The present invention relates to an exhaust purification device of a compression ignition type internal combustion engine.
Known in the art is an internal combustion engine arranging in an engine exhaust passage an NOX storage catalyst storing NOX contained in exhaust gas when the air-fuel ratio of the inflowing exhaust gas is lean and releasing the stored NOX when the air-fuel ratio of the inflowing exhaust gas becomes a stoichiometric air-fuel ratio or rich. In this internal combustion engine, NOX formed when burning fuel under a lean air-fuel ratio is stored in the NOX storage catalyst. On the other hand, as the NOX storage catalyst approaches saturation of the NOX storage ability, the air-fuel ratio of the exhaust gas is temporarily made rich, whereby NOX is released from the NOX storage catalyst and reduced.
However, fuel and lubrication oil contain sulfur. Therefore, the exhaust gas also contains SOX. This SOX is stored together with the NOX in the NOX storage catalyst. This SOX is not released from the NOX storage catalyst by just making the exhaust gas a rich air-fuel ratio. Therefore, the amount of SOX stored in the NOX storage catalyst gradually increases. As a result, the storable NOX amount ends up gradually decreasing.
However, in this case, the SOX stored in the NOX storage catalyst is gradually released from the NOX storage catalyst if raising the temperature of the NOX storage catalyst and making the exhaust gas flowing into the NOX storage catalyst a rich air-fuel ratio. However, in this case, during the release of SOX, if the NOX storage catalyst falls in temperature, the SOX release action ends up stopping. If the SOX release action ends up stopping once, the SOX release action is not performed until the NOX storage catalyst again rises in temperature. Therefore, if the NOX storage catalyst falls in temperature during release of SOX, getting the SOX released will require a long time.
Therefore, there is known a hybrid diesel engine provided with an electric motor, stopping the operation of the engine when the exhaust temperature falls so as to suppress the flow of low temperature exhaust gas into the NOX storage catalyst and the fall of the NOX storage catalyst in temperature, and using the electric motor at that time to drive the vehicle (for example, see Japanese Patent Publication (A) No. 2005-133563). In this diesel engine, when the NOX storage catalyst falls in temperature, the NOX storage catalyst is not raised in temperature to continue the SOX release action, but it is allowed to stop the SOX release action by the drop in temperature of the NOX storage catalyst.
As opposed to this, there is known an internal combustion engine arranging an SOX trap catalyst able to trap SOX in the exhaust gas in the engine exhaust passage upstream of the NOX storage catalyst (see Japanese Patent Publication (A) No. 2005-133610). In this internal combustion engine, the SOX contained in the exhaust gas is trapped by the SOX trap catalyst, therefore the flow of SOX into the NOX storage catalyst is inhibited.
In this regard, when using such an SOX trap catalyst, if the SOX trap rate falls and SOX flows into the NOX storage catalyst, that is, if the action of the SOX trap catalyst in blocking the flow of SOX into the NOX storage catalyst is stopped, there is no longer any meaning to arranging the SOX trap catalyst upstream of the NOX storage catalyst. Therefore, when using such an SOX trap catalyst, it becomes necessary to continue to maintain the SOX trap rate at a high SOX trap rate without the action of blocking the inflow of SOX into the NOX storage catalyst stopping.
In this regard, the SOX trap rate changes along with a change in the engine operating state. If the SOX trap catalyst falls in temperature or the exhaust gas flowing through the SOX trap catalyst becomes higher in spatial velocity, the SOX trap rate will fall. At this time, it becomes necessary to make the SOX trap rate rise to continue to maintain the SOX trap rate at a high SOX trap rate, but no consideration is being given to this at all at present.
An object of the present invention is to provide an exhaust purification device of an internal combustion engine able to maintain the SOX trap rate at a high SOX trap rate.
According to the present invention, there is provided an exhaust purification device of compression ignition type internal combustion engine arranging, in an engine exhaust passage, an SOX trap catalyst able to trap SOX contained in exhaust gas and arranging, in the exhaust passage downstream of the SOX trap catalyst, an NOX storage catalyst storing NOX contained in the exhaust gas when the air-fuel ratio of an inflowing exhaust gas is lean and releasing stored NOX when the air-fuel ratio of the inflowing exhaust gas becomes a stoichiometric air-fuel ratio or rich, wherein the device is provided with an electric power device able to generate vehicle drive power separate from the vehicle drive power from the engine and able to generate electric power from the engine, and the vehicle drive power from the engine and the vehicle drive power from the electric power device are adjusted so that a SOX trap rate of the SOX trap catalyst is maintained at a predetermined high SOX trap rate.
