The present technology generally relates to electrostatic rotating machines and a fill fluid for such machines. More particularly, the technology relates to machines such as motors and generators that have capacitance plates separated by a fluid, such as a dielectric fluid.
An illustrative electrostatic machine includes a shaft that is configured to rotate about an axis, a rotor electrode, and a stator electrode. The rotor electrode and the stator electrode are separated by a gap and form a capacitor. The rotor electrode is fixed to the shaft. The electrostatic machine can also include a housing that is configured to enclose the rotor electrode, the stator electrode, and at least a portion of the shaft. The stator electrode is fixed to the housing. A dielectric fluid fills a void defined by the housing, the rotor electrode, and the stator electrode. The dielectric fluid comprises at least one of an acyclic structure or a cyclic structure.
In some embodiments, the dielectric fluid is a carbonate (i.e. —OC(O)O—). In some embodiments, the dielectric fluid includes an aromatic structure in which a nitrogen atom is present at a first position in a ring of the aromatic structure and at least one nitrile (CN) group is a substituent at a second position. In some embodiments, the dielectric fluid includes 2-pyridinecarbonitrile.
In some embodiments, the dielectric fluid comprises a cyclic structure and includes a chemical functional group represented as —OC(O)N—. In some embodiments, the dielectric fluid includes 3-methyl-2-oxazolidinone, 3-ethyl-2-oxazolidinone, 3-methyl-1,3-oxazinan-2-one, or a mixture of any two or more thereof. In some embodiments, the dielectric fluid includes an acyclic, fluorinated hydrocarbon. In some embodiments, the dielectric fluid includes C5H2F10. In some embodiments, the dielectric fluid is an organic compound having a sulfonyl moiety (—S(O)2—). In some embodiments, the dielectric fluid includes dimethyl sulfone, sulfolane, or a mixture thereof.
In some embodiments, the dielectric fluid includes ethylene carbonate, dimethyl carbonate, diethyl carbonate, ethylmethyl carbonate, dipropyl carbonate, propylene carbonate, methyl butyrate, γ-butyrolactone, N-methylpyrrolidinone, vinylene carbonate, dioxolane, 6-butyrolactone, or diethyl ether. In some embodiments, the dielectric fluid includes propylene carbonate having a purity of greater than 99%. In some embodiments, the rotor electrode and the stator electrode each comprise a passivation layer formed using a second dielectric in the gap between the rotor electrode and the stator electrode. The second dielectric fluid comprises less than 99 wt % propylene carbonate. In some embodiments, the second dielectric fluid includes 93.8 vol % propylene carbonate, 6 vol % ethylene sulfite, and 0.2 vol % water. In some embodiments, a voltage is applied across the capacitor, and wherein the dielectric fluid forms a passivation layer on a surface of the rotor electrode and on a surface of the stator electrode.
In some embodiments, the electrostatic machine can further include a current sourced inverter that is configured to convert direct current power into alternating current power via a plurality of switches. The current sourced inverter is configured to provide the alternating current power across the rotor electrode and the stator electrode. No passive electrical components are electrically connected between the rotor electrode, the stator electrode, and the plurality of switches.
In some embodiments, the electrostatic machine can further include a voltage sourced inverter that is configured to convert direct current power into alternating current power via a plurality of switches. A plurality of inductors are electrically connected between the rotor electrode, the stator electrode, and the plurality of switches.
In some embodiments, the rotor electrode comprises a rotor plate, the stator electrode comprises a stator plate, and the rotor plate and the stator plate are parallel. The rotor plate comprises a plurality of teeth around a periphery of the rotor plate. The stator plate comprises an annulus with a plurality of teeth extending from an inside circumference of the annulus. The teeth of the rotor plate and the teeth of the stator plate form the capacitor. In some embodiments, the housing comprises at least one of polypropylene, chemical resistant acetal, ultra-high-molecular-weight (UHMW) polyethylene, and polytetrafluoroethylene (PTFE).
The foregoing summary is illustrative only and is not intended to be in any way limiting. In addition to the illustrative aspects, embodiments, and features described above, further aspects, embodiments, and features will become apparent by reference to the following drawings and the detailed description.
The foregoing and other features of the present disclosure will become more fully apparent from the following description and appended claims, taken in conjunction with the accompanying drawings. Understanding that these drawings depict only several embodiments in accordance with the disclosure and are, therefore, not to be considered limiting of its scope, the disclosure will be described with additional specificity and detail through use of the accompanying drawings.
In the following detailed description, reference is made to the accompanying drawings, which form a part hereof. In the drawings, similar symbols typically identify similar components, unless context dictates otherwise. The illustrative embodiments described in the detailed description, drawings, and claims are not meant to be limiting. Other embodiments may be utilized, and other changes may be made, without departing from the spirit or scope of the subject matter presented here. It will be readily understood that the aspects of the present disclosure, as generally described herein, and illustrated in the figures, can be arranged, substituted, combined, and designed in a wide variety of different configurations, all of which are explicitly contemplated and make part of this disclosure.
Electrostatic machinery include electric motors and generators that convert power between mechanical (e.g., kinetic) and electrical forms using electric field torque mechanisms. In general, electrostatic machines use capacitive principles (as opposed to inductive principles used in induction, permanent magnet, and reluctance machines). In some embodiments, electrostatic machines can use circular plates located in close proximity to one another to create a capacitance between the plates. In some embodiments, the plates can alternate between rotor plates and stator plates. Rotor plates can be plates that rotate with a shaft of the motor and/or generator and can be analogous to an armature of an induction or reluctance motor. Stator plates can remain stationary with respect to a housing or enclosure of the motor and/or generator.
In general, energy storage systems (e.g., capacitors) can naturally arrange themselves to be in a minimal energy state. In the case of variable capacitance machines (and other electrostatic machines), surfaces affixed to a shaft (e.g., rotor plates) can form a capacitance with surfaces affixed to a housing (e.g., stator plates). When voltage is applied across rotor plates and the stator plates, an electric field develops between the rotor plates and the stator plates and can exert a force (e.g., torque) on the surfaces of the rotor plates and the stator plates in a direction that will align the rotor plates and the stator plates in a position with a minimal energy state.
