Patent Grant
10352616
Field of the Invention
The present invention is directed to efficient and low cost recovery of natural gas liquids (NGL) from hydrocarbon gas streams.
Description of the Prior Art
Cryogenic processes are commonly used to recover heavy hydrocarbons from feed gases. By cooling a natural gas, it is possible to condense a portion of the heavy hydrocarbons, which can then be separated. The amount of NGL that is formed is a function of the gas composition, pressure, and temperature to which the gas is cooled. Greater quantities of NGL can be recovered by cooling to colder temperatures, but greater initial investment and ongoing operating expense is required to provide the required refrigeration and pre-treatment.
Refrigeration for the cooling can be supplied by expansion of the gas to lower pressure by the Joule-Thomson effect. Often, the processed gas must then be re-compressed to be delivered into the sales gas pipeline system. This re-compression can represent a significant capital and operating expense.
Depending on natural gas and NGL product pricing, it may not be economical to use highly cryogenic technologies to extract the hydrocarbon liquids. However, in many cases some NGL extraction is required so that the natural gas will meet pipeline specifications such as maximum heating value limitations. In this scenario, a less capital intensive technology is needed.
Simple low temperature separation (LTS) processes have been used for many years in applications where modest NGL recovery is required (see
One drawback of traditional LTS processes is a lack of selectivity in the NGL components recovered. Propane, butanes, pentanes, and heavier hydrocarbons each have different product pricing with the heavier components typically having a higher value than the lighter components in the NGL. Therefore, it is economically desirable to recover the heaviest components in the NGL until the sales gas pipeline specifications are met. However, conventional LTS processes do not have means to control the recovery of specific components, and product recovery is largely a function of gas composition at a particular temperature and pressure.
Another drawback of traditional LTS processes is re-compression of the vapor generated during stabilization of the NGL product. The high pressure NGL stream typically contains a significant quantity of lighter components (such as methane) that are also condensed during the chilling process. Heat is supplied in a fractionation tower to remove these light components from the product liquid to meet NGL specifications. These light components are commonly used to satisfy fuel requirements for the facility, but excess gas must be re-compressed and blended into the feed or sales gas stream.
What is needed is a means to improve recovery of the more valuable heavy components from the feed gas and to reduce the quantity of light components that must be re-compressed.
In one embodiment of the present invention, there is provided an enhanced low temperature process for separating light hydrocarbon components from heavy hydrocarbon components in a feed stream. The process comprises cooling the feed stream by directing the feed stream through at least one heat exchanger so as to condense at least a portion of the feed stream and directing the partially condensed feed stream into an absorber. An absorber overhead vapor stream and an absorber liquid bottoms stream are produced by separation in the absorber. The process further comprises flashing the absorber liquid bottoms stream into a de-ethanizer tower, thereby producing a de-ethanizer overhead vapor stream and a liquid product stream enriched in C3+ hydrocarbon compounds. At least a portion of the de-ethanizer overhead vapor stream is condensed to form a liquid reflux stream, and a first portion of the liquid reflux stream is used as reflux in the de-ethanizer tower. The absorber overhead vapor stream is combined with a second portion of the liquid reflux stream to produce a two-phase absorber recycle stream. Finally, at least a portion of said absorber recycle stream is directed to the absorber as liquid reflux.
