The adjacent lengths of the wire may be as closely spaced as is conveniently achievable with the chosen manufacturing process and materials for fabricating the vaporizer, to maximize the length of useable wire. However, care should be taken that no parts of the wire are touching each other within the wick, so as to avoid an electrical short circuit. A complex shape is not essential, though, and the wire may be substantially straight (linear) or gently curving between its two ends if this is deemed to deliver sufficient heating power, or if an elongate wick is preferred. This might provide a heating element that is between 1 and 2 times the length of the wick's longest side, for example.



FIGS. 4a, 4b and 4c show schematic plan views of various examples of vaporizers with differently shaped heating element wires. The example of FIG. 4a has a square wick element 37 and a heating wire 39 arranged as a double spiral so that both ends 36a can be located at the same edge of the wick. The connecting leads are omitted for simplicity. The example of FIG. 4b has a rectangular wick element 37 and a heating wire 39 in an angular, cornered, shape that is folded back on itself a plurality of times. The ends 36a are on different edges of the wick 37. The example of FIG. 4c shows a highly linear wick element 37, having a length many times greater than its width, and a heating wire 39 configured as a simple straight line between its two ends 36a at opposite short edges of the wick 37.


The heating element need not be formed from conductive wire (such as by bending). An appropriate shape that provides a conductive path of the desired length might be stamped, cut or pressed out of sheet metal, or a metallic ribbon (rather than a wire) might be bent into a suitable shape, for example.


Suitable conductive materials for the heating element include any resistive metal, for example nichrome, steel, titanium or other metals and metal alloys. Other materials may also be used, such as conductive ink (non-metal or metal based), printed, drawn or deposited along a suitably shaped path.


The wick element may have various properties. It is formed from a porous material to enable the required wicking or capillary effect for drawing source liquid through it from a source liquid reservoir (where the wick meets the source liquid at a reservoir contact site) to the vaporization interface. Porosity is typically provided by a plurality of interconnected or partially interconnected pores (holes or interstices) throughout the material, and open to the outer surface of the material. Any level of porosity may be employed depending on the material, the size of the pores and the required rate of wicking. For example a porosity of between 30% and 85% might be selected, such as between 40% and 70%, between 50% and 80%, between 35% and 75% or between 40% and 75%. This might be an average porosity value for the whole wick element, since porosity may or may not be uniform across the wick. For example, pore size at the reservoir contact site might be different from pore size nearer to the heater.


The wick element has a substantially thin flat shape. For example it may be considered as a sheet, layer, film, substrate or the like. By this it is meant that a thickness of the wick (the dimension tin FIG. 2) is less or very much less than at least one of the length (1 in FIG. 2) and the width (w in FIG. 2) of the wick. Thus, the wick thickness (its smallest dimension) is less or very much less than the longest dimension. This enables the heating element to be close to the main surfaces of the wick, with the depth of overlying wick material being slight. The thickness may or may not be substantially uniform. For example, the wicking rate may be modified by a reduced or increased thickness at the reservoir contact site compared with the remainder of the wick. The wick may be planar, as in FIGS. 2 and 3, but its shape is not limited in this regard. The “flat” characteristic is intended to have a topological definition, in that the wick may form a curved surface such a cylinder (tube), a trough or a segment of a spherical surface or other dish-like form. The thickness of the wick may, for example, be in the range of 105% to 250% of the thickness of the heater element (the diameter of a wire used as the heater element, for example), such as between 105% and 200%, or 105% and 150%, or 110% and 200%, or 110% and 150%, or 120% and 200%, or 120% and 150%. The thickness of the wick may, for example, be in the range 50 to 200 times less than the longest dimension of the wick (typically the length). For example the length l might be 50 to 150 times the thickness t, or 50 to 100 times, or 50 to 150 times, or 100 to 150 times, or 100 to 200 times. As an example, the wick might be rectangular with a length l in the range 5 mm to 15 mm, a width w in the range 5 mm to 15 mm, and a thickness t somewhat in excess of a wire thickness of 0.1 mm, such as 0.12 mm to 0.2 mm. The disclosure is not limited in this regard, however, and other dimensions, shapes and proportions of the wick may be used.


It is useful for the wick to have sufficient rigidity to support itself in a required position within the vapor source. For example, it may be mounted at or near one or two edges and be required to maintain its position substantially without flexing, bending or sagging. The rigidity may arise from the wick material in the selected wick thickness (so that an appropriate thickness is used to provide this characteristic), and where the wick is able also to support the heater embedded in it. In other examples, some structural rigidity may be derived from the heater itself, so that the heater aids in supporting the mounted wick in its required position. The overall rigidity of the wick and heating element combination may be relied upon, or the rigidity of the wick alone. The term rigid is considered to imply that the wick or vaporizer is substantially non-flexible or non-pliant.


As an example, porous ceramic is a useful material to use as the wick element. Any ceramic with appropriate porosity may be used. However, the disclosure is not so limited, and any electrically-insulating material having the same or similar properties or characteristics might be used. In general, the porous material should be considered as a “solid” or “hard” material, in contrast to “soft” fabric and fibrous materials, such as cotton and other fibers which are often used in the art as wicks and to absorb stores of source liquid in place of a reservoir of free-flowing liquid. In this context, the solid wick material is substantially non-compressible.


A vaporizer of the kind described herein may be fabricated in a straightforward manner. If porous ceramic is chosen as the porous wick material, this is available as a powder which can be formed into a solid by sintering (heating to cause coalescence, possibly under applied pressure). Thus, the heating element can be fabricated first (bending a wire into the appropriate shape, for example), and the ceramic powder can be arranged around the heating element in the desired shape, such as by filling a mould that has the heating element suspended or otherwise arranged inside it. Sintering then solidifies the ceramic to create the porous wick, with the heating element embedded in it. Fabricating the vaporizer in this way, by forming and shaping the wick element from wick material around the heating element, achieves the required embedded arrangement, giving close contact between the heating element and the wick at the vaporization interface.


Alternatively, the vaporizer may be formed from two separate layers of wick material with the heating element sandwiched between the two layers. After stacking the layers, the wick layers may be secured around the heating element by gluing, welding or other bonding methods, according to what is appropriate to the chosen wick material. The wick layers may be the same thickness, or different thicknesses. The heating element may be preformed to the desired shape, as mentioned above, or in the case of conductive ink, can be drawn or printed onto the surface of one wick layer before bonding the second wick layer on top.


A vaporizer in accordance with aspects of the disclosure may be used in conjunction with a reservoir of free flowing source liquid (although it may be combined with a reservoir of the type that is formed from a soft porous material such as cotton which is soaked with source liquid). It is envisaged that the vaporizer will be housed inside a vaporizer chamber which communicates with or forms part of the airflow channel through an electronic cigarette but which is substantially sealed against the ingress of free source liquid from an adjacent reservoir. The wick of the vaporizer forms the path for source liquid to enter the vaporizer chamber; this is achieved by arranging that a part of the wick (one or more edges, for example) extends through a wall of the chamber into the reservoir. A seal can be arranged around the wick where it traverses the wall, to limit leakage into the chamber. The part of the wick including the embedded heating element lies inside the chamber so that air flowing along the airflow channel can pick up vaporized source liquid given off from the vaporizer when the heating element is activated (electrical current is passed through it).



FIG. 5A shows a perspective side view of an example vaporization chamber 50. The chamber 50 has walls defined by a hollow tube 52 (cylindrical in this example, but other cross-sectional shapes may be used if preferred). The tube 52 is part of the air flow path through the electronic cigarette, and the aerosol stream carrying the vaporized source liquid exits the end of the tube as shown by the arrow A, to enter a next part of the air flow path for travel to the electronic cigarette's mouthpiece (not shown). At its lower end (as illustrated) the tube 52 is sealable by being joined to base portion 54 (indicated by the small arrow). The base portion 54 has a screw thread connector 56 for mechanical and electrical connection to a battery section (not shown). The base portion 54 has an air inlet 58 by which air is drawn into the vaporization chamber 50 when a user inhales on the electronic cigarette. One or more air inlets 58 may be provided, possibly in locations other than on a separate base portion 54, and they may be provided with an adjustment mechanism to deliver variable ventilation into the electronic cigarette. The base portion 54 need not be separate from the tube 52; the two components may be formed integrally.


A vaporizer 15 according to aspects of the disclosure is disposed inside the vaporization chamber 50. The wick element of the vaporizer 15 has an elongate shape (a rectangle in this example) which is longer than the width (diameter) of the tube 52. Thus, the wick extends across the full width of the tube and beyond, so that opposite end portions 16 of the wick pass through the tube walls in a sealed configuration and lie outside the vaporization chamber 50. The vaporizer is thus suspended across the vaporization chamber. One end portion 16 can be seen in FIG. 5A protruding from the chamber wall. Electrical connection leads 40 are connected to the heating element at parts of the wick inside the chamber, so that they can be connected appropriately in the base portion 54 to receive current from a battery via the screw thread connector 56. In this way, air drawn in through the air inlet 58 passes over and past the vaporizer 15 as it travels along the tube 52, thereby collecting vapor to form the aerosol stream.



FIG. 5B shows a view of the vaporization chamber looking into the tube 52 along its length. The vaporizer 15 can be seen mounted through opposite apertures in the tube walls such that its central part 17 is inside the chamber, extending fully across the tube 52, and its opposite ends 16 are outside the chamber. In an example, the protruding end portions have a protruding length of up to 2 mm, for example between 1 and 2 mm.


The ends of the wick are arranged to protrude through the walls of vaporization chamber so that they can carry source liquid to the heating element. This is achieved by locating a reservoir for the source liquid externally to the vaporization chamber.



