The present invention relates in general to the field of damage to engines by particles, and more particularly, to a novel electrostatic enhancement of inlet particle separators for engines.
Without limiting the scope of the invention, its background is described in connection with engine inlets and damage to engines by particles.
Engines such as gas turbine, gasoline, diesel, or hybrid, require a flow of ambient air during operation. Highly powerful engines such as turbine engines in aircraft or engines in high performance vehicles require an extremely large flow of air for combustion of fuel. Aircraft (helicopter, airplane, etc.) flights to and from unprepared airfields expose their engines to ingestion of foreign objects, particularly dust and sand entrained in the surrounding air as frequently stirred up by the aircraft itself. The ingestion of dust causes erosion of turbine engine components such as turbine and compressor blades and blockage of cooling-hole passages. The resulting effects include loss of power, increased fuel consumption and reduced engine life. The dust concentrations encountered during flight in natural environments vary greatly but during extreme conditions of brownout may reach 2.5 g/m3. [Barone, 2014] Typical ingested particle dust sizes range from 0-1,000 μm and the distribution may vary depending on the wind velocity, levels of precipitation, and surrounding vegetation.
Current engine protection systems include inlet particle separators (IPS), e.g., Hull and Nye, U.S. Pat. No. 3,832,086, Lastrina, et al., U.S. Pat. No. 4,527,387, and Klassen et al., U.S. Pat. No. 4,685,942; for vortex tube separators, e.g., Lundquist and Thomas, U.S. Pat. No. 7,879,123; and barrier filters, e.g., Izzi, et al., U.S. Pat. No. 4,527,387, and Klassen et al., U.S. Pat. No. 4,685,942, to limit entry of sand and dust particles. These and related inertial particle separation designs are incorporated into the present invention by reference. The first two systems provide good protection against coarse sand and dust particles but exhibit poor separation efficiency for very fine sand (0-20 μm). Barrier filters have high filtration efficiency but result in increased pressure drop over the period of operation, and therefore, need maintenance at regular intervals. There is a need in the aviation industry to efficiently filter dust particles, especially fine sand (1-80 μm).
Despite not having the highest efficiency among engine protection systems, IPS technology currently provides the most compact and light weight system for foreign object damage mitigation and engine protection that can be tightly integrated with the engine. They are designed and qualified with the engine and are typically compact with acceptable pressure drop (˜1%). They have a higher volume flow rate per unit area of intake protection than vortex tube separators, which translates to a lower drag penalty. The IPS separates particles from the intake air flow by changing the direction of motion of the flowing air, in such a way that the particle trajectories cross over the air streamlines, and the particles are concentrated into a smaller air flow called the scavenge flow. The larger air flow called the core flow has a lower concentration of dust particles and it flows from the IPS into the engine. In other words, the IPS splits the intake airflow into core flow and scavenge flow, with the latter containing majority of the dust particles. The separation efficiency can be defined as the mass of dust present in the scavenge flow divided by the mass of dust present in the intake airflow. IPSs are effective against large particles but smaller particles are not amenable to the inertial separation method. For example, the IPS separation efficiency for T700 engine is 91.7% for coarse sands and drops to 64% for fine sands. Typically, overall separation efficiency of IPSs is about 70% for fine particles (1-80 um).
U.S. Pat. No. 4,010,011, issued to Reif, discloses the use of an electrostatic device with an air spinner to treat dust laden engine air flow but with the object of electrostatically enhancing the outward migration of dust particles over the inertial affect produced by the air spinner rather than agglomerating fine dust particles. Prior patents, e.g., Lundquist and Thomas, U.S. Pat. No. 7,879,123 and Snyder and Vittal U.S. Pat. No. 6,508,052, teach the use of multiple particle separator tubes but the claimed enhanced separation is achieved by inertial separation, rather than due to agglomeration by electrostatic means. U.S. Pat. No. 4,309,199, issued to Suzuki, discloses the application of corona discharge and a cyclone separator in a single device to clean air intake of internal combustion engines. In that patent, the goal was to charge and collect the dust particles inside the cyclone separator, which requires periodic cleaning to remove dust particles that act as a dielectric layer on the collecting surface reducing the efficiency of the device.
Recent U.S. Patent Application Publication Nos. 2015/0198090 and 2016/0265435 relate to turbine engine applications describe electrostatic devices or electrostatic generators. In U.S. Patent Application Publication No. 2016/0265435, Snyder, describes the use of electrostatic generators. The present invention ensures that all of the intake air passes through the electrostatic charging stage(s) while incurring minimal pressure loss as is required for turbine engine applications. It is recognized by those experienced in the field of present invention that the electrostatic charging of particles is enhanced by high-electric field, high charge concentration, and low residence time. The present invention ensures that a high electric field is available for charging particles due to the logarithmic enhancement of the electric field. Additionally, a greater charge production is ensured due to the logarithmic enhancement of the electric field, resulting in high concentration of charges.
U.S. Patent Application Publication No. 2015/0198090, filed by Howe et al., describes an electrostatic grid that is disposed adjacent to or extending partially across the air inlet. The grid design is not described to extend along the direction of the flow. This localized implementation may not effectively charge most or all of the particles well dispersed in the airflow. In contrast, in the present invention, the residence time of the dust particles in the electrostatic device can be increased by elongation of the electric field along the direction of the flow.
U.S. Patent Application Publication No. US2015/0354461, filed by Meier et al., describes an arrangement of multiple tubes with circular cross-section to electrostatically charge particles and collect them for cooling arrangement for a gas turbine engine. Our present invention is for charging, agglomeration, and deflection of the charged and agglomerated particles into a secondary flow. The disadvantage of using tubes with circular cross-section is that there are gaps between the edges of the circular cross-section tubes because they cannot be packed efficiently. Hence the area available for flow is considerably reduced resulting in pressure drop that is significant for turbine engine intake applications. The present invention is based on honeycomb structure that has hexagonal cells resulting in better packing, greater flow area, and lower pressure loss than circular cross-section tubes. The honeycomb structure is made of hexagonal cells that share their walls among each other. Therefore the weight of the device consisting of honeycomb structure is also lower than that consisting of tubes with circular cross-section. Minimization of the weight of the device results in lower penalty on turbine engine power.
