The invention relates to fuel elements for nuclear power plants and more particularly to elongated fuel segments contained within elongated SiC cladding.
Silicon carbide (SiC) has been shown to be a very promising accident tolerant fuel (ATF) cladding, but one of the main challenges of SiC is that the fuel pellets housed in the SiC cladding tubes cannot have strong contact with the cladding without the risk of losing hermeticity in the SiC cladding.
UO2 fuel has a long and successful history of use in the nuclear industry. While UO2 has low reactivity with light water coolants, moderate swelling and stable structure during irradiation, it suffers from low thermal conductivity which limits its use to small diameter fuel rods. In use, fission products will cause swelling of the UO2 and unless there is a large enough initial gap between the fuel pellets and a non-ductile cladding such as SiC, the inevitable swelling leads to cladding failure from strong mechanical interaction between the pellet and cladding (PCMI). Increasing the initial pellet-cladding gap to solve the PCMI issue will cause even higher fuel centerline temperature due to the low thermal conductivity of helium gas in the gap and reduced uranium loading. This drawback becomes evident when UO2 is used in fuel rods with advanced, accident tolerant cladding such as SiC which requires minimal fuel to cladding mechanical interaction to avoid cracking and loss of hermeticity. Therefore, the use of UO2 in SiC cladding is not possible for cylindrical fuel rod geometry without severe economic penalties.
Fuels such as U3Si2, UN, and uranium alloys, on the other hand, can mitigate the PCMI issue due to their high fuel thermal conductivity and reduced fuel centerline temperature by leaving a larger pellet-cladding gap, but at the cost of reduced uranium loading. Furthermore, these fuels have poor water corrosion resistance, which is detrimental during a leaker event in a light water reactor because of the compromise to the accident tolerance of the fuel.
For metal claddings such as Zr, which has a strain capability of 2 to 4%, the gap is not a PCMI issue but merely needs to be large enough to load the fuel pellets. However, if a leak occurs, U3Si2, for example, will undergo oxidation, increasing the internal volume in the Zr cladding. The increased volume causes the cladding to balloon out resulting in blockage of the coolant path.
SiC cladding has improved high temperature performance during accident conditions over traditional Zr based materials. However, the rod type fuel design has limited the potential of SiC material since SiC has a limited strain capability (˜0.04 to 0.1%) to relieve local stress build up and minimize mechanical interaction between fuel and cladding. The approach to solving this problem has been to leave a large fuel-cladding gap. However, the large gap will significantly increase fuel centerline temperature, especially in a low thermal conductivity fuel such as UO2, resulting in a large fission gas release and/or swelling and also reduce the uranium loading resulting in a severe economic penalty.
Plate fuels, such as those disclosed in U.S. Pat. Nos. 3,173,843; 3,297,543; 3,586,745; 3,855,061; 4,038,135; and 4,224,106, developed initially in the 1960s and 1970s used metal cladding (e.g., aluminum or zirconium alloys) and metallic fuel or fuel dispersed in metallic matrix (e.g., UZr or UMo). Such plate fuels were found not to be suitable for commercial reactors and abandoned, but are currently used in test reactors and have been evaluated for use in small modular reactors. See Mark D. DeHart, “Fuel Element Design and Analysis for Potential LEU Conversion of the Advanced Test Reactor,” INL/JOU-17-41538 Revision 0, April 2018; Samuel J. Miller, et al., “Evaluation of U10Mo Fuel Plate Irradiation Behavior Via Numerical and Experimental Benchmarking” INL/CON-12-25074, November 2012; and Min-Gil Kim, et al., “Comparison of Thermal Hydraulic Performances of Rod Type Fuel to Plate-Type Fuel for Small Modular Reactor Application,” Proceedings of ICAPP, April 2014.
The following summary is provided to facilitate an understanding of some of the innovative features unique to the embodiments disclosed and is not intended to be a full description. A full appreciation of the various aspects of the embodiments can be gained by taking the entire specification, claims, and abstract as a whole.
To address the problems arising from pellet cladding mechanical interaction between SiC cladding and nuclear fuel, while simultaneously providing the benefit of more uranium loading and better safety margins, especially in light water reactors, a new fuel element is described herein comprised of an elongate shaped fuel with elongate shaped SiC cladding.
