Technical Field
The present disclosure relates to an electronic device having an integrated temperature sensor, and to a manufacturing method of the same. In particular, the one or more embodiments of present disclosure relates to a microfluidic-based electronic device having at least one integrated thermocouple and at least one microchannel.
Description of the Related Art
Devices for handling fluids, comprising at least one micro-channel in a substrate, e.g., a device of the “Lab-On-Chip” (LOC) type, can be used, inter alia, for analyzing or transporting very small quantities of liquids or to subject said fluids to biological or chemical reactions. Devices of this type may also be simple devices with a single duct, such as e.g., used for a flow sensor. Micro-channels in Lab-on-Chip and Point-of-Care (POC) systems specify flow control to be very accurate when delivering fluid to a processing center (e.g., an analyzer) or when retrieving fluid from a reservoir.
In fluid flow meters, one aim is to achieve optimal mass flow readings across a micromachined chip; to this end, it is highly desirable to have a uniform and laminar flow. In the known art, this is currently achieved at the packaging level.
The known art has a number of drawbacks. In particular, in thermal fluid flow meters, laminar flow conditions are not always optimally controlled at packaging level, thus dissipating a relatively high amount of heat into a turbulent flow (this makes the flow sensor less sensitive). A thermal sensor of this type, therefore, does not provide reliable results of the measured flow temperature.
Moreover, thermoelectric infrared (IR) sensors are known in the art to exploit thermocouples in order to reveal IR radiations. A thermocouple includes two different materials which are connected at one end, while the other two ends are attached to a voltage meter. If there is a temperature difference between the common junction and the thermocouple ends connected to the voltmeter, then a thermo-voltage is revealed. The magnitude of the thermo-voltage is a function of the temperature difference. If an IR radiation, coming from an external object, is collected at the thermocouple common junction, the thermocouple junction warms up in response to the incident IR radiation. In this way, it is possible to reveal the IR radiation by sensing the thermo-voltage generated by the thermocouple. However, cooling a thermocouple junction typically employs thermal dissipaters at packaging level which increase the final size of the package and does not provide for an optimal level of integration.
One or more embodiments of the present disclosure is to provide an electronic device having an integrated temperature sensor which is reliable, cost effective, and of reduced dimensions. The electronic device may be used for a plurality of applications, in particular as a flow meter and an IR sensor.
Furthermore, the electronic device according to one embodiment of the present disclosure has at least one microchannel achieving laminar flow at die level and the microchannel have integrated flow feed-back provided by the presence of the thermocouple(s). In fact, by operating the temperature sensor as a thermal flow-meter, the flow within the microchannel can be controlled via real-time feedback with no additional components required. The packaging is therefore considerably simplified.
According to one embodiment of the present disclosure it is provided an electronic device having an integrated temperature sensor and a manufacturing method thereof, as defined in the attached claims.
For a better understanding of the disclosure, preferred embodiments thereof are now described, purely by way of non-limiting example and with reference to the annexed drawings, wherein:
According to the manufacturing steps of
With reference to
With reference to
With reference to
With reference to
According to an embodiment of the present disclosure, apertures 9 adjacent along X direction are spaced from one another of a distance d in the range 1 μm-5 μm, for example 2 μm. In other words, the distance d is the length (along X direction) of the portion of the mask 8 extending between adjacent apertures 9.
The distance d may be dependent on the initial thickness of the substrate and the targeted size of the buried channel, if wet etching is used. The distance d may also be chosen in a range which is appropriate to contain as many thermocouples as is specified by the particular application. Moreover, apertures 9 have respective length l, along Y direction, in the range of 500 μm-2000 μm, for example 1000 μm. The value of length l may be dependent on the dimensions of a channel 14, which is designed in such a way that the Reynolds number is below the turbulent limit (e.g., below a Reynolds number of 2100, preferably below 500).
Table 1 below provides examples dimensions of the channel and example parameters for exemplary fluids of water and air at varying temperatures.
