The present invention generally relates to rechargeable batteries, and more particularly, but not exclusively, to flooded batteries having mud rests with internal passages.
Providing energy storage devices, such as in rechargeable batteries having an internal battery fluid, with flow path features remains an area of interest. Some existing systems have various shortcomings relative to certain applications. Accordingly, there remains a need for further contributions in this area of technology.
One embodiment of the present invention is a unique energy storage device. Other embodiments include apparatuses, systems, devices, hardware, methods, and combinations for improved battery fluid flow in an energy storage device. Further embodiments, forms, features, aspects, benefits, and advantages of the present application shall become apparent from the description and figures provided herewith.
For the purposes of promoting an understanding of the principles of the invention, reference will now be made to the embodiments illustrated in the drawings and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of the invention is thereby intended. Any alterations and further modifications in the described embodiments, and any further applications of the principles of the invention as described herein are contemplated as would normally occur to one skilled in the art to which the invention relates.
Shown in
The container 52 includes a mud well 60 having mud rests 62. The mud well 60 includes sufficient volumetric space to collect mud residue formed as a result of battery operation over period of time. The mud rests 62 provide spacing for the plates 54 from the bottom of the mud well 60 such that semi-conductive material shed from the plates to fall below the plates (into the mud well) thereby reducing opportunity for this material to short circuit the plates. As will be appreciated, the volumetric open space of the mud well 60 available for the collection of mud residue can in some embodiments be larger than the volumetric space occupied by the mud rests 62, but such a relationship need not be present in all embodiments. For example in some forms the volumetric space available for mud residue can be the same or smaller as the volumetric space occupied by the mud rests 62. The mud rests 62 extend up from a bottom of the well 60 to space the battery plate 54 from the mud residue to aid in preventing unwanted events, such as short circuits that may occur via semi-conductive mud residue. As will be described below, one or more of the mud rests 62 define a passage for the conveyance of electrolytic fluid.
The energy storage device 50 also can include a vent 64 for the expulsion of gas produced as a byproduct of a charging event. As will be appreciated, the plates that are of positive (+) polarity during a charging event can generate a gas as a byproduct of the charging event. During the final stage of a typical recharge, also known as ‘finish,’ acid stratification generated in earlier stages of recharge which reduces charging efficiency can be ameliorated via gassing. Gassing involves generating hydrogen and oxygen bubbles in the plates. These gas bubbles enter the bulk electrolyte and induce movement that mixes electrolyte and removes stratification.
Turning now to
Although the plates 54 are shown as flat and roughly quadrilateral in shape in various figures above, the plate 54 can take on any variety of shape. As such, as used herein the term plate refers to any suitable device capable of participating in an electrolytic battery cycle event whether or not the structure is arranged as a flat device having substantially planar first side and second side. Curvilinear plates and other variety of shapes are also contemplated herein.
The ribs 72 form open channels and that extend along a length of the separator 56. The channels can be the same across the entire separator surface, but in some embodiments one or more of the channels can be different. To set forth just a few nonlimiting examples, the cross sectional shape can change over the length of the channel. The channel is structurally arranged with a spacing that encourages flow of battery fluid in the presence of gaseous byproduct of charging.
The separators 56 can be arranged for positive plates or for negative plates such that the orientation of the channels relative to the particular plate 54 depends on the polarity of the plate (such as the polarity of the plate during a charging event). In some embodiments only positive plates have separators 56, other embodiments only the negative plates have separators 56, while in still other embodiments the energy storage device 50 can include one or more separators used with positive plates as well as one or more separators be used with negative plates.
The material used in the separator 56 can take on the form of a pocket for use in the device 50. The pocket can include an open top for ease of insertion of a battery plate where the top is located near the top of the container 52 including the terminals 58. As used herein the term “top” of the pocket, or for that matter the term “bottom”, are used herein for descriptive purposes and for ease of reference to distinguish between opposite ends of the pocket or other features of the device 50. The terms are not otherwise intended to be strictly limited in orientation in all embodiments.
One nonlimiting embodiment of a pocket having an open top can be seen in the separator 56 illustrated in
The separator 56 pocket can be formed from a single sheet of stock material folded either on a side or at the bottom to form the enclosure, but in other embodiments the pocket can be formed from one or more separate sheets that are joined together using any variety of techniques such as mechanical (e.g. stitching) or chemical joining (e.g. bonding), among other potential varieties.
