This application claims priority from Japanese Patent Application Serial Nos. 2009-098598 filed Apr. 15, 2009 and 2009-251900 filed Nov. 2, 2009, the contents of which are incorporated herein by reference in their entirety.
The present invention relates to an excimer discharge lamp that emits ultraviolet rays by excimer electric discharge. Further, the present invention relates to an excimer discharge lamp whose electric discharge container is made of sapphire, YAG, or single crystal yttria.
Conventionally, an excimer discharge lamp has been used as an ultraviolet ray light source for a photochemical reaction, such as photo-cleaning, surface alteration and sensitization of a chemical substance. For example, rare gas (such as xenon) and halide (such as fluoride), which are enclosed in this excimer discharge lamp, are known as light emission gas. Halogen or halide is ionized at time of lamp lighting, so as to serve as halogen ions, and the reactivity thereof to other substances becomes very high. For this reason, an electric discharge container encloses the halogen or halide of an excimer discharge lamp must take appropriate measures. Japanese Patent Application Publication No. 06-310106 teaches such an excimer discharge lamp that takes such measures.
The electric discharge container 91 is sealed by the titanium caps, using an O ring 921 made of fluorine contained resin system, so that an airtight electrical discharge space is formed inside the electric discharge container 91. This electrical discharge space is filled up with xenon gas and chlorine as electric discharge gas.
A power supply, which is not illustrated in the figure, is connected to the metal nets 931 and 932, and a high voltage of a high frequency is impressed to start the electric discharge. In the electrical discharge space, excimer electric discharge arises and ultraviolet rays with a wavelength band of 300 to 320 nm resulting from the xenon and chlorine are acquired. Since the sapphire pipe 91 has ultraviolet-rays permeability, the lamp emits the ultraviolet rays to the outside of the lamp 9 by the excimer electric discharge.
In the above-mentioned excimer discharge lamp 9, in order to enclose the electric discharge gas in the electrical discharge space, it is necessary to form a chip pipe in the titanium cap 911. Therefore, an excimer discharge lamp shown in
In
When lighting the excimer discharge lamp 9 shown in
Japanese Patent Application Publication No. 06-310106 teaches that although the cap 911 may be manufactured with high purity alumina, since the chip pipe 94 must be able to be cut off for sealing, it must be manufactured with metal material. Since electric discharge arises at least between the one metal net 931 and the chip pipe 94, the chip pipe 94 is heated, so that the thermal expansion difference occurs at the brazed portion between the cap 911 and the chip pipe 94 so that it may be damaged. Moreover, even though the portion between the cap 911 and the chip pipe 94 is not damaged, when the chip pipe 94 is heated, the O ring 922 is heated through the cap 911, so that the O-ring 922 deteriorates whereby airtightness of the electric discharge container 91 may not be maintained.
It is an object of the present invention to offer an excimer discharge lamp in which electric discharge to a chip pipe is suppressed. The excimer discharge lamp according to the present invention, includes an electric discharge container having an electric discharge space thereinside, a pair of electrodes provided on an outer face of the electric discharge container, electric discharge gas enclosed in the electric discharge space and made of at least rare gas, and halogen or halide. The electric discharge container has a tubular side wall on which the pair of electrodes is formed. One end wall seals one end of the side wall. Another end wall is provided on the other side of the side wall. The side wall and the end walls are made of sapphire, YAG or single crystal yttria. A chip pipe is provided on the another end wall. A partition member that made of sapphire, YAG, or single crystal yttria is formed between a shortest distance of the chip pipe and the inner face of the side wall where the pair of electrodes is formed.
In the excimer discharge lamp according to the first invention, by the above-mentioned feature, it is possible to make electric resistance high between the chip pipe and the inner face where the pair of electrodes is provided to suppress the electric discharge to the chip pipe.
In the excimer discharge lamp, a winding flow path is formed by the partition member and the electric discharge container.
In such a case, by the above-mentioned feature, it is possible to make the distance long between the chip pipe and the inner face of the side wall where the pair of electrodes is provided to suppress the electric discharge to the chip pipe.
In the excimer discharge lamp, a dividing wall made of sapphire, YAG, or single crystal yttria may be provided on the end wall located in the shortest distance between the chip pipe and the inner face of the side wall where the pair of electrodes is provided.