In another embodiment, there is provided an enhanced low temperature process for separating light hydrocarbon components from heavy hydrocarbon components in a feed stream. The process comprises splitting the feed stream into a first portion and a second portion, cooling the first portion in a first heat exchanger, and cooling the second portion in a second heat exchanger. The first portion and the second portion are combined to produce a combined cooled feed stream, and the combined cooled feed stream is separated in an absorber, thereby producing an absorber overhead vapor stream and an absorber liquid bottoms stream. The absorber comprises a reboiler, and the second portion of the feed stream provides at least a portion of the heating duty for the reboiler. The process further comprises passing the absorber liquid bottoms stream through the second heat exchanger to provide cooling to the second portion of the feed stream, passing the absorber liquid bottoms stream through an expansion device, and flashing the absorber liquid bottoms stream into a de-ethanizer tower, thereby producing a de-ethanizer overhead vapor stream and a liquid product stream enriched in C3+ hydrocarbon compounds. A portion of the de-ethanizer overhead vapor stream is condensed to form a liquid reflux stream, and the uncondensed portion of the de-ethanizer overhead vapor stream is compressed to form a residue vapor stream. A first portion of the liquid reflux stream is used as reflux in the de-ethanizer tower, and the absorber overhead vapor stream is combined with a second portion of the liquid reflux stream to produce a two-phase absorber recycle stream. The two-phase absorber recycle stream is cooled in a chiller, thereby producing a cooled liquid and a cooled vapor, and the cooled liquid is directed to the absorber as liquid reflux. The cooled vapor is passed through the first heat exchanger to provide cooling to the first portion of the feed stream, and the cooled vapor is combined with the residue vapor stream to produce a combined residue gas stream.
In yet another embodiment, there is provided a low-temperature separation plant for separating C3+ hydrocarbon compounds from a hydrocarbon-containing feed gas stream. The plant comprises a first conduit configured to direct a first portion of the feed gas stream through a first heat exchanger and a second conduit configured to direct a second portion of the feed gas stream through a second heat exchanger. The first portion and second portion are combined as a cooled feed stream in a third conduit after being passed through the first heat exchanger and the second heat exchanger, respectively. The plant further comprises an absorber comprising a reboiler and configured to separate the combined cooled feed stream into an absorber overhead vapor stream and an absorber liquid bottoms stream, wherein the second conduit is configured to direct the second portion of the feed gas stream to the reboiler to provide at least a portion of the heating duty for the reboiler. The absorber liquid bottoms stream is directed through the second heat exchanger to provide cooling to the second portion of the feed gas stream. The plant also comprises an expansion device operable to flash the absorber liquid bottoms stream into a de-ethanizer tower, and the de-ethanizer tower is configured to produce a de-ethanizer overhead vapor stream and a liquid product stream enriched in C3+ hydrocarbon compounds. A condenser is operable to condense a portion of the de-ethanizer overhead vapor stream to form a liquid reflux stream, and a compressor is operable to compress an uncondensed portion of the de-ethanizer overhead vapor stream, thereby forming a residue vapor stream. A de-ethanizer reflux conduit is configured to direct a first portion of the liquid reflux stream to the de-ethanizer tower, while a recycle conduit is configured to combine a second portion of the liquid reflux stream with the absorber overhead vapor stream to produce a two-phase absorber recycle stream. Further, the plant comprises a chiller operable to cool the two-phase absorber recycle stream. A reflux accumulator is used to separate the cooled two-phase absorber recycle stream into a liquid recycle stream and a cooled vapor stream. The reflux accumulator is further configured to direct the cooled liquid recycle stream to the absorber as liquid reflux and to direct the cooled vapor stream through the first heat exchanger to provide cooling to the first portion of the feed gas stream. The residue vapor stream and said cooled vapor are combined in a residue gas stream.
A conventional LTS process is shown in
The hydrocarbon-containing feed stream 110 generally includes methane, ethane, and C3 and heavier components (C3+). As used herein, the general term “Cx ” refers to a hydrocarbon component comprising x carbon atoms per molecule and, unless otherwise noted, is intended to include all straight-chain and olefinic isomers thereof. As used herein, the term “Cx and heavier” refers to hydrocarbons having x or more carbon atoms per molecule (including isomers and olefins), while the term “Cx and lighter” refers to hydrocarbons having x or less carbon atoms per molecule (including isomers and olefins). According to one embodiment, feed gas stream 110 can comprise at least 5, at least 10, at least 15, at least 20, or at least 30 mole percent (mol %) C3 and heavier components, although in some embodiments the feed gas may comprise less than about 5 mol % C3 and heavier components. Lighter components such as methane, ethane, hydrogen, and trace amounts of gases like nitrogen and carbon dioxide, generally make up the balance of the composition of the feed gas stream. Feed gas stream 110 typically comprises at least about 50, at least about 60, at least about 70, at least about 80, at least about 90, at least about 95, or at least about 98 mol % of ethane and lighter components, based on the total stream.
