The present disclosure relates generally to erasure fluids.
Inkjet printing is an effective way of producing images on a print medium, such as paper. Inkjet printing generally involves ejecting ink droplets (formed, e.g., from one or more inks) from a nozzle at high speed by an inkjet printing system onto the paper to produce the images thereon. In some instances, it may be difficult to effectively erase the inkjet ink(s) in the solid state, such as when the inks are established on the paper.
Features and advantages of examples of the present disclosure will become apparent by reference to the following detailed description and drawings.
Example(s) of the erasure fluid as disclosed herein may advantageously be used in a process designed to erase an inkjet image from the surface of a medium. The erasure fluid is specifically formulated to interact with a particular erasable inkjet ink used to form the image on the surface of the medium. It is believed that when the erasure fluid effectively interacts with the inkjet ink, the colorant of the inkjet ink degrades. It is further believed that the degradation of the colorant causes the image to disappear from the surface of the medium. In an example, about 80% to about 100% of the image may be erased via an erasing process utilizing examples of the erasure fluid disclosed herein.
The inventor of the present disclosure has found that when examples of the erasure fluid interact with examples of the erasable inkjet ink, images formed by the erasable inkjet ink are erased in a relatively “human-friendly” and “environment-friendly” manner. This may be due, at least in part, to the fact that the examples of the erasable inkjet ink and the examples of the erasure fluid are specifically formulated to include human-friendly and environment-friendly components. It is to be understood that as used herein, the terms “human-friendly” or the like and “environment-friendly” or the like are generally defined as components: listed as Generally Recognized As Safe (GRAS) by the United States Food and Drug Administration (FDA); complying with the FDA's Federal Food, Drug and Cosmetic Act (FFDCA); appearing in the United States Environmental Protection Agency's (EPA) CleanGredients® list; and/or appearing in similar lists; and/or categorized in a similar manner. Examples of the erasable inkjet ink may be found in PCT International Application Serial No. PCT/US11139023 filed concurrently herewith, which Is incorporated by reference herein in its entirety. Examples of the erasure fluid specifically designed to interact with the examples of the erasable inkjet ink will be described in detail below.
It is to be understood that the examples of the erasure fluid described herein are tied, at least in part, to the nature of the colorant(s) of the erasable Inkjet ink used to create the image on the medium. For example, certain colorants have been found to be more erasable than others; and thus a lower concentration of the component(s) responsible for causing the degradation of the colorant(s) in the erasure fluid (referred to herein as “erasure component(s)”) may be required to effectively erase the image from the medium during the erasing process. Further, certain colorant(s) of the inkjet ink may be more responsive to one particular erasure component, while other(s) may be more responsive to another particular erasure component. Accordingly, several different examples of the erasure fluid may be formulated, where each may be specifically designed to be used to erase a particular erasable inkjet ink (i.e., an ink that includes a colorant that is responsive to the erasure component of the erasure fluid).
It is further to be understood that examples of the erasure fluid are designed to erase the image from a medium such as paper. The paper may be chosen from any cellulose-based paper, i.e., paper that includes cellulose fibers. For instance, the medium may be made from pulp fibers derived from hardwood trees (e.g., deciduous trees (angiosperms) such as birch, oak, beech, maple, and eucalyptus) and/or softwood trees (e.g., coniferous trees (gymnosperms) such as varieties of fir, spruce, and pine, (e.g., loblolly pine, slash pine, Colorado spruce, balsam fir and Douglas fir)), and these pulps may be prepared via any known pulping process. Further, the cellulose-based paper may include one or more fillers to control the physical properties of the medium. Examples of fillers include ground calcium carbonate, precipitated calcium carbonate, titanium dioxide, kaolin clay, silicates, and combinations thereof. It is to be understood that the cellulose-based paper may be referred to herein as plain paper.
Other examples of the paper medium include resin-coated papers (such as, e.g., photobase paper) and papers made from or including polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), polylactic acid (PLA), and/or the like, and/or combinations thereof.
