Patent Application
20150135582
The present invention relates to a compound. In particular the present invention relates to a composition containing the compound, compositions prepared with the compound and compositions and use of the compound and compositions as cold flow improvers.
When hydrocarbon based materials such as diesel fuel and heating oils are cooled to temperatures below their cloud points, paraffinic wax crystals form within the fuel. The now widespread practice of introducing fatty acid methyl esters (FAME) into hydrocarbon based materials such as diesel fuel can lead to additional crystal formation from saturated FAME. Without the addition of appropriate cold flow additives, these wax crystals can cause a number of problems.
At temperatures close to the cloud point, filter systems such as the fuel system filters in vehicle and static installations may rapidly become blocked. At only lower temperatures, an interlocking wax crystal structure forms that prevents flow within the filter and if applicable the fuel system (i.e. the cold filter plugging point is reached)
Cold flow improvers are added to hydrocarbon based materials which are subject to such problems. Cold flow improvers act by modifying the size and/or shape of wax crystals, which in turn reduces the tendency to block filters and lines, extend the temperature range over which the hydrocarbon based materials can be used and in the case of fuels extend the temperature range over which a vehicle can operate (as measured by CFPP and other cold flow performance tests), improves operability, reduces wax settling (particularly when used with a wax anti-settling additives), and/or lowers fuel pour point and improve fuel handling.
The increased use of biofuels such as biodiesels has placed further demands on the known cold flow improvers. Furthermore, there is a desire in markets generally to replace synthetic products with those derived from natural materials. Such food based materials are often considered by consumers to be more natural than complex synthetic materials.
As discussed in US2011/0232159 surfactants are commonly used at low concentrations in commercial biodiesel additive packages to modify the size and/or shape of the crystals formed. In US2011/0232159 a total of twelve purchased/commercial surfactants and five synthesised surfactants were assessed for inclusion in polymer/biodiesel formulations by DSC and CFPP at 1% w/w concentration in biodiesel. Many of the surfactants were reported not to dissolve well in biodiesel (without warming or the use of a solvent). The surfactants tested were classified into two groups: those that dissolved and those that did not. Polyglycerol polyricinoleic (PGPR) was disclosed as one possible surfactant and was said to be soluble in biodiesel. However sucrose myristate was disclosed as being selected for further investigation in biodiesel/petro diesel blends as it was said to lower the saturated enthalpy of crystallisation to a greater degree than the other cloud point-lowering surfactants.
The present invention addresses the problems of providing a cold flow improver which is effective in hydrocarbon based materials such as diesel fuel and/or heating oils, and in particular in biodiesel, and which may be prepared from source materials typically associated with the production of food products.
In one aspect the present invention provides a compound which is an ester of
(i) a polyol wherein the polyol is selected from at least pentaerythritol, polymers thereof and mixtures thereof; and
(ii) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation of from 2 to 7.
In one aspect the present invention provides a composition comprising
(a) a compound which is an ester of
and
(b) a citric acid ester of a monoglyceride
or
(c) a copolymer of ethylene and an alkyl acrylate.
In one aspect the present invention provides a cold flow improver comprising
(A) a compound which is an ester of
or
(B) a composition comprising
(a) a compound which is an ester of
and
(b) a citric acid ester of a monoglyceride
or
(c) a copolymer of ethylene and an alkyl acrylate.
In one aspect the present invention provides a fuel composition comprising:
a fuel; and
(A) a compound which is an ester of
or
(B) a composition comprising
In one aspect the present invention provides a process for reducing, preventing or inhibiting cold filter plugging in a diesel engine, comprising the step of: dosing a fuel with
(A) a compound which is an ester of
(I) a polyol wherein the polyol has at least three hydroxyl groups; and
(II) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation of from 2 to 7, and wherein the fatty acid oligomer is prepared from a mixture of at least
or
(B) a composition comprising
(a) a compound which is an ester of
(I) a polyol wherein the polyol has at least three hydroxyl groups; and
(II) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation of from 2 to 7, and wherein the fatty acid oligomer is prepared from a mixture of at least
and
(b) a citric acid ester of a monoglyceride
or
(c) a copolymer of ethylene and an alkyl acrylate.
In one aspect the present invention provides use of
(A) a compound which is an ester of
or
(B) a composition comprising
For ease of reference these and further aspects of the present invention are now discussed under appropriate section headings. However, the teachings under each section are not necessarily limited to each particular section.
The compound of the present invention is an ester of
(i) a polyol wherein the polyol is selected from at least pentaerythritol, polymers thereof and mixtures thereof; and
(ii) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation of from 2 to 7.
The compound for use in process and use of the present invention is an ester of
(I) a polyol wherein the polyol has at least three hydroxyl groups; and
(II) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation of from 2 to 7, and wherein the fatty acid oligomer is prepared from a mixture of at least
As is understood by one skilled in the art, an ester of a polyol and a fatty acid oligomer is a compound having a polyol ‘backbone’ onto which fatty acid oligomer side chains are attached.
Polyol esters of fatty acids oligomers are typically prepared by polymerisation of the polyol, for example, polymerisation of glycerol, to provide one or more polyols to which the fatty acid oligomers are then attached. The fatty acids oligomers are generally attached by direct attachment of the fatty acid oligomers to the polyol.
When the polyol is a polymer of an alcohol such as a polyglycerol, the polymerisation typically provides a mixture of polyols of different degrees of polymerisation. The mixture of polyols (e.g. polyglycerols) of different degrees of polymerisation is described herein as a polyol (e.g. polyglycerol) composition. It will be understood by one skilled in the art that references to a polyol (e.g. polyglycerol) composition having particular polyol (e.g. polyglycerol) components requires only that those components be present in the amount specified. It will be appreciated by one skilled in the art that because of the nature of polymerisation of alcohols such as glycerol, the polyol (e.g. polyglycerol) composition may contain other polyols (e.g. polyglycerols) having degrees of polymerisation not recited herein. In determining the amounts of polyols (e.g. polyglycerols) in the polyol (e.g. polyglycerol) composition, the total amount of all polyols (e.g. polyglycerols) (irrespective of degree of polymerisation) is determined to provide the total weight of the polyol (e.g. polyglycerol) composition. Materials which are not a polyol (e.g. not a polyglycerol) do not form part of the polyol (e.g. polyglycerol) composition and their weight is not considered when determining the total weight of the polyol (e.g. polyglycerol) composition.
References in the present specification to “the combined weight of the polyols (e.g. polyglycerols)” encompass the total combined weight of all polyols (e.g. polyglycerols), irrespective of their chain length and irrespective of whether the polyol (e.g. polyglycerol) is recited in the listing of polyols (e.g. polyglycerols).
In one aspect the polyol is a polyglycerol. It will be appreciated by one skilled in the art that polyglycerols may be either in the form of a cyclic polyglycerol or an acyclic polyglycerol. Acyclic polyglycerols are straight chain and branched chain polyglycerols, that is acyclic polyglycerols are formed entirely from glycerol groups linked such that no rings are formed. Cyclic polyglycerols contain a ring structure. References in the present specification to a polyglycerol of a particular degree of polymerisation, for example triglycerol referring to a polyglycerol having an average degree of polymerisation of 3, include both the polyglycerol in cyclic form and in acyclic form.
In one aspect and particular in respect of the compound of the present invention, the polyol is at least pentaerythritol, polymers thereof and mixtures thereof.
As is understood by one skilled in the art, pentaerythritol is a compound of the formula
In one aspect the polyol is at least polypentaerythritol.