In various aspects, the fuel element for use in a nuclear reactor includes a silicon carbide cladding and a nuclear fuel housed within the cladding. The cladding has two opposing elongated walls and two opposing end walls shorter than the elongated walls. Together, the elongated walls and the end walls define an enclosure. The enclosure has a length from end wall to end wall and a width from elongated wall to elongated wall and the cladding has a longitudinal axis and a transverse axis perpendicular to the longitudinal axis. The nuclear fuel has two elongated surfaces and two end surfaces shorter than the elongated surfaces. Prior to swelling in use, each of the two elongated surfaces are minimally spaced (for example, between about 0.05 to 2.0 mm) at a first distance from, and in a facing relationship to, a different one of the elongated walls of the cladding, and each of the end surfaces are spaced at a second distance from, and in facing relationship to, a different one of the end walls of the cladding. The second distance is greater than the first distance. The first and second distances are dimensioned such that, in use, when the fuel swells, the swollen fuel swells beyond the first distance and up to but not beyond the second distance to deform the elongated walls of the cladding without deforming the end walls of the cladding and without straining the cladding more 0.1%.
The strain on the cladding due to swelling of the fuel is in various aspects, no more than 0.05%.
The second distance defines a gap between the fuel end surfaces and the cladding end walls that is dimensioned to allow for the maximum swelling of the selected fuel plus space for fission gases produced in use. Those skilled in the art can calculate by known means or determine by historical use, the maximum amount of swelling the selected fuel will undergo in use and the amount of fission gas that would be produced in use to determine the second distance. The first distance defines a gap between each of the elongated walls of the cladding and the facing elongated surface of the fuel. The first distance gap is sufficient to allow the fuel to be inserted into the cladding prior to use, typically about 0.07 mm.
The fuel may, in certain aspects, be configured in cross-section in an elliptical shape defining a vertex at each of the shorter end surfaces, with the two elongated surfaces being convexly curved. The elliptical shape has a major axis extending from vertex to vertex, and a minor axis perpendicular to the major axis. Each convexly curved surface has a co-vertex at the minor axis and curves from the co-vertex to, and meets, each vertex. The first distance in this embodiment is smallest between the co-vertexes and the elongated walls of the cladding.
In certain aspects of the fuel element, the elongated walls of the cladding may curve inwardly towards the fuel. Prior to deformation in use, the elongate walls of the cladding may curve concavely inwardly towards the fuel, and in use, are deformed outwardly. The end walls of the cladding in various aspects, may be flat prior to use and remain flat in use.
Prior to swelling in use, the elongate surfaces of the fuel may curve concavely inwardly towards each other, and in use, swell outwardly to form a convexly curved elongated surfaces that extend beyond the first distance to deform the elongate walls of the cladding. Each concavely curved elongated surface defines a co-vertex at the minor axis and curves from the co-vertex to, and meets, each end surface. Prior to swelling in use, the end surfaces of the fuel may be flat, and in use, swell outwardly to form convexly curved end surfaces. Alternatively, prior to swelling in use, the end surfaces of the fuel may be flat, and in use, remain flat.
In various aspects, prior to swelling in use, the fuel may be configured in cross-section in a rectilinear shape defining flat end surfaces and flat elongated surfaces. The rectilinear shape defines a major axis extending from end surface to end surface, and a minor axis perpendicular to the major axis. In use, the fuel swells outwardly along both the major and minor axes to form, in cross-section, an elliptical configuration. Prior to swelling in use, the cladding may be configured in cross-section in a rectilinear shape defining flat end walls and flat elongated walls which deform outwardly when in use, the fuel swells.
In various aspects, the end walls of the cladding are thicker in cross-section than the elongated walls of the cladding.
The fuel may be a fissile material selected from the group consisting of UO2, U3Si2, UN, and a uranium alloy.