The present invention relates to a multi-stage electrostatic enhancement process for improvement of particle separation efficiency of inlet particle separators used in turbine engines. The process includes the following stages: Particle Charging, Agglomeration, and their Deflection and Separation into a preferred flow stream. In the Particle Charging stage, high charge generation is achieve with low pressure drop in intake air flow and low weight penalty. Agglomeration of the charged particles is achieved by the use of electric field or by the use of turbulent mixing features. The separation efficiency of the IPS is greater for larger particles than finer particles, therefore charging and agglomeration of fine particles improves the overall separation efficiency of the IPS. Additional improvement in separation efficiency is achieved by deflection of the charged particles, away from the engine flow path (core flow) into the scavenge flow path by an electric or magnetic field. The multi-stage electrostatic enhancement process can be controlled or modulated in conjunction with a particle sensor installed in the air flow stream. Data generated in laboratory tests demonstrates improvement in the separation efficiency of a small scale IPS.
In one embodiment, the present invention includes a particle deflection system including a particle charging device including: one or more openings adapted to receive particles in a fluid stream and that impart an electrical charge to particles in the one or more openings; a particle agglomeration device in fluid communication with the particle charging device and including one or more mixing surfaces adapted to agglomerate or mix the one or more particles electrically charged by the particle charging device in the fluid stream; and a particle deflection device adapted to separate agglomerated particles in the fluid stream from a core flow that is substantially free of particles.
In another embodiment, the present invention also includes a method for using enhanced separation efficiency of inertial separators, including: unipolarly charging a device to impart predominantly positive or negative charges on particles in a gas stream; agglomerating the charged particles installed downstream to the particle charging device; and generating an electric or magnetic field to deflect the agglomerated or charged particles to enhance their separation into multiple gas streams, wherein particles are removed from the gas stream to enhance the separation efficiency of the inertial separators.
In another embodiment, the invention includes an engine including a particle deflection system upstream from the engine intake, including: a particle charging device including one or more openings adapted to receive particles in a fluid stream and that impart an electrical charge to particles in the one or more openings; a particle agglomeration device in fluid communication with the particle charging device and including one or more mixing surfaces adapted to agglomerate or mix the one or more particles electrically charged by the particle charging device in the fluid stream; and a particle deflection device adapted to separate agglomerated particles in the fluid stream from a core flow that is substantially free of particles.
Yet another embodiment, includes a kit adapted to protect an engine, including: a particle charging device including: one or more openings adapted to receive particles in a fluid stream and that impart an electrical charge to particles in the one or more openings; a particle agglomeration device in fluid communication and downstream from the particle charging device, the particle agglomeration device including one or more mixing surfaces adapted to agglomerate or mix the one or more particles electrically charged by the particle charging device in the fluid stream; and a particle deflection device in fluid communication with and downstream from the particle agglomeration device, the particle deflection device adapted to separate agglomerated particles in the fluid stream from a core flow that is substantially free of particles.
In yet another embodiment, the present invention also includes a system to enhance separation efficiency of inertial separators, including: a device to impart predominantly positive or negative charges (unipolar charging) on particles in a gas stream; a device to promote agglomeration of the charged particles in the gas stream installed downstream to the particle charging device; and a device to generate an electric or magnetic field to deflect the agglomerated or charged particles to enhance their separation into two or more gas streams, wherein particles are removed from the gas stream to enhance the separation efficiency of the inertial separators.
In one embodiment, the present invention includes a system for enhancing a particle separation efficiency including a particle charging device adapted to impart predominately unipolar charging on a plurality of particles in a fluid stream; wherein the particle charging device is positioned upstream from and adapted to provide the plurality of particles charged by the particle charging device to a particle deflection device capable of separating the particles charged by the particle charging device from a core fluid flow that is substantially free of dust particles. In one aspect, the particle charging device is adapted to impart predominately unipolar charging using an electric discharge. In another aspect, the electric discharge is generated between a rod or a wire positioned substantially along the longitudinal axis of a tube and the tube. In another aspect, the tube has a substantially circular cross section or a non-circular cross-section. In another aspect, the electric discharge is generated between a plurality of rods or wires positioned within an annulus. In another aspect, the annulus is partitioned into a plurality of partial-annulus sections, and each partial-annulus section has at least one rod or wire positioned within it. In another aspect, the electric discharge is generated between one or more protrusions and a flat or curved surface. In another aspect, the curved surface is within an annulus. In another aspect, the annulus is partitioned into a plurality of partial-annulus sections, and each partial-annulus section has at least one protrusion positioned within it. In another aspect, the electric discharge is generated between a plurality of protrusions positioned on opposite sides of the annulus. In another aspect, the electric discharge is a corona discharge, a dielectric barrier discharge, a radio-frequency-inductively coupled plasma discharge, an arc discharge, or a gliding arc discharge. In another aspect, the particle charging device is adapted to impart predominately unipolar charging using an ionizing radiation device. In another aspect, the ionizing radiation device uses ionizing radiation produce by a source of x-rays or a decay of radioactive material. In another aspect, the system further includes an agglomeration device adapted to promote agglomeration of particles charged by the particle charging device. In another aspect, the agglomeration device is adapted to promote agglomeration of particles by a turbulent mixing or by an electric field. In another aspect, the electric field is a constant electric field, a time-varying electric field, or a pulsed electric field. In another aspect, the time-varying field is an oscillating electric field. In another aspect, the turbulent mixing uses one or more protrusions in a fluid stream. In another aspect, the turbulent mixing uses vortices having rotational axes substantially parallel to a direction of flow of the fluid stream, substantially perpendicular to the direction of flow of the fluid stream, or at varying angles to the direction of flow of the fluid stream. In another aspect, the particle deflection device is adapted to separate the particles charged by the particle charging device using a constant electric field, a time-varying electric field, a pulsed electric field, a constant magnetic field, a time-varying magnetic field, or a pulsed magnetic field. In another aspect, the time-varying electric field is an oscillating electric field that is unbiased, biased positively, or biased negatively. In another aspect, the particle separation system is adapted for use with a flow separator to separate the particles charged by the particle charging device and deflected by the particle deflection device into a scavenge flow. In another aspect, the flow separator is an inertial particle separator, a centrifugal particle separator, a cyclonic particle separator, or a porous medium. In another aspect, the system further includes one or more sensors to sense a chemical composition of particles, a particle size, or a particle concentration. In another aspect, information from the one or more sensors informs control of individual components of the system. In another aspect, the one or more sensors are adapted to identify at least one of soil particles, particles from sea spray, particles from volcanic eruption, or particles from anthropogenic particulate emission. In another aspect, the one or more sensors include an optical sensor, an electrical sensor, a chemical sensor, a spectroscopic sensor, a sensor that uses Raman spectroscopy, or a sensor that uses laser-induced breakdown spectroscopy. In another aspect, the plurality of particles include particles of at least one of silica, gypsum, silicates, dolomite, salt, carbon, organic compounds, or metal oxides. In another aspect, the separation takes place in an engine that is in a stationary device, is in a vehicle, is in or about an aircraft, is in a vehicle for transportation on a land surface, is in a vehicle for transportation on the surface of a body of water, is in a vehicle for transportation on either a land surface or the surface of a body of water as needed, or is in a vehicle for transportation beneath the surface of a body of water. In another aspect, the engine is at least one of: a jet engine, a turbine engine, a supercharged engine, a compressor engine, a turbojet engine, a turbofan engine, a turboprop engine, a ramjet engine, a pulse jet engine, a scramjet engine, or an electric motor engine.