In another example, the medium may be chosen from COLORLOK® papers (available from Hewlett-Packard, Co., Houston, Tex.), which are plain papers having calcium chloride incorporated in the paper structure.
Examples of the erasure fluid will now be described herein. It is to be understood that each of these examples include a vehicle and at least an erasure component incorporated into the vehicle. As used herein, the term “vehicle” refers to the combination of at least one or more solvents to form a vehicle within which the erasure component is incorporated to form the erasure fluid. In some examples, the vehicle may also include an additive, which is a constituent of the fluid that may operate to enhance performance, environmental effects, aesthetic effects, or other similar properties of the erasure fluid. Examples of the additive include surfactants, pH buffers, biocides, and/or the like, and/or combinations thereof. In other examples, the vehicle does not include an additive.
As previously mentioned, the vehicle includes at least one solvent, which is/are used as a carrier for the erasure component and may, in some examples, constitute the bulk of the erasure fluid. In an example, the solvent is chosen from 1,2-propanediol, glycerol, tetraethylene glycol, sorbitol, and combinations thereof. The solvent(s) may be present in an amount ranging from about 1 wt % to about 50 wt % of the erasure fluid. In another example, the solvent(s) is/are present in an amount ranging from about 1 wt % to about 25 wt %. In still another example, the solvent(s) is/are present in an amount ranging from about 10 wt % to about 25 wt % of the erasing fluid.
In one example, the solvent is chosen from a combination of 1,2-propanediol and glycerol, where the 1,2-propanediol is present in an amount ranging from about 1 wt % to about 25 wt % of the erasure fluid, and the glycerol is present in an amount ranging from about 1 wt % to about 25 wt %. In another example, the 1,2-propanediol and the glycerol are each present in an amount ranging from about 5 wt % to about 15 wt % of the erasure fluid; and in still another example, each are present in an amount ranging from about 5 wt % to about 10 wt % of the erasure fluid. Further, tetraethylene glycol, if used as a solvent in the vehicle, may be present in the erasure fluid in an amount ranging from about 1 wt % to about 25 wt %; and in another example, ranges from about 5 wt % to about 15 wt % of the erasure fluid. In still another example, the tetraethylene glycol may be present in an amount ranging from 5 wt % to about 10 wt %.
In an example, the vehicle may also include a surfactant that may be used, in part, as a wetting agent to wet the surface of the device (e.g., a roll coater) that may be used to apply the erasure fluid to the image formed on the medium. In this respect, the surfactant is chosen from a non-hydrophobic material. Further, the surfactant may also be incorporated into the erasure fluid to facilitate the removal of the colorant of the erasable inkjet ink from the medium (e.g., from fibers of plain papers or coated papers). In this respect, the surfactant is also chosen from a group of surfactants that may contribute to the removal of the colorant from the fibers of the medium. Examples of the surfactant that may be incorporated into the vehicle include the surfactants of the SURFYNOL® family (such as SURFYNOL® 465, available from Air Products, Inc., Lehigh Valley, Pa.), the surfactants of the TERGITOL® family (available from the Dow Chemical Co., Midland, Mich.), SILWET® 7602 (available from Momentive Performance Materials, Albany, N.Y.), and combinations thereof. The surfactant(s), if used in the erasure fluid, may be present in the erasure fluid an amount ranging from about 0.1 wt % to about 5 wt % of the erasure fluid. In another example, the surfactant(s) may be present in an amount ranging from about 0.1 wt % to about 1 wt %.
In another example, a biocide such as PROXEL® GXL (available from Arch Chemicals, Inc., Norwalk, Conn.), may be added to the erasure fluid to protect the fluid from bacterial growth. The amount of the biocide present in the erasure fluid, if one is incorporated, ranges from about 0.05 wt % to about 1 wt %.
Further, a pH buffer may also be incorporated into the vehicle, some examples of which include 3-(N-morpholino)propanesulfonic acid (MOPS), 3-morpholino-2-hydroxy-propanesulfonic acid (MOPSO), 1,4-piperazinediethanesulfonic acid (PIPES), tris(hydroxymethyl)aminomethane (TRIS), and/or other similar biological buffers. Other examples of buffers include inorganic buffers such as sodium acetate, sodium phosphate, and/or sodium borate.