Some electrostatic machines can produce a large electric field across a pair of electrodes (e.g., stator plates and rotor plates) to generate sufficient torque for practical applications. Air has a low breakdown voltage (e.g., is prone to arcing). Thus, in some embodiments, a dielectric fluid can be located between the electrodes (e.g., stator plates and electrode plates) and a high electric field can be maintained without arcing between the electrodes.
Torque generation in an electrostatic machine can be directly related to the normal and shear forces between the electrodes. The electrostatic normal force density F between the electrodes can be estimated using Coulomb's law:
F=(½)∈0∈E2
where ∈0 is the vacuum permittivity of the medium between the electrodes in farads per meter (F/m), ∈ is the static permittivity of the medium between the electrodes, and E is the electric field in volts per meter (V/m). The force density can be optimized by using a medium between the electrodes that has a high permittivity and by applying a large electric field across the electrodes without arcing between the electrodes. In some embodiments, the medium can be in a liquid state. In most instances, liquids can have a higher relative permittivity than gases. Other considerations can be taken into account when choosing a fill medium. For example, the ionic conductivity of the medium can be low. Ionic contaminants can facilitate electron transport between the electrodes, resulting in premature dielectric breakdown and, thus, inhibiting application of a high electric field. Liquid viscosity can be low thereby minimizing drag on moving parts. In some instances, a fluid with high permittivity and low conductivity, which can be located between rotor plates and stator plates, can be generally referred to as a dielectric fluid. However, in other instances, a fluid with low relative permittivity can be used. For example, in some embodiments, acyclic carbonates and/or ethers can be used, which may have a low relative permittivity but may have other desirable characteristics.
Electrostatic machines may be divided into six categories: electrostatic induction machines, variable capacitance/elastance machines, synchronous electrostatic machines, direct current (DC) electrostatic machines, electrostatic hysteresis synchronous machines, and corona machines. In some instances, a particular machine may fall into one or more of the categories. Such categories are not exclusive, and additional categories may exist. The use of such categories is used for explanatory purposes only, and is not meant to be limiting. The following descriptions of the categories explain the general, underlying principles used in the machines of each category.
Electrostatic induction machines can use electrodes on a stator to produce a traveling potential wave. The potential wave can induce a charge distribution on a rotor adjacent to the stator. The rotor surface can be continuous and, in at least some instances, does not exhibit capacitive saliency. When the stator and the rotor have a net velocity between them (e.g., the stator and the rotor move relative to one another), a tangential component of the electrical field in a gap between the stator and the rotor can exist in the gap. The tangential component can result in a coulomb force on the rotor charge. The relative velocity between the stator and rotor can be referred to as the slip speed. In some aspects, electrostatic induction machines can be considered to be analogous to magnetic induction machines that use a version of slip.
Variable capacitance machines can be referred to as elastance machines. Variable capacitance machines can minimize elastance (or maximize capacitance) to create torque. When a voltage is applied across stator electrodes and rotor electrodes, the rotor electrodes can experience a torque in a direction to align the rotor to be in a minimum energy state with respect to the stator. The torque can be proportional to the change in capacitance per unit angle (e.g., dC/dθ). Variable capacitance machines can be designed to maximize the change in capacitance over a rotational angle. The manner in which the capacitance varies with angle may be synchronous (e.g., sinusoidal) or switched (e.g., trapezoidal). In some aspects, variable capacitance machines can be considered to be analogous to magnetism based variable reluctance machines.
Synchronous electrostatic machines can have a rotor with a fixed DC charge distribution across the rotor. The DC charge distribution can provide a DC electric flux field in the frame of the rotor. The DC field can rotate with the rotor. Electrodes of the stator can produce an alternating current (AC) charge and corresponding electric field distribution that follows the rotor as the rotor rotates. The rotor flux and the stator flux can travel at the same speed (e.g., a synchronous speed). Although the rotor flux and the stator flux travel at the same speed, the angle between the rotor flux vectors and the stator flux vectors can determine torque by varying the shear in the gap. In some embodiments, the rotor flux may be produced with a permanent electret or may be separately excited using a power supply connected through a rotating shaft power coupling (e.g. brushes and slip rings). In some aspects, synchronous electrostatic machines can be considered to be analogous to magnetic synchronous machines.
The underlying principles of direct current (DC) electrostatic machines are similar to those of synchronous electrostatic machines. However, in DC electrostatic machines, the roles of the stator and rotor are reversed from the roles of the stator and the rotor in synchronous electrostatic machines. Stator electrodes can be excited using DC power, thereby creating a static field. Charge on the rotor, however, can be commutated mechanically. As the rotor spins, charge is commutated by a brushed commutator or a non-brushed commutator such that the charge is aligned with the stator excitation, thereby producing average torque. In some aspects, DC electrostatic machines can be considered to be analogous to magnetic DC motors.
Electrostatic hysteresis synchronous machines are analogous to traditional synchronous machines in that rotor and stator flux interact to make torque. However, in electrostatic hysteresis synchronous machines, ferroelectric materials with an electrostatic hysteresis curve of an electric field versus displacement (e.g., an E-D hysteresis curve) can coat the rotor surface. An E-D hysteresis curve can be a function of the electric displacement D for an applied electric field E. In some aspects, an E-D curve for ferroelectric materials can be analogous to a B-H curve for ferromagnetic materials. The slope of an E-D curve for a material can represent the permittivity of the material at different electric field strengths. The ferroelectric material can be polarized during operation and dragged along with the stator flux wave at synchronous speed. In some aspects, electrostatic hysteresis synchronous machines can be considered to be analogous to magnetic hysteresis synchronous motors.
Corona machines are different than machines of the other five categories explained above in that the operating principle is electro hydrodynamic flow rather than creating electric shear force via normal and/or tangential fields. Charged particles can be accelerated to form an ionic “wind.” The mechanical interaction of the accelerated particles with rotor and stator structures can create torque. Corona machines can incur high electrical losses at macro scales and, therefore, may not be suitable for many applications.
In some embodiments, the teeth 105 of the rotor plate 100 can overlap with teeth 205 of the stator plate 200 when assembled. The teeth 105 and the teeth 205 may also be referred to as “electrodes.”
