Claims
- 1. An electrophoretic migration imaging process which comprises subjecting an electrically photosensitive colorant material positioned between at least two electrodes to an applied electric field and exposing said material to an image pattern of radiation to which the material is photosensitive, thereby obtaining image formation on at least one of said electrodes, the improvement which comprises using as at least a portion of said material an electrically photosensitive colorant ##STR28## wherein n equals 1 or 2;
- A represents phenylene, naphthylene, anthracenyl, anthracenediyl, and dibenzothien-diyl;
- R.sub.1 and R.sub.2, which may be the same or different when taken alone represent cyano, cyanoaryl, arylcarbonyl and hydrogen;
- R.sub.1 and R.sub.2, when taken together, represent sufficient atoms to form substituted and unsubstituted radicals selected from the group consisting of furanylidene, fluorenylidene, pyrimidinylidene, thiazolidinylidene, pyrrolinylidene, and isoxazolinylidene, pyrazolinylidene and indanylidene, wherein said substituents are selected from the group consisting of hydrogen, alkyl, cyano, aryl, oxo, thioxo, nitro, alkyl, nitroaryl, carbamoyl, and cyanoalkyl;
- alkyl represents an alkyl group having from one to six carbon atoms; aryl represents an aromatic nucleus selected from the group consisting of benzene, napthalene or anthracene; except that when:
- (A) A represents an anthracene nucleus and
- (i) R.sub.1 and R.sub.2 when taken together represent 1,3,5-trihydro-2,4,6-trioxo-pyrimidin-5-ylidene; 3-cyano-4-phenyl-2-oxo-pyrrolin-5-ylidene or 3-carboxy-inden-1-ylidene or
- (ii) taken alone R.sub.1 represents cyano and R.sub.2 represents methyl sulfonyl, phenylcarbamoyl or ethoxycarbonyl; or
- (iii) either R.sub.1 or R.sub.2 is alkylcarbonyl or phenylcarbonyl; then n represents 2; or
- (B) A represents a phenyl nucleus and R.sub.1 and R.sub.2 taken together represent 4,5-dicyano-1,3-dithiol-2-ylidene, n represents 2 or
- (C) R.sub.1 is hydrogen R.sub.2 must be other than hydrogen.
- 2. A process according to claim 1, wherein R.sub.1 and R.sub.2, when taken together represent sufficient atoms to form substituted and unsubstituted radicals selected from the group comprising 5-furanylidene; 9-fluorenylidene; 5-pyrimidinylidene; 5-thiazolidinylidene; 5-pyrrolinyl; 1 indanylidene; 4-isoxazolinylidene; and 4-pyrazolinylidene.
- 3. A process according to claim 1 wherein R.sub.1 and R.sub.2, when taken alone represent hydrogen, cyano, methylsulfonyl, phenylcarbonyl, phenylcarbamoyl, cyano alkyl, and cyano aryl.
- 4. A process according to claim 1 wherein
- n is 2;
- A represents phenylene, napthylene, anthracenediyl or benzothien-diyl;
- R.sub.1 and R.sub.2 both represent cyano or when taken together represent sufficient atoms to form a substituted or unsubstituted furanylidene and said substituent is selected from the group consisting of cyano, phenyl, nitrophenyl and oxo.
- 5. A process according to claim 1 wherein said material is selected from the group consisting of:
- 5,5'-(9,10-anthracenediyldimethylidyne)bis[3-cyano-4-phenyl-(5H)-furan-2-one]
- 5,5'-(9,10-anthracenediyldimethylidyne)bis[3,4-di-(p-nitrophenyl)-(5-H)-furan-2-one]
- 9,10-bis(dicyanoethenyl)anthracene
- 9-(9-anthracenylmethylidyne)-2,7-dinitrofluorene
- 5-(9-anthracenylmethylidyne(-1,3,5-trihydro-pyrimidine-2,4,6-trione
- 5,5'-(9,10-anthracenediyldimethylidyne)bis(1,3-diethyl1,3,5-trihydro-pyrimidine-2,4,6-trione)
- 5-(9-anthracenylmethylidyne)-1,3-diethyl-1,3,5-trihydropyrimidine-2,4,6-trione
- 5-(9-anthracenylmethylidyne)-1,3-diethyl-2-thioxo-1,3,5-trihydro-pyrimidine-4,6-dione
- 2,2'-(9,10-anthracenediyldimethylidyne)bis(indan-1,3-dione)
- 9-dicyanoethenyl anthracene
- 5,5'-(9,10-anthracenediyldimethylidyne)bis(N-ethyl-2-thioxo-thiazolidin-4-one)
- 5,5'-(9,10-anthracenediyldimethylidyne)bis(3-carbamoyl-4-phenyl-furan-2-one
- 5-(9-anthracenylmethylidyne)-3-cyano-4-phenyl-furan-5-one
- 4,4'-(9,10-anthracenediyldimethylidyne)bis(3-phenylisoxazolin-5-one)
- 4-(9-anthracenylmethylidyne)-3-phenyl-isoxazolin-5-one
- 5,5'-(9,10-anthracenediyldimethylidyne)bis(2-thioxothiazolidin-4-one)
- 4,4'-(1,4-phenylenedimethylidyne)bis(3-carbamoyl-1-phenyl pyrazolin-5-one)
- 1,1'-(1,4-phenylenedimethylidyne)bis(3-carboxy-indene)
- 2,6-bis(dicyanoethenyl)naphthalene
- 5,5'-(2,6-naphthalenediyldimethylidyne)bis(3-cyano-4-phenyl-furan-2-one)
- 2,6-bis[.beta.-cyano-.beta.-(p-cyanophenyl)ethenyl]naphthalene
- 5,5'-(dibenzothien-2,8-duyldimethylidyne)bis (3-cyano-4-phenyl-furan-2-one) and
- 5,5'-(dibenzothien-2,8-diyldimethylidyne)bis [3,4-di(p-nitrophenyl)-furan-2-one].
Parent Case Info
This is a continuation-in-part application of U.S. Ser. No. 804,042 filed June 6, 1977, to VanAllan et al now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
3915702 |
Bergfjord et al. |
Oct 1975 |
|
4052205 |
Stolka et al. |
Oct 1977 |
|
4072519 |
Pearson et al. |
Feb 1978 |
|
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
804042 |
Jun 1977 |
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