None.
Not Applicable.
Not Applicable
The present invention pertains to an energy recovery apparatus for use in a refrigeration system.
One aspect of the present invention is a method comprising selling an energy recovery apparatus. The energy recovery apparatus comprises an intake port adapted to be in fluid communication with the refrigerant cooler, a discharge port adapted to be in fluid communication with the evaporator, a nozzle, and a turbine. The nozzle comprises a necked-down region and a tube portion. The tube portion is downstream of the necked-down region. The necked-down region has a downstream end having a cross-sectional area less than a cross-sectional area of the intake port of the energy recovery apparatus. The nozzle is configured to increase velocity of the refrigerant as it passes through the nozzle. The turbine is positioned and configured to be driven by refrigerant discharged from the nozzle. The discharge port of the energy recovery apparatus is downstream of the turbine. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the nozzle in a liquid-vapor. The nozzle is also adapted and configured such that the liquid refrigerant discharged from the nozzle has a velocity that is at least 60% of the velocity of the vapor refrigerant discharged from the nozzle. The energy recovery apparatus further comprises a generator coupled to the turbine and driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the nozzle. The energy recovery apparatus further comprises a housing encompassing the turbine and the generator. The method further comprises including with the energy recovery apparatus indicia (e.g., instructions, explanation, etc.) that the energy recovery apparatus is to be placed in fluid communication with an evaporator of a refrigeration system.
Another aspect of the present invention is a method comprising modifying a refrigeration system. The refrigeration system comprises an evaporator, a compressor, a refrigerant cooler and a throttle valve. The evaporator comprises an intake port and a discharge port. The evaporator is configured to evaporate a cold refrigerant from a liquid-vapor state to a vapor state. The compressor comprises an intake port and a discharge port. The intake port of the compressor is in fluid communication with the discharge port of the evaporator. The compressor is configured to receive refrigerant discharged from the evaporator and compress the refrigerant. The refrigerant cooler comprises an intake port and a discharge port. The intake port of the refrigerant cooler is in fluid communication with the discharge port of the compressor. The refrigerant cooler is configured to receive refrigerant discharged from the compressor. The throttle valve comprises an intake port and a discharge port. The intake port of the throttle valve is in fluid communication with the discharge port of the refrigerant cooler. The discharge port of the throttle valve is in fluid communication with intake port of the evaporator. The method comprising replacing the throttle valve with an energy recovery apparatus. The energy recovery apparatus comprises an intake port adapted to be in fluid communication with the refrigerant cooler, a discharge port adapted to be in fluid communication with the evaporator, a nozzle, and a turbine. The nozzle comprises a necked-down region and a tube portion. The tube portion is downstream of the necked-down region. The necked-down region has a downstream end having cross-sectional area less than a cross-sectional area of the intake port of the energy recovery apparatus. The nozzle is configured to increase velocity of the refrigerant as it passes through the nozzle. The turbine is positioned and configured to be driven by refrigerant discharged from the nozzle. The discharge port of the energy recovery apparatus is downstream of the turbine. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the nozzle in a liquid-vapor state. The nozzle is also adapted and configured such that the liquid refrigerant discharged from the nozzle has a velocity that is at least 60% of the velocity of the vapor refrigerant discharged from the nozzle.
Another aspect of the present invention is an energy recovery apparatus for use in a refrigeration system. The refrigeration system comprises an evaporator, a compressor and a refrigerant cooler. The evaporator is configured to evaporate a cold refrigerant from a liquid-vapor state to a vapor state. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator, and a housing. The intake port is adapted to be in fluid communication with the refrigerant cooler. The discharge port is adapted to be in fluid communication with the evaporator. The nozzle is adapted and configured to increase velocity of the refrigerant as it passes through the nozzle. The turbine is positioned and configured to be driven by refrigerant discharged from the nozzle. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the nozzle. The housing encompasses the turbine and the generator.