In one aspect the polymer of pentaerythritol has a degree of polymerisation of from greater than 1 to no greater than 10. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from 2 to 10. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from greater than 1 to no greater than 5. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from 2 to 5. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from greater than 1 to no greater than 4. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from greater than 1 to no greater than 3. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from greater than 1 to no greater than 2. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from 1.1 to 10. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from 1.1 to 5. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from 1.1 to 4. In one aspect the polymer of pentaerythritol has a degree of polymerisation of from 1.1 to 3.
In one aspect the polyol is selected from at least pentaerythritol, polymers thereof and mixtures thereof; and further comprises a polyol selected from glycerol, polymers thereof and mixtures thereof.
In one aspect polyol is a mixture of at least glycerol and pentaerythritol. In one aspect polyol is a mixture of at least glycerol and dipentaerythritol. In one aspect polyol is a polymer of at least glycerol and pentaerythritol. In one aspect polyol is a polymer of at least glycerol and dipentaerythritol.
In one aspect the polyol has a hydroxyl value of from 850 to 1830, preferably from 950 to 1300.
In one aspect the polyol has a longest chain length of carbons and oxygen from 7 to 50 atoms. In one aspect the polyol has a longest chain length of carbons and oxygen from 7 to 30 atoms. In one aspect the polyol has a longest chain length of carbons and oxygen from 7 to 20 atoms. In one aspect the polyol has a longest chain length of carbons and oxygen from 7 to 15 atoms.
In one aspect the polyol has from 3 to 12 hydroxyl groups, preferably from 3 to 10 hydroxyl groups.
In one aspect the polyol comprises at least polypentaerythritol.
In one aspect the polyol comprises at least one polyol selected from dipentaerythritol, tripentaerythritol, and combinations thereof.
In one aspect the polyol is at least dipentaerythritol. As is understood by one skilled in the art, dipentaerythritol is a compound of the formula
In one aspect the polyol further comprises glycerol.
In one aspect the polyol further comprises polyglycerol.
In one aspect the polyol is at least a mixture of dipentaerythritol and glycerol.
In one aspect the polyol is at least a compound of Formula I
Preferably the polyol is at least a compound of Formula I in an amount of at least 50 wt % based on the amount of polyols. Other polyols may of course be present. Preferably the polyol is at least a compound of Formula I in an amount of at least 60 wt % based on the amount of polyols, such as in an amount of at least 70 wt % based on the amount of polyols, such as in an amount of at least 80 wt % based on the amount of polyols.
In the aspects of the present invention, such as in the fuel composition the ester is an ester of
Preferably the polyol is a polymer of an alcohol.
In one aspect the polymer of the alcohol has a degree of polymerisation of from greater than 1 to no greater than 10. In some aspects the polymer of the alcohol has a degree of polymerisation from 2 to 10. In one aspect the polymer of alcohol has a degree of polymerisation of from greater than 1 to no greater than 5. In one aspect the polymer of alcohol has a degree of polymerisation of from 2 to 5. In one aspect the polymer of alcohol has a degree of polymerisation of from greater than 1 to no greater than 4. In one aspect the polymer of alcohol has a degree of polymerisation of from greater than 1 to no greater than 3. In one aspect the polymer of alcohol has a degree of polymerisation of from greater than 1 to no greater than 2. In one aspect the polymer of alcohol has a degree of polymerisation of from 1.1 to 10. In one aspect the polymer of alcohol has a degree of polymerisation of from 1.1 to 5. In one aspect the polymer of alcohol has a degree of polymerisation of from 1.1 to 4. In one aspect the polymer of alcohol has a degree of polymerisation of from 1.1 to 3. In some aspects the polyol is a polymer of at least pentaerythritol. In some aspects the polyol is a polymer of at least glycerol.
In some aspects the polyol is a mixture of at least glycerol and pentaerythritol. In some aspects the polyol is a polymer of at least glycerol and pentaerythritol. In some aspects the polyol is a mixture of at least glycerol and dipentaerythritol. In some aspects the polyol is a polymer of at least glycerol and dipentaerythritol.
In some aspects the polyol is branched polyol.
In some aspects the polyol has a hydroxyl value of from 850 to 1830, preferably from 950 to 1300.
In some aspects the polyol has a longest chain length of carbons and oxygen of from 7 to 30 atoms.
In some aspects the polyol has from 3 to 12 hydroxyl groups, preferably from 3 to 10 hydroxyl groups.
It will be appreciated by one skilled in the art that an oligomer is a material consisting of a number of repeating units. It is distinguished from a polymer in that it has relatively few repeating units. In the present specification, and oligomer may be interpreted to mean a compound containing no greater than 30 monomer or co-monomer units.
In one aspect of the present invention the fatty acid oligomer has a degree of polymerisation of from 2 to 6.
In one aspect of the present invention the fatty acid oligomer has a degree of polymerisation from 2 to 5.
In one aspect of the present invention the fatty acid oligomer is prepared from at least one fatty acid having from 2 to 30 carbon atoms. In one aspect of the present invention the fatty acid oligomer is prepared from at least one fatty acid having from 2 to 26 carbon atoms. In one aspect of the present invention the fatty acid oligomer is prepared from at least one fatty acid having from 2 to 22 carbon atoms. In one aspect of the present invention the fatty acid oligomer is prepared from at least one fatty acid having from 6 to 22 carbon atoms.
The fatty acids of the fatty acid oligomer attached to the polyol may be of any suitable length. The polyol ester of a fatty acid oligomer may be a polyol ester of a single fatty acid oligomer, or polyol ester of an oligomer of a mixture of fatty acids. The fatty acid chain lengths of the fatty acids oligomer of the polyol ester need not be of the same length. Typically the polyol ester of the fatty acid oligomer is an ester of an oligomer of C12 to C22 fatty acid. Preferably the polyol ester of a fatty acid oligomer is an ester of an oligomer of a C16 or C18 fatty acid. Preferably the polyol ester of a fatty acid oligomer is an ester of an oligomer of a C16 and C18 fatty acid. Preferably the polyol ester of a fatty acid oligomer is an ester of an oligomer of a C18 fatty acid.
The fatty acid of the fatty acid oligomer may be saturated fatty acid, unsaturated fatty acid or a mixture of saturated fatty acid and unsaturated fatty acid. In one aspect the fatty acid of the fatty acid oligomer is an unsaturated fatty acid. The fatty acid of the fatty acid oligomer may be mono or di unsaturated fatty acid. Preferably the fatty acid of the fatty acid oligomer is a mono unsaturated fatty acid.
In one aspect of the present invention the fatty acid oligomer is prepared from at least one fatty acid having a hydroxyl group on the carbon chain of the fatty acid.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) a fatty acid having a hydroxyl group on the carbon chain of the fatty acid and
(ii) an analogous fatty acid without said hydroxyl substitution.
By ‘analogous fatty acid’ it is meant a fatty acid that is of the same chain length, and if unsaturated, the same degree, position and configuration of unsaturation, as the fatty acid to which it is analogous, the sole difference being the absence of the hydroxyl substitution, the hydroxyl substitution being replaced by a hydrogen.
The fatty acids of the fatty acid oligomer may be provided from any suitable source. Thus in one aspect, the fatty acid oligomer is prepared from fatty acids from oils selected from rape seed oil, high oleic rape seed oil, soy oil, high oleic sunflower oil, tall oil fatty acids and mixtures thereof.
In a preferred aspect, the fatty acid oligomer is prepared from hydroxyl fatty acids of hydrogenated, partial hydrogenated, non-hydrogenated castor oil or mixtures thereof.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) a C18-OH fatty acid (for example in an amount of approximately 85 wt % based on the total weight of C18 fatty acids used to prepare the fatty acid oligomer) having a hydroxyl group on the carbon chain of the fatty acid and
(ii) a C18 fatty acid (for example in an amount of approximately 15 wt % based on the total weight of C18 fatty acids used to prepare the fatty acid oligomer) without said hydroxyl substitution.