The elongate shaped fuel with elongate shaped SiC cladding enables use of the proven benefits of fuels, such as UO2, along with the accident tolerant features of SiC cladding material without compromising the fuel performance both during normal operations and under transient conditions. The proposed elongate shaped SiC cladding with elongate shaped fuel and end gaps allowing for fuel expansion offers benefits such as improved heat transfer with small gap or direct contact between fuel and cladding. The elongated SiC cladding with elongated fuel also will result in lower fuel temperatures due to the minimal gap throughout the life of the fuel, which will result in less fission gas release and swelling, less deformation on the cladding during transient events due to low temperature increases, and reduced tensile stress upon hard contact between fuel and cladding due to the increased span of the allowed cladding bulge. The elongated cladding surface can optionally be pre-curved to further mitigate local stress build up. The SiC clad elongated fuel described herein allows for the use of UO2 fuel without compromising the economics of UO2 or the accident tolerant features of SiC.
The characteristics and advantages of the present disclosure may be better understood by reference to the accompanying figures.
As used herein, the singular form of “a”, “an”, and “the” include the plural references unless the context clearly dictates otherwise. Thus, the articles “a” and “an” are used herein to refer to one or to more than one (i.e., to at least one) of the grammatical object of the article. By way of example, “an element” means one element or more than one element.
Directional phrases used herein, such as, for example and without limitation, top, bottom, left, right, lower, upper, upward, down, downward, front, back, and variations thereof, shall relate to the orientation of the elements shown in the accompanying drawing and are not limiting upon the claims unless otherwise expressly stated.
In the present application, including the claims, other than where otherwise indicated, all numbers expressing quantities, values or characteristics are to be understood as being modified in all instances by the term “about.” Thus, numbers may be read as if preceded by the word “about” even though the term “about” may not expressly appear with the number. Accordingly, unless indicated to the contrary, any numerical parameters set forth in the following description may vary depending on the desired properties one seeks to obtain in the compositions and methods according to the present disclosure. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter described in the present description should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.
Further, any numerical range recited herein is intended to include all sub-ranges subsumed therein. For example, a range of “1 to 10” is intended to include any and all sub-ranges between (and including) the recited minimum value of 1 and the recited maximum value of 10, that is, having a minimum value equal to or greater than 1 and a maximum value of equal to or less than 10.
Referring to
In use, at the beginning of the fuel life cycle, the fuel segment 14 swells. Fuel is isotropic, so it will expand evenly in all directions. With the elongate cladding and fuel configurations described herein, the elongated walls 18 present a force that prevents the fuel from swelling freely in the transverse direction (i.e., along the Y axis as shown in
In various aspects, the fuel segment can have a convex shape, as shown in
Referring to
In a preferred loading style, the major axis of the segment 114 will align with and be co-axial to the longitudinal axis 40 of cladding 12 and the minor axis will be in alignment with a co-axial to the transverse axis 44 of the cladding. Some deviation from the preferred alignment can be tolerated, as long as the end gaps 34 allow swelling of the segment 114 without increasing the strain on the cladding 12, as described above.
The fuel segment 114 is sized relative to the cladding 12 so that there is a small gap 32 between the elongated walls 18 of the cladding and the widest areas (referred to as the co-vertexes of the ellipse, along the minor axis) of the longer, convexly curved elongated surfaces 120 of fuel segment 114 allowing just enough space at the widest areas of the pellet for the segments 114 to be loaded and stacked in the cladding 12 without applying contact pressure against the interior surface 28 of the cladding 12 during loading. Because of the elliptical shape, the gap 32 widens into a gap 36 as the segment 114 curves from each co-vertex toward the ends, or vertexes 122. The fuel segment 114 is sized relative to the cladding 12 so that there is a larger gap 34 relative to the small gap 32 at each end of the cladding 12 between the end walls 16 of the cladding 12 and the end curves, or vertexes 122 of the segment 114. This shape will encourage the lateral expansion of the fuel 114 toward the end gaps 34 and maximizes fuel loading. Since there is no fuel at the end gaps 34, the SiC cladding 12 at the end walls 16 can be thickened and strengthened without impacting heat transfer and fuel temperature.
The second distance which defines gap 34 between the fuel end surfaces 22/122 and the cladding end walls 16 in the initial configuration, before any swelling, is dimensioned to allow for the maximum swelling of the selected fuel plus space for fission gases produced in use. Those skilled in the art can calculate by known means or determine by historical use, the maximum amount of swelling the selected fuel will undergo in use and the amount of fission gas that would be produced in use to determine the second distance. Gap 34 is sized to allow fission gases to accumulate at a pressure less than the design pressure of the reactor (for instance 2200 psia at 320° C. for a traditional PWR).