FIG. 6A shows a perspective view of parts of a vapor source comprising a reservoir, and the vaporization chamber 50 and vaporizer 15 of FIG. 5A. An outer tube 60 of larger width (diameter) than the tube 52 forming the vaporization chamber walls is provided, and is sized to fit over and around the tube 52 as shown by the arrow, leaving an annular space between the inside of the outer tube 60 and the outside of the inner tube 52. The outer tube 60 may or may not form part of the outer surface of the electronic cigarette. The outer tube 60 connects to the vaporizer base portion 54 which acts to seal a first (lower, as illustrated) end of the annular space. The outer tube 60 is closed at its second (upper, as illustrated) end by a top wall 61, through which extends an outlet tube 62 which is in airflow communication with the interior of the inner tube 52 to enable the aerosol stream to leave the vaporization chamber. The outlet tube 62 may form the mouthpiece of the electronic cigarette, or may be an intermediate section of the air flow path that leads towards the mouthpiece.


The annular space defined between the outer tube 60 and the inner tube 52 is sealed to make it substantially leak-proof. It forms a reservoir for free-flowing source liquid, which can exit the reservoir only via capillary action along the wick of the vaporizer 15 (assuming no accidental or unintended leaks). The protruding ends 16 of the wick lie inside the reservoir, and hence absorb source liquid that is stored in the reservoir.



FIG. 6B shows a perspective view the vapor source of FIG. 6A in assembled form, when the outer tube 60 has been placed over the inner tube 52 and connected to the base 54, thereby defining the reservoir 64 in the intervening annular space. In this example the outer tube 60 forms the outside of the electronic cigarette and is made from a transparent material, and the inner tube 52 and vaporizer 15 are visible through it. This feature allows visibility of source liquid in the reservoir also, so a user can determine how much source liquid there is. In other examples the outer tube 60 can be made from opaque material, and/or may have a casing around it, so that the reservoir contents cannot be seen.


The FIGS. 6A and 6B device is merely an example, and the vaporizer may be mounted in a vaporization chamber in any way that allows at least one part of it to reach into a reservoir to wick source liquid. The wick may extend wholly or partly across the vaporization chamber. Either ends or edges (one or more) may extend through the chamber wall(s). Opposite ends or edges or adjacent ends or edges may be used for this. The extension through the wall(s) conveniently provides support for the vaporizer, and its level of rigidity may determine how much or many of its edges should be used in this way. Also, the rate at which source liquid needs to be transferred by the wick from the reservoir to the heating element will determine what proportion of the wick should extend into the reservoir. Two or more opposite or non-adjacent ends or edge parts may be considered useful since this increases the likelihood of contact between the wick and source liquid when the reservoir is partially empty, for example when the electronic cigarette is held at an angle. The vaporizer may be mounted so that the plane of the wick is orthogonal to the main air flow direction through the vaporization chamber (as in FIGS. 5A, B and 6A, B). Alternatively, it may be mounted with its plane parallel to the air flow direction (imagine the vaporizer for FIG. 5A rotated 90 degrees about its longitudinal axis), thereby presenting the smallest (thinnest or narrowest) profile of the wick element to the direction of air flow through the chamber. A parallel arrangement allows a larger vaporizer to be accommodated in the vaporization chamber with less impediment to air flow (which would affect the “draw” as perceived by the inhaling user). Indeed, a parallel mounting allows a wick area inside the vaporization chamber to be up to the size of the longitudinal cross-sectional area of the chamber, maximizing the surface available for delivering vapor, and hence the aerosol production per puff.



FIG. 7 shows a schematic representation of a vaporization chamber with a parallel mounted vaporizer; the “edge-on” orientation enables a large wick surface area inside the chamber together with a small profile in the air-flow direction A. The two edges 16 of the wick that are parallel to the air flow direction protrude through the chamber walls for contact with source liquid in a surrounding reservoir.


As another example, the wick may be shaped as a tube and mounted in the vaporization chamber end-on (edge-on) to the air-flow direction so that air flows through it. One or more radial arms can be provided to pass through the chamber walls into the reservoir. Formation of the wick from sintered porous ceramic allows flexibility in wick shape so that more complex forms such as this example can be realized.



FIG. 8 shows a schematic representation of a vaporization chamber with a tubular vaporizer 15, mounted through apertures in the chamber wall 52 by porous radial arms 18 terminating in end parts 16 that can reach into a surrounding reservoir.


The reservoir need not be configured as an annular space around the vaporization chamber. It may be adjacent to the chamber, rather than around it, so that the reservoir and chamber have a side-by-side or above-and-below configuration. In such a case, likely only one end or edge of the wick would reach into the reservoir, but a curved wick shape could allow more than one edge for this. In any configuration, the reservoir may be immediately adjacent to the vaporization chamber (conveniently they share one or more walls, so that the reservoir and chamber lie on opposite sides of a common wall). This is not essential however, and there may be intervening space between the reservoir and the vaporization chamber that is bridged by part of the wick. Neither the vaporization chamber nor the reservoir need be defined by cylindrical walls; any shape for either volume may be used.


The vaporizer has been described in the context of being included within a cartomizer section of an electronic cigarette. However, the disclosure is not limited in this regard, and the vaporizer may be included otherwise within an electronic cigarette, in a portion which may or may not be intended to be disposable, and may or may not be intended to be separable by the user from another portion or portions of the electronic cigarette. Generally, therefore, the vaporizer is comprised within a sub-assembly of an electronic cigarette, where the sub-assembly may or not be a cartomizer, and may or may not be separable from the remainder of the electronic cigarette.


According to an embodiment a sub-assembly for an electronic vapor provision system, comprises: a reservoir for holding source liquid; a vaporization chamber having an interior in airflow communication with an airflow path through the cartridge assembly; and a vaporizer comprising: a porous wick element with a thickness at least 50 times less than a longest dimension of the wick, such as in the range 50 to 200 times less than a longest dimension of the wick; and a heating element embedded in the wick element and connectable to an electrical power source; wherein the vaporizer is supported in the vaporization chamber by one or more parts of the wick element passing through apertures in a wall of the vaporization chamber, the one or more parts extending into the reservoir such that source liquid in the reservoir is transported by wicking through the wick element to the heating element.


The various embodiments described herein are presented only to assist in understanding and teaching the claimed features. These embodiments are provided as a representative sample of embodiments only, and are not exhaustive and/or exclusive. It is to be understood that advantages, embodiments, examples, functions, features, structures, and/or other aspects described herein are not to be considered limitations on the scope of the invention as defined by the claims or limitations on equivalents to the claims, and that other embodiments may be utilized and modifications may be made without departing from the scope of the claimed invention. Various embodiments of the invention may suitably comprise, consist of, or consist essentially of, appropriate combinations of the disclosed elements, components, features, parts, steps, means, etc., other than those specifically described herein. In addition, this disclosure may include other inventions not presently claimed, but which may be claimed in future.

