Patent Application
20120064589
The present invention relates to the design of energy photoconverters acting in a continuous and closed manner for producing biofuels and other products of interest by means of the mass culturing of phytoplankton.
The invention is comprised within the technical field of the exploitation of renewable energy by means of the action of phytoplankton organisms that normally belong to the following taxonomic families: Chlorophyceae, Bacillariophyceae, Dinophyceae, Cryptophyceae, Chrysophyceae, Haptophyceae, Prasinophyceae, aphidophyceae . . . generally the taxonomic families comprising species of the chromophyte division, all of them characterized by being flagellated or nonflagellated single-celled organisms and with a strictly planktonic (holoplanktonic) life phase, or at least one of its phases being planktonic (meroplanktonic).
Particularly by means of the use of energy converters, products such as biofuels, byproducts such as naphthas, kerosene, thermal energy, electric energy, . . . are obtained.
Up until now, biofuels have been obtained from higher plant cultures, usually from the group of phanerogams or flowering plants (sunflowers, palm, European palm, . . . ), and usually on the terrestrial surface (land plants).
The obligation for the economic zones to comply with the objectives imposed by the Kyoto protocol on the reduction of CO2/SO2 emissions and the emission of other gases causing the so-called greenhouse effect is forcing countries to search for alternative and renewable fuels to prevent possible penal taxes.
Although the production of solar and wind energy is increasing in some regions, these technologies are very expensive and are not viable in all climatic areas. In these conditions, biofuels have an important role as substitutes of fossil fuels, especially in transport and heating applications.
The production costs of biofuels from plants, such as palm and rapeseed oil have always been a reason for concern. Taking into account the low oil production indexes per hectare, enormous amounts of resources would be needed to reach commercial production. Land and water are two limited resources and it is preferable to use them to produce food products, which are furthermore more profitable for farmers. Intensive fertilization is furthermore a form of land and water pollution of the first order. Extensive single crop farming is also one of the main enemies of biodiversity.
Phytoplankton represents a viable solution to the previously discussed drawback given that about 50% of the dry mass of single-celled organisms is generally biofuel. In addition, the annual production per hectare of biofuel from phytoplankton is 40 times higher than with the second most cost-effective product, palm oil. A drawback is that the production of phytoplankton oil requires covering vast stretches of land with rather shallow water, as well as introducing large amounts of CO2, an essential element for phytoplankton to produce oil. Natural production systems such as phytoplankton ponds, have a relatively low cost but the harvesting process is very laborious and, therefore expensive. On the other hand, phytoplankton culturing is carried out in open systems, making it vulnerable to contamination and to problems for cultures, which may lead to total production loss. In this same sense, an advantage of the photoconverter described in the present invention is that the system is kept closed and in conditions such that the culture is not contaminated by bacteria, fungi, . . . because in addition to being closed, the culture is enriched by means of nutrients incorporating fungicides and antibiotics.
Within the field of the design of photoconverters for producing biofuels through photosynthetic microorganisms, two types of photoconverters could be clearly differentiated: open photoconverters, in which a direct exchange of matter between the culture and the air surrounding it is allowed, and closed photoconverters, in which this exchange is eliminated by means of the placement of a transparent physical medium allowing the passage of electromagnetic radiation but not the exchange of matter. The open photoconverters have many problems derived from the little control of the culturing conditions and possible contaminations, so their application is limited due to these drawbacks. However, closed photoconverters efficiently reduce these problems by means of greater control of the culturing conditions and possible contaminations and can reach a production rate that is 400 times higher than the production rate of sunflower.
Until now no systems similar to the photoconverter object of the present invention have been described which incorporate the advantages of being a closed system with a large volume and large diameters, which works continuously, which allows obtaining large amounts of biofuels or byproducts such as naphthas, glycerin, silicon-derived compounds, such as ferrosilicates, which may further obtain thermal and electric energy that does not contaminate given that all the possible residues, such as carbon dioxide, are recirculated in the system to be used as a nutrient for the phytoplankton, or which recirculates the water used as part of the culture medium so it can be reused . . . . The present invention therefore describes a novel system (photoconverter) including all these features which allows enormous versatility and is very environmental friendly.
Patent application WO 03/094598 A1 entitled “Photobioreactor and process for biomass production and mitigation of pollutants in flue gases” describes a generic photobioreactor model mainly focused on decontaminating COx, SOx and NOx type gases. It is basically a system working in a discontinuous manner (distinguishing between day/night photoperiod) and is open, its liquid medium not being axenic. It does not control nitrogen and carbon dioxide concentrations for the purpose of increasing biofuel production. It is not designed to work with monospecific or monoclonal algae strains. Its design does not contemplate biofuel production as the main objective, rather it is focused on gas purification. On the other hand, as regards the photosynthetic organisms it refers to, it does not demand conditions disabling the system and it has no controlled recirculation because the transport is done by a turbulent flow of bubbles.