In some embodiments, voltages of the stator plates 200 and rotor plates 100 can operate at different voltages. Some such embodiments can include variable capacitance machines. For example, a first portion (e.g., one third) of the stator plates 200 and a first portion (e.g., one third) of the rotor plates 100 can operate together at a first voltage, a second portion (e.g., one third) of the stator plates 200 and a second portion (e.g., one third) of the rotor plates 100 can operate together at a second voltage, and a third portion (e.g., one third) of the stator plates 200 and a third portion (e.g., one third) of the rotor plates 100 can operate together at a third voltage. In some embodiments, the nominal voltage of the first voltage, the second voltage, and the third voltage can be the same, but can differ in phase. For example, the first voltage, the second voltage, and the third voltage can each be out of phase with one another by 120°. The first portion of the rotor plates 100 can interleave with the first portion of the stator plates 200 along a first portion of a motor shaft, the second portion of the rotor plates 100 can interleave with the second portion of the stator plates 200 along a second portion of a motor shaft, and the third portion of the rotor plates 100 can interleave with the third portion of the stator plates 200 along a third portion of a motor shaft. The first portion of the rotor plates 100, the second portion of the rotor plates, and the third portion of the rotor plates 100 can each be rotationally skewed from one another. Similarly, the first portion of the stator plates 200, the second portion of the rotor plates 200, the third portion of the rotor plates 200 can each be rotationally skewed from one another. For example, each portion can be skewed by one third of the width of teeth 105 and/or teeth 205.
The shape of the teeth 105 and the teeth 205 can determine the profile capacitance waveform.
The profile capacitance waveform can determine the corresponding torque waveform. The torque waveform form can be the derivative of capacitance with respect to the position of the rotor plate 100 and the stator plate 200. As the rotor plate 100 and stator plate 200 rotate in relation to one another, voltage can be applied to the rotor plate 100 and the stator plate 200 by a power electronic converter or other suitable device. In embodiments in which the capacitance varies as a trapezoidal waveform, such as in
The examples illustrated in
A rotor 400 can include a hollow center 405 through which a shaft can be inserted. Hub mounting holes 410 can be used to fix the rotor 400 to the shaft. Slits 415 can be formed in the rotor 400. The slits 415 can define flexure beams that allow the rotor 400 to flex axially. Spirals of the rotor 400 can include conducting sections 420 and insulating sections 425.
A stator 450 can include a hollow center 455 through which a shaft can be inserted. Plate mounting holes 460 can be used to rotationally fix the stator 450 such that the stator 450 is stationary with respect to a housing of the motor. Slits 465 can be formed in the rotor 450. The slits 465 can allow the stator 450 to flex axially. Spirals of the stator 450 can include conducting sections 470 and insulating sections 475.
Stators of the stator and rotor plates 610 can be rotationally fixed to the housing 615. Rotors of the stator and rotor plates 610 can be rotationally fixed to the shaft 605. The shaft 605 can rotate within the housing 615. The housing 615 can be filled with a dielectric fluid. The dielectric fluid can be recirculated through one or more recirculation paths 620. When the shaft 605 and, therefore, the rotor plates of the stator and rotor plates 610 are rotating, the dielectric fluid can be forced radially out and through the recirculation paths 620. The use of recirculation paths 620 can reduce the fluidic drag on the rotor plates of the stator and rotor plates 610. In some embodiments, the recirculation paths 620 can include a filter, a radiator, a heat exchanger, and/or other elements that can maintain and/or enhance performance of the dielectric fluid. The seals 630 can be configured to maintain fluid integrity of the housing 615 such that the shaft 605 can rotate while the housing 615 remains stationary, and the dielectric fluid can remain within the housing 615.
In some embodiments, rotor plates and/or stator plates can be stamped from a sheet of metal. For example, shapes illustrated in
Although
As noted above, a motor, such as motor 600, can convert electrical energy into rotational kinetic energy. The electrical energy can be three-phase alternating current (AC) power. In some embodiments, direct current (DC) power can be converted into three-phase AC power, which can be used to power an electrostatic machine, such as electrostatic induction machines, variable capacitance/elastance machines, synchronous electrostatic machines, direct current (DC) electrostatic machines, and electrostatic hysteresis synchronous machines. The DC power can be converted into three-phase AC power by an inverter. A current sourced inverter (CSI) can maintain a constant current output to a load, such as an electrostatic machine. A voltage sourced inverter (VSI) can maintain a constant voltage output to the load. In some embodiments, a CSI and/or a VSI may be pulse width modulated for a time-averaged variable output.
Some embodiments can use a VSI and/or a CSI to provide power to an electrostatic machine. In some embodiments, a CSI can have significant advantages over a VSI when used with an electrostatic machine. In some instances, a VSI may not be directly connected to a variable capacitance machine because, in order to work most efficiently, a VSI can require inductive properties at AC terminals of the VSI, which the capacitance machine does not inherently have. However, a CSI can have capacitive properties at AC terminals of the CSI in order to work most efficiently, which the capacitance machine does inherently have. Accordingly, in some embodiments, a CSI can be directly connected to an electrostatic machine without the use of passive components (e.g., resistors, capacitors, inductors, etc.) between the inverter and the electrostatic machine.
In an illustrative embodiment, each switch 910 illustrated in
In an illustrative embodiment, each switch 910 illustrated in
Electrical power 1105 can be input into VSI 1110. In some embodiments, the electrical power 1105 can be direct current power and VSI 1110 can be a voltage-sourced inverter such as inverter 935. The power of the electrical connections between the VSI 1110 and the machine 1120 can have an alternating voltage. Inductors 1115 can be placed in each leg of the electrical connections between the VSI 1110 and the machine 1120.
The voltage sensing feedback 1130 can be used in a control loop. The voltage sensing feedback 1130 can use one or more sensors to sense a voltage across stator electrodes and rotor electrodes of the machine 1120. The voltage sensing feedback 1130 can send a signal to the controller 1135 indicating the sensed voltage. The controller 1135 can compare the sensed voltage to a setpoint voltage. Based on the comparison, the controller 1135 can indicate a change in the switching of VSI 1110. The controller 1135 can use a proportional control loop, an integral control loop, a derivative control loop, or any combination thereof.