As previously mentioned, the erasure component of the erasure fluid is specifically chosen to interact with a particular colorant of the erasable inkjet ink used to form the image on the medium. It is believed that the interaction of the erasure component with the colorant causes the inkjet ink (and thus the image) established on the medium to disappear. More specifically, when the erasure fluid is applied to the inkjet ink (i.e., the image) on the medium during the erasing process, the colorant of the ink (which may include a component that acts as a catalyst for the reaction) triggers a chemical reaction between the colorant and the erasure component. This chemical reaction causes the colorant to degrade, and when this occurs, the ink substantially completely disappears from the surface of the medium, at which time the image is considered to be erased.
As used herein, an ink “substantially completely disappears” from the medium when there is no image on the medium that is noticeable or otherwise decipherable by the human eye. For instance, an ink substantially completely disappears from the medium when about 80% to about 100% of the ink disappears. The amount of ink erased may be determined by visual perception and/or by measuring the optical density or LAB coordinates between the original and erased sample. The optical density or LAB coordinates may be measured with a densitometer. For example, 90% ink disappearing (as used herein) means that 10% of the optical density remains on the erased page.
It is to be understood that the amount (e.g., percentage) of the ink remaining after erasing depends, at least in part, on the amount of the erasure fluid applied, the chemistry of the ink, or combinations thereof. Details of the chemical interaction that occurs between the colorant and the erasure component during erasing may be found in PCT International Application Serial No. PCT/US11/39025 filed concurrently herewith, which is incorporated by reference herein in its entirety.
In one example, the erasure component may be chosen from an oxidant/reductant that effectively interacts with the colorant of the erasable ink. Certain oxidants/reductants (such as, e.g., peroxides) may effectively interact with the colorant in the presence of oxygen molecules. It is believed that a degassed colorant (i.e., where no oxygen molecules are present) may be nonreactive, or have a very slow reaction rate when the colorant comes into contact with the erasure component. In an example, the oxygen molecules may come from air present in the surrounding environment within which the erasing process is being performed, or may be supplied to the medium (e.g., from an oxygen supply) during the erasing process.
Examples of oxidants/reductants that may be used for the erasure component include persulfate ions (e.g., from sodium persulfate, potassium persulfate, lithium persulfate, etc.), peroxymonosulfate ions (e.g., from sodium peroxymonosulfate, potassium peroxymonosulfate, lithium peroxymonosulfate, etc.), hydrogen peroxide, chlorate ions (e.g., from sodium chlorate, potassium chlorate, etc.), hypochlorite ions (e.g., from sodium hypochlorite, potassium hypochlorite, etc.), sodium ascorbate, and ascorbic acid.
As previously mentioned, the concentration of the erasure component depends, at least in part, on the erasability of the colorant and on desired environmental levels. For instance, it may be desirable to maintain the concentration level of the oxidants/reductants to a value at or below 3 wt % to achieve the desired erasability of the ink and desired environmental levels, though lower concentration levels may also be used. It is to be understood, however, that the lower concentration level may affect the erasability of the ink. For instance, a concentration of the oxidants/reductants of about 1 wt % may result in a 30% to 50% drop in the erasability of the ink. It may also be possible to increase the concentration of the oxidants/reductants to an amount above 3 wt % (such as, e.g., 5 wt %), but this may, in some instances, deleteriously affect the medium upon which the ink was printed. One way of achieving a higher erasability without using an oxidant/reductant concentration level higher than 3 wt % includes applying, during the erasing process, the erasure fluid having the lower concentration of oxidants/reductants two or more times.
