The present invention relates to an element substrate, a manufacturing method of the element substrate, a printhead, and a printing apparatus, and particularly to, for example, a printing apparatus which is applied in order to perform, in accordance with an inkjet method, printing using a printhead which incorporates an element substrate for integrating a temperature detection element.
For higher image quality and higher-speed printing, inkjet printheads have been changing to an arrangement in which there is a higher density of print elements and nozzles, and a large number of nozzles are arrayed. In recent years, in particular, there have been proposed a large number of full-line printheads where a plurality of element substrates are arranged across the width of a print medium such as a printing paper sheet.
On the other hand, as the number of nozzles increases, the probability that an ink discharge failure occurs in some nozzles due to nozzle clogging, bubbles trapped in an ink supply channel, leakage on a nozzle surface, or the like increases. To cope with this, a technique of specifying the nozzles where the discharge failure has occurred and giving feedback on them to image complementary printing or printhead recovery processing becomes more important. Japanese Patent Laid-Open Nos. 2008-023987 and 2012-250511 disclose an arrangement that provides each print element with a temperature detection element formed by a thin film resistor via an insulation film, detects temperature information for each nozzle, and specifies a nozzle suffering a discharge failure from a temperature change. A technique of giving feedback to image complementary printing or printhead recovery processing by this is proposed.
Japanese Patent Laid-Open No. 2012-250511 discloses a method of conducting a discharge inspection by applying a driving pulse that emphasizes the temperature change in order to facilitate detection. Such a driving method for conducting a discharge inspection is effective. In order to greatly improve sensitivity to detect the temperature change, however, it is desirable that a structure in which each temperature detection element is arranged immediately below a corresponding one of the print elements via the insulation film is adopted, and a distance between the print element and the temperature detection element is made shorter as much as possible. Taking a printhead substrate disclosed in Japanese Patent Laid-Open No. 2012-250511 as an example, it is only necessary that an interlayer insulation film between a heater and a temperature detection element can be made thin.
However, the interlayer insulation film needs to have a thickness that ensures an electrical insulating property between a wiring and another wiring, and coverage of the wirings themselves. For the arrangement described in Japanese Patent Laid-Open No. 2012-250511, the interlayer insulation film needs to have a thickness that ensures coverage of a step portion caused by a thick film wiring connected to the temperature detection element. Thus, the distance between the print element and the temperature detection element is restricted by the thickness of an insulation film between wiring layers.
Accordingly, the present invention is conceived as a response to the above-described disadvantages of the conventional art.
For example, an element substrate, a manufacturing method of the element substrate, a printhead, and a printing apparatus according to this invention are capable of forming an interlayer insulation film between an electrothermal transducer and a temperature detection element thin, and improving temperature detection sensitivity.
According to one aspect of the present invention, there is provided an element substrate having a multilayered structure comprising: a base; a wiring layer formed on a side of a front surface of the base; a first interlayer insulation film configured to cover the wiring layer; a temperature detection element formed on a surface of the first interlayer insulation film; a first electrical connecting member configured to penetrate through the first interlayer insulation film, and electrically connect the temperature detection element and a wiring for the temperature detection element of the wiring layer; a second interlayer insulation film formed on a surface of the temperature detection element and the surface of the first interlayer insulation film; an electrothermal transducer arranged at a position where at least a part of the electrothermal transducer overlaps the temperature detection element when viewed from a direction perpendicular to the front surface of the base, and formed on a surface of the second interlayer insulation film; and a second electrical connecting member configured to penetrate through at least the second interlayer insulation film, and electrically connect the electrothermal transducer and a wiring for the electrothermal transducer of the wiring layer.
According to another aspect of the present invention, there is provided a manufacturing method of an element substrate having a multilayered structure comprising: forming a first interlayer insulation film configured to cover a wiring layer with respect to a base with the wiring layer being formed on a side of a front surface of the base; forming a first via hole configured to reach the wiring layer in the first interlayer insulation film; forming a first electrical connecting member by filling the first via hole with a metal material and smoothing a surface of the first interlayer insulation film; forming a temperature detection element in a region on the surface of the first interlayer insulation film including the first electrical connecting member; forming a second interlayer insulation film on the surface of the first interlayer insulation film and a surface of the temperature detection element; and forming an electrothermal transducer on a surface of the second interlayer insulation film.