In another embodiment, the present invention includes a method of enhancing separation of particles from a fluid flow, including imparting predominately unipolar charging on each of a plurality of particles in a fluid stream; and separating the particles after they have been charged from a core fluid flow that is substantially free of particles. In one aspect, the imparting predominately unipolar charging on each of a plurality of particles in a fluid stream is performed using an electric discharge. In another aspect, the electric discharge is generated between a rod or a wire positioned substantially along the longitudinal axis of a tube and the tube. In another aspect, the tube has a substantially circular cross section or a non-circular cross-section. In another aspect, the electric discharge is generated between a plurality of rods or wires positioned within an annulus. In another aspect, the annulus is partitioned into a plurality of partial-annulus sections, and each partial-annulus section has at least one rod or wire positioned within it. In another aspect, the electric discharge is generated between one or more protrusions and a flat or curved surface. In another aspect, the curved surface is within an annulus. In another aspect, the annulus is partitioned into a plurality of partial-annulus sections, and each partial-annulus section has at least one protrusion positioned within it. In another aspect, the electric discharge is generated between a plurality of protrusions positioned on opposite sides of an annulus. In another aspect, the electric discharge is a corona discharge, a dielectric barrier discharge, a radio-frequency-inductively coupled plasma discharge, an arc discharge, or a gliding arc discharge. In another aspect, the imparting predominately unipolar charging on each of a plurality of particles in a fluid stream is performed using an ionizing radiation device. In another aspect, the ionizing radiation device uses ionizing radiation produce by a source of x-rays or a decay of radioactive material. In another aspect, the method further includes promoting agglomeration of the particles after they have been charged. In another aspect, the promoting agglomeration of particles after they have been charged is performed by a turbulent mixing or an electric field. In another aspect, the electric field is a constant electric field, a time-varying electric field, or a pulsed electric field. In another aspect, the time-varying field is an oscillating electric field. In another aspect, the turbulent mixing uses one or more protrusions in a fluid stream. In another aspect, the turbulent mixing uses vortices having rotational axes substantially parallel to a direction of flow of the fluid stream, substantially perpendicular to the direction of flow of the fluid stream, or at varying angles to the direction of flow of the fluid stream. In another aspect, the separating the particles after they have been charged is performed using a constant electric field, an time-varying electric field, a pulsed electric field, or a constant magnetic field, a time-varying magnetic field, or a pulsed magnetic field. In another aspect, the time-varying electric field is an oscillating electric field that is unbiased, biased positively, or biased negatively. In another aspect, the method is adapted for use with a flow separator to separate the particles charged by the particle charging device and deflected by the particle deflection device into a scavenge flow. In another aspect, the flow separator is an inertial particle separator, a centrifugal particle separator, a cyclonic particle separator, or a porous medium. In another aspect, the method further includes sensing a chemical composition of particles, a particle size, or a particle concentration. In another aspect, information from the sensing informs control of individual components of the system. In another aspect, the sensing includes identifying at least one of soil particles, particles from sea spray, particles from volcanic eruption, or particles from anthropogenic particulate emission. In another aspect, the sensing includes Raman spectroscopy or laser-induced breakdown spectroscopy. In another aspect, the plurality of particles includes particles of at least one of silica, gypsum, silicates, dolomite, salt, carbon, organic compounds, or metal oxides. In another aspect, the method is used with an engine that is in a stationary device, is in a vehicle, is in or about an aircraft, is a vehicle for transportation on a land surface, is a vehicle for transportation on the surface of a body of water, is a vehicle for transportation on either a land surface or the surface of a body of water as needed, or is a vehicle for transportation beneath the surface of a body of water. In another aspect, the engine is at least one of: a jet engine, a turbine engine, a supercharged engine, a compressor engine, a turbojet engine, a turbofan engine, a turboprop engine, a ramjet engine, a pulse jet engine, a scramjet engine, or an electric motor engine.
In another embodiment, the present invention includes an engine including a system for enhancing a particle separation efficiency, including a particle charging device adapted to impart predominately unipolar charging on a plurality of particles in a fluid stream; wherein the particle charging device is positioned upstream from and adapted to provide the plurality of particles charged by the particle charging device to a particle deflection device capable of separating the particles charged by the particle charging device from a core fluid flow that is substantially free of dust particles. In one aspect, the engine is at least one of: a jet engine, a turbine engine, a supercharged engine, a compressor engine, a turbojet engine, a turbofan engine, a turboprop engine, a ramjet engine, a pulse jet engine, a scramjet engine, or an electric motor engine. In one aspect, the engine is in a stationary device, is in a vehicle, is in or about an aircraft, is in a vehicle for transportation on a land surface, is in a vehicle for transportation on the surface of a body of water, is in a vehicle for transportation on either a land surface or the surface of a body of water as needed, or is in a vehicle for transportation beneath the surface of a body of water.
In another embodiment, the present invention includes a kit adapted to protect an engine, including a particle charging device adapted to impart predominately unipolar charging on a plurality of particles in a fluid stream; wherein the particle charging device is positioned upstream from and adapted to provide the plurality of particles charged by the particle charging device to a particle deflection device capable of separating the particles charged by the particle charging device from a core fluid flow that is substantially free of dust particles.
For a more complete understanding of the features and advantages of the present invention, reference is now made to the detailed description of the invention along with the accompanying figures and in which:
While the making and using of various embodiments of the present invention are discussed in detail below, it should be appreciated that the present invention provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed herein are merely illustrative of specific ways to make and use the invention and do not delimit the scope of the invention.
To facilitate the understanding of this invention, a number of terms are defined below. Terms defined herein have meanings as commonly understood by a person of ordinary skill in the areas relevant to the present invention. Terms such as “a”, “an” and “the” are not intended to refer to only a singular entity, but include the general class of which a specific example may be used for illustration. The terminology herein is used to describe specific embodiments of the invention, but their usage does not limit the invention, except as outlined in the claims.
The following detailed description explains one of the many ways in which the present invention can be applied. The three stages in the present invention 10 can be summarized as shown in
Particle Charging Stage 1.