In such a case, it is possible to further make electric resistance high between the chip pipe and the inner face of the side wall where the pair of electrodes is provided to suppress the electric discharge to the chip pipe.
Other features and advantages of the present excimer discharge lamp will be apparent from the ensuing description, taken in conjunction with the accompanying drawings, in which:
The excimer discharge lamp according to the present invention is made up of a straight tube shaped electric discharge container 2, a chip pipe 4 provided at an end of the electric discharge container 2, and a pair of electrodes 31 and 32 that is on an outer face of the electric discharge container 2.
This electric discharge container 2 is made up of a straight tube shaped side wall 21, one end wall 221 in a plate shape on an end of the side wall 21, and another annular end wall 222 at the other end of the side wall 21. The side wall 21 and the end walls 221 and 222 are made of sapphire, YAG, or single crystal yttria. A hole 222b is formed so as to penetrate the center of the other end wall 222.
Part of the outer circumference of the chip pipe 4 is inserted in the hole 222b of the end wall 222. Metallization is performed on a face that forms the hole 222b, and brazing metal such as silver solder, is filled in between the chip pipe 4 and the face. Since the chip pipe 4 is a metal material, such as nickel or an alloy material such as stainless steel, the chip pipe 4 is brazed, through brazing metal, to the face where the metallization is performed. In addition, since there is an active metal brazing method as a method for joining metal and ceramics, the chip pipe 4 may be joined with the other end wall 222 by using this active metal brazing method. Specifically, active metal brazing, which contains active metal such as titanium, is used as brazing metal, and the chip pipe 4 and the face that forms the hole 222b, are joined to each other by the active metal brazing. In the case of the active metal brazing method, the metallization may not be necessarily performed on the face, that forms the hole 222b.
A sealing portion 41 is formed by performing pressure welding on the other end portion (an end portion in the right hand side of the figure) of the chip pipe 4. In this way, an airtight electrical discharge space 23 is formed inside the electric discharge container 2. Rare gas, such as argon (Ar), krypton (Kr) and xenon (Xe); halogen, such as fluoride (F2), chlorine (Cl2), bromine (Br2) and iodine (I2); or halide, such as sulfur hexafluoride (SF6), are enclosed in this electrical discharge space 23 as electric discharge gas.
As show in
In the inside of the electrical discharge container 2, an annular partition member 8 is formed at a shortest distance (portion) L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the pair of electrodes 31 and 32 is provided. This partition member 8 is made of sapphire (single crystal alumina Al2O3), YAG (yttrium aluminum Garnett), or single crystal yttria (Y2O3). The partition member 8 may be joined to the inner face of the electrical discharge container 2 by pressing and heating, which is described below, or may be joined to the inner face of the electric discharge container 2 by an adhesive agent made of, for example, acrylic adhesive. In addition, the “shortest distance L” according to the first embodiment means that, as shown in
Next, an example of a manufacture method of the excimer discharge lamp 1 is explained referring to
For example, three plate members made of sapphire are prepared, and a rectangular hole is formed in one of the plate members so as to penetrate a central part thereof, thereby forming the rectangular member 53. As shown in
As shown in
After grinding the two plate members 51 and 52 and the rectangular member 53 in
After heating in
Although not shown in the figure, the net electrodes 31 and 32 are formed on the pair of the outer faces of the electric discharge container 2. The net electrodes are formed by applying, for example, copper paste in shape of net on the outer faces of the electric discharge container 2 by printing, and then heating the applied copper paste together with the electric discharge container 2 at high temperature, so as to perform calcination on the copper paste. This completes the excimer discharge lamp 1. When the excimer discharge lamp 1 according to the present invention is formed in such a manner, it is possible to form the sealed electric discharge space 23 without using a resin component.
In addition, the electric discharge container 2 may be a rectangular parallelepiped, which is a rectangle in a cross sectional view thereof taken in a direction perpendicular to a longitudinal direction thereof, or may be a cylindrical shape, which is a circle in a cross sectional view thereof.
According to the first embodiment, a power supply, which is not illustrated, is connected to the pair of electrodes 31 and 32 of the excimer discharge lamp 1. Next, description of an operation at lighting time of the excimer discharge lamp 1 is given.
