Information
-
Patent Grant
-
6519781
-
Patent Number
6,519,781
-
Date Filed
Friday, September 7, 200123 years ago
-
Date Issued
Tuesday, February 18, 200321 years ago
-
Inventors
-
Original Assignees
-
Examiners
- Calvert; John J.
- Patel; Tajash
Agents
-
CPC
-
US Classifications
Field of Search
US
- 002 267
- 002 455
- 002 16
- 002 25
- 002 59
- 002 459
- 002 92
- 002 456
- 002 108
- 002 69
- 002 85
- 002 62
- 002 1611
- 002 465
- 602 6
- 602 12
- 602 20
- 602 23
- 602 26
- 428 67
-
International Classifications
-
Abstract
An energy absorbing, articulated, protective pad with improved articulation for protection of areas of articulation, such as joints of a human body. A pad of energy absorbing material has score lines along a first axis and a second axis. The score lines are cut into said pad to provide articulation of the pad. The pad also has cuts along the second axis at the periphery of the pad that provide flexibility to the pad.
Description
FIELD OF THE INVENTION
This invention relates to devices that absorb the energy of an impact. More particularly, this invention relates to devices used to provide protection to joints and other areas of articulation. Still more particularly, this invention relates to devices that provide protection to joints and other areas of articulation and allow air and moisture to pass through the protection to provide breathable protection to a user that allows evacuation of perspiration.
STATEMENT OF THE PROBLEM
Many sports and occupations require safety equipment such as padding that protects the users from impacts that occur. Some non-limitative examples of sports where padding is needed include bicycling, football, hockey, in-line skating, skiing and snowboarding. A non-limitative example of an occupation that requires safety equipment is construction. Designers of such safety equipment face a number of obstacles.
One area of particular concern to designers of safety equipment is padding. Of particular concern to the designers is padding for areas of articulation. An area of articulation is a joint or other area in which at least two adjacent body parts move in different directions during an activity. For example, one common joint to protect is the knee which must bend when a user is in-line skating, running, or walking. Users prefer padding that allows a full range of motion with minimal discomfort. Users also prefer padding that allows for the evacuation of perspiration, which is known as breathing in the art. Other concerns include that the padding is washable, lightweight and durable.
Prior art padding designs do not adequately meet these needs. One type of pad, such as the pad disclosed in U.S. Pat. No. 6,029,273 issued to McCrane, has a hard outer casing. This type of pad does not allow perspiration to escape. Therefore, this type of pad is not ideal for use in clothing. Further, this type of pad restricts movement, as the outer casing is rigid and inflexible. To allow articulation, some pads with rigid casings do provide articulated plates. Articulated cases include a plurality of plates fitted together that allow the plates to move with respect to one another in order to facilitate movement. These casings may solve the mobility problem. However, the casings with articulated plates still do not allow perspiration to escape, are heavy, bulky, and are still too rigid to insert into clothing. Furthermore, the cost of making the articulated plates is expensive and time consuming.
A second type of casing includes flexible, outer casings of porous, breathable inelastic material overfilled with resilient discrete beads of elastic material. An example of this type of pad is disclosed in U.S. Pat. No. 5,920,915 issued to Bainbridge et al. This material, while breathable, still impedes movement because the overfilled pads are semi-rigid. Therefore, this type is unacceptable for padding an articulated area.
A third type of pad is a foam pad that has score lines cut into the pad to facilitate movement. An example of this type of pad is disclosed in U.S. Pat. No. 6,093,468 issued to Tums et al. Score lines are indentations cut into the material. The cuts allow the foam of the pad to flex to allow the pad to flex. The foam material is breathable and allows perspiration to escape. The score lines improve the flexibility of a pad. However, the range of motion is still impeded as the score lines do not allow the pad to twist or form completely to an area due to the excess material.
It is, therefore, the desire of those skilled in the art to provide a pad that allows perspiration to escape and has a desired flexibility.
STATEMENT OF THE SOLUTION
The above and other problems are solved and an advance in the art is made by a protective pad made in accordance with this invention. A first advantage of a protective pad made in accordance with this invention is that the pad is breathable, meaning that perspiration is allowed to escape. Furthermore, the pad is washable as part of a garment. A second advantage of this invention is that the pad is flexible and may move with an area of articulation to allow a user a full range of motion with minimal discomfort.