In the Particle Charging Stage 1 at step 14, the particles are imparted charges by a source of electrical discharge or a source of ionizing radiation. An electrical discharge is a flow of electrical charge through any matter. One type of electrical discharge is a corona discharge that is generated by maintaining a potential difference between two electrodes of non-uniform geometry such as a rod or a wire installed along the central axis of a tube.
Table 1 includes the data for
The experimentally determined charge production rate (coulombs/cm3·s) for a charger tube with hexagonal cross-section is shown in
Prolonged operation of the charger tube can result in accumulation of particles along the tube surface, which can reduce charging effectiveness and eventually lead to unstable operation due to sparking. The present invention includes a means to reduce such accumulation of particles. Application of negatively biased AC voltage (12-16 kV peak, peak-peak change of 1 kV, 10 Hz-60 kHz) to the stressed electrode is the preferred embodiment to reduce accumulation of particles in the charger tube connected to a negative voltage source. Therefore another advantage of the present invention is the application of negatively biased AC voltage to enable long term operation of electrostatic charging devices. An approach to prevent sparking in the charger tube is to internally line the ground electrode with a dielectric film and/or to encapsulate the stressed electrode in a dielectric tube. The dielectric material can be any material with dielectric strength greater than 3 MV/m. These materials include plastics (Teflon, PEEK, etc.), quartz, and ceramics (oxides, carbides, nitrides, etc). This dielectric-lined charger tube can be operated in the pulsed DC mode (12-16 kV peak with <1 ms pulse width) or biased AC mode (12-16 kV peak, peak-peak change of 1 kV, 10 Hz-60 kHz) for electrostatic charging of particles.
Particle Charging Stage 1 Geometry Considerations
For turbine engine applications a single charger tube may be used or multiple charger tubes may be arranged, such that the particles in the large intake air volume/flow can be sufficiently accommodated and charged, according to the aforementioned specifications. These charger tubes can be packed together to form a bundle similar in shape to the annular opening of the IPS. These charger tubes can have any cross-sectional shape such as a circular, hexagonal, square, triangular, rectangular, etc. and can be arranged in any layout but they should provide the greatest open area for flow to ensure low pressure drop in intake air flow for turbine engine applications. Unlike circular cross-section, other cross-sections such as circular, square, triangular, rectangular, etc. can be packed together to have common or shared walls, thereby reducing material required to build them and the total weight. A comparison between circular and hexagonal cross-section geometries shown in
Particle Agglomeration Stage 2
Air containing unipolarly charged dust particles from the Particle Charging Stage 1 can be flown into the Particle Agglomeration Stage 2. The goal of this Stage is to agglomerate the incoming charged dust particles and thereby enhance IPS separation efficiency, since the IPS separates larger particles more efficiently than finer particles. The Particle Agglomeration Stage 2 can accomplish agglomeration by the use of electric fields and/or by the use of turbulent mixing features. The electric field is distinct from the one used in Particle Charging Stage 1. One embodiment of the use of electric field is shown in
Another embodiment of Particle Agglomeration Stage 2 is the generation of turbulence in the airflow containing charged dust particles to promote interparticle collision and agglomeration.
Particle Deflection and Separation Stage 3
Air containing the charged and agglomerated dust particles is then flown into the Particle Deflection and Separation stage. This stage is integrated into an inertial separation device 200 such as the IPS as shown in
Voltage Considerations
As shown in
In laboratory testing, a bundle of six charger tubes with a circular cross-section (Φ1″×6″ long), a 3″ long agglomeration field (Φ3″×Φ1.325″ similar to
[(Dust injected into airflow−Dust captured by core filter)/Dust injected into air flow]×100
The improvement in separation efficiency of the IPS by electrostatic enhancement is shown in
Table 2 shows the data for
In similar laboratory testing, a Particle Charging Stage 1 containing seven charger tubes of hexagonal cross-section and an Agglomeration Stage 2 and Deflection Stage 3 was used with a scaled-down version of the full-scale IPS mentioned above. The hexagonal tube (0.612″ side×6″ length) was grounded while the 0.039″ diameter rod was used as the high potential electrode.
Table 3 is the data for
The multi-stage electrostatic enhancement process described above can be connected to a sensor for the activation or modulation of individual stages depending on the concentration of dust in the intake air. A sensor capable of estimating particle concentration, particle size range, and/or chemical composition of particles in the air flow can be used. The sensor can be based on techniques such as Raman Spectroscopy and Laser Induced Breakdown Spectroscopy. The particle sensor data can aid in tuning of the Particle Charging, Particle Agglomeration, and Particle Deflection. A particle sensor that provides information on the charging state of the particles can also provide feedback to the overall process to determine the charging voltage polarity, waveform, and frequency and deflection field polarity, and frequency. The above discussed particle sensors can serve as part of aircraft crew or personnel notification system.
Inlet particle separators only prevent 60-70% of fine dust particles (1-80 μm) from entering the core flow of the turbine engine. Therefore, operation of helicopters in dusty environments can cause significant damage to different sections of the turbine engines due to ingestion of fine dust particles. The damage to the engines leads to performance deterioration, frequent maintenance, reduced engine life, lower flight safety, and higher costs. Enhancement of IPS performance with minimal addition to pressure drop and engine weight is highly desirable for use of advanced turbine engines in challenging environments.
While the present invention is discussed herein in terms of aircraft, one skilled in the art will recognize that it can be used in engines of stationary devices such as generators and in engines of a variety of vehicles including aircraft, land vehicles, water-borne vehicles, amphibious vehicles, and underwater vehicles.
The approach of the present invention to improve the separation efficiency of the inlet particle separator (IPS) involves electrostatic charging of dust particles followed by their deflection into scavenge flow path of the IPS. The concept of electrostatic enhancement for a generic IPS is shown in
The electrostatic enhancement system can improve separation of particles by inlet particle separators for turbine engines during taxiing, hovering, take-off, final approach, landing and any other phases of flight. The system can be active during the whole flight or can be activated prior to approaching a dusty region such as a desert or region of volcanic activity.
The electrostatic charging of dust particles is achieved in a Corona Charger, wherein a corona discharge is produced by high strength electric field. The corona discharge is a type of low temperature plasma, generated by application of a high voltage between two electrodes of non-uniform geometry such as a tube with a wire installed at its central axis or a sharp edge positioned close to a plane. Upon application of high voltage between the electrodes, a corona discharge occurs when the dielectric strength of air (31 kV/cm at 25° C. and 1 atmosphere) is exceeded by the electric field in the gap. Charged species such as ions and electrons are generated which impart charge to dust particles though collision and subsequent adsorption.