The amount of torque output by the machine 1120 can be dependent upon the voltage signal applied across the stator electrodes and the rotor electrodes of the machine 1120. Accordingly, the controller 1135 can modify the torque output by the machine 1120 by indicating a change in the switching of the VSI 1110. In some embodiments, the voltage signal sensed by the voltage sensing feedback 1130 can be an alternating voltage signal. Similarly, the setpoint voltage can be an alternating voltage signal. The indication of a change in switching of the VSI 1110 output by the voltage sensing feedback 1130 can include an indication of a change in frequency, amplitude, phase, etc.
As shown in
Electrical power 1155 can be input into CSI 1110. In some embodiments, the electrical power 1155 can be direct current power and CSI 1110 can be a current-sourced inverter such as inverter 900. The power of the electrical connections between the CSI 1110 and the machine 1170 can have an alternating voltage. The voltage sensing feedback 1180 can be used in a control loop with controller 1185 and position sensing line 1190, which can operate as explained above with respect to
The power converters 1194 can be any suitable power converter, including a VSI or CSI power converter. As illustrated in
To scale electrostatic machines up to produce greater than 1 horsepower, medium to high voltage can be used. For example, voltages greater than 1000 V can be used between rotor plates and stator plates. Electrostatic induction machines, variable capacitance/elastance machines, synchronous electrostatic machines, and electrostatic hysteresis synchronous machines can use medium to high AC power. Direct current (DC) electrostatic machines and corona machines can use high voltage DC power. For electrostatic machines that can create greater than one quarter horsepower and less than one megawatt (MW) (e.g., about 1,341 horsepower), high voltage power electronic drives can be used. However, high voltage variable frequency AC power sources, which can also be suitable for use with electrostatic machines, are not generally commercially available.
However, as described above with reference to
Electrostatic machines can be used in a variety of applications. Electrostatic machines that can produce less than 1 horsepower can be efficient and compact. However, scaling up the size of electrostatic machines can produce hurdles in implementation.
In some instances, breakdown of the dielectric fluid can occur in the gap between the surfaces of the stator plate and the rotor plate. Torque is proportional to the square of the gap electric field. The gap electric field strength is proportional to the voltage applied across the stator plate and the rotor plate. Breakdown of the dielectric fluid can lead to arcing between the stator plate and the rotor plate. Arcing events can reduce the amount of torque that may be developed. Breakdown of the dielectric fluid can pose a problem in electrostatic induction machines, variable capacitance/elastance machines, synchronous electrostatic machines, direct current (DC) electrostatic machines, and electrostatic hysteresis synchronous machines. In some embodiments, an ultra-high vacuum (e.g., less than 10−2 Torr) can be used within the housing of the electrostatic machines to prevent arcing. However, the cost of vacuum pumps, bearing vacuum seals, etc. can be cost prohibitive. Further, the loss of the relative permittivity material in the gap between the stator plates and the rotor plates can reduce the effectiveness of the machine.
A gap displacement field of an electrostatic motor can be the displacement field in the gap between the stator plates and the rotor plates. The gap displacement field strength can be proportional to the relative permittivity of the medium filling the gap. Fluids with appreciable relative permittivity (e.g., greater than 7) and/or with low electrical conductivity (e.g., 10−9 Siemens per centimeter (S/cm)) that are chemically and electrically stable and/or suitable can be used to enhance the efficiency of the machine. Enhancing the gap displacement field can be beneficial to electrostatic induction machines, variable capacitance/elastance machines, synchronous electrostatic machines, direct current (DC) electrostatic machines, and electrostatic hysteresis synchronous machines by increasing the electrostatic shear force in the gap for a given voltage.
Accordingly, a fluid that can fill the gap between stator plates and rotor plates of an electrostatic machine that has a high permittivity, low conductivity, low viscosity, is chemically stable and suitable for machine components, and is electrically stable and suitable for machine components can be beneficial to electrostatic machines. In some embodiments, beneficial properties for a fill fluid can also include practical properties such as low toxicity and low flammability. The fill fluid may be a dielectric fluid.
Fluids with a high permittivity fluid can have a molecular structure that has a high dipole moment. In some instances, strong dipole-dipole interactions can generally lead to a higher viscosity and a higher boiling point. Therefore, many fluids with high permittivity also have relatively high viscosity.
In many instances, high permittivity fluids have inherently high conductivities. Some commercially available high permittivity liquids that are 99.5% pure contain too many contaminants to be useful as a dielectric fluid within electrostatic machines. The presence of trace amounts of ions, gas, and/or highly mobile molecules can lead to unacceptably high electrical losses and/or premature breakdown.
In some embodiments, liquids with a high permittivity can be purified using suitable techniques. For example, purification may be carried out by dehydration, degasification, or ion removal. In some embodiments, a high voltage insulator can have ionic conductivities that are less than 10−12 S/cm.
In some embodiments, the dielectric fluid may include ethylene carbonate, dimethyl carbonate, diethyl carbonate, ethylmethyl carbonate, dipropyl carbonate, propylene carbonate, methyl butyrate, γ-butyrolactone, N-methylpyrrolidinone, vinylene carbonate, dioxolane, 6-butyrolactone, diethyl ether, or a combination of any two or more thereof.
In some embodiments, the dielectric fluid can have an aromatic structure in which a nitrogen atom is present at a first position in a ring of the aromatic structure and at least one nitrile (CN) group can be a substituent at a second position. In some embodiments, the dielectric fluid may include a nitrile-substituted heteroaromatic solvent.
In some embodiments, the dielectric fluid can include an acyclic carbonate. An acyclic carbonate has a functional group consisting of a carbon atom that is double bonded to an oxygen atom and single bonded to two other oxygen atoms. Alkyl groups may be attached to the single bonded oxygen atoms. The alkyl groups do not link to each other and, therefore, the molecule does not form a ring configuration. Some examples of acyclic carbonates that can be used as a dielectric fluid include dimethyl carbonate, ethyl methyl carbonate, and diethyl carbonate.