Feed stream 110 is split into a first conduit 111 and a second conduit 113, with one portion of feed stream 110 being directed via first conduit 111 through heat exchanger 112 and a second portion of feed stream 110 being directed via second conduit 113 through heat exchanger 114. Both portions in conduits 111 and 113 are cooled in heat exchangers 112 and 114, respectively. The cooling in heat exchangers 112, 114 may be supplied by other process streams, for example, by a cold gas stream or cold liquid stream resulting from downstream processes (described below). After cooling in heat exchangers 112, 114, the split portions are recombined as a cooled feed stream in a third conduit 115 and directed through chiller 116 for further cooling. Chiller 116 may use any suitable refrigerant to accomplish said cooling. For example, in certain embodiments, chiller 116 uses propane or propylene as the refrigerant. Chilled stream 118 exits chiller 116 and generally comprises a two-phase mixture of condensed heavier hydrocarbons and vaporized lighter hydrocarbons.
Chilled stream 118 comprising the two-phase mixture is fed into cold separator 120, which acts to separate the condensed liquid portion of the mixture from the vapor portion. The vapor portion exits cold separator 120 as vapor steam 122. Vapor stream 122 comprises primarily methane, ethane, and lighter hydrocarbons, although some amount of propane and heavier hydrocarbons are also present in vapor steam 122. Vapor stream 122 leaving cold separator 120 is significantly colder than feed stream 110, so vapor stream 122 may be used to provide cooling in heat exchanger 112. Upon exiting heat exchanger 112, vapor stream 122 may be compressed as required in compressor 144 and exits the system as residue gas.
The condensed liquid portion exits cold separator 120 as liquid bottoms stream 124. While liquid bottoms stream 124 will generally comprise mostly methane and ethane (due to large amount of methane and ethane in natural gas feed sources), there will be a larger mole fraction of propane and heavier hydrocarbons in liquid bottoms stream 124 than in vapor stream 122. Liquid bottoms stream 124 is passed through heat exchanger 114 to cool the portion of feed gas stream 110 being conducted through conduit 113 and then directed through expansion device 126. It will be appreciated that expansion device 126 may be located downstream of heat exchanger 114 (as shown in
Liquid bottoms stream 124 flashes into de-ethanizer 130 to separate the ethane and lighter hydrocarbons as de-ethanizer overhead 131 from the NGL liquid product 138 enriched with propane and heavier (C3+) hydrocarbons. De-ethanizer overhead 131 comprises primarily methane and ethane, although some amount of propane and heavier hydrocarbons are also present. Condenser 132 is configured to condense at least a portion of de-ethanizer overhead 131 (predominantly the propane and heavier hydrocarbons), and thus the stream leaving condenser 132 is generally a two-phase vapor-liquid mixture. The at least partially condensed overhead stream is then fed into reflux accumulator 134, which directs liquid portion of the overhead stream back to de-ethanizer 130 as reflux through pump 137 and valve 139 de-ethanizer reflux conduit 133. The vapor portion leaves accumulator 134 as vapor stream 136 comprising predominantly methane and ethane, which will be combined with vapor stream 122 to form residue gas stream 142. However, vapor stream 136 exits accumulator 134 at a relatively low temperature and pressure (as compared to vapor stream 122 and standard natural gas transport conditions), and thus vapor stream 136 must be re-compressed. Therefore, vapor stream 136 is directed through compressor 140 to increase pressure prior to being combined with vapor stream 122. Compression of vapor stream 136 by compressor 140 accounts for significant energy consumption (operating cost) associated with the conventional LTS process. In certain embodiments, stream 136 may be warmed prior to being compressed, particularly when the volume of vapor stream 136 is particularly large.
A number of cryogenic technologies aimed at the recovery of propane and heavier components from a feed gas are known in the art. These technologies use various two-tower configurations to supply reflux liquid from a downstream de-ethanizer tower to an upstream absorber tower to achieve high propane recovery levels. As referenced herein, cryogenic hydrocarbon recovery technologies (particularly technologies for the recovery of propane and heavier components from a feed gas) are recognized in the art as technologies that utilize operating temperatures of about −100° F. or lower in one or more of the processes. Cryogenic operating temperatures are typically achieved using expansion cooling, mechanical refrigeration, or a combination of both. One such cryogenic process is shown in U.S. Patent Application Publication No. 2012/0000245 (“the '245 publication”).