One or both of the front and back sides of the pocket can be “coupled” together in the sense that multiple separate pieces of separator material can be joined together near an edge of the separator 56 to form the pocket, or the sides can be “coupled” in the sense that each side is a separate geometric feature of the pocket of an otherwise single piece of material, such that the sides are conventionally considered “coupled” together at a change in feature like from the first side to the second side.
If a separator pocket is used to enclose the plate considered the positive (+) battery plate during charging, the grooved/channeled surface of the separator pocket would be located on an inside of the pocket to facilitate removal of the gaseous byproduct. Such a pocket can have an open bottom or a closed bottom. If the separator pocket is used to enclose the plate considered the negative (−) battery plate during charging, the grooved/channeled surface of the separator pocket would be located on an outside of the pocket to face the adjacent positive (+) plate (as viewed during the charging event) to facilitate removal of the gaseous byproduct.
In those embodiments in which the separator 56 pocket includes a closed bottom and is used on the positive (+) plate when charged, openings can be formed in the bottom of the separator 56 pocket. Such openings can all be the same or different sizes, and can be formed at the apex of the fold, or in a location near the fold if the separator is formed from a sheet of material which folds around the bottom of the pocket. The openings can be formed via perforations, such as with a processing machine used to form the pocket that includes a cutter employed specifically to form the perforations.
The channels on the separators (as seen in one embodiment in
Turning now to the mud rests 60, as depicted above in some form the container 52 can include one or more mud rests 62 upon which the plates 54 rest. The mud rests 62 can be formed integral with the base of the container 52, but in some forms the mud rests 62 are separately formed and later coupled with the container 52. Any number of mud rests 62 can be used having any size and shape. Depicted in the embodiment of
Turning now to another alternative and/or additional feature of the application, various passages 74 can be provided near the bottom of the container 52 to permit flow of battery fluid transverse to the mud rests 62 such that battery fluid can circulate. In some forms the passages 74 can extend across all mud rests 62 at roughly the same orientation and location on each plate, but other arrangements are also contemplated herein.
The passages can take on a variety of forms. In one embodiment nonlimiting embodiment shown in
In those embodiments in which the passage 74 is formed internal to the mud rest, the internal passages can include inlet/outlet apertures having any size and shape. Any number of apertures can be provided, and can be provided in any configuration. The apertures can change size and/or shape from one side of the mud rest to another. The passage extending between the apertures can have constant cross sectional shape and size, but can also vary in some embodiments from one end to the other.
In some forms the apertures constitute a single inlet and a single outlet in which a continuous through hole extends between the inlet to the outlet. In other embodiments, a through hole may be coupled with one or more inlets and/or one or more outlets. Thus, some embodiments of the mud rests 62 can include passages 74 having a single inlet and outlet, along with one or more passages 74 a plurality of inlets and/or outlets.
In the embodiments in which the passages 74 are partially formed in the top of the mud rest 62 (e.g. indentations), the inlet/outlet openings (functionally similar to the apertures in the internal passage embodiment above) in the mud rest 62 will be understood to be the contour formed in the mud rest 62 (e.g. from the indentation) that permits the beginnings of a flow path. An enclosed flow path will be formed when the plate or plate/separator combo are used in conjunction with the mud rest 62 such that the plate or plate separator form one side of the flow path and the contour formed in the mud rest 62 forms another side. The openings can extend any length away from the location of the plate or plate/separator combo. Such an indentation formed in the mud rest 62 can proceed in a line from one lateral side of the mud rest 62 to the other, but in additional and/or alternative embodiments the indentations can proceed in a curvilinear, piecewise linear, nonlinear, etc manner from one portion of the mud rest 62 to the other.
The shape, length, size, and manner of forming the apertures, openings, and passages can be the same or different for any of the other apertures, openings, and passages. Furthermore, the apertures, openings, and passages can be formed through any variety of techniques. In one nonlimiting embodiment the apertures, openings, and/or passages can be formed as perforations, such as those that are formed through a process in which an instrument is used to penetrate a material, or alternatively penetrate to weaken a material for subsequent completion of process. In other alternative and/or additional techniques, the apertures, openings, and/or passages can be molded and/or cast into the material that is used to form the mud well and/or mud rests.
