Statutory regulations require pressure isolation, among other things, across reservoir zones in a subterranean well during plug and abandonment of the well. In this context, wellbore tubulars through such permeable zones may be required to be pressure-isolated at both the outside and the inside of the particular wellbore tubular in the well.
Reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:
In the drawings and descriptions that follow, like parts are typically marked throughout the specification and drawings with the same reference numerals, respectively. The drawn figures are not necessarily to scale. Certain features of the disclosure may be shown exaggerated in scale or in somewhat schematic form and some details of certain elements may not be shown in the interest of clarity and conciseness. The present disclosure may be implemented in embodiments of different forms.
Specific embodiments are described in detail and are shown in the drawings, with the understanding that the present disclosure is to be considered an exemplification of the principles of the disclosure, and is not intended to limit the disclosure to that illustrated and described herein. It is to be fully recognized that the different teachings of the embodiments discussed herein may be employed separately or in any suitable combination to produce desired results.
Unless otherwise specified, use of the terms “connect,” “engage,” “couple,” “attach,” or any other like term describing an interaction between elements is not meant to limit the interaction to a direct interaction between the elements and may also include an indirect interaction between the elements described. Unless otherwise specified, use of the terms “up,” “upper,” “upward,” “uphole,” “upstream,” or other like terms shall be construed as generally away from the bottom, terminal end of a well; likewise, use of the terms “down,” “lower,” “downward,” “downhole,” or other like terms shall be construed as generally toward the bottom, terminal end of a well, regardless of the wellbore orientation. Use of any one or more of the foregoing terms shall not be construed as denoting positions along a perfectly vertical axis. Unless otherwise specified, use of the term “subterranean formation” shall be construed as encompassing both areas below exposed earth and areas below earth covered by water such as ocean or fresh water.
Many of today's subterranean wells, particularly intelligent completions, employ one or more control lines that run alongside the wellbore tubular, often in an annulus between the wellbore tubular and the wellbore. Unfortunately, traditional plugging and abandonment techniques employing cement have difficulties sealing the control lines. As such, fluid/gas can later migrate though the control lines from the wellbore and/or reservoir to the surface since the control lines can be vertical leak paths through the cement barriers.
Based at least in part upon the foregoing, the present disclosure has envisioned using expandable metal as part of the control lines and/or the overall control line system to prevent undesired fluid communication (e.g., from within the control line) when the expandable metal is intentionally or accidently exposed to certain reactive fluids. For example, the expandable metal can react when unexpectedly exposed to a reactive fluid (e.g., ocean water) to self-plug the affected control line and prevent hydrocarbons contaminating the seabed. In an alternative embodiment, control lines downhole can be intentionally exposed to a specific reactive fluid (e.g., brine) to create control line barriers at specific places in the control line system. This can be used in place of, or in conjunction with typical cementing or traditional plugging methods to provide a more reliable method of placing barriers in the control line system. Another benefit of expandable metal used in the control line system is to self-heal and plug control line leaks that occur downhole, ultimately reducing workovers and increase the robustness of the downhole system.
Referring to
The wellbore 120 may be drilled into the subterranean formation 130 using any suitable drilling technique. In the example illustrated in
In accordance with the disclosure, the wellbore 120 may include a wellbore tubular 150. The wellbore tubular 150, in the illustrated embodiment of
In the illustrated embodiment of
Further to the embodiment of
The term expandable metal, as used herein, refers to the expandable metal in a pre-expansion form. Similarly, the term expanded metal, as used herein, refers to the resulting expanded metal after the expandable metal has been subjected to reactive fluid, as discussed below. The expanded metal, in accordance with one or more aspects of the disclosure, comprises a metal that has expanded in response to hydrolysis. In certain embodiments, the expanded metal includes residual unreacted metal. For example, in certain embodiments the expanded metal is intentionally designed to include the residual unreacted metal. The residual unreacted metal has the benefit of allowing the expanded metal to self-heal if cracks or other anomalies subsequently arise, or for example to accommodate changes in the tubular or mandrel diameter due to variations in temperature and/or pressure. Nevertheless, other embodiments may exist wherein no residual unreacted metal exists in the expanded metal.