In some embodiments, the dielectric fluid can include a cyclic carbonate. A cyclic carbonate has a functional group consisting of a carbon atom that is double bonded to an oxygen atom and single bonded to two other oxygen atoms. Alkyl groups are attached to the single bonded oxygen atoms. The alkyl groups do link together such that the molecule forms a ring configuration. Some examples of cyclic carbonates that can be used as a dielectric fluid include ethylene carbonate, propylene carbonate, and vinylene carbonate. In some embodiments, the cyclic carbonate can have a moiety that is represented as —OC(O)N. In some embodiments, a methyl group can be attached to the nitrogen atom at the 3 position. For example, the dielectric fluid can comprise 3-methyl-2-oxazolidinone, 3-ethyl-2-oxazolidinone, and/or 3-methyl-1,3-oxazinan-2-one.
In some embodiments, the carbonate can include a sulfone group. A sulfone has a functional group consisting of a sulfur atom that is double bonded to two different oxygen atoms and has single bonds to two separate alkyl groups. In some embodiments, the sulfone can be acyclic. For example, the dielectric fluid can include dimethyl sulfone, in which both alkyl substituents are methyl groups. In alternative embodiments, the sulfone can be cyclic. For example, the dielectric fluid can include sulfolane, in which the alkyl groups are linked together forming a 5 member ring. In some embodiments, the dielectric fluid can be dimethyl sulfone, sulfolane or a mixture of dimethyl sulfone and sulfolane.
In some embodiments, the dielectric fluid includes propylene carbonate. In some embodiments, the dielectric fluid can be propylene carbonate. The carbonate functional group (—OC(O)C— and/or —OC(O)O—), in cyclical form, has a high dipole moment of 4.94 debyes (D). In some embodiments, a carbonate functional group with an acyclic form can be used. Propylene carbonate has a relative permittivity of 64, which is higher than most other liquids. Propylene carbonate has a relatively low viscosity of 2.53 centipoise (cP). Propylene carbonate has a relatively wide range of temperatures at which it remains in a liquid state (from about −49° C. to about 242° C.). Propylene carbonate is nontoxic, is nonflammable, and is reasonably cost effective. In some embodiments, one or more co-solvents or additives can be used with propylene carbonate.
In some instances, 99.99% pure propylene carbonate can have an ionic conductivity that can be too high to be suitably efficient. Propylene carbonate can be commercially available at a purity of 99.99%, but such a purity can contain about 20 parts per million (ppm) each of propylene glycol, propylene oxide, water, ionic contaminates, etc. Further, imperfect methods of shipping and/or handling of propylene carbonate can lead to absorption of atmospheric moisture into the propylene carbonate. Thus, in some instances, commercially available propylene carbonate can be received with a moisture content much higher than 20 ppm.
In some embodiments, propylene carbonate of 99.99% purity or greater may be used in the electrostatic machines of some embodiments. In some instances, a suitable purity level of propylene carbonate can depend on the contaminant. For example, higher purity levels can be used in instances in which water and ions are contaminants. In another example, relatively lower purity levels can be used for contaminates that are more innocuous than water and ions. Propylene carbonate at such a purity may have an ionic conductivity of approximately 10−10 S/cm. Propylene carbonate at 99.99% purity may be produced using a suitable purification method. Water can be removed from propylene carbonate with 4 angstrom (A) molecular sieves, a plurality of vacuum distillations, and/or degasification. Such methods can produce a propylene carbonate with a purity level that has a conductivity of less than 10−11 S/cm. For example, propylene carbonate can be soaked in molecular sieves to reduce water content to be below 2 ppm. Multiple vacuum distillations of the propylene carbonate may reduce the amount of (e.g., virtually eliminate) propylene glycol, propylene oxide, and/or ionic contaminates. The ionic conductivity can be reduced to a desirable level that limits self-heating.
In some instances, propylene carbonate is a solvent. Because of its high dipole moment, especially at elevated temperatures, propylene carbonate may be an effective solvent for plastics (e.g., polyvinyl chloride (PVC)) that contain plasticizer additives. Thus, materials of construction for machines using a dielectric fluid such as propylene carbonate can be chosen such that contaminates do not leach into the dielectric fluid from other components of the machine. For example, a housing (or other component) of an electrostatic machine can be comprised of plastics that do not contaminate the dielectric fluid, have a low conductivity, and are mechanically rigid, even when exposed to heated propylene carbonate. Some suitable plastics include polypropylene, chemical resistant acetal, ultra-high-molecular-weight (UHMW) polyethylene, polytetrafluoroethylene (PTFE), etc.
In alternative embodiments, fluids other than propylene carbonate can be used. For example, hydrofluorocarbons such as a specialty fluid Vertrel XF produced by E. I. du Pont de Nemours and Company (DuPont), which is a noncyclic fluorinated hydrocarbon with a chemical formula of C5H2F10, have physical properties that can be suited for a dielectric fluid in an electrostatic machine. In some embodiments, such as those with small electrode gaps (e.g., less than 0.38 mm), Vertrel has an inherent breakdown voltage of greater than 20 kilovolts per millimeter (kV/mm). In some embodiments, Vertrel can be suitably pure as commercially available. For example, conductivities of about 10−12 Siemens per centimeter (S/cm) can be commercially available and can be suitable for use in an electrostatic machine. In such an example, a solvent for purification may not be required. The viscosity of Vertrel is relatively low (0.67 cP). Vertrel is nonflammable and has a low toxicity. In alternative embodiments, the dielectric fluid can comprise (or can be) other hydrofluorocarbons, such as Novec 7100 produced by 3M. Novec 7100 is a noncyclic fluorinated hydrocarbon with a chemical formula C4F9OCH3. Novec 7100 has properties similar to those of Vertrel.
However, Vertrel has a relative permittivity of 7.1, which can generate less torque in an electrostatic machine than fluids with a higher permittivity. Vertrel has a boiling point of 55° C., and, therefore, can be volatile and problematic for elevated working temperatures. In some embodiments, Vertrel can be used as a dielectric fluid in an electrostatic machine. In alternative embodiments, Vertrel can be used as a co-solvent with a fluid that has a relatively high permittivity.
In some embodiments, one or more fluids can be mixed together to produce a dielectric fluid to be used in an electrostatic machine. The mixture can have a combination of properties that is better than any of its constituent fluids. For example, a mixture of a high permittivity fluid with a low viscosity fluid can have a relatively high permittivity and a relatively low viscosity. In general, some high permittivity fluids are also highly viscous and conductive. In some embodiments, such high permittivity fluids can be mixed with a low permittivity fluid that has low viscosity and low conductivity. The resulting mixture can have a balance of physical properties that can be better suited as a dielectric fluid within an electrostatic machine.