Claims
  • 1. A sub-assembly for an electronic vapor provision system comprising: a source of liquid for vaporization; anda vaporizer for vaporizing a portion of the liquid for inhalation by a user, the vaporizer comprising: a wick component, andan electrical heating element comprising a metallic wire embedded in the wick component so that at each cross-sectional position along the wire, the material of the wick component is in contact with the wire around its full circumference;wherein the wick component is a sheet of a porous electrically-insulating material and is arranged to wick liquid from the source of liquid to a surface of the wick component adjacent to the embedded electrical heating element for vaporization.
  • 2. The sub-assembly according to claim 1, in which the porous electrically-insulating material is a porous ceramic.
  • 3. The sub-assembly according to claim 1, wherein the wick component has a porosity in a range of 30% to 85%.
  • 4. The sub-assembly according to claim 1, wherein the wick component has a thickness at least 50 times less than a longest dimension of the wick component.
  • 5. The sub-assembly according to claim 1, wherein the heating element has an embedded shape including one or more bends and a length embedded in the wick component of between 2 and 20 times the longest dimension of the wick component.
  • 6. The sub-assembly according to claim 5, wherein the one or more bends define adjacent portions of the heating element that have a center-to-center spacing not greater than twice an embedded width of the heating element.
  • 7. The sub-assembly according to claim 1, wherein a thickness of the wick component is in a range of 105% to 250% of an embedded width of the heating element.
  • 8. The sub-assembly according to claim 1, wherein the heating element is embedded centrally with respect to a thickness of the wick component.
  • 9. The sub-assembly according to claim 1, wherein the wick component is planar.
  • 10. The sub-assembly according to claim 1, wherein the vaporizer is supported in a vaporization chamber by one or more parts of the wick component passing through apertures in one or more walls of the vaporization chamber to extend into the source of liquid.
  • 11. The sub-assembly according to claim 10, wherein the one or more parts of the wick component that pass through apertures in one or more walls of the vaporization chamber are at opposite sides of the wick component.
  • 12. The sub-assembly according to claim 11, wherein the vaporizer is supported in the vaporization chamber such that a thinnest profile of the wick component is presented to a direction of airflow through the vaporization chamber.
  • 13. The sub-assembly according to claim 10, wherein the source of liquid comprises a reservoir having an annular shape and surrounding the vaporization chamber.
  • 14. The sub-assembly according to claim 13, wherein the wall of the vaporization chamber is also an inner wall of the reservoir.
  • 15. The sub-assembly according to claim 1, wherein the sub-assembly is a cartomizer for an electronic vapor provision system.
  • 16. An electronic vapor provision system comprising a sub-assembly according to claim 1.
  • 17. A method of making a vaporizer for an electronic vapor provision system, the method comprising: forming an electrically conductive heating element from a metallic wire;arranging powdered ceramic material around the heating element in a desired shape for a wick component; andsintering the ceramic material to form a porous ceramic wick component with the heating element embedded therein such that at each cross-sectional position along the wire the material of the wick component is in contact with the wire around its full circumference.
  • 18. A method of making a vaporizer for an electronic vapor provision system, the method comprising: forming an electrically conductive heating element from a metallic wire;arranging the heating element between a first layer and a second layer of sheet porous electrically-insulating material; andbonding the first layer and the second layer together to form a porous wick component with the heating element embedded therein such that at each cross-sectional position along the wire, the material of the wick component is in contact with the wire around its full circumference.
  • 19. An electronic vapor provision device comprising: a reservoir for source liquid; anda vaporization chamber adjacent the reservoir in which source liquid can be vaporized, the vaporization chamber housing a vaporizer comprising: a porous ceramic wick component, anda metallic heating element comprising a metallic wire embedded in the wick component such that at each cross-sectional position along the wire, the material of the wick component is in contact with the wire around its full circumference, and connectable to a battery in the electronic vapor provision device;wherein two ends of the wick component pass through apertures in walls of the vaporization chamber to suspend the vaporizer across the vaporization chamber, the two ends penetrating into the reservoir to absorb source liquid and transport the source liquid to the heating element by capillary action through pores in the wick component.
Priority Claims (1)
Number Date Country Kind
1607322 Apr 2016 GB national
PCT Information
Filing Document Filing Date Country Kind
PCT/GB2017/051139 4/25/2017 WO
Publishing Document Publishing Date Country Kind
WO2017/187148 11/2/2017 WO A
US Referenced Citations (422)
Number Name Date Kind
228598 Buckley Jun 1880 A
353327 Randolph Nov 1886 A
576653 Bowlby Feb 1897 A
595070 Oldenbusch Dec 1897 A
744074 Hiering Nov 1903 A
799844 Fuller Sep 1905 A
885374 Pohlig Apr 1908 A
1163183 Stoll Dec 1915 A
D53386 Thomas May 1919 S
1436157 Fazio Nov 1922 A
1807936 Saunders Jun 1931 A
1815069 Petro Jul 1931 A
1937120 Julius et al. Nov 1933 A
1937987 Sexton Dec 1933 A
2057353 Whittemore, Jr. Oct 1936 A
2262318 Fox Nov 1941 A
2371006 Weaver Mar 1945 A
2411946 Max et al. Dec 1946 A
2467923 Allen Apr 1949 A
2483304 Rudolf et al. Sep 1949 A
2522952 Joseph Sep 1950 A
2658368 Siegel Nov 1953 A
2782910 Saul et al. Feb 1957 A
2809634 Hirotada Oct 1957 A
3080624 Weber Mar 1963 A
3111396 Ball Nov 1963 A
3165225 Georg et al. Jan 1965 A
3221752 Strahm Dec 1965 A
3402724 Blount, et al. Sep 1968 A
3431393 Katsuda Mar 1969 A
3433632 Elbert, et al. Mar 1969 A
3490718 Vary et al. Jan 1970 A
3496336 Hingorany et al. Feb 1970 A
3521643 Toth Jul 1970 A
3604428 Moukaddem Sep 1971 A
3722742 Wertz Mar 1973 A
3743136 Chambers Jul 1973 A
3804100 Fariello Apr 1974 A
3861523 Fountain et al. Jan 1975 A
3863803 Valcic Feb 1975 A
3964902 Fletcher et al. Jun 1976 A
4009713 Simmons et al. Mar 1977 A
4031906 Knapp Jun 1977 A
4094119 Sullivan Jun 1978 A
4145001 Weyenberg et al. Mar 1979 A
4161283 Hyman Jul 1979 A
4190412 Nitta Feb 1980 A
4193513 Bull Mar 1980 A
4214658 Crow Jul 1980 A
4253476 Sato Mar 1981 A
4449039 Fukazawa May 1984 A
4503851 Braunroth Mar 1985 A
D279508 Shaak et al. Jul 1985 S
4588976 Jaselli May 1986 A
4676237 Wood et al. Jun 1987 A
4677992 Bliznak Jul 1987 A
4733794 Kent Mar 1988 A
4735217 Gerth et al. Apr 1988 A
4753383 Focke et al. Jun 1988 A
4793478 Tudor Dec 1988 A
4830028 Lawson et al. May 1989 A
4848374 Chard et al. Jul 1989 A
4878832 Lynch Nov 1989 A
4885129 Leonard et al. Dec 1989 A
4917301 Munteanu Apr 1990 A
4922901 Brooks et al. May 1990 A
4923052 Englebert May 1990 A
4923059 Evers et al. May 1990 A
4947874 Brooks et al. Aug 1990 A
4947875 Brooks et al. Aug 1990 A
4961438 Korte Oct 1990 A
4978814 Honour Dec 1990 A
5027837 Clearman et al. Jul 1991 A
5044550 Lamm Sep 1991 A
5046514 Bolt Sep 1991 A
5060671 Counts et al. Oct 1991 A
D322687 Tschudin Dec 1991 S
5095647 Zobele et al. Mar 1992 A
5095921 Losee et al. Mar 1992 A
5096921 Bollinger et al. Mar 1992 A
5099861 Clearman et al. Mar 1992 A
5121881 Lembeck Jun 1992 A
5167242 Turner et al. Dec 1992 A
5179966 Losee et al. Jan 1993 A
5247947 Clearman Sep 1993 A
5269327 Counts et al. Dec 1993 A
D346878 Utsch et al. May 1994 S
5322075 Deevi et al. Jun 1994 A
5357271 Wiklof et al. Oct 1994 A
5388574 Ingebrethsen Feb 1995 A
5390864 Alexander Feb 1995 A