With reference to
A second etching step is carried out to remove selective portions of the first dielectric layer 4 exposed through the mask 8 and through the etched portions of the second dielectric layer 6. In this way, portions 2a′ of the top surface 2a of the substrate 2 are exposed through trenches 10, as shown in
As it is apparent to the skilled person in the art, the shape of the trenches 10 are analogous to those of apertures 9 in the mask 8; however, dimensions of trenches 10, along X and Y directions, may be higher than corresponding dimensions of apertures 9, since, during the first and second etching step, a certain degree of under etch may be observed. Accordingly, when designing the mask 8, the possible underetch is to be taken into account, as it is apparent to the skilled person. The minimum distance d′, along X direction, representing the distance of a trench 10 from the adjacent trench 10, when considered from the top view of
With reference to
According to
In more details,
According to different embodiments, the covering layer 16 may be of a material other than polysilicon, which can be oxidized.
With reference to
It is noted that, given the relatively low thickness of the covering layer 16, the thermal oxidation step to form oxide layer 18 is self-controlled in the sense that, when substantially all the polysilicon material of the covering layer 16 has reacted with the oxygen-based gas supplied to the growth chamber, the oxide growth naturally comes to an end. Alternatively, the oxide-growing step may be monitored and stopped when the channel 12 is completely covered.
The oxide layer 18 is also formed in other regions of the wafer 1, in particular, where the previously formed covering layer 16 is present.
The oxide layer 18 may be formed using a different technique, for example a deposition technique, depositing silicon oxide (SiO2). Alternatively, another material, different from an oxide, may be used, for example silicon nitride (SiN). Accordingly, independent from the material used, the layer 18 is more generally a structural layer 18 which has the function of filling the spaces between the beams 11 in such a way to completely cover the channel 12 and forming the buried channel 14. The structural layer 18, moreover, covers the internal walls 12a, 12b of the channel 12. The material of the structural layer 18 may be chosen according to the type of fluid which, during use, is supplied to the buried channel 14. In particular, specifications such as biological compatibility may be taken into account. Silicon oxide and polysilicon oxide guarantee biological compatibility.
With reference to
With reference to
According to
According to the further embodiment of
According to further embodiments, not shown, the buried micro-channel 14/28/31 may have other shapes, such as oval or circular.
Irrespective of the particular cross section geometry of the buried channel, to have laminar flow, the Reynold number “Re” should be such that: Re=(u·l·F)/i where “u” is the average velocity of the flow (using meters/sec), “1” is the diameter of the channel (using meters), “F” is the density (in kg/m3) of the fluid, and “i” is the shear viscosity of the fluid (in kg/ms). Fluid flow in microchannels having a low Reynolds number (typically lower than 2100) is laminar. According to an aspect of the present disclosure, given a certain liquid to be supplied to the channel 14/28/31, the channel 14/28/31 is configured or designed in such a way to have a Reynolds number well below 2100, in particular lower than 1000, preferably lower than 500, e.g., equal to about 100.
Micro-pumps may be used to drive the fluid through the microchannel (to create a high pressure drop), for example integrating a pump at the system level. The pumping strength may influence the velocity of the fluid flow, but this is controllable, as it can be appreciated by the skilled technician, in order to not increase the Reynolds number “Re” over the laminar-flow threshold value.
Irrespective of the shape of channel 28 or channel 31 according to the embodiment of
With reference to
With reference to
With reference to
The first dielectric layer 36 is formed, in particular, by a known deposition technique, e.g., PECVD or LPCVD. The thickness of the first dielectric layer 36 is not uniform over the entire wafer 30, in particular it is thicker (e.g., in the range 1 μm-2 μm) around the sacrificial island 34 and thinner (e.g., in the range 0.5 μm-1.5 μm) on the sacrificial island 34, in such a way that the top surface 34a of the sacrificial island 34 substantially extends parallel to the XY plane. This is achieved by executing a polishing step (e.g., chemical-mechanical-polishing, CMP) after forming the first dielectric layer 36.
With reference to
With reference to
The shape and arrangement of the strip-like region 42 can be better appreciated considering
With reference to
With reference to
With reference to
With reference to
A channel 42 is thus formed.
With reference to
The covering layer 46 has a thickness from 450 nm to 1000 nm, in particular equal to 450 nm.
According to different embodiments, the covering layer 46 may be of a material other than polysilicon, for example silicon nitride (SiN) or silicon oxide (SiO2).