In accordance with this invention, an energy absorbing protective pad has a pad of energy absorbing material. The pad has score lines along a first axis and a second axis. The score lines are cut into the pad to provide articulation. Along the second axis, the pad has cuts at the periphery of the pad. The cuts provide flexibility to the pad.
The energy absorbing material may be a foam or any other semi-rigid material. The foam may be single layered or multi-layered. Preferably, the energy absorbing material is a bi-density foam. The bi-density foam has a first layer on a bottom side of the pad having a first density and a second layer on a top side of the pad having a second density that is a higher density than the first density. The score lines are cut through the second layer of foam and through a substantial portion of the first layer. Preferably, the score lines are cut through three-quarters of the pad. However, the score lines may also be cut to any other depth including, but not limited to, one-half and one-quarter through the pad.
The inner side of the pad may be affixed to a piece of stretch or non-stretch fabric. The pad may be sewn or glued to the fabric. A piece of outer fabric may be affixed to the piece of stretch fabric around a perimeter of the pad to enclose the pad. The pad is not affixed to the outer fabric to add flexibility. When the pad is affixed to the stretch fabric, the score lines may completely sever the pad into a plurality of individual members.
The score lines may be cut into the pad in the following manner. A first plurality of score lines are cut into the pad substantially along a first axis. The first axis is substantially longitudinal with reference to the area of articulation being protected. For example, in a knee pad, the first axis would be substantially parallel to the leg. A second plurality of score lines are cut substantially along a second axis. The second axis is substantially perpendicular to the first axis. The first and second plurality of score lines define a plurality of polygons on the pad. The polygons are preferably narrower along the first axis than the second axis to promote flexibility along the first axis.
In a preferred embodiment, the cuts along the periphery of pad along second axis promote flexibility. The Cuts completely sever members at the periphery of the pad along the second axis to allow flexing of the pad. Polygons defined by cuts have reduced dimensions in the direction of the first axis to further promote flexibility and shaping of the pad to the member protected by the pad. The cuts also eliminate excess material in the direction of the first axis. The excess material is removed because this excess material impedes flexing of the pad in the direction of the first axis.
The pad may be molded to have a curvature traversing the second axis. A concave side of the pad is fitted to the area of articulation being protected. In a preferred embodiment, the energy absorbing material of the pad is heat moldable and heat is applied to the pad to form the curvature.
The protective pad may then be inserted in pockets or enclosures in a garment to form any number of pads. For example, a protective pad in accordance with this invention may be incorporated into a knee pad, a hip pad, a shoulder pad, or an elbow pad.
BRIEF DESCRIPTION OF THE DRAWINGS
The above and other advantages and features of this invention are set forth in the detailed description below and the following drawings:
FIG. 1
illustrating an energy absorbing pad in accordance with the invention;
FIG. 2
illustrating a front view of an energy absorbing pad in accordance with the invention;
FIG. 3
illustrating a cross sectional side view of an energy absorbing pad affixed to fabric in accordance with the invention;
FIG. 4
illustrating a top side view of a curved pad in accordance with the invention;
FIG. 5
illustrating a bottom side view of a curved pad in accordance with the invention;
FIG. 6
illustrating an exploded view of a jacket incorporating energy absorbing pads in accordance with the invention;
FIG. 7
illustrating a pair of pants incorporating energy absorbing pads in accordance with the invention;
FIG. 8
illustrating a knee pad incorporating energy absorbing pads in accordance with the invention;
FIG. 9
illustrating a cross section of a foam pad in accordance with the invention;
FIG. 10
illustrating a pad in accordance with this invention attached to a stretch fabric; and
FIG. 11
illustrating a cross sectional view of a member of a pad attached to a stretch fabric.
DETAILED DESCRIPTION
FIG. 1
illustrates a preferred embodiment of energy absorbing protective pad in accordance with the invention. Pad
100
is made of energy absorbing material. The energy absorbing material may be, but not limited to, a single density or multi-density foam. In a preferred embodiment, the energy absorbing material is a bi-density foam. An example of such a foam is described in WO Document No. 00/16652 by Brock, which is incorporated by reference as if set forth herein.