Compared to the present invention object of the patent, a completely novel system is set forth which is based, in contrast, on the following features:
The present invention relates to an energy photoconverter for obtaining biofuels and other, though not less important, byproducts. Said photoconverter uses a Tichelmann-type flow control system which allows providing equal pressure in any part thereof and thus continuously controls the extraction.
A first aspect of the present invention consists of a photoconverter consisting at least of the following elements:
The decanting, extraction and flow control towers (1) contain at least densimeters (20), oxygen extraction valves (11) located in the upper part thereof and hydrogen extraction valves (12) and they have gas sensors (13) coupled thereto, which gas sensors act such that they open at a higher gas concentration. They are transparent tubes having a diameter from 0.80 to 1.50 meters with a height from 3 to 5 meters. In addition, they are equipped with electromagnetic extraction valves (9) in the lower part thereof and with nutrient ionization injectors (7) next to them, gas extraction valves in the upper part (11) and motor-driven Tichelmann-type flow circulation valves.
The tubes for conducting photosynthesis (2) can be horizontally or vertically arranged and are arranged perpendicular to the decanting, extraction and flow control towers (1). In addition, photosynthesis is carried out therein by means of the phytoplankton present therein and therefore these tubes are preferably made of a transparent material so as to allow the passage of electromagnetic radiation during hours of sunlight. In this same sense they contain fiber-optic (
The mixture and buffer tanks (3) contain nutrients necessary for the development and growth of the phytoplankton mainly contained in (1) and (2). They are cylindrical shaped, made of a transparent material and have an internal volume comprised within the range from 500 to 3000 m3. With respect to the mixture and buffer tanks (3), they are made of a transparent material, are cylindrical and are arranged vertically. They have a level and nutrient inlet control using pH, temperature and concentration sensors, etc.
The culturing conditions of the phytoplankton in the photoconverters are as follows:
When referring to nutrients, these nutrients are carbon dioxide, hereinafter CO2, NOx, vitamins, antibiotics, fungicides, water, trace elements and orthophosphoric acid.
The antibiotics added to the culture are a mixture of penicillin and streptomycin at a concentration range from 100 to 300 mg/l each, preferably at a concentration range from 150 to 250 mg/l and more preferably at a concentration of 200 mg/l for each of the components of the mixture.
The fungicides added to the culture are a mixture of griseofulvin and nystatin at a concentration range from 100 to 300 mg/l each, preferably at a concentration range from 150 to 250 mg/l and more preferably at a concentration of 200 mg/l for each of the components of the mixture.
The water added for the phytoplankton culture can be freshwater, brackish water or salt water.
The recirculation pumps (4) are centrifugal-type pumps and allow a flow rate comprised within the range from 4 to 100 cm/sec.
The heat exchangers (5) are laminar flow plate-type exchangers, are controlled by temperature sensors and are used to maintain the temperature by means of water from the cooling towers or condenser (19) of the system.
The desuperheaters (6) are laminar flow plate-type desuperheaters and have the purpose of reducing the inlet temperature of CO2 and NOx (6a) coming from a pyrolysis gasifier.
Pyrolysis gasifier is understood to be a combustion process occurring at a temperature ranging between 800 and 1200° C. and which allows using and recycling most of the available waste. The process allows treating segregated or mixed urban and industrial waste. It is also technically possible, without any additional difficulties, to treat toxic waste, hospital waste, tires in the same industrial plants, i.e. to propose an overall definitive solution to the problems set forth by waste. The different advantages include the fact that the process is economically viable and less expensive than any other process, and particularly, incineration, thermolysis, methanation processes, and the fact that the process is completely ecological, without any environmental impact and offers a definitive solution to the waste problem, i.e., a “zero dump” solution. The pyrolysis gasifier achieves that all the waste is transformed into synthesis gas, hydrochloric acid, hydrofluoric acid and hydrogen sulfide, the latter three being three products which can be relatively easily made inert.
A synthesis gas is understood as a gas formed by a mixture of carbon monoxide, hereinafter CO, and hydrogen, hereinafter H2, which is obtained from a mixture of methane, hereinafter CH4, and oxygen, hereinafter O2, obtained from the air and steam by means of a pyrolysis gasifier.
The photoconverter can additionally include at least 50 ion sprayers (7) per hectare of surface, such that the nutrients are ionized and better and more efficient assimilation of the nutrients by the phytoplankton contained in (1) and (2) is thus allowed. Ion sprayer is understood as any system known in the state of the art that is able to ionize molecules.