With reference to
It is noted that, given the relatively low thickness of the covering layer 46, the thermal oxidation step to form oxide layer 48 is self-controlled in the sense that, when substantially all the polysilicon material of the covering layer 46 has reacted with the oxygen-based gas supplied to the growth chamber, the oxide growth naturally comes to an end. Alternatively, the oxide-growing step may be monitored and stopped when the channel 42 is completely covered, thus obtaining the buried channel 44.
The oxide layer 48 is also formed in other regions of the wafer 30, in particular, where the previously formed covering layer 46 is present. In particular, since the superficial portions of the first dielectric layer 36 facing the inside of the channel 42, 44 were covered by a polysilicon layer, the oxidation step of
The oxide layer 48 may be formed using a different technique, for example a deposition technique, depositing silicon oxide (SiO2). Alternatively, another material, different from an oxide, may be used, for example silicon nitride (SiN). Accordingly, independently from the material used, the layer 48 is more generally a structural layer 48 which has the function of filling the aperture 41 in such a way to completely cover the channel 42 and to form the buried channel 44. The structural layer 48, moreover, covers the internal walls of the channel 44. The material of the structural layer 48 may be chosen according to the type of fluid which, during use, is supplied to the buried channel 44. In particular, specifications such as biological compatibility may be taken into account. Silicon oxide and polysilicon oxide guarantee biological compatibility.
With reference to
With reference to
According to an aspect of the present disclosure, after completing the manufacturing steps of
The manufacturing steps for forming thermopiles are shown in
According to further embodiments, not shown, the buried channel 14 may have other shapes, such as oval or circular.
Moreover, process steps of
In the following, further manufacturing steps are executed on dielectric layers 20 and 22 of
With reference to
With reference to
Each L-shaped element 65 has a leg 65′ extending over a portion of the buried channel 14, and another leg 65″, electrically coupled to the leg 65′, staggered with respect to the buried channel 14. Leg 65′ is the shorter leg of the “L”, while leg 65″ is the longer leg of the “L”. Accordingly, a portion (the leg 65′) of each L-shaped element 65 completely extends over, when considered along Z direction, the buried channel 14, and another portion (the leg 65″) of each L-shaped element 65 does not completely extends over the buried channel 14.
The L-shaped elements 65 may have dimensions chosen according to the specifications, and limited by the photolithographic technique used. For example, for each element 65, the shorter leg 65′ has a length of about 25 μm, while the longer leg 65″ has a length of about 200 μm.
As it will be appreciated later on, the elements 65 forming the mask 64 may have a shape different from “L”. For example, they may be straight elements having the form of a “I”, or other polygonal shapes. In any case, irrespective of the shape of each element 65, a portion of each element 65 extends over the buried channel 14 (i.e., that portion is aligned, along Z direction, with a respective portion of the channel 14), and another portion of the element 65 does not extend over the buried channel 14 (i.e., that portion is not aligned, along Z direction, with a respective portion of the channel 14).
With reference to
With reference to
With reference to
With reference to
With reference to
In particular, the superficial portions 74′ have, in a top view, a “L” shape analogous to the shape described for the first thermo-elements 68 and are formed in such a way that each exposed superficial portion 74′ is arranged between two adjacent first thermo-elements 68. Moreover, each exposed superficial portion 74′ has a region which overlaps a respective region of a first thermo-element 68 and another region which overlaps a respective region of another first thermo-element 68, wherein the two considered first thermo-elements 68 are adjacent to one another.
During an etching step, the third electrical-isolation layer 74 is selectively removed at the superficial portion 74′, exposing the second electrical-isolation layer 72 beneath.
During a further etching step, the second electrical-isolation layer 72 is selectively etched at the overlapping regions with the first thermo-elements 68 underlying, so as to form apertures 80 which expose the first thermo-elements 68.
With reference to
Moreover, the step of forming the second thermo-element layer 77 includes depositing the aluminum on the second electrical-isolation layer 72 where it is exposed.
A subsequent step of polishing (e.g., CMP) allows the removal of the second thermo-element layer 77 above the third electrical-isolation layer 74, and not where the second thermo-element layer 77 is in direct contact with the second electrical-isolation layer 72.
Second thermo-elements 82 are thus formed (
A plurality of thermocouples (each thermocouple including one first thermo-element 68 and one second thermo-element 82 electrically coupled together as described) are thus formed and, accordingly, it is also formed a thermopile 85 which includes a plurality of thermocouples connected in series to one another.