Despite the adjustability of the concentration of the erasure component depending on the colorant of the inkjet ink, the erasure component concentration still falls within a preset range. In an example, if the oxidant/reductant is chosen from persulfate ions, peroxymonosulfate ions, hydrogen peroxide, chlorate ions, and hypochlorite ions, the concentration of the oxidant/reductant ranges from about 0.25 wt % to about 6 wt % of the erasure fluid. In another example, the hydrogen peroxide is present in an amount ranging from about 2 wt % to about 4 wt % of the erasure fluid; and in yet another example, is present in an amount of about 3 wt %. The persulfate ions, peroxymonosulfate ions, chlorite ions, and hypochlorite ions may be present in an amount ranging from about 1 wt % to about 3 wt % of the erasure fluid; and in yet another example, are present in an amount of about 1 wt %. Furthermore, the ascorbic acid may be present in an amount ranging from about 1 wt % to about 10 wt %; in another example, is present in an amount ranging from about 2 wt % to about 5 wt %; and in yet another example, is present in an amount of about 4 wt %.
It is believed that the oxidants/reductants identified above may, in some cases, require a catalyst to facilitate the chemical reaction between the erasure component and the colorant of the erasable inkjet ink. For example, the ferrous ion (Fe+2) (which may come from an iron ascorbate colorant (which is a dark, violet colorant) of the inkjet ink) may be used to catalyze a reaction between hydrogen peroxide and the iron ascorbate colorant to degrade the iron ascorbate colorant and erase the image formed by the ink from the surface of the medium. In this example, the iron ascorbate acts as both a colorant for the inkjet ink and as the catalyst for its own degradation during the erasing.
It is to be understood that other catalysts may be used to facilitate the reaction between the colorant and the erasure component, and these other catalysts may not necessarily be part of the colorant itself. Examples of other catalysts that may be used include manganese ions, cobalt ions, copper ions, and/or zinc ions. In an example, the other catalyst may be incorporated into the medium upon which the inkjet ink is established to form the image. For instance, sodium peroxymonosulfate may be activated by a chloride ion (Cl−) already present in certain coated papers, such as COLORLOK® papers (available from Hewlett-Packard Co., Houston, Tex.) to form the hypochlorite ion. It is believed that the hypochlorite ion then reacts with, and degrades many, if not all, of the colorants of the erasable inkjet ink disclosed in PCT International Application Ser. No. PCT/US11/39023 mentioned above.
The erasure component may also or otherwise be chosen from a chelating agent, and this erasure component is useful for erasing inkjet inks containing ionically-complexed colorants that tend to have a stronger tendency to form an ion than to form a color-forming ligand. An example of such a colorant is an ionically-complexed colorant containing iron, for instance, iron ascorbate. Examples of chelating agents that may be used as the erasure component include citric acid, gluconic acid, sodium phosphate, sodium bicarbonate, ethylenediamine tetraacetic acid (EDTA), and combinations thereof. In an example, the chelating agent is present in an amount ranging from about 1 wt % to about 10 wt % of the erasure fluid. In another example, the citric acid, gluconic acid, sodium phosphate, and sodium bicarbonate (individually or in combinations thereof) may be present in an amount ranging from about 1 wt % to about 10 wt % of the erasure fluid; in another example, ranging from about 2 wt % to about 5 wt %; and in still another example, is about 4 wt %. EDTA may, for example, be present in an amount ranging from about 1 wt % to about 4 wt %; and in another example, from about 1 wt % to about 2 wt % of the erasure fluid.
In an example, the erasure fluid may further contain a polymer having a viscosity greater than 10 cP, which may allow the erasure fluid to be applied via roll coating or other non-inkjet printing methods. It is believed that the use of a polymer having a large viscosity (i.e., a viscosity larger than 10 cP) in the erasure fluid allows the fluid to stay on the surface of the medium when the fluid is applied thereto during the erasing process. In another example, the erasure fluid may further contain a polymer having a viscosity less than 10 cP, which may allow the erasure fluid to be jetted from an inkjet printhead. It is further believed that the polymer also contributes to the efficiency of the erasing process compared to water in the fibers of the paper (which may render the medium as reactive for certain reactants).