When high voltage of high frequency is supplied to the excimer discharge lamp 1, electric charges are accumulated on the inner face of the electric discharge container 2 on which the high voltage side electrode (for example, one electrode 31) is formed, whereby the electric charges move toward the low voltage side electrode (for example, the other electrode 32). When the electric discharge gas is argon and sulfur hexafluoride, the electric discharge gas is ionized in response to the electric charges, so that argon ions and fluoride ions are formed. The excimer molecules that consist of argon and fluoride are formed from these ions, so that ultraviolet rays with a wavelength of 193 nm are generated. The electric discharge container 2 is exposed to the fluoride ions at this time, and since the electric discharge container 2 is made of sapphire, YAG, or single crystal yttria so that its reactivity with halogen ions is low, the electric discharge container 2 can be used for a long time. Furthermore, since, unlike the prior art, the airtight electrical discharge space 23 is formed without using a resin component for the present electric discharge container 2, there is no degradation problem of such a resin component.
Since the electric discharge container 2 has ultraviolet-rays permeability, it is possible to emit the 193 nm ultraviolet rays produced in the electrical discharge space 23 to the outside thereof.
The chip pipe 4 is made of metal material or an alloy material in order to form the sealing portion 41 of the excimer discharge lamp 1 according to the first embodiment. For this reason, at time of lamp lighting, both the low voltage side electrode (hereinafter, for example, the other electrode 32) and the chip pipe 4, are also in a low-voltage state with respect to the high voltage side electrode (hereinafter, for example, one electrode 31), so that an electric field may be generated between the high voltage side electrode 31 and the chip pipe 4. At this time, electric charges are accumulated in the inner face 211 of the side wall 21 on which the high voltage side electrode 31 is provided, so that the electric charges may cause electric discharge toward the chip pipe 4. There is a high possibility that this electric discharge occurs in the shortest distance (portion) L since the electric discharge tends to occur in a portion where electric resistance thereof is the lowest between the chip pipe 4 and the inner face 211 of the side wall 21 on which the high voltage side electrode 31 is provided. In the excimer discharge lamp 1 according to the first embodiment, the partition member 8 made of sapphire, YAG, or single crystal yttria is formed, in the shortest distance (portion) L between the chip pipe 4 and the inner face of the side wall 21 on which the pair of electrodes 31 and 32 is provided. The electric resistance nature of the partition member 8 is higher than that of the chip pipe 4, and is also higher than the electric resistance nature of the electrodes 31 and 32. For this reason, according to the first embodiment, it is possible to make the resistance high, by providing the partition member 8 between the chip pipes 4 and the inner face on which the pair of electrodes 31 and 32 is provided, thereby suppressing generation of such electric discharge.
In
In addition to the first embodiment,
Since the partition member 8 is in the shape of a plate, the partition member 8 is located not only between the shortest distance L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the pair of electrodes 31 and 32 is provided, but also in every space through which a straight line connecting the chip pipe 4 and the inner face 211 passes. Thereby, the chip pipe 4 and the inner face 211 of the side wall 21 on which a pair of electrodes 31 and 32 is provided, do not face each other directly.
In the first embodiment, since there is a portion of the hole of the center of the partition member 8, where the chip pipe 4 and the inner faces 211 of the side wall 21 on which the pair of electrodes 31 and 32 is provided, face each other directly, electric discharge may arise in the portion in which they face each other, as voltage impressed at time of lamp lighting goes up to high voltage. For this reason, in the second embodiment, since the partition member is provided, so that the chip pipe 4 and the inner face 211 on which the pair of electrodes 31 and 32 is provided, do not face directly each other, it is possible to make the electric resistance high, thereby suppressing generation of such electric discharge.