The electromagnetic flow control or extraction valves (9) are located at the base of the decanting, extraction and flow control towers (1) and depend on photovalves operating by the difference of the light intensity between two points (controlled opening).
The control sensors (10) control the temperature, pH, the carbon dioxide, oxygen, trace element, antibiotic and fungicide concentration.
The photoconverter can additionally contain at least 5 gas sensors (13) per hectare of surface.
The decanting tanks (14) separate the biomass produced by the phytoplankton of the water of the culture medium. These decanting tanks are static tanks. The separated biomass contains, among other products and in no limiting sense, lipids, carbohydrates and products derived from the secondary metabolism of the phytoplankton. A transesterification reaction is carried out in the lipids present in the biomass separated by (14) such that biofuels and other energetic products are produced.
The carbohydrates obtained from the biomass separated by (14) are subjected to catalysis such that naphthas, kerosenes, polymers and gases coming from the catalysis of carbohydrates are obtained.
Transesterification refers to the chemical reaction by means of which the alkoxy group of an ester is exchanged for another alcohol, as shown in the following reaction:
To carry out transesterification of the lipids obtained as part of the biomass produced by the phytoplankton described in this process, ethanol and methanol from a Fischer Tropsch-type reactor are used, which reactor is in turn fed by means of synthesis gas, steam and heat from a pyrolysis gasifier for biomass or waste from dumps. On the other hand, the biomass pyrolysis gasifier produces CO2 and NOx which are part of the nutrients used for the feeding and growing cultured phytoplankton present in (1) and (2). The excess gases of the pyrolysis gasifier are furthermore reused to obtain electric and thermal energy, the latter being reused for desalinization.
A greenhouse-type system allows light to pass through to the natural light inlets (15), which are covered with translucent plastic, to limit the light or electromagnetic radiation intensity depending on the season of the year. In this same sense, the electromagnetic energy supplied comprises wavelengths of the spectrum ranging from 430 to 690 nm.
In addition, the decanting, extraction and flow control towers (1) and tubes for conducting photosynthesis (2) contain fiber-optic (
The control panels (17) control the injection of the different nutrients of the culture medium flow.
The recirculation systems (18) cause a Venturi-type effect which consists of the pressure of the fluid in the current of a fluid inside a closed conduit being reduced as the velocity increases when it passes through an area having a smaller section. If at this point of the conduit the end of another conduit is introduced, the fluid contained in this second conduit is suctioned for recirculation to prevent the algae from being destroyed due to the pressure.
The pumps (21) for reintroducing liquid are connected to the decanting tanks (14), such that the water separated in (14) recirculates to (3) passing through (21).
Another aspect of the present invention are the products obtained by means of the photoconverter, such that mainly biofuels are obtained, in addition to pharmacopeial products such as fatty acids and lutein, among others, cosmetic products such as glycerin, pigments and emulsifying substances, industrial products with a high silica content such as borosilicates and ferrosilicates, fertilizing products, agricultural products, industrial products and livestock products, and thermal and electric energy.
An inoculum of a phytoplankton strain is introduced in (3), culture medium and nutrients are added which are detected and regulated by means of (10) and (17). Circulation thus begins so as to establish a continuous flow within which the phytoplankton cells will travel, at the same time reproducing through (1) where they are insufflated with carbon dioxide (6a) coming from (6) which controls the temperature and are ionized in (7), and then they will move to (2), uptaking the electromagnetic energy by means of (15) and (16) and (22), in order to conduct photosynthesis.
This is where the luminous intensity is controlled by means of (23) and in (24) is where the electromagnetic field aids in polarizing the CO2 molecules, thus aiding in their dissolution and thus increasing the biomass, rich in lipids and carbohydrates, among other products. Then it will go to the next (1), also with CO2, with turbulence being generated and to stabilize itself, the phytoplankton tries to float in the medium. For each turbulence step, O2 is lost by means of (11) and is detected by (13), and the same occurs for H2 by means of (12) and is detected by (13). A recirculation process (8) is carried out within a Tichelmann-type pressure equilibrium process until the phytoplankton biomass is sufficient and detected by (20) in order to begin the extraction of part of it through (9) and from there the extracted part goes to (14), in which the water is separated from the biomass and is again propelled by (21) to the Venturi-type recirculation systems (18), finally going to (3) and to (1). The part that is not extracted due to a lack of density and therefore not detected by (20) is reintroduced into the system by (4), passing through (5) to maintain its temperature.
| Number | Date | Country | Kind |
|---|---|---|---|
| P200601567 | Jun 2006 | ES | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/ES2007/000336 | 6/7/2007 | WO | 00 | 4/15/2009 |
