This application claims priority from Japanese Patent Application Serial No. 2009-095894 filed Apr. 10, 2009, the contents of which are incorporated herein by reference in their entirety.
The present invention relates to an excimer discharge lamp which emits ultraviolet rays by excimer electric discharge. Especially, the present invention relates to an excimer discharge lamp whose electric discharge container is made of sapphire, YAG, or single crystal yttria.
Conventionally, an excimer discharge lamp has been used, as an ultraviolet ray light source, for a photochemical reaction, such as photo-cleaning, surface alteration and sensitization of a chemical substance. For example, rare gas such as xenon and halide such as fluoride, which are enclosed in this excimer discharge lamp, are known as light emission gas. The halogen or halide is ionized at time of lamp lighting, so as to serve as halogen ions, and the reactivity thereof to other substances becomes very high. For this reason, measures against it are required for an electric discharge container of such an excimer discharge lamp, which encloses such halogen or halide. Japanese Patent Application Publication No. H06-310106 teaches such an excimer discharge lamp in which the measures therefor are taken.
The electric discharge container 91 is sealed by the titanium caps using O rings 921 made of fluorine contained resin system, so that an airtight electrical discharge space is formed inside the electric discharge container 91. This electrical discharge space is filled up with xenon gas and chlorine as the electric discharge gas.
A power supply, which is not illustrated in the figure, is connected to the metal nets 93, and high voltage of high frequency is impressed thereto, to start the electric discharge. In the electrical discharge space, excimer electric discharge arises, so that ultraviolet rays with a wavelength band of 300 to 320 nm resulting from the xenon and chlorine, are acquired. Since the sapphire pipe 91 has ultraviolet-ray permeability, the lamp emits the ultraviolet rays produced by the excimer electric discharge to the outside of the lamp 9.
In the above-mentioned excimer discharge lamp 9, in order to enclose the electric discharge gas in the electrical discharge space, it is necessary to form a chip pipe in the titanium cap 911. For this reason, an excimer discharge lamp shown in
Portions of
When the excimer discharge lamp 9 as shown in
Although high voltage is impressed to one of the metal nets 93 at time of lamp lighting, since the chip pipe 94 is at low voltage with respect to this high voltage, electric discharge has arisen between the one of the metal nets 93 and the chip pipe 94.
If electric discharge arises between the one of the metal nets 93 and the chip pipe 94, the chip pipe 94 is heated, so that the thermal expansion difference between the cap 911 and the chip pipe 94 occurs at the brazed portion whereby it may be damaged.
Moreover, even though the portion between the cap 911 and the chip pipe 94 is not damaged, when the chip pipe 94 is heated, the O ring 922 is heated through the cap 911, so that the O ring 922 deteriorates, and the airtightness of the electric discharge container 91 may not be maintained.
It is an object of the present invention to offer an excimer discharge lamp in which electric discharge to a chip pipe is suppressed.
An excimer discharge lamp comprises an electric discharge container that has an electrical discharge space, a pair of electrodes provided in an outer face of the electric discharge container. The electrical discharge space encloses at least a rare gas and halogen or halide as electric discharge gas. The electric discharge container is made up of a tubular side wall on which the pair of electrodes are provided. One end wall seals one end of the tubular side wall, and another end wall seals another end of the tubular side wall. The one end wall and the another end wall are made of sapphire, YAG, or single crystal yttrias. A chip pipe made of metal or an alloy is formed on the another end wall, and wherein a dividing wall made of sapphire, YAG, or single crystal yttria is provided at a portion of the another end wall that is located in a shortest distance between the chip pipe and an inner face of the side wall on which the pair of electrodes is provided.
In the excimer discharge lamp according to the present invention, it is possible to make resistance high between the chip pipe and the inner face where the pair of electrodes is provided, thereby suppressing the electric discharge to the chip pipe.