FIG. 2
illustrates a cross section of a side view of pad
100
made of a bi-density foam. As can be seen in
FIG. 2
, pad
100
has a top side or outer layer
201
of high density foam. A second bottom side or inner layer
202
of foam is made of a lower density foam. Bi-density foam is preferred because the foam is breathable, elastic, and provides a softer surface close to the area to be protected and a harder surface on the side exposed to the source of trauma.
FIG. 9
illustrates a cross sectional view of a piece of foam
900
that may be used in pad
100
. The foam
900
is made of discrete beads
900
that are affixed to one at points
906
. One skilled in the art will recognize that the beads may be melted together, glued together, or in some other way connected. The beads may be compressed to form a higher density foam. At the edges and on the surface of sides beads
903
are cut to provide a smooth surface.
Referring back to
FIG. 1
, pad
100
has a first, longitudinal axis
110
that is substantially longitudinal to an area of articulation being protected. For purposes of this discussion, an area of articulation is a joint or other area of a body in which at least two adjacent body parts move in different directions during an activity. Some examples of areas of articulation include, but are not limited to, knees, elbows, shoulders, and hips. For discussion purposes, the longitudinal axis is the line which essentially bisects the body parts that articulate. For example, a longitudinal axis of a knee is the line that bisects the two positions of the leg which are joined at the knee.
A second axis
120
traverses the area of articulation and intersects first axis
110
. Preferably, second axis
120
of pad
100
is substantially perpendicular to the first axis
110
and traverses the area of articulation. Typically, second axis
120
is the shorter width of the pad.
Score lines
101
are articulation lines cut substantially along the first axis. Score lines
102
are articulation lines cut substantially along the second axis. Score lines
101
and
102
allow the pad to bend and flex to match the area of articulation protected. In the preferred embodiment, score lines
101
and
102
are cut to three-quarters (¾) the depth of the pad. Those skilled in the art will recognize that score lines may be cut to other depths including, but not limited to, one-half and one-quarter of the thickness of pad
100
. Those skilled in the art will also recognize that score lines may be cut along any other axis in any other direction according to need.
Score lines
101
and
102
define individual members
105
of pad
100
. Individual members
105
are in the form of polygons. In the preferred embodiment, the polygons are hexagonal to provide enhanced flexibility. Pentagonal polygons have also been found to have flexibility advantages. However, one skilled in the art will recognize that the polygons may be in any shape desired. Also, to promote flexibility of the joint, individual members
105
are preferably reduced in dimension along the first axis
110
than across the second axis
120
. That is, because the individual members are narrower in a direction along the first axis than along the second axis, there are more score lines per unit length along the first axis, increasing flexibility.
To provide better flexibility, pad
100
also has cuts
103
along the periphery of pad
100
along second axis
120
. Cuts
103
completely sever members
105
at the periphery of pad
101
along second axis
120
to allow flexing in pad
101
. Polygons defined by cuts
103
have reduced dimensions in the direction of first axis
110
to further promote flexibility and shaping of pad
100
to the member protected by pad
100
. Cuts
103
also eliminate excess material in the direction of first axis
110
. The excess material is removed because this excess material impedes flexing of pad
100
in the direction of first axis
110
.
Referring back to
FIG. 2
, individual members, such as
209
, are preferably tapered in a direction from the bottom side toward the top, such as at
210
. Individual members also have rounded edges, such as at
211
and
212
. Preferably, the top layer
201
of all elements is tapered and rounded at all edges that are not connected to another element, such as at
214
. The tapering and rounding increases flexibility, facilitates smooth interfacing of elements as they may contact during flexing, makes entry of a pad into a pocket easier, and gives a smooth, finished appearance to the pad.
Sometimes pad
101
is affixed to a fabric for fitting into a garment.
FIG. 3
illustrates a cross section of pad
100
along first axis
110
to show pad
100
affixed to a fabric. Pad
100
is affixed to a piece of stretch fabric
304
. Preferably, pad
100
is glued or laminated to fabric piece
304
, although pad
100
may be affixed to fabric piece
304
in other manners, such as sewing the pad to fabric piece
304
. Fabric piece
304
is made of a lycra polyester blend or other stretch material that is lightweight, breathable, and flexible. A material such as Gore-Tex may also be used, although Gore-Tex is normally not stretchable. When pad
100
is affixed to fabric piece
304
, score lines
101
and
102
may be cut completely through the pad to completely sever members
105
to maximize flexibility.