Examples of polymers that may be incorporated into the erasure fluid (e.g., into the vehicle) include carboxymethylcelluloses having a weight average molecular weight ranging from 90,000 to 1,000,000 (which has a viscosity ranging from less than about 10 cP to about 2,000 cP, depending, at least in part, on the amount of polymer added), methyl celluloses (such as, e.g., methyl hydroxyethyl ether cellulose, which can achieve viscosities ranging from less than about 10 cP to greater than about 1000 cP, again depending on the amount of the polymer added), polyethylene glycols having a weight average molecular weight of 1,000 to 20,000 (which has a viscosity ranging from about 5 cP to about 100 cP, yet again depending on the amount of the polymer added), guar gum (which has a viscosity ranging from about 100 cP to about 1000 cP, still again depending on the amount of the polymer added), starches (such as, e.g., rice starch, which has a viscosity ranging from less than about 10 cP to about 150 cP, again depending on the amount of the polymer added), and combinations thereof. Sugar components (such as, e.g., sorbitol, mannitol, and other related glycogens, which have a viscosity lower than about 5 cP) may also be added to the polymers, and are capable of interacting with the polymer(s) to increase the viscosity.
It is to be understood that the concentration of the polymer in the erasure fluid depends, at least in part, on the polymer chosen to be incorporated into the fluid. For instance, carboxymethylcelluloses and methyl hydroxyethyl ether cellulose may be present in an amount ranging from about 0.10 wt % to about 6 wt % of the erasure fluid; in another example, ranging from about 0.25 wt % to about 3 wt %; and in yet another example, ranging from about 1 wt % to about 2 wt %. The polyethylene glycols may be present in an amount ranging from about 1 wt % to about 20 wt % of the erasure fluid; in another example, ranging from about 5 wt % to about 15 wt %; and in still another example, ranging from about 10 wt % to about 15 wt %. Rice starch may be present in an amount ranging from about 1 wt % to about 10 wt % of the erasure fluid; in another example, ranging from about 2 wt % to about 6 wt %; and in yet another example, ranging from about 2 wt % to about 4 wt %. Sorbitol, for example, may be present in an amount ranging from about 1 wt % to about 20 wt % of the erasure fluid; in another example, ranging from about 2 wt % to about 10 wt %; and in yet another example, is about 5 wt %. Guar gum may be present in an amount ranging from about 1 wt % to about 3 wt %. The sugar(s) may be present in an amount ranging from about 3 wt % to about 20 wt %; and in another example, ranging from about 5 wt % to about 10 wt % of the erasure fluid.
In an example, the balance of the erasure fluid is water.
Additionally, the inventor has found that the concentration of the solvent in the erasure fluid may contribute to the integrity of the medium, e.g., with respect to curl, cockle, reliability, and durability. Further, the polymers may impart a stiffening effect to the medium, which may balance the oily effect of the solvents used in the erasure fluid after repeated erasing cycles. Improvements in curl, for example, may be accomplished by balancing the amount of curl obtained with anti-curl solvents (e.g., 1,2-propanediol, glycerol, and tetraethylene glycol) and polymers of the erasure fluid with the amount of solvent absorbed by the medium during repeated printing and erasing cycles.
In some cases, the solvent absorbed by the medium after repeated cycles of printing and erasing increases, which may cause the medium to have an oily or greasy feel. In one example, a curl-to-oil balance may be achieved with a solvent concentration ranging from about 10 wt % to about 30 wt % of the erasure fluid. In another example, the curl-to-oil balance may be achieved with a solvent concentration ranging from about 15 wt % to about 30 wt % of the erasure fluid; and in yet another example, a solvent concentration ranging from about 20 wt % to about 30 wt %. It is also believed that the application of the erasure fluid is substantially even (i.e., a substantially even amount of the fluid is coated across the surface of the medium), which may also contribute to an improvement in curl.
It is further believed that cockle may be managed by using appropriate solvents in the erasure fluid, and the durability/reliability of the medium may be managed by using the least amount of erasure fluid as possible to effectively erase the ink from the medium. In an example, the amount of the erasure fluid may be minimized by formulating the erasure fluid to perform more effectively when erasing the ink. For instance, effective performance of the erasure fluid may be achieved by increasing the viscosity of the erasing fluid (e.g., by adding higher viscosity polymer(s) to the fluid) so that the erasure fluid remains on the surface of the medium when applied thereto (noting, however, that if the erasure fluid is to be applied via inkjet printing, the viscosity of the erasure fluid should generally be less than about 10 cP).