According to still another aspect of the present invention, there is provided a printhead that uses an element substrate having a multilayered structure, uses an electrothermal transducer as a print element, and discharges ink by applying thermal energy to ink by the print element, comprising: an orifice provided near the print element and configured to discharge ink; a supply port configured to supply ink to the print element; and a pressure chamber configured to communicate with the supply port and the orifice, in which ink bubbles due to heat generation of the print element, wherein the element substrate comprises: a base; a wiring layer formed on a side of a front surface of the base; a first interlayer insulation film configured to cover the wiring layer; a temperature detection element formed on a surface of the first interlayer insulation film; a first electrical connecting member configured to penetrate through the first interlayer insulation film, and electrically connect the temperature detection element and a wiring for the temperature detection element of the wiring layer; a second interlayer insulation film formed on a surface of the temperature detection element and the surface of the first interlayer insulation film; an electrothermal transducer arranged at a position where at least a part of the electrothermal transducer overlaps the temperature detection element when viewed from a direction perpendicular to the front surface of the base, and formed on a surface of the second interlayer insulation film; and a second electrical connecting member configured to penetrate through at least the second interlayer insulation film, and electrically connect the electrothermal transducer and a wiring for the electrothermal transducer of the wiring layer.
According to still another aspect of the present invention, there is provided a printing apparatus which prints an image by discharging ink to a print medium by using a printhead that uses an element substrate having a multilayered structure, uses an electrothermal transducer as a print element, and discharges ink by applying thermal energy to ink by the print element, wherein the printhead comprises: an orifice provided near the print element and configured to discharge ink; a supply port configured to supply ink to the print element; and a pressure chamber configured to communicate with the supply port and the orifice, in which ink bubbles due to heat generation of the print element, wherein the element substrate comprises: a base; a wiring layer formed on a side of a front surface of the base; a first interlayer insulation film configured to cover the wiring layer; a temperature detection element formed on a surface of the first interlayer insulation film; a first electrical connecting member configured to penetrate through the first interlayer insulation film, and electrically connect the temperature detection element and a wiring for the temperature detection element of the wiring layer; a second interlayer insulation film formed on a surface of the temperature detection element and the surface of the first interlayer insulation film; an electrothermal transducer arranged at a position where at least a part of the electrothermal transducer overlaps the temperature detection element when viewed from a direction perpendicular to the front surface of the base, and formed on a surface of the second interlayer insulation film; and a second electrical connecting member configured to penetrate through at least the second interlayer insulation film, and electrically connect the electrothermal transducer and a wiring for the electrothermal transducer of the wiring layer.
According to still another aspect of the present invention, there is provided an element substrate having a multilayered structure comprising: a base; a wiring layer formed on a side of a front surface of the base; a first interlayer insulation film configured to cover the wiring layer; a temperature detection element formed on a surface of the first interlayer insulation film; a first electrical connecting member configured to penetrate through the first interlayer insulation film, and electrically connect the temperature detection element and a wiring for the temperature detection element of the wiring layer; a second interlayer insulation film which is formed on a surface of the temperature detection element and the surface of the first interlayer insulation film, and is thinner than the first interlayer insulation film; an electrothermal transducer formed on a surface of the second interlayer insulation film; and a second electrical connecting member configured to penetrate through at least the second interlayer insulation film, and electrically connect the electrothermal transducer and a wiring for the electrothermal transducer of the wiring layer.
The invention is particularly advantageous since it is possible to form the interlayer insulation film between the electrothermal transducer and the temperature detection element thin, and improve temperature detection sensitivity. This improves, for example, the detection accuracy of an ink discharge state of an inkjet printhead that incorporates the element substrate.
Further features of the present invention will become apparent from the following description of exemplary embodiments with reference to the attached drawings.
Exemplary embodiments of the present invention will now be described in detail in accordance with the accompanying drawings.
In this specification, the terms “print” and “printing” not only include the formation of significant information such as characters and graphics, but also broadly include the formation of images, figures, patterns, and the like on a print medium, or the processing of the medium, regardless of whether they are significant or insignificant and whether they are so visualized as to be visually perceivable by humans.
Also, the term “print medium (or sheet)” not only includes a paper sheet used in common printing apparatuses, but also broadly includes materials, such as cloth, a plastic film, a metal plate, glass, ceramics, wood, and leather, capable of accepting ink.