Referring to
On the other hand, the exhaust manifold 5 is connected to an inlet of an exhaust turbine 7b of the exhaust turbocharger 7. The outlet of the exhaust turbine 7b is connected to an inlet of a catalyst converter 12. Inside the catalyst converter 12, an SOX trap catalyst 13 and NOX storage catalyst 14 are arranged in order from the upstream side. Inside the catalyst converter 12 between the SOX trap catalyst 13 and the NOX storage catalyst 14, a temperature sensor 15 for detecting the temperature of the exhaust gas flowing out from the SOX trap catalyst 13 is provided. In the embodiment according to the present invention, the temperature of the SOX trap catalyst 13 is estimated from the detection value of this temperature sensor 15. Further, inside the exhaust manifold 5, a reducing agent feed valve 16 for feeding a reducing agent comprised of for example a hydrocarbon into the exhaust manifold 5 is attached.
The exhaust manifold 5 and intake manifold 4 are connected to each other through an exhaust gas recirculation (hereinafter referred to as “EGR”) passage 17. Inside the EGR passage 17, an electronic control type EGR control valve 18 is arranged. Further, around the EGR passage 17, a cooling device 19 for cooling the EGR gas flowing through the EGR passage 17 is arranged. In the embodiment shown in
On the other hand, in the embodiment shown in
Further, the electric motor 27 coupled with the output shaft 26 of the transmission 25 comprises an electric power device able to generate vehicle drive power separate from the vehicle drive power from the engine and able to generate electric power by the engine. In this embodiment shown in
The electronic control unit 40 is comprised of a digital computer and is provided with a ROM (read only memory) 42, RAM (random access memory) 43, CPU (microprocessor) 44, input port 45, and output port 46 which are connect to each other by a bi-directional bus 41. The output signals of the intake air detector 8 and the temperature sensor 15 are input through corresponding AD converters 47 to an input port 45. Further, the input port 45 receives as input various signals showing the gear of the transmission 25, the rotational speed of the output shaft 26, etc.
On the other hand, the accelerator pedal 32 is connected to a load sensor 33 generating an output voltage proportional to the amount of depression L of an accelerator pedal 32. The output voltage of the load sensor 33 is input through a corresponding AD converter 47 to the input port 45. Further, the input port 45 is connected to a crank angle sensor 34 generating an output pulse each time the crankshaft rotates by for example 10°. On the other hand, the output port 46 is connected through a corresponding drive circuit 48 to the fuel injector 3, the reducing agent feed valve 16, EGR control valve 18, transmission 25, motor drive control circuit 30, etc.
The feed of electric power from the electric motor 27 to the excitation coil of the stator 29 is normally stopped. At this time, the rotor 28 rotates together with the output shaft 26 of the transmission 25. On the other hand, when driving the electric motor 27, the DC high voltage of the battery 31 is converted at the motor drive control circuit 30 to a three-phase alternating current of a frequency of fm and a current value of Im, and this three-phase alternating current is fed to the excitation coil of the stator 29. This frequency fm is the frequency required for making the rotating magnetic field generated by the excitation coil rotate in synchronization with the rotation of the rotor 28. This frequency fm is calculated by a CPU 44 based on the rotational speed of the output shaft 26. At the motor drive control circuit 30, this frequency fm is made the frequency of the three-phase alternating current.
On the other hand, the output torque of the electric motor 27 is substantially proportional to the current value Im of the three-phase alternating current. This current value Im is calculated at the CPU 44 based on the required output torque of the electric motor 27. In the motor drive control circuit 30, this current value Im is made the current value of the three-phase alternating current.
Further, if driving the electric motor 27 by external force, the electric motor 27 operates as a generator. At this time, the generated electric power is recovered by the battery 31. Whether to use external force to drive the electric motor 27 is judged by the CPU 44. When it is judged that external force should be used to drive the electric motor 27, a motor control circuit 3 is used to control the electric motor 27 so that the generated electric power is recovered at the battery 31.
Next, the NOX storage catalyst 14 shown in
In the embodiment according to the present invention, as the precious metal catalyst 61, platinum Pt is used. As the ingredient forming the NOX absorbent 62, for example, at least one element selected from potassium K, sodium Na, cesium Cs, and other such alkali metals, barium Ba, calcium Ca, and other such alkali earths, lanthanum La, yttrium Y, and other rare earths is used.