The expandable metal, in some embodiments, may be described as expanding to a cement like material. For example, the expandable metal may go from metal to micron-scale particles and then these particles expand and lock together to, in essence, seal two or more surfaces together. The reaction may, in certain embodiments, occur in less than 2 days in a reactive fluid and in certain temperatures. Nevertheless, the time of reaction may vary depending on the reactive fluid, the expandable metal used, the downhole temperature, and surface-area-to-volume ratio (SA:V) of the expandable metal.
In some embodiments, the reactive fluid may be a brine solution such as may be produced during well completion activities, and in other embodiments, the reactive fluid may be one of the additional solutions discussed herein, including ocean water, wellbore fluid, etc. The expandable metal is electrically conductive in certain embodiments. The expandable metal, in certain embodiments, has a yield strength greater than about 2,000 psi, e.g., 2,000 psi +/−50%. In yet another embodiment, the expandable metal has a yield strength greater than about 8,000 psi, e.g., 8,000 psi +/−50%. In even yet another embodiment, the expandable metal has a yield strength greater than about 15,000 psi, e.g., 15,000 psi +/−50%.
The hydrolysis of the expandable metal can create a metal hydroxide. The formative properties of alkaline earth metals (Mg—Magnesium, Ca—Calcium, etc.) and transition metals (Zn—Zinc, Al—Aluminum, etc.) under hydrolysis reactions demonstrate structural characteristics that are favorable for use with the present disclosure. Hydration results in an increase in size from the hydration reaction and results in a metal hydroxide that can precipitate from the fluid.
The hydration reactions for magnesium is:
Mg+2H2O→Mg(OH)2+H2,
where Mg(OH)2 is also known as brucite. Another hydration reaction uses aluminum hydrolysis. The reaction forms a material known as Gibbsite, bayerite, boehmite, aluminum oxide, and norstrandite, depending on form. The possible hydration reactions for aluminum are:
Al+3H2O→Al(OH)3+3/2H2.
Al+2H2O→Al O(OH)+3/2H2
Al+3/2H2O→½Al2O3+3/2H2
Another hydration reaction uses calcium hydrolysis. The hydration reaction for calcium is:
Ca+2H2O→Ca(OH)2+H2,
Where Ca(OH)2 is known as portlandite and is a common hydrolysis product of Portland cement. Magnesium hydroxide and calcium hydroxide are considered to be relatively insoluble in water. Aluminum hydroxide can be considered an amphoteric hydroxide, which has solubility in strong acids or in strong bases. Alkaline earth metals (e.g., Mg, Ca, etc.) work well for the expandable metal, but transition metals (Al, etc.) also work well for the expandable metal. In one embodiment, the metal hydroxide is dehydrated by the swell pressure to form a metal oxide.
In at least one embodiment, the expandable metal is a non-graphene based expandable metal. By non-graphene based material, it is meant that is does not contain graphene, graphite, graphene oxide, graphite oxide, graphite intercalation, or in certain embodiments, compounds and their derivatized forms to include a function group, e.g., including carboxy, epoxy, ether, ketone, amine, hydroxy, alkoxy, alkyl, aryl, aralkyl, alkaryl, lactone, functionalized polymeric or oligomeric groups, or a combination comprising at least one of the forgoing functional groups. In at least one other embodiment, the expandable metal does not include a matrix material or an exfoliatable graphene-based material. By not being exfoliatable, it is meant that the expandable metal is not able to undergo an exfoliation process. Exfoliation as used herein refers to the creation of individual sheets, planes, layers, laminae, etc. (generally, “layers”) of a graphene-based material; the delamination of the layers; or the enlargement of a planar gap between adjacent ones of the layers, which in at least one embodiment the expandable metal is not capable of.