Embodiments of the present invention can be used to enhance particle separation in fluid streams such as engine intake flow, core flow, or scavenge flow, and that embodiments of the present invention can be used to enhance particle separation with a inertial particle separator, a centrifugal particle separator, a cyclonic particle separator, or with a porous medium such as a filter.
Embodiments of the present invention use an electric discharge suitable to charge particles that is generated using a variety of equipment geometries, including a rod or a wire positioned substantially along the longitudinal axis of a tube and the tube, where the tube has either a substantially circular cross section or a non-circular cross-section such a triangular, square, rectangular, hexagonal cross-section, and the electric discharge is generated between the rod or wire and the tube. Embodiments of the present invention also generate a suitable electric discharge between a rod or wire positioned within an annulus and the annulus. Embodiments of the present invention also generate a suitable electric discharge between a plurality of rods or wired positioned within an annulus, which may be partitioned into partial-annulus sections, each with a rod or wire positioned within it. Embodiments of the present invention also generate a suitable electric discharge between a protrusion and a flat or curved surface, where the curved surface may be within a annulus, and the annulus may be partitioned into a plurality of partial-annulus sections, each with a protrusion positioned within it. Embodiments of the present invention also generate a suitable electric discharge between a plurality of protrusions positioned on opposite sides of an annulus.
Further, embodiments of the present invention charge particles in a variety of ways, including an electric discharge (including a corona discharge, a dielectric barrier discharge, a radio-frequency-inductively coupled plasma discharge, an arc discharge, or a gliding arc discharge), or an ionizing radiation device (e.g., from a source of x-rays or from the decay of radioactive material).
Further, embodiments of the present invention deflect charged particles in a variety of ways, including an electric field of constant magnitude, a time-varying electric field at any frequency (e.g., an oscillating field), a pulsed electric field at any frequency, or a magnetic field of constant magnitude, a time-varying magnetic field at any frequency (e.g., an oscillating field), a pulsed magnetic field at any frequency. The time-varying field may be unbiased, biased positively, or biased negatively.
Embodiments of the present invention use sensors to estimate the chemical composition of particles, particle size, and particle concentration in fluid flow. Embodiments of the present invention use such sensors to communicate with one or more computers to control or modulate the individual devices in the embodiments. Embodiments of the present invention include sensors adapted to detect, size, and quantify from sources of particles, such as soil erosion, sea spray, volcanic eruptions, and anthropogenic sources of particulate emission, and such particles may include particles of silica, gypsum, silicates, dolomite, salt, carbon, organic compounds, and oxides of various metals. Embodiments of the present invention include one or more optical sensors, electrical sensors, chemical sensors, and sensors that use spectroscopy, including Raman spectroscopy and laser-induced breakdown spectroscopy.
Herein follows an analysis where multiple factors are modeled leading to an inventive Corona Charger that improves particle separation (along with the Deflection Field) within an IPS at high flow velocity (short particle retention times) with low pressure drop. The electrostatic charging of dust particles is achieved in the charging field of the Corona Charger due to collision between particles and ions moving rapidly in an electric field. The ions generated in the Corona Charger are driven to a particle along the applied electric field and they collide with a particle and transfer their charge to it. The number of charges n(t) imparted by ions in an electric field E for a given residence time t is given as follows:
Here ε is the dielectric constant of the particles, E is the applied electric field, dp is the particle diameter, kE is Coulomb's law constant (8.987×109 Nm2/C2), e is the charge of an electron (1.602×10−19 C) and Zi is the mobility of ions (for air, Zi˜1.5×10−4 m2/Vs). A linear dependence of particle charging on electric field and residence time is evident from Equation 1. It can also be inferred that larger particles can acquire greater charge than smaller particles for similar residence times as the charging process is proportional to the square of the particle diameter.
The second mechanism of charging occurs when an ion collides with a particle due to Brownian motion and there is a charge transfer to the particle. This process is dependent on the temperature of the gas and does not require an electric field. As the number of collisions increase with time, charges accumulate on the particle, which produces a field that repels additional ions. If sufficient time is allowed, these particles achieve a Boltzmann distribution in the absence of any external field. An approximation for the number of charges n(t) acquired by a particle of diameter dp by diffusion during time t is given by Equation 2:
Here
The electrostatic charging of dust particles is dependent on the following factors: (i) Corona Charger parameters, (ii) particle residence time in the Charger, (iii) particle size and concentration, and (iv) particle material. The effect of each of these factors on electrostatic charging will be discussed in detail below.
Effect of Corona Charger Parameters: The Corona Charger parameters that control the electrostatic charging of dust particles are ion concentration and electric field. The effect of ion concentration on the amount of charge imparted to silica particles is shown in
The effect of change in electric field in the Corona Charger on the electrostatic charging of 10 μm silica particles is shown in
Effect of Particle Residence Time: The particle residence time in the Corona Charger is dictated by the velocity of intake air in the Charger. Based on airflow of 8-10 lb/s and the dimensions the Corona Charger, the residence time of the particles is on the order of few milliseconds. The effect of particle residence time was studied by varying it as follows: approximately 1.3 (1×), 4.0 (3×), and 6.7 ms (5×). The total charge imparted per particle was calculated as per Equation 1 and Equation 2 and is shown in
Effect of Particle Size and Concentration: To demonstrate how particles of different sizes are charged, six different particle sizes ranging from 1 to 80 μm were selected from the Arizona A2 fine test dust datasheet. The particle material was assumed to be silica and the concentration was fixed at 53 mg/m3 for each of the six cases. The particle residence time for each case was 1.33 ms. The total number of charges imparted to each particle of a particular diameter is shown in
The dust concentration recommended for engine testing is 53 mg/m3 as per MIL-SPEC. (Specification Development Document—Engines, Aircraft, Turboshaft, Sep. 2, 2014.) During takeoff and landing from dusty fields, higher concentration of dust particles may exist and approach 2500 mg/m3 (brownout). The smallest and largest particle sizes (1 and 80 μm) are considered for this analysis. These two sizes would provide the largest and smallest values of number concentration. Assuming all the particles have a diameter of 1 μm, the number concentration ranges from 3.96×1010 to 1.87×1012/m3 as shown in
Effect of Particle Material: The solid particles encountered by aircraft engines vary not only in size but also in chemical composition. The solid particles may include fine sand, dust, ash, etc. The chemical composition of the solid particles varies widely based on geographic location and season. For laboratory investigation of effect of solid particle ingestion on engine components and performance, standardized test dusts have been developed such as ISO12103-1, Arizona A2 Fine (ISO 12103-1 Arizona Test Dust Contaminants A2 Fine, Powder Technology Inc.) and AFRL03 (AFRL03, Proposed particle size specification, Powder Technology Inc.).