The first distance defines gap 32 between the elongated walls 18 of the cladding 12 and the elongated surfaces 20/120 of the fuel in the initial configuration, before any swelling. The first distance gap 32 is sufficient to allow the fuel to be inserted into the cladding prior to use, typically about 0.07 mm.
Since the SiC cladding 12 will bulge outwardly after short irradiation times, in various aspects, the cladding elongated walls 18 can be pre-curved inward, in a concave shape, toward the fuel segment, to accommodate displacement during irradiation and mitigate local stress build up. This occurs because the initial expansion of the fuel segment puts compressive rather than tensional forces on the cladding. The concave curve as the initial configuration will mitigate the stress build up from the SiC swelling gradient. In addition, or alternatively, the fuel can be concavely shaped to minimize stress in the direction of the minor axis 44.
Referring to
Like fuel elements 10 and 100, a smaller gap 232 is provided between elongated walls 218 of the cladding and elongated surfaces 220 of the fuel segment in the initial configuration. Upon swelling, the gap 232 closes at a contact area 230 between the walls 218′ and the surfaces 220′ along the transverse axis 44 as the fuel element elongated concave surfaces 220 expand in the Y direction to elongated convex surfaces 220′. In the initial configuration, a larger gap 234 is provided between each end wall 16 of the cladding 214 and the facing end surface 222 of the fuel segment 214. Upon swelling, the larger end gaps 234 on each end close to a smaller, but still present gap 234′, as the fuel element 214 expands along the longitudinal axis 40, in the X direction. The center of the cladding walls 218 can withstand a large displacement in the Y direction along axis 44 due to the width (in the direction from axis 44 to end walls 16) of the fuel segment 214. This shape will encourage the lateral expansion of the fuel 214 toward the end gaps 234 and maximize fuel loading. Since there is no fuel at the end gaps 234, the SiC cladding 212 at the end walls 16 can be thickened and strengthened without impacting heat transfer and fuel temperature.
The SiC cladding may preferably be made of a material such as a SiC monolith, SiC fibers, or a combination of the two, as taught in U.S. Pat. Nos. 6,246,740; 5,391,428; 5,338,576; and 5,182,077, and U.S. Patent Application Publications 2006/0039524, 2007/0189952; and 2015/0078505, the relevant portions of which are incorporated herein by reference. In various aspects, the ceramic yarn is formed from SiC fibers. The SiC fiber may preferably be a SiC fiber containing primarily Si and C, and some trace or relatively small amounts of O. Exemplary amounts may include
The SiC fiber cladding would utilize SiC in the form of fiber tows with between 500 to 5000 fibers per tow and a thickness between 100 and 600 microns.
The fuel used in the fuel elements 10, 100 or 200 may be selected from known fissile materials for use in commercial nuclear reactors for energy production, such as, but not limited to, UO2, U3Si2, UN, and uranium alloys and other oxide fuels. The fuel element design described herein, while able to accommodate any suitable known fuel, is particularly useful with UO2, which had heretofore been unsuitable for use with SiC claddings.
As shown in
As indicated above, silicon carbide is a very promising accident tolerant fuel cladding, but there were challenges in implementing SiC in traditional rod type fuels that the fuel element configurations described herein overcome. To prevent excess strain on the cylindrical rod type cladding, there is a uniform annular gap between the cylindrical rod cladding and the cylindrical fuel pellets which must be large enough to accommodate the fuel swelling in the radial direction after some time in the reactor, typically greater than 6 months. When the SiC cladding swells at the beginning of the fuel life cycle, it further expands the cladding, increasing the initial annular gap. At the beginning of the life cycle, the fuel shrinks. Because the fissile content is at its highest at the beginning of life, the fuel pellet generates the most heat at this time and combined with the initially shrinking pellet and swelling cladding, the widening initial gap presents a danger that the fuel pellet centerline temperature will exceed its melting point early in life. As the fuel cycle progresses, the pellet stops shrinking and begins to expand due to the buildup of fission products which are less dense than the original uranium fuel. Since the cladding swelling stops early in the cycle, the expanding pellet then has the possibility of contacting and breaking the SiC cladding. Because fuels such as UO2 do not have a very good thermal conductivity, the wider gap negatively effects energy production by requiring the reactor to be run at low powers.