Another aspect of the present invention is an energy recovery apparatus for use in a refrigeration system. The refrigeration system comprises an evaporator, a compressor, and a refrigerant cooler. The refrigeration system is configured to circulate refrigerant along a flow path such that the refrigerant flows from the evaporator to the compressor, and from the compressor to the refrigerant cooler, and from the refrigerant cooler to the evaporator. The energy recovery apparatus is adapted and configured to be in the flow path operatively between the refrigerant cooler and the evaporator. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator and a housing. The intake port is adapted to permit refrigerant to flow into the energy recovery apparatus. The discharge port is adapted to permit refrigerant to flow out of the energy recovery apparatus. The nozzle comprises a conduit region downstream of the intake port. The conduit region defines a passageway. The passageway is adapted to constitute a portion of the flow path. The passageway has an upstream cross-section, a downstream cross-section, a passageway length extending from the upstream cross-section to the downstream cross-section, and a discharge end. The downstream cross-section of the passageway is closer to the discharge end of the passageway than to the upstream cross-section. The passageway at the downstream cross-section has an effective diameter. The effective diameter is defined as (4A/π)1/2, where A is the cross-sectional area of the passageway at the downstream cross-section. The passageway length is at least five times the effective diameter. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the discharge end of the passageway in a liquid-vapor state with a liquid component and a vapor component. The turbine is positioned and configured to be driven by refrigerant discharged from the discharge end of the passageway. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and adapted to be driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the discharge end of the passageway. The turbine and the generator are within the housing.
Another aspect of the present invention is an energy recovery apparatus for use in a refrigeration system. The refrigeration system comprises an evaporator, a compressor, and a refrigerant cooler. The refrigeration system is configured to circulate refrigerant along a flow path such that the refrigerant flows from the evaporator to the compressor, and from the compressor to the refrigerant cooler, and from the refrigerant cooler to the evaporator. The energy recovery apparatus is adapted and configured to be in the flow path operatively between the refrigerant cooler and the evaporator. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator and a housing. The intake port is adapted to permit refrigerant to flow into the energy recovery apparatus. The discharge port is adapted to permit refrigerant to flow out of the energy recovery apparatus. The nozzle comprises a conduit region downstream of the intake port. The conduit region defines a passageway. The passageway is adapted to constitute a portion of the flow path. The passageway has an upstream cross-section, a downstream cross-section, a passageway length extending from the upstream cross-section to the downstream cross-section, and a discharge end. The discharge end of the passageway is adjacent the downstream cross-section of the passageway. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the discharge end of the passageway in a liquid-vapor state with a liquid component and a vapor component. The nozzle is adapted and configured to discharge the liquid component of the refrigerant from the discharge end of the passageway at a velocity of at least about 190 feet per second (58 m/s). The turbine is positioned and configured to be driven by refrigerant discharged from the discharge end of the passageway. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and adapted to be driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the discharge end of the passageway. The turbine and the generator are within the housing.
Another aspect of the present invention is an energy recovery apparatus for use in a refrigeration system. The refrigeration system comprises an evaporator, a compressor, and a refrigerant cooler. The refrigeration system is configured to circulate refrigerant along a flow path such that the refrigerant flows from the evaporator to the compressor, and from the compressor to the refrigerant cooler, and from the refrigerant cooler to the evaporator. The energy recovery apparatus is adapted and configured to be in the flow path operatively between the refrigerant cooler and the evaporator. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator, and a housing. The intake port is adapted to permit refrigerant to flow into the energy recovery apparatus. The discharge port is adapted to permit refrigerant to flow out of the energy recovery apparatus. The nozzle comprises a conduit region downstream of the intake port. The conduit region defines a passageway. The passageway is adapted to constitute a portion of the flow path. The passageway has an upstream cross-section, a downstream cross-section, a passageway length extending from the upstream cross-section to the downstream cross-section, and a discharge end. The discharge end of the passageway is adjacent the downstream cross-section of the passageway. The cross-sectional area of the passageway at the downstream cross-section is not greater than the cross-sectional area of the passageway at any point along the passageway length. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the discharge end of the passageway in a liquid-vapor state with a liquid component and a vapor component. The nozzle is adapted and configured such that the liquid component of the refrigerant discharged from the discharge end of the passageway has a velocity that is at least 60% that of the vapor component of the refrigerant discharged from the discharge end of the passageway. The turbine is positioned and configured to be driven by refrigerant discharged from the discharge end of the passageway. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and adapted to be driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the discharge end of the passageway. The turbine and the generator are within the housing.