Arizona A2 fine test dust is widely used in testing of air cleaning and filtration equipment for automotive and aircraft engines. The results from chemical analysis of the Arizona A2 fine test dust is shown in Table 4. The density and relative permittivity (dielectric constant) were compiled from literature survey to determine the effectiveness of electrostatic charging for each of the reported constituents. The density of particles determines the number concentration for a particle mass concentration and particle size. The relative permittivity reflects the strength of the electrostatic field produced within the particle by a fixed potential relative to that produced in a vacuum under the same conditions.
The influence of particle material on the ability to acquire charge is seen in
The AFRL03 test dust is used to study the effects of particle ingestion, such as impact erosion in the cold sections of the engine and formation of glassy deposits in the hot sections of engines. Table 5 lists the constituents and their proportions used to prepare AFRL03 test dust. The major components are quartz, gypsum, aplite, dolomite, and salt. Aplite is a mixture of quartz and aluminosilicates such as potassium feldspar (KAlSi3O8), albite (NaAlSi3O8), and anorthite (CaAl2Si2O8). The density and relative permittivity were compiled from literature survey. Among aluminosilicates, the density and relative permittivity for only orthoclase feldspar was found in our survey.
A preliminary design of the Corona Charger was developed for enhancement in separation efficiency of a generic IPS. The Corona Charger was designed to have a cross-section similar to the inlet of the generic IPS.
The Corona Charger is used to generate a corona discharge which contains charged species such as ions and electrons, which are transferred to the dust particles through collision and subsequent adsorption. The corona discharge is generated by application of a high voltage between two electrodes of non-uniform geometry such as a tube with a wire installed at its central axis or a sharp edge positioned close to a plane. Upon application of high voltage between the electrodes, a corona discharge occurs when the dielectric strength of air (31 kV/cm at 25° C. and 1 atmosphere) is exceeded by the electric field in the gap. Various designs of the Corona Charger that can provide the ion concentration and field strength required for electrostatic charging of dust particles were evaluated. The design based on vane-like electrodes was selected due to its robustness, least obstruction to air flow, and low pressure loss.
Testing using a single vane-like electrode was conducted to determine the current, voltage, and power required for operation of the Corona Charger. A test article 2600 was designed and built as shown in
The electrode 2605 was connected to a high voltage DC power supply 2607 and the voltage was increased from 8 kV in 1 kV increments. The stable current was noted for each voltage setting. The set voltages and corresponding discharge currents are shown in the graph in
The electric field distribution within the Corona Charger was calculated using finite element analysis performed on a CAD model of the Corona Charger (see
Based on the specified voltage and geometry, the electric field within the Corona Charger is calculated by finite element analysis. The distribution of electric field within the Charger is shown in
The flowpath of charged particles can be altered in an electrostatic field due to the Coulomb force exerted on the particles. The generic IPS with the addition of an electric field for deflection of the particles is known as the Field-Enhanced IPS and is shown in
The deflection of the dust particles within the IPS can be calculated as follows. Consider a charged particle leaving the Corona Charger and entering the IPS wherein the outer shroud is energized. The particle is travelling in the x-direction from the inlet of the IPS towards the splitter. The electrostatic force Fy experienced by a particle carrying nq charges due to an electrostatic field acting in the y-direction is given by Equation 3:
{right arrow over (Fy)}=nq{right arrow over (Ey)} Equation 3:
Here n is the number of unit charges on the particle, q is the value of unit charge, and Ey is the electrostatic field. The electrostatic field in the IPS inlet was estimated for application of 40 kV along the outer shroud using a finite element analysis model.
The acceleration experienced by the particle due to the electrostatic force acting on it is given by Equation 4:
Here dp and ρp is the diameter and density of the particle. The displacement of the particle in the y-direction is given by Equation 5:
Here uy is the initial velocity in the y-direction and t is the residence time of particles in the electric field. For these calculations, since displacement in the y-direction due to electrostatic force is being compared, the initial velocity in the y-direction uy is assumed to be zero. The residence time of the particles t is calculated using the mass flowrate (8-10 lb/s), temperature (15.2° C.), and pressure of inlet air and volume (238.05 in3) of the region of interest (electrostatic field). The residence time is 1.32, 1.15 and 1.05 ms for mass flowrates of 8.00, 9.18, and 10.00 lb/s, respectively.
The calculated displacement in y-direction (towards scavenge flowpath) of charged particles ranging from 0.66 μm to 65 μm is shown in
The agglomeration of the unipolarly charged particles may occur in the Corona Charger and the Deflection Field because the motion of the charged dust particles is influenced by the electric field present in both the electrostatic devices. The extent of inter-particle agglomeration is not expected to be significant because of the millisecond residence time and unipolar charging of the particles. Therefore, electrostatic charging of dust particles followed by their deflection into scavenge flow path of the IPS is the most promising approach to enhance IPS separation efficiency.
Nevertheless, in some embodiments of the present invention, agglomeration of charged particles is an important feature, and one skilled in the art will recognize that agglomeration of particles can be promoted by turbulent mixing, by an electric field that is constant, time-varying (e.g., oscillating) at any frequency, or pulsed at any frequency, or a by a combination of turbulent mixing and an electric field that is constant, time-varying (e.g., oscillating) at any frequency, or pulsed at any frequency. Turbulent mixing can be promoted by a series of protrusions in the fluid stream. In embodiments of the present invention, turbulent mixing can take the form of vortices having rotational axes parallel or perpendicular to the fluid flow direction, or vortices may have rotational axes having a variety of angles varying in relation to the fluid flow.
A mathematical modeling approach was developed for estimation of improvement in IPS performance by electrostatic charging in the Corona Charger followed by electrostatic deflection within a generic IPS. The modeling approach was based on the assumption that the separation efficiency for a particle depends on its size (or mass) and its location of entry at the IPS inlet. Each particle was assigned a separation efficiency based on its size and location of entry at the IPS inlet. The particles flowing along the flowstream lines from the inlet may lead to the core flow section or the scavenge flow section within an IPS are shown in
The particle size distribution for one batch of Arizona A2 fine test dust (10666F) is shown in
For the mathematical model of a generic IPS, ten thousand particles were selected to create a population that has size distribution similar to that for Arizona A2 fine test dust.
The ten thousand particles in the sample population were randomly assigned initial positions (y=0 to 32.5 mm) at the IPS inlet.