In the embodiments shown herein, the fuel-cladding gap is minimized, which minimizes the centerline temperature rise during transients and reduces the stored energy in the fuel. In addition, the fuel elements 10, 100, and 200 described herein provide a mechanism for the cladding 12 to accommodate fuel thermal expansion and swelling without suffering mechanical failure due to the force and resulting high strain that would otherwise be exerted against the cladding in prior rod type configurations.
The elongate shaped fuel 14, 114, and 214 with gaps 34 and 234 and elongate SiC cladding 12 described herein can accommodate contact between the swollen fuel and the cladding elongated walls 18 because the cladding 12 has the freedom to move laterally (in the direction of the axis 44 in the Y direction) and can tolerate strain to a greater extent from the fuel 14/114/214 due to the large expanse over the width (the distance from axis 44 to each end walls 16) of the elongate cladding. The elongated fuel design described herein also provides more expansion (in the direction of axis 40 in the X direction) for the fuel segments 14/114/214 within the longer walls 18 of cladding 12 under contact (depending on the length of the end gap 34 on the two end walls 16). The various embodiments of the fuel element 10, 100, 200 shown in
In summary, the fuel elements 10, 100, and 200 provide the following benefits:
The fuel elements 10, 100, and 200 described herein can utilize SiC cladding with UO2 fuel with minimal initial gaps between the cladding and the fuel. The gaps 34/234 on the ends of the fuel elements 10/100/200 provide volume for fission gas and expansion of the fuel segments 14/114/214 along the major axis 40 which will reduce the stress on the cladding 12 compared to a rod design when the fuel segments 14/114/214 and cladding 12 are in contact. In certain aspects, the elongated side walls 18 of the SiC cladding can be pre-curved to mitigate the stress build up from SiC swelling gradient and/or the fuel can be convexly or concavely shaped to minimize stress in the direction of the minor axis 44.
The fuel elements 10, 100, and 200 described herein can significantly reduce the stress build up in SiC cladding and mitigate SiC mechanical failure from fuel-cladding mechanical interaction. The fuel elements 10, 100, and 200 enable the compatibility of SiC cladding with UO2 in light water reactors and also work with other high thermal conductivity fuels, such as U3Si2, UN, and uranium alloys.
The present invention has been described in accordance with several examples, which are intended to be illustrative in all aspects rather than restrictive. Thus, the present invention is capable of many variations in detailed implementation, which may be derived from the description contained herein by a person of ordinary skill in the art.
All patents, patent applications, publications, or other disclosure material mentioned herein, are hereby incorporated by reference in their entirety as if each individual reference was expressly incorporated by reference respectively. All references, and any material, or portion thereof, that are said to be incorporated by reference herein are incorporated herein only to the extent that the incorporated material does not conflict with existing definitions, statements, or other disclosure material set forth in this disclosure. As such, and to the extent necessary, the disclosure as set forth herein supersedes any conflicting material incorporated herein by reference and the disclosure expressly set forth in the present application controls.
The present invention has been described with reference to various exemplary and illustrative embodiments. The embodiments described herein are understood as providing illustrative features of varying detail of various embodiments of the disclosed invention; and therefore, unless otherwise specified, it is to be understood that, to the extent possible, one or more features, elements, components, constituents, ingredients, structures, modules, and/or aspects of the disclosed embodiments may be combined, separated, interchanged, and/or rearranged with or relative to one or more other features, elements, components, constituents, ingredients, structures, modules, and/or aspects of the disclosed embodiments without departing from the scope of the disclosed invention. Accordingly, it will be recognized by persons having ordinary skill in the art that various substitutions, modifications or combinations of any of the exemplary embodiments may be made without departing from the scope of the invention. In addition, persons skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, many equivalents to the various embodiments of the invention described herein upon review of this specification. Thus, the invention is not limited by the description of the various embodiments, but rather by the claims.
This invention was made with government support under Contract No. DE-NE0008824 awarded by the Department of Energy. The U.S. Government has certain rights in this invention.
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