If the ratio of the air and fuel (hydrocarbons) fed into the engine intake passage, combustion chamber 2, and exhaust passage upstream of the NOX storage catalyst 14 is called the “air-fuel ratio of the exhaust gas”, an NOX absorption and release action such that the NOX absorbent 62 absorbs the NOX when the air-fuel ratio of the exhaust gas is lean and releases the absorbed NOX when the oxygen concentration in the exhaust gas falls is performed.
That is, explaining this taking as an example the case of using barium Ba as the ingredient forming the NOX absorbent 62, when the air-fuel ratio of the exhaust gas is lean, that is, the oxygen concentration in the exhaust gas is high, the NO contained in the exhaust gas, as shown in
As opposed to this, for example if the reducing agent feed valve 16 feeds the reducing agent to make the exhaust gas a rich air-fuel ratio or stoichiometric air-fuel ratio, the oxygen concentration in the exhaust gas falls, so the reaction proceeds in the reverse direction (NO3−→NO2), therefore the nitrate ions NO3− in the NOX absorbent 62 are released in the form of NO2 from the NOX absorbent 62. Next, the released NOX is reduced by the unburned HC and CO contained in the exhaust gas.
In this way, when the air-fuel ratio of the exhaust gas is lean, that is, when burning the fuel under a lean air-fuel ratio, the NOX in the exhaust gas is absorbed in the NOX absorbent 62. However, when the fuel continues to be burned under a lean air-fuel ratio, the NOX absorbent 62 eventually ends up becoming saturated in NOX absorption ability, therefore the NOX absorbent 62 ends up becoming unable to absorb the NOX. Therefore, in this embodiment of the present invention, before the NOX absorbent 62 becomes saturated in absorption ability, the reducing agent is fed from the reducing agent feed valve 16 to make the exhaust gas temporarily rich air-fuel ratio and thereby make the NOX absorbent 62 release the NOX.
On the other hand, the exhaust gas contains SOX, that is, SO2. If this SO2 flows into the NOX storage catalyst 62, this SO2 is oxidized on the platinum Pt 61 and becomes SO3. Next, this SO3 is absorbed in the NOX absorbent 62, bonds with the barium oxide BaO, is diffused in the form of sulfate ions SO42− in the NOX absorbent 62, and forms stable sulfate BaSO4. However, the NOX absorbent 62 has a strong basicity, so this sulfate BaSO4 is stable and hard to break down. If just making the exhaust gas rich air-fuel ratio, the sulfate BaSO4 remains as is without breaking down. Therefore, in the NOX absorbent 62, the sulfate BaSO4 increases along with the elapse of time, therefore the NOX amount which the NOX absorbent 62 can absorb falls along with the elapse of time.
In this regard, in this case, if making the air-fuel ratio of the exhaust gas flowing into the NOX storage catalyst 14 rich in the state where the temperature of the NOX storage catalyst 14 is made to rise to the SOX release temperature of 600° C. or more, the NOX absorbent 62 releases SOX. However, in this case, the NOX absorbent 62 only releases a little SOX at a time. Therefore, to make the NOX absorbent 62 release all of the absorbed SOX, it is necessary to make the air-fuel ratio rich over a long time, therefore there is the problem that a large amount of fuel or reducing agent becomes necessary. Further, the SOX released from the SOX absorbent 62 is exhausted into the atmosphere. This is also not preferable.
Therefore, in an embodiment of the present invention, the SOX trap catalyst 13 is arranged upstream of the NOX storage catalyst 14 to trap the SOX contained in the exhaust gas by this SOX trap catalyst 13 and thereby prevent SOX from flowing into the NOX storage catalyst 14. Next this SOX trap catalyst 13 will be explained.
Now, the SOX contained in the exhaust gas, that is, SO2, is oxidized on the platinum Pt 67 as shown in
In
Note that the SOX concentration near the surface of the coat layer 66 becomes higher after for example the engine is run over a long distance of about 50,000 km. Therefore, the SOX trap ability of the SOX trap catalyst 13 will not weaken over a long period. Note that when the SOX trap ability weakens, in the embodiment according to the present invention, the temperature of the SOX trap catalyst 13 is made to rise under a lean air-fuel ratio of the exhaust gas by temperature elevation control and thereby the SOX trap ability is restored.