Furthermore, the term “ink” (to be also referred to as a “liquid” hereinafter) should be broadly interpreted to be similar to the definition of “print” described above. That is, “ink” includes a liquid which, when applied onto a print medium, can form images, figures, patterns, and the like, can process the print medium, and can process ink. The process of ink includes, for example, solidifying or insolubilizing a coloring agent contained in ink applied to the print medium.
Further, a “nozzle (to be also referred to as a “print element” hereinafter)” generically means an ink orifice or a liquid channel communicating with it, and an element for generating energy used to discharge ink, unless otherwise specified.
An element substrate for a printhead (head substrate) used below means not merely a base made of a silicon semiconductor, but an arrangement in which elements, wirings, and the like are arranged.
Further, “on the substrate” means not merely “on an element substrate”, but even “the surface of the element substrate” and “inside the element substrate near the surface”. In the present invention, “built-in” means not merely arranging respective elements as separate members on the base surface, but integrally forming and manufacturing respective elements on an element substrate by a semiconductor circuit manufacturing process or the like.
<Overview of Printing Apparatus (
As shown in
Not only the printhead 3 is mounted on the carriage 2 of the printing apparatus 1. An ink tank 6 that stores ink to be supplied to the printhead 3 is also attached to the carriage 2. The ink tank 6 is detachable from the carriage 2.
The printing apparatus 1 shown in
The printhead 3 according to this embodiment employs an inkjet method of discharging ink using thermal energy. Hence, the printhead 3 includes an electrothermal transducer (heater). The electrothermal transducer is provided in correspondence with each orifice. When a pulse voltage is applied to a corresponding electrothermal transducer in accordance with a print signal, ink is discharged from a corresponding orifice. Note that the printing apparatus is not limited to the above-described serial type printing apparatus and is also applicable to a so-called full-line type printing apparatus which arranges, in the conveyance direction of the print medium, a printhead (line head) with orifices arrayed in the widthwise direction of the print medium.
As shown in
Also, referring to
In addition, reference numeral 620 denotes a switch group including a power switch 621, a print switch 622, a recovery switch 623, and the like.
Reference numeral 630 denotes a sensor group configured to detect an apparatus state, which includes a position sensor 631, a temperature sensor 632, and the like.
Furthermore, reference numeral 640 denotes a carriage motor driver that drives the carriage motor M1 configured to make the carriage 2 reciprocally scan in the direction of the arrow A; and 642, a conveyance motor driver that drives the conveyance motor M2 configured to convey the print medium P.
At the time of print scan by the printhead 3, the ASIC 603 transfers data used to drive a heating element (heater for ink discharge) to the printhead while directly accessing the storage area of the RAM 604. This printing apparatus additionally includes, as a user interface, a display unit formed by an LCD or LED.
Embodiments of the element substrate integrated on the printhead mounted in the printing apparatus with the above-described arrangement will be described next.
<Description of Element Substrate (
To describe the arrangement of each layer of a base plate 402 below, a surface on a side where a nozzle plate 403 is provided is described as a front surface, and a surface on a side opposite to this is described as a back surface. In addition, in a layering direction on the base plate 402, a side on which the nozzle plate 403 is provided is described as an upper side, and an opposite side is described as a lower side.
As shown in
As shown in
Referring to
Then, the wiring 103 and the print element 109 that operates as an electrothermal transducer (heater) and is formed by a tantalum silicon nitride film or the like are electrically connected via conductive plugs 108 (electrical connecting members) which penetrate through the interlayer insulation film 104 and the interlayer insulation film 107, and made of tungsten or the like.
Note that instead of the conductive plugs 108, electrical connecting members may be used, which are formed by connecting conductive plugs which penetrate through the interlayer insulation film 104, and conductive plugs which are formed by a different process from that of the other conductive plugs and penetrate through the interlayer insulation film 107 via a spacer formed by an intermediate wiring layer. When thus connecting the conductive plugs in a lower layer and the conductive plugs in an upper layer, they are generally connected by sandwiching the spacer formed by the intermediate wiring layer. Applied to this embodiment, however, since the film thickness of the temperature detection element serving as the intermediate wiring layer is as small as about several ten nm, the accuracy of overetching control with respect to a temperature detection element film serving as the spacer is required when forming a via hole. Moreover, the thin film is also disadvantageous in pattern miniaturization of a temperature detection element layer.