In one aspect of the present invention the fatty acid oligomer is prepared from at least an unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid.
In one aspect of the present invention the fatty acid oligomer is prepared from at least an unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid, wherein the unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid is present in an amount of no greater than 50 wt %, such as in an amount of no greater than 45 wt %, such as in an amount of no greater than 40 wt %, such as in an amount of no greater than 35 wt %, such as in an amount of no greater than 30 wt %, such as in an amount of no greater than 25 wt %, such as in an amount of no greater than 20 wt %, such as in an amount of no greater than 15 wt %, such as in an amount of no greater than 10 wt %, such as in an amount of no greater than 5 wt %, based on the total weight of fatty acids used to prepare the fatty acid oligomer.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) a saturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid, (for example in an amount of approximately 80 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer)
(ii) an unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid. (for example in an amount of approximately 20 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer)
In one aspect of the present invention the fatty acid oligomer is prepared from at least 12-hydroxy stearic acid.
In one aspect of the present invention the fatty acid oligomer is prepared from at least ricinoleic acid.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) 12-hydroxy stearic acid and
(ii) ricinoleic acid.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) 12-hydroxy stearic acid in an amount of 60-90 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and
(ii) ricinoleic acid in an amount of 10-40 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) 12-hydroxy stearic acid in an amount of 70-90 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and
(ii) ricinoleic acid in an amount of 10-30 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) 12-hydroxy stearic acid in an amount of 75-85 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and
(ii) ricinoleic acid in an amount of 15-25 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) 12-hydroxy stearic acid in an amount of approximately 80 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and
(ii) ricinoleic acid in an amount of approximately 20 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture which further comprises a fatty acid group which does not contain a hydroxyl group on the fatty acid chain.
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) an unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid (for example in an amount of approximately 85 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer) and
(ii) an analogous unsaturated fatty acid without said hydroxyl substitution (for example in an amount of approximately 15 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer).
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) a saturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid (for example in an amount of approximately 85 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer) and
(ii) an analogous saturated fatty acid without said hydroxyl substitution (for example in an amount of approximately 15 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer).
In one aspect of the present invention the fatty acid oligomer is prepared from a mixture of at least
(i) an unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid (for example in an amount of approximately 85 wt % based on the total weight of unsaturated fatty acids used to prepare the fatty acid oligomer);
(ii) an unsaturated fatty acid analogous to (i) without said hydroxyl substitution (for example in an amount of approximately 15 wt % based on the total weight of unsaturated fatty acids used to prepare the fatty acid oligomer);
(iii) a saturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid (for example in an amount of approximately 85 wt % based on the total weight of saturated fatty acids used to prepare the fatty acid oligomer); and
(iv) a saturated fatty acid analogous to (iii) without said hydroxyl substitution (for example in an amount of approximately 15 wt % based on the total weight of saturated fatty acids used to prepare the fatty acid oligomer).
In one aspect of the present invention the fatty acid oligomer has a degree of polymerisation of from 2 to 5 when measured by NMR.
In one aspect of the present invention the fatty acid oligomer has an acid value of from 20 to 100, such as from 30 to 80, such as from 30 to 70, such as from 40 to 70.
In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:50 to 1:1. In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:50 to 1:4. In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:25 to 1:4. In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:50 to 1:10. In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:40 to 1:10. In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:30 to 1:10. In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:25 to 1:10. In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:25 to 1:15. In one aspect of the present invention the ratio of polyol to fatty acid oligomer based on weight is from 1:23 to 1:19.
In one aspect of the present invention the polyol is present in an amount of from 60 to 99 wt. % and the fatty acid oligomer is present in an amount of from 1 to 40 wt. %, wherein the amounts are based on the total amount of polyol and fatty acid oligomer. In one aspect of the present invention the polyol is present in an amount of from 70 to 99 wt. % and the fatty acid oligomer is present in an amount of from 1 to 30 wt. %, wherein the amounts are based on the total amount of polyol and fatty acid oligomer. In one aspect of the present invention the polyol is present in an amount of from 80 to 99 wt. % and the fatty acid oligomer is present in an amount of from 1 to 20 wt. %, wherein the amounts are based on the total amount of polyol and fatty acid oligomer. In one aspect of the present invention the polyol is present in an amount of from 90 to 99 wt. % and the fatty acid oligomer is present in an amount of from 1 to 10 wt. %, wherein the amounts are based on the total amount of polyol and fatty acid oligomer. In one aspect of the present invention the polyol is present in an amount of from 91 to 97 wt. % and the fatty acid oligomer is present in an amount of from 3 to 9 wt. %, wherein the amounts are based on the total amount of polyol and fatty acid oligomer. In one aspect of the present invention the polyol is present in an amount of approximately 96 wt. % and the fatty acid oligomer is present in an amount of approximately 4 wt. %, wherein the amounts are based on the total amount of polyol and fatty acid oligomer. In one aspect of the present invention the polyol is present in an amount of approximately 95.6 wt. % and the fatty acid oligomer is present in an amount of approximately 4.4 wt. %, wherein the amounts are based on the total amount of polyol and fatty acid oligomer.
Preferably the polyol is at least dipentaerythritol. and the fatty acid oligomer is prepared from a mixture of at least (i) 12-hydroxy stearic acid and (ii) ricinoleic acid. In this aspect, preferably the ratio of dipentaerythritol to fatty acid oligomer based on weight is from 1:50 to 1:1, in particular from 1:50 to 1:4, in particular from 1:25 to 1:4, in particular from 1:50 to 1:10, in particular from 1:40 to 1:10, in particular from 1:30 to 1:10, in particular from 1:25 to 1:10, in particular from 1:25 to 1:15, in particular from 1:23 to 1:19.
Preferably the polyol is at least dipentaerythritol and the fatty acid oligomer is prepared from a mixture of at least (i) 12-hydroxy stearic acid in an amount of 60-90 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and (ii) ricinoleic acid in an amount of 10-40 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer. In this aspect, preferably the ratio of dipentaerythritol to fatty acid oligomer based on weight is from 1:50 to 1:1, in particular from 1:50 to 1:4, in particular from 1:25 to 1:4, in particular from 1:50 to 1:10, in particular from 1:40 to 1:10, in particular from 1:30 to 1:10, in particular from 1:25 to 1:10, in particular from 1:25 to 1:15, in particular from 1:23 to 1:19.
Preferably the polyol is at least dipentaerythritol and the fatty acid oligomer is prepared from a mixture of at least (i) 12-hydroxy stearic acid in an amount of 70-90 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and (ii) ricinoleic acid in an amount of 10-30 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer. In this aspect, preferably the ratio of dipentaerythritol to fatty acid oligomer based on weight is from 1:50 to 1:1, in particular from 1:50 to 1:4, in particular from 1:25 to 1:4, in particular from 1:50 to 1:10, in particular from 1:40 to 1:10, in particular from 1:30 to 1:10, in particular from 1:25 to 1:10, in particular from 1:25 to 1:15, in particular from 1:23 to 1:19.
Preferably the polyol is at least dipentaerythritol and the fatty acid oligomer is prepared from a mixture of at least (i) 12-hydroxy stearic acid in an amount of 75-85 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and (ii) ricinoleic acid in an amount of 15-25 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer. In this aspect, preferably the ratio of dipentaerythritol to fatty acid oligomer based on weight is from 1:50 to 1:1, in particular from 1:50 to 1:4, in particular from 1:25 to 1:4, in particular from 1:50 to 1:10, in particular from 1:40 to 1:10, in particular from 1:30 to 1:10, in particular from 1:25 to 1:10, in particular from 1:25 to 1:15, in particular from 1:23 to 1:19.