A condensed liquid exits absorber 220 as liquid bottoms stream 124. Liquid bottoms stream 124 is passed through heat exchanger 114 and used to cool a portion of feed stream 110 being conducted via conduit 113. After exiting heat exchanger 114, liquid bottoms stream 124 is flashed through expansion device 126 and fed into de-ethanizer 130.
De-ethanizer 130 operates similarly in the cryogenic prior art process as in the conventional LTS process insofar as ethane is to be rejected from the liquid product stream. However, a portion of the condensed liquid exiting reflux accumulator 134 is subcooled and recycled back and fed directly to absorber 220. De-ethanizer overhead 131 is at least partially condensed in condenser 132, and the at least partially condensed overhead stream is fed into reflux accumulator 134. The vapor portion leaves accumulator 134 as vapor stream 136, which is compressed in compressor 140 and ultimately exits the system as residue or sales gas. A first portion 133 of the liquid exiting reflux accumulator 134 is directed back to de-ethanizer 130 as reflux through pump 137 and valve 139 via de-ethanizer reflux conduit 133, while a second portion is subcooled in exchanger 250, directed through valve 239, and recycled back directly into absorber 220, via recycle conduit 234, to be used as reflux.
The liquid in recycle conduit 234 is fed to an upper portion of absorber 220 to reduce the content of propane and heavier components in the overhead vapor stream. As the liquid in recycle conduit 234 enters absorber 220, a portion of the stream is vaporized and provides cooling in absorber 220 such that the overhead vapor is colder than any of the feeds to absorber 220 and is typically the coldest stream within the process. As a result, the overhead vapor portion recovered from absorber 220 as cooled vapor stream 224 is directed through heat exchangers 250 and 112 to provide subcooling for the absorber reflux liquid of stream in conduit 234 and to provide the initial cooling of the portion of feed stream 110 being conducted through conduit 111. After exiting heat exchanger 112, vapor stream 224 may be compressed as required and combined with compressed vapor stream 136 prior to exiting the system as residue gas or as a natural gas product.
During periods of low NGL prices, when the capital investment and operating expenses associated with cryogenic operation may not economically justify high recovery levels, it is desirable to adjust the operating conditions within the system to only recover sufficient NGL to meet residue gas specifications. Embodiments of the inventive, enhanced LTS process are directed to a low cost alternative, which meets residue gas specification requirements, while operating at substantially lower costs than conventional LTS or cryogenic processes.
One embodiment of the enhanced LTS process in accordance with the present invention is shown in
The portion of feed stream 110 being conducted via conduit 113 can be used to provide some or all of the thermal energy necessary for reboiler 222 of absorber 220. Heat exchange occurring in reboiler 222 provides further cooling to the portion of feed stream in conduit 113, as well as heating to the bottoms portion of absorber 220. Heating the bottoms portion of absorber 220 reduces the content of lighter hydrocarbons contained in the stream and reduces the stream 124 volume, reducing the size of equipment located downstream
Absorber overhead stream 224 exits absorber 220 as a vapor stream comprising predominantly methane and ethane, although some amount of propane and heavier hydrocarbons are also present. A condensed liquid exits absorber 220 as liquid bottoms stream 124. As a result of the warmer operating temperature of absorber 220 as compared to prior art processes, liquid bottoms stream 124 is significantly warmer than in prior art processes. In certain embodiments, the temperature of liquid bottoms stream 124 is greater than about 35° F., preferably greater than about 45° F., more preferably greater than about 55° F., and most preferably greater than about 60° F. The absorber and related streams operate at relatively higher pressures than prior art cryogenic processes. For example, in certain embodiments the absorbers operates at greater than about 400 pisa, preferably greater than about 600 psia, more preferably greater than about 700 psia, and most preferably greater than about 800 psia. Despite the warmer temperatures, liquid bottoms stream 124 may still be passed through heat exchanger 114 and used to cool a portion of feed stream 110 being conducted via conduit 113.