FIG. 10
illustrates an example of members
105
being severed. In
FIG. 10
, a piece of stretch fabric
1001
has a plurality of members
1002
affixed to piece
1001
via glue
1009
. Gaps
1004
between members
1002
allow piece of fabric
1001
to be flex freely. This allows the fabric to conform to an underlying body easily.
FIG. 11
is a cross sectional view of a member
1002
. Member
1002
has a top layer
1006
of high density foam. Bottom layer
1008
is a low density foam affixed to the top layer
1006
. Epoxy
1009
is then applied to a bottom side of bottom layer
1008
to affix member
102
to fabric
1001
.
A second piece of fabric
302
may then cover pad
100
and be affixed to fabric piece
304
at points
306
,
307
around the perimeter of pad
100
. The second piece of fabric
302
is affixed by glue, stitches, or in some other manner. Preferably, the second piece of fabric
302
is not affixed to a top side
305
of pad
100
. Instead, a gap
310
is formed between pad
100
and the second piece of fabric
302
. This promotes flexibility and breathability of pad
100
. In a preferred embodiment, the construction shown in
FIG. 3
is used for removable protective devices such as the devices shown in FIG.
6
and described below.
In a preferred embodiment, pad
100
is curved to better enclose an area of articulation being protected.
FIGS. 4 and 5
illustrate a curved pad
100
. As can be seen from
FIG. 4
, in the preferred embodiment pad
100
has a curvature
400
along the second axis
120
. The curvature is formed by heat molding pad
100
in the preferred embodiment. To heat mold pad
100
, the energy absorbing material must be heat moldable such as the bi-density foam described above. The pad
100
also may be curved along the first axis
110
, though usually, if there is such curvature, it is less than along the second axis.
FIG. 5
shows concave area
500
of an inner side of pad
100
. Concave area
500
is curved to fit the area of articulation being protected into the concave area and more completely protect the area of articulation. One skilled in the art will recognize that the exact amount of curvature of pad
100
will depend on the area of articulation being protected and the amount of the area desired to be protected.
FIG. 6
illustrates one type of garment that may benefit from a protective pad in accordance with the invention. Jacket
600
is a jacket worn for such activities as skiing and snowboarding. Jacket
600
includes shoulder pad
610
, tricep pad
620
, elbow pad
630
and forearm pad
640
. Shoulder pad
610
and elbow pad
630
are substantially triangular shaped pads as the pad
100
shown in FIG.
1
and incorporate the invention. Tricep pad
620
and forearm pad
640
are smaller pads that protect areas that do not articulate and may or may not incorporate the invention.
An inner side of shoulder pad
610
is affixed to fabric
613
and a second piece of fabric
612
is then affixed to fabric
613
proximate the perimeter of fabric
613
to enclose shoulder pad
610
and to form enclosed shoulder pad
615
. This process is shown in FIG.
3
and described above. Enclosed shoulder pad
615
fits into pocket
611
on the shoulder of jacket
600
. One skilled in the art will recognize that pocket
611
may be sewn or glued shut or have a zipper that allows removal of shoulder pad
610
.
An inner side of tricep pad
620
is affixed to fabric
623
. A second piece of fabric
622
is then affixed to fabric
613
proximate the perimeter of fabric
613
to enclose tricep pad
620
and form enclosed tricep pad
625
. This shown in FIG.
3
and discussed above. Enclosed tricep pad
625
fits into pocket
621
on an upper back side of a sleeve of jacket
600
. Pocket
621
may be sewn or glued shut or have a zipper allowing access to remove tricep pad
620
.
An inner side of elbow pad
630
is affixed to piece of fabric
633
. A second piece of fabric
632
is affixed to fabric
633
proximate the perimeter of fabric
633
to enclose elbow pad
630
and to form enclosed elbow pad
635
. This process is shown in FIG.
3
and described above. Enclosed elbow pad
635
fits into pocket
631
in an elbow of the sleeve of jacket
600
. Pocket
631
may be sewn or glued shut or have a zipper allowing access to remove elbow pad
630
.
An inner side of forearm pad
640
is affixed to piece of fabric
643
. A second piece of fabric is then affixed to fabric
643
proximate the perimeter of fabric
643
to enclose forearm pad
640
and to form enclosed forearm pad
645
. Enclosed forearm pad
645
fits into pocket
641
on a lower end of the sleeve of jacket
600
. Pocket
641
may be sewn or glued shut or have a zipper or other fixture allowing access to remove forearm pad
640
.