Preferably the polyol is at least dipentaerythritol and the fatty acid oligomer is prepared from a mixture of at least (i) 12-hydroxy stearic acid in an amount of approximately 80 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and (ii) ricinoleic acid in an amount of approximately 20 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer. In this aspect, preferably the ratio of dipentaerythritol to fatty acid oligomer based on weight is from 1:50 to 1:1, in particular from 1:50 to 1:4, in particular from 1:25 to 1:4, in particular from 1:50 to 1:10, in particular from 1:40 to 1:10, in particular from 1:30 to 1:10, in particular from 1:25 to 1:10, in particular from 1:25 to 1:15, in particular from 1:23 to 1:19.
Preferably the polyol is dipentaerythritol present in an amount of approximately 4.4 wt. %, (based on the total amount of polyol and fatty acid oligomer) and the fatty acid oligomer is present in an amount of approximately 95.6 wt. % (based on the total amount of polyol and fatty acid oligomer) wherein the fatty acid oligomer prepared from a mixture of at least (i) 12-hydroxy stearic acid in an amount of approximately 80 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and (ii) ricinoleic acid in an amount of approximately 20 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
In one aspect of the present invention the compound is of Formula II
wherein each of R1 to R6 is independently selected from OH and fatty acid oligomer esters, wherein at least one of R1 to R6 is a fatty acid oligomer ester.
Preferably the compound is at least a compound of Formula II in an amount of at least 60 wt % based on the amount of esters. Other esters may of course be present. Preferably the ester is at least a compound of Formula II in an amount of at least 70 wt % based on the amount of esters, such as in an amount of at least 80 wt % based on the amount of esters.
In one aspect wherein each of R1 to R6 is independently selected from OH and fatty acid oligomers of Formula III
wherein b is 0 or 1, m is an integer from 0 to 28, n is selected from 2m-b, 2m-2-b, 2m-4-b, x is an integer from 0 to 28, y is selected from 2x-1, 2x-3, 2x-5, and a is an integer from 1 to 9.
In one aspect b is 0. In one aspect b is 1.
In one aspect m is an integer from 0 to 20. In one aspect m is an integer from 10 to 20. In one aspect m is an integer from 12 to 18. In one aspect m is an integer from 14 to 18. In one aspect m is 14 or 16
In one aspect n is 2m-b. In one aspect n is 2m-2-b. In one aspect n is 2m-4-b.
In one aspect x is an integer from 0 to 20. In one aspect x is an integer from 10 to 20. In one aspect x is an integer from 12 to 18. In one aspect x is an integer from 14 to 18. In one aspect x is 14 or 16
In one aspect y is 2x-1. In one aspect y is 2x-3. In one aspect y is 2x-5.
In one aspect a is from 1 to 7. In one aspect a is from 1 to 5. In one aspect a is from 1 to 4. In one aspect a is 1. In one aspect a is 2. In one aspect a is 3. In one aspect a is 4. In one aspect a is 5. In one aspect a is 6. In one aspect a is 7. In one aspect a is 8. In one aspect a is 9.
As discussed herein, in one aspect the present invention provides a composition comprising
(a) a compound which is an ester of
and
(b) a citric acid ester of a monoglyceride
or
(c) a copolymer of ethylene and an alkyl acrylate.
In one aspect the composition comprises
(a) a compound as defined herein (such as in any one of claims 1 to 13) and
(b) a citric acid ester of a monoglyceride.
As understood by one skilled in the art, no monoglyceride is a single pure substance. It typically contains a mixture of fatty acid groups attached to the glycerol backbone. Furthermore, it typically contains a mixture of mono and di glycerides. References herein to citric acid ester of a monoglyceride therefore encompass citric acid esters of monoglycerides and diglycerides.
In one aspect the citric acid ester of a monoglyceride is a citric acid ester of a monoglyceride derived from an oil selected from sunflower oil, high oleic sunflower oil and rapeseed oil.
In one aspect the ratio of (a) to (b) based on weight is from 20:1 to 1:10.
In one aspect the ratio of (a) to (b) based on weight is from 10:1 to 1:3
The fatty acids of the citric acid ester monoglyceride may be provided from any suitable source. Thus in one aspect, the citric acid ester monoglyceride is prepared from fatty acids from oils selected from rape seed oil, high oleic rape seed oil, soy oil, high oleic sunflower oil, tall oil fatty acids and mixtures thereof.
In one preferred aspect the citric acid ester of monoglyceride is provided in the composition in the form of a blend of a triglyceride and a citric acid ester of monoglyceride. The triglyceride may be provided from any suitable source. Preferred oils that may provide the source of the triglyceride are the group consisting of soy oil, rapeseed oil, soy oil, olive oil, palm olein, other vegetable oils such as Jathropha oil, and mixtures thereof The citric acid ester of monoglyceride may be blended with the triglyceride in any suitable amount and the desired amount of triglyceride may vary between the different oils. In one aspect the triglyceride is present in an amount of 5-50 wt. %, such as 5-40 wt. %, such as 5-30 wt. %, such as 10-30 wt. %, such as 15-25 wt. %, such as approximately 20 wt. %, based on the total weight of the triglyceride and the citric acid ester of monoglyceride.
In one aspect the composition comprises
(a) a compound as defined herein (such as in any one of claims 1 to 13) and
(c) a copolymer of ethylene and an alkyl acrylate.
In one aspect the alkyl acrylate has up to 10 carbon atoms in the alkyl chain.
In one aspect the alkyl group of the alkyl acrylate is selected from methyl, ethyl, n-butyl and 2-ethylhexyl.
In one aspect the alkyl acrylate is selected from the group consisting of methyl acrylate, ethyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate and mixtures thereof.
In one aspect the alkyl acrylate is methyl acrylate.
In one aspect the copolymer is derived from copolymerization of ethylene with from 45 to 75 weight % of an alkyl acrylate wherein the copolymer has a number average molecular weight (Mn) above about 40,000 and a melt index of from 2 to 14 g/10 min.
In one aspect the copolymer further comprising a curing agent, one or more additives, or combinations thereof wherein the additive includes an antioxidant, an internal release agent, a scorch retarder, a plasticizer, an accelerator, or a filler and the composition is optionally a cured or post-cured composition.
In one aspect the copolymer further comprises at least one additional polymer, a curing agent, an additive, or combinations of two or more thereof wherein the additional polymer includes an ethylene alkyl acrylate copolymer, a polyacrylate copolymer, or combinations thereof. The additive may include an antioxidant, an internal release agent, a scorch retarder, a plasticizer, an accelerator, or a filler and optionally the composition is a cured or post-cured composition.
In one aspect the copolymer further comprises a curing agent, a second polymer, and optionally an additive and optionally the composition is a cured composition wherein the second polymer includes a thermoset, thermoplastic, or combinations thereof. The thermoset may include unsaturated polyester resin, vinyl ester resin, or combinations thereof and the additive includes filler, reinforcing fiber, fibrous structure, or combinations of two or more thereof.
In one aspect the copolymer comprises methyl acrylate and Mn from about 40,000 to about 65,000, has a melt index from 2 to 12 g/10 min, and has a polydispersity from about 3 to about 7.
In one aspect the copolymer has a polydispersity from 4 to 6.
In one aspect the copolymer is an ethylene methyl acrylate copolymer, has an Mn from about 40,000 to about 65,000, has a melt index from 2 to 12 g/10 min, and has a polydispersity from about 3 to about 7.