5404890 Gentry et al. Apr 1995 A
5408574 Deevi et al. Apr 1995 A
5448317 Huang Sep 1995 A
5479948 Counts et al. Jan 1996 A
5497792 Prasad et al. Mar 1996 A
5501236 Hill et al. Mar 1996 A
5505214 Collins et al. Apr 1996 A
5530225 Hajaligol Jun 1996 A
5540241 Kim Jul 1996 A
5553791 Alexander Sep 1996 A
5568819 Gentry et al. Oct 1996 A
5636787 Gowhari Jun 1997 A
5649554 Sprinkel et al. Jul 1997 A
5659656 Das Aug 1997 A
5666977 Higgins et al. Sep 1997 A
5692291 Deevi et al. Dec 1997 A
D392069 Rowland Mar 1998 S
5743251 Howell et al. Apr 1998 A
D404201 Wennerstrom Jan 1999 S
5865185 Collins et al. Feb 1999 A
5875968 Miller et al. Mar 1999 A
5878722 Gras et al. Mar 1999 A
5878752 Adams et al. Mar 1999 A
5896984 Focke et al. Apr 1999 A
D414892 Chen Oct 1999 S
5967312 Jacobs Oct 1999 A
6040560 Fleischhauer et al. Mar 2000 A
6058711 Maciaszek et al. May 2000 A
6065592 Wik May 2000 A
6095505 Miller Aug 2000 A
D432263 Issa Oct 2000 S
D434217 Packard et al. Nov 2000 S
D434979 Liu Dec 2000 S
6155268 Takeuchi Dec 2000 A
D436725 Rogers Jan 2001 S
D438003 Minagawa et al. Feb 2001 S
D441133 Emery Apr 2001 S
6275650 Lambert Aug 2001 B1
D449521 Pinkus et al. Oct 2001 S
6321757 McCutcheon Nov 2001 B1
6446793 Layshock Sep 2002 B1
D466012 Baker Nov 2002 S
D470765 Baker Feb 2003 S
D471804 Staples Mar 2003 S
D472012 South Mar 2003 S
6527166 Focke et al. Mar 2003 B1
6530495 Joseph Mar 2003 B1
6561391 Baker May 2003 B1
6652804 Neumann et al. Nov 2003 B1
6681998 Sharpe et al. Jan 2004 B2
6701921 Sprinkel, et al. Mar 2004 B2
6715605 Manservigi et al. Apr 2004 B1
D493617 Armato Aug 2004 S
6790496 Levander et al. Sep 2004 B1
6830046 Blakley et al. Dec 2004 B2
D509732 Staples Sep 2005 S
7100618 Dominguez Sep 2006 B2
7112712 Ancell Sep 2006 B1
D545186 Liebe et al. Jun 2007 S
D549573 Liebe et al. Aug 2007 S
7253282 Dehmlow et al. Aug 2007 B2
7263228 Mori Aug 2007 B2
7263282 Meyer Aug 2007 B2
D550455 Barnhart Sep 2007 S
D566329 Bagaric et al. Apr 2008 S
D566890 Bagaric et al. Apr 2008 S
7389878 Torrico Jun 2008 B1
D573889 Short et al. Jul 2008 S
7400940 McRae et al. Jul 2008 B2
D575451 Jones et al. Aug 2008 S
7455176 Focke, et al. Nov 2008 B2
7540286 Cross Jun 2009 B2
7565969 He Jul 2009 B2
D606854 Greenhalgh Dec 2009 S
D610983 Wai Mar 2010 S
D611806 Bried Mar 2010 S
D613903 Wu et al. Apr 2010 S
D613904 Wu et al. Apr 2010 S
D616753 Beam et al. Jun 2010 S
7767698 Warchol et al. Aug 2010 B2
7832410 Hon Nov 2010 B2
D628469 Taylor et al. Dec 2010 S
D631838 Cheng Feb 2011 S
D636257 Bougoulas et al. Apr 2011 S
7992554 Radomski et al. Aug 2011 B2
D649658 Belfance et al. Nov 2011 S
D650738 Leung Dec 2011 S
8113343 Åkerlind Feb 2012 B2
D656094 Wu Mar 2012 S
8156944 Han Apr 2012 B2
D661016 Borges et al. May 2012 S
D671677 Wu Nov 2012 S
D671678 Wu Nov 2012 S
8307834 Palmerino, Sr. et al. Nov 2012 B1
D672642 Supranowicz Dec 2012 S
D674539 Wu Jan 2013 S
8365742 Hon Feb 2013 B2
8375957 Hon Feb 2013 B2
8393331 Hon Mar 2013 B2
8430106 Potter et al. Apr 2013 B2
8448783 Vecchi May 2013 B2
8490628 Hon Jul 2013 B2
8511318 Hon Aug 2013 B2
D693055 Manca et al. Nov 2013 S
D700397 Manca et al. Feb 2014 S
8689805 Hon Apr 2014 B2
8752545 Buchberger Jun 2014 B2
8794245 Scatterday Aug 2014 B1
8833364 Buchberger Sep 2014 B2
D715760 Kim et al. Oct 2014 S
D716267 Kim et al. Oct 2014 S
8869793 Spandorfer et al. Oct 2014 B1
8910640 Sears et al. Dec 2014 B2
D720884 Liu Jan 2015 S
8948578 Buchberger Feb 2015 B2
D723738 Liu Mar 2015 S
8967155 Bundren et al. Mar 2015 B2
9055617 Thorens Jun 2015 B2
D736460 McKeon et al. Aug 2015 S
D737507 Liu Aug 2015 S
9609894 Abramov et al. Apr 2017 B2
9623205 Buchberger Apr 2017 B2
9730276 Vissa Aug 2017 B2
9943108 Lord Apr 2018 B2
9961939 Reevell May 2018 B2
9974335 Lord May 2018 B2
9986760 Macko Jun 2018 B2
10010695 Buchberger Jul 2018 B2
10045562 Buchberger Aug 2018 B2
10278421 Lord May 2019 B2
10368582 Lord Aug 2019 B2
20010004934 Yamamoto et al. Jun 2001 A1
20010042546 Umeda et al. Nov 2001 A1
20020005207 Wrenn et al. Jan 2002 A1
20020016370 Shytle et al. Feb 2002 A1
20020079309 Cox et al. Jun 2002 A1
20030005620 Ananth et al. Jan 2003 A1
20030049025 Neumann et al. Mar 2003 A1
20030056791 Nichols et al. Mar 2003 A1
20030064340 Pappas Apr 2003 A1
20030079309 Vandenbelt et al. May 2003 A1
20030106552 Sprinkel et al. Jun 2003 A1
20030108342 Sherwood et al. Jun 2003 A1
20030108743 Anderson Jun 2003 A1
20030136399 Foley et al. Jul 2003 A1
20030136404 Hindle et al. Jul 2003 A1
20030168057 Snyder et al. Sep 2003 A1
20030200964 Blakley et al. Oct 2003 A1
20030202169 Liu Oct 2003 A1
20040025865 Nichols et al. Feb 2004 A1
20040031485 Rustad et al. Feb 2004 A1
20040056651 Marietta Bersana Mar 2004 A1
20040081624 Nguyen et al. Apr 2004 A1
20040129793 Nguyen et al. Jul 2004 A1
20040210151 Tsukashima Oct 2004 A1
20040223917 Hindle et al. Nov 2004 A1
20040226568 Takeuchi et al. Nov 2004 A1
20040255941 Nichols et al. Dec 2004 A1
20050016550 Katase Jan 2005 A1
20050063686 Whittle et al. Mar 2005 A1
20050087460 Bruhn et al. Apr 2005 A1
20050133049 Fournier et al. Jun 2005 A1
20050145260 Inagaki et al. Jul 2005 A1
20050155985 Meyer Jul 2005 A1
20050194013 Wright Sep 2005 A1
20050204799 Koch Sep 2005 A1
20050211243 Esser Sep 2005 A1
20050224375 Focke et al. Oct 2005 A1
20050235991 Nichols et al. Oct 2005 A1
20050268911 Cross et al. Dec 2005 A1
20060018840 Lechuga-Ballesteros et al. Jan 2006 A1
20060078477 Althouse et al. Apr 2006 A1
20060095311 Thompson May 2006 A1
20060137681 Von et al. Jun 2006 A1
20060180143 Lind et al. Aug 2006 A1
20060196518 Hon Sep 2006 A1
20060283468 Lipowicz Dec 2006 A1
20070014549 Demarest et al. Jan 2007 A1
20070045288 Nelson Mar 2007 A1
20070062548 Horstmann et al. Mar 2007 A1
20070102013 Adams et al. May 2007 A1
20070107879 Radomski et al. May 2007 A1
20070144514 Yeates et al. Jun 2007 A1
20070155255 Galauner et al. Jul 2007 A1
20070193895 Weiss et al. Aug 2007 A1
20070267031 Hon Nov 2007 A1
20070267032 Shan Nov 2007 A1
20080017204 Braunshteyn et al. Jan 2008 A1
20080092912 Robinson et al. Apr 2008 A1
20080149118 Oglesby et al. Jun 2008 A1
20080156326 Belcastro et al. Jul 2008 A1
20080216828 Wensley et al. Sep 2008 A1
20080223382 Zeanah Sep 2008 A1
20080241255 Rose et al. Oct 2008 A1
20090009534 Perani et al. Jan 2009 A1
20090090472 Radomski Apr 2009 A1
20090095311 Han Apr 2009 A1
20090095312 Herbrich et al. Apr 2009 A1
20090133691 Yamada et al. May 2009 A1
20090188490 Han Jul 2009 A1
20090220222 Rabin et al. Sep 2009 A1
20090241947 Bedini et al. Oct 2009 A1
20090266837 Gelardi et al. Oct 2009 A1
20090272379 Thorens et al. Nov 2009 A1
20090288966 Minarelli et al. Nov 2009 A1
20090293892 Williams et al. Dec 2009 A1
20090324206 Young et al. Dec 2009 A1
20100003904 Duescher Jan 2010 A1
20100006113 Urtsev et al. Jan 2010 A1
20100039066 Yuan et al. Feb 2010 A1
20100059070 Potter et al. Mar 2010 A1
20100065653 Wingo et al. Mar 2010 A1
20100083959 Siller Apr 2010 A1
20100108059 Axelsson et al. May 2010 A1
20100181387 Zaffaroni et al. Jul 2010 A1
20100182608 Egoyants Jul 2010 A1
20100211011 Haar Aug 2010 A1
20100236546 Yamada et al. Sep 2010 A1
20100242974 Pan Sep 2010 A1
20100313901 Fernando et al. Dec 2010 A1
20110011396 Fang Jan 2011 A1
20110036363 Urtsev et al. Feb 2011 A1
20110094523 Thorens et al. Apr 2011 A1
20110126848 Zuber Jun 2011 A1
20110155153 Thorens Jun 2011 A1
20110155718 Greim et al. Jun 2011 A1
20110180433 Rennecamp Jul 2011 A1
20110192914 Ishigami Aug 2011 A1
20110209717 Han Sep 2011 A1
20110226236 Buchberger Sep 2011 A1
20110277757 Terry Nov 2011 A1
20110278189 Terry et al. Nov 2011 A1
20110290267 Yamada et al. Dec 2011 A1
20110297166 Takeuchi et al. Dec 2011 A1
20110303231 Li et al. Dec 2011 A1
20110309157 Yang et al. Dec 2011 A1
20120111347 Hon May 2012 A1
20120145169 Wu Jun 2012 A1
20120180994 Yang et al. Jul 2012 A1
20120180995 Yang et al. Jul 2012 A1
20120199146 Marangos Aug 2012 A1
20120227752 Alelov Sep 2012 A1
20120227753 Newton Sep 2012 A1
20120242974 LaValley et al. Sep 2012 A1
20120255567 Rose et al. Oct 2012 A1
20120260927 Liu Oct 2012 A1
20120285476 Hon Nov 2012 A1
20130074857 Buchberger Mar 2013 A1
20130081623 Buchberger Apr 2013 A1
20130087160 Gherghe Apr 2013 A1
20130098786 Collins Apr 2013 A1
20130112214 Bundren et al. May 2013 A1