In some embodiments, a propylene carbonate-Vertrel mixture can be used. For example, some mixed dielectric fluids can have a weight ratio of propylene carbonate to Vertrel of 60% to 40%, 70% to 30%, 80% to 20%, etc. or any ratio therein. A propylene carbonate-Vertrel mixture where the component ratio maximizes the combination of permittivity and breakdown voltage can be used for an application in which high torque production is the top priority. In alternative embodiments, a propylene carbonate-Vertrel mixture can be tailored to minimize the conductivity of the fluid for an application in which electrical efficiency of the electrostatic machine is most important. In yet other embodiments, a different propylene carbonate-Vertrel mixture can be used to create a dielectric fluid mixture that has appropriate properties for the specific application.
In some embodiments, ethylene carbonate can be used as a dielectric fluid. Ethylene carbonate is a cyclic carbonate that has similar properties as propylene carbonate. However, small structural differences between ethylene carbonate and propylene carbonate can give ethylene carbonate a higher permittivity than propylene carbonate. The relative permittivity of ethylene carbonate is close to 90, which is about 40% higher than the permittivity of propylene carbonate. The high permittivity of ethylene carbonate allows more torque to be generated in an electrostatic machine when compared to propylene carbonate.
Ethylene carbonate possesses other properties that may not be ideal for use as a dielectric fluid in some embodiments. The relatively high melting point of ethylene carbonate (e.g., 37° C.) can preclude ethylene carbonate from being the sole dielectric fluid in some embodiments of an electrostatic machine. However, in some embodiments, the dielectric fluid can be operated at elevated temperature applications that allow the ethylene carbonate to be a liquid.
In some embodiments, ethylene carbonate can be mixed with other fluids, such as propylene carbonate, to create a liquid solution at room temperature with high permittivity. For example, a mixture of 70% to 80% of ethylene carbonate and 30% to 20% of propylene carbonate can be used. Although ethylene carbonate is commercially available at 99.99% purity, additional purification can be performed to increase the suitableness for electrostatic machines. Any suitable method of purification can be used.
In some embodiments, a passivation layer can be created between electrodes (e.g., rotor plates and stator plates) and the dielectric fluid. In some instances, high permittivity fluids, such as propylene carbonate, can be thermodynamically unstable in a high electric filed. Such fluids can produce a gas that can lower the breakdown voltage, thereby leading to arcing between the electrodes. For example, propylene carbonate can be reduced at a negative electrode to produce propylene gas, and can be oxidized at the positive electrode to produce carbon dioxide gas.
In some embodiments, a passivation layer can be formed on the surface of the electrodes to reduce and/or eliminate gas formation by creating a barrier that hinders electron transfer between the electrode and the fluid. For example, a propylene carbonate based fluid including 6% by volume ethylene sulfite and 0.2% by volume water can be used as a dielectric fluid within an electrostatic machine to create a passivation layer. Ethylene sulfite can form an effective passivation layer on the negative electrode in propylene carbonate based solutions. Doping propylene carbonate with trace amounts of water can form an effective passivation layer on positively charged electrodes. For example, the breakdown voltage of a machine without a passivation layer can be 4.7 kV/mm. With the addition of a passivation layer on the electrodes of the machine, the breakdown voltage can be increased to 9.9 kV/mm. In alternative embodiments, any suitable fluid can be used to create a dielectric fluid for forming a passivation layer on the electrodes. Although ethylene sulfite and water are used in the example above, in alternative embodiments, any suitable additives can be used with propylene carbonate to form a passivation layer on the electrodes. For example, a mixture of 99% by weight propylene carbonate and 1% by weight additives can be used. In other examples, 98.5%, 98%, 95%, 90%, 80%, etc. by weight propylene carbonate can be used.
In some embodiments, a first dielectric fluid can be used to create a passivation layer (e.g., a propylene carbonate based fluid including 6% by volume ethylene sulfite and 0.2% by volume water) and a second dielectric fluid can be used while operating the electrostatic machine (e.g., high purity propylene carbonate). The rotor electrodes and stator electrodes can be immersed in a first dielectric fluid. The first dielectric fluid can fill a gap between stator electrodes and rotor electrodes. In some embodiments, a DC voltage can be applied across the stator electrodes and the rotor electrodes. The first dielectric fluid can react with surfaces of the stator electrodes and rotor electrodes, thereby forming a passivation layer on the electrodes. The first dielectric fluid can be removed from the electrodes. In some instances, the stator electrodes and rotor electrodes can be rinsed with distilled water and dried. In some embodiments, the passivation layer can be produced on the stator electrodes and rotor electrodes while the electrodes are outside of a housing of the electrostatic machine. The stator electrodes and the rotor electrodes can be assembled and placed in the housing. The housing of the electrostatic machine can be filled with the second dielectric fluid. The electrostatic machine can be run as intended with the second dielectric fluid.
In alternative embodiments, any suitable method can be used to provide a passivation layer on electrodes of an electrostatic machine. For example, the electrodes can be covered with carbon (e.g., diamond), silver, ceramic (e.g., BaTiOP3), etc. In yet other embodiments, no passivation layer may be used. In such embodiments, circulation of the dielectric fluid can be sufficient to prevent gas from building up on the electrodes.
Several factors can effect efficiency and power output of electrostatic machines. The force density between stator plates and rotor plates increases with the square of the applied electric field. Such a relationship can be seen in Coulombs law, discussed above. Thus, the applied electric field can be an important factor in creating an efficient and useful electrostatic machine. The permittivity of a fluid can be defined by the maximum electric field that can be applied before breakdown (e.g., arcing). Many factors can affect permittivity of a fluid including the gap size between rotor plates and stator plates, the material of the rotor plates and the stator plates, surface condition of the rotor plates and stator plates, geometry of the rotor plates and stator plates, liquid molecular structure and presence of impurities in the dielectric fluid, the nature of applied voltage, temperature, pressure, and uniformity of the electric field. One or more of such factors can be influenced to maximize permittivity of the fluid.