In one aspect the copolymer is a copolymer as described in U.S. Pat. No. 7,544,757 (incorporated herein by reference).
In one aspect the ratio of (a) to (c) based on weight is from 100:1 to 1:2.
In one aspect the ratio of (a) to (c) based on weight is from 50:1 to 1:1.
In one aspect the composition comprises
(a) a compound as defined herein (such as in any one of claims 1 to 13);
(b) a citric acid ester of a monoglyceride; and
(c) a copolymer of ethylene and an alkyl acrylate.
In one aspect the ratio of (a) to (b) based on weight is from 20:1 to 1:10; and the ratio of (a) to (c) based on weight is from 100:1 to 1:2.
the ratio of (a) to (b) based on weight is from 10:1 to 1:3; and
the ratio of (a) to (c) based on weight is from 50:1 to 1:1.
The fuel may be any fuel in which cold filter plugging or wax deposition is a problem. Preferably the fuel is a fuel for a high compression spontaneous ignition engine. In one aspect the fuel is selected from diesel, heavy fuel oil, marine gasoil (MGO) and kerosene. The diesel may be biodiesel, low sulphur diesel and ultra-low sulphur diesel. Preferably the fuel is biodiesel or a biodiesel blend.
The biodiesel in one aspect is selected from the group consisting of tallow oil biodiesel soy bean oil biodiesel, rapeseed oil biodiesel, palm oil biodiesel, and mixtures thereof.
The biodiesel in one aspect is a blend of petro diesel and a biodiesel selected from the group consisting of tallow oil biodiesel, soy bean oil biodiesel, rapeseed oil biodiesel, palm oil biodiesel, and mixtures thereof.
The biodiesel may be blended with the petro diesel in any suitable amount to provide a bio/petro diesel blend. For example the biodiesel may comprise at least 1 wt % of the bio/petro diesel blend, such as at least 2 wt % of the blend, such as at least 5 wt % of the blend, such as at least 7 wt % of the blend, such as at least 10 wt % of the blend, such as at least 20 wt % of the blend, such as at least 30 wt % of the blend, such as at least 40 wt % of the blend, such as at least 50 wt % of the blend, such as at least 60 wt % of the blend, such as at least 70 wt % of the blend, such as at least 80 wt % of the blend, such as at least 90 wt % of the blend, such as at least 95 wt. % of the blend, based on the total amount of biodiesel and petro diesel.
Further the biodiesel may comprises no greater than 95 wt % of the bio/petro diesel blend, such as no greater than 90 wt % of the blend, such as no greater than 80 wt % of the blend, such as no greater than 70 wt % of the blend, such as no greater than 60 wt % of the blend, such as no greater than 50 wt % of the blend, such as no greater than 40 wt % of the blend, such as no greater than 30 wt % of the blend, such as no greater than 20 wt % of the blend, such as no greater than 10 wt % of the blend, such as no greater than 7 wt % of the blend, such as no greater than 5 wt % of the blend, such as no greater than 2 wt % of the blend, such as no greater than 1 wt % of the blend, based on the total amount of biodiesel and petro diesel.
In one aspect the diesel is solely a biodiesel selected from the group consisting of tallow oil biodiesel, soy bean oil biodiesel, rapeseed oil biodiesel, palm oil biodiesel, and mixtures thereof.
In one aspect, the ester of a polyol and a fatty acid oligomer is typically dosed into a fuel in an amount of no greater than 1 wt % of the ester, such as no greater than 0.9 wt % of the ester, such as no greater than 0.8 wt % of the ester, such as no greater than 0.7 wt % of the ester, such as no greater than 0.6 wt % of the ester, such as no greater than 0.5 wt % of the ester, such as no greater than 0.4 wt % of the ester, such as no greater than 0.3 wt. % based on the total amount of fuel.
The ester of a polyol and a fatty acid oligomer is typically dosed into a fuel in an amount of at least 0.01 wt % of the ester, such as at least 0.02 wt % of the ester, such as at least 0.03 wt % of the ester, such as at least 0.04 wt % of the ester, such as at least 0.05 wt % of the ester, such as at least 0.06 wt % of the ester, such as at least 0.07 wt % of the ester, such as at least 0.08 wt % of the ester, such as at least 0.09 wt % of the ester, such as at least 0.1 wt % of the ester, such as at least 0.12 wt % of the ester, such as at least 0.15 wt % of the ester, such as at least 0.17 wt % of the ester, such as at least 0.2 wt % of the ester, such as at least 0.25 wt % of the ester, such as at least 0.3 wt % of the ester, based on the total amount of fuel.
In one aspect, the amount of ester of a polyol and a fatty acid oligomer dosed into a fuel may be reduced based on the proportion of biodiesel present in a blend of biodiesel and petro diesel. Therefore in one aspect the fatty acid oligomer is dosed into a blend of biodiesel and petro diesel in an amount of at least 0.01 wt % of the ester, such as at least 0.02 wt % of the ester, such as at least 0.03 wt % of the ester, such as at least 0.04 wt % of the ester, such as at least 0.05 wt % of the ester, such as at least 0.06 wt % of the ester, such as at least 0.07 wt % of the ester, such as at least 0.08 wt % of the ester, such as at least 0.09 wt % of the ester, such as at least 0.1 wt % of the ester, such as at least 0.12 wt % of the ester, such as at least 0.15 wt % of the ester, such as at least 0.17 wt % of the ester, such as at least 0.2 wt % of the ester, such as at least 0.25 wt % of the ester, such as at least 0.3 wt % of the ester, based on the amount of fuel biodiesel. For example in a blend of biodiesel and petro diesel comprising 10 wt % biodiesel and 90 wt % petro diesel, the recited amounts may be divided by 10 to provide the dosage of ester based on the total amount of fuel.
In one aspect, the ester of a polyol and a fatty acid oligomer is typically dosed into a blend of biodiesel and petro diesel in an amount of no greater than 1 wt % of the ester, such as no greater than 0.9 wt % of the ester, such as no greater than 0.8 wt % of the ester, such as no greater than 0.7 wt % of the ester, such as no greater than 0.6 wt % of the ester, such as no greater than 0.5 wt % of the ester, such as no greater than 0.4 wt % of the ester, such as no greater than 0.3 wt. % based on the total amount of biodiesel.
In one aspect, the citric acid ester of a monoglyceride is typically dosed into a fuel in an amount of no greater than 1 wt % of the ester, such as no greater than 0.9 wt % of the ester, such as no greater than 0.8 wt % of the ester, such as no greater than 0.7 wt % of the ester, such as no greater than 0.6 wt % of the ester, such as no greater than 0.5 wt % of the ester, such as no greater than 0.4 wt % of the ester, such as no greater than 0.3 wt. %, such as no greater than 0.2 wt. % based on the total amount of fuel.
In one aspect, the citric acid ester of a monoglyceride is typically dosed into a fuel in an amount of at least 0.01 wt % of the ester, such as at least 0.02 wt % of the ester, such as at least 0.03 wt % of the ester, such as at least 0.04 wt % of the ester, such as at least 0.05 wt % of the ester, such as at least 0.06 wt % of the ester, such as at least 0.07 wt % of the ester, such as at least 0.08 wt % of the ester, such as at least 0.09 wt % of the ester, such as at least 0.1 wt % of the ester, such as at least 0.12 wt % of the ester, such as at least 0.15 wt % of the ester, such as at least 0.17 wt % of the ester, such as at least 0.2 wt % of the ester, based on the amount of fuel.