20130142782 Rahmel et al. Jun 2013 A1
20130192615 Tucker et al. Aug 2013 A1
20130192619 Tucker et al. Aug 2013 A1
20130192621 Li et al. Aug 2013 A1
20130192623 Tucker et al. Aug 2013 A1
20130213419 Tucker et al. Aug 2013 A1
20130228191 Newton Sep 2013 A1
20130255702 Griffith, Jr. et al. Oct 2013 A1
20130284192 Peleg et al. Oct 2013 A1
20130306084 Flick Nov 2013 A1
20130319407 Liu Dec 2013 A1
20130333700 Buchberger Dec 2013 A1
20130340779 Liu Dec 2013 A1
20130341218 Liu Dec 2013 A1
20130342157 Liu Dec 2013 A1
20140000638 Sebastian et al. Jan 2014 A1
20140007863 Chen Jan 2014 A1
20140007892 Liu Jan 2014 A1
20140020697 Liu Jan 2014 A1
20140048086 Zhanghua Feb 2014 A1
20140053831 Leamon et al. Feb 2014 A1
20140060528 Liu Mar 2014 A1
20140060554 Collett et al. Mar 2014 A1
20140060555 Chang et al. Mar 2014 A1
20140064715 Greim et al. Mar 2014 A1
20140123989 LaMothe May 2014 A1
20140182608 Egoyants et al. Jul 2014 A1
20140196717 Liu Jul 2014 A1
20140196731 Scatterday Jul 2014 A1
20140202454 Buchberger Jul 2014 A1
20140202476 Egoyants et al. Jul 2014 A1
20140209105 Sears et al. Jul 2014 A1
20140216485 Egoyants et al. Aug 2014 A1
20140238396 Buchberger Aug 2014 A1
20140238422 Plunkett et al. Aug 2014 A1
20140238423 Tucker et al. Aug 2014 A1
20140238424 Macko Aug 2014 A1
20140261488 Tucker Sep 2014 A1
20140261490 Kane Sep 2014 A1
20140261495 Novak, III et al. Sep 2014 A1
20140270726 Egoyants et al. Sep 2014 A1
20140270730 Depiano et al. Sep 2014 A1
20140283825 Buchberger Sep 2014 A1
20140286630 Buchberger Sep 2014 A1
20140299125 Buchberger Oct 2014 A1
20140305431 Holley et al. Oct 2014 A1
20140332019 Liu Nov 2014 A1
20140338680 Abramov et al. Nov 2014 A1
20150114411 Buchberger Apr 2015 A1
20150128964 Bundren et al. May 2015 A1
20150128971 Verleur et al. May 2015 A1
20150136756 Vissa May 2015 A1
20150157055 Lord Jun 2015 A1
20150164143 Maas Jun 2015 A1
20150181934 Lyubomirskiy et al. Jul 2015 A1
20150181937 Dubief et al. Jul 2015 A1
20150196058 Lord Jul 2015 A1
20150201675 Lord Jul 2015 A1
20150208728 Lord Jul 2015 A1
20160021934 Cadieux et al. Jan 2016 A1
20160073693 Reevell Mar 2016 A1
20160101909 Schennum et al. Apr 2016 A1
20160106154 Lord Apr 2016 A1
20160106155 Reevell Apr 2016 A1
20160120218 Schennum et al. May 2016 A1
20160278163 Chen Sep 2016 A1
20160353804 Lord Dec 2016 A1
20170006916 Kimree Jan 2017 A1
20170027225 Buchberger et al. Feb 2017 A1
20170042245 Buchberger Feb 2017 A1
20170188629 Dickens et al. Jul 2017 A1
20170188630 Buchberger Jul 2017 A1
20170197043 Buchberger Jul 2017 A1
20170197044 Buchberger Jul 2017 A1
20170197046 Buchberger Jul 2017 A1
20180192705 Lord Jul 2018 A1
20180235284 Lord Aug 2018 A1
20190254350 Lord Aug 2019 A1
20190289920 Lord Sep 2019 A1
Foreign Referenced Citations (465)
Number Date Country
507187 Mar 2010 AT
507187 Mar 2010 AT
507188 Mar 2010 AT
508244 Dec 2010 AT
508244 Dec 2010 AT
510405 Apr 2012 AT
510504 Apr 2012 AT
6393173 Jun 1975 AU
6391373 Jun 1975 AU
6391373 Jun 1975 AU
6393173 Jun 1975 AU
2015359102 Jun 2018 AU
2017256084 Sep 2020 AU
6402132 Jul 1986 BR
2309376 Nov 2000 CA
2309376 Nov 2000 CA
2824970 Aug 2012 CA
698603 Sep 2009 CH
199400288 Aug 1995 CL
199900377 Mar 1999 CL
2092880 Jan 1992 CN
2092880 Jan 1992 CN
2220168 Feb 1996 CN
2220168 Feb 1996 CN
1126425 Jul 1996 CN
1205849 Jan 1999 CN
1205849 Jan 1999 CN
1312730 Sep 2001 CN
1329567 Jan 2002 CN
1333657 Jan 2002 CN
2485265 Apr 2002 CN
1530041 Sep 2004 CN
2660914 Dec 2004 CN
1607911 Apr 2005 CN
2719043 Aug 2005 CN
2719043 Aug 2005 CN
1694765 Nov 2005 CN
1703279 Nov 2005 CN
2754386 Feb 2006 CN
1286409 Nov 2006 CN
2904674 May 2007 CN
200966824 Oct 2007 CN
101115901 Jan 2008 CN
201023852 Feb 2008 CN
201079011 Jul 2008 CN
20123 8609 May 2009 CN
201238609 May 2009 CN
201240612 May 2009 CN
201375023 Jan 2010 CN
201375023 Jan 2010 CN
101648041 Feb 2010 CN
101648041 Feb 2010 CN
201430913 Mar 2010 CN
101843368 Sep 2010 CN
201592850 Sep 2010 CN
101878958 Nov 2010 CN
101878958 Nov 2010 CN
101925309 Dec 2010 CN
201657770 Dec 2010 CN
102014677 Apr 2011 CN
201830900 May 2011 CN
201860753 Jun 2011 CN
102264249 Nov 2011 CN
102264420 Nov 2011 CN
102326869 Jan 2012 CN
202122096 Jan 2012 CN
102389166 Mar 2012 CN
202172846 Mar 2012 CN
202172846 Mar 2012 CN
102655773 Sep 2012 CN
102655773 Sep 2012 CN
102753047 Oct 2012 CN
202722498 Feb 2013 CN
202722498 Feb 2013 CN
202750708 Feb 2013 CN
202750708 Feb 2013 CN
103052380 Apr 2013 CN
103338664 Oct 2013 CN
103960782 Aug 2014 CN
203986095 Dec 2014 CN
204048047 Dec 2014 CN
104602553 May 2015 CN
204317492 May 2015 CN
104684422 Jun 2015 CN
204598339 Aug 2015 CN
104983079 Oct 2015 CN
105310114 Feb 2016 CN
105394816 Mar 2016 CN
205106385 Mar 2016 CN
106102863 Nov 2016 CN
106998820 Oct 2019 CN
594585 Mar 1934 DE
1950439 Apr 1971 DE
1950439 Apr 1971 DE
2653133 May 1978 DE
2940797 Apr 1981 DE
3148335 Jul 1983 DE
3148335 Jul 1983 DE
3218760 Dec 1983 DE
3218760 Dec 1983 DE
3936687 May 1990 DE
3936687 May 1992 DE
29719509 Jan 1998 DE
19630619 Feb 1998 DE
19630619 Feb 1998 DE
19654945 Mar 1998 DE
19654945 Mar 1998 DE
10330681 Jun 2004 DE
10330681 Jun 2004 DE
202006013439 Oct 2006 DE
202006013439 Oct 2006 DE
102006004484 Aug 2007 DE
202013100606 Feb 2013 DE
202013100606 Feb 2013 DE
019736 May 2014 EA
022685 Feb 2016 EA
280262 Aug 1981 EP
0280262 Aug 1988 EP
0295122 Dec 1988 EP
0358002 Mar 1990 EP
0358002 Mar 1990 EP
0358114 Mar 1990 EP
0358114 Mar 1990 EP
0444553 Sep 1991 EP
0444553 Sep 1991 EP
0488488 Jun 1992 EP
04888488 Jun 1992 EP
0845220 Jun 1998 EP
0845220 Jun 1998 EP
0847220 Jun 1998 EP
0295122 Dec 1998 EP
0893071 Jan 1999 EP
0893171 Jan 1999 EP
1166814 Jan 2002 EP
1166847 Jan 2002 EP
L166814 Jan 2002 EP
L166847 Jan 2002 EP
1468618 Oct 2004 EP
1736065 Dec 2006 EP
L736065 Dec 2006 EP
1757921 Feb 2007 EP
1757921 Feb 2007 EP
1772166 Apr 2007 EP
1772199 Apr 2007 EP
1820748 Aug 2007 EP
1847671 Oct 2007 EP
1950439 Jul 2008 EP
2018886 Jan 2009 EP
2018886 EP Jan 2009 EP
2022349 Feb 2009 EP
2022349 Feb 2009 EP
2022350 Feb 2009 EP
2113178 Nov 2009 EP
2113178 Nov 2009 EP
2234891 Oct 2010 EP
2340729 Jul 2011 EP
2358223 Aug 2011 EP
2358418 Aug 2011 EP
2404515 Jan 2012 EP
2468116 Jun 2012 EP
2468118 Jun 2012 EP
2698070 Feb 2014 EP
2698070 Feb 2014 EP
2907397 Apr 2014 EP
2762019 Aug 2014 EP
2762019 Aug 2014 EP
2785208 Oct 2014 EP
2801273 Nov 2014 EP
2835062 Feb 2015 EP
2835062 Feb 2015 EP
2871985 May 2015 EP
2907397 Aug 2015 EP
2907397 Sep 2017 EP
3284500 Feb 2018 EP
3117860 Jan 2019 EP
3229621 Jan 2020 EP
3738632 Feb 2022 EP
472030 Nov 1914 FR
960469 Apr 1950 FR
960469 Apr 1950 FR
1292446 May 1962 FR
190903566 Jun 1909 GB
190930472 Dec 1909 GB
191100628 Nov 1911 GB
25575 Mar 1912 GB
191311086 Sep 1913 GB
110216 Oct 1917 GB
111454 Nov 1917 GB
120016 Oct 1918 GB
160493 Mar 1921 GB
163124 May 1921 GB
215992 May 1924 GB
220229 Aug 1924 GB
268967 Apr 1927 GB
402064 Nov 1933 GB
438750 Nov 1935 GB
507955 Jun 1939 GB
544329 Apr 1942 GB
565574 Nov 1944 GB
611596 Nov 1948 GB
626888 Jul 1949 GB
871869 Jul 1961 GB
1313525 Apr 1973 GB
1313525 Apr 1973 GB
1046183 Jul 1988 GB
2275464 Aug 1994 GB
2068034 Nov 1997 GB
2369108 May 2002 GB
4000273 Dec 2006 GB
4006615 Oct 2008 GB
2504075 Jan 2014 GB
2513635 Nov 2014 GB
1196511 Dec 2014 HK
1196511 Dec 2014 HK
1226611 Oct 2017 HK
S5289386 Jul 1977 JP
S57-052456 Mar 1982 JP
S5752456 Mar 1982 JP
S57140354 Aug 1982 JP
S59106340 Jun 1984 JP
S59-106340 Jan 1986 JP
61-096765 May 1986 JP
S61-096763 May 1986 JP
S6121542 May 1986 JP
S6196763 May 1986 JP
S6196765 May 1986 JP
H01117775 May 1989 JP
2124081 May 1990 JP
H02124081 May 1990 JP
H02124082 May 1990 JP
H0548944 Feb 1993 JP
H05103836 Apr 1993 JP
H05-309136 Nov 1993 JP
H05309136 Nov 1993 JP
3003543 Oct 1994 JP
H6-315366 Nov 1994 JP
H06303837 Nov 1994 JP
H06315366 Nov 1994 JP
H07147965 Jun 1995 JP
H08-299862 Nov 1996 JP
H08299862 Nov 1996 JP
H08511176 Nov 1996 JP
11089551 Apr 1999 JP
H1189551 Apr 1999 JP
H11503912 Apr 1999 JP
H11514018 Nov 1999 JP
H11514018 Nov 1999 JP
H11514081 Nov 1999 JP
3003543 Jan 2000 JP
2001502542 Feb 2001 JP
2001248842 Sep 2001 JP
2002527153 Aug 2002 JP
3093201 Apr 2003 JP
2003226577 Aug 2003 JP
2004097617 Apr 2004 JP
2004332069 Nov 2004 JP
2004332069 Nov 2004 JP
2005013092 Jan 2005 JP
2005034021 Feb 2005 JP
2005514991 May 2005 JP
2005138773 Jun 2005 JP