End portions E1, E2 of the thermopile 85 forms electrical terminals across which a voltage difference or voltage drop VOUT is present. The voltage VOUT varies with varying temperature of the thermocouples junctions, as it is per se known.
The manufacturing process according to the embodiment disclosed is completed,
It is noted that the plurality of first thermo-elements 68 and the plurality of second thermo-elements 82 (connected together forming a single thermopile) are at least partially suspended over the buried channel 14. Moreover, the first thermo-elements 68 and the second thermo-elements 82 are buried within a structural layer 87 which substantially forms a suspended membrane over the buried channel 14. Such a structural layer 87 comprises, in particular, the portion of dielectric layer 18 suspended over the buried channel 14 and the dielectric or insulating layers 20, 22, 70, 72, 74, 79, according to the embodiment of
The disclosed manufacturing method (according to any one of the described embodiments) is applicable to the manufacturing of flow-meter sensors (see
A thermal flow sensor (or flow-meter) 99, according to an embodiment of the present disclosure, is schematically shown in
The temperature sensors 102 and 103 are thermopiles, manufactured as disclosed, in particular, with reference to
The heater 100, which is substantially a strip (or serpentine) of a material which shows Joule effect when a current is made to flow through its ends, is integrated in the thermal flow sensor 99 above the channel 104, and is arranged between the first temperature sensor 102 and the second temperature sensor 103, for example buried within the third dielectric layer 20, or the fourth dielectric layer 22, or within the above electrical-isolation layers 70, 72 or 74 (not shown in
The oxide layer 18 forms a membrane 108 suspended over the channel 104, such that the first temperature sensor 102, the second temperature sensor 103 and the heater 100 are arranged at least partially over the membrane 108.
To measure the flow of a fluid which flows within the buried channel 104, it is supposed that the first temperature sensor 102 is arranged upstream and the second temperature sensor 103 is, consequently, arranged downstream. The “upstream” and “downstream” locations are, of course, defined with reference to the fluid flow direction (indicated by arrow F in
As a principle, the mass flow in the buried channel 104 is detected by a shift in the thermal balance of the first and second temperature sensors 102, 103.
The metering, or measuring, method is schematically explained in the following; however, it is generally known in the art. Here, the fluid flows through the buried channel 104. The first temperature sensor 102 is at a temperature Tup while the second temperature sensor 103 is at a temperature Tdown. The heater 100 is powered at a constant power. The resulting temperature profile in the buried channel 104 is asymmetric when the fluid flow is higher than zero (i.e., the fluid is flowing in the channel 104 at a certain velocity). The resulting temperature difference ΔT between Tup and Tdown is a measure for the mass flow, because the thermal shift is substantially related to the number of molecules passing the sensor.
The temperature Theater of the heater 100 is maintained at a certain value above the temperature of the incoming fluid (supposed to be Tup, measured by temperature sensor 102). When no fluid flows, Tup and Tdown are affected similarly by the heat from the heater 100. When there is a fluid flow (for example from Tup to Tdown), Tup falls while Tdown increases. This effect can be associated to a flow rate of the fluid, in a per se known way.
It is noted that relative values of the signal outputted by the two thermopiles 102, 103 are of practical interest, rather than the absolute value. The difference in the voltage outputs (VOUT2−VOUT1) of the downstream and upstream thermopiles 103, 102 can easily be associated to the temperatures to which thermopiles 102, 103 are subject and, as a consequence, to the velocity of the flow in the channel 104, from which the flow rate can be calculated in a per se known way.
If, according to another embodiment, not shown, the fluid were to flow on top the thermopiles 102, 103 rather than under, they would face the same situation. To obtain reliable results, the output of the temperature sensors 102, 103 is calibrated using a reference temperature sensor (not shown). For example, an output of value “Vout” from a thermopile may correspond to a temperature of “Tout” ° C. This calibration curve may then be stored in a memory (e.g., EEPROM) and a microcontroller references this curve before furnishing the final output. Furthermore, as the specific heat capacity and thermal capacitance or conductance of a material is constant, the heat dissipated by the dielectric/insulating layers extending between the membrane 108 and the temperature sensors 102, 103 is always a constant and can easily be compensated as an offset to the sensitivity of the device.