That is, if making the SOX trap catalyst 13 rise in temperature under a lean air-fuel ratio of the exhaust gas, the SOX present concentrated near the surface of the coat layer 66 diffuses toward the deep part of the coat layer 66 so that the SOX concentration in the coat layer 66 becomes uniform. That is, the nitrate produced in the coat layer 66 changes from an unstable state where it concentrates near the surface of the coat layer 66 to the stable state where it diffuses uniformly in the coat layer 66 as a whole. If the SOX present near the surface of the coat layer 66 diffuses toward the deep part of the coat layer 66, the SOX concentration near the surface of the coat layer 66 falls, therefore when control for raising the temperature of the SOX trap catalyst 13 ends, the SOX trap ability is restored.
As explained above, the SOX trap catalyst 13 will not weaken in SOX trap ability over a long period of time. However, the SOX trap rate changes in accordance with the engine operating state. This change of the SOX trap rate is shown in
If the SOX trap rate falls, the SOX passing through the SOX trap catalyst 13 flows into the NOX storage catalyst 14. If the SOX flows into the NOX storage catalyst 14 in this way, that is, if the action of the SOX trap catalyst 13 in blocking the inflow of SOX into the NOX storage catalyst 14 is stopped, there is no longer any meaning to arranging the SOX trap catalyst 13 upstream of the NOX storage catalyst 14. Therefore, when using the SOX trap catalyst 13, it becomes necessary to maintain the SOX trap rate at a high SOX trap rate without the action of blocking inflow of SOX to the NOX storage catalyst 14 stopping.
Therefore, in the present invention, the vehicle drive power from the engine and the vehicle drive power from the electric power device are adjusted so as to utilize the electric power device to maintain the SOX trap rate of the SOX trap catalyst 13 at a predetermined high SOX trap rate, for example substantially 100%.
That is, when the temperature T of the SOX trap catalyst 13 is lower than the limit temperature To, if increasing the vehicle drive power from the engine, the exhaust temperature rises and therefore the temperature T of the SOX trap catalyst 13 can be made higher than the limit temperature To. However, if at this time the amount of intake air Ga is lower than the limit amount of air Go, the SOX trap rate rises to the predetermined high SOX trap rate, but when the amount of intake air Ga is greater than the limit amount of air Go, the SOX trap rate cannot rise to the predetermined high SOX trap rate.
Therefore, in the embodiment according to the present invention, when the temperature T of the SOX trap catalyst 13 is less than the limit temperature To, the vehicle drive power from the engine and the vehicle drive power from the electric power device are adjusted in accordance with whether the SOX trap rate becomes a predetermined high SOX trap rate when increasing the output torque of the engine.
That is, specifically speaking, when increasing the output torque of the engine, when the SOX trap rate becomes a predetermined high SOX trap rate, the output torque of the engine is increased from the required torque. To explain this,
That is, for example assume now the operating state shown by the point A in
Further, in this embodiment, when the output torque of the engine is made to increase by ΔTQ, the increase ΔTQ of the output torque is made to be consumed for the generation of electric power by the electric power device so that the vehicle drive power is not increased. That is, at this time, the electric power device is operated as a generator and the increase ΔTQ of the output torque is used for the action of the generator of generating power.
As opposed to this, the temperature T of the SOX trap catalyst 13 becomes less than the limit temperature To, and when the SOX trap rate will not become a predetermined high SOX trap rate even if increasing the output torque of the engine, that is, when the amount of intake air Ga is greater than the limit amount of air Go, SOX continues to flow into the NOX storage catalyst 14 even if increasing the output torque of the engine. Therefore, there is no longer any meaning in arranging the SOX trap catalyst 13 upstream of the NOX storage catalyst 14. Therefore, at this time, the engine is stopped and the vehicle is driven by the electric power device. That is, at this time, if the output torque of the engine is for example the output torque shown by the point A in
In this way, in the embodiment according to the present invention, when the temperature T of the SOX trap catalyst 13 becomes less than the limit temperature To and the amount of intake air Ga is greater than the limit amount of air Go, the engine is stopped. Such an operating state mainly occurs at the time of engine warmup operation. Therefore, at the time of engine warmup operation, sometimes the engine is stopped.