FIG. 7
illustrates a pair of pants
700
that incorporates protective pads in accordance with the invention. Pants
700
includes pockets
710
which receive pads
100
to provide hip protection. Pads
100
that fit into pockets
710
are preferably shaped much like pad
100
shown in FIG.
1
. Pockets may have a zipper or other fastener to allow the pads to be removed. Pants
700
also may include pockets
720
that receive pads to protect a knee. As stated above, pockets
720
may have a fastener to allow removal of the pads or may be sewn or glued shut.
FIG. 8
illustrates a configuration of a knee pad in accordance with the invention. A knee pad is made of two protective pads
810
and
820
having score and cut lines in accordance with the invention. Pad
810
protects a top or upper part of a knee and has a substantially triangular end
811
the fits over a knee cap. Pad
820
protects a lower part of the knee and has an upper end
821
that is shaped to mate with part
811
of pad
810
when a knee is straight. When a knee is bent, pads
810
and
820
separate to maximize bending of the knee. Pads
810
and
820
then are fitted into pocket
720
as shown in FIG.
7
.
The above description is of a protective pad in accordance with the invention. It is expected that those skilled in the art can and will design alternative pads that infringe on the invention as set forth in the claims below either literally or through the Doctrine of Equivalents.
Claims
- 1. An energy absorbing, articulated, protective pad comprising:a pad of energy absorbing material; score lines along a first axis and about a second axis wherein said score lines are cut into said pad to provide articulation of said pad; and cuts through said pad about said second axis at a periphery of said pad that provide flexibility to said pad wherein the cuts about the second axis are in two directions.
- 2. The energy absorbing protective pad of claim 1 wherein said energy absorbing material is a single density foam.
- 3. The energy absorbing protective pad of claim 1 wherein said energy absorbing material is a multi-density foam.
- 4. The energy absorbing protective pad of claim 3 wherein said multi-density foam comprises:a first layer on an outer side of said pad having a first density; and a second layer on an inner side of said pad having a second density that is a higher density than said first density.
- 5. The energy absorbing protective pad of claim 1, further comprising a piece of stretch fabric affixed to an inner side of said pad.
- 6. The energy absorbing protective pad of claim 5, further comprising a piece of outer fabric affixed to said piece of stretch fabric around a perimeter of said pad to enclose said pad.
- 7. The energy absorbing protective pad of claim 5 wherein said score lines sever said pad into a plurality of individual members.
- 8. The energy absorbing protective pad of claim 1 wherein said score lines comprise:a first plurality of score lines substantially along a first axis that is longitudinal to an area of articulation; and a second plurality of score lines substantially along a second axis that is substantially perpendicular to said first axis.
- 9. The energy absorbing protective pad of claim 8 wherein said first and second pluralities of score lines are cut at least one-quarter of a way through said pad.
- 10. The energy absorbing pad of claim 8 wherein said first and said second pluralities of score lines are cut at least one-half of a way though said pad.
- 11. The energy absorbing pad of claim 8, further comprising a plurality of polygons in said pad defined by said first and said second plurality of score lines.
- 12. The energy absorbing protective pad of claim 11 wherein each of said plurality of polygons is narrower along said first axis than along said second axis.
- 13. The energy absorbing protective pad of claim 11 wherein said polygons are selected from the group consisting of hexagons and pentagons.
- 14. The energy absorbing protective pad of claim 8 wherein said pad further comprises a curvature of said pad traversing said second axis wherein a concave side of said pad is fitted to a body part to be protected.
- 15. The energy absorbing protective pad of claim 14 wherein said energy absorbing material of said pad is heat moldable and heat is applied to form said curvature.
- 16. The energy absorbing protective pad of claim 15, further comprising a pocket in a garment that receives said pad.
- 17. The energy absorbing protective pad of claim 16 wherein said protective pad is a knee pad.
- 18. The energy absorbing protective pad of claim 16 wherein said protective pad is an elbow pad.
- 19. The energy absorbing protective pad of claim 16 wherein said protective pad is a hip pad.
- 20. The energy absorbing protective pad of claim 16 wherein said protective pad is a shoulder pad.
- 21. The energy absorbing pad of claim 1 wherein said cuts eliminate excess material that impedes flexing at said plurality of score lines.