Another aspect of the present invention is a trans-critical refrigeration system comprising an evaporator, a compressor, a gas cooler, and an energy recovery apparatus. The refrigeration system is configured to circulate refrigerant along a flow path such that the refrigerant flows from the evaporator to the compressor, and from the compressor to the gas cooler, and from the gas cooler to the energy recovery apparatus, and from the energy recovery apparatus to the evaporator. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator, and a housing. The intake port is adapted to permit refrigerant to flow into the energy recovery apparatus. The discharge port is adapted to permit refrigerant to flow out of the energy recovery apparatus. The nozzle comprises a conduit region downstream of the intake port. The conduit region defines a passageway. The passageway is adapted to constitute a portion of the flow path. The passageway has an upstream cross-section, a downstream cross-section, a passageway length extending from the upstream cross-section to the downstream cross-section, and a discharge end. The discharge end of the passageway coincides with the downstream cross-section of the passageway. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the discharge end of the passageway in a liquid-vapor state with a liquid component and a vapor component. The nozzle is adapted and configured such that the liquid component of the refrigerant discharged from the discharge end of the passageway has a velocity that is at least 60% that of the vapor component of the refrigerant discharged from the discharge end of the passageway. The turbine is positioned and configured to be driven by refrigerant discharged from the discharge end of the passageway. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and adapted to be driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the discharge end of the passageway. The turbine and the generator are within the housing.
Another aspect of the present invention is a trans-critical refrigeration system comprising an evaporator, a compressor, a gas cooler, and an energy recovery apparatus. The refrigeration system is configured to circulate refrigerant along a flow path such that the refrigerant flows from the evaporator to the compressor, and from the compressor to the gas cooler, and from the gas cooler to the energy recovery apparatus, and from the energy recovery apparatus to the evaporator. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator, and a housing. The intake port is adapted to permit refrigerant to flow into the energy recovery apparatus. The discharge port is adapted to permit refrigerant to flow out of the energy recovery apparatus. The nozzle comprises a conduit region downstream of the intake port. The conduit region defines a passageway. The passageway is adapted to constitute a portion of the flow path. The passageway has an upstream cross-section, a downstream cross-section, a passageway length extending from the upstream cross-section to the downstream cross-section, and a discharge end. The discharge end of the passageway coincides with the downstream cross-section of the passageway. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the discharge end of the passageway in a liquid-vapor state with a liquid component and a vapor component, the nozzle being adapted and configured to discharge the liquid component of the refrigerant from the discharge end of the passageway at a velocity of at least about 190 feet per second (58 m/s). The turbine is positioned and configured to be driven by refrigerant discharged from the discharge end of the passageway. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and adapted to be driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the discharge end of the passageway. The turbine and generator are within the housing.
Another aspect of the present invention is an energy recovery apparatus for use in a trans-critical refrigeration system. The refrigeration system comprises an evaporator, a compressor, and a gas cooler. The refrigeration system is configured to circulate refrigerant along a flow path such that the refrigerant flows from the evaporator to the compressor, and from the compressor to the gas cooler, and from the gas cooler to the evaporator. The energy recovery apparatus is adapted and configured to be in the flow path operatively between the gas cooler and the evaporator. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator and a housing. The intake port is adapted to permit refrigerant to flow into the energy recovery apparatus. The discharge port is adapted to permit refrigerant to flow out of the energy recovery apparatus. The nozzle comprises a conduit region downstream of the intake port. The conduit region defines a passageway. The passageway is adapted to constitute a portion of the flow path. The passageway has an upstream cross-section, a downstream cross-section, a passageway length extending from the upstream cross-section to the downstream cross-section, and a discharge end. The downstream cross-section of the passageway is closer to the discharge end of the passageway than to the upstream cross-section. The passageway at the downstream cross-section has an effective diameter. The effective diameter is defined as (4A/π)1/2, where A is the cross-sectional area of the passageway at the downstream cross-section. The passageway length is at least five times the effective diameter. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the discharge end of the passageway in a liquid-vapor state with a liquid component and a vapor component. The turbine is positioned and configured to be driven by refrigerant discharged from the discharge end of the passageway. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and adapted to be driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the discharge end of the passageway. The turbine and the generator are within the housing.
Another aspect of the present invention is an energy recovery apparatus for use in a trans-critical refrigeration system. The trans-critical refrigeration system comprises an evaporator, a compressor, and a gas cooler. The refrigeration system is configured to circulate refrigerant along a flow path such that the refrigerant flows from the evaporator to the compressor, and from the compressor to the gas cooler, and from the gas cooler to the evaporator. The energy recovery apparatus is adapted and configured to be in the flow path operatively between the gas cooler and the evaporator. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator and a housing. The intake port is adapted to permit refrigerant to flow into the energy recovery apparatus. The discharge port is adapted to permit refrigerant to flow out of the energy recovery apparatus. The nozzle comprises a conduit region downstream of the intake port. The conduit region defines a passageway. The passageway is adapted to constitute a portion of the flow path. The passageway has an upstream cross-section, a downstream cross-section, a passageway length extending from the upstream cross-section to the downstream cross-section, and a discharge end. The discharge end of the passageway is adjacent the downstream cross-section of the passageway. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the discharge end of the passageway in a liquid-vapor state with a liquid component and a vapor component. The nozzle is adapted and configured to discharge the liquid component of the refrigerant from the discharge end of the passageway at a velocity of at least about 190 feet per second (58 m/s). The turbine is positioned and configured to be driven by refrigerant discharged from the discharge end of the passageway. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and adapted to be driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the discharge end of the passageway. The turbine and the generator are within the housing.