In yet another embodiment, the expandable metal does not include graphite intercalation compounds, wherein the graphite intercalation compounds include intercalating agents such as, for example, an acid, metal, binary alloy of an alkali metal with mercury or thallium, binary compound of an alkali metal with a Group V element (e.g., P, As, Sb, and Bi), metal chalcogenide (including metal oxides such as, for example, chromium trioxide, PbO2, MnO2, metal sulfides, and metal selenides), metal peroxide, metal hyperoxide, metal hydride, metal hydroxide, metals coordinated by nitrogenous compounds, aromatic hydrocarbons (benzene, toluene), aliphatic hydrocarbons (methane, ethane, ethylene, acetylene, n-hexane) and their oxygen derivatives, halogen, fluoride, metal halide, nitrogenous compound, inorganic compound (e.g., trithiazyl trichloride, thionyl chloride), organometallic compound, oxidizing compound (e.g., peroxide, permanganate ion, chlorite ion, chlorate ion, perchlorate ion, hypochlorite ion, As2O5, N2O5, CH3ClO4, (NH4)2S2O8, chromate ion, dichromate ion), solvent, or a combination comprising at least one of the foregoing. Thus, in at least one embodiment, the expandable metal is a structural solid expanded metal, which means that it is a metal that does not exfoliate and it does not intercalate. In yet another embodiment, the expandable metal does not swell by sorption.
In an embodiment, the expandable metal used can be a metal alloy. The expandable metal alloy can be an alloy of the base expandable metal with other elements in order to either adjust the strength of the expandable metal alloy, to adjust the reaction time of the expandable metal alloy, or to adjust the strength of the resulting metal hydroxide byproduct, among other adjustments. The expandable metal alloy can be alloyed with elements that enhance the strength of the metal such as, but not limited to, Al—Aluminum, Zn—Zinc, Mn—Manganese, Zr—Zirconium, Y—Yttrium, Nd—Neodymium, Gd—Gadolinium, Ag—Silver, Ca—Calcium, Sn—Tin, and Re—Rhenium, Cu—Copper. In some embodiments, the expandable metal alloy can be alloyed with a dopant that promotes corrosion, such as Ni—Nickel, Fe—Iron, Cu—Copper, Co—Cobalt, Ir—Iridium, Au—Gold, C—Carbon, Ga—Gallium, In—Indium, Mg—Mercury, Bi—Bismuth, Sn—Tin, and Pd—Palladium. The expandable metal alloy can be constructed in a solid solution process where the elements are combined with molten metal or metal alloy. Alternatively, the expandable metal alloy could be constructed with a powder metallurgy process. The expandable metal can be cast, forged, extruded, sintered, welded, mill machined, lathe machined, stamped, eroded or a combination thereof. The metal alloy can be a mixture of the metal and metal oxide. For example, a powder mixture of aluminum and aluminum oxide can be ball-milled together to increase the reaction rate.
Optionally, non-expanding components may be added to the starting metallic materials. For example, ceramic, elastomer, plastic, epoxy, glass, or non-reacting metal components can be embedded in the expandable metal or coated on the surface of the expandable metal. In yet other embodiments, the non-expanding components are metal fibers, a composite weave, a polymer ribbon, or ceramic granules, among others. Alternatively, the starting expandable metal may be the metal oxide. For example, calcium oxide (CaO) with water will produce calcium hydroxide in an energetic reaction. Due to the higher density of calcium oxide, this can have a 260% volumetric expansion (e.g., converting 1 mole of CaO may cause the volume to increase from 9.5cc to 34.4cc). In one variation, the expandable metal is formed in a serpentinite reaction, a hydration and metamorphic reaction. In one variation, the resultant material resembles a mafic material. Additional ions can be added to the reaction, including silicate, sulfate, aluminate, carbonate, and phosphate. The metal can be alloyed to increase the reactivity or to control the formation of oxides.