After exiting heat exchanger 114, liquid bottoms stream 124 is flashed through expansion device 126 and fed into de-ethanizer 130. Similar to the conventional process, in certain embodiments, expansion device 126 is located downstream of heat exchanger 114 (as shown in
De-ethanizer 130 operates similarly in the enhanced LTS process as in the conventional and prior art cryogenic process insofar as ethane is rejected from the product stream. However, in the enhanced LTS process of the present invention, a portion of the condensed liquid exiting reflux accumulator 134 is recycled back and combined with overhead vapor stream 224, rather than directly to absorber 220. De-ethanizer overhead 131 is at least partially condensed in condenser 132, and the at least partially condensed overhead stream is fed into reflux accumulator 134. In some embodiments, however, de-ethanizer overhead 131 is entirely condensed in condenser 132. In embodiments where the overhead is partially condensed, the vapor portion leaves accumulator 134 as vapor stream 136, which is compressed in compressor 140 and ultimately exits the system as residue or sales gas. As a result of the warmer absorber feed and incorporation of an absorber reboiler, a greater amount of ethane and lighter compounds are removed from the liquid stream before being fed to de-ethanizer 130, and thus the flow of vapor stream 136 is significantly less than the conventional LTS or cryogenic processes. The significantly lower flow of vapor stream 136 provides a lower amount of vapor material flowing through compressor 140 compared to prior art processes, which decreases the amount of power (and cost) required to operate compressor 140. In certain embodiments in accordance with the present invention, a first portion of the liquid exiting reflux accumulator 134 is directed back to de-ethanizer 130 as reflux via de-ethanizer reflux conduit 133, while a second portion is recycled back and combined with vapor stream 224 to supplement the reflux of absorber 220 via recycle conduit 234.
The liquid in recycle conduit 234 is combined with absorber overhead vapor stream 224 to form two-phase recycle stream 335. Increased separation in absorber 220 is achieved by further condensing a portion of recycle stream 335 in chiller 326 to be used as reflux for absorber 220. In another embodiment of the present invention, the liquid in recycle conduit 234 may be combined with absorber overhead vapor stream 224 downstream of chiller 326. Advantageously, the required refrigerant compressor costs associated with the cooling in chiller 326 is lower than in chiller 116 (of the conventional LTS process), as there is a smaller temperature difference and less mass flow needed to cool in chiller 326 than in chiller 116. After exiting chiller 326, recycle stream 335 is directed into reflux accumulator 328, where the condensed liquid portion of recycle stream 335 is separated from the vapor portion. The vapor portion exits reflux accumulator 328 as cooled vapor stream 122 and is directed through heat exchanger 112 to provide cooling for the portion of feed stream 110 being conducted through conduit 111. After exiting heat exchanger 112, vapor stream 322 is combined with compressed vapor stream 136 and exits the system as residue gas or as a natural gas product.
The condensed liquid portion of recycle stream 335 exits reflux accumulator 328 as reflux stream 329 and is directed back into absorber 220. With final cooling of chiller 326 located downstream of absorber 220, stream 115 is fed to absorber 220 at much warmer temperatures and absorber 220 operates at much warmer temperatures than prior art processes. This causes a greater amount of both lighter components (e.g., ethane, methane) and heavier components (e.g., propane, butane) to be ejected in overhead vapor stream 224. The greater amount of heavier components in overhead vapor stream 224 causes the volume of reflux stream 329 to be much greater than absorber reflux streams of prior art cryogenic processes, which results in improved recovery of the butane and heavier components.