In one aspect, the amount of citric acid ester of a monoglyceride dosed into a fuel may be reduced based on the proportion of biodiesel present in a blend of biodiesel and petro diesel. Therefore in one aspect the citric acid ester of a monoglyceride is dosed into a fuel blend of biodiesel and petro diesel in an amount of at least 0.01 wt % of the ester, such as at least 0.02 wt % of the ester, such as at least 0.03 wt % of the ester, such as at least 0.04 wt % of the ester, such as at least 0.05 wt % of the ester, such as at least 0.06 wt % of the ester, such as at least 0.07 wt % of the ester, such as at least 0.08 wt % of the ester, such as at least 0.09 wt % of the ester, such as at least 0.1 wt % of the ester, such as at least 0.12 wt % of the ester, such as at least 0.15 wt % of the ester, such as at least 0.17 wt % of the ester, such as at least 0.2 wt % of the ester, based on the total amount of biodiesel.
In one aspect, the citric acid ester of a monoglyceride is typically dosed into a blend of biodiesel and petro diesel in an amount of no greater than 1 wt % of the ester, such as no greater than 0.9 wt % of the ester, such as no greater than 0.8 wt % of the ester, such as no greater than 0.7 wt % of the ester, such as no greater than 0.6 wt % of the ester, such as no greater than 0.5 wt % of the ester, such as no greater than 0.4 wt % of the ester, such as no greater than 0.3 wt. %, such as no greater than 0.2 wt. % based on the total amount of biodiesel.
In one aspect, the copolymer of ethylene and an alkyl acrylate is typically dosed into a fuel in an amount of no greater than 0.1 wt % of the ester, such as no greater than 0.09 wt % of the ester, such as no greater than 0.08 wt % of the ester, such as no greater than 0.07 wt % of the ester, such as no greater than 0.06 wt % of the ester, such as no greater than 0.05 wt % of the ester, such as no greater than 0.04 wt % of the ester, such as no greater than 0.03 wt. %, such as no greater than 0.02 wt. % based on the total amount of fuel.
In one aspect, the copolymer of ethylene and an alkyl acrylate is typically dosed into a fuel in an amount of at least 0.001 wt % of the ester, such as at least 0.002 wt % of the ester, such as at least 0.003 wt % of the ester, such as at least 0.004 wt % of the ester, such as at least 0.005 wt % of the ester, such as at least 0.006 wt % of the ester, such as at least 0.007 wt % of the ester, such as at least 0.008 wt % of the ester, such as at least 0.009 wt % of the ester, such as at least 0.01 wt % of the ester, such as at least 0.012 wt % of the ester, such as at least 0.015 wt % of the ester, such as at least 0.017 wt % of the ester, such as at least 0.02 wt % of the ester, based on the total amount of fuel.
In one aspect, the amount of copolymer of ethylene and an alkyl acrylate dosed into a fuel may be reduced based on the proportion of biodiesel present in a blend of biodiesel and petro diesel. Therefore in one aspect the copolymer of ethylene and an alkyl acrylate is dosed into a fuel blend of biodiesel and petro diesel in an amount of at least 0.001 wt % of the ester, such as at least 0.002 wt % of the ester, such as at least 0.003 wt % of the ester, such as at least 0.004 wt % of the ester, such as at least 0.005 wt % of the ester, such as at least 0.006 wt % of the ester, such as at least 0.007 wt % of the ester, such as at least 0.008 wt % of the ester, such as at least 0.009 wt % of the ester, such as at least 0.01 wt % of the ester, such as at least 0.012 wt % of the ester, such as at least 0.015 wt % of the ester, such as at least 0.017 wt % of the ester, such as at least 0.02 wt % of the ester, based on the total amount of biodiesel.
In one aspect, the copolymer of ethylene and an alkyl acrylate is typically dosed into a blend of biodiesel and petro diesel in an amount of no greater than 0.1 wt % of the ester, such as no greater than 0.09 wt % of the ester, such as no greater than 0.08 wt % of the ester, such as no greater than 0.07 wt % of the ester, such as no greater than 0.06 wt % of the ester, such as no greater than 0.05 wt % of the ester, such as no greater than 0.04 wt % of the ester, such as no greater than 0.03 wt. %, such as no greater than 0.02 wt. % based on the total amount of biodiesel.
The composition or fuel composition according to the present invention may comprise one or more additives for example, to improve various aspects of the fuel to which the composition is typically added or to improve various aspects of the combustion system performance. Suitable additional additives include detergents, carrier oils, anti-oxidants, corrosion inhibitors, colour stabilisers, metal deactivators, cetane number improvers, other combustion improvers, antifoams, pour point depressants, further cold filter plugging depressants, wax anti-settling additives, dispersants, reodorants, dyes, smoke suppressants, lubricity agents, and other particulate filter regeneration additives.
It will be understood by one skilled in the art that fuels are typical hydrocarbon based materials which suffer from the problems of cold flow and to which the addition of a cold flow improver is desirable. However the problem of cold flow may be exhibited in other hydrocarbon based materials. Therefore in a further aspect the present invention provides the following.
In one aspect the present invention provides a hydrocarbon composition comprising: a hydrocarbon fluid; and
(A) a compound which is an ester of
or
(B) a composition comprising
In one aspect the present invention provides a process for reducing, preventing or inhibiting cold filter plugging by a hydrocarbon fluid, comprising the step of: dosing a hydrocarbon fluid with
(A) a compound which is an ester of
(I) a polyol wherein the polyol has at least three hydroxyl groups; and
(II) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation of from 2 to 7, and wherein the fatty acid oligomer is prepared from a mixture of at least
or
(B) a composition comprising
(a) a compound which is an ester of
(I) a polyol wherein the polyol has at least three hydroxyl groups; and
(II) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation of from 2 to 7, and wherein the fatty acid oligomer is prepared from a mixture of at least
We have also surprisingly found that in some aspects of the present invention it is not essential for the ester of a polyol and fatty acid oligomer to be present. Thus the present invention may provide:
using a compound selected from a citric acid ester of a monoglyceride, a copolymer of ethylene and an alkyl acrylate and mixtures thereof.
In one further aspect the present invention provides a fuel composition comprising:
(I) a fuel; and
(II) a citric acid ester of a monoglyceride.
Preferably the fuel composition further comprises a copolymer of ethylene and an alkyl acrylate.
In one further aspect the present invention provides a hydrocarbon fluid composition comprising:
(I) a hydrocarbon fluid; and
(II) a citric acid ester of a monoglyceride.
Preferably the hydrocarbon fluid composition further comprises a copolymer of ethylene and an alkyl acrylate.
In one further aspect the present invention provides a fuel composition comprising:
(I) a fuel; and
(II) a copolymer of ethylene and an alkyl acrylate.
Preferably the fuel composition further comprises a citric acid ester of a monoglyceride.
In one further aspect the present invention provides a hydrocarbon fluid composition comprising:
(I) a hydrocarbon fluid; and
(II) a copolymer of ethylene and an alkyl acrylate.
Preferably the fuel composition further comprises a citric acid ester of a monoglyceride.
In one aspect the present invention provides a process for reducing, preventing or inhibiting cold filter plugging in a diesel engine, comprising the step of: dosing a fuel with a citric acid ester of a monoglyceride. Preferably the process further comprises the step of dosing the fuel with a copolymer of ethylene and an alkyl acrylate.
In one aspect the present invention provides a process for reducing, preventing or inhibiting cold filter plugging in a diesel engine, comprising the step of: dosing a fuel with a copolymer of ethylene and an alkyl acrylate. Preferably the process further comprises the step of dosing the fuel with a citric acid ester of a monoglyceride.