It is to be understood that the effectiveness of the erasure fluid depends, at least in part, on certain variables of the fluid in addition to the erasure component selected, such as, e.g., the pH of the fluid. In an example, the pH of the erasure fluid should fall within a predefined range in order for the erasure component to effectively interact with a particular colorant of the inkjet ink. This is true, at least in part, because the chemical reaction that takes place between the colorant of the ink and the erasure component depends, at least in part, on the pH of the reacting medium. In some instances, it is desirable to maintain the pH of the erasure fluid above 4, whereas in other instances, a lower pH (such as 3 or lower) is also effective, for example, for applications other than for removing an inkjet ink from paper such as, e.g., in industrial applications that use non-paper substrates that can tolerate the lower pH values.
As one example, an erasure fluid containing hydrogen peroxide, persulfate ions, peroxymonosulfate ions, chlorite ions, or hypochlorite ions, should be formulated to have a pH ranging from about 2 to about 8; in another example, a pH ranging from about 4 to about 7.5; and in yet another example, a pH ranging from about 5 to about 7. An erasure fluid containing ascorbic acid should be formulated to have a pH ranging from about 3 to about 8; in another example, a pH ranging from about 4 to about 7.5; and in yet another example, a pH ranging from about 4 to about 6. Further, an erasure fluid containing citric acid should be formulated to have a pH ranging from about 3 to about 8; in another example, a pH ranging from about 4 to about 7; and in yet another example, a pH ranging from about 4 to about 5. Additionally, an erasure fluid containing gluconic acid should be formulated to have a pH ranging from about 4 to about 9; in another example, a pH ranging from about 6 to about 9; and in still another example, a pH ranging from about 7 to about 9.
Some specific example formulations of the erasure fluid are provided in Tables 1 through 5 below. It is to be understood that water makes up the balance of each of the formulations below.
An example of a method of making the erasure fluid involves forming a vehicle including at least a solvent, and adding an erasure component to the vehicle. More specifically, the erasure component is selected from the group of erasure components identified above based, at least in part, on the colorant of the erasable inkjet ink previously established or otherwise printed on the medium. In some cases, other components may be added to the vehicle, such as polymers, surfactants, and/or other additives mentioned above.
The erasure fluid may, in an example, be applied to the image formed on the medium using an inkjet printing process (e.g., thermal inkjet printing or piezoelectric inkjet printing). For instance, the erasure fluid may be packaged in an ink chamber, and then incorporated into a printing system. In some instances, the erasure fluid may be part of an ink set, e.g., where a single erasure fluid may be designed and used to erase any of the colored inks included in the ink set. It is also contemplated to incorporate more than one erasure fluid into the ink set, e.g., if a particular erasure fluid is required to erase a particular ink of the ink set. The erasure fluid may otherwise stand alone as a component of the printing system that is separate from the ink(s). In an example, the medium having the image formed thereon may be fed into the printing system, and droplets of the erasure fluid may be ejected from nozzles of the printing system and deposited onto the image.
In another example, the erasure fluid may be applied to the image formed on the medium as a post-processing coating process. For instance, the medium having the image formed thereon, may be fed into a post-processing coating apparatus, such as, e.g., a roll coater, and the erasure fluid may be applied to the medium as the medium passes through the roll coater. This roll coating apparatus may be incorporated into, or be separate from the printing system. It is to be understood that applying the erasure fluid during a post-coating process may allow the erasure fluid to contain additional additives that otherwise would not be included if the fluid was ejected using an inkjet printing system, at least in part because the additional additives may not be ink-jettable.