Considering this situation, it is preferable that the conductive plugs 108 are adopted, which penetrate through the interlayer insulation film 104 and the interlayer insulation film 107 as in this embodiment.
Note that the wiring 103 includes a wiring 103a for a temperature detection element connected to the temperature detection element 106 and a wiring 103b for a print element (wiring for the electrothermal transducer) connected to the print element 109. These wiring 103a and wiring 103b are electrically independent of each other. In this embodiment, the respective wiring 103a and wiring 103b are formed from the wiring 103 formed as the same layer. However, the respective wirings may be formed from wiring layers formed as different layers in the layering direction.
Next, the base plate 402 is obtained by forming a protective film (coated membrane) 110 such as a silicon nitride film, and then forming an anti-cavitation film 111 that contains tantalum or iridium or includes a layered film of tantalum and iridium on the protective film 110. Furthermore, an orifice 113 is formed by a nozzle forming member 112 made of a photosensitive resin or the like.
Note that in this embodiment, the print element 109 and the thick film wiring 103 arranged in the lower layer are connected via the conductive plugs 108. In addition, the surface of the interlayer insulation film 107 is smoothed. Thus, a step caused by the thick film wiring 103 is not created on the surface side of the element substrate, making it possible to ensure coverage even if the protective film 110 that covers the print element 109 is made thin. It is therefore possible to shorten a distance from the temperature detection element 106 to an interface with ink by forming the protective film 110 thin, and to increase sensitivity to detect a temperature state on the surface of the anti-cavitation film 111 which serves as the interface with ink.
As described above, the element substrate of this embodiment has the multilayered structure 101 where an independent intermediate layer of the temperature detection element 106 is provided between the layer of the print element 109 and the layer of the wiring 103 (to be referred to as the wiring layer 103 hereinafter). Note that the plurality of interlayer insulation films 104 each in which the wiring layer 103 is embedded may be layered on the lower side of the temperature detection element 106. In this case, a plurality of wiring layers embedded in different interlayer insulation films may be connected via a plug.
Note that the nozzle forming member 112 corresponds to the nozzle plate 403 in
As shown in
With such an array of the conductive plugs, a region where the temperature detection element film and a print element film overlap increases when viewing the element substrate from an upper surface, allowing the temperature detection element film to detect heat conducted by a temperature change of the print element more efficiently. As a result, temperature detection with higher sensitivity is implemented. In addition, the arrangement positions of the conductive plugs 108 that perform electrical connection between the print element 109 and the wiring layer 103, and the conductive plugs 105 that perform electrical connection between the temperature detection element 106 and the wiring layer 103 are changed, and they are arranged in a region other than the region where the temperature detection element film and the print element film overlap. With this arrangement, in addition to an improvement in sensitivity of the temperature detection element, a planar region of the element substrate is used effectively to suppress an increase in size of the element substrate 401.
Note that as for the conductive plugs 105 connected to the temperature detection element 106, it is only necessary that at least a pair of conductive plugs 105 is provided in order to supply a current to the temperature detection element 106. In addition, as for the conductive plugs 108 connected to the print element 109, it is only necessary that at least a pair of conductive plugs 108 is provided in order to supply a current to the print element 109. One of at least the pair of conductive plugs 108 is connected to one end of the print element 109 in a right-and-left direction (first direction) of
Heat conduction considered in the multilayered structure of this embodiment will be described next.
When using, as a print element, an electrothermal transducer (heater) formed in the multilayered structure, a heat storage layer having heat conductivity which is low to some extent preferably exists between the print element and the silicone base in order to apply heat to ink efficiently. On the other hand, in order to drive the print element at a high speed, heat conductivity to some extent is also required so unnecessary ink bubbling does not occur by diffusing excess heat quickly.
In this embodiment, the interlayer insulation film 104 arranged immediately below the print element 109 functions as a heat storage layer having a thickness t1, and the interlayer insulation film 107 arranged immediately below the print element 109 functions as a heat storage layer having a thickness t2. As shown in
Note that the thickness t1 is the thickness of a portion of the interlayer insulation film 104 located on the metal layer 115. Further, the thickness t2 is the thickness of a portion of the interlayer insulation film 107 located on the temperature detection element 106. With such a heat dissipation channel, the arrangement has appropriate heat storage and heatsink characteristics.