Another aspect of the present invention is an energy recovery apparatus for use in a refrigeration system. The refrigeration system comprises an evaporator, a compressor, and a gas cooler. The refrigeration system is configured to circulate refrigerant along a flow path such that the refrigerant flows from the evaporator to the compressor, and from the compressor to the gas cooler, and from the gas cooler to the evaporator. The energy recovery apparatus is adapted and configured to be in the flow path operatively between the gas cooler and the evaporator. The energy recovery apparatus comprises an intake port, a discharge port, a nozzle, a turbine, a generator, and a housing. The intake port is adapted to permit refrigerant to flow into the energy recovery apparatus. The discharge port is adapted to permit refrigerant to flow out of the energy recovery apparatus. The nozzle comprises a conduit region downstream of the intake port. The conduit region defines a passageway. The passageway is adapted to constitute a portion of the flow path. The passageway has an upstream cross-section, a downstream cross-section, a passageway length extending from the upstream cross-section to the downstream cross-section, and a discharge end. The discharge end of the passageway is adjacent the downstream cross-section of the passageway. The cross-sectional area of the passageway at the downstream cross-section is not greater than the cross-sectional area of the passageway at any point along the passageway length. The nozzle is adapted and configured such that refrigerant entering the nozzle is reduced in temperature and pressure as it passes through the nozzle and is discharged from the discharge end of the passageway in a liquid-vapor state with a liquid component and a vapor component. The nozzle is adapted and configured such that the liquid component of the refrigerant discharged from the discharge end of the passageway has a velocity that is at least 60% that of the vapor component of the refrigerant discharged from the discharge end of the passageway. The turbine is positioned and configured to be driven by refrigerant discharged from the discharge end of the passageway. The discharge port of the energy recovery apparatus is downstream of the turbine. The generator is coupled to the turbine and adapted to be driven by the turbine. The generator is configured to produce electricity as a result of the turbine being driven by refrigerant discharged from the discharge end of the passageway. The turbine and the generator are within the housing.
Reference numerals in the written specification and in the drawing figures indicate corresponding items.
An embodiment of a refrigeration system of the present invention is indicated generally by reference numeral 10 in
An embodiment of an energy recovery apparatus of the present invention is indicated generally by reference numeral 14 in
The housing 16 is preferably comprised of three parts. A first, lower center housing part 22 has an interior that supports a bearing assembly 24. The center part 22 is attached to a second, side wall part 26 of the housing. The side wall 26 is preferably generally cylindrical in shape and extends around an interior volume of the housing 16. The center housing part 22 also includes a hollow center column 28. The interior of the center column 28 supports a second bearing assembly 30. A third, cover part of the housing 32 is attached to the top of the side wall 26. The cover part 32 encloses the hollow interior of the housing 16. The center housing part 22 preferably has an outlet opening (or discharge port) 34 that is the outlet for the refrigerant passing through the energy recovery apparatus 14. The discharge port 34 of the energy recovery apparatus 14 is downstream of the turbine 18. The housing side wall 26 is preferably formed with a refrigerant inlet opening 38. This is the inlet for the refrigerant entering the energy recovery apparatus 14. Referring to
The turbine 18 includes a center shaft 36 mounted for rotation in the two bearing assemblies 24, 30. As shown in
Referring to
In operation of the energy recovery apparatus 14 of the invention in a refrigerant system (e.g., an air conditioning system) such as that shown in
The refrigerant passing through the energy recovery apparatus 14 causes rotation of the turbine wheel 48 and the turbine shaft 46, which also causes rotation of the permanent magnets 56 on the cylindrical wall 54 of the rotor of the generator 20. The rotation of the permanent magnets 56 induces a current in the stator windings 60 which produces electricity from the energy recovery apparatus 14. The electricity produced can be routed back to a fan of the air conditioning system to help power its needs. This increases the energy efficiency of the air conditioning system and increases the SEER rating and the EER rating of the air conditioning system. The energy recovery apparatus 14 also increases the capacity of the evaporator by increasing the liquid percentage of the refrigerant entering the evaporator. It is also to be understood that the generator could be omitted. In a system without the generator, the turbine could be used to turn a fan or otherwise power (e.g., mechanically power) some component of the air conditioning system.