For instance, the erasure fluid may contain additional additives that improve curl, cockle, reliability, and durability of the medium such as, e.g., high molecular weight polymers (e.g., polymers having a weight average molecular weight that is greater than about 25,000) at concentrations greater than about 0.5 wt %, which may increase the viscosity of the erasure fluid to a value that is greater than about 10 cP (which viscosity is such that the fluid cannot effectively be printed from an inkjet pen). The erasure fluid may also or otherwise include a larger solids content (e.g., greater than about 10 wt %) in cases where the erasure fluid is applied to the medium by means other than by an inkjet pen.
To further illustrate the present disclosure, examples are given herein. It is to be understood that these examples are provided for illustrative purposes and are not to be construed as limiting the scope of the disclosure. It is to be understood that the recitation of weight percents (wt %) herein is with respect to the total weight of the respective formulation (i.e., the erasable inkjet ink or the erasure fluid).
The images formed on the paper in
The amount (%) of ink removed from the medium was determined by measurement with a densitomer. In this Example, given the color of the ink was yellow, the B* coordinate from the LAB space (B* would most directly correspond to yellow) was measured. Based on this data, the amount of erased yellow ink was measured as about 90-92% in each of the blocks 100′-110′. Thus, about 8-10% of ink remained in each of the blocks 100′-110′ after five prints and five erasures.
The image was printed on the paper (as shown in
The paper having the image erased therefrom rested for another twenty-four hours, and then another image was reprinted onto the paper. This cycle was repeated on each side of the paper for a total of six printings (three for each side) and four erasings (two for each side). The result shown in
The image shown in
The paper having the image erased therefrom rested for another twenty-four hours, and then another image was reprinted onto the paper. This cycle was repeated on one side of the paper for a total of four printings and three erasings. The result shown in
It is to be understood that concentrations, amounts, and other numerical data have been presented herein in range format. It is to be understood that this range format is used merely for convenience and brevity and should be interpreted flexibly to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a weight range of about 2 wt % to about 50 wt % should be interpreted to include not only the explicitly recited concentration limits of about 2 wt % to about 50 wt %, but also to include individual concentrations such as 10 wt %, 20 wt %, 21.5 wt %, 35 wt %, etc., and sub-ranges such as 10 wt % to 40 wt %, 15 wt % to 25 wt %, etc. As a further example, a viscosity range of less than about 10 cP should be interpreted to include 9.9 cP, 8 cP, 5 cP, 1 cP, etc., and sub-ranges such as 1 cP to 8 cP, 2 cP to 6 cP, etc. Furthermore, when “about” is utilized to describe a value, this is meant to encompass minor variations (up to +/−5%) from the stated value.
It is further to be understood that, as used herein, the singular forms of the articles “a,” “an,” and “the” include plural references unless the content clearly indicates otherwise.
Additionally, the term “any of”, when used in conjunction with lists of components (e.g., solvents, additives, etc.) refers to one of the components included in the list alone or combinations of two or more components. For instance, the term “any of”, when used with reference to a polymer, includes i) a carboxymethylcellulose alone, ii) methyl cellulose alone, iii) guar gum alone, iv) starches alone, v) or combinations of two or more of these polymers.
While several examples have been described in detail, it will be apparent to those skilled in the art that the disclosed examples may be modified. Therefore, the foregoing description is not to be considered limiting.