2005524067 Aug 2005 JP
2005537918 Dec 2005 JP
2005537918 Dec 2005 JP
2005537919 Dec 2005 JP
2005538149 Dec 2005 JP
2005538159 Dec 2005 JP
2007057532 Mar 2007 JP
2007097787 Apr 2007 JP
2007512880 May 2007 JP
2007297124 Nov 2007 JP
2008501406 Jan 2008 JP
2008544834 Dec 2008 JP
2009509523 Mar 2009 JP
2009526714 Jul 2009 JP
2009529871 Aug 2009 JP
2009537119 Oct 2009 JP
2010080261 Apr 2010 JP
2011087569 May 2011 JP
2011515093 May 2011 JP
2011518567 Jun 2011 JP
2012013247 Jan 2012 JP
2012026933 Feb 2012 JP
2012029633 Feb 2012 JP
2012057859 Mar 2012 JP
2012506263 Mar 2012 JP
2012-249854 Dec 2012 JP
2012249854 Dec 2012 JP
2013516159 May 2013 JP
2013-545473 Dec 2013 JP
2014501107 Jan 2014 JP
2014511175 May 2014 JP
2014520542 Aug 2014 JP
2014524313 Sep 2014 JP
2014525251 Sep 2014 JP
2015500025 Jan 2015 JP
2015505476 Feb 2015 JP
2015506182 Mar 2015 JP
2015513970 May 2015 JP
2015521847 Aug 2015 JP
2017518033 Jul 2017 JP
2017522868 Aug 2017 JP
2017525348 Sep 2017 JP
6507248 Apr 2019 JP
920017172 Sep 1992 KR
100244670 Feb 2000 KR
20050037919 Apr 2005 KR
20-2009-0008142 Aug 2009 KR
20100006995 Jul 2010 KR
20110006928 Jul 2011 KR
20120025569 Mar 2012 KR
20120070731 Jul 2012 KR
20130004985 Jan 2013 KR
20130006714 Jan 2013 KR
2013 0006714 Nov 2013 KR
200470732 Jan 2014 KR
20140128449 Nov 2014 KR
101955000 Mar 2019 KR
102148901 Aug 2020 KR
6617184 Jun 1967 NL
12017500957 Oct 2017 PH
2311859 Dec 2007 RU
2328192 Jul 2008 RU
2336001 Oct 2008 RU
2360583 Jul 2009 RU
89927 Dec 2009 RU
89927 Dec 2009 RU
94815 Jun 2010 RU
94815 Jun 2010 RU
103281 Apr 2011 RU
103281 Apr 2011 RU
115629 May 2012 RU
115629 May 2012 RU
121706 Nov 2012 RU
122000 Nov 2012 RU
122000 Nov 2012 RU
124120 Jan 2013 RU
124120 Jan 2013 RU
132318 Sep 2013 RU
2509516 Mar 2014 RU
89752 Mar 2010 UA
67598 Feb 2012 UA
78167 Mar 2013 UA
9527412 Oct 1995 WO
WO9527412 Oct 1995 WO
9632854 Oct 1996 WO
WO9632854 Oct 1996 WO
9748293 Dec 1997 WO
WO9748293 Dec 1997 WO
WO-9817131 Apr 1998 WO
0009188 Feb 2000 WO
WO200009188 Feb 2000 WO
0021598 Apr 2000 WO
WO200021598 Apr 2000 WO
WO-0028842 May 2000 WO
WO-0050111 Aug 2000 WO
0102040 Jan 2001 WO
WO-02051468 Jul 2002 WO
02058747 Aug 2002 WO
WO-02060769 Aug 2002 WO
WO2002058747 Aug 2002 WO
WO-03005045 Jan 2003 WO
03028409 Apr 2003 WO
WO2003028409 Apr 2003 WO
03050405 Jun 2003 WO
WO 2003050405 Jun 2003 WO
WO-03059424 Jul 2003 WO
03083283 Oct 2003 WO
WO2003083283 Oct 2003 WO
03101454 Dec 2003 WO
WO 2003101454 Dec 2003 WO
2004022128 Mar 2004 WO
2004022242 Mar 2004 WO
2004022243 Mar 2004 WO
WO2004022128 Mar 2004 WO
WO2004022242 Mar 2004 WO
WO2004022243 Mar 2004 WO
2005106350 Nov 2005 WO
WO2005106350 Nov 2005 WO
WO-2005120614 Dec 2005 WO
2006082571 Aug 2006 WO
WO2006082571 Aug 2006 WO
2007040941 Apr 2007 WO
2007042941 Apr 2007 WO
WO 2007042941 Apr 2007 WO
WO 2007040941 Apr 2007 WO
WO-2007108877 Sep 2007 WO
2007131449 Nov 2007 WO
WO 2007131449 Nov 2007 WO
WO-2007131448 Nov 2007 WO
WO-2007141668 Dec 2007 WO
WO-2008006048 Jan 2008 WO
WO-2008015918 Feb 2008 WO
WO-2008038144 Apr 2008 WO
WO-2008104870 Sep 2008 WO
WO-2009001085 Dec 2008 WO
2009015410 Feb 2009 WO
WO2009015410 Feb 2009 WO
WO-2009092862 Jul 2009 WO
WO-2009092419 Sep 2009 WO
2009118085 Oct 2009 WO
WO2009118085 Oct 2009 WO
2009135729 Nov 2009 WO
2009132793 Nov 2009 WO
WO2009132793 Nov 2009 WO
2010045670 Apr 2010 WO
2010045671 Apr 2010 WO
WO2010045670 Apr 2010 WO
WO2010045671 Apr 2010 WO
2011050943 May 2011 WO
WO 2011050943 May 2011 WO
WO-2011050964 May 2011 WO
WO-2011079932 Jul 2011 WO
2011109849 Sep 2011 WO
WO2011109849 Sep 2011 WO
WO-2011137453 Nov 2011 WO
2012025496 Mar 2012 WO
WO2012025496 Mar 2012 WO
WO-2012065310 May 2012 WO
WO-2012065754 May 2012 WO
WO-2012085203 Jun 2012 WO
WO-2012085207 Jun 2012 WO
WO-2012106739 Aug 2012 WO
WO-2012114082 Aug 2012 WO
WO-2013013808 Jan 2013 WO
WO-2013025921 Feb 2013 WO
2013034453 Mar 2013 WO
2013034460 Mar 2013 WO
WO2013034453 Mar 2013 WO
WO2013034460 Mar 2013 WO
2013057185 Apr 2013 WO
WO-2013045942 Apr 2013 WO
WO2013057185 Apr 2013 WO
2013082173 Jun 2013 WO
WO 2013082173 Jun 2013 WO
WO-2013083631 Jun 2013 WO
2013098395 Jul 2013 WO
WO2013098395 Jul 2013 WO
2013116558 Aug 2013 WO
WO2013116558 Aug 2013 WO
WO-2013116571 Aug 2013 WO
WO-2013116572 Aug 2013 WO
WO2014130695 Aug 2013 WO
WO-2013142671 Sep 2013 WO
2013152873 Oct 2013 WO
WO2013152873 Oct 2013 WO
WO-2013178769 Dec 2013 WO
WO-2013189050 Dec 2013 WO
WO-2013189052 Dec 2013 WO
WO-2014005275 Jan 2014 WO
WO2014012906 Jan 2014 WO
WO-2014015463 Jan 2014 WO
2014061477 Apr 2014 WO
WO2014061477 Apr 2014 WO
WO-2014071329 May 2014 WO
2014130695 Aug 2014 WO
2014140320 Sep 2014 WO
2014150131 Sep 2014 WO
WO2014140320 Sep 2014 WO
WO2014150131 Sep 2014 WO
WO-2015114327 Aug 2015 WO
WO2015114328 Aug 2015 WO
2015149404 Oct 2015 WO
WO2015165812 Nov 2015 WO
WO-2015198049 Dec 2015 WO
Non-Patent Literature Citations (184)
Entry
International Preliminary Report on Patentability for corresponding International Application No. PCT/GB2015/051213 dated Jul. 14, 2016.
International Search Report for corresponding International Application No. PCT/GB2015/051213 dated Jul. 16, 2015.
Written Opinion of the International Preliminary Examining Authority for International Application No. PCT/GB2015/051213 dated Jul. 16, 2016.
International Search Report and Written Opinion dated Feb. 6, 2013 for PCT/EP0212/070647 filed Oct. 18, 2012.
Chinese Office Action for Chinese Application No. 201480024978.X dated Jan. 18, 2017.
European Search Report for European Application No. 15178588 dated Apr. 14, 2016.
International Preliminary Report on Patentability, dated Apr. 22, 2014, for International Patent Application No. PCT/EP2012/070647, filed Oct. 18, 2012.
International Search Report and Written Opinion for International Application No. PCT/EP2012/003103, dated Nov. 26, 2012.
International Search Report and Written Opinion for PCT/AT/2012/000017 dated Jul. 3, 2012.
International Search Report and Written Opinion for PCT/GB2014/051333 dated Jul. 17, 2014.
International Search Report and Written Opinion, International Application No. PCT/GB2014/051332 dated Jul. 21, 2014.
International Search Report and Written Opinion, International Application No. PCT/GB2014/051334 dated Jul. 21, 2014.
IPRP dated Aug. 5, 2015 for International Application No. PCT/GB2014/051333.
IPRP, International Application No. PCT/GB2014/051332 dated Nov. 12, 2015.
IPRP, International Application No. PCT/GB2014/051334 dated Nov. 12, 2015.
Japanese Notice of Reasons for Rejection for Japanese Application No. 2015-137361 dated May 31, 2016.
Russian Search Report for Russian Application No. 2015146843/12 (072088) date completed Apr. 24, 2017.
Russian Office Action, Application No. 2014120213/12, dated Oct. 26, 2016, 7 pages.
Russian Office Action, Application No. 2014120213/12, dated Sep. 22, 2017, 11 pages.
Chinese Office Action, Application No. 201480024988.3, dated Dec. 30, 2016, 26 pages.
Chinese Office Action, Application No. 201480024988.3, dated Sep. 11, 2017, 21 pages.
European Extended Search Report, Application No. 17189951.1, dated Jan. 4, 2018, 8 pages (11 pages with translation).
Plasma polymerization (the company Diener electronic GmbH+Co. KG), www.plasma.de, retrieved on Oct. 17, 2017, 19 pages.
International Preliminary Report on Patentability (WIPO English Translation), dated Aug. 13, 2013 for International Patent Application No. PCT/AT2012/000017, filed Feb. 2, 2012.
Pulmonary Pharmacoloy: Delivery Devices and Medications, dated Sep. 6, 2017, 2 pages, available at www.cdeu.org/cecourses/z98207/ch4.htm.
Dunn P and Reay D, Heat Pipes, 4th edition, 1994, ISBN 0080419038, 14 pages.
Application and File History for U.S. Appl. No. 13/125,343, filed Apr. 21, 2011 inventor Buchberger.
Japanese Notice of Reasons for Rejection dated Sep. 8, 2015 for Japanese Application No. 2014179732.
Application and File History for U.S. Appl. No. 14/306,831, filed Jun. 17, 2014, inventor Buchberger.
European Search Report for European Application No. 16166656 dated Oct. 11, 2016.
Notice of Opposition Letter from EPO. Opposition against: EP2358418 dated Mar. 1, 2017.
Rudolph G, Bat Cigarettenfabriken GmbH, 1987, The Influence of CO2 on the Sensory Characteristics of the Favor-System, http://legacy.library.ucsf.edu/tid/sla51f00.