In one aspect the present invention provides use of a citric acid ester of a monoglyceride, for reducing, preventing or inhibiting cold filter plugging in a diesel engine. Preferably the use further comprises the use of a copolymer of ethylene and an alkyl acrylate for reducing, preventing or inhibiting cold filter plugging in a diesel engine.
In one aspect the present invention provides use of a copolymer of ethylene and an alkyl acrylate, for reducing, preventing or inhibiting cold filter plugging in a diesel engine. Preferably the use further comprises the use of a citric acid ester of a monoglyceride for reducing, preventing or inhibiting cold filter plugging in a diesel engine.
Each of the preferred aspects recited herein in respect of the citric acid ester of a monoglyceride and in respect of the copolymer of ethylene and an alkyl acrylate, apply equally to these further aspects of the invention.
Aspects of the invention are defined in the appended claims.
The present invention will now be described in further detail in the following examples, in which:
In the present Examples, the following abbreviations are used
CFI is a cold flow improver.
CFI A is cold flow improver which is an ester of a polyol and a fatty acid oligomer as described herein.
CFI B is cold flow improver which is a citric acid ester of a monoglyceride as described herein.
CFI C is cold flow improver which is a copolymer of ethylene and an alkyl acrylate as described herein.
CFPP is cold filter plugging point.
OHV is hydroxyl value
PFA is polymerised fatty acid. In this context polymerised provides oligomers and PFA is a fatty acid oligomer as described herein.
DPE is dipentaerythritol.
RA is ricinoleic acid
HSA is 12-hydroxy stearic acid
2IN1 is GRINDSTED® CITREM 2-IN-1
TME is a tallow oil based biodiesel available from DAKA.
SME is a soy bean oil based biodiesel available from Emmelev.
RME is a rapeseed oil based biodiesel available from ADM.
PME is a palm oil based biodiesel available from ADM.
When a biodiesel material incorporates a number, the number denotes the wt. % of biodiesel blended with petro diesel, where the petro diesel makes up the remainder of the diesel blend. For example, B100 RME means that this is solely rapeseed oil based biodiesel and no petro diesel is added, whereas B7 SME is a blend of petro diesel and biodiesel where the biodiesel is soy bean oil based biodiesel and corresponds to 7 wt % of the blend.
For the preparation of the fatty acid oligomer, the following general preparation process is used.
The fatty acids are slowly heated up to 90° C. protected under nitrogen-cover, reduce pressure to 50 mb, temperature is slowly raised to a reaction temperature of 205° C. The polymerisation process continues until an acid value of 40-45 mg KOH/g is reached (processing time approx. 7-8 hours). See table 6 for examples. Description of analysis method is found in Appendix 1.
Glycerol is heated up to approx. 220° C. protected under Nitrogen-cover, reduce pressure slowly to 250-200 mb, temperature is raised to reaction temperature of 235° C. The polymerisation process continues until a hydroxyl value (OHV) of 800-1200 is reached (processing time approx. 15 hours). The polyol product will have a certain polyol distribution.
In an alternative, a polyol may be purchased as a commercial product.
A number of polyol distributions from both polyols prepared as described and purchased polyols are given in table 5. A description of analysis method is found in Appendix 2.
The mixture of PFA+Polyol+NaOH aq. (50%), wherein the PFA+Polyol are present in the amount described in Table 1 and the NaOH is present in an amount of approximately one twentieth that of the polyol is slowly heated up to 90° C. protected under nitrogen-cover, reduce pressure to 50 mb, temperature is slowly raised to reaction temperature of 205° C. The esterification process continues until an acid value of <2 mg KOH/g is reached (processing time approx. 7-8 hours). See table 2, 3 and 4 for examples of the physical parameters that characterize CFI A. Descriptions of analysis methods are found in Appendix 3, 4, 5 & 6.
Several batches are made of this product A.
In a preferred aspect the polyol in CFI A is dipentaerythritol (DPE). If not stated otherwise the DPE of the Examples (which is available as a commercial product) is 85% pure.
In a preferred aspect the fatty acid polymer reactant in CFI A is synthesized from 80 wt % 12-hydroxystearic acid and 20 wt % ricinoleic acid both derived from castor oil.
A number of CFI A products are synthesised and analysed. The details of the analysis are given below
The polyol distribution of the following products is analysed.
The results are given in Tables 2b and 2c.
The acid value, saponification value, hydroxyl value and average fatty acid chain length is determined for the following CFI A materials.
The results are given in Table 3b.
The fatty acid distribution is determined for the following materials.
The results are given in Table 4b.
The acid values for the following PFAs used to prepare the CFI A materials are measured.
The results are given in Table 6.
Acid value is an accurate indirect measure of the degree of polymerisation of the fatty acid in the polymerized fatty acid.
As discussed herein, in one aspect the present invention provides a citric acid ester of a monoglyceride which may be used as a CFI. Citric acid esters of monoglyceride are typically referred to as CITREMs.
In the present examples, CFI B is a cold flow improver which is a citric acid ester of a monoglyceride as described herein.
In the present examples the CFI Bs are GRINDSTED® CITREM 2-IN-1 (a number of different batches), Citrem LR10 extra and Citrem SP70. Each of which is a citric acid ester of a monoglyceride available from DuPont (formerly Danisco A/S, Denmark). The Citrems are prepared from monoglycerides derived from a variety of oil sources. The oil sources for the tested Citrems are given below. Different lab batches of GRINDSTED® CITREM 2-IN-1 are denoted by batch numbers, such as 2447/085 and 2447/088.
As discussed herein, in one aspect the present invention provides a copolymer of ethylene and an alkyl acrylate which may be used as a CFI.
In the present examples, CFI C is cold flow improver which is a copolymer of ethylene and an alkyl acrylate.
This polymer is a commercial DuPont product, Vamac DP. Suitable CFI C polymers may also be prepared in accordance with the teachings of U.S. Pat. No. 7,544,757.
The following CFIs are tested: A, A+B, A+C and A+B+C.
In the following there will be examples of CFPP results divided in to these groups:
Sample A is categorized into three groups to assist in the assessment of the classes which are being tested. The following denotations are used:
CFI A Ery=esters of PFA+pentaerythritol derivatives
CR A Hex=esters of PFA+Hexaglycerol
CFI A Poly=esters of PFA+other Polyols
CFI A Ery is referred to in the figures as Abest or Abes
A range of esters of PFA+pentaerythritol derivatives dosed in biodiesel B100 RME are tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
A preferred ester of PFA+pentaerythritol derivative is then dosed in bio diesel B100 TME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
Preferred ester of PFA+pentaerythritol derivatives in combination with preferred Citrems are dosed in bio diesel B100 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive. B100 RME is a blend of methyl esters derived from a transesterification of rapeseed oil with methanol. B100 means that this is solely biodiesel and no petro diesel is added. If instead B7 where mentioned it is a blend of petro diesel and biodiesel where the biodiesel corresponds to 7% of the blend.
The combinations of (i) ester of PFA+pentaerythritol derivatives and (ii) Citrems are then dosed in biodiesel blends and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive. TME is a tallow oil biodiesel available from DAKA. SME is a soy bean oil based biodiesel available from Emmelev. RME is a rapeseed oil based biodiesel available from ADM. PME is a palm oil based biodiesel.
CFI A 2526/211 is then tested with each of 2IN1 and LR10 in biodiesel B7 RME. B7 RME is a rape seed biodiesel containing 7% biodiesel and 93% petro diesel.
CFI A 2526/211 is then tested with 2IN1 in a number of biodiesel blends.
Preferred ester of PFA+pentaerythritol derivatives in combination with preferred copolymers of ethylene and an alkyl acrylate are dosed in biodiesel B100 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive. Vamac DP is a copolymer of ethylene and an alkyl acrylate available from DuPont.