Other features and advantages of the present excimer discharge lamp will be apparent from the ensuing description, taken in conjunction with the accompanying drawings, in which:
The excimer discharge lamp 1 according to the first embodiment is made up of the straight tube shaped electric discharge container 2, a chip pipe 4 formed in an end of the electric discharge container 2, and a pair of electrodes 31 and 32 provided apart from each other on an outer surface of the electric discharge container 2.
This electric discharge container 2 is made up of the straight tube shaped side wall 21, one end wall 221 in shape of a plate, which is provided at an end of the side wall 21, and another annular end wall 222 provided at the other end of the side wall 21, and is made of sapphire (single crystal alumina Al2O3), YAG (yttrium aluminum Garnett), or single crystal yttria (Y2O3). A hole 222b which penetrates the other end wall 222 at the center thereof is formed. This hole 222b is made up of a small diameter hole 222c located in a left side of the hole 222b in the figure, and a large diameter hole 222d, which is continuous from the small diameter hole 222c, and has a larger diameter than that of the small diameter hole 222c. A level difference is formed by the small diameter hole 222c and the large diameter hole 222d therebetween, that is, the level difference serves as a dividing wall 222a.
Part of the outer circumference of the chip pipe 4 is inserted in the large diameter hole 222d of the end wall 222, and one end portion of the chip pipe 4 (end portion in the left hand side of the chip pipe 4 in the figure) is brought into contact with the dividing wall 222a. Metallization is performed on a face that forms the large diameter hole 222d, and brazing metal, such as silver solder, is filled up between the chip pipe 4 and the face. Since the chip pipe 4 is made of metal material, such as nickel or an alloy material (such as a nickel-chromium (Ni—Cr) system alloy, a nickel-copper (Ni—Cu) system alloy or a nickel-iron (Ni—Fe) system alloy), the chip pipe 4 is joined through brazing metal on the face where the metallization is performed. In addition, there is an active metal brazing method as a method for joining metal and ceramics. Therefore, the chip pipe 4 may be joined with the other end wall 222 by using this active metal brazing method. Specifically, active metal brazing, which contains active metal such as titanium, is used as brazing metal, and the chip pipe 4 and the face that forms the large diameter hole 222d are joined by the active metal brazing. In the case of the active metal brazing method, the metallization may not be necessarily performed on the face, which forms the large diameter hole 222d.
A sealing portion 41 is formed by performing pressure welding on the other end portion of the chip pipe 4 (end portion of the right hand side of the chip pipe 4 in the figure). In this way, the airtight electrical discharge space 23 is formed inside the electric discharge container 2. The electrical discharge space 23 encloses a rare gas, such as argon (Ar), krypton (Kr) and xenon (Xe), and halogen, such as fluoride (F2), chlorine (Cl2), bromine (Br2) and iodine (I2), or halide such as sulfur hexafluoride (SF6) as an electric discharge gas.
A pair of electrodes 31 and 32 are arranged apart from each other on an outer surface of the electric discharge container 2. Thus, the pair of electrodes 31 and 32 face each other through the side wall 21 and the electrical discharge space 23 of the electric discharge container 2.
In the excimer discharge lamp 1 according to the first embodiment, the dividing wall 222a is provided on the shortest distance (portion) L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the one electrode 31 is provided. The dividing wall 222a is also provided on the shortest distance (portion) L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the electrode 32 is provided. In addition, the “shortest distance (part) L” according to the first embodiment means, as shown in
Next, examples of a manufacture method of the excimer discharge lamp 1 are explained, referring to
For example, three plate members made of sapphire are prepared, and a rectangular hole is formed in one of the plate members so as to penetrate a central part thereof, thereby forming the rectangular member 53. As shown in
As shown in
After grinding the two plate members 51 and 52 and the one rectangular member 53 in
After heating in
Although not shown in the figure, the net electrodes 31 and 32 are formed on the pair of the outer faces of the electric discharge container 2. The net electrodes are formed by applying, for example, copper paste in a shape of the net on the outer faces of the electric discharge container 2 by printing, and then heating the applied paste copper together with the electric discharge container 2 at high temperature, so as to perform calcination on the paste copper. Thereby, the excimer discharge lamp 1 is completed. When the excimer discharge lamp 1 according to the present invention is formed in such a manner, it is possible to form the sealed electric discharge space 23 without using a resin component.