Application and File History for U.S. Appl. No. 15/470,078, filed Mar. 27, 2017, inventor Buchberger.
Application and File History for U.S. Appl. No. 15/470,095, filed Mar. 27, 2017, inventor Buchberger.
Japanese Notification of Reasons for Refusal for Japanese Application No. 2014179732 dated Sep. 3, 2015 dated Sep. 8, 2015.
Japanese Notice of Reasons for Refusal, dated Oct. 7, 2013 dated Oct. 15, 2013 for Japanese Application No. 2011532464.
International Search Report for International Application No. PCT/AT2009/000413 dated Jan. 25, 2010.
Translation of Chinese First Office Action for Chinese Application No. 200980152395.4 dated Dec. 3, 2012.
Translation of Chinese Second Office Action for Chinese Application No. 200980152395.4 dated Aug. 20, 2013.
Japanese Reasons for Rejection for Japanese Application No. 2016134648 dated May 23, 2017.
Japanese Decision to Grant, Application No. 2016-134648, dated May 22, 2018, 3 pages (4 pages with translation).
Japanese Office Action, Application No. 2016-564977, dated Dec. 5, 2017, 3 pages (6 pages with translation).
Japanese Search Report, Application No. 2016-864977, dated Oct. 25, 2017, 9 pages (19 pages with translation).
Chinese Office Action, Application No. 201580022356.8, dated Jul. 18, 2018, 8 pages (15 pages with translation).
International Search Report for International Application No. PCT/AT2009/000414 dated Jan. 26, 2010.
Kynol, Kynol Standard Specifications of Activated Carbon Fiber Products, 2 pages, as retrieved on Sep. 19, 2013.
Application and File History for U.S. Appl. No. 14/296,803, filed Jun. 5, 2014 inventor Buchberger.
Application and File History for U.S. Appl. No. 15/454,156, filed Mar. 9, 2017, inventor Buchberger.
Application and File History for U.S. Appl. No. 15/307,095, filed Oct. 27, 2016, inventor Buchberger.
Chinese Office Action, Application No. 2016103 71843.1, dated Sep. 30, 2018, 6 pages (11 pages with translation).
Application and File History for U.S. Appl. No. 15/470,089, filed Mar. 27, 2017, inventor Buchberger.
International Search Report and Written Opinion, Application No. PCT/GB2017/051139, dated Aug. 9, 2017, 16 pages.
International Preliminary Report on Patentability, Application No. PCT/GB2017/051139, dated Aug. 6, 2018, 8 pages.
Application and File History for U.S. Appl. No. 13/984,512, filed Aug. 29, 2013, inventor Buchberger.
Application and File History for U.S. Appl. No. 14/268,909, filed May 2, 2014, inventor Buchberger.
Application and File History for U.S. Appl. No. 15/997,113, filed Jun. 4, 2018, inventor Buchberger.
Application and File History for U.S. Appl. No. 14/353,256, filed Apr. 21, 2014, inventor Buchberger.
Application and File History for U.S. Appl. No. 14/594,065, filed May 12, 2017, inventor Buchberger.
Application and File History for U.S. Appl. No. 14/235,210, filed Mar. 4, 2014, inventor Buchberger.
Application and File History for U.S. Appl. No. 14/787,946, filed Oct. 29, 2015, inventor Lord, 228 pages.
Application and File History for U.S. Appl. No. 14/888,514, filed Nov. 2, 2015, inventor Reevell, 188 pages.
Application and File History for U.S. Appl. No. 14/888,517, filed Nov. 2, 2015, Inventor Reevell, 136 pages.
Company Filtrona Richmond Inc., http://www.filtronaporoustechnologies.com, Nov. 19, 2018, 1 page.
Decision on Appeal, U.S. Appl. No. 14/306,831, dated Mar. 26, 2020, 6 pages.
Decision to Grant dated Feb. 5, 2018 for Ukraine Application No. 201607243, 6 pages.
Decision to Grant dated Apr. 11, 2016 for Russian Application No. 2015100321, 8 pages (No translation available).
Decision to Grant dated Jun. 23, 2016 for Ukrainian Application No. 201500198, 6 pages (No translation available).
Decision to Grant dated Apr. 27, 2017 for Russian Application No. 2015146845, 8 pages.
Decision to Grant for Australian Application No. 2017105898, dated Mar. 16, 2018, 12 pages.
Decision to Grant for Great Britain Application No. GB1405720.2, dated Sep. 26, 2017, 2 pages.
Decision to Grant for Russian Application No. 120267, dated Oct. 26, 2016, 7 pages.
Decision to Grant dated Apr. 1, 2014 for Russian Application No. 2011120430, 16 pages.
Decision to Grant dated Aug. 5, 2014 for Japanese Application No. 2011-532464, 6 pages.
ECF, “Welcome to the World's Largest E-Cigarette Website: The Voice of Vaping since 2007,” Nichrome or Kanthal Specs for Purchasing, Apr. 19, 2020, 39 pages.
Examination Report for Great Britain Application No. GB1405720.2, dated Jun. 27, 2017, 3 pages.
Examination Report dated Nov. 20 for Australian Application No. 2017256084, 3 pages.
Examination Report dated Dec. 15, 2017, for Australian Application No. 201512626, 3 pages.
Extended European Search Report for Application No. 18205608.5, dated Jul. 12, 2019, 7 pages.
Extended European Search Report for Application No. EP17197150.5, dated Mar. 1, 2018, 6 pages.
Extended European Search Report for Application No. 16151458.3, dated Jul. 11, 2016, 8 pages.
Extended European Search Report for Application No. 19196432.9, dated Dec. 9, 2019, 14 pages.
Extended European Search Report for European Application No. 15178588, dated Apr. 22, 2016, 4 pages.
First Office Action for Chinese Application No. 201480031926.5 dated Apr. 21, 2017, 12 pages.
Hegboom T., “Integrating Electrical Heating Elements in Appliance Design,” resulting in interlocutory decision dated Aug. 7, 2019, 4 pages.
Hong Kong Publication, Application No. 14110165.2, published on Dec. 19, 2014, 1 page.
Hong Kong Publication, Application No. 16113324.2, published on Oct. 6, 2017, 1 page.
Iatty, “An Idea of the Iatty, Welcome to the World's Largest E-Cigarette Website: The Voice of Vaping since 2007,” retrieved on Dec. 17, 2019, p. 23, Post 443, 7 pages.
Iatty, “An Idea of the Iatty, Welcome to the World's Largest E-Cigarette Website: The Voice of Vaping since 2007,” retrieved on Dec. 17, 2019, p. 24, Post 467, 6 pages.
Iatty, “An Idea of the Iatty, Welcome to the World's Largest E-Cigarette Website: The Voice of Vaping since 2007,” retrieved on Dec. 17, 2019, p. 37, Post 727, 6 pages.
Iatty, “An Idea of the Iatty, Welcome to the World's Largest E-Cigarette Website: The Voice of Vaping since 2007,” retrieved on Dec. 17, 2019, Page, Post 1, 7 pages.
Iatty, “E-Cigarette Forum,” Imeothansis and Iorderos33, p. 10, Feb. 11, 2019, 8 pages.
“Integrating Electrical Heating Elements in Product Design,” Metallic Resistance Heating Wire, Chapter 1, Section 1.1 to 1.3.2, resulting in interlocutory decision dated Aug. 7, 2019, 6 pages.
“Integrating Electrical Heating Elements in Product Design,” Metallic Resistance Heating Wire, Chapter 1, resulting in interlocutory decision dated Aug. 7, 2019, 1 page.
“Integrating Electrical Heating Elements in Product Design,” Metallic Resistance Heating Wire, resulting in interlocutory decision dated Aug. 7, 2019, 8 pages.
International Preliminary Report on Patentability for Application No. PCT/AT2009/000413, dated May 5, 2011, 7 pages, Written Opinion for Application No. PCT/AT2009/000413, dated Jan. 25, 2010, 5 pages.
International Preliminary Report on Patentability for Application No. PCT/AT2009/000414, dated Apr. 26, 2011, 7 pages, Written Opinion for Application No. PCT/AT2009/000414, dated Jan. 26, 2010, 14 pages.
International Preliminary Report on Patentability for Application No. PCT/EP2012/003103, dated Feb. 6, 2014, 7 pages.
International Preliminary Report on Patentability for Application No. PCT/GB2014/051688, dated Dec. 17, 2015, 6 pages.
International Preliminary Report on Patentability for Application No. PCT/GB2015/050195, dated May 13, 2016, 17 pages.
International Preliminary Report on Patentability for Application No. PCT/GB2015/053445, dated Jan. 24, 2017, 19 pages.
International Preliminary Report on Patentability dated Sep. 9, 2014 for Application No. PCT/EP2013/64922, filed Jul. 15, 2013, 10 pages.
International Search Report and Written Opinion for Application No. PCT/GB2015/053445, dated Apr. 18, 2016, 21 pages.
International Search Report and Written Opinion dated Oct. 11, 2013 for Application No. PCT/EP2013/064922, filed Jul. 15, 2013, 6 pages.
International Search Report for App No. PCT/GB2015/050195, dated Sep. 2, 2015, 4 pages.