The mathematical model describing the performance of a generic IPS is developed as follows. The separation efficiency ηi is assigned to particles based on their diameter i and position at entry y, according to Equation 6:
ηi=y*f+ηi0 Equation 6:
Here ηi0 is separation efficiency at the inner shroud for a particle with diameter i. It is bound as follows 0.5%≤ηi0≥56%. The position at entry is bound as follows: 0 mm≤y≥32.5 mm. Here y=0 corresponds to the inner shroud surface, while y=32.5 corresponds to the outer shroud surface. The factor f determines increase in separation efficiency with displacement towards outer shroud; the value off for different particle diameters is shown in
The separation efficiency plot based on the mathematical model of a generic IPS is shown in
The average separation efficiency for a particular size can be obtained by averaging separation efficiency values for all y-values. The average separation efficiency was calculated in this manner for all particles with diameter ranging from 0.66 μm to 65.02 μm. The average separation efficiency is plotted in
To find the IPS separation efficiency ηIPS, the mass-weighted average was calculated as per Equation 7:
Here, ηi is the average separation efficiency corresponding to particle diameter i. Using the IPS model, ten simulation runs were conducted for the IPS without electrostatic enhancement and another ten runs were conducted with electrostatic enhancement. The displacement in y-direction δy due to electrostatic field within the IPS as calculated in the earlier section was then added to the initial position at entry to obtain a new position at entry (y′=y+δy). The particle will then follow the flowstream line originating at the new location of entry and be separated out into the scavenge flow at the separation efficiency corresponding to the new location.
The mathematical model described above was used to calculate IPS separation efficiency with and without electrostatic enhancement. The calculated IPS separation efficiencies for three inlet flow rates of 8.00, 9.18 and 10.00 lb/s are shown in
The improvement in separation efficiency is higher when it is calculated on a particle number basis for the population of ten thousand particles. Since ηi is the average separation efficiency corresponding to particle diameter i and there are 49 particle diameters (i=0.66 to 65.02) under consideration, the separation efficiency on a number basis can be calculated as per Equation 8:
Using the mathematical model of the IPS, the average separation efficiency on a number basis without electrostatic enhancement is 52.16%, 52.22% and 52.33% for three inlet flow rates of 8.00, 9.18 and 10.00 lb/s as shown in
To demonstrate the effect of particle size distribution on improvement of IPS separation efficiency by electrostatic enhancement, a new population was created with equal number of particles with diameter ranging from 1 μm to 22 μm. The size distribution of the particles in the new population is shown in
The new population was used in the mathematical model of the IPS to calculate separation efficiency without and with electrostatic enhancement. The results from simulation runs to calculate mass-weighted separation efficiency and number-based separation efficiency are shown in
For particles of 1-22 μm, the improvement in mass-weighted IPS separation efficiency is 10.00%, 7.90%, and 6.79% for 8, 9.18, and 10 lb/s inlet air flowrates, as shown in
Thus the Corona Charging and Deflection Field can appreciably improve IPS separation efficiency based on particle size distribution. It is to be noted that the calculated improvement is a conservative estimate because all the particles were assumed to be silica, which are the hardest to impart charge among all the constituents of Arizona A2 fine and AFRL03 test dust. From the above analysis, it can be concluded that for flow velocities ranging from 64.6 to 80.7 m/s at the IPS inlet, the IPS separation efficiency can be appreciably improved with a system as follows: (i) a Corona Charger with maximum and average field strength of 51.6 kV/cm and 15.53 kV/cm, respectively and (ii) a Deflection Field with field strength of 18.55 kV/cm.
The pressure loss due to the Corona Charger was estimated by the following steps. The cross-sectional area (70.799 in2) and the wetted perimeter (124.944 in) for the Corona Charger were first calculated. This involves taking into account the annular opening of the Corona Charger as well as the 54 electrodes present in the flow path. The hydraulic radius (0.567 in) was then calculated by dividing the cross-sectional area with the wetted perimeter. The equivalent diameter (2.267 in) was then calculated by multiplying the hydraulic radius by 4. The equivalent diameter was then used in the Darcy's equation to obtain the pressure loss, assuming no major change in air density and velocity as it flows through the Corona Charger. The intake air flow rate was 9.18 lb/s at 15.2° C. and 1 atm. The calculated pressure loss for the Corona Charger is 0.31 inches water column or 0.08% for the active length of 3.5″ considered in this study. For additional length of the Charger, the incurred pressure loss is shown in Table 8.
The integration 4700 of one embodiment of the Corona Charger with vane-like electrodes with triangular-shaped tips as in
The Deflection Field can be applied to the IPS 4706 in one of the following two schemes: (i) The outer shroud 4707 (˜4.9″ long section) of the IPS 4706 is maintained at positive potential by connection to a high voltage power source 4708 and the inner hub 4709 is grounded. In this scheme, a spacer 4725 is required to isolate the positively charged outer shroud 4707 of the IPS 4706 from the Corona Charger 4705. The exact length of the spacer 4725 is to be determined but 2″ is an initial approximation, which is twice the electrode-ground gap in the Corona Charger 4705. The spacer 4725 consists of an inner frame 4730 and outer frame 4720 similar to the Charger 4705. The spacer 4725 is to be fabricated from a dielectric material. Assuming a length of 2″ and density of alumina, the spacer 4725 weight is about 1.28 lbs. The total weight of the Corona Charger 4705 and the spacer 4725 is about 3.33 lbs. (ii) In the second scheme, the inner hub 4709 is maintained at negative potential. Therefore the negatively charged particles are pushed outwards due to electrostatic repulsion with the inner hub 4709. In this scheme, no spacer 4725 is required and a single power supply may be used for the Charger 4705 and the Deflection Field. It is to be noted that the Deflection Field can be generated within any separation device such as an IPS by maintaining an electric field across the flow path. The electric field is generated by applying a potential difference across the walls defining the flow path. The Deflection Field can be generated within a single IPS, single IPS with adjustable scavenge path (U.S. Pat. No. 7,927,408 B2), or plurality of IPSes attached to a single engine (U.S. Pat. No. 6,508,052 B1),
The Deflection Field is applied in the volume of the IPS flowpath and therefore does not require any additional space. The IPS splitter will need to be fabricated from a dielectric material to isolate rest of the engine from the outer shroud of the IPS which is maintained at a high potential. Since no change in volume of the IPS is expected from its electrostatic enhancement, the change in weight due change in material of the IPS splitter is not expected to be significant. The volume, weight and power requirements are summarized in Table 9.