In addition, the electric discharge container 2 may be a rectangular parallelepiped, which is a rectangle in a cross sectional view thereof taken in a direction perpendicular to a longitudinal direction, or may be a cylindrical shape, which is a circle in a cross sectional view thereof taken therein.
A power supply, which is not illustrated, is connected to the pair of electrodes 31 and 32 of the excimer discharge lamp 1 according to the first embodiment. Next, description of a lighting operation of the excimer discharge lamp 1 will be given below.
When a high voltage of a high frequency is supplied to the excimer discharge lamp 1, electric charges are accumulated on an inner face of the electric discharge container 2 on which the high voltage side electrode (for example, one electrode 31) is formed, and the electric charges move toward the low voltage side electrode (for example, the other electrode 32). When the electric discharge gas is argon and sulfur hexafluoride (SF6), the electric discharge gas is ionized in response to the electric charges, so that argon ions and fluoride ions are formed. The excimer molecules, which consist of argon and fluoride, are formed from these ions, so that ultraviolet rays with a wavelength of 193 nm are generated. The electric discharge container 2 is exposed to the fluoride ions at this time, and since the electric discharge container 2 is made of sapphire, YAG or single crystal yttria, and its reactivity with halogen ions is low, the discharge container 2 can be used for a long time. Furthermore, since, unlike the prior art, the airtight electrical discharge space 23 is formed without using a resin component for the present electric discharge container 2, there is no problem of degradation of such a resin component. Therefore, it is possible to maintain the airtightness of the electric discharge space 23 for a long time.
Since the electric discharge container 2 has ultraviolet-rays permeability, it is possible to emit the 193 nm ultraviolet rays produced in the electrical discharge space 23 to the outside thereof.
The chip pipe 4 is made from a metal member or an alloy member in order to form the sealing portion 41 of the excimer discharge lamp 1 according to the first embodiment. For this reason, at time of lamp lighting, both the low voltage side electrode (hereinafter, for example, the other electrode 32) and the chip pipe 4, are also in a low-voltage state with respect to the high voltage side electrode (hereinafter, for example, one electrode 31), so that an electric field may be generated between the high voltage side electrode 31 and the chip pipe 4. At this time, electric charges are accumulated in the inner face 211 of the side wall 21 on which the high voltage side electrode 31 is provided, so that the electric charges may cause electric discharge toward the chip pipe 4. Therefore, in the excimer discharge lamp 1 according to the first embodiment, at the end wall 222 located on the shortest distance L between the chip pipe 4 and the inner face of the side wall on which the pair of electrodes 31 and 32 is provided, the dividing wall 222a made of sapphire, YAG, or single crystal yttria is formed. The electric resistance nature of the dividing wall 222a is higher than that of the chip pipe 4, and is also higher than the electrodes 31 and 32. For this reason, in the first embodiment, it is possible to make the resistance high, by providing the dividing wall 222a between the chip pipes 4 and the inner face on which the pair of electrodes 31 and 32 is provided, thereby suppressing generation of such electric discharge.
In addition to the first embodiment,
The small diameter hole 222c provided in an end wall 222 is much smaller than the small diameter hole 222c shown in
In the second embodiment, the dividing wall 222a made of sapphire, YAG, or single crystal yttria is formed at the end wall 222 located on the shortest distance L between the chip pipe 4 and the inner face 211 of the side wall 21 on which a pair of electrodes 31 and 32 is provided. Therefore, similar effects to those of the first embodiment can be obtained.
An hole 222c that penetrates the center of the other end wall 222 is formed therein. An annular concave portion 222e, which is not connected to the through hole 222b, is formed in an outside of the other end wall 222, (an outer face in the right hand side of
In the third embodiment, a dividing wall 222a made of sapphire, YAG, or single crystal yttria is formed at the end wall 222 located on the shortest distance L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the pair of electrodes 31 and 32 is provided. Therefore, similar effects to those of the first embodiment can be obtained.