International Search Report for Application No. PCT/GB2014/051633, dated Dec. 4, 2014, 7 pages.
International Search Report for Application No. PCT/GB2014/051688, dated Aug. 26, 2014, 4 pages.
Notice of Allowance dated Oct. 18, 2019 for Korean Application No. 1020167018457, 2 pages (with translation—3 pages).
Notice of Allowance dated May 30, 2017 for Korean Application No. 1020157001277, 4 pages (No translation available).
Notice of Allowance dated Jun. 27, 2018 for Korean Application No. 1020167020977, 3 pages.
Notice of Opposition dated Oct. 30, 2019 for European Application No. 16166656.5, 39 pages.
Notice of Reasons for Rejection dated Oct. 15, 2013 for Japanese Application No. 2011532464, 6 pages.
Notice of Reasons for Revocation dated Apr. 17, 2017 for Japanese Patent No. 5960358, with English translation, 12 pages.
Notification of Transmittal of IPRP for International Application No. PCT/GB2014/051633 dated Oct. 23, 2015, 9 pages.
Notification to Grant Patent Right for Invention dated Oct. 25, 2018 for Chinese Application No. 201610086101.4, 2 pages.
Office Action and Search Report dated Feb. 28, 2019 for Japanese Application No. 2018-088088, 25 pages.
Office Action dated Sep. 3, 2014, for Russian Application No. 2013504605, 7 pages.
Office Action dated Jul. 2, 2020 for Chinese Application No. 201780020023.0 filed Sep. 25, 2018, 22 pages.
Office Action dated Nov. 21, 2017 for Russian Application No. 2016142584, 8 pages.
Office Action dated Nov. 22, 2016 for Canadian Application No. 2878951, 3 pages.
Office Action dated Sep. 22, 2017 for Russian Application No. 2015146847, 11 pages.
Office Action dated Nov. 23, 2018 for Korean Application No. 1020167018457, 6 pages (12 pages with translation).
Office Action dated Apr. 25, 2017 for Japanese Application No. 2016123816, 2 pages (No translation available).
Office Action dated May 12, 2017 for Korean Application No. 10-20157034538, 10 pages.
Office Action for European Application No. 16166656, dated Jul. 29, 2020, 7 pages.
Office Action for Chilean Application No. 201701486 dated Nov. 11, 2019, 10 pages.
Office Action for Chinese Application No. 201480031296.1 dated Mar. 27, 2017, 13 pages.
Office Action dated Jun. 2, 2016 for Chinese Application No. 201380038075.2, 7 pages (with translation—19 pages).
Office Action dated Dec. 12, 2018 for Korean Application No. 10-2017-7015164, 3 pages.
Office Action dated Jun. 15, 2018 for Korean Application No. 10-2017-7015164, 13 pages.
Office Action dated Mar. 16, 2020 for Chinese Patent Application No. 201610255788.X, filed Oct. 21, 2009, 21 pages.
Office Action dated Jan. 25, 2019 for European Application No. 17189951.1, 4 pages.
Office Action dated Jun. 26, 2018 for Japanese Application No. 2017-530762, 16 pages.
Office Action dated Nov. 26, 2019 for Brazilian Application No. 112015000872, 4 pages.
Office Action dated Sep. 27, 2019 for Korean Application No. 10-20197005785, 13 pages.
Office Action dated May 4, 2018 for Chinese Application No. 201610086101.4, 7 pages.
Office Action dated Apr. 10, 2019, for Korean Application No. 1020167018457, 13 pages.
Office Action dated Apr. 23, 2018 for Chinese Application No. 201580006377.0, 9 pages (20 pages with translation).
Office Action dated Dec. 8, 2017, for Korean Application No. 1020167020977, 13 pages.
Office Action dated Jan. 23, 2018, for Japanese Application No. 2016548373, 3 pages, (6 pages with translation).
Office Action dated Jun. 5, 2018, for Chinese Application No. 201610552323.0, 11 pages, (18 pages with translation).
Office Action dated Mar. 14, 2018, for Russian Application No. 2016131333, 7 pages (13 pages with translation).
Opposition Statement dated Mar. 30, 2017 for Japanese Patent No. 5960358, 144 pages (No translation available).
Partial EPO Opposition, resulting in interlocutory decision dated Aug. 7, 2019, 75 pages.
Search Report for Chilean Application No. 2019-11665, dated Nov. 11, 2019, 10 pages.
Search Report for Japanese Application No. 2011532464, dated Sep. 18, 2013, 116 pages.
Search Report for Japanese Application No. 2014-179732, dated Sep. 9, 2015, 12 pages.
Search Report for Japanese Application No. 2016134648, dated Mar. 28, 2017, 29 pages.
Search Report for Japanese Application No. 2016-564977, dated Oct. 25, 2017, 19 pages.
Search Report for Japanese Application No. 2011532464, dated Sep. 24, 2013, 53 pages.
Search Report dated Feb. 1, 2017 for Japanese Application No. 2016517671, 13 pages.
Search Report dated Apr. 14, 2017 for Japanese Application No. 2016-134648, 31 pages.
Search Report dated Sep. 19, 2013 for Japanese Application No. 2011-532464, 116 pages.
Search Report dated Jun. 24, 2019 for Russian Application No. 2018137583, 2 pages.
Search Report dated Apr. 25, 2018 for Chinese Application No. 201610086101.4, 1 page.
Search Report dated Aug. 25, 2015 for Japanese Application No. 2014-179732, 10 pages.
Search Report dated Apr. 29, 2019 for Russian Application No. 2018137501, 12 pages.
Search Report dated May 29, 2015 for Great Britain Application No. 1422018, 3 pages.
Search Report dated Mar. 20, 2015, for Great Britain Application No. GB1401520.0, 2 pages.
Sharafat et al., “Ceramic Foams: Inspiring New Solid Breeder Materials,” 12th International Workshop on Ceramic Breeder Blanket Interactions, Germany, Sep. 16-17, 2004, 22 pages.
Supulveda et al., “Processing of Cellular Ceramics by Foaming and In Situ Polymerisation of Organic Monomers,” Loughborough University, 1999, 22 pages.
Wires.co.uk, “Bare Nickel Chrome/Nichrome Section,” Jun. 20, 2012, 33 pages.
Wires.co.uk, “Specialist in Craft Wire,” Jun. 20, 2012, 5 pages.
Written Opinion for Application No. PCT/AT2012/000017, dated Jul. 3, 2012, 4 pages.
Written Opinion for Application No. PCT/GB2014/051633, dated Dec. 4, 2014, 11 pages.
Written Opinion for Application No. PCT/GB2014/051688, dated Aug. 26, 2014, 4 pages.
Written Opinion dated Jun. 23, 2014 for Application No. PCT/EP2013/064922, filed Jul. 15, 2013, 4 pages.
Written Opinion of the International Preliminary Examining Authority for Application No. PCT/GB2015/050195 dated Jan. 20, 2016, 8 pages.
Written Opinion of the International Searching Authority for Application No. PCT/GB2015/050195, dated Sep. 2, 2015, 8 pages.
Office Action For Chinese Application No. 201780020023.0, dated Mar. 8, 2021, 19 pages.
Notice of Reasons for Rejection for Japanese Application No. 2020-121265, dated Jul. 20, 2021, 8 pages.
Office Action For Korean Application No. 10-2018-7031081, dated Dec. 15, 2021, 6 pages.
Search Report for Japanese Application No. 2018-546893, dated Nov. 25, 2019, 27 pages.
European Search Report for Application No. 22155057.7, dated Jun. 15, 2022, 10 pages.
Notice of Reasons for Rejection for Japanese Application No. 2020-121265, dated Jun. 21, 2022, 8 pages.
Kynol, “Standard Specifications of Kynol Activated Carbon Fiber Products”, published by Kynol.
Decision to Grant for Russian Application No. 2017105898, dated Mar. 16, 2018, 12 Pages (Official Copy Only).
“Feature Analysis of Claim 1”, BATMark Limited, Opposition Against EP3117860B1, Exhibit D6, Oct. 30, 2019, 1 Page. (Official Copy Only).
Japanese Search Report, Application No. 2016-564977, dated Oct. 25, 2017, 19 pages (10 pages of English Translation and 9 pages Of Official Copy).
Letter from Patentee for European Application No. 17189951.1, dated Aug. 21, 2018, 11 Pages (Official Copy Only).
Notice of Opposition—Imperial Tobacco Limited for European Application No. 20171293.2, dated Nov. 16, 2022, 28 pages.
Notice of Opposition—Philip Morris for European Application No. 20171293.2, dated Nov. 17, 2022, 27 Pages.
Notice of Reasons for Rejection received for Japanese Application No. 2020-181572 dated Feb. 13, 2023, 29 Pages (14 Pages of English Translation and 15 Pages of Official Copy).
Notification to Grant received for Chinese Patent Application No. 201610256674.7. dated Jan. 12, 2023, 7 Pages (2 Pages of English Translation and 5 Pages of Official Copy).
Wikipedia , “Electronic Cigarette”, Available at <https://en.wikipedia.org/w/index.phptitle=Electronic_cigratte&oldid=284227163>, April 2009, 7 Pages.
Related Publications (1)
Number Date Country
20190133186 A1 May 2019 US