On the other hand, in the embodiment according to the present invention, when the temperature T of the SOX trap catalyst 13 is higher than the limit temperature To, the vehicle is driven by the engine so long as the SOX trap rate does not drop due to a reason other then the drop of the temperature of the SOX trap catalyst 13. As opposed to this, when the temperature T of the SOX trap catalyst 13 is higher than the limit temperature To, when the amount of intake air Ga becomes greater than even the limit amount of air Go and the SOX trap rate falls, to lower the temperature T of the SOX trap catalyst 13, the output torque of the engine is decreased from the required torque. At this time, to prevent the drive power of the vehicle from changing, the decrease in the output torque is made up for by the vehicle drive power from the electric power device.
That is, for example, now assume the operating state shown by the point B in
Referring to
As will be understood from
As opposed to this, when it is judged at step 72 that G>Go, to make the SOX trap rate rise to substantially 100%, the routine proceeds to step 77, where the output torque of the engine is gradually decreased. That is, first, at step 77, the torque decrease correction amount ΔTQD is increased by a constant value α. Next, at step 78, the required torque TQ calculated at step 70 is decreased by the torque decrease correction amount ΔTQD and the result is made the final required torque of the engine TQe (=TQ−ΔTQD). Next, at step 79, the fuel injection is controlled so as to obtain the final required torque TQe.
Next, at step 80, the torque decrease correction amount ΔTQD is made the output torque TQm of the electric motor 27 for driving the vehicle. Next, at step 81, the electric motor 27 is driven so as to generate the output torque TQm. Next, at step 82, the torque increase correction amount ΔTQU is cleared.
On the other hand, when it is judged at step 71 that T≦To, the routine proceeds to step 83 where it is judged if the amount of intake air G is larger than the limit amount of air Go. When G≦Go, the SOX trap catalyst 13 is raised in temperature, whereby the SOX trap rate can be made substantially 100%. Therefore, when G≦Go, the routine proceeds to step 84 where the output torque of the engine is gradually increased.
That is, first, at step 84, the torque increase correction amount ΔTQU is increased by a constant value β. Next, at step 85, the required torque TQ calculated at step 70 is increased by the torque increase correction amount ΔTQU and the result is made the final required torque of the engine TQe (=TQ+ΔTQU). Next, at step 86, fuel injection is controlled so that this final required torque TQe is obtained.
Next, at step 87, the electric motor 27 is made to operate as a generator, and the torque increase correction amount ΔTQU is consumed for generating power. Next, at step 88, the torque decrease correction amount ΔTQD is cleared.
As opposed to this, when it is judged at step 83 that G>Go, even if adjusting the output torque of the engine, the SOX trap rate cannot be raised to substantially 100%. Therefore, at this time, the routine proceeds to step 89 where the engine is stopped. Next, at step 90, the required torque TQ calculated at step 70 is made the output torque TQm of the electric motor 27 for driving the vehicle. Next, at step 91, the electric motor 27 is driven so as to generate the output torque TQm. At this time, the transmission 25 is set to the neutral position. Next, the routine proceeds to step 76.
Next, another embodiment of the electric power device will be explained with reference to
If referring to
Explanation of the detailed operation of this electric power device will be omitted, but generally speaking, the motor/generator 100 mainly operates as an electric motor, while the motor/generator 101 mainly operates as a generator.
That is, when driving the vehicle by only the output of the internal combustion engine 1, the rotation of the motor/generator 101 is stopped. At this time, when the output shaft 111 of the internal combustion engine 1 rotates, the ring gear 104 is made to rotate. If the ring gear 104 is made to rotate, the rotational force of the ring gear 104 is transmitted through the belt 109 to the output shaft 110 whereby the vehicle is driven. At this time, the motor/generator 100 is idling.
On the other hand, if driving the vehicle by only electric power, the operation of the internal combustion engine 1 is stopped and the vehicle is driven by the motor/generator 100. That is, if the motor/generator 100 is made to rotate, the ring gear 104 is made to rotate, the rotational power of the ring gear 104 is transmitted through the belt 109 to the output shaft 110, and thereby the vehicle is driven. On the other hand, at this time, the planetary carrier 106 is not rotating, so if the ring gear 104 rotates, the sun gear 103 is made to rotate. At this time, the motor/generator 101 is idling.
On the other hand, when superposing electric power on the drive power of the internal combustion engine, the motor/generator 100 is driven in addition to the internal combustion engine 1. At this time, the rotational force of the planetary carrier 106 is superposed on the rotational force of the ring gear 104. On the other hand, at this time, the motor/generator 101 acts to generate power.
Number | Date | Country | Kind |
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2007-016196 | Jan 2007 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2008/051464 | 1/24/2008 | WO | 00 | 1/21/2009 |