The enhanced LTS process in accordance with the present invention may be used in an LTS plant and advantageously provides increased selectivity in recovery of valuable NGL products (i.e., butane and heavier hydrocarbons) while reducing operating costs. The process is capable of producing an NGL liquid product stream comprising at least about 90 mol %, preferably at least about 95 mol %, and more preferably at least about 98 mol % propane and heavier hydrocarbons. The residue gas produced by the process comprises at least about 80 mol %, preferably at least about 90 mol %, and more preferably at least about 95 mol % ethane and lighter hydrocarbons. The enhanced LTS process reduces operating costs by using an absorber rather than a condenser/cold separator combination to achieve adequate initial separation of the lighter natural gas products from the heavier NGL products. Thus, the enhanced LTS process requires less external cooling of the feed stream and therefore less refrigerant compression costs. Use of the absorber and reflux recycling in the enhanced LTS process also results in a decrease of natural gas products requiring separation by de-ethanizer 130, and ultimately a significantly decreased molar flow rate of vapor stream 136 being directed through compressor 140. As less compression is required by compressor 140, there are reduced operating costs associated with this relatively high-cost process step.
The following examples set forth LTS process simulations prepared using Aspen HYSYS software by AspenTech. These examples provide more detail regarding specific stream and operating conditions of the conventional LTS, prior art cryogenic, and enhanced LTS processes generally described above. It is to be understood, however, that these examples are provided by way of illustration and nothing therein should be taken as a limitation upon the overall scope of the invention.
In this example, there is provided a process simulation of a conventional LTS process such as the process shown in
Details regarding the stream conditions and equipment operating conditions resulting from a process simulation using the conventional LTS process are provided below:
In this example, there is provided a process simulation of a prior art cryogenic process such as the process shown in
In this example, there is provided a process simulation of an enhanced LTS process in accordance with the present invention, such as the process shown in
Therefore, the enhanced LTS process provides the highest butane recovery levels while requiring 22% less total compression power than the conventional LTS process and 3.5% less than the prior art cryogenic process. Further, the feed flow to the de-ethanizer in stream 124 is 33% lower than the conventional LTS process and 15% lower than the prior art cryogenic process, allowing for smaller piping and equipment sizes.
Details regarding the stream conditions and equipment operating conditions resulting from a process simulation using the enhanced LTS process are provided below:
This application claims the benefit of U.S. Provisional Patent Application No. 62/248,148, filed Oct. 29, 2015, which is incorporated by reference herein in its entirety.
| Number | Name | Date | Kind |
|---|---|---|---|
| 2547970 | Phillips et al. | Apr 1951 | A |
| 4171964 | Campbell et al. | Oct 1979 | A |
| 4251249 | Gulsby | Feb 1981 | A |
| 4509967 | Sweet | Apr 1985 | A |
| 5035732 | McCue, Jr. | Jul 1991 | A |
| 5685170 | Sorensen | Nov 1997 | A |
| 6601406 | Deng et al. | Aug 2003 | B1 |
| 20040025535 | Mak | Feb 2004 | A1 |
| 20050204774 | Foglietta et al. | Sep 2005 | A1 |
| 20070219401 | Duc | Sep 2007 | A1 |
| 20070284286 | Duhon et al. | Dec 2007 | A1 |
| 20090173103 | Mak | Jul 2009 | A1 |
| 20120000245 | Currence et al. | Jan 2012 | A1 |
| 20120267137 | Raasch | Oct 2012 | A1 |
| 20140075987 | Mak | Mar 2014 | A1 |
| 20140187840 | Fan et al. | Jul 2014 | A1 |
| 20140260420 | Mak | Sep 2014 | A1 |
| 20150025292 | Pham Duc et al. | Jan 2015 | A1 |
| 20150153101 | Gahier | Jun 2015 | A1 |
| Number | Date | Country |
|---|---|---|
| 101445419 | Oct 2012 | CN |
| 102009038456 | Mar 2011 | DE |
| 2341738 | Dec 2008 | RU |
| 2493898 | Sep 2013 | RU |
| Entry |
|---|
| Mowrey, E. Ross, “Efficient, High Recovery of Liquids From Natural Gas Utilizing a High Pressure Absorber” Lummus Process Technology—Randall Gas Technologies, 2003. |
| Search Report and Written Opinion dated Feb. 3, 2017, in PCT/US2016/059259 filed Oct. 28, 2016. |
| Number | Date | Country | |
|---|---|---|---|
| 20170122658 A1 | May 2017 | US |
| Number | Date | Country | |
|---|---|---|---|
| 62248148 | Oct 2015 | US |