Preferably, the housing 16, the turbine 18 and the generator 20 are arranged and configured such that refrigerant introduced into the housing cools and lubricates the generator. The housing 16 is configured such that, during normal operation of the energy recovery apparatus 14, refrigerant passing through the energy recovery apparatus escapes from the housing 16 only via the discharge port 34. The turbine and generator are in fluid communication with each other such that at least some refrigerant directed to the turbine is able to flow to the generator. The internal generator also eliminates any external shafts that would have to be refrigerant sealed. In other words, the housing 116 is preferably devoid of any openings for the passage of external shafts. As shown in
In operation, the intake port 38 of the energy recovery apparatus 14 is operatively coupled (e.g., via a refrigerant line) in fluid communication to the discharge port of a refrigerant cooler of a refrigerant system such that refrigerant discharged from the refrigerant cooler flows into the energy recovery apparatus. The refrigerant is discharged from the nozzle 42 at a low temperature, high velocity liquid-vapor and toward the blades 50 of the turbine 18. The refrigerant impacting the turbine blades causes the turbine to rotate about the turbine axis X, which also causes rotation of the permanent magnets on the cylindrical wall which form the rotor of the generator 20. The rotation of the permanent magnets induces a current in the stator windings of the generator to thereby produce electricity. The refrigerant then flows through the turbine 18 and is discharged out the discharge port 34 of the energy recovery apparatus 114 and conveyed to the evaporator. Preferably, the energy recovery apparatus 14 is configured to match the refrigerant cooler and evaporator such that the refrigerant passing from the refrigerant cooler through the energy recovery apparatus enters the evaporator at a pressure and temperature desirable for the evaporator. When operated in a in typical R410A five ton system, the energy recovery apparatus 14 should generate about 100 watts of electrical power at 80° F. ambient indoor temperate and 82° F. outdoor temperature, and about 200 watts at 95° F. outdoor temperature. In other words, the energy recovery apparatus 14 recovers about ⅓ of the available expansion energy.
The energy recovery apparatus of the present invention may be sold or distributed as part of a complete refrigerant system or as a separate unit to be added to a refrigeration system (e.g., to replace a throttle valve of an existing refrigeration system). In connection with the sale or distribution of the energy recovery apparatus, a user (e.g., a purchaser of the energy recovery apparatus) is instructed that the purpose of the energy recovery apparatus is to replace the throttle valve. The user is induced to have the energy recovery apparatus placed in fluid communication with a refrigerant cooler and evaporator of a refrigeration system.
A second embodiment of an energy recovery apparatus of the present invention is indicated generally by reference numeral 114 in
A third embodiment of an energy recovery apparatus of the present invention is indicated generally by reference numeral 214 in
As various modifications could be made in the constructions and methods herein described and illustrated without departing from the scope of the invention, it is intended that all matter contained in the foregoing description or shown in the accompanying drawings shall be interpreted as illustrative rather than limiting. For example, although the energy recovery apparatus 14 is shown as having only one nozzle, it is to be understood that an energy recovery apparatus in accordance of the present invention may have one, two or more nozzles, such as the energy recovery apparatus described in co-pending U.S. patent application Ser. No. 14/179,899 filed Feb. 13, 2014 (incorporated herein by reference). Thus, the breadth and scope of the present invention should not be limited by any of the above-described exemplary embodiments, but should be defined only in accordance with the following claims appended hereto and their equivalents.
It should also be understood that when introducing elements of the present invention in the claims or in the above description of exemplary embodiments of the invention, the terms “comprising,” “including,” and “having” are intended to be open-ended and mean that there may be additional elements other than the listed elements. Additionally, the term “portion” should be construed as meaning some or all of the item or element that it qualifies. Moreover, use of identifiers such as first, second, and third should not be construed in a manner imposing any relative position or time sequence between limitations. Still further, the order in which the steps of any method claim that follows are presented should not be construed in a manner limiting the order in which such steps must be performed.
Filing Document | Filing Date | Country | Kind |
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PCT/US14/54002 | 9/4/2014 | WO | 00 |