Next, a requirement to provide the layer of the temperature detection element 106 between the print element 109 and the metal layer 115 will be given.
The interlayer insulation film 107 having the thickness t2 needs to assuredly insulate the temperature detection element 106 and the print element 109, further suppress the influence of an action of the temperature detection element 106 as a heat dissipation element, and be set in a range that satisfies these. It is therefore preferable that the thickness t2 of the interlayer insulation film 107 is equal to or more than 0.2 μm. On the other hand, in order to improve the sensitivity of the temperature detection element 106, the thickness t2 of the interlayer insulation film 107 is preferably 0.5 μm or less. That is, it is preferable that the thickness t2 of the interlayer insulation film 107=0.2 μm to 0.5 μm.
From the viewpoint of heat storage, a total thickness t1+t2 of the interlayer insulation film 104 and the interlayer insulation film 107 serving as the heat storage layers needs to be a predetermined thickness. In order to assuredly cover the wiring layer 103, the interlayer insulation film 104 is generally formed such that the thickness t1 becomes equal to or larger than the thickness of the wiring layer 103. Note that a large current flows because the wiring layer 103 is a wiring of a power source driven by the print element 109 or a GND. Therefore, in order to satisfy a reduction in resistance and a predetermined current density or less, the wiring layer 103 needs to have a sufficient thickness of about several μm (for example, 1 μm). Note that the metal layer 115 formed by the same process as the wiring layer 103 is also formed with the same thickness as the wiring layer 103.
That is, it is required that the total thickness t1+t2 as the heat storage layers has the predetermined thickness while increasing t1 in order to cover the wiring layer 103 which has sufficient thickness. On the other hand, the interlayer insulation film 107 is required to obtain sensitivity to a temperature change as much as possible while satisfying requirements of insulation properties and a heatsink influence. In order to satisfy these requirements, the distribution ratio of the thicknesses t1 and t2 is preferably set to t1>t2 as in this embodiment.
As shown in
As shown in
<Heat Conductive Property (
Conditions for this calculation are as follows.
the thickness (t2) of the interlayer insulation film 107:
t2=0.4 μm, t2=0.9 μm
the size of the print element 109 serving as a heat source:
width 15.6 μm×length 23.6 μm×thickness 20 nm
heat generation amount: 4.8×1016 w/m3
heat generation time: 0.7 μsec
initial temperature: room temperature
Referring to
By thus making the interlayer insulation film 107 between the print element 109 and the temperature detection element 106 thin, a sharp high-speed temperature waveform with suppressed attenuation is obtained, and sensitivity to detect a temperature state at the interface of the anti-cavitation film 111 improves.
<Element Substrate Manufacturing Process (
Step A (Formation and Smoothing of First Interlayer Insulation Film)
Above an insulation film 301 layered on the silicone base, an etching mask for patterning a wiring layer 302 is formed on the wiring layer 302 by photolithography. More specifically, a resist pattern is formed on a wiring layer by spin-coating a positive photosensitive resist material serving as a mask on a base plate, performing exposure via a photomask where a wiring pattern is drawn, and performing development.
Subsequently, a wiring pattern is formed by removing the wiring layer 302 in regions which are not masked with the resist pattern by dry etching. At this time, a photoresist is removed by plasma ashing after a metal film is anisotropically etched by reactive ion etching. When forming a wiring pattern from the wiring layer 302, a wiring for a temperature detection element connected to a temperature detection element 308 and a wiring for a print element connected to a print element 314 are formed to be electrically independent of each other. The above-described metal layer 115 for heatsink is also formed from the wiring layer 302. This makes it possible to suppress a load in the manufacturing process.
Subsequently, a silicon oxide film is formed on the wiring layer 302 as an interlayer insulation film 303. At this time, an HDP (High Density Plasma) oxide film, which is obtained by overlapping bias sputtering elements in order to embed the silicon oxide film in even a fine gap between wirings without any gap, also forms the interlayer insulation film 303 formed by the silicon oxide film in combination with a lower layer portion.
Subsequently, the upper surface of the interlayer insulation film 303 is smoothed by polishing the silicon oxide film by CMP (Chemical Mechanical Polishing).