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/US2011/039014 | 6/3/2011 | WO | 00 | 10/31/2013 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2012/166147 | 12/6/2012 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
2960558 | Marsal et al. | Nov 1960 | A |
3850831 | Hellsten | Nov 1974 | A |
4261799 | Anizan et al. | Apr 1981 | A |
4413266 | Aviram et al. | Nov 1983 | A |
4874537 | Peterson et al. | Oct 1989 | A |
4954174 | Imagawa | Sep 1990 | A |
4960464 | Chen | Oct 1990 | A |
5281358 | Urushibata et al. | Jan 1994 | A |
5507926 | Keller et al. | Apr 1996 | A |
5643409 | Hamaguchi et al. | Jul 1997 | A |
5691292 | Marshall | Nov 1997 | A |
5711791 | Croker et al. | Jan 1998 | A |
5852073 | Villiger et al. | Dec 1998 | A |
6013122 | Klitzman et al. | Jan 2000 | A |
6030519 | Keller et al. | Feb 2000 | A |
6096349 | Petri | Aug 2000 | A |
6110883 | Petri et al. | Aug 2000 | A |
6163673 | Shindo | Dec 2000 | A |
6436342 | Petri et al. | Aug 2002 | B1 |
6444021 | Weisbecker et al. | Sep 2002 | B1 |
6544601 | Kong | Apr 2003 | B1 |
6783657 | Marsh et al. | Aug 2004 | B2 |
6905539 | Patel et al. | Jun 2005 | B2 |
7192335 | Lee et al. | Mar 2007 | B2 |
7192911 | Sunder et al. | Mar 2007 | B2 |
7767057 | Rosencrance et al. | Aug 2010 | B2 |
9315042 | Adamic | Apr 2016 | B2 |
20030119687 | Chikosi | Jun 2003 | A1 |
20040107505 | Harrison | Jun 2004 | A1 |
20040138084 | Gohl | Jul 2004 | A1 |
20040167048 | Sunder | Aug 2004 | A1 |
20040225032 | Spencer et al. | Nov 2004 | A1 |
20050003984 | Himmrich et al. | Jan 2005 | A1 |
20050019421 | Hobbs et al. | Jan 2005 | A1 |
20050119151 | Mayer | Jun 2005 | A1 |
20050143274 | Ghosh | Jun 2005 | A1 |
20050272622 | Hariharan | Dec 2005 | A1 |
20060034984 | Baydo et al. | Feb 2006 | A1 |
20060089281 | Gibson | Apr 2006 | A1 |
20060147717 | Hasegawa et al. | Jul 2006 | A1 |
20060281655 | Stehr | Dec 2006 | A1 |
20070022800 | Zifferer et al. | Feb 2007 | A1 |
20070049510 | Fujii et al. | Mar 2007 | A1 |
20070054827 | Cheung | Mar 2007 | A1 |
20070151945 | Miyamachi et al. | Jul 2007 | A1 |
20070159517 | Hashimoto et al. | Jul 2007 | A1 |
20070228005 | Hasegawa et al. | Oct 2007 | A1 |
20080193725 | De Saint-Romain | Aug 2008 | A1 |
20090143273 | Cheung | Jun 2009 | A1 |
20090165228 | Kilkenny | Jul 2009 | A1 |
20090258156 | Chretien et al. | Oct 2009 | A1 |
20090270304 | Cermenati | Oct 2009 | A1 |
20090325839 | Wortley et al. | Dec 2009 | A1 |
20100022427 | Warkotsch et al. | Jan 2010 | A1 |
20100123759 | Matsui et al. | May 2010 | A1 |
20100160201 | Scheuing | Jun 2010 | A1 |
20100234269 | Dreilinger | Sep 2010 | A1 |
20100273695 | Sehgal et al. | Oct 2010 | A1 |
20110150949 | Gonzales | Jun 2011 | A1 |
20110150950 | Gonzales et al. | Jun 2011 | A1 |
20120238005 | Wieland | Sep 2012 | A1 |
20130022556 | Gonzales et al. | Jan 2013 | A1 |
Number | Date | Country |
---|---|---|
0118004 | Sep 1984 | EP |
0446564 | Sep 1991 | EP |
0492224 | Jul 1992 | EP |
56-040577 | Apr 1981 | JP |
04-039100 | Feb 1992 | JP |
2000056497 | Feb 2000 | JP |
2000154345 | Jun 2000 | JP |
20090041874 | Apr 2009 | KR |
WO 03101753 | Dec 2003 | WO |
WO 2007005063 | Jan 2007 | WO |
WO2011032988 | Mar 2011 | WO |
Entry |
---|
Heinze, Jurgen, “Ultramicroelectrodes in Electrochemistry”, Angew. Chem. Int. Ed. Engl., 1993, 32, pp. 1268-1288. |
Number | Date | Country | |
---|---|---|---|
20140066348 A1 | Mar 2014 | US |