A hole 222b, which extends along the central axis of an electric discharge container 2, is formed in the other side of the end wall 222, and in the middle of the other side end wall 222, this hole 222b extends perpendicular to the central axis of the electric discharge container 2 therefrom, so that an electrical discharge space 23 and the inner side of a chip pipe 4 are connected to each other. The chip pipe is inserted in a hole provided in the end wall 222 and joined thereto by a brazing metal. In the fourth embodiment, a power supply, which is not illustrated, is connected to the pair of electrodes 31 and 32, one of which serves as a high voltage side electrode, and the other one of which serves as a low voltage side electrode. However, a dividing wall 222a made of sapphire, YAG, or single crystal yttria is formed at the end wall 222 located on the shortest distance L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the pair of electrodes 31 and 32 are provided. That is, since in the fourth embodiment, at the end wall 222 located on the shortest distance L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the pair of electrodes 31 and 32 is provided, the dividing wall 222a made of sapphire, YAG, or single crystal yttria is formed, it is possible to obtain similar effects to those of the first embodiment. In addition, the “shortest distance L” according to the fourth embodiment, means, as shown in
Next, an experiment showing effects of the excimer discharge lamp according to the present invention is explained below. In the experiment, three kinds of excimer discharge lamps were prepared. Two of these three kinds of lamps were prepared as comparative examples, and the remaining one was prepared according to the present invention.
The comparative example 1 of
As common portions among these excimer discharge lamps, sapphire was used for the electric discharge container, nickel was used for the chip pipe, copper in form of paste, which was calcinated, was used for the electrode, and argon gas was used for electric discharge gas. As a peculiar structure of the comparative example 1, nickel was used for a cap.
The specification (dimension etc.) common to these excimer discharge lamps will be described below. The width (the length in up-and-down directions in
In the experiment, the electrode was used as the high voltage side electrode, and the chip pipe was connected to a power supply as a ground side electrode, in which voltage (electric discharge starting voltage) was measured until electric discharge started between the electrode and the chip pipe. The electric discharge starting voltage of the respective excimer discharge lamps 1 was measured five times, and the average value thereof was calculated, respectively. Since in the comparative example 1, nickel was used for the cap, the electrical connection was established between the chip pipe and the cap, so that electric discharge begun between the cap and the electrode. On the other hand, since, in the comparative example 2, a sealed electric discharge container 2 was configured so as not to use metal cap, the electric shortest distance L between the electrode and the chip pipe became longer than that of the comparative example 1, so that the insulated space (electrical discharge space) thereof was extended, whereby the electric discharge starting voltage became larger than that of the comparative example 1 by 1.8 kV (p-p). Furthermore, in the present invention, since the dividing wall was provided between the chip pipe and the inner face of the side wall on which the electrode was provided, this dividing wall functions as an insulator, so that electric discharge starting voltage became larger than that of the comparative example 2 by 1.1 kV (p-p).
Thus, according to the present invention, it turned out that the electric discharge starting voltage could be made 70% higher than that in the case of the excimer discharge lamp of the prior art (comparative example 1). That is, since the electric discharge container of the excimer discharge lamp 1 according to the present invention was sealed airtightly without using any metal cap, and since the dividing wall was provided between the chip pipe and the inner face of the side wall on which the electrode was provided, the electric resistance thereof between the electrode and the chip pipe could be made high, and the electric discharge starting voltage could be increased.
The preceding description has been presented only to illustrate and describe exemplary embodiments of the present excimer discharge lamp. It is not intended to be exhaustive or to limit the invention to any precise form disclosed. It will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the claims. The invention may be practiced otherwise than is specifically explained and illustrated without departing from its spirit or scope.
Number | Date | Country | Kind |
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2009-095894 | Apr 2009 | JP | national |