The Corona Charger is powered by a high voltage DC power supply capable of providing 52 kV and 66.42 mA (1.23 mA/electrode×54 electrodes). Therefore the net power for the Charger is 3,454 W. The Deflection Field requires very low power (40 kV×0.1 mA=4 W). Commercially available power supplies of similar capability are about 80-90% efficient and therefore the gross power is expected to be 3.84-4.32 kW. As shown in Table 9, the power requirement is a small fraction of the rated engine power. Depending on the Deflection Field, scheme the weight and volume of the power supply will vary. If the first scheme is used, two separate power supplies are needed to power the Corona Charger and the Deflection Field. If the second scheme is used, only the power supply for the Corona Charger is needed. The weights listed in Table 9 are for commercially available power supplies of similar output. These supplies include electronics for local operation and monitoring, which are not required for the IPS application since these power supplies will be integrated with the aircraft electronics. Therefore, the volume and weight of the power supplies are expected to be lower than the listed values.
The total number of vane-like electrodes is important because too few electrodes, e.g., nine electrodes, as shown in
In summary:
The Corona Chargers can adequately perform electrostatic charging of simulant dust particles (Arizona A2 Fine ISO 12103-1 and AFRL 03). The electric field in the Corona Charger is the most important parameter for electrostatic charging of particles. High electric fields up to 5.2×106 V/m were calculated for the Corona Charger.
Larger particles acquire greater charge, while smaller particles are deflected the most due to their higher charge/mass ratio. Deflection for 0.66-65.02 μm particles ranged from 0.04″ to 7.16″, thereby improving their probability for separation into the IPS scavenge path.
Among the various constituents of Arizona A2 fine and AFRL03 test dust, silica particles acquire the least charge. Titanium dioxide and dolomite acquire most charge in Arizona A2 fine and AFRL03 test dust, respectively.
Preliminary design of the Corona Charger was developed for a generic IPS. For Arizona A2 fine test dust, 2.6% improvement in IPS separation efficiency was estimated at 8 lb/s air flow. For 1-22 μm particles, 10% improvement was estimated. In general, higher the mass fraction of fine particles, the greater is the improvement due to electrostatic charging and deflection.
The design of the Corona Charger minimizes obstruction in flow path. Therefore a low pressure loss (<0.12%) in intake air flow is estimated.
The space, weight and power penalty due to the Corona Charger is low. The Corona Charger increases the length of the IPS by 3.5-5.5″ and increases the weight by 2-3.5 lbs. The power required for operation is less than 0.2% of rated power for a 3000 shp engine.
It is contemplated that any embodiment discussed in this specification can be implemented with respect to any method, kit, reagent, or composition of the invention, and vice versa. Furthermore, compositions of the invention can be used to achieve methods of the invention.
It will be understood that particular embodiments described herein are shown by way of illustration and not as limitations of the invention. The principal features of this invention can be employed in various embodiments without departing from the scope of the invention. Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, numerous equivalents to the specific procedures described herein. Such equivalents are considered to be within the scope of this invention and are covered by the claims.
All publications and patent applications mentioned in the specification are indicative of the level of skill of those skilled in the art to which this invention pertains. All publications and patent applications are herein incorporated by reference to the same extent as if each individual publication or patent application was specifically and individually indicated to be incorporated by reference.
The use of the word “a” or “an” when used in conjunction with the term “comprising” in the claims and/or the specification may mean “one,” but it is also consistent with the meaning of “one or more,” “at least one,” and “one or more than one.” The use of the term “or” in the claims is used to mean “and/or” unless explicitly indicated to refer to alternatives only or the alternatives are mutually exclusive, although the disclosure supports a definition that refers to only alternatives and “and/or.” Throughout this application, the term “about” is used to indicate that a value includes the inherent variation of error for the device, the method being employed to determine the value, or the variation that exists among the study subjects.
As used in this specification and claim(s), the words “comprising” (and any form of comprising, such as “comprise” and “comprises”), “having” (and any form of having, such as “have” and “has”), “including” (and any form of including, such as “includes” and “include”) or “containing” (and any form of containing, such as “contains” and “contain”) are inclusive or open-ended and do not exclude additional, unrecited elements or method steps. In embodiments of any of the compositions and methods provided herein, “comprising” may be replaced with “consisting essentially of” or “consisting of”. As used herein, the phrase “consisting essentially of” requires the specified integer(s) or steps as well as those that do not materially affect the character or function of the claimed invention. As used herein, the term “consisting” is used to indicate the presence of the recited integer (e.g., a feature, an element, a characteristic, a property, a method/process step or a limitation) or group of integers (e.g., feature(s), element(s), characteristic(s), propertie(s), method/process steps or limitation(s)) only.
The term “or combinations thereof” as used herein refers to all permutations and combinations of the listed items preceding the term. For example, “A, B, C, or combinations thereof” is intended to include at least one of: A, B, C, AB, AC, BC, or ABC, and if order is important in a particular context, also BA, CA, CB, CBA, BCA, ACB, BAC, or CAB. Continuing with this example, expressly included are combinations that contain repeats of one or more item or term, such as BB, AAA, AB, BBC, AAABCCCC, CBBAAA, CABABB, and so forth. The skilled artisan will understand that typically there is no limit on the number of items or terms in any combination, unless otherwise apparent from the context.
As used herein, words of approximation such as, without limitation, “about”, “substantial” or “substantially” refers to a condition that when so modified is understood to not necessarily be absolute or perfect but would be considered close enough to those of ordinary skill in the art to warrant designating the condition as being present. The extent to which the description may vary will depend on how great a change can be instituted and still have one of ordinary skilled in the art recognize the modified feature as still having the required characteristics and capabilities of the unmodified feature. In general, but subject to the preceding discussion, a numerical value herein that is modified by a word of approximation such as “about” may vary from the stated value by at least ±1, 2, 3, 4, 5, 6, 7, 10, 12 or 15%.
All of the compositions and/or methods disclosed and claimed herein can be made and executed without undue experimentation in light of the present disclosure. While the compositions and methods of this invention have been described in terms of preferred embodiments, it will be apparent to those of skill in the art that variations may be applied to the compositions and/or methods and in the steps or in the sequence of steps of the method described herein without departing from the concept, spirit and scope of the invention. All such similar substitutes and modifications apparent to those skilled in the art are deemed to be within the spirit, scope and concept of the invention as defined by the appended claims.
This application claims the benefit of U.S. Provisional Application No. 62/444,051 filed Jan. 9, 2017, the entire contents of which are incorporated herein by reference.
This invention was made with government support under Contract No. W911W6-15-C-0011 awarded by U.S. Army Research Development and Engineering Command. The government has certain rights in the invention.
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Number | Date | Country | |
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20180193848 A1 | Jul 2018 | US |
Number | Date | Country | |
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62444051 | Jan 2017 | US |