CFI A 2526/211 is then tested with Vamac DP in a biodiesel blend.
Preferred esters of PFA+pentaerythritol derivatives in combination with preferred citric acid esters of monoglycerides and preferred copolymers of ethylene and an alkyl acrylate are dosed in biodiesel B100 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive. Vamac 3038, Vamac GLS and Vamac VCD are copolymers of ethylene and an alkyl acrylate available from DuPont.
CFI A 2526/211 is then tested with 2IN1 and Vamac DP in a biodiesel blend.
Preferred esters of PFA+pentaerythritol derivatives in combination with preferred citric acid esters of monoglycerides and preferred copolymers of ethylene and an alkyl acrylate are dosed in biodiesel B7 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
CFI A 2526/211 is then tested with 2IN1 and Vamac DP in a further biodiesel blend.
A range of esters of PFA+hexaglycerol dosed in biodiesel B100 RME are tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
A preferred ester of PFA+hexaglycerol is then dosed in biodiesel B100 TME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive. As discussed above, B100 TME is a 100% biodiesel.
Combinations of (i) ester of PFA+hexaglycerol and (ii) Citrems are then dosed in bio diesel blends and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive. As discussed above B100RME is a 100% biodiesel.
A preferred ester of PFA+hexaglycerol in combination with preferred copolymers of ethylene and an alkyl acrylate are dosed in bio diesel B100 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
A preferred ester of PFA+hexaglycerol in combination with preferred copolymers of ethylene and an alkyl acrylate are dosed in biodiesel B100 XME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
Preferred esters of PFA+pentaerythritol derivatives in combination with preferred citric acid esters of monoglycerides and preferred copolymers of ethylene and an alkyl acrylate are dosed in biodiesel B7 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
A range of esters of PFA+other polyols dosed in bio diesel B100 RME are tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
Preferred citric acid esters of monoglycerides are dosed in biodiesel B100 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
Preferred copolymers of ethylene and an alkyl acrylate are dosed in biodiesel B100 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
Preferred citric acid esters of monoglycerides and preferred copolymers of ethylene and an alkyl acrylate are dosed in biodiesel B100 RME and tested. The cold filter plugging point is measured and can be compared against the control diesel containing no additive.
We have shown that an ester of a polyol and a fatty acid oligomer is effective in reducing the cold filter plugging point of fuels, such as diesel and in particular biodiesels.
When a combined product is provided which further includes a citric acid ester of a monoglyceride we have effectively decreased the cold filter plugging point (CFPP) in biodiesel rapeseed methyl esters (RME) to −30° C.
It is believed that the ester of a polyol and a fatty acid oligomer acts as an anticrystallizer and the citric acid ester of a monoglyceride is an emulsifier which has a dual action impacting the anticrystallization and crystal growth.
Furthermore when a further component, namely a copolymer of ethylene and an alkyl acrylate, is added further effects are seen. These combination additives can reduce the CFPP from −29° C. to −34° C. in B7 based on 7% RME (7% biodiesel in petro diesel).
The invention will be described in further detail in the following numbered paragraphs. The present invention provides:
(i) a polyol wherein the polyol is selected from at least pentaerythritol, polymers thereof and mixtures thereof; and
(ii) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation of from 2 to 7.
(i) a fatty acid having a hydroxyl group on the carbon chain of the fatty acid and
(ii) an analogous fatty acid without said hydroxyl substitution.
(i) a C18-OH fatty acid having a hydroxyl group on the carbon chain of the fatty acid and
(ii) a C18 fatty acid without said hydroxyl substitution.
wherein the unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid is present in an amount of no greater than 50 wt. % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
(i) a saturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid,
(ii) an unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid.
(i) 12-hydroxy stearic acid and
(ii) ricinoleic acid.
(i) 12-hydroxy stearic acid in an amount of 60-90 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and
(ii) ricinoleic acid in an amount of 10-40 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
(i) 12-hydroxy stearic acid in an amount of 70-90 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and
(ii) ricinoleic acid in an amount of 10-30 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
(i) 12-hydroxy stearic acid in an amount of 75-85 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and
(ii) ricinoleic acid in an amount of 15-25 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
(i) 12-hydroxy stearic acid in an amount of approximately 80 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer and
(ii) ricinoleic acid in an amount of approximately 20 wt % based on the total weight of fatty acids used to prepare the fatty acid oligomer.
(i) an unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid and
(ii) an analogous unsaturated fatty acid without said hydroxyl substitution.
(i) a saturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid and
(ii) an analogous saturated fatty acid without said hydroxyl substitution.
(i) an unsaturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid;
(ii) an unsaturated fatty acid analogous to (i) without said hydroxyl substitution;
(iii) a saturated fatty acid having a hydroxyl group on the carbon chain of the fatty acid; and
(iv) a saturated fatty acid analogous to (iii) without said hydroxyl substitution.
wherein each of R1 to R6 is independently selected from —OH and fatty acid oligomer esters, wherein at least one of R1 to R6 is a fatty acid oligomer ester.
wherein b is 0 or 1, m is an integer from 0 to 28, n is selected from 2m-b, 2m-2-b, 2m-4-b, x is an integer from 0 to 28, y is selected from 2x-1, 2x-3, 2x-5, and a is an integer from 1 to 9.
(a) a compound as defined in any one of paragraphs 1 to 45
and
(b) a citric acid ester of a monoglyceride
or
(c) a copolymer of ethylene and an alkyl acrylate
(a) a compound as defined in any one of paragraphs 1 to 45 and
(b) a citric acid ester of a monoglyceride.
(a) a compound as defined in any one of paragraphs 1 to 45 and
(c) a copolymer of ethylene and an alkyl acrylate.
(a) a compound as defined in any one of paragraphs 1 to 45;
(b) a citric acid ester of a monoglyceride; and
(c) a copolymer of ethylene and an alkyl acrylate.
the ratio of (a) to (b) based on weight is from 20:1 to 1:10; and
the ratio of (a) to (c) based on weight is from 100:1 to 1:2.
the ratio of (a) to (b) based on weight is from 10:1 to 1:3; and
the ratio of (a) to (c) based on weight is from 50:1 to 1:1.
(a) a fuel;
(b) a compound which is an ester of
(I) a polyol wherein the polyol has at least three hydroxyl groups; and
(II) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation from 2 to 7, and wherein the fatty acid oligomer is prepared from a mixture of at least
(a) a fuel;
(b) a compound as defined in any one of paragraphs 1 to 45 or a composition as defined in any one of paragraphs 46 to 60.
(I) a polyol wherein the polyol has at least three hydroxyl groups; and
(II) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation from 2 to 7, and wherein the fatty acid oligomer is prepared from a mixture of at least
(I) a polyol wherein the polyol has at least three hydroxyl groups; and
(II) a fatty acid oligomer, wherein the fatty acid oligomer has a degree of polymerisation from 2 to 7, and wherein the fatty acid oligomer is prepared from a mixture of at least
All publications mentioned in the above specification are herein incorporated by reference. Various modifications and variations of the described methods and system of the invention will be apparent to those skilled in the art without departing from the scope and spirit of the invention. Although the invention has been described in connection with specific preferred embodiments, it should be understood that the invention as claimed should not be unduly limited to such specific embodiments. Indeed, various modifications of the described modes for carrying out the invention which are obvious to those skilled in chemistry or related fields are intended to be within the scope of the following claims
| Number | Date | Country | Kind |
|---|---|---|---|
| 1208795.3 | May 2012 | GB | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2013/060174 | 5/16/2013 | WO | 00 |