In some embodiments, increasing the distance between the electrodes (e.g., rotor plates and stator plates) can produce a significant drop in the permittivity. Experimentation with propylene carbonate confirmed that decreasing the gap improves the breakdown voltage until the gap is reduced to below 0.30 millimeters (mm). The permittivity can be largely independent of gap for gap sizes smaller than 0.30 mm. Accordingly, in some embodiments gaps between stator plates and rotor plates in machines can be about 0.30 mm.
Different metals can differ in their ability to donate or receive electrons. Accordingly, the proper pairing of electrodes can produce space-charge effects that can alter the uniformity of the applied electric field and, consequently, can affect the permittivity and ionic conductivity. In some embodiments, aluminum can be used for the negatively charged plates and stainless steel can be used for the positively charged plates with propylene carbonate as the dielectric fluid. Such a configuration can produce a force density of 10 pounds per square inch (psi). By changing the material of the positively charged plates to be aluminum, a force density of 4.5 psi can be produced. Accordingly, in some embodiments, materials of construction for the rotor plates can be different than materials of construction for the stator plates.
In some embodiments, one or more additives can be added to the dielectric fluid. For example, a small amount (e.g., 10% by volume) of 2-pyridine carbonitrile can be added to propylene carbonate. Such a combination has been discovered by experimentation to produce the greatest force density, which was measured at 11.8 psi. The improved efficacy of this mixture can be due to space-charge effects. The improved efficacy can also (or alternatively) be the result of a large cross sectional area and resonance stability, which makes the combination of fluids an effective electron absorber.
Electrostatic machines that are compact and easy to manufacture can increase the utility of such machines. In some instances, compact packaging of an electrostatic machine can be difficult because of the high voltage clearances required of the internal parts (e.g., stator plates and rotor plates) with respect to the housing. Further, seals capable of maintaining a high vacuum within the housing can be mechanically challenging. Because of the clearances needed between stator plates and rotor plates and maintenance of high vacuum, in some instances, electrostatic machines can be bulky and oversized.
However, electrostatic machines that use a dielectric fluid in the gap between the stator plates and the rotor plates may not need a high vacuum within the housing of the machine. Accordingly, the housing can be more compact and thinner, complicated vacuum seals may not be used, and a vacuum pump and associated hoses may not be used. Further, by using a dielectric fluid between the gaps of the stator plates and the rotor plates, the clearances between the stator plates and the rotor plates can be reduced, thereby reducing the size of the machine. Thus, by using a dielectric fluid, in some embodiments, the power density of electromagnetic machines can be increased.
Additionally, use of a dielectric fluid can be used as a heat transfer medium. Electrical and mechanical losses (e.g., inefficiencies) can create heat. Excessive heat can further reduce the efficiency of electrostatic machines. As discussed above, in some embodiments, an electrostatic machine can include one or more recirculation paths that can flow dielectric fluid around various parts of the electrostatic machine. Thus, the dielectric fluid can transfer heat from hotter components (e.g., stator plates, rotor plates, shafts, bearings, etc.) to cooler components (e.g., housing). Further, the one or more recirculation paths can include one or more heat exchangers configured to dissipate heat from the dielectric fluid.
As mentioned above, various aspects of an electrostatic motor system can be controlled, monitored, communicated with, etc. with one or more controllers.
In some embodiments, controller 1200 can include processor 1205. Processor 1205 can be configured to carry out and/or cause to be carried out one or more operations described herein. Processor 1205 can execute instructions as known to those skilled in the art. The instructions may be carried out by one or more special purpose computers, logic circuits (e.g., programmable logic circuits (PLC)), and/or hardware circuits. Thus, processor 1205 may be implemented in hardware, firmware, software, or any combination of these methods. The term “execution” is the process of running an application or the carrying out of the operation called for by an instruction. The instructions may be written using one or more programming language, scripting language, assembly language, etc. Processor 1205 executes an instruction, meaning that it performs the operations called for by that instruction. Processor 1205 operably couples with memory 1210, communications transceiver 1220, I/O transceiver 1210, power source 1230, user interface 1225, etc. to receive, to send, and to process information and to control the operations of the controller 1200. Processor 1205 may retrieve a set of instructions from a permanent memory device such as a read-only memory (ROM) device and copy the instructions in an executable form to a temporary memory device that is generally some form of random access memory (RAM). Controller 1200 may include a plurality of processors that use the same or a different processing technology. In an illustrative embodiment, the instructions may be stored in memory 1210.
In some embodiments, controller 1200 can include memory 1210. Memory 1210 can be an electronic holding place or storage for information so that the information can be accessed by processor 1205 as known to those skilled in the art. Memory 1210 can include, but is not limited to, any type of random access memory (RAM), any type of read-only memory (ROM), any type of flash memory, etc. such as magnetic storage devices (e.g., hard disk, floppy disk, magnetic strips, etc.), optical disks (e.g., compact disk (CD), digital versatile disk (DVD), etc.), smart cards, flash memory devices, etc. Controller 1200 may have one or more computer-readable media that use the same or a different memory media technology. Controller 1200 may have one or more drives that support the loading of a memory medium such as a CD, a DVD, a flash memory card, etc.
In some embodiments, controller 1200 can include a communications transceiver 1220. Communications transceiver 1220 can be configured to receive and/or transmit information. In some embodiments, communications transceiver 1220 can communicate information via a wired connection, such as an Ethernet connection, one or more twisted pair wires, coaxial cables, fiber optic cables, etc. In some embodiments, communications transceiver 1220 can communicate information via a wireless connection using microwaves, infrared waves, radio waves, spread spectrum technologies, satellites, etc. Communications transceiver 1220 can be configured to communicate with another device using cellular networks, local area networks, wide area networks, the Internet, etc. In some embodiments, one or more of the elements of controller 1200 communicate via wired or wireless communications.
In some embodiments, controller 1200 can include an I/O transceiver 1215. The I/O transceiver 1215 can be configured to communicate with and/or receive information from one or more sensors, devices, etc. The I/O transceiver 1215 can further be configured to transmit information to switches of a power converter (e.g., switches 910, switches 975, etc.). The I/O transceiver 1215 can be configured to receive information from one or more sensors, such as temperature sensors, pressure sensors, power sensors, voltage sensors, current sensors, torque sensors, etc. The I/O transceiver 1215 can be configured to send and transmit discrete information, analog information, digital information, etc. The I/O transceiver can include multiple cards and/or communication ports.