As will be appreciated when referencing
In one embodiment the energy storage system includes the following:
(1) perforated or discontinuous mud rests below the plates that allow free lateral flow of electrolyte;
(2) pocket separators applied to negative plates such that the gas channel adjacent to the positive plate is open to the battery fluid reservoir in the mud well OR in the case of positive plate pocket separators, the bottom is perforated at the fold to similarly allow access to the acid in the mud well either case facilitates the upward flow of electrolyte; and
(3) a charge algorithm that includes reduced overcharge since copious charge is no longer required to mix electrolyte.
In another non-limiting embodiment the energy storage system includes:
(1) a pocket separator is applied to the positive plates by cutting to length, wrapping bottom to top, and mechanically sealing the sides as in typical methods. However, as the separator material is cut to length, an additional cutting operation is performed that perforates the separator at the midpoint where the separator will be folded around the bottom of the plate. This may be accomplished by adding an additional blade to the roll cutter. The perforations allow the material the hinge or fold around the plate as before. The perforations further provide openings between the gas channels and the electrolyte in the mud well below;
(2) The mud rests that support the plates from below are perforated or molding in a discontinuous form such the lateral flow of electrolyte is not impeded; and
(3) The free flow of electrolyte enabled by 1 and 2 above allow acid stratification to be quickly removed when gassing begins in the later stage of recharge, Therefore prolonged recharge for the purpose of mixing is not required. The charge termination criteria then can limit charge length to that which is required to charge the plates. This minimizes overcharge and avoids accelerated positive grid corrosion.
In still another embodiment the energy storage device includes:
(1) a pocket separator is applied to the negative plates by cutting to length, wrapping bottom to top, and mechanically sealing the sides as in typical methods. Since the separator is wrapped around the negative plate with the ribs facing the positive plate, gas channels are open to the battery uid in the mud well below;
(2) the mud rests that support the plates from below are perforated or molding in a discontinuous form such the lateral flow of electrolyte is not impeded; and
(3) the free flow of electrolyte enabled by 1 and 2 above allow acid stratification to be quickly removed when gassing begins in the later stage of recharge. Therefore prolonged recharge for the purpose of mixing is not required. The charge termination criteria then can limit charge length to that which is required to charge the plates. This minimizes overcharge and avoids accelerated positive grid corrosion.
In still a further embodiment the energy storage device includes:
(1) a pocket separator is applied to the positive plates by cutting to length, wrapping around the side, and mechanically sealing the remaining side as in typical methods. Since the separator is wrapped around the plate without sealing the bottom, the gas channels are open to the electrolyte in the mud well below;
(2) the mud rests that support the plates from below are perforated or molding in a discontinuous form such the lateral flow of electrolyte is not impeded; and
(3) the free flow of electrolyte enabled by 1 and 2 above allow acid stratification to be quickly removed when gassing begins in the later stage of recharge. Therefore prolonged recharge for the purpose of mixing is not required. The charge termination criteria then can limit charge length to that which is required to charge the plates. This minimizes overcharge and avoids accelerated positive grid corrosion.
The embodiment immediately above which uses a pocket separator having an open bottom, sometimes referred to as a sleeve separator are typically used in batteries of capacity associated for use in forklifts and renewable energy storage.
While the invention has been illustrated and described in detail in the drawings and foregoing description, the same is to be considered as illustrative and not restrictive in character, it being understood that only the preferred embodiments have been shown and described and that all changes and modifications that come within the spirit of the inventions are desired to be protected. It should be understood that while the use of words such as preferable, preferably, preferred or more preferred utilized in the description above indicate that the feature so described may be more desirable, it nonetheless may not be necessary and embodiments lacking the same may be contemplated as within the scope of the invention, the scope being defined by the claims that follow. In reading the claims, it is intended that when words such as “a,” “an,” “at least one,” or “at least one portion” are used there is no intention to limit the claim to only one item unless specifically stated to the contrary in the claim. When the language “at least a portion” and/or “a portion” is used the item can include a portion and/or the entire item unless specifically stated to the contrary.
Number | Date | Country | |
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62273585 | Dec 2015 | US |