Step B (Formation of Via Hole)
Via holes where conductive plugs are formed in the interlayer insulation film 303, which have a resist pattern with mask openings of via hole portions, are formed by the same process as photolithography described above. Subsequently, via holes 304 are formed by inductively coupled plasma reactive ion etching. Consequently, the surface of the wiring layer 302 for the temperature detection element is partially exposed from each via hole 304. In addition, a resist used as an etching mask is removed by performing plasma ashing.
Step C (Formation of First Barrier Metal)
A barrier metal 305 made of a layered film of a contact metal, titanium serving as a diffusion preventing film, and titanium nitride is formed by sputtering film forming.
Step D (Film Forming of First Tungsten Film)
By low-pressure CVD film forming, a tungsten film 306 is formed, as a conductive plug material, with a film thickness that fills the via holes sufficiently.
Step E (First Polishing)
By CMP, while leaving only conductive plugs 307 in the via holes, the barrier metal 305 and the tungsten film 306 on the interlayer insulation film 303 are polished to be removed without any residual, smoothing the surface of the interlayer insulation film 303.
Note that, for this step, there is also a method of removing the conductive plug material and the barrier metal by using etch back.
Step F (Formation of Temperature Detection Element)
Sputtering film forming is performed for the layered film of titanium and titanium nitride used as a temperature detection element of this embodiment. Subsequently, a resist mask is formed by photolithography, and a temperature detection element 308 is formed by dry etching.
Step G (Formation and Smoothing of Second Interlayer Insulation Film)
By plasma CVD, an interlayer insulation film 309 formed by a silicon oxide film is formed on the temperature detection element 308. Then, the silicon oxide film is polished by CMP, smoothing the upper surface of the interlayer insulation film 309.
Step H (Formation of Via Hole)
Via holes that penetrate through the interlayer insulation film 303 and the interlayer insulation film 309 are formed, which have a resist pattern with mask openings of via hole portions, are formed by the same process as photolithography described above. Subsequently, via holes 310 are formed by inductively coupled plasma reactive ion etching. Consequently, the surface of the wiring layer 302 for an electrothermal transducer is partially exposed from each via hole 310. Note that a resist used as an etching mask is removed by performing plasma ashing.
Step I (Formation of Second Barrier Metal)
A barrier metal 311 made of a layered film of a contact metal, titanium serving as a diffusion preventing film, and titanium nitride is formed by sputtering film forming.
Step J (Film Forming of Second Tungsten Film)
By low-pressure CVD film forming, a tungsten film 312 is formed, as a conductive plug material, with a film thickness that fills the via holes sufficiently.
Step K (Second Polishing)
By CMP the barrier metal 311 and the tungsten film 312 on the interlayer insulation film 309 are polished to be removed without any residual, smoothing the surface of the interlayer insulation film 309, while leaving only conductive plugs 313 in the via holes. Note that, for this step, there is also a method of removing the conductive plug material and the barrier metal by using etch back.
Step L (Formation of Print Element)
Sputtering film forming is performed for a film of a print element that serves as an electrothermal transducer (heater) which is formed by a tantalum silicon nitride film or the like used as a print element. Then, a resist mask is formed by photolithography, and the print element 314 is formed by dry etching.
Step M (Formation of Element Substrate)
An element substrate is obtained by forming a passivation film (protective film) 315 such as a silicon nitride film and an anti-cavitation film 316 made of tantalum or the like.
Step N (Formation of Orifice)
A photosensitive resin is used for a nozzle forming member 317, and an orifice is formed by using a photolithography technique.
Therefore, according to the above-described embodiment, because an interlayer insulation film between a print element and a temperature detection element can be made thin, a temperature change characteristic of the temperature detection element follows a temperature change of the print element satisfactorily, improving temperature detection sensitivity. This makes it possible to improve the detection accuracy of an ink discharge state.
Note that as shown in
While the present invention has been described with reference to exemplary embodiments, it is to be understood that the invention is not limited to the disclosed exemplary embodiments. The scope of the following claims is to be accorded the broadest interpretation so as to encompass all such modifications and equivalent structures and functions.
This application claims the benefit of Japanese Patent Application No. 2017-197771, filed Oct. 11, 2017, and Japanese Patent Application No. 2018-160602, filed Aug. 29, 2018 which are hereby incorporated by reference herein in their entirety.
Number | Date | Country | Kind |
---|---|---|---|
2017-197771 | Oct 2017 | JP | national |
2018-160602 | Aug 2018 | JP | national |