The lamp 1 shown in
In the third embodiment, the partition members 8 are respectively in a shape of a plate, and the number of these plate shaped partition members 8 is two. When the electric discharge container 2 has the shape for example, of a rectangular parallelepiped, the side wall 21 thereof is made up of four (4) faces. One partition member 8 (on the left hand side in the figures) is formed so as to be brought in contact with three faces of the side wall 21. Although another partition member 8 (on the right hand side in the figures) is also brought in contact with the three faces of the side wall 21, one of the three faces of the side face 21, which is in contact with the another partition member 8, is different from any one of those faces, which is in contact with the one partition member 8, as shown in
In the description of the first embodiment, electric charges, which are accumulated in the inner face 211 of the side wall 21 on which the pair of electrode 31 and 32 is provided, move directly toward the chip pile 4, thereby causing electric discharge between the chip pile 4 and the inner face 211. However, in addition to such electric discharge, there is the so-called creeping discharge, which occurs when the electric charges accumulated in the inner face 211 of the side wall 21 moves along with the inner face of the electric discharge container 2, thereby reaching the chip pipe 4 provided in the electric discharge container 2. In the third embodiment, because the winding flow path formed by the electric discharge container 2 and the pair of partition members 8, a face along which the electric charges move is created. For this reason, in the structure of the third embodiment, the creepage distance between the chip pile 4 and the inner face 211 of the side wall 21 on which the pair of the electrodes 31 and 32 is provided, becomes long so that it is possible to suppress electric discharge to the chip pipe 4, which is the creeping discharge.
Moreover, in the third embodiment, since the chip pipe 4 and the inner face 211 of the side wall 21 on which the pair of electrodes 31 and 32 is provided, do not face each other directly due to the partition members 8, the effects of the first embodiment and the second embodiment can be acquired.
The shape of partition members 8 shown in
The partition members 8 have an L-shaped structure which is respectively bent twice. The pair of partition members 8 is arranged so that an S-shaped winding flow path is formed. Thereby, in the fourth embodiment, the flow path formed by an electric discharge container 2 and a pair of partition plates 8 winds its way for a longer distance than that of the third embodiment.
In the fourth embodiment, since the flow path is formed by the electric discharge container 2 and the partition members 8, the same effects of the third embodiment can be acquired.
The lamp 1 shown in
In the fifth embodiment, the electric resistance between a chip pipes 4 and a side wall 21 on which a pair of electrodes 31 and 32 is provided can be increased, and the winding flow path formed by an electric discharge container 2 and the partition members 8 can be lengthened. Thereby, for the electric charges accumulated in the side wall 21, the creepage distance to the chip pipe 4 is elongated.
In the fifth embodiment, since the flow path is formed by the electric discharge container 2 and the partition members 8, the same effects of the third embodiment can be acquired.
A hole 222b that penetrates a center of another end wall 222 is provided therein. This hole 222b is made up of a small diameter hole 222c located in a left side of the figure, and a large diameter hole 222d, which is continuous from the small diameter hole 222c, and has a larger diameter than that of the small diameter hole 222c. A level difference is formed between the small diameter hole 222c and the large diameter hole 222d, that is, the level difference serves as the dividing wall 222a. This dividing wall 222a is made of sapphire, YAG, or single crystal yttria. Consequently, in the sixth embodiment, the dividing wall 222a is provided on the shortest distance (portion) L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the one electrode 31 is formed, and, in addition, the partition 222a is provided in the shortest distance L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the other electrode 32 is formed.
In the sixth embodiment, in addition to the partition member 8, the dividing wall 222a is formed between the chip pipes 4 and the inner faces 211 of the side wall 21 on which the pair of electrodes 31 and 32 is formed, the electric resistance therebetween can be increased so that it is possible to suppress the electric discharge to the chip pipe 4.
In the seventh embodiment, since the dividing wall 222a is formed, the same effects as those of the sixth embodiment can be acquired. Such a dividing wall 222a may be applied to the first, fourth, and fifth embodiment.
Next, an experiment showing the effects of the excimer discharge lamp according to the second and third embodiments will be described below. In the experiment, three kinds of excimer discharge lamps were prepared. One of these three kinds of lamps was prepared as a comparative example, and the remaining two were prepared according to the present invention. The excimer discharge lamp 1 shown in
Compared with the comparative example, this experiment shows the effects of the suppression of electric discharge in case where the partition member 8 was provided (
In each excimer discharge lamp, the other electrode (not shown in
The common specification of these excimer discharge lamps 1 will be given below. The width of the electric discharge container 2 (the length thereof in an up-and-down direction of
The specification of the partition member 8 according to Invention 1 will be given below. The width thereof (the length thereof in an up and down direction of
The specification of the partition member 8 according to Invention 2 will be given below. The width of the partition member 8 in a left side of
In the experiment, the electrode was used as a high voltage side electrode, and the chip pipe was connected to a power supply as a ground side electrode, voltage (electric discharge starting voltage) was measured until electric discharge started between the electrode and the chip pipe. The electric discharge starting voltage of the respective excimer discharge lamps 1 was measured twelve times respectively, and an average value thereof was calculated, respectively.