- 22. A method for providing an energy absorbing, articulated, protective pad comprising the steps of:defining score lines along a first axis and about a second axis of a pad of energy absorbing material wherein said score lines provide articulation of said pad; and cutting through said pad about said second axis in two directions at a periphery of said pad to provide flexibility to said pad.
- 23. The method of claim 22 wherein said energy absorbing material is a single density foam.
- 24. The method of claim 22 wherein said absorbing material is a multi-density foam.
- 25. The method of claim 24 wherein said multi-density foam has a first layer on a outer side of said pad having a first density and a second layer on an inner side of said pad having a second density that is a higher density than said first density.
- 26. The method of claim 22, further comprising the step of affixing a piece of stretch fabric to an inner side of said pad.
- 27. The method of claim 26, further comprising the step of affixing a piece of outer fabric to said piece of stretch fabric around a perimeter of said pad to enclose said pad.
- 28. The method of claim 27, further comprising the step of severing said pad into a plurality of individual members affixed to said stretch fabric with said score lines.
- 29. The method of claim 22 wherein said step of defining said score lines comprises the steps of:cutting a first plurality of score lines substantially along a first axis that is longitudinal to an area of articulation; and cutting a second plurality of score lines substantially along a second axis that is substantially perpendicular to said first axis.
- 30. The method of claim 29 wherein said first and second pluralities of score lines are cut at least one-quarter of a way through said pad.
- 31. The method of claim 29 wherein said first and said second pluralities of score lines are cut at least one-half of a way though said pad.
- 32. The method of claim 29 further comprising the step of defining a plurality of polygons in said pad defined by said first and said second plurality of score lines.
- 33. The method of claim 32 wherein said step of defining comprises defining polygons selected from the group consisting of hexagons and pentagons.
- 34. The method of claim 33 wherein each of said plurality of polygons is narrower along said first axis than along said second axis.
- 35. The method of claim 22, further comprising the step of forming a curvature of said pad traversing said second axis wherein a concave side of said pad is fitted to a body part to be protected.
- 36. The method of claim 35 wherein said energy absorbing material of said pad is heat moldable and said method further comprises the step of applying heat to said pad to form said curvature.
- 37. The method of claim 22, further comprising the step of inserting said pad into a pocket in a garment that receives said pad.
- 38. The method of claim 37 wherein said protective pad is a knee pad.
- 39. The method of claim 37 wherein said protective pad is an elbow pad.
- 40. The method of claim 37 wherein said protective pad is a hip pad.
- 41. The method of claim 36 wherein said protective pad is a shoulder pad.
- 42. The method of claim 22 further comprising the step of:Removing excess material between said cuts to promote flexibility along said plurality of score lines.
- 43. An energy absorbing, articulated protective pad comprising:a pad of energy absorbing material; and score lines along a first axis and about a second axis wherein said score lines are cut into said pad to provide articulation of said pad, said score lines defining a plurality of polygons having a first dimension along a first axis and a second dimension along a second axis, said first dimension being smaller than said second dimension.
- 44. An energy absorbing protective pad as in claim 43 wherein said polygons are selected from the group consisting of hexagons and pentagons.
- 45. An energy absorbing, articulated, protective pad comprising:a plurality of discrete beads of substantially elastic and resilient material, said beads being integrally joined to each other to form a pad; and score lines along a first axis and about a second axis in two directions wherein said score lines are cut into said pad to provide articulation of said pad.
- 46. An articulated pad as in claim 45 wherein said score lines comprise:a first plurality of score lines substantially along said first axis that is longitudinal to an area of articulation; and a second plurality of score lines substantially about said second axis that is substantially perpendicular to said first axis.
- 47. The energy absorbing pad of claim 46 further comprising a plurality of polygons in said pad defined by said first and said second plurality of score lines.
- 48. The energy absorbing protective pad of claim 46 wherein each of said plurality of polygons is narrower along said first axis than about said second axis.
- 49. The energy absorbing protective pad of claim 46 wherein said polygons are selected from the group consisting of hexagons and pentagons.
US Referenced Citations (11)
Foreign Referenced Citations (3)
Number |
Date |
Country |
0 880 908 |
Dec 1998 |
EP |
WO0016652 |
Mar 2000 |
WO |
WO0069293 |
Nov 2000 |
WO |