The volume flow rate Q is given by Q=V·A, where A is the measure of the channel cross-section (in X direction); and V is the average velocity of the fluid.
Mass flow rate W is given by W=r·Q, where r is the fluid density; and Q is the volume flow rate calculated as shown above.
A simple block diagram of a flow sensor system 121, including the flow sensor 99 and provided with computation circuitry, is shown in
The flow sensor 99 further includes a micro pump 110, configured to pump the fluid within the buried channel 104, with, e.g., a certain, predetermined, velocity which depends on the particular application. The information obtained by the measure of the mass flow rate can be used by the control unit 117 to control the micro-pump 110 such as to increment or reduce the mass flow rate of the fluid flowing in the buried channel 104. The pump 110 may be controlled by the control unit 117 in such a way to alter other parameters of the fluid, e.g., the quantity of the fluid inputted in the buried channel 14.
According to a further embodiment of the present disclosure, the manufacturing steps previously described with reference to
The IR absorbing layer 142 may be, according to a further embodiment, an IR filter.
The thermocouple/thermopile 144 provides at output a voltage signal VIR_OUT which is a measure of the temperature at the thermocouple/thermopile 144, due to the heat generated by the incoming IR radiation.
The output a voltage signal VIR_OUT is acquired, and interpreted, by a control circuit 147. The mere presence of a voltage signal VIR_OUT higher than a predefined threshold (which is a noise threshold) indicates that an IR radiation is revealed. Moreover, by calibrating the control circuit 147, the acquired value of the voltage signal VIR_OUT is also indicative of an amount of IR radiation which impinges on the IR absorber 142 and, as a consequence, warms up the thermocouple/thermopile 144.
Moreover, the thermocouple or thermopile 144 is preferably protected from visible and near-infrared light, in order to further increase measurement accuracy. Therefore, a shield blocking visible and near-infrared light may be provided, for preventing that such light reaches the thermocouple or thermopile, but not interfering with the IR radiation to be sensed. In the embodiment of
It is noted that, according to an aspect of the present disclosure, when the device 140 is used as an IR sensor, a buried channel 146 may anyway be provided under the thermocouple/thermopile 144, and a fluid may be pumped through the channel 146 by a controllable (micro)pump 148. In this case, the fluid flowing within the buried channel 146 acts as a coolant for the thermocouple/thermopile 144, thus achieving a cooled IR sensor which does not need external cooling means. The pump 148 may be controlled in such a way to alter the velocity or the quantity of the fluid in the buried channel such as to increase or reduce the cooling effect.
Finally, it is apparent that modifications and variations may be made to the embodiments described and illustrated herein, without thereby departing from the scope of protection of the present disclosure.
In the embodiments shown and described so far, a single buried channel was shown integrated in the substrate. In many applications, the number of buried channels may be higher than one. The length and course of the channels can be adapted to the respective specifications. Also depending on the intended application, several thermocouples/thermopiles can be integrated over a same single channel or over respective channels, such that a flow measurement or cooled IR detection can be carried out at several locations of a single fluidic-based device.
Moreover, it is noted that the “L” shape for the conductive elements forming a thermocouple is one of the numerous configurations in which a thermocouple may be fabricated. Two L-shaped elements form complementary elements of the thermocouple. These L-shaped elements are, in fact, serially connected together to form one large thermopile. This is one of the many possible configurations in which the two elements of the thermocouple, and the thermopile as a whole, may be fabricated and arranged. In some configurations, the two conductive elements of the thermocouple directly overlap each other, and the connection of one element to another is provided by a metal plug that runs perpendicular to the plane of the substrate (buried in insulating layers). In some configurations, the two elements may be placed side-by-side (but always separated by at least an insulating layer of dielectric such as oxide, e.g., SiO2). Finally, the L-shape is one among many possible shapes that can be possibly employed in the fabrication of a MEMS thermopile system. The short arm of the “L” is a lead that provides some space for the second “L” found on an upper level, to make contact with. In some examples, the elements of the thermocouple may be straight (as in the case where they are directly overlapped). Also, a serial connection of these thermocouples to form the thermopile lends itself to at least one level of “L”.
The various embodiments described above can be combined to provide further embodiments. These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.
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