The expandable metal can be configured in many different fashions, as long as an adequate volume of material is available for sealing the leak. For example, the expandable metal may be formed into a single long member, multiple short members, rings, among others. In at least one embodiment, the control line tubular has a length (Lt) between exposed ends, the sleeve of expandable metal has a length (Ls), and the length (Ls) is at least 25% of the length (Lt). In yet another embodiment, the length (Ls) is at least 50% of the length (Lt). In even yet another embodiment, the length (Ls) is at least 75% of the length (Lt), or even at least 90%. In one optional embodiment, the length (Ls) is equal to the length (Lt). (See, for example, the control line tubular 210 and the sleeve of expandable metal 200 illustrated in the embodiment of
Additionally, a barrier layer may be applied to one or more portions of the expandable metal to delay the expanding reactions. For example, the barrier layer could be positioned between the control line tubular and the sleeve of expandable metal. In yet another embodiment, the barrier layer coats an inside surface of the sleeve of expandable metal. In one embodiment, the material configured to delay the hydrolysis process is a fusible alloy. In another embodiment, the material configured to delay the hydrolysis process is a eutectic material. In yet another embodiment, the material configured to delay the hydrolysis process is a wax, oil, or other non-reactive material.
The well system 100 illustrated in the embodiment of
Turning to
Additionally, in at least one embodiment, the width (Wt) of the control line tubular 210 is no greater than 50 mm. In another embodiment, the width (Wt) of the control line tubular 210 is no greater than 26 mm, and in yet another embodiment no greater than 13 mm. Additionally, in at least one embodiment, the wall thickness (Tt) of the control line tubular 210 is no greater than 6 mm. In another embodiment, the wall thickness (Tt) of the control line tubular 210 is no greater than 3 mm, and in yet another embodiment no greater than 1 mm.
The control line tubular 210 may comprise many different shapes and remain within the scope of the disclosure. In at least one embodiment, however, a cross-sectional shape of the control line tubular 210 is circular or oval. Notwithstanding, a polygonal or other cross-sectional shape is within the scope of the disclosure.
The control line tubular 210 may additionally comprise many different materials and remain within the scope of the disclosure. In at least one embodiment, the control line tubular 210 comprises a metal, such as nickel alloy, stainless steel, aluminum, copper, etc. In yet another embodiment, the control line tubular 210 comprises a composite material, or any other known or hereafter discovered material that might be used for the control line tubular 210.
The control line 200, in accordance with the disclosure, may additionally include a sleeve of expandable metal 220 positioned within the control line tubular 210. The sleeve of expandable metal 220, in the illustrated embodiment, comprises a metal configured to expand in response to hydrolysis to seal the control line tubular 210 when contacting a reactive fluid. The expandable metal, in certain embodiments, comprises one or more of the metals discussed in the paragraphs above.
The sleeve of expandable metal 220, in the illustrated embodiment, has a length (Ls) (e.g., between exposed ends 215a, 215b) and wall thickness (Ts). In at least one embodiment, the length (Ls) of the sleeve of expandable metal 220 is at least 3 cm. In at least one other embodiment, the length (Ls) of the sleeve of expandable metal 220 is at least 4 m, and in yet another embodiment at least 15 m, if not at least 75 m. In yet another embodiment, the length (Ls) of the sleeve of expandable metal 220 is at least 1000 m. For example, in at least one embodiment the length (Ls) is at least 25% of the length (Lt). In yet another embodiment, the length (Ls) is at least 50% of the length (Lt). In even yet another embodiment, the length (Ls) is at least 75% of the length (Lt), or even at least 90%. In one optional embodiment, the length (Ls) is equal to the length (Lt). Additionally, in at least one embodiment, the wall thickness (Ts) of the sleeve of expandable metal 220 is no greater than 10 mm. In another embodiment, the wall thickness (Ts) of the sleeve of expandable metal 220 is no greater than 3 mm, and in yet another embodiment no greater than 1 mm.
In at least one embodiment, such as shown in
Turning to
In the illustrated embodiment of
Further to the embodiment of
Turning to
Turning to
Turning to
The well system 600 of
Turning to
Turning to
Aspects Disclosed Herein Include:
A. A control line for use in a well system, the control line including: 1) a control line tubular, the control line tubular having a length (Lt), a width (Wt) and wall thickness (Tt); and 2) a sleeve of expandable metal positioned within the control line tubular, the sleeve of expandable metal comprising a metal configured to expand in response to hydrolysis to seal the control line tubular when contacting a reactive fluid
B. A method for sealing a control line, the method including: 1) positioning a control line within a wellbore located in a subterranean formation, the control line including: a) a control line tubular, the control line tubular having a length (Lt), a width (Wt) and wall thickness (Tt); and b) a sleeve of expandable metal positioned within the control line tubular, the sleeve of expandable metal comprising a metal configured to expand in response to hydrolysis; and 2) subjecting an exposed region of the sleeve of expandable metal to a reactive fluid to form an expanded metal seal in the control line tubular.