In the comparative example, although there were the electric discharge suppression effects since the partition 222a was provided on the end wall 222 that was located on the shortest distance (portion) L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the high voltage side electrode was formed, electric discharge started at an average of 5.1 kV (p-p).
On the other hand, in Invention 1, electric discharge starting voltage was an average of 6.1 kV (p-p), which was 1 kV higher than that of the comparative example, since the partition member 8 was provided in the Invention 1. This is because the partition member 8 was provided in the shortest distance (portion) L between the chip pipe 4 and the inner face 211 of the side wall 21 on which the high voltage side electrode was formed, so that the electric resistance between the shortest distance L was increased. Moreover, since the chip pipe 4 and the inner face 211 of the side wall 21 on which the electrode was formed do not face each other directly due to the partition member 8, the electric resistance could be further increased therebetween so that it was possible to suppress generation of electric discharge therebetween.
In the invention 2, the electric discharge starting voltage became 9 kV (p-p) or more, namely, electric discharge did not start between the high voltage side electrode and the chip pipe 4. Since the flow path was formed by the pair of partition members 8 and the electric discharge container 2, not only the electric resistance could be increased between the chip pipes 4 and the inner face 211 of the side wall 21 on which the electrode was formed, but the creepage distance therebetween could be also lengthened, so that it was possible to suppress the creeping discharge. For this reason, it would appear that even if high voltage of 9 kV (p-p) or more was impressed, electric discharge did not start.
Thus, in the excimer discharge lamp 1 according to the second embodiment, since the partition member 8 was provided between the chip pipe 4 and the inner face 211 of the side wall 21 on which the electrode was provided so as not to face each other directly, it was possible to increase electric resistance therebetween, which suppresses the electric discharge. In addition, in the excimer discharge lamp according to the third embodiment, the pair of partition members 8 is provided between the chip pipe 4 and the inner face 211 of the side wall 21 on which the electrode is formed so as not to face each other, and the winding flow path is formed between the pair of the partition members 8 and the electric discharge container 2, which make it possible to increase the electric resistance therebetween, thereby suppressing not only electric discharge but also creeping discharge.
The preceding description has been presented only to illustrate and describe exemplary embodiments of the present excimer discharge lamp. It is not intended to be exhaustive or to limit the invention to any precise form disclosed. It will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the claims. The invention may be practiced otherwise than is specifically explained and illustrated without departing from its spirit or scope.
Number | Date | Country | Kind |
---|---|---|---|
2009-095873 | Apr 2009 | JP | national |
2009-098598 | Apr 2009 | JP | national |
2009-251900 | Nov 2009 | JP | national |
Number | Name | Date | Kind |
---|---|---|---|
4983881 | Eliasson et al. | Jan 1991 | A |
5444331 | Matsuno et al. | Aug 1995 | A |
5514934 | Matsumoto et al. | May 1996 | A |
5801495 | Smolka et al. | Sep 1998 | A |
5889367 | Hofmann et al. | Mar 1999 | A |
7164223 | Lee | Jan 2007 | B2 |
7772779 | Bang | Aug 2010 | B2 |
7800308 | Ode et al. | Sep 2010 | B2 |
20070285015 | Yasuda | Dec 2007 | A1 |
20100259168 | Moriyasu et al. | Oct 2010 | A1 |
Number | Date | Country |
---|---|---|
64-59754 | Mar 1989 | JP |
H02-007353 | Jan 1990 | JP |
06-310106 | Nov 1994 | JP |
2006-244898 | Sep 2006 | JP |
10-2009-0023065 | Mar 2009 | KR |
Number | Date | Country | |
---|---|---|---|
20100259170 A1 | Oct 2010 | US |