In some embodiments, controller 1200 can include power source 1230. Power source 1230 can be configured to provide electrical power to one or more elements of controller 1200. In some embodiments, power source 1230 can include an alternating power source, such as available line voltage (e.g., 120 Volts alternating current at 60 Hertz in the United States). Power source 1230 can include one or more transformers, rectifiers, etc. to convert electrical power into power useable by the one or more elements of controller 1200, such as 1.5 V, 8 V, 12 V, 24 V, etc. Power source 1230 can include one or more batteries.
In some embodiments, controller 1200 can include user interface 1225. User interface 1225 can be configured to receive and/or provide information from/to a user. User interface 1225 can be any user interface known in the art. User interface 1225 can be an interface for receiving user input and/or machine instructions for entry into controller 1200 as known to those skilled in the art. User interface 1225 may use various input technologies including, but not limited to, a keyboard, a stylus and/or touch screen, a mouse, a track ball, a keypad, a microphone, voice recognition, motion recognition, disk drives, remote controllers, input ports, one or more buttons, dials, joysticks, etc. to allow an external source, such as a user, to enter information into controller 1200. User interface 1225 can be used to navigate menus, adjust options, adjust settings, adjust display, etc. User interface 1225 can be configured to provide an interface for presenting information from controller 1200 to external systems, users, or memory. For example, user interface 1225 can include an interface for a display, a printer, a speaker, alarm/indicator lights, a network interface, a disk drive, a computer memory device, etc. User interface 1225 can include a color display, a cathode-ray tube (CRT), a liquid crystal display (LCD), a plasma display, an organic light-emitting diode (OLED) display, etc.
In an illustrative embodiment, any of the operations described herein can be implemented at least in part as computer-readable instructions stored on a computer-readable memory. Upon execution of the computer-readable instructions by a processor, the computer-readable instructions can cause a node to perform the operations.
The herein described subject matter sometimes illustrates different components contained within, or connected with, different other components. It is to be understood that such depicted architectures are merely exemplary, and that in fact many other architectures can be implemented which achieve the same functionality. In a conceptual sense, any arrangement of components to achieve the same functionality is effectively “associated” such that the desired functionality is achieved. Hence, any two components herein combined to achieve a particular functionality can be seen as “associated with” each other such that the desired functionality is achieved, irrespective of architectures or intermedial components. Likewise, any two components so associated can also be viewed as being “operably connected”, or “operably coupled”, to each other to achieve the desired functionality, and any two components capable of being so associated can also be viewed as being “operably couplable”, to each other to achieve the desired functionality. Specific examples of operably couplable include but are not limited to physically mateable and/or physically interacting components and/or wirelessly interactable and/or wirelessly interacting components and/or logically interacting and/or logically interactable components.
With respect to the use of substantially any plural and/or singular terms herein, those having skill in the art can translate from the plural to the singular and/or from the singular to the plural as is appropriate to the context and/or application. The various singular/plural permutations may be expressly set forth herein for sake of clarity.
It will be understood by those within the art that, in general, terms used herein, and especially in the appended claims (e.g., bodies of the appended claims) are generally intended as “open” terms (e.g., the term “including” should be interpreted as “including but not limited to,” the term “having” should be interpreted as “having at least,” the term “includes” should be interpreted as “includes but is not limited to,” etc.). It will be further understood by those within the art that if a specific number of an introduced claim recitation is intended, such an intent will be explicitly recited in the claim, and in the absence of such recitation no such intent is present. For example, as an aid to understanding, the following appended claims may contain usage of the introductory phrases “at least one” and “one or more” to introduce claim recitations. However, the use of such phrases should not be construed to imply that the introduction of a claim recitation by the indefinite articles “a” or “an” limits any particular claim containing such introduced claim recitation to inventions containing only one such recitation, even when the same claim includes the introductory phrases “one or more” or “at least one” and indefinite articles such as “a” or “an” (e.g., “a” and/or “an” should typically be interpreted to mean “at least one” or “one or more”); the same holds true for the use of definite articles used to introduce claim recitations. In addition, even if a specific number of an introduced claim recitation is explicitly recited, those skilled in the art will recognize that such recitation should typically be interpreted to mean at least the recited number (e.g., the bare recitation of “two recitations,” without other modifiers, typically means at least two recitations, or two or more recitations). Furthermore, in those instances where a convention analogous to “at least one of A, B, and C, etc.” is used, in general such a construction is intended in the sense one having skill in the art would understand the convention (e.g., “a system having at least one of A, B, and C” would include but not be limited to systems that have A alone, B alone, C alone, A and B together, A and C together, B and C together, and/or A, B, and C together, etc.). In those instances where a convention analogous to “at least one of A, B, or C, etc.” is used, in general such a construction is intended in the sense one having skill in the art would understand the convention (e.g., “a system having at least one of A, B, or C” would include but not be limited to systems that have A alone, B alone, C alone, A and B together, A and C together, B and C together, and/or A, B, and C together, etc.). It will be further understood by those within the art that virtually any disjunctive word and/or phrase presenting two or more alternative terms, whether in the description, claims, or drawings, should be understood to contemplate the possibilities of including one of the terms, either of the terms, or both terms. For example, the phrase “A or B” will be understood to include the possibilities of “A” or “B” or “A and B.” Further, unless otherwise noted, the use of the words “approximate,” “about,” “around,” etc., mean plus or minus twenty percent.
The foregoing description of illustrative embodiments has been presented for purposes of illustration and of description. It is not intended to be exhaustive or limiting with respect to the precise form disclosed, and modifications and variations are possible in light of the above teachings or may be acquired from practice of the disclosed embodiments. It is intended that the scope of the invention be defined by the claims appended hereto and their equivalents.
The present application claims the benefit of U.S. Provisional Patent Application No. 62/059,903, filed Oct. 5, 2014, which is incorporated herein by reference in its entirety.
The present disclosure was made with government support under IIP 1345755 awarded by the National Science Foundation. The government has certain rights in the invention.
Number | Date | Country | |
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62059903 | Oct 2014 | US |