C. A well system, the well system including: 1) a wellbore located within a subterranean formation; and 2) a control line located in the wellbore, the control line including: a) a control line tubular, the control line tubular having a length (Lt), a width (Wt) and wall thickness (Tt); and b) a sleeve of expandable metal positioned within the control line tubular, the sleeve of expandable metal comprising a metal configured to expand in response to hydrolysis to seal the control line tubular when contacting a reactive fluid.
Aspects A, B, and C may have one or more of the following additional elements in combination: Element 1: further including a barrier layer positioned between the control line tubular and the sleeve of expandable metal. Element 2: further including an electric communication line or optical fiber communication line placed within the control line tubular and the sleeve of expandable metal. Element 3: further including a sleeve of filler material placed within the control line tubular and the sleeve of expandable metal. Element 4: wherein the sleeve of filler material is positioned between the sleeve of expandable metal and the electric communication line or optical fiber communication line. Element 5: wherein the length (Lt) of the control line tubular is at least 4 cm, the width (Wt) of the control line tubular is no greater than 50 mm, and the wall thickness (Tt) of the control line tubular is no greater than 6 mm. Element 6: wherein the sleeve of expandable metal has a length (Ls) and wall thickness (Ts), and further wherein the length (Ls) is at least 3 cm, and the wall thickness (Ts) is no greater than 10 mm. Element 7: wherein the length (Ls) is at least 75% of the length (Lt). Element 8: wherein the length (Ls) is at least 90% of the length (Lt). Element 9: wherein the wall thickness (Ts) of the sleeve of expandable metal is no greater than 3 mm. Element 10: wherein the control line tubular forms at least a portion of a control line splice configured to couple two separate control lines together. Element 11: further including a wellbore tubular located within the wellbore, the control line positioned in an annulus between the wellbore tubular and the wellbore, and further including severing the wellbore tubular and the control line tubular during a plug and abandonment application, the severing creating the exposed region, and further wherein the expanded metal seal seals the control line tubular. Element 12: wherein a crack in the control line forms the exposed region, the expanded metal seal sealing the crack in the control line. Element 13: wherein subjecting the exposed region of the sleeve of expandable metal to the reactive fluid includes intentionally subjecting the exposed region of the sleeve of expandable metal to the reactive fluid. Element 14: wherein subjecting the exposed region of the sleeve of expandable metal to the reactive fluid includes unexpectedly subjecting the exposed region of the sleeve of expandable metal to the reactive fluid. Element 15: further including a wellbore tubular located in the wellbore, the control line located in an annulus between the wellbore tubular and the wellbore. Element 16: further including an electric communication line or optical fiber communication line placed within the control line tubular and the sleeve of expandable metal. Element 17: further including a sleeve of filler material placed within the control line tubular and the sleeve of expandable metal. Element 18: wherein the sleeve of filler material is positioned between the sleeve of expandable metal and the electric communication line or optical fiber communication line. Element 19: wherein the length (Lt) of the control line tubular is at least 4 cm, the width (Wt) of the control line tubular is no greater than 50 mm, and the wall thickness (Tt) of the control line tubular is no greater than 6 mm. Element 20: wherein the sleeve of expandable metal has a length (Ls) and wall thickness (Ts), and further wherein the length (Ls) is at least 3 cm, and the wall thickness (Ts) is no greater than 10 mm. Element 21: wherein the length (Ls) is at least 75% of the length (Lt). Element 22: wherein the length (Ls) is at least 90% of the length (Lt). Element 23: wherein the wall thickness (Ts) of the sleeve of expandable metal is no greater than 3 mm. Element 24: wherein the control line tubular forms at least a portion of a control line splice configured to couple two separate control lines together.
Those skilled in the art to which this application relates will appreciate that other and further additions, deletions, substitutions and modifications may be made to the described embodiments.